EP3973042A1 - Fabric conditioning composition - Google Patents
Fabric conditioning compositionInfo
- Publication number
- EP3973042A1 EP3973042A1 EP20727173.5A EP20727173A EP3973042A1 EP 3973042 A1 EP3973042 A1 EP 3973042A1 EP 20727173 A EP20727173 A EP 20727173A EP 3973042 A1 EP3973042 A1 EP 3973042A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- cationic
- composition according
- oil
- quaternary ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 183
- 239000004744 fabric Substances 0.000 title claims abstract description 88
- 230000003750 conditioning effect Effects 0.000 title claims abstract description 44
- -1 cationic polysaccharide Chemical class 0.000 claims abstract description 99
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 85
- 239000005017 polysaccharide Substances 0.000 claims abstract description 85
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims abstract description 43
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 23
- 239000008158 vegetable oil Substances 0.000 claims abstract description 23
- 150000004676 glycans Chemical class 0.000 claims abstract description 8
- 125000002091 cationic group Chemical group 0.000 claims description 40
- 150000002148 esters Chemical class 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 23
- 239000002304 perfume Substances 0.000 claims description 22
- 125000003342 alkenyl group Chemical group 0.000 claims description 21
- 239000003921 oil Substances 0.000 claims description 21
- 235000019198 oils Nutrition 0.000 claims description 21
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 19
- 239000003205 fragrance Substances 0.000 claims description 13
- 235000019486 Sunflower oil Nutrition 0.000 claims description 10
- 239000002600 sunflower oil Substances 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 150000001450 anions Chemical group 0.000 claims description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 6
- 235000008390 olive oil Nutrition 0.000 claims description 6
- 239000004006 olive oil Substances 0.000 claims description 6
- 235000019489 Almond oil Nutrition 0.000 claims description 5
- 239000008168 almond oil Substances 0.000 claims description 5
- 125000003368 amide group Chemical group 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 125000006686 (C1-C24) alkyl group Chemical group 0.000 claims description 2
- NQACPPULWUTWKR-UHFFFAOYSA-M 2-hydroxyethyl-methyl-dioctadecylazanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(CCO)CCCCCCCCCCCCCCCCCC NQACPPULWUTWKR-UHFFFAOYSA-M 0.000 claims description 2
- 238000010790 dilution Methods 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- NUCJYHHDSCEKQN-UHFFFAOYSA-M dimethyl-bis(2-octadecanoyloxyethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC(=O)OCC[N+](C)(C)CCOC(=O)CCCCCCCCCCCCCCCCC NUCJYHHDSCEKQN-UHFFFAOYSA-M 0.000 claims description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 claims 2
- 150000004804 polysaccharides Chemical class 0.000 description 43
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 39
- 150000004665 fatty acids Chemical group 0.000 description 32
- 229920006235 chlorinated polyethylene elastomer Polymers 0.000 description 30
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 229930006000 Sucrose Natural products 0.000 description 19
- 239000005720 sucrose Substances 0.000 description 19
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 18
- 235000014113 dietary fatty acids Nutrition 0.000 description 18
- 239000000194 fatty acid Substances 0.000 description 18
- 229930195729 fatty acid Natural products 0.000 description 18
- 239000007788 liquid Substances 0.000 description 17
- 238000000136 cloud-point extraction Methods 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 16
- 239000000975 dye Substances 0.000 description 16
- 238000005406 washing Methods 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- 239000003599 detergent Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- 229920002678 cellulose Polymers 0.000 description 12
- 235000010980 cellulose Nutrition 0.000 description 12
- 150000005690 diesters Chemical class 0.000 description 12
- 239000000178 monomer Substances 0.000 description 11
- 229920005862 polyol Polymers 0.000 description 11
- 150000001720 carbohydrates Chemical class 0.000 description 10
- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 9
- 230000008901 benefit Effects 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 9
- 125000001453 quaternary ammonium group Chemical group 0.000 description 9
- 230000002829 reductive effect Effects 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 125000001033 ether group Chemical group 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 6
- 235000000346 sugar Nutrition 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 150000001412 amines Chemical group 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 5
- 239000000981 basic dye Substances 0.000 description 5
- 229920006317 cationic polymer Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000032050 esterification Effects 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- MAUMSNABMVEOGP-UHFFFAOYSA-N (methyl-$l^{2}-azanyl)methane Chemical compound C[N]C MAUMSNABMVEOGP-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 4
- FKUPPRZPSYCDRS-UHFFFAOYSA-N Cyclopentadecanolide Chemical compound O=C1CCCCCCCCCCCCCCO1 FKUPPRZPSYCDRS-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 235000012343 cottonseed oil Nutrition 0.000 description 4
- 239000002385 cottonseed oil Substances 0.000 description 4
- 150000002016 disaccharides Chemical class 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 4
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 4
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 235000012424 soybean oil Nutrition 0.000 description 4
- 239000003549 soybean oil Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- 150000005691 triesters Chemical class 0.000 description 4
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- 244000144725 Amygdalus communis Species 0.000 description 3
- 229920000926 Galactomannan Polymers 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 235000009421 Myristica fragrans Nutrition 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 235000021319 Palmitoleic acid Nutrition 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000000980 acid dye Substances 0.000 description 3
- 230000010933 acylation Effects 0.000 description 3
- 238000005917 acylation reaction Methods 0.000 description 3
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 3
- 150000004056 anthraquinones Chemical class 0.000 description 3
- 239000004599 antimicrobial Substances 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- 229920003086 cellulose ether Polymers 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 238000004900 laundering Methods 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 150000002772 monosaccharides Chemical group 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- FVUGZKDGWGKCFE-UHFFFAOYSA-N 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalen-2-yl)ethanone Chemical compound CC1(C)CCCC2=C1CC(C(C)=O)(C)C(C)C2 FVUGZKDGWGKCFE-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- BJLRAKFWOUAROE-UHFFFAOYSA-N 2500-83-6 Chemical compound C12C=CCC2C2CC(OC(=O)C)C1C2 BJLRAKFWOUAROE-UHFFFAOYSA-N 0.000 description 2
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 2
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 description 2
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- YPZUZOLGGMJZJO-UHFFFAOYSA-N Ambronide Chemical compound C1CC2C(C)(C)CCCC2(C)C2C1(C)OCC2 YPZUZOLGGMJZJO-UHFFFAOYSA-N 0.000 description 2
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 description 2
- 235000011437 Amygdalus communis Nutrition 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- 229920002307 Dextran Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- 244000165082 Lavanda vera Species 0.000 description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920000057 Mannan Polymers 0.000 description 2
- 244000270834 Myristica fragrans Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229940022663 acetate Drugs 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
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- 231100000584 environmental toxicity Toxicity 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Chemical class CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
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- LUEWUZLMQUOBSB-GFVSVBBRSA-N mannan Chemical class O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](O[C@H]3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-GFVSVBBRSA-N 0.000 description 1
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- 230000003000 nontoxic effect Effects 0.000 description 1
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- 239000003605 opacifier Substances 0.000 description 1
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- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002924 oxiranes Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- LMXFTMYMHGYJEI-UHFFFAOYSA-N p-menthane-3,8-diol Chemical compound CC1CCC(C(C)(C)O)C(O)C1 LMXFTMYMHGYJEI-UHFFFAOYSA-N 0.000 description 1
- 229930006948 p-menthane-3,8-diol Natural products 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- QQBPIHBUCMDKFG-UHFFFAOYSA-N phenazopyridine hydrochloride Chemical group Cl.NC1=NC(N)=CC=C1N=NC1=CC=CC=C1 QQBPIHBUCMDKFG-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229940100595 phenylacetaldehyde Drugs 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 239000010471 pistachio oil Substances 0.000 description 1
- 229940082415 pistachio oil Drugs 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 239000010499 rapseed oil Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 231100000940 skin sensitizing potential Toxicity 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- CITBNDNUEPMTFC-UHFFFAOYSA-M sodium;2-(hydroxymethylamino)acetate Chemical compound [Na+].OCNCC([O-])=O CITBNDNUEPMTFC-UHFFFAOYSA-M 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000992 solvent dye Substances 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- AUIQILSKFKITRO-UHFFFAOYSA-N styrene;trimethylazanium;chloride Chemical compound [Cl-].C[NH+](C)C.C=CC1=CC=CC=C1 AUIQILSKFKITRO-UHFFFAOYSA-N 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 235000001019 trigonella foenum-graecum Nutrition 0.000 description 1
- VZTGWJFIMGVKSN-UHFFFAOYSA-O trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium Chemical compound CC(=C)C(=O)NCCC[N+](C)(C)C VZTGWJFIMGVKSN-UHFFFAOYSA-O 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 150000004961 triphenylmethanes Chemical class 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 235000016788 valerian Nutrition 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 229940117960 vanillin Drugs 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Chemical class 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 230000037331 wrinkle reduction Effects 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 150000004823 xylans Chemical class 0.000 description 1
- FUQAYSQLAOJBBC-PAPYEOQZSA-N β-caryophyllene alcohol Chemical compound C1C[C@](C2)(C)CCC[C@]2(O)[C@H]2CC(C)(C)[C@@H]21 FUQAYSQLAOJBBC-PAPYEOQZSA-N 0.000 description 1
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 description 1
- SFEOKXHPFMOVRM-BQYQJAHWSA-N γ-ionone Chemical compound CC(=O)\C=C\C1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-BQYQJAHWSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
Definitions
- the present invention relates to a composition, in particular a fabric conditioning composition, comprising a quaternary ammonium compound, a cationic polysaccharide, a non-ionic polysaccharide and a vegetable oil.
