EP3884020A1 - Cleaning agent with clear-rinsing agent for automatic metering unit - Google Patents
Cleaning agent with clear-rinsing agent for automatic metering unitInfo
- Publication number
- EP3884020A1 EP3884020A1 EP19812716.9A EP19812716A EP3884020A1 EP 3884020 A1 EP3884020 A1 EP 3884020A1 EP 19812716 A EP19812716 A EP 19812716A EP 3884020 A1 EP3884020 A1 EP 3884020A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- acid
- detergent
- preparation
- cleaning agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 140
- 239000003795 chemical substances by application Substances 0.000 title description 14
- 238000002360 preparation method Methods 0.000 claims abstract description 223
- 102000004190 Enzymes Human genes 0.000 claims abstract description 39
- 108090000790 Enzymes Proteins 0.000 claims abstract description 39
- 239000003599 detergent Substances 0.000 claims description 150
- 239000000203 mixture Substances 0.000 claims description 69
- 238000004851 dishwashing Methods 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 57
- 230000008569 process Effects 0.000 claims description 39
- XINQFOMFQFGGCQ-UHFFFAOYSA-L (2-dodecoxy-2-oxoethyl)-[6-[(2-dodecoxy-2-oxoethyl)-dimethylazaniumyl]hexyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCOC(=O)C[N+](C)(C)CCCCCC[N+](C)(C)CC(=O)OCCCCCCCCCCCC XINQFOMFQFGGCQ-UHFFFAOYSA-L 0.000 claims description 36
- 229940088598 enzyme Drugs 0.000 claims description 31
- 239000002253 acid Substances 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 24
- 239000011521 glass Substances 0.000 claims description 23
- 150000003839 salts Chemical class 0.000 claims description 22
- 239000008139 complexing agent Substances 0.000 claims description 20
- 239000002736 nonionic surfactant Substances 0.000 claims description 19
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 16
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 16
- 108091005804 Peptidases Proteins 0.000 claims description 15
- 239000004365 Protease Substances 0.000 claims description 15
- 108010065511 Amylases Proteins 0.000 claims description 14
- 102000013142 Amylases Human genes 0.000 claims description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 14
- 235000019418 amylase Nutrition 0.000 claims description 14
- 230000007797 corrosion Effects 0.000 claims description 14
- 238000005260 corrosion Methods 0.000 claims description 14
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 claims description 13
- 229940071118 cumenesulfonate Drugs 0.000 claims description 13
- 239000003112 inhibitor Substances 0.000 claims description 13
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 12
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 10
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 10
- 239000002535 acidifier Substances 0.000 claims description 10
- 229940025131 amylases Drugs 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 102000035195 Peptidases Human genes 0.000 claims description 9
- 235000019253 formic acid Nutrition 0.000 claims description 9
- 239000003752 hydrotrope Substances 0.000 claims description 9
- 150000003751 zinc Chemical class 0.000 claims description 9
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 claims description 8
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 8
- 239000011976 maleic acid Substances 0.000 claims description 8
- 229960004063 propylene glycol Drugs 0.000 claims description 8
- 229940071104 xylenesulfonate Drugs 0.000 claims description 8
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 7
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 108090001060 Lipase Proteins 0.000 claims description 6
- 102000004882 Lipase Human genes 0.000 claims description 6
- 239000004367 Lipase Substances 0.000 claims description 6
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000001361 adipic acid Substances 0.000 claims description 6
- 235000011037 adipic acid Nutrition 0.000 claims description 6
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 6
- 238000011049 filling Methods 0.000 claims description 6
- 235000019421 lipase Nutrition 0.000 claims description 6
- 239000004246 zinc acetate Substances 0.000 claims description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 5
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000001530 fumaric acid Substances 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 239000005022 packaging material Substances 0.000 claims description 5
- 150000004760 silicates Chemical class 0.000 claims description 5
- 108010084185 Cellulases Proteins 0.000 claims description 4
- 102000005575 Cellulases Human genes 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- 229940045136 urea Drugs 0.000 claims description 4
- 229920002873 Polyethylenimine Polymers 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 3
- 108010002430 hemicellulase Proteins 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 claims description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 2
- DUFKCOQISQKSAV-UHFFFAOYSA-N Polypropylene glycol (m w 1,200-3,000) Chemical compound CC(O)COC(C)CO DUFKCOQISQKSAV-UHFFFAOYSA-N 0.000 claims description 2
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 229960001484 edetic acid Drugs 0.000 claims description 2
- 229960002989 glutamic acid Drugs 0.000 claims description 2
- 235000013922 glutamic acid Nutrition 0.000 claims description 2
- 239000004220 glutamic acid Substances 0.000 claims description 2
- 229960003330 pentetic acid Drugs 0.000 claims description 2
- DCCWEYXHEXDZQW-BYPYZUCNSA-N (2s)-2-[bis(carboxymethyl)amino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O DCCWEYXHEXDZQW-BYPYZUCNSA-N 0.000 claims 1
- JPGSFSFMINKKJZ-UHFFFAOYSA-N 2-[1,2-dicarboxyethyl(hydroxy)amino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)N(O)C(CC(O)=O)C(O)=O JPGSFSFMINKKJZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 abstract description 15
- 239000004480 active ingredient Substances 0.000 description 36
- 239000003205 fragrance Substances 0.000 description 35
- 238000004140 cleaning Methods 0.000 description 33
- 239000012876 carrier material Substances 0.000 description 31
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 26
- 229920001577 copolymer Polymers 0.000 description 26
- -1 alkali metal salts Chemical class 0.000 description 24
- 239000000178 monomer Substances 0.000 description 24
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 150000007513 acids Chemical class 0.000 description 12
- 239000013543 active substance Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 10
- 239000003086 colorant Substances 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- 239000000975 dye Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 239000004382 Amylase Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 6
- 229920003345 Elvax® Polymers 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000002191 fatty alcohols Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 235000019645 odor Nutrition 0.000 description 6
- 239000002304 perfume Substances 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 229920005646 polycarboxylate Polymers 0.000 description 6
- 235000019419 proteases Nutrition 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- 102100032487 Beta-mannosidase Human genes 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 108010055059 beta-Mannosidase Proteins 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 5
- 229940100530 zinc ricinoleate Drugs 0.000 description 5
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 description 4
- VXWBQOJISHAKKM-UHFFFAOYSA-N (4-formylphenyl)boronic acid Chemical compound OB(O)C1=CC=C(C=O)C=C1 VXWBQOJISHAKKM-UHFFFAOYSA-N 0.000 description 4
- 229920000858 Cyclodextrin Polymers 0.000 description 4
- 108090000854 Oxidoreductases Proteins 0.000 description 4
- 102000004316 Oxidoreductases Human genes 0.000 description 4
- 108010056079 Subtilisins Proteins 0.000 description 4
- 102000005158 Subtilisins Human genes 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 229940097362 cyclodextrins Drugs 0.000 description 4
