EP3985137A1 - Nicocraly-alloy, a powder, a coating and a component - Google Patents

Nicocraly-alloy, a powder, a coating and a component Download PDF

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Publication number
EP3985137A1
EP3985137A1 EP20201694.5A EP20201694A EP3985137A1 EP 3985137 A1 EP3985137 A1 EP 3985137A1 EP 20201694 A EP20201694 A EP 20201694A EP 3985137 A1 EP3985137 A1 EP 3985137A1
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EP
European Patent Office
Prior art keywords
coating
alloy
powder
optionally
coatings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20201694.5A
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German (de)
French (fr)
Inventor
Xin-hai LI
Snezana Djordjevic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Energy Global GmbH and Co KG
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Siemens Energy Global GmbH and Co KG
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Filing date
Publication date
Application filed by Siemens Energy Global GmbH and Co KG filed Critical Siemens Energy Global GmbH and Co KG
Priority to EP20201694.5A priority Critical patent/EP3985137A1/en
Priority to EP21786784.5A priority patent/EP4196620A1/en
Priority to PCT/EP2021/076386 priority patent/WO2022078733A1/en
Priority to CN202180069346.5A priority patent/CN116324035A/en
Priority to US18/029,907 priority patent/US20230366066A1/en
Publication of EP3985137A1 publication Critical patent/EP3985137A1/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/12—Metallic powder containing non-metallic particles
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/056—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C23C28/3215—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer at least one MCrAlX layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06—Metallic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06—Metallic material
    • C23C4/073—Metallic material containing MCrAl or MCrAlY alloys, where M is nickel, cobalt or iron, with or without non-metal elements
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00—Metallic composition of the powder or its coating
    • B22F2301/15—Nickel or cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy

Definitions

  • the invention relates to a composition of a NiCoCrAlY based alloy especially used for gas turbines, a powder, a coating and a component.
  • This invention is to solve the problem by using recent research results and upgraded thermodynamic modelling to design an optimized and innovative NiCoCrAlX alloy coatings applied by means of thermal spraying in air, vacuum, or protected atmosphere, physical deposition, and plating on Ni or Co based superalloys.
  • X is a combination of minor elements such as Y, Ru, Ir, Si, Hf, Ta and etc. instead of Yttrium (Y) in the current NiCoCrAlY coatings. It means that we will introduce other minor elements to replace part of Yttrium (Y) functions in order to keep Yttrium (Y) content low.
  • NiCoCrAlX coatings are fabricated using Ruthenium (Ru) and Iridium (Ir) and reduces diffusion rate of Aluminum (Al) and forms diffusion barrier to minimize the interdiffusion between NiCoCrAlX coating and substrates. Ru addition increases mechanical durability of the coatings. Moreover, another approach in designing and manufacturing the innovative NiCoCrAlX coatings is reduce S content to ⁇ 10ppm to further increase coating lifetime.
  • the coating thickness should be in the range of 30-800 ⁇ m depending on type of applications and application methods.
  • the new NiCoCrAlX coating is Ni-based and possesses the preferred following composition (in wt%):
  • a powder with this alloy composition can be mixed with a binder and/or refractory metals or ceramics if used as an abrasive coating.
  • a metallic substrate like a nickel or cobalt based superalloy is used on which the inventive coating is applied on.
  • the coating is applied especially by the thermal spray and electron beam vapor deposition processes.
  • a layer system therefore at least comprises a metallic substrate, especially a Nickel based superalloy and at least a coating with the inventive alloy and optionally a ceramic layer on top the metallic bond and oxidation coating.
  • the ceramic layer comprises preferably a Zirconia based composition, partly or fully stabilized.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Ceramic Engineering (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention comprisesa Nickel-based alloy,and least comprising (in wt%):25.7 % - 27.3% Cobalt (Co),15.0% - 16.0% Chromium (Cr),12.2% - 13.2% Aluminum (Al),0.3% - 0.5% Yttrium (Y),2.5% - 3.5% Ruthenium (Ru),0.4% - 0.8% Silicon (Si),0.4% - 0.6% Tantalum (Ta),0.4% - 0.6% Molybdenum (Mo).