- the present invention also relates to a method of use of the composition, in particular a method for treating fabrics.
- Fabric conditioning compositions are often used in rinse cycle of the laundering process to soften fabrics and to impart them nice smell.
- fabric conditioning systems are based on quaternary ammonium compounds (“quats”).
- ester quats can be used as the fabric conditioning actives.
- ester quats are bio-degradable and exhibit lower eco toxicity, which are highly desired characteristics in light of environment concerns.
- fabric conditioning compositions should have good softening performance, excellent capacity of depositing benefit agents (e.g. perfumes) to fabrics, as well as good stability. Stability is very important as compositions with poor stability may become unpourable and have inadequate dispensing and dissolving characteristics in rinse water. Methods have been developed to enhance stability of fabric conditioning compositions. One option is to lower the quats content in the compositions by replacing part of the quats with a cationic polymer, such as a cationic polysaccharide. Reduction of the quat content is also of interest for cost considerations.
- quats and cationic polysaccharides in the same composition will lead to certain problems. Specifically, quats and cationic polysaccharides, when used in combination, tend to phase separate. As a result, the composition is no longer homogeneous and segregates into different phases. This phenomenon may pose difficulties to consumers and may affect retailers when they place products on the shelves, without mentioning any associated loss of performance of the softening products.
- the present invention relates to a composition
- a composition comprising (a) a quaternary ammonium compound; (b) a cationic polysaccharide; (c) a non-ionic polysaccharide; and (d) a vegetable oil.
- the quaternary ammonium compound may be an alkyl quat.
- the quat may contain at least an ester group, such as a di-ester quat.
- the cationic polysaccharide may notably be a cationic guar.
- the non-ionic polysaccharide may notably be a non-ionic guar.
- the vegetable oil is preferably selected from sunflower oil, olive oil and almond oil, in particular sunflower oil.
- a method for treating a fabric such as for conditioning a fabric, wherein the method comprises a step of contacting the fabric with a composition comprising: (a) a quaternary ammonium compound; (b) a cationic polysaccharide; (c) a non-ionic polysaccharide; and (d) a vegetable oil.
- compositions for conditioning a fabric comprising : (a) a quaternary ammonium compound; (b) a cationic polysaccharide; (c) a non-ionic polysaccharide; and (d) a vegetable oil.
- composition according to the present invention provides excellent softening performance on fabrics.
- the composition also has good storage stability. Furthermore, it has been found that the composition can perform well under different conditions of the laundry operation.
- any particular upper concentration, weight ratio or amount can be associated with any particular lower concentration, weight ratio or amount, respectively.
- fabric conditioning is used herein the broadest sense to include any conditioning benefit(s) to textile fabrics, materials, yarns, and woven fabrics.
- One such conditioning benefit is softening fabrics.
- Other non-limiting conditioning benefits include fabric lubrication, fabric relaxation, durable press, wrinkle resistance, wrinkle reduction, ease of ironing, abrasion resistance, fabric smoothing, anti felting, anti-pilling, crispness, appearance enhancement, appearance rejuvenation, color protection, color rejuvenation, anti-shrinkage, in-wear shape retention, fabric elasticity, fabric tensile strength, fabric tear strength, static reduction, water absorbency or repellency, stain repellency; refreshing, anti-microbial, odor resistance; perfume freshness, perfume longevity, and mixtures thereof.
- alkyl means a saturated hydrocarbon radical, which may be straight, branched or cyclic, such as, methyl, ethyl, n-propyl, iso-propyl, n-butyl, sec-butyl, t-butyl, pentyl, n-hexyl, cyclohexyl.
- alkenyl as a group or part of a group denotes an aliphatic hydrocarbon group containing at least one carbon-carbon double bond and which may be straight or branched.
- the group may contain a plurality of double bonds in the normal chain and the orientation about each is independently E or Z.
- Exemplary alkenyl groups include, but are not limited to, ethenyl, propenyl, butenyl, pentenyl, hexenyl, heptenyl, octenyl and nonenyl.
- the group may be a terminal group or a bridging group.
- hydroxyalkyl means an alkyl radical, which is substituted with a hydroxyl groups, such as hydroxymethyl, hydroxyethyl, hydroxypropyl, and hydroxydecyl.
- cationic polymer as used herein means any polymer which has a cationic charge.
- quaternary ammonium compound (also referred to as“quat”) as used herein means a compound containing at least one quaternized nitrogen wherein the nitrogen atom is attached to four organic groups.
- the quaternary ammonium compound may comprise one or more quaternized nitrogen atoms.
- cationic polysaccharide means a polysaccharide or a derivative thereof that has been chemically modified to provide the polysaccharide or the derivative thereof with a net positive charge in a pH neutral aqueous medium.
- the cationic polysaccharide may also include those that are non-permanently charged, e.g. a derivative that can be cationic below a given pH and neutral above that pH.
- Non-modified polysaccharides such as starch, cellulose, pectin, carageenan, guars, xanthans, dextrans, curdlans, chitosan, chitin, and the like, can be chemically modified to impart cationic charges thereon.
- a common chemical modification incorporates quaternary ammonium substituents to the polysaccharide backbones.
- Other suitable cationic substituents include primary, secondary or tertiary amino groups or quaternary sulfonium or phosphinium groups. Additional chemical modifications may include cross- linking, stabilization reactions (such as alkylation and esterification), phophorylations, hydrolyzations.
- non-ionic polysaccharide refers to a polysaccharide or a derivative thereof that has been chemically modified to provide the polysaccharide or the derivative thereof with a net neutral charge in a pH neutral aqueous medium; or a non-modified polysaccharide.
- first rinse means a step of rinsing fabrics which is conducted subsequent to the laundering of the fabrics, without any additional rinsing of the fabrics in between.
- the first rinse may be a rinsing cycle of an automated or non-automated washing machine.
- the first rinse may be a hand rinsing process subsequent to the laundering of the fabrics.