- 229940079919 digestives enzyme preparation Drugs 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 235000018102 proteins Nutrition 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- 108010005400 cutinase Proteins 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000002552 dosage form Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000009969 flowable effect Effects 0.000 description 3
- 239000010794 food waste Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 229910052739 hydrogen Chemical group 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 3
- 229910000165 zinc phosphate Inorganic materials 0.000 description 3
- MTDAKBBUYMYKAR-SNVBAGLBSA-N (3r)-3,7-dimethyloct-6-enenitrile Chemical compound N#CC[C@H](C)CCC=C(C)C MTDAKBBUYMYKAR-SNVBAGLBSA-N 0.000 description 2
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- IAUGBVWVWDTCJV-UHFFFAOYSA-N 1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical class CCC(S(O)(=O)=O)NC(=O)C=C IAUGBVWVWDTCJV-UHFFFAOYSA-N 0.000 description 2
- JMSUNAQVHOHLMX-UHFFFAOYSA-N 1-cyclohexylethanol Chemical compound CC(O)C1CCCCC1 JMSUNAQVHOHLMX-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- CTMHWPIWNRWQEG-UHFFFAOYSA-N 1-methylcyclohexene Chemical compound CC1=CCCCC1 CTMHWPIWNRWQEG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- YXVSKJDFNJFXAJ-UHFFFAOYSA-N 4-cyclohexyl-2-methylbutan-2-ol Chemical compound CC(C)(O)CCC1=CC=CC=C1 YXVSKJDFNJFXAJ-UHFFFAOYSA-N 0.000 description 2
- PYFSVNDANBWHDY-UHFFFAOYSA-N 5-cyclohexyl-2-(5-methyl-2-propan-2-ylcyclohexyl)pentan-1-ol Chemical compound C1(CC(C(CC1)C(C)C)C(CO)CCCC1CCCCC1)C PYFSVNDANBWHDY-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 108010059892 Cellulase Proteins 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 108010025880 Cyclomaltodextrin glucanotransferase Proteins 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 241000223258 Thermomyces lanuginosus Species 0.000 description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 239000004599 antimicrobial Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- SFOQXWSZZPWNCL-UHFFFAOYSA-K bismuth;phosphate Chemical compound [Bi+3].[O-]P([O-])([O-])=O SFOQXWSZZPWNCL-UHFFFAOYSA-K 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 229940106157 cellulase Drugs 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 2
- 229930008394 dihydromyrcenol Natural products 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- VXLYKKNIXGIKAE-UHFFFAOYSA-N prop-2-enoyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(=O)C=C VXLYKKNIXGIKAE-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000006277 sulfonation reaction Methods 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- VQJMAIZOEPPELO-KYGIZGOZSA-N (1S,2S,6R,14R,15R,16R)-5-(cyclopropylmethyl)-16-(2-hydroxy-5-methylhexan-2-yl)-15-methoxy-13-oxa-5-azahexacyclo[13.2.2.12,8.01,6.02,14.012,20]icosa-8(20),9,11-trien-11-ol hydrochloride Chemical compound Cl.CO[C@]12CC[C@@]3(C[C@@H]1C(C)(O)CCC(C)C)[C@H]1Cc4ccc(O)c5O[C@@H]2[C@]3(CCN1CC1CC1)c45 VQJMAIZOEPPELO-KYGIZGOZSA-N 0.000 description 1
- SVZNRBAZGGBJOW-UHFFFAOYSA-N (2-methylprop-2-enoylamino)methanesulfonic acid Chemical compound CC(=C)C(=O)NCS(O)(=O)=O SVZNRBAZGGBJOW-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- NPMRPDRLIHYOBW-UHFFFAOYSA-N 1-(2-butoxyethoxy)propan-2-ol Chemical compound CCCCOCCOCC(C)O NPMRPDRLIHYOBW-UHFFFAOYSA-N 0.000 description 1
- UWGPEJUKUUDXRC-UHFFFAOYSA-N 1-(2-methylprop-2-enoylamino)butane-2-sulfonic acid Chemical class CCC(S(O)(=O)=O)CNC(=O)C(C)=C UWGPEJUKUUDXRC-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- BXMNDXHSERZBRZ-UHFFFAOYSA-N 1-benzyl-4-but-1-enylbenzene Chemical compound C(C)C=CC1=CC=C(C=C1)CC1=CC=CC=C1 BXMNDXHSERZBRZ-UHFFFAOYSA-N 0.000 description 1
- VDNSZPNSUQRUMS-UHFFFAOYSA-N 1-cyclohexyl-4-ethenylbenzene Chemical compound C1=CC(C=C)=CC=C1C1CCCCC1 VDNSZPNSUQRUMS-UHFFFAOYSA-N 0.000 description 1
- WJNKJKGZKFOLOJ-UHFFFAOYSA-N 1-dodecyl-4-ethenylbenzene Chemical compound CCCCCCCCCCCCC1=CC=C(C=C)C=C1 WJNKJKGZKFOLOJ-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- ATQUFXWBVZUTKO-UHFFFAOYSA-N 1-methylcyclopentene Chemical compound CC1=CCCC1 ATQUFXWBVZUTKO-UHFFFAOYSA-N 0.000 description 1
- GQCZPFJGIXHZMB-UHFFFAOYSA-N 1-tert-Butoxy-2-propanol Chemical compound CC(O)COC(C)(C)C GQCZPFJGIXHZMB-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical compound CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
- PKVDGQHNRICJLA-UHFFFAOYSA-N 2,4-dimethylhex-1-ene Chemical compound CCC(C)CC(C)=C PKVDGQHNRICJLA-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical group COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- AIIITCMZOKMJIM-UHFFFAOYSA-N 2-(prop-2-enoylamino)propane-2-sulfonic acid Chemical compound OS(=O)(=O)C(C)(C)NC(=O)C=C AIIITCMZOKMJIM-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- XMWLVXXYIYBETQ-UHFFFAOYSA-N 2-hydroxy-3-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)NCC(O)CS(O)(=O)=O XMWLVXXYIYBETQ-UHFFFAOYSA-N 0.000 description 1
- KOQQKLZTINXBAS-UHFFFAOYSA-N 2-hydroxy-3-prop-2-enoxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(O)COCC=C KOQQKLZTINXBAS-UHFFFAOYSA-N 0.000 description 1
- VSSGDAWBDKMCMI-UHFFFAOYSA-N 2-methyl-2-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)NC(C)(C)CS(O)(=O)=O VSSGDAWBDKMCMI-UHFFFAOYSA-N 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- ONPJWQSDZCGSQM-UHFFFAOYSA-N 2-phenylprop-2-enoic acid Chemical compound OC(=O)C(=C)C1=CC=CC=C1 ONPJWQSDZCGSQM-UHFFFAOYSA-N 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- KXYAVSFOJVUIHT-UHFFFAOYSA-N 2-vinylnaphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC=C21 KXYAVSFOJVUIHT-UHFFFAOYSA-N 0.000 description 1
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 1
- ZRKSKKQONQUFMR-UHFFFAOYSA-N 3-amino-2-methyl-3-oxoprop-1-ene-1-sulfonic acid Chemical compound NC(=O)C(C)=CS(O)(=O)=O ZRKSKKQONQUFMR-UHFFFAOYSA-N 0.000 description 1
- BTTCOCQDAWAAJR-UHFFFAOYSA-N 3-ethylcyclohexyne Chemical compound CCC1CCCC#C1 BTTCOCQDAWAAJR-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 description 1
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 240000006439 Aspergillus oryzae Species 0.000 description 1
- 241000193744 Bacillus amyloliquefaciens Species 0.000 description 1
- 241000193422 Bacillus lentus Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 241000194110 Bacillus sp. (in: Bacteria) Species 0.000 description 1
- 108091005658 Basic proteases Proteins 0.000 description 1
- 108700038091 Beta-glucanases Proteins 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 108010073997 Bromide peroxidase Proteins 0.000 description 1
- 240000007436 Cananga odorata Species 0.000 description 1
- 108010053835 Catalase Proteins 0.000 description 1
- 102000016938 Catalase Human genes 0.000 description 1
- 108010031396 Catechol oxidase Proteins 0.000 description 1
- 102000030523 Catechol oxidase Human genes 0.000 description 1
- 108010035722 Chloride peroxidase Proteins 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 102000016680 Dioxygenases Human genes 0.000 description 1
- 108010028143 Dioxygenases Proteins 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 1
- 108010067770 Endopeptidase K Proteins 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000427940 Fusarium solani Species 0.000 description 1
- 102220644676 Galectin-related protein_D96L_mutation Human genes 0.000 description 1
- 241000193385 Geobacillus stearothermophilus Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241001480714 Humicola insolens Species 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- 108010029541 Laccase Proteins 0.000 description 1
- 108010054320 Lignin peroxidase Proteins 0.000 description 1
- 108010059896 Manganese peroxidase Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- 108090000417 Oxygenases Proteins 0.000 description 1
- 102000004020 Oxygenases Human genes 0.000 description 1
- 108010029182 Pectin lyase Proteins 0.000 description 1
