EP4053866A1 - Film capacitor element - Google Patents
Film capacitor element Download PDFInfo
- Publication number
- EP4053866A1 EP4053866A1 EP20882048.0A EP20882048A EP4053866A1 EP 4053866 A1 EP4053866 A1 EP 4053866A1 EP 20882048 A EP20882048 A EP 20882048A EP 4053866 A1 EP4053866 A1 EP 4053866A1
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- European Patent Office
- Prior art keywords
- metal
- film
- metal layer
- electrode
- dielectric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003990 capacitor Substances 0.000 title claims abstract description 56
- 239000002184 metal Substances 0.000 claims abstract description 180
- 238000009413 insulation Methods 0.000 claims description 39
- 239000007787 solid Substances 0.000 claims description 6
- 239000010408 film Substances 0.000 description 173
- 239000010410 layer Substances 0.000 description 59
- 239000011104 metalized film Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 238000007751 thermal spraying Methods 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/32—Wound capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/33—Thin- or thick-film capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/012—Form of non-self-supporting electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/015—Special provisions for self-healing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/30—Stacked capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/14—Organic dielectrics
- H01G4/18—Organic dielectrics of synthetic material, e.g. derivatives of cellulose
Definitions
- the present disclosure relates to a film capacitor device.
- Patent Literature 1 A known technique is described in, for example, Patent Literature 1.
- Patent Literature 1 Japanese Patent No. 5984097
- a film capacitor device includes a film stack being rectangular, a first metal electrode, and a second metal electrode.
- the film includes a plurality of dielectric films being stacked.
- Each of the plurality of dielectric films including a metal layer on a surface of the dielectric film and includes, at an edge of the surface of the dielectric film in a first direction, an edge insulation area continuously extending in a second direction perpendicular to the first direction.
- the plurality of dielectric films include adjacent dielectric films in 180° opposite orientations in the first direction on the surface and alternate dielectric films having the edge insulation areas overlapping in a plan view.
- the first metal electrode and the second metal electrode are on a pair of end faces of the film stack in the first direction.
- the metal layer is electrically connected to at least the first metal electrode or the second metal electrode.
- the metal layer electrically connected at least to the first metal electrode includes a common metal layer and a plurality of metal strips.
- the common metal layer is located on another end of the surface in the first direction and extends in the second direction.
- the plurality of metal strips extend in the first direction and are electrically connected to the common metal layer.
- At least one of a pair of end faces of the film stack in the second direction includes a recess continuously extending in a direction in which the plurality of dielectric films are stacked and separating the film stack from the first metal electrode.
- a film capacitor with the structure that forms the basis of a film capacitor device includes either a wound metalized film or metalized films stacked in one direction, which are metal films to be an electrode formed by vapor deposition, on the surface of a dielectric film of, for example, a polypropylene resin.
- the metal films are cut together with the dielectric film.
- the metal films can come in contact with one another at the cut surface and may cause an insulation failure.
- metalized films have exposed film surface portions called insulation margins including no metal film and including grooves or strips with a uniform width (gap strips). These surface portions may include bends that extend obliquely to the direction parallel to the direction in which the insulation margins extend to improve the withstanding pressure at the cut surface of the stack of the metalized films.
- Patent Literature 1 may have much capacitance loss at around the cut surface of the film stack.
- One or more aspects of the present disclosure are directed to a stacked film capacitor device with less capacitance loss.
- a film capacitor device 10 includes, on one surface of a base film, multiple dielectric films 1 and 2 that are stacked alternately. Each of the dielectric films 1 and 2 includes a metal layer 3.
- the metal layer 3 is an interdigital metal layer including multiple metal strips 3a and one common metal layer 3c.
- the metal strips 3a are electrically connected to the common metal layer 3c.
- the metal layer 3 may further include, between the metal strips 3a and the common metal layer 3c, connecting portions 3b that connect the metal strips 3a and the common metal layer 3c together. Each connecting portion 3b connects an end of the metal strip 3a to a side of the common metal layer 3c.
- the metal strips 3 serve as internal electrodes of the capacitor.
- the dielectric films 1 and 2 have the same structure as the structures shown in FIG. 1B and subsequent figures with the difference being their stacking orientations.
- the metal strips 3a are denoted with numerals 1A to 1L or numerals 2A to 2L in this order from an end of the dielectric film as shown in FIGs. 1A and 1C .
- the direction in which the metal strips 3a extend parallel to one another is referred to as a first direction (x-direction), and the direction in which the metal strips 3a align parallel to one another (y-direction perpendicular to x-direction) is referred to as a second direction.
- the films are stacked on one another in a third direction (z-direction in the figures) perpendicular to the first and second directions.
- the obtained stack, or a film stack 4 will be described in detail later.
- the metal strips 3a on the surface of each of the dielectric films 1 and 2 are formed by depositing metal on a base film by vapor deposition.
- Each of the dielectric films 1 and 2 has surface portions each exposed between the metal strips 3a adjacent to each other in y-direction (hereafter, insulation margins S).
- the metal strips 3a are thus electrically insulated from one another.
- Each of the insulation margins S is continuous with an edge insulation area T at an end of the dielectric film in the first direction (x-direction).
- the edge insulation area T continuously extends in the second direction (y-direction).
- the common metal layer 3c is opposite to the edge insulation area T, or more specifically, at the other end of the dielectric films 1 or 2 in the first direction.
- the common metal layer 3c extends in the second direction.
- the metal strips 3a are electrically insulated from one another by the insulation margins S. However, the metal strips 3a are connected to the single common metal layer 3c to allow the metal layer 3 to be electrically conductive across the metal layer 3.
- each connecting portion 3b has the center in the width direction aligned with the center of the corresponding metal strip 3a in the width direction.
- Each connecting portion 3b has the length (width) in the second direction shorter (smaller) than the length (width) of each metal strip 3a in the second direction.
