EP3952821A1

EP3952821A1 - Shampoo for more hair volume

Info

Publication number: EP3952821A1
Application number: EP20705318.2A
Authority: EP
Inventors: Soeren Scheele; Thomas Schroeder; Manuela METTE
Original assignee: Henkel AG and Co KGaA
Current assignee: Henkel AG and Co KGaA
Priority date: 2019-04-08
Filing date: 2020-02-10
Publication date: 2022-02-16
Also published as: DE102019204971A1; WO2020207641A1

Abstract

Cosmetic cleaning compositions comprising a) at least one surfactant selected from anionic, amphoteric, zwitterionic and/or nonionic surfactants, b) at least one naturally occurring gel former and c) particles containing at least two constituents from at least two different groups i. to viii.: i. optionally aftertreated pyrogenic silica, ii. microcrystalline cellulose and/or cellulose ether, iii. polyols having 3 to 8 carbon atoms, iv. dyes, v. vitamins, vi. oils and/or waxes, vii. plant extracts in powder form, viii. charcoal, are suitable for use as cosmetic hair cleaning products for improving a very wide variety of haircare parameters, and in particular for increasing hair volume, improving hair hand, reducing weighing-down of hair and/or reducing frizz.

Description

"Shampoo for more hair volume"

The application describes cosmetic cleaning agents based on surfactants, naturally occurring gel formers and specific particles.

The application also describes the use of these means of improvement

different hair care parameters, especially to improve hair volume.

With the help of cosmetic cleaning agents such as hair shampoos, human hair and the scalp can be cleaned and freed from sebum, styling agent residues and other soiling.

Due to the (mostly anionic) surfactants usually contained in cosmetic hair cleaning agents, hair cleaning is always accompanied by the removal of lipids and proteins from the hair or the scalp, which in particular with frequent cleaning results in damage to the hair structure and / or drying out of the scalp can.

Damage to the hair structure or the hair fibers, in particular split ends and / or hair breakage, can also be promoted by environmental influences (such as intense sunlight), mechanical loads (such as combing under the heat of a blow dryer) and chemical influences (such as coloring, shaping or straightening the hair) will.

To prevent and / or reduce hair damage, hair shampoos often have oil-based care substances, mostly silicones, added.

The use of silicones in hair cleaning agents is now controversial and has disadvantages, because by wetting the hair surface, silicones reduce the penetration of active ingredients and auxiliaries into the hair fibers and make hairstyle design more difficult.

Furthermore, the regular use of shampoos containing silicones sometimes leads to weighting of the hair, which is caused by the deposition and adhesion of too large amounts of silicone on the hair fibers.

In addition, the silicones in common hair cleaning products are usually polymeric

Compounds and / or alkoxylated nonionic emulsifiers have to be stabilized in a laborious manner, as a result of which the compositions become undesirably complex.

Finally, for reasons of sustainability, efforts are made to use as large a proportion as possible of biodegradable active ingredients and / or active ingredients of natural origin in cosmetic products.

The provision of nourishing cosmetic cleaning agents such as hair shampoos that are 'poor in' or 'free from' silicones, alkoxylated nonionic emulsifiers and / or declared as “poly ...” Ingredients (and which are not derived from natural sources) is therefore a relevant task in the field of (hair) cosmetics.

The present application was based on the task of making cosmetic cleaning agents available that do not improve the product performance of conventional silicones (and / or compounds declared as “PEG -...” and / or as “Poly -...” come from natural sources) containing cosmetic cleaning agents.

In addition to gentle and thorough cleaning - especially of (scalp) skin and hair - the use of cosmetic cleaning agents should preferably also ensure an improvement in parameters relevant to hair care, such as fullness, elasticity and softness.

Another task was to increase consumer acceptance of conventional products by providing such cosmetic cleaning agents.

The incorporation of specific particles in compositions containing surfactants made it possible to provide cleaning agents suitable for cosmetic purposes, in particular hair cleaning agents, with high care potential, in particular with high hair care potential. Compared to conventional (silicone-based) formulations, these have at least a comparable to improved product performance.

Only naturally occurring gel formers can be used as stabilizers for the particles, which is advantageous for reasons of sustainability.

Hair treated with the cleaning agents in particular has more volume and an improved hair grip. Another advantage is that by using the

Detergents reduce frizz and / or weighting of hair.

A first subject of this application is a cosmetic cleaning agent that

a) at least one surfactant selected from anionic, amphoteric, zwitterionic and / or nonionic surfactants,

b) at least one naturally occurring gelling agent, and

c) contains particles, the at least two components of at least two

different groups i. to viii. contain:

i. possibly aftertreated, pyrogenic silica,

ii. microcrystalline cellulose and / or cellulose ethers,

iii. Polyols with 3 to 8 carbon atoms,

iv. Dyes,

v. Vitamins,

vi. Oils and / or waxes,

vii. Plant extracts in powder form,

viii. Charcoal. According to a first preferred embodiment, particularly preferred cosmetic cleaning agents contain (based on the weight of the entire agent)

2.50 to 30.00% by weight of at least one surfactant a),

0.01 to 2.00% by weight of at least one naturally occurring gel former b),

0.01 to 10.00% by weight of at least particles c).

The cosmetic cleaning agents according to the invention are in principle suitable for cleaning and / or caring for the entire human body. They are particularly suitable for cleaning and / or caring for heavily haired body surfaces and in particular for cleaning and / or caring for the scalp and / or scalp hair.

The cosmetic cleaning agents according to the invention contain the active ingredients a) to c) preferably in a cosmetically acceptable carrier. In the context of the invention, this is preferably understood to mean an aqueous or aqueous-alcoholic carrier.

The cosmetic carrier preferably contains at least 75% by weight, more preferably at least 77% by weight, particularly preferably at least 78% by weight and particularly preferably at least 80% by weight of water.

The cosmetic carrier can furthermore contain 0.01 to 10% by weight, preferably 0.05 to 9% by weight and in particular 0.10 to 6% by weight of at least one alcohol.

Suitable alcohols are, for example, ethanol, ethyl diglycol, 1-propanol, 2-propanol,

Isopropanol, 1,2-propylene glycol, glycerine, diglycerine, triglycerine, 1-butanol, 2-butanol, 1,2-butanediol, 1,3-butanediol, 1-pentanol, 2-pentanol, 1,2-pentanediol, 1, 5-pentanediol, 1, hexanol, 2-hexanol, 1, 2-hexanediol, 1, 6-hexanediol, polyethylene glycols, sorbitol, sorbitan, benzyl alcohol, phenoxyethanol or mixtures of these alcohols.