- 108700020962 Peroxidase Proteins 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- 240000008299 Pinus lambertiana Species 0.000 description 1
- 240000002505 Pogostemon cablin Species 0.000 description 1
- 235000011751 Pogostemon cablin Nutrition 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 108010059820 Polygalacturonase Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241000589755 Pseudomonas mendocina Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 241001292348 Salipaludibacillus agaradhaerens Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- 108090000787 Subtilisin Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 102000003425 Tyrosinase Human genes 0.000 description 1
- 108060008724 Tyrosinase Proteins 0.000 description 1
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 description 1
- CANRESZKMUPMAE-UHFFFAOYSA-L Zinc lactate Chemical compound [Zn+2].CC(O)C([O-])=O.CC(O)C([O-])=O CANRESZKMUPMAE-UHFFFAOYSA-L 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229940095602 acidifiers Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 108090000637 alpha-Amylases Proteins 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical class [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000005620 boronic acid group Chemical class 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- AIXMJTYHQHQJLU-UHFFFAOYSA-N chembl210858 Chemical compound O1C(CC(=O)OC)CC(C=2C=CC(O)=CC=2)=N1 AIXMJTYHQHQJLU-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- KHAYCTOSKLIHEP-UHFFFAOYSA-N docosyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)C=C KHAYCTOSKLIHEP-UHFFFAOYSA-N 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 108010093305 exopolygalacturonase Proteins 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 108010046301 glucose peroxidase Proteins 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- BRMYZIKAHFEUFJ-UHFFFAOYSA-L mercury diacetate Chemical compound CC(=O)O[Hg]OC(C)=O BRMYZIKAHFEUFJ-UHFFFAOYSA-L 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 108020004410 pectinesterase Proteins 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical class OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 1
- 108010031354 thermitase Proteins 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 108010068608 xanthan lyase Proteins 0.000 description 1
- 108010083879 xyloglucan endo(1-4)-beta-D-glucanase Proteins 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- SRWMQSFFRFWREA-UHFFFAOYSA-M zinc formate Chemical compound [Zn+2].[O-]C=O SRWMQSFFRFWREA-UHFFFAOYSA-M 0.000 description 1
- 239000011670 zinc gluconate Substances 0.000 description 1
- 235000011478 zinc gluconate Nutrition 0.000 description 1
- 229960000306 zinc gluconate Drugs 0.000 description 1
- 239000011576 zinc lactate Substances 0.000 description 1
- 229940050168 zinc lactate Drugs 0.000 description 1
- 235000000193 zinc lactate Nutrition 0.000 description 1
- 229940006174 zinc valerate Drugs 0.000 description 1
- MXODCLTZTIFYDV-JHZYRPMRSA-L zinc;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Zn+2].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O.C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O MXODCLTZTIFYDV-JHZYRPMRSA-L 0.000 description 1
- YISPIDBWTUCKKH-UHFFFAOYSA-L zinc;4-methylbenzenesulfonate Chemical compound [Zn+2].CC1=CC=C(S([O-])(=O)=O)C=C1.CC1=CC=C(S([O-])(=O)=O)C=C1 YISPIDBWTUCKKH-UHFFFAOYSA-L 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- NHXVNEDMKGDNPR-UHFFFAOYSA-N zinc;pentane-2,4-dione Chemical compound [Zn+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O NHXVNEDMKGDNPR-UHFFFAOYSA-N 0.000 description 1
- BUDAIZWUWHWZPQ-UHFFFAOYSA-L zinc;pentanoate Chemical compound [Zn+2].CCCCC([O-])=O.CCCCC([O-])=O BUDAIZWUWHWZPQ-UHFFFAOYSA-L 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C11D2111/18—
Definitions
- the invention relates to a cleaning agent which contains, separately from one another, at least one enzyme-containing and at least one builder-containing preparation in a packaging means, as well as a rinse aid preparation.
- devices for multiple dosing of cleaning agents are from
- Devices can be differentiated between metering containers integrated in the dishwasher on the one hand and independent devices independent of the dishwasher on the other. By means of these devices, the multiple of those necessary for carrying out a cleaning process
- Containing amount of detergent, detergent portions are metered into the interior of the cleaning machine in an automatic or semi-automatic manner in the course of several successive cleaning processes. For the consumer, this eliminates the need to dose the detergent before the start of each individual cleaning cycle. Examples of such devices are described in European patent application EP 1 759 624 A2 (Reckitt Benckiser) or in German patent application DE 10 2005 062 479 A1 (BSH Bosch and Siemens Hausmaschine GmbH).
- temperatures are the first approximation of the water temperatures used to carry out the cleaning processes. These temperatures can be up to 95 ° C, with usually only temperatures between 50 and 75 ° C being achieved in the area of machine dishwashing.
- a cleaning agent contained in a device provided for multiple dosing is accordingly repeatedly heated in the course of several cleaning processes to temperatures significantly above the temperatures customary for transport and storage, in particular temperature-sensitive ones
- Dishwasher remains before a rinse cycle is carried out, have the problem that the cleaning performance of the products, especially for stubborn ones, in particular
- the object of the present application was therefore to provide a
- a first subject of the present application is therefore a cleaning agent supply form, comprising
- Detergent preparation B with a water content above 1% by weight, containing b1) at least 5% by weight of at least one cleaning-active enzyme preparation c) a liquid (20 ° C.) detergent preparation C,
- c5) optionally less than 1% by weight, preferably less than 0.5% by weight, in particular less than 0.1% by weight of enzyme preparation, and
- Renewal or the replacement of the active ingredient composition and the detergent preparations does not have to worry a lot. He exchanges the combination together and does not have to worry about replacing individual products separately. In particular, he needs do not worry about an additional dosage of rinse aid in the rinse aid chamber of the dishwasher.
- the subject of this application are corresponding forms of detergent which are obtained by the combination of three liquid detergent preparations A, B and C.
- the liquid cleaning agent preparations A, B and C differ in their composition from one another.
- Detergent preparations are phosphate-free, i.e. that they contain less than 1% by weight of phosphate, preferably less than 0.5% by weight of phosphate, particularly preferably less than 0.1% by weight of phosphate and in particular no phosphate.
- the cleaning agent preparation A contains one or more builders as the first essential component.
- the builders include in particular carbonates, organic cobuilders and silicates.
- Forms of cleaning agent according to the invention are preferably characterized in that the builder a1) is selected from the group of carbonates, bicarbonates, citrates, silicates, polymeric carboxylates and polymers containing sulfonic acid groups or mixtures thereof.
- Preferred forms of detergent supply comprise a detergent preparation A which, based on its total weight, 2 to 50% by weight, preferably 6 to 45% by weight and
- builders a1) from the group of the carbonates and / or hydrogen carbonates, preferably alkali carbonates, is particularly preferred
- Sodium carbonate in amounts of 2 to 30% by weight, preferably 3 to 20% by weight and in particular 4 to 15% by weight, in each case based on the weight of the
- Organic cobuilders include, in particular, polycarboxylates / polycarboxylic acids, polymeric carboxylates, (poly) aspartic acid, polyacetals, dextrins and organic cobuilders. These classes of substances are described below.