- Each connecting portion 3b functions as a fuse for the corresponding metal strip 3a.
- dielectric breakdown in the base film causes one metal strip 3a to be short-circuited with another metal strip 3a with flow of a current exceeding a specified level, the corresponding connecting portion 3b burns out and causes wire breakage, thus preventing the film capacitor device 10 from disabling its entire functions.
- the base film for the dielectric film 1 or 2 may be formed from an organic resin material such as polypropylene, polyethylene terephthalate, polyarylate, or cyclic olefin polymer.
- the film stack 4 includes the dielectric films 1 and 2 that are adjacent to each other in the vertical direction (z-direction) in the figure and are stacked alternately in 180° opposite orientations in x-direction. More specifically, the dielectric films 1 and 2 are stacked on one another to have their edge insulation areas T each located at an end of the corresponding dielectric film to be alternately opposite to each other in x-direction. Similarly, the dielectric films 1 and 2 are stacked on one another to have the common metal layers 3c each located at another end of the corresponding dielectric film 1 or 2 to be alternately opposite to each other in x-direction.
- the film stack 4 includes, on its two end faces in x-direction, metal electrodes that are formed by metal thermal spraying (hereafter, metal-sprayed electrodes).
- a metal-sprayed electrode at one end in x-direction is referred to as a metal-sprayed electrode 5A (first metal electrode), and a metal-sprayed electrode at the other end in x-direction is referred to as a metal-sprayed electrode 5B (second metal electrode).
- first metal electrode first metal electrode
- a metal-sprayed electrode at the other end in x-direction is referred to as a metal-sprayed electrode 5B (second metal electrode).
- the metal-sprayed electrode 5A is electrically connected to the common metal layer 3c on the dielectric film 1, and is also electrically connected to each metal strip 3a through the common metal layer 3c.
- the metal layer 3 on the dielectric film 1 and the metal-sprayed electrode 5A are electrically insulated by the edge insulation area T.
- the metal-sprayed electrode 5B is electrically connected to the common metal layer 3c on the dielectric film 2, and is also electrically connected to each metal strip 3a through the common metal layer 3c.
- the metal layer 3 on the dielectric film 2 and the metal-sprayed electrode 5B are electrically insulated by the edge insulation area T. Electrically connecting the metal-sprayed electrode 5A or 5B and the common metal layer 3c reliably allows the metal strips 3a to connect to the metal-sprayed electrode 5A or 5B through the common metal layer 3c.
- the film capacitor device 10 according to the embodiment including the metal-sprayed electrodes 5A and 5B has, at its two ends in y-direction (second direction), recesses 11 that separate the metal strips 3a (internal electrodes) from the metal-sprayed electrodes 5A and 5B (external electrodes) as shown in FIG. 1C .
- the film capacitor device 10 has four recesses 11 in total, which are two recesses 11 at one end of the film stack 4 in x-direction and two recesses 11 at the other end.
- Each recess 11 continuously extends in the stacking direction of the film (z-direction) between the metal-sprayed electrode 5A or 5B and the film stack 4, in an area including the interface (boundary) between the metal-sprayed electrode 5A or 5B and the film stack 4, or in an area of the connecting portion 3b.
- the recess 11 is open to an end face of the film stack 4 in y-direction and has a depth D (y-direction) from the end face in y-direction greater than the pitch P, which is the interval between the insulation margins S as described above.
- the recess 11 has a width W (in x-direction) at the end face in y-direction greater than the width of the common metal layer 3c.
- the recess 11 has the width W (x-direction) greater than the smaller one of the width of the insulation margin S in y-direction and the width of the connecting portion 3b in x-direction.
- each recess 11 electrically insulates at least one metal strip 3a located at each of the two ends in y-direction from the metal-sprayed electrode 5A or 5B.
- each recess 11 electrically insulates at least one metal strip 3a located at each of the two ends in y-direction from the metal-sprayed electrode 5A or 5B.
- the film capacitor device 10 has the recesses 11 that separate and electrically insulate one or two of the metal strips 3a at each end of the stacked dielectric film 1 in y-direction from the metal-sprayed electrode 5Ain FIG. 1C .
- the separated and electrically insulated metal strips 3a may be at positions 1A and 1B at the left end in the figure and at positions 1K and 1L at the right end in the figure.
- the recesses 11 separate and electrically insulate one or two metal strips 3a located at each end of the stacked dielectric film 2 in y-direction from the metal-sprayed electrodes 5A and 5B in FIG. 1C .
- the separated and electrically insulated metal strips 3a may be at positions 2K and 2L at the left end not shown in the figure and at positions 2A and 2B at the right end also not shown in the figure.
- a film capacitor including the above film capacitor device 10 may include the metal strips 3a that linearly extend in x-direction.
- This structure includes fewer metal strips 3a to be cut or insulated at each end in y-direction.
- the film capacitor according to the embodiment thus has less capacitance loss at around the cut surface of the stack (each end in y-direction) than a film capacitor with the structure that forms the basis of the film capacitor device according to one or more embodiments of the present disclosure including a device with oblique insulation margins (refer to Patent Literature 1).
- One or two metal strips 3a at each end in y-direction may be cut to the depth D from the end face in y-direction to allow appropriate insulation with the recesses 11. More specifically, each recess 11 may have the depth D about one to three times the pitch P of the insulation margin S as shown in the upper-right area of FIG. 1A . At least one of the metal strips 3a at each end in y-direction may thus be reliably insulated, with the metal strip 3a at the end in y-direction having any width or the width P1 in y-direction of 1A, 2A, 1L, and 2L that varies depending on the cutting position of the film stack 4 in this example.
- FIGs. 5 to 8 are schematic views showing a process for manufacturing a film capacitor device according to an embodiment.