- rinse solution means a solution, notably an aqueous solution, used to rinse fabrics after the fabrics have been laundered.
- the rinse solution may be used in an automated or non- automated washing machine, or in the case of hand washing, may be used in a simple container, such as a basin or bucket.
- laundry residue means any material that may be present either on fabrics or in the detergent liquid during the wash cycle of the laundry operation and that is carried over with laundered fabrics to the rinse solution.
- “laundry residue” includes but is not limited to, residual soils, particulate matter, detergent surfactants, detergent builders, bleaching agents, metal ions, lipids, enzymes and any other materials that may have been present in the wash cycle solution.
- excess wash cycle solutions may be squeezed, wrung, or spun out of fabrics to remove excess laundry residue, prior to adding the fabrics to the rinse solution.
- laundry residue includes“surfactant residue”, which means a surfactant material that may be present either on the fabrics or in the detergent liquid during the wash cycle of the laundry process and that is carried over with the laundered fabrics into the rinse solution.
- the present invention relates to a composition, notably a fabric conditioning composition, which comprises (a) a quaternary ammonium compound; (b) a cationic polysaccharide; (c) a non-ionic polysaccharide; and (d) a vegetable oil.
- a fabric conditioning composition which comprises (a) a quaternary ammonium compound; (b) a cationic polysaccharide; (c) a non-ionic polysaccharide; and (d) a vegetable oil.
- the composition of the present invention is preferably an aqueous fabric conditioning composition.
- the composition may also be a home care composition having, among other properties, fabric conditioning properties, such as a detergent composition with conditioning properties.
- the quaternary ammonium compound may have the general formula (I) :
- Ri , R 2 , R3 and R 4 which may be the same or different, is a Ci-C 4 o hydrocarbon group, respectively, optionally containing a heteroatom or an ester or amide group;
- X is an anion, for instance, a halide such as Cl or Br, sulphate, alkyl sulphate, nitrate and acetate;
- y is the valence of X.
- Ri, R 2 , R 3 and R 4 is, respectively, a Ci-C 4 o alkyl, alkenyl, hydroxyalkyl, or ethoxylated alkyl group.
- Ri, R 2 , R 3 and R 4 is, respectively, a Ci-C 4 o hydrocarbon group containing a heteroatom or an ester or amide group.
- the quaternary ammonium compound is an alkyl quat, such as a di-alkyl quat.
- the quat may notably be a compound of general formula (II) :
- R5 is a C16-C22 alkyl, alkenyl or hydroxyalkyl group
- R6 is a C 1 -C 4 alkyl, alkenyl or hydroxyalkyl group
- R7 is R5 or Re
- X is an anion, for example halide such as Cl or Br, sulphate, alkyl sulphate, nitrate or acetate;
- y is the valence of X.
- alkyl quat is dihydrogenated tallow dimethyl ammonium chloride.
- the quaternary ammonium compound is an ester quat such as a di-alkyl di-ester quat.
- the quat has the general formula (III) :
- Re is a C 1 -C 24 alkyl, alkenyl, or hydroxylalkyl group
- Rg is a C 1 -C 4 alkyl, alkenyl, or hydroxylalkyl group
- n is an integer from 0 to 5;
- n is selected from 1 , 2 and 3;
- X is an anion, for example a chloride, bromide, nitrate or methosulphate ion; y is the valence of X.
- m as defined in general formula (III) is 2.
- the quaternary ammonium compound may have the general formula of (IV) :
- the average chain length of the fatty acid chains is at least C 14 , more preferably at least C16. Even more preferably at least half of the chains have a length of C18.
- the fatty acid chains of the ester quat suitable for the invention may comprise from 20 to 35 weight percent of saturated Cie chains and from 20 to 35 weight percent of monounsaturated Ci 8 chains by weight of total fatty acid chains.
- the ester quat is derived from palm or tallow feedstocks. These feedstocks may be pure or predominantly palm or tallow based. Blends of different feedstocks may be used.
- the fatty acid chains of the ester quat comprise from 25 to 30 weight percent, preferably from 26 to 28 weight percent of saturated Cie chains and from 25 to 30 weight percent, preferably from 26 to 28 weight percent of monounsaturated Cie chains, by weight of total fatty acid chains.
- the fatty acid chains of the ester quat comprise from 30 to 35 weight percent, preferably from 33 to 35 weight percent of saturated Cie chains and from 24 to 35 weight percent, preferably from 27 to 32 weight percent of monounsaturated Cie chains, by weight of total fatty acid chains.
- the fatty acid chains may be predominantly linear, although a degree of branching, especially mid-chain branching, is within the scope of the invention.
- the quat is preferably a triethanolamine-based quaternary ammonium of general formula (V) :
- Rn is a C12-C20 alkyl, alkenyl, or hydroxyalkyl group
- z is an integer from 1 to 3.
- the quaternary ammonium compound may also be a mixture of various quaternary ammonium compounds, notably a mixture of mono-, di- and tri ester components or a mixture of mono-, and di- ester components, wherein for instance the amount of di-ester quaternary is comprised between 30 and 99% by weight based on the total amount of the quaternary ammonium compound.
- the quaternary ammonium compound is a mixture of mono-, di- and tri-ester components, wherein:
- the amount of di-ester quaternary is comprised between 30 and 70% by weight based on the total amount of the quaternary ammonium compound, preferably between 40 and 60% by weight,
- the amount of mono-ester quaternary is comprised between 10 and 60% by weight based on the total amount of the quaternary ammonium compound, preferably between 20 and 50% by weight,
- the amount of tri-ester quaternary is comprised between 1 and 20% by weight based on the total amount of the quaternary ammonium compound.
- the quaternary ammonium compound is a mixture of mono- and di- ester components, wherein:
- the amount of di-ester quaternary is comprised between 30 and 99 % by weight based on the total amount of the quaternary ammonium compound, preferably between 50 and 99 by weight,
- the amount of mono-ester quaternary is comprised between 1 and 50 % by weight based on the total amount of the quaternary ammonium compound, preferably between 1 and 20% by weight.
- Very preferred quaternary ammonium compounds include :
- TET Di(tallowcarboxyethyl)hydroxyethyl methyl ammonium methylsulfate
- TEO Di(oleocarboxyethyl)hydroxyethyl methyl ammonium methylsulfate
- TES Distearyl hydroxyethyl methyl ammonium methylsulfate
- DEEDMAC Dimethylbis[2-[(1-oxooctadecyl)oxy]ethyl]ammonium chloride.
- the quaternary ammonium compound is bis- (2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.5 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, of from 0.5 to 60, and from 0.5 to 5 % by weight fatty acid.
- the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is a mixture of at least one di-ester of formula :
- R12 is the hydrocarbon group of a fatty acid moiety R12COO-.
- such bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester has a molar ratio of fatty acid moieties to amine moieties of from 1.85 to 1.99, the fatty acid moiety has an average chain length of from 16 to 18 carbon atoms and an iodine value, calculated for the free fatty acid, of from 0.5 to 60, preferably from 0.5 to 50.
- the average chain length is preferably from 16.5 to 17.8 carbon atoms.
- the iodine value is preferably from 5 to 40, more preferably, from 15 to 35.
- the iodine value is the amount of iodine in g consumed by the reaction of the double bonds of 100 g of fatty acid, which may notably be determined by the method of ISO 3961.
- the fatty acid moiety may be derived from a mixture of fatty acids comprising both saturated and unsaturated fatty acids.
- the quaternary ammonium compound is a compound of the general formula :
- R15 is either hydrogen, a short chain C1-C6, preferably C1-C3 alkyl or hydroxyalkyl group, poly(C2-C3 alkowy), preferably polyethoxy, benzyl, or mixtures thereof;
- Ri3 is a hydrocarbyl, or substituted hydrocarbyl group
- Ri4 is a C1-C6 alkylene group, preferably an ethylene group
- G is an oxygen atom, or an -NR10- group wherein R10 is as defined above.