- Usable organic builders are, for example, the polycarboxylic acids which can be used in the form of the free acid and / or their sodium salts, polycarboxylic acids being understood to mean those carboxylic acids which carry more than one acid function. For example, these are citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid,
- Polycarboxylic acids are preferably understood to mean non-polymeric polycarboxylates. Such polymeric polycarboxylates have a larger number, preferably 4 and more carboxylic acid-containing monomers. In addition to their builder action, the free acids typically also have the property of an acidifying component and thus also serve to establish a lower and milder pH of
- Citric acid Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any mixtures thereof can be mentioned in particular.
- Particularly preferred cleaning agent preparations A according to the invention contain citrate as one of their essential builders.
- Forms of detergent characterized in that the detergent preparation A, based on their total weight, contains 2 to 40% by weight, preferably 5 to 30% by weight and in particular 7 to 20% by weight of citrate, are preferred according to the invention.
- Citrate or citric acid have in particular in combination with phosphonate, in particular 1-hydroxyethane-1, 1-diphosphonic acid, and / or
- Polymers containing sulfonic acid groups have proven to be the most effective builders in terms of cleaning performance, such as rinse aid performance and in particular scale inhibition.
- Polymeric polycarboxylates are also suitable as builders, for example the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example those with a relative molecular weight of 500 to 70,000 g / mol.
- Suitable polymers are, in particular, polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Because of their superior solubility, the short-chain polyacrylates with molecular weights from 2000 to 10000 g / mol, and particularly preferably from 3000 to 5000 g / mol, can in turn be preferred from this group.
- Copolymers of polycarboxylates are also suitable, in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid.
- Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable.
- Their relative molecular weight, based on free acids, is generally 2,000 to 70,000 g / mol, preferably 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.
- the amount of (co) polymeric polycarboxylates in the dishwasher detergents is preferably 0.5 to 20% by weight and in particular 3 to 10% by weight.
- Automatic dishwashing agents can use crystalline layered silicates of the general formula NaMSix0 2x + i y H2O, where M represents sodium or hydrogen, x is a number from 1.9 to 22, preferably from 1.9 to 4, with particularly preferred values for x 2, 3 or 4, and y represents a number from 0 to 33, preferably from 0 to 20.
- Amorphous sodium silicates with a module Na2Ü: S1O2 from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which are preferred, can also be used
- the silicate content based on the total weight of the automatic dishwashing agent, is limited to amounts below 10% by weight, preferably below 5% by weight and in particular below 2% by weight.
- Particularly preferred automatic dishwashing agents according to the invention are silicate-free.
- dishwashing detergents are characterized in that the dishwashing detergent contains at least two builders from the group of the carbonates and citrates, and the polymers containing sulfonic acid groups, the proportion by weight of these
- Builders based on its total weight of the automatic dishwashing detergent, is preferably 2 to 50% by weight, preferably 5 to 45% by weight and in particular 10 to 40% by weight.
- the combination of two or more builders from the group mentioned above has proven to be advantageous for the cleaning and rinsing performance of automatic dishwashing agents according to the invention.
- a sulfopolymer preferably a copolymeric polysulfonate, preferably a hydrophobically modified copolymeric polysulfonate, is preferably used as the sulfone group-containing polymer.
- the copolymers can have two, three, four or more different monomer units.
- Preferred copolymers polysulfonates contain, in addition to monomer (s) containing sulfonic acid groups, at least one monomer from the group of unsaturated carboxylic acids.
- unsaturated carboxylic acids are acrylic acid, methacrylic acid, ethacrylic acid, a-chloroacrylic acid, a-cyanoacrylic acid, crotonic acid, a-phenyl-acrylic acid, maleic acid,
- H 2 C CH-X-S0 3 H
- H 2 C C (CH3) -X-S0 3 H or H0 3
- SX- (R 6 ) C C (R 7 ) -X-S0 3 H
- a cleaning agent preparation preferably contains
- Detergent preparation A such a polymer comprising, as a monomer containing sulfonic acid groups, acrylamidopropane sulfonic acids, methacrylamidomethyl propane sulfonic acids or acrylamidomethyl propane sulfonic acid.
- Particularly preferred monomers containing sulfonic acid groups are 1-acrylamido-1-propanesulfonic acid, 2-acrylamido-2-propanesulfonic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, 2-methacrylamido-2-methyl-1-propanesulfonic acid, 3- Methacrylamido-2-hydroxy-propanesulfonic acid, allylsulfonic acid, methallylsulfonic acid, allyloxybenzenesulfonic acid, Methallyloxybenzenesulfonic acid, 2-hydroxy-3- (2-propenyloxy) propanesulfonic acid, 2-methyl-2-propenl-sulfonic acid, styrenesulfonic acid, vinylsulfonic acid, 3-sulfopropyl acrylate, 3-sulfopropyl methacrylate, sulfomethacrylamide, sulfomethyl methacrylamide and mixtures of the acids mentioned or their water-
- All or part of the sulfonic acid groups are present in neutralized form, which means that the acidic hydrogen atom of the sulfonic acid group in some or all of the sulfonic acid groups can be replaced by metal ions, preferably alkali metal ions and in particular by sodium ions.
- metal ions preferably alkali metal ions and in particular by sodium ions.
- the use of partially or fully neutralized copolymers containing sulfonic acid groups is preferred according to the invention.
- the monomer distribution of the copolymers preferably used according to the invention is preferably 5 to 95% by weight in each case in copolymers which only contain monomers containing carboxylic acid groups and monomers containing sulfonic acid groups, particularly preferably the proportion of the monomer containing sulfonic acid groups is 50 to 90% by weight % and the share of
- Monomers containing carboxylic acid groups from 10 to 50% by weight the monomers here being preferably selected from the abovementioned.
- the molar mass of the sulfo copolymers preferably used according to the invention can be varied in order to adapt the properties of the polymers to the desired intended use.
- Preferred cleaning agents are characterized in that the copolymers have molar masses from 2000 to 200,000 g mol -1 , preferably from 4000 to 25,000 g mol -1 and in particular from 5000 to 15,000 g mol -1 .
- the copolymers also comprise
- Monomer containing carboxyl groups and monomer containing sulfonic acid groups furthermore at least one nonionic, preferably hydrophobic monomer.
- the detergent preparations particularly preferably comprise, in particular
- Detergent preparation A comprising a copolymer
- Preferred nonionic monomers are monomers of the general formula
- nonionic monomers are butene, isobutene, pentene, 3-methylbutene, 2-methylbutene, cyclopentene, hexene, hexene-1, 2-methylpentene-1, 3-methylpentene-1, cyclohexene, methylcyclopentene, cycloheptene, methylcyclohexene, 2,4 , 4-trimethylpentene-1, 2,4,4-trimethylpentene-2,2,3-dimethylhexene-1, 2,4-dimethylhexene-1, 2,5-dimethylhexene-1, 3,5-dimethylhexene-1 , 4,4-dimethylhexane-1, ethylcyclohexyne, 1-octene, ⁇ -olefins with 10 or more
- Carbon atoms such as 1-decene, 1-dodecene, 1-hexadecene, 1-octadecene and C22-a-olefin, 2-styrene, a-methylstyrene, 3-methylstyrene, 4-propylstryol, 4-cyclohexylstyrene, 4-dodecylstyrene, 2 Ethyl 4-benzylstyrene, 1-vinylnaphthalene, 2-vinylnaphthalene, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, pentyl acrylate,
- AMPS 2-acrylamido-2-methylpropanesulfonic acid
- the detergent preparation A contains a second essential component
- the weight fraction of the complexing agent in the total weight of the cleaning agent preparation A is preferably 2 to 60% by weight, preferably 3 to 55% by weight, preferably 4 to 55% by weight and in particular 8 to 50% by weight.