Description

  • The invention relates to a composition of a NiCoCrAlY based alloy especially used for gas turbines, a powder, a coating and a component.
  • When further increasing engine efficiency, output power, availability, and reliability in the current gas turbine development, it is often limited by temperature capacity and lifetime of protective coatings for protection against hot corrosion and oxidation and bonding thermal barrier coating TBC on the hot turbine components. The used coatings were all developed more than 10 years ago and can not fulfil demands of further turbine development. In the MCrAlY coatings available today, one relies on Yttrium (Y) incorporation very much to have pegging and scavenge effects to increase oxidation and corrosion resistances of the coatings. However, it has recently been reported that Yttria inclusions in the protective aluminum oxide scale on top of MCrAlY provide fast oxygen diffusion routes, and therefore, accelerate oxidation of the coating (Nijdam TJ, Sloof WG. Acta Materialia 2007;55:5980).
    High content of Sulfur > 10ppm existed in the current MCrAlY shortens coating lifetime (Smialek JL, Jayne DT, Schaeffer JC, Murphy WH. Thin Solid Films 1994;253:285; and Smialek JL. Metallurgical Transactions A, Physical Metallurgy and Materials Science 1991;22A:739). In addition, the increase in oxidation and corrosion lifetime of the MCrAlY coatings is often achieved in expense of their mechanical durability. The development of advanced turbines with flexible operations demands coatings withstanding operations with both higher temperature and longer time exposure and higher mechanical loadings.
  • This problem has not been solved yet.
  • It is therefore aim of the invention to overcome the problems mentioned above.
  • The problem is solved by an alloy of claim 1, by a powder of claim 2, a coating by claim 3 and a layer system according to claim 4.
  • Further advantages of the invention are listed in the dependent claims which can be combined arbitrarily with each other to yield further advantages.
  • This invention is to solve the problem by using recent research results and upgraded thermodynamic modelling to design an optimized and innovative NiCoCrAlX alloy coatings applied by means of thermal spraying in air, vacuum, or protected atmosphere, physical deposition, and plating on Ni or Co based superalloys.
    X is a combination of minor elements such as Y, Ru, Ir, Si, Hf, Ta and etc. instead of Yttrium (Y) in the current NiCoCrAlY coatings. It means that we will introduce other minor elements to replace part of Yttrium (Y) functions in order to keep Yttrium (Y) content low. Introduction of Ruthenium (Ru) and Iridium (Ir) reduces diffusion rate of Aluminum (Al) and forms diffusion barrier to minimize the interdiffusion between NiCoCrAlX coating and substrates. Ru addition increases mechanical durability of the coatings.
    Moreover, another approach in designing and manufacturing the innovative NiCoCrAlX coatings is reduce S content to ≤10ppm to further increase coating lifetime. The coating thickness should be in the range of 30-800 µm depending on type of applications and application methods.
  • The new NiCoCrAlX coating is Ni-based and possesses the preferred following composition (in wt%):
    • Ni balanced,
    • 25.7 % - 27.3% Cobalt (Co),
    • 15.0% - 16.0% Chromium (Cr),
    • 12.2% - 13.2% Aluminum (Al),
    • 0.3% - 0.5% Yttrium (Y),
    • 2.5% - 3.5% Ruthenium (Ru),
    • and
    • optionally
    • 0.4% - 0.8% Silicon (Si),
    • 0.4% - 0.6% Tantalum (Ta),
    • 0.4% - 0.6% Molybdenum (Mo).
  • This invention results in NiCoCrAlYRu, NiCoCrAlYRuSi, NiCoCrAlYRuTa, NiCoCrAlYRuMo, NiCoCrAlYRuSiTa, NiCoCrAlYRuSiMo, NiCoCrAlYRuTaMo, NiCoCrAlRuMoSiTa coatings with a higher temperature capacity, longer life, and larger mechanical durability than the NiCoCrAlY coatings available today.
  • A powder with this alloy composition can be mixed with a binder and/or refractory metals or ceramics if used as an abrasive coating.
  • For turbine application especially a metallic substrate like a nickel or cobalt based superalloy is used on which the inventive coating is applied on.
  • The coating is applied especially by the thermal spray and electron beam vapor deposition processes.
  • Even SLM, SLS or any AM technique is possible to apply coatings or to produce components of this alloy or used as repair material.
  • A layer system therefore at least comprises
    a metallic substrate,
    especially a Nickel based superalloy and
    at least a coating with the inventive alloy and optionally a ceramic layer on top the metallic bond and oxidation coating.
  • The ceramic layer comprises preferably a Zirconia based composition, partly or fully stabilized.