- a non-limiting example of compound (VIII) is 1 -methyl-1 - stearoylamidoethyl-2- stearoylimidazolinium methylsulfate.
- the quaternary ammonium compound is a compound of the general formula (IX): wherein R13, Ru and G are defined as above.
- R 13 is defined as above.
- the quaternary ammonium compound may be present in an amount of from 0.5 to 45 wt% based on the total weight of the composition, for instance from 0.5 to 10 wt% based on the total weight of the composition, for instance from 2 to 8 wt% based on the total weight of the composition, for instance from 2.5 to 6 wt% based on the total weight of the composition.
- the composition comprises a cationic polysaccharide, or a mixture of cationic polysaccharides.
- the cationic polysaccharide can be obtained by chemically modifying polysaccharides (generally natural polysaccharides). By such modification, cationic side groups, such as quaternary ammonium groups, can be introduced into the polysaccharide backbone.
- the cationic polysaccharides suitable for the present invention include but are not limited to :
- cationic cellulose and derivatives thereof cationic starch and derivatives thereof, cationic callose and derivatives thereof, cationic xylan and derivatives thereof, cationic mannan and derivatives thereof, cationic galactomannan and derivatives thereof, such as cationic guar and derivatives thereof.
- the cationic celluloses may be cellulose ethers comprising quaternary ammonium groups, cationic cellulose copolymers or celluloses grafted with a water-soluble quaternary ammonium monomer.
- cellulose ethers include those sold under the names“JR” (JR 400, JR 125, JR 30M) or“LR” (LR 400, LR 30M) by the Dow Company. These polymers are also defined in the CTFA dictionary as hydroxyethylcellulose quaternary ammoniums that have reacted with an epoxide substituted with a trimethylammonium group.
- Suitable cationic celluloses also include LR3000 KC from the Solvay Company.
- the cationic cellulose copolymers or the celluloses grafted with a water- soluble quaternary ammonium monomer may be those described in US patent no. 4,131 ,576, such as hydroxyalkylcelluloses, for instance hydroxymethyl-, hydroxyethyl- or hydroxypropylcelluloses grafted especially with a methacryloyl-ethyltrimethylammonium, methacrylamidopropyltrimethylammonium or dimethyl-diallylammonium salt.
- the commercial products corresponding to this definition are more particularly the products sold under the names Celquat ® L 200 and Celquat ® H 100 by the Akzo Nobel Company.
- Cationic starches suitable for the present invention include the products sold under Polygelo ® (cationic starches from Sigma), the products sold under Softgel ® , Amylofax ® and Solvitose ® (cationic starches from Avebe), CATO from the National Starch Company.
- Suitable cationic galactomannans can be those derived from Fenugreek Gum, Konjac Gum, Tara Gum, Cassia Gum or Guar Gum.
- the cationic polysaccharide is preferably a cationic guar.
- Guars are polysaccharides composed of the sugars galactose and mannose.
- the backbone is a linear chain of b 1 ,4-linked mannose residues to which galactose residues are 1 ,6-linked at every second mannose in average, forming short side units.
- the cationic guars are cationic derivatives of guars.
- the cationic group may be a quaternary ammonium group bearing 3 radicals, which may be identical or different, preferably chosen from hydrogen, alkyl, hydroxyalkyl, epoxyalkyl, alkenyl, or aryl, preferably containing 1 to 22 carbon atoms, more particularly 1 to 14 and advantageously 1 to 3 carbon atoms.
- the counterion is generally a halogen.
- One example of the halogen is chlorine.
- Examples of the quaternary ammonium group include : 3-chloro- 2-hydroxypropyl trimethyl ammonium chloride (CHPTMAC), 2,3- epoxypropyl trimethyl ammonium chloride (EPTAC), diallyldimethyl ammonium chloride (DMDAAC), vinylbenzene trimethyl ammonium chloride, trimethylammonium ethyl metacrylate chloride, methacrylamidopropyltrimethyl ammonium chloride (MAPTAC), and tetraalkylammonium chloride.
- CHPTMAC 3-chloro- 2-hydroxypropyl trimethyl ammonium chloride
- EPTAC 2,3- epoxypropyl trimethyl ammonium chloride
- DMDAAC diallyldimethyl ammonium chloride
- VMAAC methacrylamidopropyltrimethyl ammonium chloride
- tetraalkylammonium chloride tetraalkylammonium chloride.
- cationic functional group in the cationic polysaccharides is trimethylamino(2-hydroxyl)propyl, with a counter ion.
- Various counter ions can be utilized, including but not limited to halides, such as chloride, fluoride, bromide, and iodide, sulfate, nitrate, methylsulfate, and mixtures thereof.
- the cationic guars suitable for the present invention may be chosen from: cationic hydroxyalkyl guars, such as cationic hydroxyethyl guar, cationic hydroxypropyl guar, cationic hydroxybutyl guar, and cationic carboxylalkyl guars including cationic carboxymethyl guar, cationic alkylcarboxy guars such as cationic carboxylpropyl guar and cationic carboxybutyl guar, cationic carboxymethylhydroxypropyl guar.
- the cationic polysaccharide is a guar hydroxypropyltrimonium chloride or a hydroxypropyl guar hydroxypropyltrimonium chloride.
- the cationic polysaccharides such as the cationic guars, may have an weight average molecular weight (Mw) of between 100,000 Daltons and 3,500,000 Daltons, preferably between 100,000 Daltons and 1 ,500,000 Daltons.
- Mw weight average molecular weight
- the composition may comprise from 0.05 to 10 wt% of the cationic polysaccharide based on the total weight of the composition, for instance from 0.05 to 5 wt% based on the total weight of the composition, for instance from 0.2 to 2 wt% based on the total weight of the composition.
- DS Degree of Substitution
- cationic polysaccharides such as cationic guars
- DS is the average number of hydroxyl groups substituted per sugar unit.
- DS may notably represent the number of the carboxymethyl groups per sugar unit.
- DS may be determined by titration.
- the DS of the cationic polysaccharide may be in the range of 0.01 to 1 , for instance in the range of 0.05 to 1 , for instance in the range of 0.05 to 0.2.
- CD Charge Density
- the CD of the cationic polysaccharide such as the cationic guar, may be in the range of 0.1 to 3 meq/gm, for instance in the range of 0.1 to 2 meq/gm, for instance in the range of 0.1 to 1 meq/gm.
- the non-ionic polysaccharide according to the present invention can be a modified non-ionic polysaccharide or a non-modified non-ionic polysaccharide.
- the modified non-ionic polysaccharide may comprise hydroxyalkylation and/or esterification.
- the level of modification of non-ionic polysaccharides can be characterized by Molar Substitution (MS), which means the average number of moles of substituents, such as hydroxypropyl groups, per mole of the monosaccharide unit.
- MS can be determined by the Zeisel-GC method, notably based on the following literature reference: K. L. Hodges, W. E. Kester, D. L. Wiederrich, and J.
- Carrier gas Flow Helium— 1 ml/min
- Injection volume 1 microliter.
- the MS of the non-ionic polysaccharide may be in the range of 0 to 3, for instance in the range of 0.1 to 3.