The cosmetic cleaning agents according to the invention contain, as the first essential ingredient, at least one surfactant a) selected from anionic, amphoteric, zwitterionic and / or nonionic surfactants.

The mildness and the good foam properties of the cleaning agents according to the invention can be controlled to a particular extent by carefully selecting the amounts of surfactant and / or the types of surfactants.

The cleaning agents according to the invention preferably contain at least one anionic surfactant, which is essential for generating satisfactory amounts of foam and foam properties. To achieve an optimal balance between mildness and

A mixture of at least one anionic surfactant and at least one mild co-surfactant, which can preferably be selected from amphoteric and / or zwitterionic and / or nonionic surfactants, has been found to have foam properties of the agents according to the invention. The combination of the surfactant (s) (e) a) with components b) and c) in turn enables the relevant hair care parameters to be increased.

In a second preferred embodiment, the cosmetic cleaning agents according to the invention therefore contain (based on the weight of the total agent)

2.50 to 20.00% by weight of at least one anionic surfactant ai) and / or 0.50 to 10.00% by weight of at least one amphoteric and / or zwitterionic surfactant aii),

particularly preferably at least one anionic surfactant ai) and at least one amphoteric and / or zwitterionic surfactant aii) in the aforementioned amounts.

Suitable types of anionic surfactants which can be used in the agents according to the invention include, for example:

linear and branched fatty acids with 8 to 30 carbon atoms (soaps),

Ether carboxylic acids of the formula R-0- (CH ₂ -CH ₂ 0) x-CH ₂ -C00H, in which R is a linear or branched, saturated or unsaturated alkyl group with 8 to 30 carbon atoms and x = 0 or 1 to 16 ,

Acyl sarcosides with 8 to 24 carbon atoms in the acyl group (sarcosinate surfactants),

Acyl taurides with 8 to 24 carbon atoms in the acyl group (taurate surfactants),

Acyl isethionates with 8 to 24 carbon atoms in the acyl group (isethionate surfactants),

Sulfosuccinic acid mono- and / or dialkyl esters with 8 to 24 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkyl polyoxyethyl esters with 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups (sulfosuccinate surfactants),

Alpha-olefin sulfonates with 8 to 24 carbon atoms (alpha-olefin sulfonate surfactants),

Alkyl sulfates and / or alkyl ether sulfate salts of the formula R- (0CH2-CH2) n-0-S03X, in which R is preferably a straight-chain or branched, saturated or unsaturated alkyl group with 8 to 30 carbon atoms, x is the number 0 or 1 to 12 and X is an alkali, alkaline earth, ammonium or alkanolamine ion,

Sulfonates of unsaturated fatty acids with 8 to 24 carbon atoms and 1 to 6 double bonds,

Esters of tartaric acid and citric acid with alcohols which are addition products of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols having 8 to 22 carbon atoms, and / or

Alkyl and / or alkenyl ether phosphates of the formula

O

R- (OCH ₂ CH ₂ ) - o - p II - OR

ox

in which R ^{1 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{2 is} hydrogen, a radical (CH ₂ CH ₂ 0) _n R ¹ or X, n is numbers from 0 to 10 and X is represents hydrogen, an alkali or alkaline earth metal or the group —NR ³ R ⁴ R ⁵ R ⁶ , with R ³ to R ⁶ independently of one another represent a C 1 to C ₄ hydrocarbon radical.

Particularly preferred are alkyl sulfate and / or alkyl ether sulfate salts, (salts of)

Ether carboxylic acids, sarcosinates, isethionates, taurates, sulfosuccinates and / or alpha-olefin sulfonates, in particular alkyl sulfate and / or alkyl ether sulfate salts.

The anionic surfactant (s) ai) is (are) used in the cleaning agents according to the invention (based on the weight of the total agent) preferably in an amount of 2.50 to 20.00% by weight, more preferably 3.00 to 18.00% by weight, particularly preferably from 4.00 to 16.00% by weight, very particularly preferably from 5.00 to 14.00% by weight and in particular from 6.00 to 12.50% by weight .-% used.

In a very preferred embodiment, the anionic surfactant ai) is at least one (e) alkyl sulfate and / or alkyl ether sulfate salt, ether carboxylic acid (salt), sarcosinate, isethionate, taurate, sulfosuccinate and / or alpha-olefin sulfonate, in particular an alkyl sulfate and / or

Alkyl ether sulfate salt, used in the aforementioned amounts in the cleaning agents according to the invention.

The suitable amphoteric and / or zwitterionic surfactant types aii), which are in the

Cosmetic cleaning agents according to the invention which can be used include, for example, one or more compounds of the following formulas (i) to (vii). The radical R therein preferably represents a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 7 to 23 carbon atoms (formulas (i) and (ii)) or a straight-chain or branched, saturated or single or polyunsaturated alkyl or alkenyl radical with 8 to 24 carbon atoms (formulas (iii) to (vii)):

Preferred amphoteric surfactants of the aforementioned formulas (i) to (vii) contain as radical R predominantly a straight-chain or branched, saturated, mono- or polyunsaturated alkyl radical with 8 to 20, more preferably 8 to 18 and in particular 8 to 16 C. Atoms. Amphoteric surfactants b) in which the remainder R is derived from coconut oil are particularly preferred. Particularly preferred are those under the INCI names Sodium Cocoamphodiacetate, Disodium Cocoamphodiacetate, Sodium Lauroamphodiacetate, Sodium Lauroamphodiacetate, Sodium Cocoamphopropionate, Disodium Cocoamphodipropionate, Coco Betaine, Lauryl Betaine, Cocamidopropylbetain and surfactants known from several suppliers and / or lauramidopropyl betaine and / or lauramide.

Surfactants with the INCI names cocamidopropyl betaine, lauramidopropyl betaine, cocoampho (di) acetate and / or lauroapho (di) acetate are particularly preferred.

The amphoteric and / or zwitterionic co-surfactant (s) is (are) used in the cosmetic cleaning agents according to the invention (based on their total weight) preferably in an amount of 0.50 to 10.00 wt. -%, more preferably from 0.75 to 8.00% by weight, particularly preferably from 1.00 to 6.00% by weight and in particular from 1.25 to 5.00% by weight.