Claims (5)

  1. Nickel-based alloy,
    and least comprising (in wt%),
    especially consisting of:
    Cobalt (Co) 25.7% - 27.3%
    especially 26.5%
    Chromium (Cr) 15.0% - 16.0%
    especially 15.5%
    Aluminum (Al) 12.2% - 13.2%
    especially 12.7%
    Yttrium (Y) 0.3% - 0.5%
    especially 0.4%
    Ruthenium (Ru) 2.5% - 3.5%
    especially 3.0%
    optionally
    Molybdenum (Mo) 0.4% - 0.6%
    especially 0.5%
    Silicon (Si) 0.4% - 0.8%
    especially 0.6%
    Tantalum (Ta) 0.4% - 0.6%
    especially 0.5%,
    optionally Sulfur (S) ≤ 10ppm.
  2. Alloy
    comprising NiCoCrAlYRu, NiCoCrAlYRuSi, NiCoCrAlYRuMo, NiCoCrAlYRuTa, NiCoCrAlYRuSiTa, NiCoCrAlYRuSiMo, NiCoCrAlYRuTaMo or NiCoCrAlYRuSiTaMo.
  3. Powder,
    comprising,
    especially consisting of,
    an alloy according to claim 1 or 2,
    optionally comprising a binder and/or ceramic particles.
  4. Coating,
    having a composition of an alloy according to claim 1, 2 or
    produced with powder of claim 3,
    especially having a thickness in the range of 30µm to 800µm.
  5. Component,
    comprising
    a metallic substrate,
    especially Nickel-based or Cobalt-based superalloy,
    a metallic coating with a composition according to claim 1, 2
    or
    a coating according to claim 4,
    and optionally
    a ceramic coating above the substrate and the metallic coating.
EP20201694.5A 2020-10-14 2020-10-14 Nicocraly-alloy, a powder, a coating and a component Withdrawn EP3985137A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP20201694.5A EP3985137A1 (en) 2020-10-14 2020-10-14 Nicocraly-alloy, a powder, a coating and a component
EP21786784.5A EP4196620A1 (en) 2020-10-14 2021-09-24 Nicocraly-alloy, a powder, a coating and a component
PCT/EP2021/076386 WO2022078733A1 (en) 2020-10-14 2021-09-24 Nicocraly-alloy, a powder, a coating and a component
CN202180069346.5A CN116324035A (en) 2020-10-14 2021-09-24 NiCoCrAlY alloys, powders, coatings and components
US18/029,907 US20230366066A1 (en) 2020-10-14 2021-09-24 NiCoCrAlY- ALLOY, A POWDER, A COATING AND A COMPONENT

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20201694.5A EP3985137A1 (en) 2020-10-14 2020-10-14 Nicocraly-alloy, a powder, a coating and a component

Publications (1)

Publication Number Publication Date
EP3985137A1 true EP3985137A1 (en) 2022-04-20

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EP20201694.5A Withdrawn EP3985137A1 (en) 2020-10-14 2020-10-14 Nicocraly-alloy, a powder, a coating and a component
EP21786784.5A Pending EP4196620A1 (en) 2020-10-14 2021-09-24 Nicocraly-alloy, a powder, a coating and a component

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US (1) US20230366066A1 (en)
EP (2) EP3985137A1 (en)
CN (1) CN116324035A (en)
WO (1) WO2022078733A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000075398A1 (en) * 1999-06-02 2000-12-14 Abb Research Ltd. Coating composition for high temperature protection
EP2256221A1 (en) * 2008-03-28 2010-12-01 Mitsubishi Heavy Industries, Ltd. Alloy material having high-temperature corrosion resistance, heat-shielding coating material, turbine member, and gas turbine
EP2423439A2 (en) * 2010-08-26 2012-02-29 Honeywell International, Inc. Methods for the formation of MCrA1Y coatings on gas turbine engine components
WO2013056935A1 (en) * 2011-10-20 2013-04-25 Siemens Aktiengesellschaft Coating, coating layer system, coated superalloy component

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US9138963B2 (en) * 2009-12-14 2015-09-22 United Technologies Corporation Low sulfur nickel base substrate alloy and overlay coating system
CN104757863B (en) * 2015-03-17 2016-08-17 浙江三禾厨具有限公司 Plasma non-stick pan and manufacture method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000075398A1 (en) * 1999-06-02 2000-12-14 Abb Research Ltd. Coating composition for high temperature protection
EP2256221A1 (en) * 2008-03-28 2010-12-01 Mitsubishi Heavy Industries, Ltd. Alloy material having high-temperature corrosion resistance, heat-shielding coating material, turbine member, and gas turbine
EP2423439A2 (en) * 2010-08-26 2012-02-29 Honeywell International, Inc. Methods for the formation of MCrA1Y coatings on gas turbine engine components
WO2013056935A1 (en) * 2011-10-20 2013-04-25 Siemens Aktiengesellschaft Coating, coating layer system, coated superalloy component

Non-Patent Citations (3)

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