- the non-ionic polysaccharide may be especially chosen from glucans, modified or non-modified starches (such as those derived, for example, from cereals, for instance wheat, corn or rice, from vegetables, for instance yellow pea, and tubers, for instance potato or cassava), amylose, amylopectin, glycogen, dextrans, celluloses and derivatives thereof (methylcelluloses, hydroxyalkylcelluloses, ethylhydroxyethylcelluloses), mannans, xylans, lignins, arabans, galactans, galacturonans, chitin, chitosans, glucuronoxylans, arabinoxylans, xyloglucans, glucomannans, pectic acids and pectins, arabinogalactans, carrageenans, agars, gum arabics, gum tragacanths, ghatti gums, karaya gums, carob gums,
- celluloses that are especially used are hydroxyethylcelluloses and hydroxypropylcelluloses. Mention may be made of the products sold under the names Klucel ® EF, Klucel ® H, Klucel ® LHF, Klucel ® MF and Klucel ® G by the Aqualon Company, and Cellosize ® Polymer PCG-10 by the Amerchol Company, and HEC, HPMC K200, HPMC K35M by the Ashland Company.
- the non-ionic polysaccharide is preferably a non-ionic guar, which can be modified or non- modified.
- Suitable non-modified non-ionic guars include the products sold under the name Vidogum ® GH 175 by the Unipectine Company and under the names Meypro ® -Guar 50 and Jaguar ® C by the Solvay Company.
- the modified non-ionic guars are especially modified with C1-C6 hydroxyalkyl groups.
- the hydroxyalkyl groups that may be mentioned, for example, are hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups.
- guars are well known in the prior art and can be prepared, for example, by reacting the corresponding alkene oxides such as, for example, propylene oxides, with the guar so as to obtain a guar modified with hydroxypropyl groups.
- the non-ionic polysaccharide may have a weight average molecular weight (Mw) of between 100,000 Daltons and 3,500,000 Daltons, preferably between 500,000 Daltons and 3,500,000 Daltons.
- Mw weight average molecular weight
- the composition may comprise from 0.05 to 10 wt% of the non-ionic polysaccharide based on the total weight of the composition, for instance from 0.05 to 5 wt% based on the total weight of the composition, for instance from 0.2 to 2 wt% based on the total weight of the composition.
- the weight ratio between the quaternary ammonium compound and the total polysaccharides comprised in the composition may be between 2:1 and 100:1 , preferably between 5:1 and 30:1.
- the weight ratio between the cationic polysaccharide and the non-ionic polysaccharide comprised in the composition may be between 1 :10 and 10:1 , preferably between 1 :3 and 3:1.
- the vegetable oils suitable for the present invention is typically an oil derived from a plant, for example, oils from seeds or fruits.
- vegetable oils include sunflower oil, coconut oil, soybean oil, canola oil, rapeseed oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, safflower oil, sesame oil, linseed oil, palm kernel oil, tung oil, jatropha oil, mustard oil, camelina oil, pennycress oil, castor oil, wheatgerm oil, apricot kernel oil, pistachio oil, poppy oil, pine oil, avocado oil, hazel nut oil, grapeseed oil, colza oil, cade oil, peach kernel oil, coffee bean oil, jojoba oil, and a mixture thereof.
- said vegetable oil may be a mixture of the mono- and di- and tri-esters of a fatty acid mixture and glycerine, wherein said fatty acid mixture has the same or substantially similar fatty acid composition as a plant-based oil, such as one of the above mentioned plant-based oils.
- the vegetable oil is preferably selected from sunflower oil, olive oil and almond oil, in particular sunflower oil.
- Sunflower oil usually has a fatty acid composition of about 0.1 wt% laurinic acid, about 0.2 wt% myristinic acid, from about 4.0 to about 8.0 wt% palmitic acid, about 0.3 wt% palmitoleic acid, from about 3.0 to about 7.0 wt% stearic acid, from about 14.0 to about 39.4 wt% oleic acid, from about 60.0 to about 88.0 wt% linoleic acid, about 0.3 wt% linolenic acid, about 0.5 wt% arachidic acid, about 0.3 wt% gadoleinic acid and from about 0.3 to about 1.5 wt% behenic acid.
- Olive oil is plant-based oil pressed from the pulp and from the kernel of olives.
- Olive oil usually contains fatty acids as a mixture of from about 64.0 to about 68.0 wt% oleic acid, from about 11.0 to about 16.0 wt% linoleic acid, from about 8.0 to about 10.0 wt% palmitic acid, from about 4.0 to about 6.0 wt% eicosaenic acid and from about 4.0 to about 6.0 wt% palmitoleic acid.
- the name almond oil ( Prunus amygdalus du/cis (Sweet Almond) Oil) means the plant-based oil, which is obtained from both the sweet ( /at : dulcis) and also the bitter ( /at : amarus) almonds (by employing cold-pressing, for example).
- the fatty acid mixture of almond oil typically contains about 0.1 wt% of saturated fatty acids with a chain length of less than about 16 carbon atoms, from about 4.0 to about 9.0 wt% palmitic acid, about 0.8 wt% palmitoleic acid, about 0.2 wt% margarine acid, about 3.0 wt% stearic acid, from about 62.0 to about 86.0 wt% oleic acid, from about 20.0 to about 30.0 wt% linoleic acid, about 0.4 wt% linolenic acid, about 0.2 wt% arachidic acid, about 0.3 wt% eicosenoic acid, about 0.2 wt% behenic acid and about 0.1 wt% erucic acid.
- Every plant oil is exemplified by its content of various fatty acids within specific quantity ranges. Since plant-based oils are natural ingredients, the specified fatty acid quantities are subject to natural a fluctuation range, which can vary slightly depending on the origin or the oil and the prevailing environmental conditions. The usual quantity ranges are therefore given for all the fatty acids contained in the oil concerned. Of course, all specified weight percentages are added to a maximum of about 100 wt% in each special oil batch.
- the vegetable oil may be present in an amount of from 0.1 to 5 wt%, based on the total weight of the composition, for instance from 0.5 to 5 wt%, for instance from 1 wt% to 3 wt%.
- composition notably a fabric conditioning composition, which comprises (a) a quaternary ammonium compound; (b) a cationic polysaccharide; (c) a non-ionic polysaccharide; and (d) a vegetable oil; wherein the composition is substantially free or completely free of any silicone.
- the term “substantially free” when used with reference to the absence of silicone means that the composition comprises less than 0.1 wt % of the silicone, more preferably less than 0.01 wt % of the silicone, based on the total weight of the composition.
- the term “completely free” when used with reference to the absence of silicone i.e. , 0 wt% of the silicone, means that the composition comprises no silicone at all.
- Vegetable oil may be included in the composition for enhanced stability or enhanced softening performance, among other benefits, without the need for silicones to be included in the composition. Silicones may cause environmental concerns, and are thus less favourable for certain applications.
- compositions can impart fabrics, aside from softness and other conditioning benefits, pleasant odour. This will require the compositions to contain a fragrance material or perfume in an amount sufficient for imparting the odour to the fabrics after the treatment. In addition, it is highly desired that the fragrance material or perfume can be effectively deposited onto the fabrics and the odour provided by them can be of high intensity and be long lasting on the fabrics.
- fragrance material or perfume means any organic substance or composition which has a desired olfactory property and is essentially non-toxic.
- substances or compositions include all fragrance material and perfumes that are commonly used in perfumery or in household compositions (laundry detergents, fabric conditioning compositions, soaps, all-purpose cleaners, bathroom cleaners, floor cleaners) or personal care compositions.
- the compounds involved may be natural, semi-synthetic or synthetic in origin.
- fragrance materials and perfumes may be assigned to the classes of substance comprising the hydrocarbons, aldehydes or esters.
- the fragrances and perfumes also include natural extracts and/or essences, which may comprise complex mixtures of constituents, i.e. fruits such as almond, apple, cherry, grape, pear, pineapple, orange, lemon, strawberry, raspberry and the like; musk, flower scents such as lavender, jasmine, lily, magnolia, rose, iris, carnation and the like; herbal scents such as rosemary, thyme, sage and the like; woodland scents such as pine, spruce, cedar and the like.