- the direction in which the metal strips 3a continuously extend parallel to one another is referred to as the first direction (x-direction in the figures)
- the direction in which the common metal layer 3c extends y-direction perpendicular to x-direction
- the film stacking direction perpendicular to the first and second directions is referred to as the third direction (z-direction in the figures) as in FIGs. 1A to 1C .
- multiple dielectric films 1 and 2 each including multiple metal strips 3a that continuously extend in x-direction and the common metal layer 3c extending in y-direction on its surface are first stacked alternately in opposite orientations in x-direction. More specifically, the stacked dielectric films 1 and 2 include adjacent dielectric films in 180° opposite orientations in x-direction (first direction) and alternate dielectric films having their edge insulation areas T overlapping in a plan view.
- the dielectric films 1 and 2 have the same structure but different orientations in x-direction.
- the elongated dielectric films 1 and 2 may be stacked with a known method, such as winding the films around a cylindrical core or a polygonal core.
- the imaginary lines (two-dot chain lines) in FIG. 5 indicate the lines along which the films wound around a cylinder or another core are to be cut.
- FIG. 6 is a view of the film stack 4 cut into a predetermined length as viewed from the cut surface (end face in y-direction). As shown in FIG. 6 , the vertically adjacent dielectric films 1 and 2 are slightly displaced (offset) from each other in x-direction in the stacked structure. The common metal layer 3c is thus exposed at the corresponding end face of the film stack 4 in x-direction.
- the film stack 4 in the embodiment includes an insulating layer 12 on its upper surface.
- the insulating layer 12 includes, for example, a dielectric film with no metal layer 3 and serving as a protective layer for the stack.
- the insulating layer 12 may be eliminated.
- the first metal electrode (metal-sprayed electrode 5A) and the second metal electrode (metal-sprayed electrode 5B) are then formed by metal thermal spraying onto the two end faces of the film stack 4 in x-direction.
- the common metal layer 3c has its end exposed at the corresponding end face as described above.
- the metal strips 3a on the dielectric films 1 and 2 are thus electrically connected to the corresponding metal-sprayed electrode 5A or 5B through the common metal layer 3c to function as internal electrodes of the device.
- the recesses 11 are formed on the two end faces of the film stack 4 in y-direction, which are the cut surfaces of the stack.
- the recesses 11 are open to the end faces in y-direction, and separate and electrically insulate the metal strips 3a at the cut surfaces from the metal-sprayed electrodes 5A and 5B.
- the film capacitor device 70 includes four recesses 11 in total, which are two recesses 11 at one end of the film stack 4 in y-direction and two recesses 11 at the other end.
- the recesses 11 may be formed to continuously extend in the stacking direction (z-direction) by, for example, machining or cutting.
- the recesses 11 may be, for example, cutouts, slits, or notches.
- Each recess 11 may have the depth D in y-direction at least greater than the pitch P, which is the sum of the width of one metal strip 3a and the width of one insulation margin S. More specifically, the recess 11 may have the depth about one to three times the pitch P to insulate one or two metal strips 3a at each end in y-direction. The recess 11 may have the depth less than or equal to three times the pitch P to avoid increase in the capacitance loss at the ends.
- the width W in x-direction may be greater than the width of the common metal layer 3c in x-direction.
- the width W in x-direction may be greater than the smaller one of the width of one insulation margin S in y-direction and the width of one connecting portion 3b in x-direction.
- the recesses 11 may be between the film stack 4 and the metal-sprayed electrode 5A or 5B in x-direction as in a film capacitor device 20 shown in FIG. 8 or may be in an area including the interface (boundary) between the metal-sprayed electrode 5A or 5B and the film stack 4 as in a film capacitor device 80 shown in FIG. 9 .
- the recesses 11 at the two ends may be in the film stack 4 in an area adjacent to the interface between the metal-sprayed electrode 5A or 5B and the film stack 4.
- each recess 11 is at a distance Q in x-direction from the corresponding end 31 on the dielectric film 1 or from the corresponding end 32 on the dielectric film 2 of another metal strip 3a that is not exposed at the inner surface of the recess 11.
- FIG. 2B is a plan view of the film capacitor device 20 viewed from above showing the positions of the recesses 11 in x-direction.
- the ends 31 of the metal strips 3a on the dielectric film 1 are located inside the film stack 4 in x-direction.
- the above recesses 11 are thus located outward from the ends 31 with the distance Q (adjacent to the metal-sprayed electrode 5A).
- This structure provides reliable electrical insulation from the internal electrodes (metal strips 3a).
- the distance Q between the recesses 11 and the ends 31 or 32 of the metal strips 3a may be at least 200 ⁇ m.
- the structure includes the four recesses 11 in total, which are two recesses 11 at each end in x-direction and in y-direction.
- the structure may include two recesses 11 in total as shown in FIGs. 3A to 3C , which are the recesses 11 between the film stack 4 and the metal-sprayed electrode 5A or 5B at each end in y-direction.
- the two recesses 11 may be located at different ends in x-direction that are diagonal to each other on the xy plane of a film capacitor device 30 or may be located at ends in y-direction at the same end in x-direction.
- the structure according to another embodiment may include three recesses 11 in total, which are two recesses 11 between the film stack 4 and the metal-sprayed electrode 5A at each end in y-direction and one recess 11 between the film stack 4 and the metal-sprayed electrode 5B at one end in y-direction.
- the film stack 4 includes the dielectric films 1 and 2 that are stacked alternately in 180° opposite orientations in x-direction.
- the dielectric films 1 and 2 thus have the same structure but different orientations.
- the film stack 4 includes the dielectric film 1 and a dielectric film 13 that are stacked alternately but have their edge insulation areas T at one end in x-direction in the alternately opposite orientations.
- the dielectric film 13 includes a solid metal layer 3' with a solid pattern that covers the overall area of one surface of the base film except the edge insulation area T. As shown in FIG.