- the phosphonates form a first group of preferred complexing agents.
- the complex-forming phosphonates comprise a number
- DTPMP diethylenetriaminepenta- (methylenephosphonic acid)
- hydroxyalkane or aminoalkanephosphonates are of particular importance as a cobuilder. It is preferably used as the sodium salt, the disodium salt being neutral and the
- Tetrasodium salt reacts alkaline (pH 9).
- Preferred aminoalkane phosphonates are ethylenediaminetetramethylenephosphonate (EDTMP), diethylenetriaminepentamethylenephosphonate (DTPMP) and their higher homologues. They are preferably in the form of the neutral sodium salts, e.g. B. as the hexasodium salt of EDTMP or as the hepta and octa sodium salt of DTPMP.
- the class becomes the class becomes the
- Phosphonates preferably used HEDP.
- the aminoalkanephosphonates also have a pronounced heavy metal binding capacity. Accordingly, it may be preferred, particularly if the agents also contain bleach, to use aminoalkanephosphonates, in particular DTPMP, or to use mixtures of the phosphonates mentioned.
- a cleaning agent preparation A preferred in the context of this application contains one or more phosphonate (s) from the group
- ATMP aminotrimethylenephosphonic acid
- ETMP ethylenediaminetetra (methylenephosphonic acid)
- DTPMP Diethylenetriaminepenta (methylenephosphonic acid)
- HDTMP hexamethylenediaminetetra (methylenephosphonic acid)
- NTMP Nitrilotri (methylenephosphonic acid)
- Detergent preparations A which contain 1-hydroxyethane-1,1-diphosphonic acid (HEDP) or diethylenetriaminepenta (methylenephosphonic acid) (DTPMP) as phosphonates are particularly preferred.
- HEDP 1-hydroxyethane-1,1-diphosphonic acid
- DTPMP diethylenetriaminepenta
- phosphonates are particularly preferred.
- the automatic dishwashing agents according to the invention can of course contain two or more different phosphonates.
- the total weight of cleaning agent preparations A according to the invention is preferably 1 to 8% by weight, preferably 1.2 to 6% by weight, preferably 1.3 to 5% by weight; particularly preferably 1.4 to 4.5% by weight and in particular 1.5 to 4% by weight.
- the complexing agent a2) is selected from the group of hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, glutamic acid diacetic acid, especially L-glutamic acid - / ⁇ /, / ⁇ / - diesiacetic acid, iminodisuccinic acid, hydroxynacetic acid, pa rag i nsä u red iessig acid, hydroxyethane-1, 1-diphosphonic acid or diethylenetriaminepenta (methylenephosphonic acid) and their salts or mixtures thereof, preferably L-glutamic acid - / ⁇ /, / ⁇ / - diesiacetic acid and / or
- Methylglycinediacetic acid and its salts include not only the free acids but also their salts, for example their sodium or potassium salts.
- the cleaning agent preparations A according to the invention can in particular L-glutamic acid - / ⁇ /, / ⁇ / - diacetic acid and / or the corresponding alkali salt (GLDA), preferably the tetrasodium salt, and / or methylglycinediacetic acid and / or the corresponding alkali salt, preferably that Trisodium salt.
- GLDA alkali salt
- Trisodium salt preferably the trisodium salt of methylglycinediacetic acid (MGDA) or the corresponding
- preferred detergent preparations A being characterized in that they are based on the total weight of the
- Detergent preparations A 3.0 to 35 wt .-%, preferably 4.0 to 30 wt .-% and in particular 8.0 to 25 wt .-% methylglycinediacetic acid.
- the cleaning agent preparation A contains the complexing agents selected from phosphonates, in particular HEDP, provided that
- the builders then include citrate and carbonate and / or hydrogen carbonate.
- the detergent preparation A based on its total weight, contains MGDA and / or its salts in amounts of 5 to 30% by weight, in particular 8 to 25% by weight, for example 10 to 15% by weight .-%, citrate in amounts of 3 to 20% by weight, in particular 4 to 15% by weight, and carbonate in amounts of 5 to 30% by weight, in particular 7 to 20% by weight.
- citrate amounts of 3 to 20% by weight, in particular 4 to 15% by weight, and carbonate in amounts of 5 to 30% by weight, in particular 7 to 20% by weight, are also preferred, provided this is for regulatory reasons is permissible to contain phosphonate and / or its salt in amounts of 1.2 to 6% by weight, particularly preferably 1.4 to 4.5% by weight, in particular 1.5 to 4% by weight.
- one of the cleaning agent preparation preferably cleaning agent preparation B, furthermore contains at least one surfactant, in particular selected from anionic, nonionic, zwitterionic and amphoteric surfactants.
- the surfactants can also be contained in a cleaning agent preparation different from the cleaning agent preparations A and B. If used in a cleaning agent preparation B according to the invention, surfactants are preferably used in an amount of up to 40% by weight, in particular 2 to 40% by weight or 4 to 40% by weight, particularly preferably in an amount of 5 to 35% by weight .-%, in particular 10 to 30 wt .-%, contain.
- Detergent preparation A preferably contains less than 2% by weight of surfactant, preferably less than 1% by weight of surfactant, particularly preferably less than 1% by weight of surfactant, in particular no surfactant, in each case based on the total weight of detergent preparation A.
- the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical is linear or preferably in 2- Position may be methyl branched or may contain linear and methyl branched radicals in the mixture, as are usually present in oxo alcohol radicals.
- alcohol ethoxylates with linear residues from alcohols of native origin with 12 to 18 carbon atoms, for example from coconut, palm, tallow fat or oleyl alcohol, and an average of 2 to 8 EO per mole of alcohol are particularly preferred.
- the preferred ethoxylated alcohols include, for example, C12-14 alcohols with 3 EO, 4 EO or 7 EO, Cg-n alcohol with 7 EO, Cs alcohols with 3 EO, 5 EO, 7 EO or 8 EO, Ci2 -i8-alcohols with 3 EO, 5 EO or 7 EO and mixtures thereof, such as mixtures of Ci 2 -i 4 -alcohol with 3 EO and Ci2-is-alcohol with 7 EO.
- the degrees of ethoxylation given represent statistical averages, which can be an integer or a fraction for a specific product.
- Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
- fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO,
- Nonionic surfactants which contain EO and PO groups together in the molecule can also be used according to the invention.
- block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
- mixed alkoxylated nonionic surfactants can also be used, in which the EO and PO units are not distributed in blocks, but are statistically distributed. Such products can be obtained from the simultaneous action of ethylene and propylene oxide on fatty alcohols.
- the content of nonionic surfactants in the cleaning preparation B is 5 to 30% by weight, preferably 7 to 20% by weight and in particular 9 to 15% by weight, based on the total amount of the cleaning preparation B.
- the cleaning preparation B can also contain anionic surfactants.
- Anionic surfactants used are, for example, those of the sulfonate and sulfate type.
- the surfactants of the sulfonate type are preferably C9-i3-alkylbenzenesulfonates, olefin sulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates such as are obtained, for example, from Ci2-is monoolefins with an end or internal double bond by sulfonation Gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation products.
- alkanesulfonates which are obtained from Ci2-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
- the esters of a-sulfofatty acids (ester sulfonates), for example the a-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids, are also suitable.
- the anionic surfactants including the soaps can be in the form their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
- the anionic surfactants are preferably in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
- the anionic surfactant content of the cleaning preparation B is 0.1 to 30% by weight, preferably 2 to 20% by weight, based on the
- a preferred pH value of cleaning preparations A according to the invention is between 9 and 14, in particular 9 and 12.
- the pH can be adjusted if necessary
- pH adjusting agents in particular sodium or potassium hydroxide, are carried out.