In a further particularly preferred embodiment, the cosmetic cleaning agents according to the invention contain

as an anionic surfactant ai) at least one compound from the group of

Alkyl (ether) sulfates, sarcosinates, taurates, isethionates, sulfosuccinates and / or

Olefin sulfonates, and

as amphoteric and / or zwitterionic surfactant aii) at least one compound from the group of alkylampho (di) acetates and / or propionates and / or alkylamidopropyl betaines.

Particularly preferred anionic surfactants for the purposes of the present invention are alkyl (ether) sulfates because of their excellent foam properties. These are - to increase the mildness - preferably combined with cocamidopropyl betaine and / or cocoampho (di) acetate as co-surfactant. For some forms of application - for example for cleaning and caring for severely damaged hair and / or particularly fine hair and / or baby or toddler hair - it can be advantageous not to use sulfate surfactants.

Dispensing with sulfate surfactants often results in a dramatic deterioration in the

Foam properties (quantity and quality) go hand in hand, so that the selection of suitable surfactants is very laborious. The incorporation of oil-based care substances into hair cleaning agents also has a negative effect on the stability, viscosity and foam properties of the agent.

It has been found that hair cleaning agents with good foam properties and excellent care potential can be produced if at least one surfactant from the group of anionic taurate surfactants and / or isethionate surfactants and / or alpha-olefin sulfonate surfactants is selected as the anionic, sulfate-free surfactant base . At least one of these surfactants is preferably combined with cocamidopropyl betaine and / or cocoampho (di) acetate as a co-surfactant.

Suitable nonionic surfactants for use as co-surfactants are, for example

Amine oxides which can be selected from compounds of the general formulas (I) or

(II)

in which R each represents a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 6 to 24 carbon atoms, preferably 8 to 18 carbon atoms.

Particularly preferred are the surfactants of the aforementioned formula (I) or (II) known under the INCI names Cocamine Oxide, Lauramine Oxide and / or Cocamidopropylamine oxide and available commercially from various suppliers.

Fatty acid alkanolamides of the following general formula,

in which R is preferably a linear or branched, saturated or unsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms and the radicals R 'are hydrogen or the group - (CH2) nOH, in which n is the numbers 2 or 3, with the proviso that at least one of the radicals R 'stands for the aforementioned radical - (CH2) nOH,

Mixtures of alkyl (oligo) glucosides and fatty alcohols, for example the commercially available product Montanov ^® 68,

Sterols. Sterols are understood to be a group of steroids which have a hydroxyl group on the carbon atom 3 of the steroid structure and which come from animal tissue (zoosterols) as well as can also be isolated from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol,

Stigmasterol and sitosterol. Sterols, the so-called mycosterols, are also isolated from fungi and yeasts.

Phospholipids. These include, above all, the glucose phospholipids, which e.g. as lecithins or phosphidylcholines from e.g. Egg yolks or plant seeds (e.g. soybeans) are obtained,

Alkyl (oligo) glycosides. Suitable alkyl (oligo) glycosides can be selected from

Compounds of the general formula of RO- [G] _x , in which [G] is preferably derived from aldoses and / or ketoses with 5-6 carbon atoms, preferably from glucose.

The index number x stands for the degree of oligomerization (DP), i.e. for the distribution of the mono- and oligoglycosides. The index number x preferably has a value in the range from 1 to 10, particularly preferably in the range from 1 to 3, it being not a whole number but a fractional number which can be determined analytically.

Particularly preferred alkyl (oligo) glycosides have a degree of oligomerization between 1.2 and 1.5. The radical R preferably stands for at least one alkyl and / or alkenyl radical having 4 to 24 carbon atoms.

Particularly preferred alkyl (oligo) glycosides are the compounds known under the INCI names Caprylyl / Capryl Glucoside, Decyl Glucoside, Lauryl Glucoside and Coco Glucoside.

Particularly preferred nonionic surfactants which can be contained as co-surfactants in the agents according to the invention are fatty acid alkanolamides, alkyl (oligo) glucosides and amine oxides.

Fatty acid alkanolamides are particularly preferred.

The nonionic co-surfactant (s) is (are) used in the inventive

cosmetic cleaning agents (based on their total weight) preferably in an amount from 0.05 to 3.00% by weight, more preferably from 0.10 to 2.50% by weight, particularly preferably from 0.20 to 2.25 % By weight and in particular from 0.30 to 2.00% by weight are used.

A fatty acid alkanolamide is particularly preferably used in the aforementioned amounts in the agents according to the invention.

A second essential component in the cosmetic cleaning agents according to the invention is at least one naturally occurring gel former b).

In addition to the adjustment to the desired viscosity, the gel former b) ensures the

Stabilization of the particles c) in the compositions according to the invention. It was also found that the presence of gel formers b) could improve the foam quality of the agents. Naturally occurring gel formers b) suitable for the agents according to the invention can preferably be selected from:

1) galactomannans such as guar gum, tara gum, locust bean gum and / or cassia gum,

2) Biosaccharide gums such as xanthan gum, gum arabic, ghatti gum, karaya gum, tragacanth gum, carrageenan gum, linseed gum, agar agar, pectin and / or alginate,

3) starch fractions and / or derivatives of starches such as amylose, amylopectin and / or

Dextrin,

4) cellulose derivatives such as alkyl cellulose, carboxyalkyl cellulose and / or hydroxyalkyl cellulose,

5) gelatin,

6) clays and / or layered silicates.

Particularly suitable gel formers b) are due to their thixotropic properties, their stability over a large pH and temperature range and due to their excellent stability towards salts:

Galactomannans 1), in particular modified and / or unmodified guar gum.

Unmodified guar gums are, for example, sold under the trade name Jaguar ^® C from Rhone Poulenc. Modified guar gums contain C1-C6 hydroxyalkyl groups such as hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups. Such modified guar gums are known in the prior art and can be produced, for example, by reacting the guar gums with alkylene oxides. The degree of hydroxyalkylation, which corresponds to the number of alkylene oxide molecules consumed in relation to the number of free hydroxy groups in the guar gum, is preferably between 0.4 and 1.2. Such modified guar gum under the trade names Jaguar ^® HP8, Jaguar ^® HP60, Jaguar ^® HP120, Jaguar DC 293 and Jaguar ^® ^® HP105 Rhone Poulenc are commercially available.

Biosaccharide gum 2), especially xanthan gum,

Cellulose derivatives 4), such as methyl cellulose, ethyl cellulose, propyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose and hydroxymethyl cellulose,

Hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose.

In a particularly preferred embodiment, the agents according to the invention contain, as naturally occurring gel formers b), galactomannans 1), preferably guar gum, and / or biosaccharide gums 2), preferably xanthan gum.