- the film stack 4 includes, on its two ends in x-direction, metal-sprayed electrodes 5A and 5B.
- the metal-sprayed electrode 5A first metal electrode
- the metal-sprayed electrode 5B second metal electrode
- the metal-sprayed electrode 5B is electrically connected to the solid metal layer 3' on the dielectric film 13.
- the structure in the present embodiment may have a recess 11 in an upper (in x-direction) right (in y-direction) end in FIG. 4A to define a space between an end 33 of the solid metal layer 3' and the metal-sprayed electrode 5A.
- the structure may also have a recess 11 in an upper (in x-direction) left (in y-direction) end in the figure. This structure allows insulation of at least one metal strip 3a at an end in y-direction on the dielectric film 1 in the same manner as in the above embodiments.
- the structure may further have a recess 11 in a lower (in x-direction) left or right (in y-direction) end in the figure.
- the number of recesses 11 and their positions may be varied depending on the position and the arrangement pattern of each metal film that serves as an internal electrode, as in the film capacitor devices 30, 40, and 50 in FIGs. 3A to 3C and a film capacitor device 60 in FIGs. 4A and 4B .
- a film capacitor using the film capacitor device 30, 40, 50, or 60 that differs in the number of recesses 11 and their positions may produce the same advantageous effects and functions as a film capacitor including the above film capacitor device 10, 20, 70, 80, or 90.
- the recesses 11 separate and electrically insulate one or two of the metal strips 3a at each end in y-direction (second direction) from the metal-sprayed electrode 5A or 5B.
- This structure reduces the capacitance loss at around the cut surface of the stack (each end in y-direction) as compared with a known film capacitor including a device with oblique insulation margins.
- the film capacitor device according to each of the above embodiments may be used to form a stacked film capacitor with less capacitance loss at the cut surface.
- a film capacitor device includes a film stack being rectangular, a first metal electrode, and a second metal electrode.
- the film includes a plurality of dielectric films being stacked.
- Each of the plurality of dielectric films including a metal layer on a surface of the dielectric film and includes, at an edge of the surface of the dielectric film in a first direction, an edge insulation area continuously extending in a second direction perpendicular to the first direction.
- the plurality of dielectric films include adjacent dielectric films in 180° opposite orientations in the first direction on the surface and alternate dielectric films having the edge insulation areas overlapping in a plan view.
- the first metal electrode and the second metal electrode are on a pair of end faces of the film stack in the first direction.
- the metal layer is electrically connected to at least the first metal electrode or the second metal electrode.
- the metal layer electrically connected at least to the first metal electrode includes a common metal layer and a plurality of metal strips.
- the common metal layer is located on another end of the surface in the first direction and extends in the second direction.
- the plurality of metal strips extend in the first direction and are electrically connected to the common metal layer.
- At least one of a pair of end faces of the film stack in the second direction includes a recess continuously extending in a direction in which the plurality of dielectric films are stacked and separating the film stack from the first metal electrode.
- the stacked film capacitor device has less capacitance loss in a cut portion of the film stack cut in a predetermined direction.
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Abstract
Description
- The present disclosure relates to a film capacitor device.
- A known technique is described in, for example,
Patent Literature 1. - Patent Literature 1:
Japanese Patent No. 5984097 - A film capacitor device according to an aspect of the present disclosure includes a film stack being rectangular, a first metal electrode, and a second metal electrode. The film includes a plurality of dielectric films being stacked. Each of the plurality of dielectric films including a metal layer on a surface of the dielectric film and includes, at an edge of the surface of the dielectric film in a first direction, an edge insulation area continuously extending in a second direction perpendicular to the first direction. The plurality of dielectric films include adjacent dielectric films in 180° opposite orientations in the first direction on the surface and alternate dielectric films having the edge insulation areas overlapping in a plan view. The first metal electrode and the second metal electrode are on a pair of end faces of the film stack in the first direction. The metal layer is electrically connected to at least the first metal electrode or the second metal electrode. The metal layer electrically connected at least to the first metal electrode includes a common metal layer and a plurality of metal strips. The common metal layer is located on another end of the surface in the first direction and extends in the second direction. The plurality of metal strips extend in the first direction and are electrically connected to the common metal layer. At least one of a pair of end faces of the film stack in the second direction includes a recess continuously extending in a direction in which the plurality of dielectric films are stacked and separating the film stack from the first metal electrode.
- The objects, features, and advantages of the present disclosure will become more apparent from the following detailed description and the drawings.
-
-
FIG. 1A is a plan view of a film capacitor device according to an embodiment showing metalized dielectric films. -
FIG. 1B is a schematic cross-sectional view of the film capacitor device showing stacked films. -
FIG. 1C is a plan view of the film capacitor device viewed from above. -
FIG. 2A is a cross-sectional view of a film capacitor device showing the positions of recesses. -
FIG. 2B is a plan view of the film capacitor device showing the positions of the recesses. -
FIG. 3A is a plan view of a film capacitor device according to another embodiment showing the positions of recesses. -
FIG. 3B is a plan view of a film capacitor device according to another embodiment showing the positions of recesses. -
FIG. 3C is a plan view of a film capacitor device according to another embodiment showing the positions of recesses. -
FIG. 4A is a plan view of a dielectric film including a metal layer in a different pattern. -
FIG. 4B is a schematic cross-sectional view of a film stack including the dielectric films including the metal layers in the different pattern. -
FIG. 5 is an exploded perspective view describing a method for manufacturing a film capacitor device according to an embodiment. -
FIG. 6 is an external perspective view of the device including the stacked films. -
FIG. 7 is an external perspective view of the device including metal electrodes formed by thermal spraying. -
FIG. 8 is an external perspective view of the device having recesses for insulation showing the positions of the recesses. -
FIG. 9 is a view of a device according to another embodiment having recesses for insulation at different positions. -
FIG. 10 is a view of a device according to another embodiment having recesses for insulation at different positions. - A film capacitor with the structure that forms the basis of a film capacitor device according to one or more embodiments of the present disclosure includes either a wound metalized film or metalized films stacked in one direction, which are metal films to be an electrode formed by vapor deposition, on the surface of a dielectric film of, for example, a polypropylene resin.