- Non limitative examples of synthetic and semi-synthetic fragrance materials and perfumes are :
- hexylcinnamaldehyde 2-methyl-3-(tert-butylphenyl)propionaldehyde, 7- acetyl-1 ,2,3,4,5,6,7,8-octahydro-1 ,1 ,6,7-tetramethylnaphthalene, benzyl salicylate, 7-acetyl-1 ,1 ,3,4,4,6-hexamethyltetralin, para-tert-butylcyclohexyl acetate, methyl dihydrojasmonate, (b -naphthol methyl ether, methyl g- naphthyl ketone, 2-methyl-2-(para-isopropylphenyl)propionaldehyde,
- fragrance materials and perfumes are essential oils, resinoids and resins from a large number of sources, such as, Peru balsam, olibanum resinoid, styrax, labdanum resin, nutmeg, cassia oil, benzoin resin, coriander, clary sage, eucalyptus, geranium, lavender, mace extract, neroli, nutmeg, spearmint, sweet violet leaf, valerian and lavandin.
- sources such as, Peru balsam, olibanum resinoid, styrax, labdanum resin, nutmeg, cassia oil, benzoin resin, coriander, clary sage, eucalyptus, geranium, lavender, mace extract, neroli, nutmeg, spearmint, sweet violet leaf, valerian and lavandin.
- fragrance materials and perfumes may be encapsulated, typical perfume components which it is advantageous to encapsulate, include those with a relatively low boiling point. It is also advantageous to encapsulate perfume components which have a low Clog P (i.e. those which will be partitioned into water), preferably with a Clog P of less than 3.0.
- Clog P means the calculated logarithm to base 10 of the octanol/water partition coefficient (P).
- fragrance materials and perfumes include: phenylethyl alcohol, terpineol, linalool, linalyl acetate, geraniol, nerol, 2-(1 ,1- dimethylethyl)cyclo-hexanol acetate, benzyl acetate, and eugenol.
- the fragrance material or perfume can be used as single substance or in a mixture with one another.
- Perfumes frequently include solvents or diluents, for example: ethanol, isopropanol, diethylene glycol monoethyl ether, dipropylene glycol, diethyl phthalate and triethyl citrate.
- solvents or diluents for example: ethanol, isopropanol, diethylene glycol monoethyl ether, dipropylene glycol, diethyl phthalate and triethyl citrate.
- the composition may comprise from 0.01 to 10 wt% of the fragrance material or perfume based on the total weight of the composition, for instance from 0.1 to 5 wt% based on the total weight of the composition, for instance from 0.3 to 5 wt% based on the total weight of the composition.
- stabilising products such as salts of amines having a short chain, which are quaternised or non-quaternised, for example of triethanolamine, N-methyldiethanolamine, and also non-ionic surfactants, such as ethoxylated fatty alcohols, ethoxylated fatty amines, polysorbate, and ethoxylated alkyl phenols; typically used at a level of from 0 to 15 wt% by weight of the composition;
- products that improve viscosity control which is preferably added when the composition comprises high concentrations of fabric conditioning active (such as the quaternary ammonium compound); for example inorganic salts, such as calcium chloride, magnesium chloride, calcium sulphate, sodium chloride; products which can be used improve the stability in concentrated compositions, such as compounds of the glycol type, such as, glycerol, polyglycerols, ethylene glycol, polyethylene glycols, dipropylene glycol, other polyglycols; and thickening agents for diluted compositions, for example, acrylamide based polymers (e.g. Flosoft ® 222 from the SNF Company), hydrophobically-modified ethoxylated urethanes (e.g. Acusol 880 from the Dow Company);
- fabric conditioning active such as the quaternary ammonium compound
- inorganic salts such as calcium chloride, magnesium chloride, calcium sulphate, sodium chloride
- products which can be used improve the stability in concentrated
- components for adjusting the pH which is preferably from 2 to 8, such as any type of inorganic and/or organic acid, for example hydrochloric, sulphuric, phosphoric, citric acid;
- agents that improve soil release such as the known polymers or copolymers based on terephthalates;
- antioxidants such as antioxidants, colouring agents, perfumes, germicides, fungicides, anti-corrosive agents, anti-crease agents, opacifiers, optical brighteners, pearl lustre agents.
- the composition may further comprise at least one surfactant system.
- surfactants can be used in the composition of the invention, including cationic, nonionic and/or amphoteric surfactants, which are commercially available from a number of sources.
- the composition may comprise a non-ionic surfactant which is an alkoxylated compound.
- the non-ionic surfactant may comprise an average of from 2 to 100 moles of alkylene oxide per mole of the nonionic surfactant. This is referred to herein as the alkoxylation number (of the non-ionic surfactant).
- the composition may comprise a dye, such as an acid dye, a hydrophobic dye, a basic dye, a reactive dye, a dye conjugate.
- Suitable acid dyes include azine dyes such as acid blue 98, acid violet 50, and acid blue 59, non-azine acid dyes such as acid violet 17, acid black 1 and acid blue 29.
- Flydrophobic dyes selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone and mono-azo or di-azo dye chromophores.
- Suitable hydrophobic dyes are those dyes which do not contain any charged water solubilising group.
- the hydrophobic dyes may be selected from the groups of disperse and solvent dyes. Blue and violet anthraquinone and mono-azo dye are preferred.
- Basic dyes are organic dyes which carry a net positive charge. They deposit onto cotton. They are of particular utility for used in composition that contain predominantly cationic surfactants.
- Dyes may be selected from the basic violet and basic blue dyes listed in the Colour Index International.
- Preferred examples include triarylmethane basic dyes, methane basic dye, anthraquinone basic dyes, basic blue 16, basic blue 65, basic blue 66, basic blue 67, basic blue 71 , basic blue 159, basic violet 19, basic violet 35, basic violet 38, basic violet 48; basic blue 3, basic blue 75, basic blue 95, basic blue 122, basic blue 124, basic blue 141.
- Reactive dyes are dyes which contain an organic group capable of reacting with cellulose and linking the dye to cellulose with a covalent bond.
- the reactive group is hydrolysed or reactive group of the dyes has been reacted with an organic species such as a polymer, so as to the link the dye to this species.
- Particularly preferred dyes are: direct violet 7, direct violet 9, direct violet 11 , direct violet 26, direct violet 31 , direct violet 35, direct violet 40, direct violet 41 , direct violet 51 , direct violet 99, acid blue 98, acid violet 50, acid blue 59, acid violet 17, acid black 1 , acid blue 29, solvent violet 13, disperse violet 27 disperse violet 26, disperse violet 28, disperse violet 63, disperse violet 77 and mixtures thereof.
- the composition may comprise an antimicrobial.
- the antimicrobial may be a halogenated material. Suitable halogenated materials include 5-chloro-2- (2,4-dichlorophenoxy)phenol, o-Benzyl-p-chloro- phenol, and 4-chloro-3- methylphenol.
- the antimicrobial may be a non-halogenated material. Suitable non-halogenated materials include 2-Phenylphenol and 2-(1 -Hydroxy-1 -methylethyl)-5- methylcyclohexanol. Phenyl ethers are one preferred sub-set of the antimicrobials.
- the antimicrobial may also be a bi- halogenated compound. Most preferably this comprises 4-4' dichloro-2- hydroxy diphenyl ether, and /or 2,2- dibromo-3-nitrilopropionamide (DBNPA).
- DBNPA 2,2- dibromo-3-nitrilopropionamide
- composition may also comprise preservatives. Preferably only those preservatives that have no, or only slight, skin sensitizing potential are used. Examples are phenoxy ethanol, 3-iodo-2-propynylbutyl carbamate, sodium N-(hydroxymethyl)glycinate, biphenyl-2-ol as well as mixtures thereof.
- the composition may also comprise antioxidants to prevent undesirable changes caused by oxygen and other oxidative processes to the solid composition and/or to the treated textile fabrics.