The naturally occurring gel former (s) b) is (are) in the compositions according to the invention preferably in a weight fraction of 0.01 to 2 wt .-%, more preferably 0.025 to 1.9 wt .-%, particularly preferably 0, 05 to 1.8 wt.%, Very particularly preferably 0.1 to 1.7 wt.% And in particular 0.15 to 1.6 wt.% Of the total weight of the compositions are used. Within this embodiment, it is particularly preferred if guar gum and / or xanthan gum are used in the aforementioned amounts in the compositions according to the invention.

Further essential components in the cosmetic cleaning agents according to the invention are particles c) which ensure the improvement of various hair care parameters.

The particles c) can - depending on the purpose for which the invention

Compositions to be applied mainly - differently

be composed. They contain at least two components from at least two different groups i. to viii. :

i. possibly aftertreated, pyrogenic silica,

ii. microcrystalline cellulose and / or cellulose ethers,

iii. Polyols with 3 to 8 carbon atoms,

iv. Dyes,

v. Vitamins,

vi. Oils and / or waxes,

vii. Plant extracts in powder form,

viii. Charcoal.

Among suitable components i. the particles c) are preferably understood to mean hydrophobic, pyrogenic silicas. Preference is given to hydrophobic, pyrogenic silicas which have been modified on the surface of the silica particles with hydrophobic groups, preferably with alkyl groups. Particularly preferably, hydrophobic pyrogenic silicas suitable according to the invention contain hydrophobic groups such as (CH3) 3Si-0-, (-Si (CH3) ₂ 0-) _n , (H3C) 2Si (0) 2 and / or C7Hi8Si (0) 3 on their surface . Alkyl-modified, hydrophobic fumed silicas are commercially available, for example under the trade name Aerosil ^® R from Degussa. The commercial products of Aerosil ^® R202, Aerosil ^® R805, Aerosil ^® R812, Aerosil ^® R972, Aerosil ^® R974, Aerosil ^® R976, besides also the Cab-O-Sil ^® TS series of Cabot, particularly Cab-O-Sil are especially preferred ^® TS-530.

The use of the alkyl-modified, hydrophobic pyrogenic silicas known under the INCI name Silica Dimethyl Silylate is particularly preferred in the

agents according to the invention. These are for example available under the trade names Aerosil ^® R972, Aerosil ^® R974.

Component (s) i. can (can) in the particles c) preferably in a weight proportion of up to 50% by weight (more preferably up to 40% by weight, particularly preferably up to 30% by weight and in particular up to 20% by weight ) be present on the total weight of the particles c).

Among suitable components ii. the particles c) are preferably understood to mean microcrystalline cellulose and / or cellulose ethers. Suitable microcrystalline cellulose is preferably obtained by partial hydrolysis of celluloses under such conditions that only attack and completely dissolve the amorphous areas (approx. 30% of the total cellulose mass) of the celluloses, the crystalline areas (approx. 70% of the total cellulose mass) but leave it undamaged. Subsequent deaggregation of the microfine celluloses formed by hydrolysis yields the microcrystalline celluloses which have primary particles of approx. 5 μm in diameter and can be compacted, for example, to granules with an average particle size of 200 μm.

Suitable cellulose ethers are preferably derivatives of cellulose, in which the free

Hydroxyl groups have been partially replaced by alkoxy and / or hydroxyalkoxy radicals.

Alkoxy radicals are preferably Ci-C ₄ -alkoxy radicals, hydroxyalkoxy radicals are preferably hydroxy-C 1 -C ₄ -alkoxy radicals.

Examples of preferred particularly suitable cellulose ethers are carboxymethyl cellulose, methyl cellulose, ethyl cellulose, propyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxybutyl cellulose, methylhydroxyethyl cellulose,

Ethyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, and methyl hydroxybutyl cellulose.

In principle, it is also possible to use so-called mixed ethers (which contain two or more different substituents) which contain both hydroxyalkoxy and alkoxy groups.

Mixed ethers can be particularly preferred, in particular under the INCI name

Hydroxypropyl methylcellulose known and commercially, for example under the names Tegocel ^® or Methocel ^® from different vendors available compounds.

It can furthermore be preferred to combine microcrystalline cellulose and cellulose ethers with one another in the particles c).

Microcrystalline cellulose and / or the aforementioned cellulose ether is (are) in the particles c) preferably in a weight fraction of up to 50% by weight (more preferably up to 40% by weight, particularly preferably up to 30% by weight and in particular up to 20% by weight of the total weight of the particles c) are used.

A mixture of microcrystalline cellulose and at least one cellulose ether is particularly preferably used in the aforementioned amounts in the particles c). A mixture of microcrystalline cellulose and hydroxypropyl methyl cellulose is particularly preferred.

Among suitable components iii. the particles c) are preferably understood to be polyols having 3 to 8 carbon atoms. These preferably have three to six hydroxyl groups. Sugar alcohols such as mannitol (mannitol), isomalt, sorbitol (sorbitol), xylitol (xylitol) Threit, erythritol and / or arabitol (arabitol) are preferred, with mannitol, sorbitol, xylitol and / or erythritol being particularly preferred and mannitol being particularly preferred is.

Polyol (s) with 3 to 8 carbon atoms is (are) in the particles c) preferably in a weight proportion of up to 98% by weight (more preferably up to 95% by weight, particularly preferably up to 90% by weight and in particular up to 85% by weight) based on the total weight of the particles c). As suitable dyes iv. for the particles c) all dyes and / or pigments suitable for cosmetic purposes are suitable. The dyes and / or pigments are preferably iv. insoluble in water. Dyes iv. can be present in the particles c) preferably in a weight fraction of up to 1.0% by weight (more preferably up to 0.9% by weight, particularly preferably up to 0.8% by weight and in particular up to 0, 7% by weight) based on the total weight of the particles c) are used.

Under suitable vitamins v. for the particles c) the following vitamins are preferred,

Understand provitamins and vitamin precursors and their derivatives:

• Vitamin A: the group of substances called vitamin A includes retinol (vitamin Ai) and 3,4-didehydroretinol (vitamin A2). The ß-carotene is the provitamin of retinol. Vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters, such as palmitate and acetate, can be considered as the vitamin A component.

• Vitamin B: belong to the vitamin B group or to the vitamin B complex. a.

> Vitamin Bi (thiamine)

> Vitamin B2 (riboflavin)

> Vitamin B3. The compounds nicotinic acid and nicotinic acid amide (niacinamide) are often used under this name.