- the cleaning agent preparations B according to the invention contain at least one cleaning-active enzyme as their first essential constituent.
- the weight fraction of the cleaning-active enzyme preparation in the total weight of the cleaning agent preparation B is preferably 5 and 80% by weight, preferably 5 and 60% by weight, particularly preferably 10 and 50% by weight and in particular 10 and 30% by weight.
- the enzyme preparations used in this way each contain from 0.1 to 40% by weight, preferably from 0.2 to 30% by weight and particularly preferably from 0.4 to 20% by weight and in particular from 0.8 up to 10% by weight of active enzyme protein.
- the enzymes used with particular preference include proteases, amylases, lipases, hemicellulases, cellulases, perhydrolases or oxidoreductases, and preferably their mixtures. In principle, these enzymes are of natural origin; Based on the natural molecules, improved variants are available for use in cleaning agents, which are accordingly preferred.
- Detergents preferably contain enzymes in total amounts of 1 x 10 6 to 5 wt .-% based on active protein. The protein concentration can be determined using known methods, for example the BCA method or the biuret method.
- Detergent preparations B characterized in that they contain at least one cleaning-active enzyme from the group of amylases and / or proteases and / or cellulases and / or mannanases, in particular from the group of amylases and / or proteases.
- subtilisin type those of the subtilisin type are preferred.
- subtilisins BPN 'and Carlsberg and their further developed forms the protease PB92, the subtilisins 147 and 309, the alkaline protease from Bacillus lentus, Subtilisin DY and the enzymes Thermitase, Proteinase K and the proteases TW3 and TW7 which can no longer be assigned to the subtilisins in the narrower sense.
- Liquid detergent preparations B preferred according to the invention contain, based on the total weight of the detergent preparation, 5 to 50% by weight, preferably 7 to 40% by weight and in particular 10 to 30% by weight of protease preparations.
- amylases which can be used according to the invention are the a-amylases from Bacillus licheniformis, from B. amyloliquefaciens, from B. stearothermophilus, from Aspergillus niger and A. oryzae and the further developments of the aforementioned amylases which are improved for use in cleaning agents. Furthermore, the a-amylase from Bacillus sp. A 7-7 (DSM 12368) and the cyclodextrin glucanotransferase (CGTase) from B. agaradherens
- Liquid detergent preparations B preferred according to the invention contain, based on the total weight of the detergent preparation, 0.1 to 30% by weight, preferably 1.0 to 25% by weight and in particular 2.0 to 20% by weight of amylase preparations.
- Further liquid cleaning preparations B preferred according to the invention contain, based on the total weight of the cleaning agent preparation, 0.1 to 30% by weight, preferably 1.0 to 25% by weight and in particular 2.0 to 20% by weight of cellulase preparations.
- Further liquid cleaning preparations B preferred according to the invention contain, based on the total weight of the cleaning agent preparation, 0.1 to 30% by weight, preferably 1.0 to 25% by weight and in particular 2.0 to 20% by weight of mannanase preparations.
- Lipases or cutinases can also be used according to the invention, in particular because of their triglyceride-cleaving activities, but also in order to generate peracids in situ from suitable precursors. These include, for example, those originally from Humicola lanuginosa
- Thermomyces lanuginosus available or further developed lipases, especially those with the amino acid exchange D96L.
- the cutinases can be used, for example, which were originally isolated from Fusarium solani pisi and Humicola insolens. Lipases or cutinases, their Parent enzymes originally isolated from Pseudomonas mendocina and Fusarium solanii.
- Further liquid cleaning preparations B preferred according to the invention contain, based on the total weight of the cleaning agent preparation, 0.1 to 30% by weight, preferably 1.0 to 25% by weight and in particular 2.0 to 20% by weight of lipase preparations.
- enzymes can be used, which are called hemicellulases
- oxidoreductases for example oxidases, oxygenases, catalases, peroxidases, such as halo-, chloro-, bromo-, lignin, glucose or manganese peroxidases, dioxygenases or laccases (phenoloxidases, polyphenol oxidases) can be used according to the invention.
- organic, particularly preferably aromatic, compounds interacting with the enzymes are additionally added in order to increase the activity of the oxidoreductases in question (enhancers) or to reduce the redox potential between the oxidizing enzymes and the enzymes
- Cleaning-active enzymes in particular proteases and amylases, are generally not provided in the form of the pure protein, but rather in the form of stabilized, storable and transportable preparations.
- These prefabricated preparations include, for example, the solid preparations obtained by granulation, extrusion or lyophilization or, particularly in the case of liquid or gel form agents, solutions of the enzymes, advantageously as concentrated as possible, low in water and / or with stabilizers or other auxiliaries.
- the enzymes can be encapsulated both for the solid and for the liquid administration form, for example by spray drying or extrusion of the enzyme solution together with a preferably natural polymer or in the form of capsules, for example those in which the enzymes are enclosed as in a solidified gel or in those of the core-shell type in which an enzyme-containing core with a water, air and / or
- Chemical-impermeable protective layer is coated. Additional active ingredients, for example stabilizers, emulsifiers, pigments, bleaching agents or dyes, can additionally be applied in superimposed layers. Capsules of this type are applied by methods known per se, for example by granular or roll granulation or in fluid-bed processes. Such granules are advantageously polymeric, for example by applying them
- Film former low in dust and stable in storage due to the coating. Furthermore, it is possible to assemble two or more enzymes together, so that a single granulate has several enzyme activities.
- the enzyme protein forms only a fraction of the total weight of conventional enzyme preparations.
- Enzyme preparations preferably used according to the invention in particular the protease and amylase preparations, contain from 0.1 to 40% by weight, preferably from 0.2 to 30% by weight, particularly preferably from 0.4 to 20% by weight and in particular from 0.8 to 10% by weight of the enzyme protein.
- Liquid detergent preparations B which are particularly preferred according to the invention therefore contain, based on the total weight of the detergent preparation, 7 to 40% by weight, in particular 10 to 30% by weight of protease preparations and 2 to 20% by weight, in particular 4.0 to 16 Wt .-% amylase preparations used, each 0.4 to 20 wt .-%,
- active protein contains in particular from 0.8 to 10% by weight of active protein.
- enzymes and / or enzyme preparations preferably liquid protease preparations and / or amylase preparations, and optionally cellulase preparations and / or mannanase preparations are preferably used.
- a preferred pH value of detergent preparations B according to the invention is between 6 and 9.
- the cleaning agent preparations B of the cleaning agent dosage forms according to the invention preferably contain less than 2.5% by weight of complexing agents. They preferably contain less than 2.5% by weight of complexing agents and / or builders. The lowering of the
- detergent preparation B contains less than 2.0% by weight of complexing agent, preferably less than 1.0% by weight of complexing agent, particularly preferably less than 0.5% by weight of complexing agent and in particular none Contains complexing agents.
- the total amount of complexing agent and / or builders contained in the detergent preparation B is preferably less than 10% by weight, preferably less than 6% by weight, particularly preferably less than 2% by weight and in particular 0% by weight.
- An optional component of the cleaning agent preparations according to the invention, in particular cleaning agent preparation B, are organic solvents.
- Preferred organic solvents come from the group of mono- or polyhydric alcohols, alkanolamines or glycol ethers.
- the solvents are preferably selected from ethanol, n- or i-propanol, butanol, glycol, propane or butanediol, glycerol, monoethanolamine, diglycol, propyl or butyl diglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene ether , Diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, dipropylene glycol methyl or ethyl ether, methoxy, ethoxy or butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol- t-butyl ether and mixtures of these solvents.