- This class of compounds includes, for example, substituted phenols, hydroquinones, pyrocatechols, aromatic amines and vitamin E.
- the composition may comprise a polymeric thickening agent.
- Suitable polymeric thickening agents are water soluble or dispersable.
- Monomers of the polymeric thickening agent may be non-ionic, anionic or cationic. Following is a non-restrictive list of monomers performing a nonionic function: acrylamide, methacrylamide, N-Alkyl acrylamide, N-vinyl pyrrolidone, N-vinyl formamide, N-vinyl acetamide, vinylacetate, vinyl alcohol, acrylate esters, allyl alcohol.
- monomers performing an anionic function acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid, as well as monomers performing a sulfonic acid or phosphonic acid functions, such as 2- acrylamido-2-methyl propane sulfonic acid (ATBS).
- ATBS 2- acrylamido-2-methyl propane sulfonic acid
- the monomers may also contain hydrophobic groups.
- Suitable cationic monomers are selected from the group consisting of the following monomers and derivatives and their quaternary or acid salts: dimethylaminopropylmethacrylamide, dimethylaminopropylacrylamide, diallylamine, methyldiallylamine, dialkylaminoalkyl-acrylates and methacrylates, dialkylaminoalkyl- acrylamides or -methacrylamides.
- Polymeric thickening agents particularly useful in the composition of the invention include those described in WO2010/078959. These are crosslinked water swellable cationic copolymers having at least one cationic monomer and optionally other nonionic and/or anionic monomers. Preferred polymers of this type are copolymers of acrylamide and trimethylaminoethylacrylate chloride.
- composition of the present invention may optionally contain an oily sugar derivative.
- An oily sugar derivative is a liquid or soft solid derivative of a cyclic polyol (CPE) or of a reduced saccharide (RSE), said derivative resulting from 35 to 100% of the hydroxyl groups in said polyol or in said saccharide being esterified or etherified.
- the derivative has two or more ester or ether groups independently attached to a C8-C22 alkyl or alkenyl chain.
- the CPE or RSE does not have any substantial crystalline character at 20 °C. Instead it is preferably in a liquid or soft solid state as herein defined at 20 °C.
- liquid or soft solid (as hereinafter defined) CPEs or RSEs suitable for use in the present invention result from 35 to 100% of the hydroxyl groups of the starting cyclic polyol or reduced saccharide being esterified or etherified with groups such that the CPEs or RSEs are in the required liquid or soft solid state. These groups typically contain unsaturation, branching or mixed chain lengths.
- the CPEs or RSEs have 3 or more ester or ether groups or mixtures thereof, for example 3 to 8, especially 3 to 5. It is preferred if two or more of the ester or ether groups of the CPE or RSE are independently of one another attached to a Cs to C22 alkyl or alkenyl chain.
- the Cs to C22 alkyl or alkenyl groups may be branched or linear carbon chains.
- the CPE or RSE contains at least 35% tri or higher esters, e.g. at least 40%.
- the CPE or RSE has at least one of the chains independently attached to the ester or ether groups having at least one unsaturated bond. This provides a cost effective way of making the CPE or RSE a liquid or a soft solid. It is preferred if predominantly unsaturated fatty chains, derived from, for example, rape oil, cotton seed oil, soybean oil, oleic, tallow, palmitoleic, linoleic, erucic or other sources of unsaturated vegetable fatty acids, are attached to the ester/ether groups.
- the ester or ether chains of the CPE or RSE are preferably predominantly unsaturated.
- Preferred CPEs or RSEs include sucrose tetratallowate, sucrose tetrarapeate, sucrose tetraoleate, sucrose tetraesters of soybean oil or cotton seed oil, cellobiose tetraoleate, sucrose trioleate, sucrose triapeate, sucrose pentaoleate, sucrose pentarapeate, sucrose hexaoleate, sucrose hexarapeate, sucrose triesters, pentaesters and hexaesters of soybean oil or cotton seed oil, glucose tiroleate, glucose tetraoleate, xylose trioleate, or sucrose tetra-,tri-, penta- or hexa- esters with any mixture of predominantly unsaturated fatty acid chains.
- CPEs or RSEs are those with monounsaturated fatty acid chains, i.e. where any polyunsaturation has been removed by partial hydrogenation.
- CPEs or RSEs based on polyunsaturated fatty acid chains e.g. sucrose tetralinoleate, may be used provided most of the polyunsaturation has been removed by partial hydrogenation.
- liquid CPEs or RSEs are any of the above but where the polyunsaturation has been removed through partial hydrogenation.
- Preferably 40% or more of the fatty acid chains contain an unsaturated bond, more preferably 50% or more, most preferably 60% or more. In most cases 65% to 100%, e.g. 65 % to 95% contain an unsaturated bond.
- CPEs are preferred for use with the present invention.
- Inositol is a preferred example of a cyclic polyol. Inositol derivatives are especially preferred.
- cyclic polyol encompasses all forms of saccharides. Indeed saccharides are especially preferred for use with this invention. Examples of preferred saccharides for the CPEs or RSEs to be derived from are monosaccharides and disaccharides.
- Examples of monosaccharides include xylose, arabinose, galactose, fructose, sorbose and glucose. Glucose is especially preferred.
- Examples of disaccharides include maltose, lactose, cellobiose and sucrose. Sucrose is especially preferred.
- An example of a reduced saccharide is sorbitan.
- the liquid or soft solid CPEs can be prepared by methods well known to those skilled in the art. These include acylation of the cyclic polyol or reduced saccharide with an acid chloride; trans-esterification of the cyclic polyol or reduced saccharide fatty acid esters using a variety of catalysts; acylation of the cyclic polyol or reduced saccharide with an acid anhydride and acylation of the cyclic polyol or reduced saccharide with a fatty acid.
- the CPE or RSE has 3 or more, preferably 4 or more ester or ether groups. If the CPE is a disaccharide it is preferred if the disaccharide has 3 or more ester or ether groups. Particularly preferred CPEs are esters with a degree of esterification of 3 to 5, for example, sucrose tri, tetra and penta esters.
- each ring of the CPE has one ether or ester group, preferably at the Ci position.
- Suitable examples of such compounds include methyl glucose derivatives.
- CPEs examples include esters of alkyl(poly)glucosides, in particular alkyl glucoside esters having a degree of polymerisation from 1 to 2.
- the length of the unsaturated (and saturated if present) chains in the CPE or RSE is C8-C22, preferably C12-C22. It is possible to include one or more chains of Ci-Cs, however these are less preferred.
- the liquid or soft solid CPEs or RSEs which are suitable for use in the present invention are characterised as materials having a solidliquid ratio of between 50:50 and 0:100 at 20 °C as determined by T2 relaxation time NMR, preferably between 43:57 and 0:100, most preferably between 40:60 and 0:100, such as, 20:80 and 0:100.
- the T2 NMR relaxation time is commonly used for characterising solidliquid ratios in soft solid products such as fats and margarines.
- any component of the signal with a T2 of less than 100 ps is considered to be a solid component and any component with T2 > 100 ps is considered to be a liquid component.
- the prefixes e.g. tetra and penta
- the compounds exist as a mixture of materials ranging from the monoester to the fully esterified ester. It is the average degree of esterification which is used herein to define the CPEs and RSEs.
- the FILB of the CPE or RSE is typically between 1 and 3.
- the CPE or RSE is preferably present in the composition in an amount of 0.5 to 50 wt% by weight, based on the total weight of the composition, for instance 1 to 30 wt%, for instance 2 to 20 wt%.
- the CPEs and RSEs for use in the compositions of the invention include sucrose tetraoleate, sucrose pentaerucate, sucrose tetraerucate and sucrose pentaoleate.