- When a stacked film capacitor is cut into an appropriate size from a stack of metalized films, the metal films are cut together with the dielectric film. The metal films can come in contact with one another at the cut surface and may cause an insulation failure.
- In a film capacitor device described in
Patent Literature 1, metalized films have exposed film surface portions called insulation margins including no metal film and including grooves or strips with a uniform width (gap strips). These surface portions may include bends that extend obliquely to the direction parallel to the direction in which the insulation margins extend to improve the withstanding pressure at the cut surface of the stack of the metalized films. - However, the stacked film capacitor described in
Patent Literature 1 may have much capacitance loss at around the cut surface of the film stack. - One or more aspects of the present disclosure are directed to a stacked film capacitor device with less capacitance loss.
- A film capacitor device according to one or more embodiments will now be described with reference to the drawings. As shown in
FIG. 1A , afilm capacitor device 10 according to an embodiment includes, on one surface of a base film, multipledielectric films dielectric films metal layer 3. - In the present embodiment, the
metal layer 3 is an interdigital metal layer includingmultiple metal strips 3a and onecommon metal layer 3c. Themetal strips 3a are electrically connected to thecommon metal layer 3c. Themetal layer 3 may further include, between themetal strips 3a and thecommon metal layer 3c, connectingportions 3b that connect themetal strips 3a and thecommon metal layer 3c together. Each connectingportion 3b connects an end of themetal strip 3a to a side of thecommon metal layer 3c. - After being stacked, the
metal strips 3 serve as internal electrodes of the capacitor. Thedielectric films FIG. 1B and subsequent figures with the difference being their stacking orientations. To indicate the orientations in the stacked structure, themetal strips 3a are denoted withnumerals 1A to 1L ornumerals 2A to 2L in this order from an end of the dielectric film as shown inFIGs. 1A and1C . - In the figures, the direction in which the
metal strips 3a extend parallel to one another is referred to as a first direction (x-direction), and the direction in which themetal strips 3a align parallel to one another (y-direction perpendicular to x-direction) is referred to as a second direction. The films are stacked on one another in a third direction (z-direction in the figures) perpendicular to the first and second directions. The obtained stack, or afilm stack 4, will be described in detail later. - The metal strips 3a on the surface of each of the
dielectric films dielectric films metal strips 3a adjacent to each other in y-direction (hereafter, insulation margins S). The metal strips 3a are thus electrically insulated from one another. Each of the insulation margins S is continuous with an edge insulation area T at an end of the dielectric film in the first direction (x-direction). The edge insulation area T continuously extends in the second direction (y-direction). The interval (pitch P) between the insulation margins S is equal to the sum of a width P1 of onemetal strip 3a in y-direction and a width P2 of one insulation margin S in y-direction (P = P1 + P2). - The
common metal layer 3c is opposite to the edge insulation area T, or more specifically, at the other end of thedielectric films common metal layer 3c extends in the second direction. The metal strips 3a are electrically insulated from one another by the insulation margins S. However, themetal strips 3a are connected to the singlecommon metal layer 3c to allow themetal layer 3 to be electrically conductive across themetal layer 3. For themetal layer 3 including the connectingportions 3b, each connectingportion 3b has the center in the width direction aligned with the center of the correspondingmetal strip 3a in the width direction. Each connectingportion 3b has the length (width) in the second direction shorter (smaller) than the length (width) of eachmetal strip 3a in the second direction. Each connectingportion 3b functions as a fuse for thecorresponding metal strip 3a. When, for example, dielectric breakdown in the base film causes onemetal strip 3a to be short-circuited with anothermetal strip 3a with flow of a current exceeding a specified level, the corresponding connectingportion 3b burns out and causes wire breakage, thus preventing thefilm capacitor device 10 from disabling its entire functions. - The base film for the
dielectric film - As shown in
FIG. 1B , thefilm stack 4 includes thedielectric films dielectric films dielectric films common metal layers 3c each located at another end of the correspondingdielectric film - The
film stack 4 includes, on its two end faces in x-direction, metal electrodes that are formed by metal thermal spraying (hereafter, metal-sprayed electrodes). A metal-sprayed electrode at one end in x-direction is referred to as a metal-sprayedelectrode 5A (first metal electrode), and a metal-sprayed electrode at the other end in x-direction is referred to as a metal-sprayedelectrode 5B (second metal electrode). These electrodes are at different positions but have the same structure. For example, the metal-sprayedelectrode 5A is electrically connected to thecommon metal layer 3c on thedielectric film 1, and is also electrically connected to eachmetal strip 3a through thecommon metal layer 3c. Themetal layer 3 on thedielectric film 1 and the metal-sprayedelectrode 5A are electrically insulated by the edge insulation area T. The metal-sprayedelectrode 5B is electrically connected to thecommon metal layer 3c on thedielectric film 2, and is also electrically connected to eachmetal strip 3a through thecommon metal layer 3c. Themetal layer 3 on thedielectric film 2 and the metal-sprayedelectrode 5B are electrically insulated by the edge insulation area T. Electrically connecting the metal-sprayedelectrode common metal layer 3c reliably allows the metal strips 3a to connect to the metal-sprayedelectrode common metal layer 3c. - The
film capacitor device 10 according to the embodiment including the metal-sprayedelectrodes metal strips 3a (internal electrodes) from the metal-sprayedelectrodes FIG. 1C . In the present embodiment, thefilm capacitor device 10 has fourrecesses 11 in total, which are tworecesses 11 at one end of thefilm stack 4 in x-direction and tworecesses 11 at the other end. - Each
