EP3947322A1 - Method for preparing nitrogenous fertilizer and soil conditioner from liquid manure and/or manure - Google Patents
Method for preparing nitrogenous fertilizer and soil conditioner from liquid manure and/or manureInfo
- Publication number
- EP3947322A1 EP3947322A1 EP20782352.7A EP20782352A EP3947322A1 EP 3947322 A1 EP3947322 A1 EP 3947322A1 EP 20782352 A EP20782352 A EP 20782352A EP 3947322 A1 EP3947322 A1 EP 3947322A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquid
- manure
- charcoal
- pyrolysis
- fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/24—Sulfates of ammonium
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C3/00—Treating manure; Manuring
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
- C02F1/586—Treatment of water, waste water, or sewage by removing specified dissolved compounds by removing ammoniacal nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/10—Addition or removal of substances other than water or air to or from the material during the treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/10—Addition or removal of substances other than water or air to or from the material during the treatment
- C05F17/15—Addition or removal of substances other than water or air to or from the material during the treatment the material being gas
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/40—Fertilisers incorporated into a matrix
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/10—Treatment of sludge; Devices therefor by pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Definitions
- the object of the invention is a method for preparing nitrogenous fertilizer and soil conditioner from liquid manure and/or manure, which method com ⁇ prises the following steps:
- ammonium salt solution (ammonium nitro gen)
- biochar produced from manure by means of pyrolysis as soil conditioner and fertilizer. Charcoal retains water and prevents nutrients, particularly phosphorus and nitrogen, from being washed into wa ⁇ terways. Further, charcoal obtained from solid manure or the solid fraction of the method according to the invention contains a significant amount of phos ⁇ phorus.
- Publication US 9919976 B1 discloses a method in which soil conditioner con taining biochar is produced by means of pyrolysis from manure or by anaero ⁇ bic digestion from the solid matter fraction of processed manure.
- the nutri ⁇ ent content of biochar produced by means of pyrolysis is improved by adding thereto nutrients separated from the liquid fraction obtained from the diges ⁇ tion process.
- the separation of the solid fraction and the liquid fraction is performed only after the digestion process.
- the solid matter obtained from the digestion process is not particularly suitable for pyrolysis, as the majority of charcoal has exited with the biogases. Separating nutrients from the liquid fraction of the digestion process requires hygienization and the nitrogen ob tained is in the form of ammonia dissolved into liquid, wherein the ammonia is a volatile, smelly gas.
- the purpose of the invention is to further develop the above-mentioned known methods so that their advantages can be combined in a method with which a new type of fertilizer can be prepared from fresh manure without a digestion process, which fertilizer acts as both nitrogenous fertilizer and soil conditioner.
- This purpose is achieved according to the accompanying claim 1 in such a way that in addition to the process steps mentioned hereinbefore, ammo ⁇ nium salt solution obtained from the nitrogen recovery step is charged into the charcoal formed during the pyrolysis process, whereby nitrogenous ferti ⁇ lizer and soil conditioner is obtained as the end product.
- Manure and/or liquid manure is provided as starting material, which may also contain other fractions, such as washing water. Any manure of animal origin can be used as the manure and/or liquid manure. The manure and/or liquid manure is fed into the separation of solid matter.
- the liquid manure and/or manure is separated into a solid fraction and a liquid fraction.
- a separator, wire sieve or precipitation can be used as equip ment.
- a polymer binding to the solid matter can be added to the precipita ⁇ tion tank and the precipitate sinks to the bottom, wherefrom the solid matter can be removed with a scraper.
- Another separation method, such as a centri fuge, can be used for separating the solid matter. The aim is to essentially separate the solid and liquid fractions of the manure and/or liquid manure.
- the separated liquid fraction can be subjected to a biological pretreatment before the concentration of nitrogen.
- the pretreatment is an aerobic micro ⁇ bial treatment as described e.g. in patent publication EP 2279153 B1 by the applicant.
- the pH of the liquid fraction can be increased to a desired level to facilitate the concentration of nitrogen.
- the liquid fraction is subjected to am- monia stripping, thereby obtaining a liquid fraction with a low nitrogen con tent and a gas phase containing ammonia.
- the nitrogen is recovered into a liquid solution containing acid (a so-called receiving solution), whereby an ammonium salt solution (ammonium nitrogen) is ob tained.
- Diluted sulfuric acid (H2SO4) is primarily used as the liquid solution, in which case the ammonium salt solution is ammonium sulfate ((NH ⁇ SC ).
- the receiving solution used in the gas phase washer may also comprise an acid other than sulfuric acid or it may consist of a mixture of different acids.
- a dilute liquid fraction with a significantly lowered nitrogen con ⁇ tent is obtained from the ammonia stripping step.
- This dilute liquid fraction can be used as nitrogenous fertilizer that can be spread directly on a field or it can be transferred as such to a wastewater treatment plant.
- nitrogen and organic matter can be removed from the dilute liquid fraction using membrane technology, whereby the purified liquid fraction can be re ⁇ leased straight into nature.
- the solid fraction obtained from separating the solid matter is treated with pyrolysis, wherein charcoal, pyrolysis liquid and pyrolysis gas are formed.
- pyrolysis organic matter is decomposed in anoxic or low oxygen conditions.
- the pyrolysis process is carried out as slow pyrolysis.
- the solid fraction Before py ⁇ rolysis, the solid fraction can be pre-dried and/or heated.