- composition may be prepared by procedures known by a skilled person, for example, by using procedures disclosed in PCT patent publication no. WO2015/192971.
- the composition may take a variety of physical forms including solid (such as granule), liquid, liquid-gel, paste-like, foam in either aqueous or non- aqueous form, and any other suitable form known by a person skilled in the art.
- a preferred form of the composition is a liquid form, and preferably in the form of an aqueous dispersion in water.
- the composition may also be dispensed with dispensing means such as a sprayer or aerosol dispenser.
- the composition usually also contains a liquid carrier, which may provide the balance of the composition.
- Suitable liquid carriers are selected from water, organic solvents and mixtures thereof.
- the liquid carrier employed in the composition is preferably water due to its low cost, safety, and environmental compatibility. Mixtures of water and organic solvent may be used.
- Preferred organic solvents are; monohydric alcohol, such as ethanol, propanol, iso-propanol or butanol; dihydric alcohol, such as glycol; trihydric alcohols, such as glycerol, and polyhydric (polyol) alcohols.
- a composition comprising (a) from 0.5 wt% to 10 wt% of a quaternary ammonium compound; (b) from 0.05 wt% to 10 wt% of a cationic polysaccharide; (c) from 0.05 wt% to 10 wt% of a non-ionic polysaccharide; (d) from 0.1 wt% to 5 wt% of a vegitable oil, weight percentages are based on the total weight of the composition.
- composition comprising (a) from 2 wt% to 8 wt% of a quaternary ammonium compound; (b) from 0.05 wt% to 5 wt% of a cationic polysaccharide; (c) from 0.05 wt% to 5 wt% of a non-ionic polysaccharide; (d) from 1 wt% to 3 wt% of a vegetable oil; weight percentages are based on the total weight of the composition.
- the present invention also concerns use of the composition described herein for treating a fabric, for example, for conditioning a fabric.
- the invention also concerns use of the composition described herein as a textile care agent.
- the present invention also provides a method for conditioning a fabric by using the composition described herein.
- the method notably comprises the step of contacting the composition, or a dilution thereof, with the fabric.
- the composition can be used in a so-called rinse process.
- the rinse step may be a rinse cycle in an automated or non-automated washing machine.
- the washing machine can either be front loaded or top loaded.
- the rinse step may be a hand rinsing process, which can be performed in a container, such as a basin or bucket.
- the composition is added during the rinse cycle of an automatic laundry machine (such as an automatic fabric washing machine).
- the composition is first diluted in an aqueous rinse solution.
- the laundered fabrics which have been washed with a detergent liquor and optionally rinsed in a first inefficient rinse step are placed in the rinse solution.
- Laundry operation in which a fabric conditioning composition is used usually involves washing fabrics with a detergent, such as a detergent liquor, removing majority of the detergent, and subsequently treating the fabrics with a rinse solution containing the fabric conditioning composition.
- a detergent such as a detergent liquor
- removing majority of the detergent and subsequently treating the fabrics with a rinse solution containing the fabric conditioning composition.
- Such use of the fabric conditioning composition in conjunction with the detergent has certain problems.
- fabric conditioning actives which are unusually cationic in nature, may interact with laundry residues carried over to the rinse solution from the washing step.
- Such laundry residues notably include anionic surfactants which are commonly used in detergents.
- the interaction between the fabric conditioning actives and the carry-over laundry residues may result in a reduced conditioning effect, such as a reduced softening effect.
- the interaction may also lead to presence of poorly soluble floes in the rinse solution which causes troubles to consumers.
- a fabric conditioning composition can universally perform under laundry conditions which may vary between territories and/or population, and which may be subject to practice of the consumers.
- the softening conditioning composition can perform well regardless the laundry residues have been sufficiently or insufficiently removed from the fabrics before the conditioning step.
- composition according to the invention can provide excellent softening performance in absence of laundry residues. Also, the composition, when being used in the first rinse in which the rinse solution contains considerable amount of laundry residues, can provide superior softening effects compared to conventional fabric conditioning compositions.
- Cationic Polysaccharide 1 a guar hydroxypropyltrimonium chloride having a weight average molecular weight of below 1 ,500,000 Daltons;
- Non-ionic Polysaccharide 1 a hydroxypropyl guar having a weight average molecular weight of between 1 ,500,000 and 2,500,000 Daltons and a MS of between 0.9 and 1.6;
- Vegetable Oil 1 NATUREL ® Sunflower Oil (SFO);
- Revised ASTM D5237-05 Standard was adopted for fabric softness evaluation.
- the softness of the treated towels was rated in a scale of 1 to 5, wherein 1 represents the lowest softness and 5 represents the highest softness. A difference in +0.25 suggested slight difference, +0.50 suggested significant difference between two softness.
- PS shown in Tables 1 and 2 refers to mixture of Cationic Polysaccharide 1 and Non-ionic Polysaccharide 1 (1 :3 by weight)
- inventive compositions provided excellent softening performance under both conditions of fabric treatment.
- inventive compositions provided same level of softening performance as that comprising high content quat alone (10.5 wt%), while in presence of laundry residue, a marked enhancement was evident.
- inventive compositions provided better softening performance compared to that comprising quat and polysaccharides components, or that comprising quat and vegetable oil components.
- PS shown in Table 3 refers to mixture of Cationic Polysaccharide 1 and Non-ionic
- results showed that the inventive composition exhibited good stability up to 16 weeks of storage without phase separation. In contrast, the composition without the polysaccharides component was phase separated, indicating poor storage stability.
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Abstract
Description
Claims
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EP2019063135 | 2019-05-21 | ||
PCT/EP2020/063243 WO2020234061A1 (en) | 2019-05-21 | 2020-05-12 | Fabric conditioning composition |
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EP20727173.5A Withdrawn EP3973042A1 (en) | 2019-05-21 | 2020-05-12 | Fabric conditioning composition |
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CN (1) | CN113874483A (en) |
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WO2023099593A1 (en) * | 2021-12-02 | 2023-06-08 | Unilever Ip Holdings B.V. | Fabric conditioner |
WO2023099595A1 (en) * | 2021-12-02 | 2023-06-08 | Unilever Ip Holdings B.V. | Fabric softening composition |
WO2024013174A1 (en) * | 2022-07-12 | 2024-01-18 | Unilever Ip Holdings B.V. | Laundry composition |
WO2024013171A1 (en) * | 2022-07-12 | 2024-01-18 | Unilever Ip Holdings B.V. | Laundry composition |
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US4131576A (en) | 1977-12-15 | 1978-12-26 | National Starch And Chemical Corporation | Process for the preparation of graft copolymers of a water soluble monomer and polysaccharide employing a two-phase reaction system |
AU734821B2 (en) | 1996-09-19 | 2001-06-21 | Procter & Gamble Company, The | Fabric softeners having increased performance |
CN102482619B (en) | 2009-01-06 | 2016-04-20 | S.P.C.M.股份有限公司 | Cationic polymer thickeners |
ES2569045T3 (en) * | 2011-08-24 | 2016-05-06 | Unilever N.V. | Delivery particles of a benefit agent comprising non-ionic polysaccharides |
KR102254335B1 (en) * | 2014-06-18 | 2021-05-24 | 로디아 오퍼레이션스 | Method of use of composition comprising a quaternary ammonium compound, a cationic polysaccharide and a nonionic polysaccharide |
MX2017004642A (en) * | 2014-10-08 | 2017-07-26 | Procter & Gamble | Fabric enhancer composition. |
EP3390601B1 (en) * | 2015-12-15 | 2019-04-10 | Unilever Plc. | Fabric conditioning composition |
CA3010919A1 (en) * | 2016-01-25 | 2017-08-03 | The Procter & Gamble Company | Treatment compositions |
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- 2020-05-12 CN CN202080037765.6A patent/CN113874483A/en active Pending
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