- Preferred solvents are preferably selected from glycerol, 1, 2-propylene glycol, 1, 3-propylene glycol, dipropylene glycol and polyethylene glycols, in particular those polyethylene glycols which have an average molecular weight between 100 and 800, preferably 200 and 600 g / mol. The proportion by weight of these organic solvents in the total weight of each
- Detergent preparations according to the invention are preferably 5 to 80% by weight, preferably 10 to 60% by weight and in particular 20 to 50% by weight.
- a particularly preferred organic solvent which is particularly effective in terms of stabilizing the cleaning agent preparation, in particular cleaning agent preparation B, is 1,2-propylene glycol.
- the proportion by weight of 1,2-propylene glycol in the total weight of the detergent preparations B according to the invention can vary within wide limits, but such preparations have proven to be particularly stable, based on the
- Total weight of the respective detergent preparation B 5 to 80 wt .-%, preferably 10 to 60 wt .-% and in particular 20 to 50 wt .-% 1, 2-propylene glycol. Corresponding preparations are therefore preferred according to the invention.
- boric acid or a boric acid derivative is a boric acid or a boric acid derivative.
- the boronic acids or their salts or esters are preferably used, in particular derivatives with aromatic groups, for example ortho, meta- or para-substituted phenylboronic acids, in particular 4-formylphenyl-boronic acid (4-FPBA), or the Salts or esters of the compounds mentioned.
- 4-FPBA 4-formylphenyl-boronic acid
- the total weight of detergent preparations B according to the invention is preferably 0.001 to 10% by weight, preferably 0.002 to 6% by weight and in particular 0.05 to 3% by weight.
- a particularly preferred boric acid derivative which is particularly effective in terms of stabilizing the cleaning agent preparation is 4-formylphenyl-boronic acid.
- the proportion by weight of 4-formylphenyl boronic acid in the total weight of the cleaning agent according to the invention Preparations can vary within wide limits, but such preparations have proven to be particularly stable which, based on the total weight of the cleaning agent preparation B, 0.001 to 10% by weight, preferably 0.002 to 6% by weight and in particular 0.05 to 3 % By weight. Corresponding preparations are therefore preferred according to the invention.
- Another optional component of the cleaning agent preparations according to the invention is a Ca or Mg ion source.
- the weight fraction of the Ca or Mg ion source in the total weight of cleaning agent preparations B according to the invention is preferably 0.01 to 10% by weight, preferably 0.2 to 8% by weight and in particular 0.5 to 5% by weight.
- the organic calcium salts have proven to be particularly preferred and particularly effective in terms of stabilizing the cleaning agent preparation B.
- the proportion by weight of the organic calcium salts in the total weight of the cleaning agent preparations according to the invention can vary within wide limits, but those preparations which, based on the total weight of the cleaning agent preparations according to the invention can vary within wide limits, but those preparations which, based on the total weight of the cleaning agent preparations according to the invention.
- Detergent preparation 0.01 to 10 wt .-%, preferably 0.2 to 8 wt .-% and in particular 0.5 to 5 wt .-% contain. Corresponding preparations are therefore preferred according to the invention.
- detergent preparations B according to the invention may also contain polyols, in particular sorbitol.
- the liquid cleaning agent preparations B preferably contain 30% by weight and less, preferably 25% by weight and less, in particular 15% by weight and less.
- the detergent preparations B contain, based on their total weight, 0.5 to 30% by weight, preferably 1.0 to 25% by weight and in particular 1.5 to 30% by weight of water.
- the form of detergent supply further comprises a liquid detergent preparation C, the detergent preparation C being different from the detergent preparations A and B.
- cleaning agent preparations A and B are used in combination with at least one further cleaning agent preparation C.
- the cleaning agent preparation C is liquid (20 ° C), phosphate-free and contains at least one acidifying agent and a glass corrosion inhibitor.
- the cleaning agent preparations C according to the invention contain at least one
- Acidifying agent can be the inventive
- Detergent preparations C are added to lower the pH of the liquor in the rinse aid. Both inorganic acids and organic acids are suitable here, provided they are compatible with the other ingredients.
- the solid mono-, oligo- and polycarboxylic acids can be used in particular for reasons of consumer protection and handling safety. Preferred from this group are formic acid, citric acid,
- Tartaric acid succinic acid, malonic acid, adipic acid, maleic acid, fumaric acid, oxalic acid and polyacrylic acid.
- Organic sulfonic acids such as amidosulfonic acid can also be used.
- Sokalan ® DOS (trademark of BASF), a mixture of succinic acid (max. 31% by weight), glutaric acid (max. 50% by weight) and adipic acid (commercially available and also preferably used as an acidifying agent in the context of the present invention) max. 33% by weight).
- Detergent preparations C based on the total weight of the
- Detergent preparation C one or more acidifying agents, preferably mono-, oligo- and polycarboxylic acids, particularly preferably formic acid, tartaric acid, succinic acid,
- the use of formic acid is preferred because, in addition to the acid function to improve the rinse aid result, it also has a positive influence on the storage stability of the cleaning preparation C, which, as explained above, is subject to severe temperature fluctuations due to storage in the interior of the dishwasher. Furthermore, it has a disinfectant effect, so that when using formic acid in the rinse cycle, both the number of bacteria is reduced. This applies both to those bacteria that are in the rinse liquor of the rinse cycle and to those that remain in the sump of the dishwasher during and after the rinse cycle as well as the interior of the dishwasher. The number of residual germs on the washed dishes can also be reduced as a result.
- the detergent preparations according to the invention also contain C and
- preparation (s) C and, if appropriate, the preparation (s) A particularly preferably comprise, preferably at least
- Preparation (s) C an appropriate amount of glass corrosion inhibitor (s).
- glass corrosion inhibitors are preferably selected from water-soluble zinc salts, preferably zinc chloride, zinc sulfate and / or zinc acetate, particularly preferably zinc acetate, polyalkyleneimines, in particular polyethyleneimines.
- the preparations according to the invention, in particular preparations A and / or C contain at least one zinc salt as a further constituent,
- the inorganic zinc salt is preferably selected from the group consisting of zinc bromide, zinc chloride, zinc iodide, zinc nitrate and zinc sulfate.
- the organic zinc salt is preferably selected from the group consisting of zinc salts of monomeric or polymeric organic acids, in particular from the group of zinc acetate, zinc acetylacetonate, zinc benzoate, zinc formate, zinc lactate, zinc gluconate, zinc ricinoleate, zinc abietate, zinc valerate and zinc p-toluenesulfonate.
- zinc acetate is used as the zinc salt.
- the zinc salt in cleaning agent preparations according to the invention is preferably in an amount of 0.01% by weight to 5% by weight, particularly preferably in an amount of 0.05% by weight to 3% by weight, in particular in an amount of 0.1% by weight to 2% by weight, based on the total weight of the respective detergent preparation, in particular the respective detergent preparation A or C.
- Polyethyleneimines as are available, for example, under the name Lupasol® (BASF), are preferably used in an amount of 0 to 5% by weight, in particular 0.01 to 2% by weight, based on the total weight of the respective preparation Glass corrosion inhibitors are used.
- the cleaning agent preparation C contains a zinc salt, preferably in an amount of 0.01% by weight to 5% by weight, particularly preferably in an amount of 0.05% by weight to 3% by weight. , in particular in an amount of 0.1 wt .-% to 2 wt .-%, based on their total weight.
- the cleaning agent preparation preferably contains a nonionic surfactant.
- a surfactant-containing cleaning agent preparation C it can be used in the
- nonionic surfactants described above are particularly suitable as surfactant additives for the cleaning agent preparation C.