> Vitamin Bs (pantothenic acid and panthenol). In this group, preference is given to using panthenol. Usable derivatives of panthenol are in particular the esters and ethers of panthenol, pantolactone and cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic ones

Panthenol derivatives.

> Vitamin Bb (pyridoxine as well as pyridoxamine and pyridoxal).

• Vitamin C (ascorbic acid): the use in the form of the palmitic acid ester, the

Glucosides or phosphates may be preferred. Use in combination with tocopherols can also be preferred.

• Vitamin E (tocopherols, especially α-tocopherol).

• Vitamin F: the term “vitamin F” is usually understood to mean essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.

• Vitamin H: The compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] -imidazole-4-valeric acid is designated as vitamin H, for which the common name biotin has meanwhile established itself.

Vitamins, provitamins and vitamin precursors from groups A, B, E and H are particularly preferred. Nicotinic acid amide, biotin, pantolactone and / or panthenol are particularly preferred. Vitamins, provitamins and vitamin precursors mentioned above can be contained in the particles c) preferably in a weight fraction of up to 10% by weight (more preferably up to 9% by weight, particularly preferably up to 8% by weight and in particular up to 7% by weight) % By weight) based on the total weight of the particles c) are used.

Under suitable oils and / or waxes vi. the particles c) are preferably to be understood as meaning vegetable oils and / or vegetable waxes.

The vegetable oils can preferably be selected from amaranth seed oil, apricot kernel oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, canola oil, cranberry oil, safflower oil, peanut oil, pomegranate kernel oil, grapefruit seed oil, coconut seed oil, coconut oil, carob nut oil, hempseed oil, hazelnut kernel oil , Pumpkin seed oil, linseed oil, macadamia nut oil, corn oil, mallow oil, almond oil, mango seed oil, marula oil, poppy seed oil, evening primrose oil, olive oil, palm oil, palm kernel oil, peach kernel oil, rambutan oil, rapeseed oil, rice bran oil, castor oil, sacha inchi oil, sea buckthorn oil, safflower oil , Shea butter, soybean oil, sunflower oil, tea tree oil, grapeseed oil, tsubaki oil, walnut oil, wheat germ oil, meadowfoam oil and / or wild rose oil.

The vegetable waxes can preferably be selected from beeswax,

Carnauba wax, candelilla wax, flower waxes such as rose wax and / or jojoba oil.

It is also possible to use a mixture of vegetable oils and vegetable waxes in the particles c).

Previously mentioned oils and / or waxes vi. (in particular vegetable oils and / or vegetable waxes) can be used in the particles c), preferably in a weight fraction of up to 10% by weight (more preferably up to 8% by weight, particularly preferably up to 7.5% by weight and in particular up to 5% by weight) of the total weight of the particles c) can be used.

Among suitable plant extracts in powder form vii. for the particles c) are usually understood to mean extracts obtainable by extraction of the entire plant (but in individual cases also exclusively from flowers and / or leaves and / or seeds and / or other plant parts). After extraction, these are freed from the extraction agents and pulverized. Particularly suitable plant extracts in powder form vii. can, for example, from green tea, witch hazel, chamomile, marigold, pansy, paeonie, aloe vera, horse chestnut, sage, willow bark, cinnamon tree, chrysanthemum, oak bark, nettle, hops, burdock root, horsetail, hawthorn, linden blossom, sea lily , Spruce needles, sandalwood, juniper, coconut, kiwi, guava, lime, mango, apricot, wheat, melon, orange, grapefruit, avocado, rosemary, birch, beech sprouts, bamboo, mallow,

Meadowfoam, yarrow, quendel, thyme, lemon balm, restock, marshmallow (Althaea),

Mallow (Malva sylvestris), violets, black currant leaves, coltsfoot,

Five-finger herb, ginseng, ginger root and sweet potato come from. Are also beneficial

Algae extracts from green algae, brown algae, red algae or blue algae (cyanobacteria). Preferred Algae extracts come from seaweed, blue algae, from the green alga Codium tomentosum and from the brown alga Fucus vesiculosus.

Extracts from the group aloe (Aloe Barbadensis), bamboo (Bambusa Vulgaris), witch hazel (Hamamelis virginiana L), grape leaves (Vitis vinifera L), roses (Rosa gallica L), sandalwood (Pterocarpus Santalinus), rooibos (Aspalathus linearis) are particularly preferred ), Horse chestnut (Aesculus Hippocastanum L), white water lily (Nymphaea Alba), clover (especially red clover, Trifolium pratense), cinnamon (Cinnamomum zeylanicum nees) and cassis (especially made from cassis leaves, Ribes nigrum L).

However, plant powders can also be used which are derived from the above-mentioned using mechanical and / or chemical techniques. Plants are obtained. The

Plant components are mechanically crushed in an optional first step. Examples of mechanical grinding methods include cutting, pureeing and pressing. In the second essential step, the comminuted plant components can then be obtained from the plant components by means of mechanical separation methods which are based on the utilization of mechanical forces such as gravity, centrifugal force, pressure or vacuum. These include, for example, decanting, filtration,

Sedimentation, ultrafiltration and centrifugation.

In addition, plant extracts can be used, which by means of chemical separation methods, for example an extraction or a chromatographic process, from the

Plant components are obtained.

Plant extracts mentioned above in powder form vii. can in the particles c) preferably in a weight proportion of up to 10% by weight (more preferably up to 9% by weight, particularly preferably up to 8% by weight and in particular up to 7% by weight) of the total weight the particles c) are used.

Charcoal viii. can in the particles c) preferably in a weight proportion of up to 10% by weight (more preferably up to 9% by weight, particularly preferably up to 8% by weight and in particular up to 7% by weight) of the total weight the particles c) are used.

The particles c) preferably comprise a high proportion of ingredients from natural sources, particularly preferably they contain (based on their total weight)> 70% by weight and particularly preferably> 80% by weight ingredients from natural sources.

Preferred particles c) for use in the compositions according to the invention appear macroscopically round. Furthermore, they are solid and swell in water and in the compositions according to the invention without dissolving or disintegrating. As a result of the usually gentle rubbing with the fingers during the application of the compositions according to the invention, the particles c) are gently crushed and the active ingredients can be released Distribute evenly on the skin and / or hair. After rinsing out the agents with water, no undesirable residues remain on the hair and / or the skin.

For the stabilization with the naturally occurring gel formers b) and for reasons of aesthetics, it has proven to be advantageous if the particles c) have a certain diameter.