recess 11 continuously extends in the stacking direction of the film (z-direction) between the metal-sprayedelectrode film stack 4, in an area including the interface (boundary) between the metal-sprayedelectrode film stack 4, or in an area of the connectingportion 3b. Therecess 11 is open to an end face of thefilm stack 4 in y-direction and has a depth D (y-direction) from the end face in y-direction greater than the pitch P, which is the interval between the insulation margins S as described above. Therecess 11 has a width W (in x-direction) at the end face in y-direction greater than the width of thecommon metal layer 3c. In the structure including the connectingportions 3b, therecess 11 has the width W (x-direction) greater than the smaller one of the width of the insulation margin S in y-direction and the width of the connectingportion 3b in x-direction. In this structure, eachrecess 11 electrically insulates at least onemetal strip 3a located at each of the two ends in y-direction from the metal-sprayedelectrode - In the structure including the connecting
portions 3b as in the present embodiment, the depth D of eachrecess 11 from the end face of thefilm stack 4 in y-direction is greater than the value Dmin = (P1/2) + P2 + (P3/2), which is the sum of 1/2 of the width P1 of themetal strip 3a in y-direction (P1/2) and the width P2 of each insulation margin S in y-direction ((P1/2) + P2), and further 1/2 of the width P3 of the connectingportion 3b in y-direction (P3/2). In this structure, eachrecess 11 electrically insulates at least onemetal strip 3a located at each of the two ends in y-direction from the metal-sprayedelectrode - More specifically, the
film capacitor device 10 has therecesses 11 that separate and electrically insulate one or two of themetal strips 3a at each end of the stackeddielectric film 1 in y-direction from the metal-sprayed electrode 5AinFIG. 1C . For example, the separated and electrically insulatedmetal strips 3a may be atpositions positions 1K and 1L at the right end in the figure. In the same manner, therecesses 11 separate and electrically insulate one or twometal strips 3a located at each end of the stackeddielectric film 2 in y-direction from the metal-sprayedelectrodes FIG. 1C . For example, the separated and electrically insulatedmetal strips 3a may be atpositions positions - In other words, a film capacitor including the above
film capacitor device 10 may include themetal strips 3a that linearly extend in x-direction. This structure includesfewer metal strips 3a to be cut or insulated at each end in y-direction. The film capacitor according to the embodiment thus has less capacitance loss at around the cut surface of the stack (each end in y-direction) than a film capacitor with the structure that forms the basis of the film capacitor device according to one or more embodiments of the present disclosure including a device with oblique insulation margins (refer to Patent Literature 1). - One or two
metal strips 3a at each end in y-direction may be cut to the depth D from the end face in y-direction to allow appropriate insulation with therecesses 11. More specifically, eachrecess 11 may have the depth D about one to three times the pitch P of the insulation margin S as shown in the upper-right area ofFIG. 1A . At least one of themetal strips 3a at each end in y-direction may thus be reliably insulated, with themetal strip 3a at the end in y-direction having any width or the width P1 in y-direction of 1A, 2A, 1L, and 2L that varies depending on the cutting position of thefilm stack 4 in this example. As described above for the structure including the connectingportions 3b, the depth D of eachrecess 11 may be greater than the value Dmin = (P1/2) + P2 + (P3/2) and less than or equal to the value obtained by adding twice the pitch P to the value Dmin. - The positions of the
recesses 11 in x-direction (first direction) will be described later, together with the internal structure of thefilm stack 4. -
FIGs. 5 to 8 are schematic views showing a process for manufacturing a film capacitor device according to an embodiment. InFIGs. 5 to 8 showing the structure in a second embodiment and inFIGs. 9 and10 showing structures in modifications, the direction in which the metal strips 3a continuously extend parallel to one another is referred to as the first direction (x-direction in the figures), the direction in which thecommon metal layer 3c extends (y-direction perpendicular to x-direction) is referred to as the second direction, and the film stacking direction perpendicular to the first and second directions is referred to as the third direction (z-direction in the figures) as inFIGs. 1A to 1C . - The process for manufacturing a stacked
film capacitor device 70 will now be described. As shown inFIG. 5 , multipledielectric films multiple metal strips 3a that continuously extend in x-direction and thecommon metal layer 3c extending in y-direction on its surface are first stacked alternately in opposite orientations in x-direction. More specifically, the stackeddielectric films - As described above, the
dielectric films dielectric films FIG. 5 indicate the lines along which the films wound around a cylinder or another core are to be cut. -
FIG. 6 is a view of thefilm stack 4 cut into a predetermined length as viewed from the cut surface (end face in y-direction). As shown inFIG. 6 , the vertically adjacentdielectric films common metal layer 3c is thus exposed at the corresponding end face of thefilm stack 4 in x-direction. - The
film stack 4 in the embodiment includes an insulatinglayer 12 on its upper surface. The insulatinglayer 12 includes, for example, a dielectric film with nometal layer 3 and serving as a protective layer for the stack. The insulatinglayer 12 may be eliminated. - As shown in
FIG. 7 , the first metal electrode (metal-sprayedelectrode 5A) and the second metal electrode (metal-sprayedelectrode 5B) are then formed by metal thermal spraying onto the two end faces of thefilm stack 4 in x-direction. Thecommon metal layer 3c has its end exposed at the corresponding end face as described above. The metal strips 3a on thedielectric films electrode common metal layer 3c to function as internal electrodes of the device. - In the