- Another solid frac ⁇ tion essentially containing charcoal or solid manure that does not need to be passed through the solid matter separation step can be added to the pyroly ⁇ sis.
- the biochar formed as the pyrolysis product contains significants amount of phosphorus (P) and potassium (K) as well as other nutrients important to plants.
- the charcoal can be ground or crushed to granules of a suitable size for further use and treatment.
- the pyrolysis gas and the pyrolysis liquid can be utilized as energy or for other purposes of use.
- the ammo ⁇ nium salt solution obtained from the nitrogen recovery step is charged into the charcoal formed in the pyrolysis process, whereby nitrogenous fertilizer and soil conditioner is obtained as the end product.
- the ammonium salt solu ⁇ tion can be charged into the ground or crushed charcoal by spraying, for ex ⁇ ample.
- the ammonium salt solution is typically ammonium sulfate (NH ⁇ SCM. Other nutrients and/or trace elements can also be charged into the charcoal according to cultivation needs.
- the desired nutrient content to be charged into the charcoal is adjusted using flow measurement based on weight.
- Ground or crushed charcoal is fed as a continuous stream through a weighing apparatus and the feed volume of the ammonium salt solution is controlled based on the weight recorded.
- the ratios of the amounts of nitrogen and phosphorus are adjusted accord ⁇ ing to the cultivation plan.
- the amount of phosphorus con- tained in the charcoal is first analyzed, and the amount of nitrogen to be charged into the charcoal is adjusted accordingly.
- the amount of nitrogen and phosphorus per cultivation area has been provided for in directives and national decrees.
- the end product is an NPK fertilizer impregnated in charcoal, further acting as soil conditioner owing to its charcoal content.
- the above-described process steps may comprise heating and/or cooling processes.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Soil Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Materials Engineering (AREA)
- Environmental Sciences (AREA)
- Analytical Chemistry (AREA)
- Fertilizers (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20195277A FI128744B (en) | 2019-04-05 | 2019-04-05 | Method for preparing nitrogenous fertilizer and soil conditioner from liquid manure and/or manure |
PCT/FI2020/050219 WO2020201636A1 (en) | 2019-04-05 | 2020-04-03 | Method for preparing nitrogenous fertilizer and soil conditioner from liquid manure and/or manure |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3947322A1 true EP3947322A1 (en) | 2022-02-09 |
EP3947322A4 EP3947322A4 (en) | 2022-12-28 |
Family
ID=72666331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20782352.7A Pending EP3947322A4 (en) | 2019-04-05 | 2020-04-03 | Method for preparing nitrogenous fertilizer and soil conditioner from liquid manure and/or manure |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP3947322A4 (en) |
FI (1) | FI128744B (en) |
WO (1) | WO2020201636A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022079043A1 (en) | 2020-10-12 | 2022-04-21 | Mezt B.V. | Process to separate an aqueous feed |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0351922A1 (en) * | 1988-07-19 | 1990-01-24 | DRESE, Jan Theo | A process and an apparatus for treatment of manure, in particular liquid manure |
FI20085371A0 (en) * | 2008-04-25 | 2008-04-25 | Pellonpaja Oy | Process for the treatment and / or pretreatment of liquid manure or reject from biogasver for the elimination of pollutants, in particular nitrogen, phosphorus and odor molecules |
US8361186B1 (en) * | 2009-06-08 | 2013-01-29 | Full Circle Biochar, Inc. | Biochar |
CA2826025C (en) * | 2011-02-17 | 2019-05-21 | Anaergia Inc. | Organics and nutrient recovery from anaerobic digester residues |
US10118870B2 (en) * | 2011-06-06 | 2018-11-06 | Cool Planet Energy Systems, Inc. | Additive infused biochar |
US9919976B1 (en) * | 2016-07-05 | 2018-03-20 | Magic Dirt Horticultural Products LLC | Soil conditioners and method of making them |
CN108395331A (en) * | 2018-05-04 | 2018-08-14 | 上海首牛新能源科技有限公司 | A kind of cow dung prepares the method and system of soil conditioner |
-
2019
- 2019-04-05 FI FI20195277A patent/FI128744B/en active IP Right Grant
-
2020
- 2020-04-03 EP EP20782352.7A patent/EP3947322A4/en active Pending
- 2020-04-03 WO PCT/FI2020/050219 patent/WO2020201636A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP3947322A4 (en) | 2022-12-28 |
WO2020201636A1 (en) | 2020-10-08 |
FI128744B (en) | 2020-11-30 |
FI20195277A1 (en) | 2020-10-06 |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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A4 | Supplementary search report drawn up and despatched |
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RIC1 | Information provided on ipc code assigned before grant |
Ipc: C01C 1/24 20060101ALI20221122BHEP Ipc: C02F 9/00 20060101ALI20221122BHEP Ipc: C05G 5/40 20200101ALI20221122BHEP Ipc: C05F 17/10 20200101ALI20221122BHEP Ipc: C05G 3/80 20200101ALI20221122BHEP Ipc: C10B 53/02 20060101ALI20221122BHEP Ipc: C01C 1/02 20060101ALI20221122BHEP Ipc: A01C 3/00 20060101ALI20221122BHEP Ipc: C02F 1/20 20060101ALI20221122BHEP Ipc: C02F 1/58 20060101ALI20221122BHEP Ipc: C05C 3/00 20060101ALI20221122BHEP Ipc: C05F 3/00 20060101AFI20221122BHEP |