According to the invention, it has been found to be particularly advantageous if the particles c) have an average particle diameter of 0.5 μm to 2000 μm, particularly preferably from 2 μm to 1000 μm and in particular from 5 μm to 500 μm.

In the context of the present invention, the term “mean diameter” or “mean particle diameter” is to be understood as meaning the volume-mean D 50 particle diameter, which can be determined by conventional methods. The volume-average D 50 particle diameter is that point in the particle size distribution at which 50% by volume of the particles have a smaller diameter and 50% by volume of the particles have a larger diameter. The middle ones

Particle diameters can in particular be determined with the aid of dynamic light scattering, which is usually carried out on dilute suspensions containing, for example, 0.01 to 1% by weight of particles.

In a further preferred embodiment, contain the invention

Compositions Particles c) which have an average particle diameter of 0.5 μm to 2000 μm, particularly preferably from 2 μm to 1000 μm and in particular from 5 μm to 500 μm.

For reasons of the stability of the particles c) and / or for reasons of stabilizing the particles c) in the compositions according to the invention and / or more relevant for optimization

Hair care parameters, it is also advantageous if the particles c) at least three components from at least three different groups i. to v. contain.

Particles c) are preferably used in the compositions according to the invention in a weight proportion of 0.10 to 10% by weight, more preferably 0.25 to 7.50% by weight, particularly preferably 0.50 to 5.00% by weight , very particularly preferably 0.75 to 4.00% by weight and in particular 1.00 to 3.00% by weight of the total weight of the compositions. Particularly preferred are particles c) in the abovementioned amounts in the

Compositions according to the invention used which contain at least three components from at least three different groups i. to v. contain.

In a further particularly preferred embodiment are according to the invention

Cleaning agents characterized in that they contain particles c) which

1 to 30% by weight of at least one component from group i., 1 to 30% by weight of at least one component from group ii.,

40 to 98% by weight of at least one component from group iii.

0 to 1% by weight of at least one component from group iv.,

0 to 10% by weight of at least one component from group v. contain, the quantitative data being based on the total weight of the particles c).

In a further particularly preferred embodiment are according to the invention

Cleaning agents characterized in that they contain particles c) which

i. Fumed silica aftertreated with hexamethyldisilazane (INCI name:

Silica Dimethyl Silylate),

ii. microcrystalline cellulose and / or cellulose ethers such as methyl cellulose, ethyl cellulose, propyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxyethyl methyl cellulose, hydroxypropyl methyl cellulose and mixtures thereof, and iii. Contains sorbitol, mannitol, xylitol, erythritol and mixtures thereof.

Within this embodiment it is particularly preferred if the particles c)

i. compounds known under the INCI name Silica Dimethyl Silylate, ii. microcrystalline cellulose and / or hydroxypropyl methyl cellulose, and

iii. Contain mannitol.

To further increase the care properties of the cleaning agents according to the invention, it is advantageous if, in addition to the particles c), further care active ingredients are added to them. Preferred additional care substances for the purposes of the present invention can be selected from

cationic care polymers and / or

Oils and / or fatty substances.

Suitable cationic care polymers are to be understood, for example:

quaternized cellulose polymers, especially Polyquaternium-10, as they are under the

Names Celquat ^® and Polymer JR ^® are commercially available

hydrophobically modified cellulose derivatives, for example the cationic polymers sold under the trade name SoftCat ^® ,

cationic alkyl polyglycosides,

cationized honey, for example the commercial product Honeyquat ^® 50,

cationic galactomannan derivatives, in particular cationic guar and / or cassia polymers such as those sold under the trade name Jaguar ^®, N-Hance ^®, Polycare ^®, Clearhance ^®. Particularly suitable: Jaguar ^® C-162, Jaguar ^® C500, Jaguar ^® Styl 100, N-Hance 3196 ^®, N-Hance ^® HPCG 1000 and / or Polycare ^® Therapy Split polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid, especially polyquaternium-6 and polyquaternium-7. The products available commercially under the names Merquat ^® 100 (poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,

Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as, for example, vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers quaternized with diethyl sulfate. Such compounds are commercially available under the names Gafquat ^® 734 and Gafquat ^® 755,

Vinylpyrrolidone-vinylimidazolium methochloride copolymers, as offered under the names Luviquat ^® FC 370, FC 550, FC 905 and HM 552,

quaternized polyvinyl alcohol,

as well as those under the designations

Polyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 and Polyquaternium 89 known polymers.

Particularly preferred cationic care polymers are quaternized cellulose polymers, hydrophobically modified quaternized cellulose polymers, cationic guar derivatives, cationic cassia derivatives and / or cationic polymers based on acrylic acid (derivative), which are particularly preferably selected from the polymers known under the INCI names: guar, hydroxypropyltrimonium, guypropyltrimonium, hydroxypropyltrimonium, guypropyltrimonium chloride, guypropyltrimonium, guypropyltrimonium chloride Chloride, Cassia Hydroxypropyltrimonium Chloride, Polyquaternium-4, Polyquaternium-6, Polyquaternium-7, Polyquaternium-10, Polyquaternium-37, Polyquaternium-67 and / or Polyquaternium-72.

The proportion by weight of the cationic care polymer (s) in the total weight of the

according to the invention

Cleaning agent is preferably from 0.01 to 2% by weight, particularly preferably from 0.05 to 1.50% by weight and in particular from 0.10 to 1.00% by weight.

In a further preferred embodiment, contain the invention

Compositions of at least one cationic polymer in a weight proportion of 0.01 to 2.00% by weight based on the total weight of the cosmetic cleaning agent.

In the context of the present invention, suitable oil and / or fatty substances are understood to mean in particular vegetable oils which have already been described earlier in this application as potential constituents of the particles c). The invention

Compositions can instead of or in addition to a content of vegetable oils in the Particles c) contain vegetable oils in the detergent base in a weight proportion of 0.01 to 1.00% by weight.

In a further preferred embodiment, the cleaning agents according to the invention therefore contain at least one vegetable oil in a weight proportion of 0.01 to 1.00% by weight of the total weight of the cosmetic cleaning agent.

Suitable further fatty substances for the purposes of the present invention can be selected from mineral oils such as paraffin and isoparaffin oils and synthetic hydrocarbons. An example of a usable hydrocarbon is for example the commercial product available as a 1, 3-di- (2-ethylhexyl) -cyclohexane (Cetiol ^® S).

A dialkyl ether can also serve as the oil component.