film capacitor device 70 according to a second embodiment, therecesses 11 are formed on the two end faces of thefilm stack 4 in y-direction, which are the cut surfaces of the stack. Therecesses 11 are open to the end faces in y-direction, and separate and electrically insulate themetal strips 3a at the cut surfaces from the metal-sprayedelectrodes film capacitor device 70 includes fourrecesses 11 in total, which are tworecesses 11 at one end of thefilm stack 4 in y-direction and tworecesses 11 at the other end. - The
recesses 11 may be formed to continuously extend in the stacking direction (z-direction) by, for example, machining or cutting. Therecesses 11 may be, for example, cutouts, slits, or notches. - Each
recess 11 may have the depth D in y-direction at least greater than the pitch P, which is the sum of the width of onemetal strip 3a and the width of one insulation margin S. More specifically, therecess 11 may have the depth about one to three times the pitch P to insulate one or twometal strips 3a at each end in y-direction. Therecess 11 may have the depth less than or equal to three times the pitch P to avoid increase in the capacitance loss at the ends. For therecess 11 formed nearer thecommon metal layer 3c, the width W in x-direction may be greater than the width of thecommon metal layer 3c in x-direction. For therecess 11 formed nearer themetal strips 3a, the width W in x-direction may be greater than the smaller one of the width of one insulation margin S in y-direction and the width of one connectingportion 3b in x-direction. - The
recesses 11 may be between thefilm stack 4 and the metal-sprayedelectrode film capacitor device 20 shown inFIG. 8 or may be in an area including the interface (boundary) between the metal-sprayedelectrode film stack 4 as in afilm capacitor device 80 shown inFIG. 9 . In afilm capacitor device 90 shown inFIG. 10 in another embodiment, therecesses 11 at the two ends may be in thefilm stack 4 in an area adjacent to the interface between the metal-sprayedelectrode film stack 4. - Any of the above structures may produce the same advantageous effects. The metal strips 3a and the
common metal layer 3c on thedielectric film 1 or the metal strips 3a and thecommon metal layer 3c on thedielectric film 2 are exposed at the inner surface of eachrecess 11. As shown inFIG. 2A , eachrecess 11 is at a distance Q in x-direction from thecorresponding end 31 on thedielectric film 1 or from thecorresponding end 32 on thedielectric film 2 of anothermetal strip 3a that is not exposed at the inner surface of therecess 11. -
FIG. 2B is a plan view of thefilm capacitor device 20 viewed from above showing the positions of therecesses 11 in x-direction. As shown in the lower half of the figure, the ends 31 of the metal strips 3a on thedielectric film 1 are located inside thefilm stack 4 in x-direction. The above recesses 11 are thus located outward from theends 31 with the distance Q (adjacent to the metal-sprayedelectrode 5A). This structure provides reliable electrical insulation from the internal electrodes (metal strips 3a). The distance Q between therecesses 11 and theends metal strips 3a may be at least 200 µm. - In each of the embodiments described with reference to
FIGs. 1A to 1C ,2A ,2B , and8 to 10 , the structure includes the fourrecesses 11 in total, which are tworecesses 11 at each end in x-direction and in y-direction. In other embodiments, the structure may include tworecesses 11 in total as shown inFIGs. 3A to 3C , which are therecesses 11 between thefilm stack 4 and the metal-sprayedelectrode recesses 11 may be located at different ends in x-direction that are diagonal to each other on the xy plane of afilm capacitor device 30 or may be located at ends in y-direction at the same end in x-direction. The structure according to another embodiment (not shown) may include threerecesses 11 in total, which are tworecesses 11 between thefilm stack 4 and the metal-sprayedelectrode 5A at each end in y-direction and onerecess 11 between thefilm stack 4 and the metal-sprayedelectrode 5B at one end in y-direction. - Another embodiment will now be described. In the above embodiments, the
film stack 4 includes thedielectric films dielectric films film stack 4 includes thedielectric film 1 and adielectric film 13 that are stacked alternately but have their edge insulation areas T at one end in x-direction in the alternately opposite orientations. As shown inFIG. 4A , thedielectric film 13 includes asolid metal layer 3' with a solid pattern that covers the overall area of one surface of the base film except the edge insulation area T. As shown inFIG. 4B , thefilm stack 4 includes, on its two ends in x-direction, metal-sprayedelectrodes electrode 5A (first metal electrode) is electrically connected to thecommon metal layer 3c on thedielectric film 1. The metal-sprayedelectrode 5B (second metal electrode) is electrically connected to thesolid metal layer 3' on thedielectric film 13. - The structure in the present embodiment may have a
recess 11 in an upper (in x-direction) right (in y-direction) end inFIG. 4A to define a space between anend 33 of thesolid metal layer 3' and the metal-sprayedelectrode 5A. The structure may also have arecess 11 in an upper (in x-direction) left (in y-direction) end in the figure. This structure allows insulation of at least onemetal strip 3a at an end in y-direction on thedielectric film 1 in the same manner as in the above embodiments. The structure may further have arecess 11 in a lower (in x-direction) left or right (in y-direction) end in the figure. - As described above, the number of
recesses 11 and their positions may be varied depending on the position and the arrangement pattern of each metal film that serves as an internal electrode, as in thefilm capacitor devices FIGs. 3A to 3C and afilm capacitor device 60 inFIGs. 4A and 4B . A film capacitor using thefilm capacitor device recesses 11 and their positions may produce the same advantageous effects and functions as a film capacitor including the abovefilm capacitor device - In the film capacitor device according to each of the above embodiments, the
recesses 11 separate and electrically insulate one or two of themetal strips 3a at each end in y-direction (second direction) from the metal-sprayedelectrode - The present disclosure may be implemented in the following forms.