Dialkyl ethers that can be used are in particular di-n-alkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n -undecyl ether, di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether and di - tert-butyl ether, di-iso-pentyl ether, di-3-ethyldecyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methylpentyl-n-octyl ether. Particularly preferably, the di-n-octyl ether is, which is commercially available under the name Cetiol ^® OE.

Fatty substances are also to be understood as meaning fatty alcohols.

The fatty alcohols used can be saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C6-C30, preferably C10-C22 and very particularly preferably C12-C22 carbon atoms. Examples of these are decanol, octanol, octenol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinol alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol and, alcohol ethers, myristyl alcohol and, linoleic alcohol, and linoleyl alcohol, linoleic alcohol, and linoleyl alcohol, linoleic alcohol, and linoleyl alcohol, linoleyl alcohol, linoleyl alcohol, linoleyl alcohol, linoleyl alcohol, arachidyl alcohol , whereby this list is intended to be exemplary and not limiting. The fatty alcohols, however, are preferably derived from natural fatty acids, and it can usually be assumed that they are obtained from the esters of the fatty acids by reduction. According to the invention, those fatty alcohol cuts which are obtained by reducing naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil,

Cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols are produced, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® such as Stenol ^® 1618 or Lanette ^® such as Lanette ^® O or Lorol ^®, for example, Lorol ^® C8, Lorol C14 ^®, Lorol C18 ^®, ^® Lorol C8-18, HD-Ocenol ^®, Crodacol ^® such as Crodacol ^® CS, Novol ^®, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb ^® 12, Isocarb ^® 16 or lsocarb ^® 24 for sale. Of course you can be used according to the invention also wool wax alcohols, as are commercially available, for example under the names of Corona ^®, White Swan ^®, Coronet ^® or Fluilan ^®. Further suitable fatty substances are, for example

Ester oils. Ester oils are to be understood as meaning the esters of C6 - C30 fatty acids with C2 - C30 fatty alcohols. The monoesters of fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linoleic acid, aroleic acid, linoleic acid. Behenic acid and erucic acid and their technical mixtures.

Examples of the fatty alcohol fractions in the ester oils are isopropyl alcohol, capro alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, elaeolachyl alcohol, linoxyl alcohol, elaeolachyl alcohol, linostearyl alcohol, elaeolachyl alcohol, linroidyl alcohol, linostearyl alcohol, oleo-aryl alcohol, 2-ethylhexyl alcohol, oleo-aryl alcohol, 2-ethylhexyl alcohol, oleo-aryl alcohol. Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. Isopropyl myristate (Rilanit ^® IPM), isononanoic acid C16-18-alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), are particularly preferred

2-ethylhexyl stearate (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, coconut fatty alcohol caprylate / caprylate (Cetiol ^® LC), n-butyl stearate, oleyl eucate (Cetiol ^® J 600), isopropyl palmitate (Rilanit ^® Oleate), ^® ), lauric acid hexyl ester (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B), myristyl myristate (Cetiol ^® MM), cetearyl isononanoate (Cetiol ^® SN),

Oleic acid decyl ester (Cetiol ^® V).

Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl celaate, and diol esters such as ethylene glycol dioleate, ethylene glycol di-isotridecanoate, propylene glycol di (2- ethylhexanoate), propylene glycol di-isostearate,

Propylene glycol di-pelargonate, butanediol di-isostearate, neopentyl glycol dicaprylate,

symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, glycerine carbonate or dicaprylyl carbonate (Cetiol ^® CC),

ethoxylated or non-ethoxylated mono-, di- and tri-fatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerine, such as Monomuls ^® 90-018 (INCI name: Glyceryl Oleate), Monomuls ^® 90-L12 (INCI- Name: Glyceryl Laurate), Cetiol ^® HE (INCI name: PEG-7 Glyceryl Cocoate) or Cutina ^® MD (INCI name: Glyceryl Stearate).

The proportion by weight of other fatty substances in the total weight of the substances according to the invention

Cleaning agent is preferably 0.01 to 3.00% by weight, particularly preferably 0.025 to 2.50% by weight and in particular 0.05 to 2.00% by weight.

In a particularly preferred embodiment, in the inventive

Cleaning agents Mixtures of at least one vegetable oil and at least one further fatty substance - preferably glyceryl ester, and in particular PEG-7 glyceryl cocoate - can be used.

For the cleaning agents according to the invention to be very well tolerated by the skin (head), it is advantageous if they have a slightly acidic pH.

It has been found that cosmetic cleaning agents according to the invention have particularly good skin tolerance and mildness in a pH range from 4.0 to 6.0.

In a further preferred embodiment, the cosmetic cleaning agents according to the invention therefore have a pH in the range from 4.0 to 6.0, more preferably from 4.2 to 5.9 and particularly preferably from 4.5-5.8.

The cosmetic cleaning agents according to the invention have an at least comparable product performance compared to conventional (silicone-based) formulations with the additional advantage that in addition to the naturally occurring gel formers b) no further stabilizing agents have to be incorporated into the cleaning agents, and that even with regular use of the agents Over-conditioning (especially no

Weighting of the hair) occurs.

In a further preferred embodiment there are cosmetic products according to the invention

Cleaning agents are therefore essentially free of silicone.

“Essentially free” is understood to mean that the cosmetic products according to the invention

Cleaning agents preferably contain less than 0.25% by weight, more preferably less than 0.10% by weight and in particular no silicones and / or other stabilizers at all, such as alkoxylated nonionic emulsifiers (based on the total weight of the cosmetic cleaning agents) .

The quantities given above apply to freely added silicone

and / or further stabilizers, such as alkoxylated nonionic emulsifiers, as well as for silicones and / or alkoxylated nonionic emulsifiers, which may be contained as by-products in commercial products.

It was found that the agents according to the invention are also suitable for use as

Anti-dandruff preparations are suitable.

The proportion by weight of anti-dandruff agents in the total weight of the agents according to the invention can preferably be 0.01 to 10% by weight, more preferably 0.025 to 7.5% by weight, particularly preferably 0.05 to 5% by weight and in particular 0.075 to 3% by weight .-%.

Suitable anti-dandruff ingredients can be selected from Piroctone Olamine, Climbazole,

Zinc pyrithione, ketoconazole, salicylic acid, sulfur, selenium sulfide, tar preparations,

Undecenoic acid derivatives, burdock root extracts, poplar extracts, nettle extracts,

Walnut shell extracts, birch extracts, willow bark extracts, rosemary extracts and / or Arnica extracts. Climbazole, zinc pyrithione and piroctone olamine are preferred. Zinc pyrithione is particularly preferred.