- A film capacitor device according to one or more embodiments of the present disclosure includes a film stack being rectangular, a first metal electrode, and a second metal electrode. The film includes a plurality of dielectric films being stacked. Each of the plurality of dielectric films including a metal layer on a surface of the dielectric film and includes, at an edge of the surface of the dielectric film in a first direction, an edge insulation area continuously extending in a second direction perpendicular to the first direction. The plurality of dielectric films include adjacent dielectric films in 180° opposite orientations in the first direction on the surface and alternate dielectric films having the edge insulation areas overlapping in a plan view. The first metal electrode and the second metal electrode are on a pair of end faces of the film stack in the first direction. The metal layer is electrically connected to at least the first metal electrode or the second metal electrode. The metal layer electrically connected at least to the first metal electrode includes a common metal layer and a plurality of metal strips. The common metal layer is located on another end of the surface in the first direction and extends in the second direction. The plurality of metal strips extend in the first direction and are electrically connected to the common metal layer. At least one of a pair of end faces of the film stack in the second direction includes a recess continuously extending in a direction in which the plurality of dielectric films are stacked and separating the film stack from the first metal electrode.
- The stacked film capacitor device according to one or more embodiments of the present disclosure has less capacitance loss in a cut portion of the film stack cut in a predetermined direction.
- Although the embodiments of the present disclosure have been described in detail, the present disclosure is not limited to the above embodiments, and may be modified or changed variously without departing from the spirit and scope of the present disclosure. The components described in the above embodiments may be entirely or partially combined as appropriate unless any contradiction arises.
-
- 1, 2, 13
- dielectric film
- 3
- metal layer
- 3a
- metal strip
- 3b
- connecting portion
- 3c
- common metal layer
- 3'
- solid metal layer
- 4
- film stack
- 5A, 5B
- metal-sprayed electrode
- 10
- film capacitor device
- 11
- recess
- S
- insulation margin
- T
- edge insulation area
Claims (3)
- A film capacitor device, comprising:a film stack being rectangular and including a plurality of dielectric films being stacked, each of the plurality of dielectric films including a metal layer on a surface of the dielectric film and including, at an edge of the surface of the dielectric film in a first direction, an edge insulation area continuously extending in a second direction perpendicular to the first direction, the plurality of dielectric films including adjacent dielectric films in 180° opposite orientations in the first direction on the surface and alternate dielectric films having the edge insulation areas overlapping in a plan view;a first metal electrode; anda second metal electrode, the first metal electrode and the second metal electrode being on a pair of end faces of the film stack in the first direction, the metal layer being electrically connected to at least the first metal electrode or the second metal electrode,wherein the metal layer electrically connected at least to the first metal electrode includes a common metal layer and a plurality of metal strips, the common metal layer is located on another end of the surface in the first direction and extends in the second direction, and the plurality of metal strips extend in the first direction and are electrically connected to the common metal layer, andat least one of a pair of end faces of the film stack in the second direction includes a recess continuously extending in a direction in which the plurality of dielectric films are stacked and separating the film stack from the first metal electrode.
- The film capacitor device according to claim 1, whereinthe metal layer electrically connected to the first metal electrode further includes a connecting portion connecting the common metal layer and the plurality of metal strips, andthe connecting portion has a length in the second direction less than a length of each of the plurality of metal strips in the second direction.
- The film capacitor device according to claim 1 or claim 2, wherein
the metal layer electrically connected to the second metal electrode includes a solid metal layer on an overall area of the surface of each of the plurality of dielectric film except the edge insulation area.
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JP2019197888 | 2019-10-30 | ||
PCT/JP2020/039277 WO2021085219A1 (en) | 2019-10-30 | 2020-10-19 | Film capacitor element |
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EP4053866A1 true EP4053866A1 (en) | 2022-09-07 |
EP4053866A4 EP4053866A4 (en) | 2023-11-29 |
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EP20882048.0A Pending EP4053866A4 (en) | 2019-10-30 | 2020-10-19 | Film capacitor element |
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US (1) | US20220359123A1 (en) |
EP (1) | EP4053866A4 (en) |
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Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS6414911A (en) * | 1987-07-08 | 1989-01-19 | Shizuki Electric | Capacitor with safety mechanism for series winding structure |
FR2640804A1 (en) * | 1988-12-20 | 1990-06-22 | Europ Composants Electron | LAYERED CAPACITOR FOR SEVERE ELECTRICAL PROCESSING AND METHODS OF MAKING SUCH CAPACITOR |
JPH04302122A (en) * | 1991-03-28 | 1992-10-26 | Marcon Electron Co Ltd | Composite laminated film capacitor, manufacture thereof and circuit using the capacitor |
JPH1097942A (en) * | 1996-09-24 | 1998-04-14 | Mitsubishi Materials Corp | Laminated ceramic capacitor |
JP2000012368A (en) * | 1998-06-22 | 2000-01-14 | Matsushita Electric Ind Co Ltd | Metallized film capacitor |
JP2003257783A (en) * | 2002-03-05 | 2003-09-12 | Matsushita Electric Ind Co Ltd | Method for producing multilayer thin film capacitor and multilayer thin film capacitor |
JP3914854B2 (en) * | 2002-10-10 | 2007-05-16 | 松下電器産業株式会社 | Metalized film capacitor, inverter smoothing capacitor and automotive capacitor using the same |
JP2010016047A (en) * | 2008-07-01 | 2010-01-21 | Shizuki Electric Co Inc | Metallized film capacitor |
KR101106982B1 (en) * | 2010-01-27 | 2012-01-25 | 주식회사 뉴인텍 | Deposite film and film capacitor ussing the same |
CN102543438B (en) | 2011-12-07 | 2014-04-16 | 厦门法拉电子股份有限公司 | Electrode structure of laminated metallic film capacitor |
JPWO2019069624A1 (en) * | 2017-10-04 | 2020-11-05 | パナソニックIpマネジメント株式会社 | Film capacitor |
-
2020
- 2020-10-19 US US17/770,231 patent/US20220359123A1/en active Pending
- 2020-10-19 JP JP2021553433A patent/JPWO2021085219A1/ja active Pending
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CN114586122A (en) | 2022-06-03 |
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