Further active ingredients, auxiliaries and additives that are used in the cosmetic according to the invention

Cleaning agents can preferably be included, for example:

Protein hydrolysates,

Plant extracts,

Humectants,

Perfumes,

- UV filter,

Structurants such as maleic acid,

Dimethyl isosorbide,

Cyclodextrins,

fiber structure-improving active ingredients, in particular mono-, di- and oligosaccharides such as glucose, galactose, fructose, fruit sugar and lactose,

Dyes for coloring the product,

Active ingredients such as bisabolol and / or allantoin,

Complexing agents such as EDTA, NTA, ß-alaninediacetic acid and phosphonic acids,

Ceramides. Ceramides are understood to mean N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogs of such lipids (so-called pseudo-ceramides),

Propellants such as propane-butane mixtures, N2O, dimethyl ether, CO2 and air,

Antioxidants,

Preservatives, such as sodium benzoate or salicylic acid,

Additional viscosity regulators such as salts (NaCl).

A second subject of the invention is the cosmetic use of the cosmetic cleaning agent according to the invention as a hair cleaning agent for improving various types of hair

Hair care parameters, especially for

Increase in hair volume,

Improvement of hair grip,

Reducing the weight of hair and / or

Reduction of frizz.

With regard to further preferred embodiments of the use according to the invention, what has been said about the agents according to the invention applies mutatis mutandis.

The following examples are intended to illustrate the subject matter of the present invention without, however, restricting it. Patent examples:

a) The following cleaning compositions according to the invention were prepared (the

Quantities relate to% by weight):

* anionic, amphoteric, zwitterionic and / or nonionic surfactant

Particles c) containing

1 to 30% by weight Silica Dimethyl Sililate,

1 to 30% by weight of microcrystalline cellulose and hydroxypropyl methyl cellulose, 40 to 98% by weight of mannitol,

0 to 10% by weight of dye (s),

0 to 10% by weight of vitamin (e).

** Guar Hydroxypropyltrimonium Chloride, Hydroxypropyl Guar Hydroxypropyltrimonium

Chloride, Cassia Hydroxypropyltrimonium Chloride, Polyquaternium-4, Polyquaternium-6, Polyquaternium-7, Polyquaternium-10, Polyquaternium-37, Polyquaternium-67 and / or Polyquaternium-72

b) Assessment of hair with one (I) according to the invention and one not

Hair cleaning agents (II) according to the invention were washed

* Particles c), containing 80 wt .-% mannitol, 10 wt .-% microcrystalline cellulose, 10 wt .-% silica silylate)

The shampoos I and II were assessed by experienced hairdressers in a half-page test. In each case 5.5 g of the shampoos I and II were applied to one side of the wet hair, in Usually massaged in and rinsed out in the same way with the same amounts of water. The hairdressers then assessed both the properties of the

Compositions, as well as various hair care parameters, assigning grades 1 (bad) to 6 (very good). The results are shown in the following table, with an arithmetic mean (Wilcoxon signed rank test) being formed from the individual results of the evaluations:

Claims

1. Cosmetic cleaning agent containing

b) at least one naturally occurring gelling agent, and

c) particles containing at least two components of at least two different

Groups i. to viii. contain:

i. possibly aftertreated, pyrogenic silica,

ii. microcrystalline cellulose and / or cellulose ethers,

iii. Polyols with 3 to 8 carbon atoms,

iv. Dyes,

v. Vitamins,

vi. Oils and / or waxes,

vii. Plant extracts in powder form,

viii. Charcoal.

2. Cosmetic cleaning agent according to claim 1, containing (based on the weight of the total agent)

- 2.50 to 30.00% by weight of at least one surfactant a),

- 0.01 to 2.00% by weight of at least one naturally occurring gel former b),

- 0.10 to 10.00% by weight of particles c).

3. Cosmetic cleaning agent according to one of the preceding claims, containing

(based on the weight of the entire product)

ai) 2.5 to 20% by weight of at least one anionic surfactant and / or

aii) 1.0 to 10% by weight of at least one amphoteric and / or zwitterionic

Surfactants.

4. Cosmetic cleaning agent according to one of the preceding claims, wherein the

naturally occurring gel formers b) is selected from

3) starch fractions and / or derivatives of starches such as amylose, amylopectin and / or dextrin, 4) cellulose derivatives such as alkyl cellulose, carboxyalkyl cellulose and / or hydroxyalkyl cellulose,

5) gelatin,

6) clays and / or layered silicates.

5. Cosmetic cleaning agent according to claim 4, wherein the gel former b) is selected from natural sources

a. Galactomannans, preferably from guar gum, and / or

b. Biosaccharide gums, preferably made from xanthan gum.

6. Cosmetic cleaning agent according to one of the preceding claims, wherein the particles c) have an average particle diameter in the range from 0.5 pm to 2000 pm, preferably from 2 pm to 1000 pm and in particular from 5 pm to 500 pm.

7. Cosmetic cleaning agent according to one of the preceding claims, wherein the particles c) at least three components from at least three different groups i. to v.

contain.

8. Cosmetic cleaning agent according to one of the preceding claims, wherein the particles c)

1 to 30% by weight of at least one component from group i.,

1 to 30% by weight of at least one component from group ii.,

40 to 98% by weight of at least one component from group iii.,

0 to 1% by weight of at least one component from group iv. ,

9. Cosmetic cleaning agent according to one of the preceding claims, wherein the particles c)

i. Fumed silica aftertreated with hexamethyldisilazane (INCI name:

Silica Dimethyl Silylate),

10. Cosmetic cleaning agent according to claim 9, wherein the particles c)

i. compounds known under the INCI name Silica Dimethyl Silylate, ii. microcrystalline cellulose and / or hydroxypropyl methyl cellulose, and iii. Contain mannitol.

11. Cosmetic cleaning agent according to one of the preceding claims, containing at least one cationic polymer in a weight proportion of 0.01 to 2.0% by weight based on the total weight of the cosmetic cleaning agent.

12. Cosmetic cleaning agent according to one of the preceding claims, containing at least one vegetable oil in a weight proportion of 0.01 to 1, 0 wt .-% of the total weight of the cosmetic cleaning agent.

13. Use of a cosmetic cleaning agent according to one of claims 1 to 12 as a cosmetic hair cleaning agent to improve various hair care parameters, in particular for

Increase in hair volume,

Improvement of hair grip,

Reducing the weight of hair and / or

Reduction of frizz.