- nonionic surfactants of the general formula R 1 -CH (0H) CH 2 0- (A0) w- (AO) x- (A'O) y - (A ”O) zR 2 in which
- R 1 is a linear or branched, saturated or mono- or polyunsaturated C6 is 24 alkyl or alkenyl radical;
- R 2 for a linear or branched hydrocarbon radical with 2 to 26
- A, A ', A ”and A' independently of one another for a residue from the group -CH2CH2, -CH2CH2-CH2, -CH 2 -CH (CH 3 ), -CH2-CH2-CH2-CH2, -CH2-CH (CH 3 ) -CH 2 -, -CH 2 - CH (CH 2 -CH 3 ) stand,
- w, x, y and z stand for values between 0.5 and 120, where x, y and / or z can also be 0
- non-ionic surfactants of the general formula R 1 -CH (0H) CH 2 0- (A0) wR 2 , in which the
- R 1 for a straight-chain or branched, saturated or single or
- R 2 represents a linear or branched hydrocarbon radical having 2 to 26 carbon atoms
- A represents a radical from the group CH2CH2, -CH2CH2-CH2, -CH2-CH (CH 3 ), and
- w stands for values between 1 and 120, preferably 10 to 80, in particular 20 to 40.
- the group of these nonionic surfactants includes, for example, the C4-22 fatty alcohol (EO) io-8o-2-hydroxyalkyl ethers, in particular also the C8-12 fatty alcohol (EO) 22 -2-hydroxydecyl ether and the C4-22 fatty alcohol (EO) 40 -80-2-hydroxyalkyl ether.
- Detergent preparation C is preferably from 1.0 to 20% by weight, preferably from 2.0 to 18% by weight, particularly preferably from 4.0 to 15% by weight and in particular from 6.0 to 12% by weight.
- Detergent preparation in particular at least one detergent preparation further comprising a nonionic surfactant, particularly preferably at least
- Detergent preparation B and / or D at least one hydrotrope (hereinafter also referred to as a solubilizer).
- Preferred hydrotropes are xylene sulfonate, cumene sulfonate, urea and / or / V-methylacetamide, particularly preferably cumene sulfonate and / or xylene sulfonate, especially cumene sulfonate. It was found that the use of hydrotropes, in particular cumene sulfonate, enormously improves the phase stability with regard to the temperature fluctuations. This can be observed in particular for preparations which contain at least one nonionic surfactant.
- At least the detergent preparation C in particular the detergent preparations C and B, have at least one hydrotrope, preferably xylene sulfonate, cumene sulfonate, urea and / or N-methylacetamide, particularly preferably cumene sulfonate and / or xylene sulfonate, especially cumene sulfonate, preferably in an amount from 2 to 25% by weight, in particular from 4 to 20% by weight and particularly preferably in an amount of 6 to 15, for example from 7 to 12% by weight, based on the total weight of the respective detergent preparation.
- hydrotrope preferably xylene sulfonate, cumene sulfonate, urea and / or N-methylacetamide, particularly preferably cumene sulfonate and / or xylene sulfonate, especially cumene sulfonate, preferably in an amount from 2 to 25% by weight, in particular from 4 to 20% by weight and particularly
- the weight ratio of the at least one nonionic surfactant to the at least one hydrotrope preferably xylene sulfonate, cumene sulfonate, urea and / or N-methylacetamide, particularly preferably cumene sulfonate and / or xylene sulfonate, in particular cumene sulfonate, is preferred.
- the detergent preparation C preferably contains less than 1% by weight, preferably less than 0.5% by weight, in particular less than 0.1% by weight of enzyme preparation and / or less than 2 mg of active enzyme protein / g of composition, preferably less as 1 mg of active enzyme protein / g composition, in particular less than 0.5 mg of active enzyme protein / g composition, particularly preferably the cleaning agent preparation C contains less than 0.1 mg of active enzyme protein / g composition. It very particularly preferably contains
- Detergent preparation C no enzyme preparation.
- composition of some exemplary cleaning agent forms according to the invention comprising the cleaning agent preparations A, B and C, can be found in the following tables.
- the combination of cleaning agents described above is packaged using a packaging agent in which the cleaning agent preparations A, B and C are present separately from one another.
- This separation can be achieved, for example, by separate receiving chambers, each of these receiving chambers containing one of the cleaning agents combined with one another.
- Examples of such assembly forms are cartridges with two, three, four or more separate receiving chambers, for example two, three, four or multi-chamber bottles.
- the viscosity of all cleaning agent preparations A, B and C is preferably less than 120 mPas, in particular from 1 to 100 mPas, in particular 10 to 80 mPas, preferably 20 to 60 mPas (measured at 20 ° C. with a Brookfield instrument LVDV II +, spindle 31, 100 rpm).
- This has the advantage that the detergent preparations from the packaging material can only be opened by opening a valve on the underside of the packaging material (in particular the cartridge) on the basis of gravity, preferably without the involvement of electrical or electronic means, e.g. Pumps etc. can be dosed.
- the chambers are preferably largely completely emptied, i.e. without large residual amounts of the dosed
- the packaging or the cartridge remain.
- Embodiment in the packaging means is additionally at least one active substance composition which is present separately from the cleaning agent preparations, in particular from the cleaning agent preparations A, B and C and which contains at least one carrier material, preferably a water-insoluble carrier material, and at least one active substance D.
- the polymeric carrier material of the particles consists at least in part of ethylene / vinyl acetate copolymer. Another preferred subject of the present application is therefore one
- a polymeric carrier material contains at least 10% by weight, preferably at least 30% by weight, particularly preferably at least 70% by weight of ethylene / vinyl acetate copolymer, preferably entirely of ethylene / vinyl acetate copolymer is made.
- Ethylene / vinyl acetate copolymers is the name for copolymers of ethylene and vinyl acetate. This polymer is generally produced in a process comparable to the production of low density polyethylene (LDPE). With a
- the crystallinity of the polyethylene is interrupted and in this way the melting and softening points or the hardness of the resulting products are reduced.
- the vinyl acetate also makes the copolymer more polar and thus improves its adhesion to polar substrates.
- ethylene / vinyl acetate copolymers described above are widely available commercially, for example under the tradename Elvax ® (Dupont).
- Elvax ® Particularly suitable in the context of the present invention, polyvinyl alcohols are, for example Elvax ® 265, Elvax ® 240, Elvax ® 205W, Elvax ® 200W, as well as Elvax ® 360.
- Elvax ® 360 are also suitable.
- active substance compositions are particularly preferred in which ethylene / vinyl acetate copolymer is used as the polymeric carrier material and this copolymer contains 5 to 50% by weight of vinyl acetate, preferably 10 to 40% by weight .-% vinyl acetate and in particular 20 to 30 wt .-% vinyl acetate, each based on the total weight of the copolymer contains.
- suitable carrier materials are the cyclodextrins.
- inorganic carrier materials are preferably also used. Be particularly preferred
- Forms of cleaning agent characterized in that at least one of the carrier materials is an inorganic carrier material, preferably a silicate, phosphate or borate.
- the silicates, phosphates or borates are preferably in the form of a glass, particularly preferably in the form of a water-soluble glass.
- Particularly preferred glasses are glasses containing zinc and / or bismuth, in particular those containing bismuth phosphate and / or
- the carrier material is water-soluble and contains in its substance, the active ingredient, in particular the glass corrosion inhibitors zinc and / or bismuth) in the carrier material.
- the detergent dosage forms can contain such zinc or bismuth-containing glasses, particularly preferably zinc phosphate-containing glasses, in addition to a further active ingredient composition comprising a carrier material, preferably a
- cleaning agents contain water-insoluble carrier material and at least one active ingredient D. These can then be contained in a common chamber or in separate chambers, in particular in one or more chambers which have openings, in particular openings such that the washing liquor and / or the air can flow through them.
- Preferred forms of cleaning agents are those which contain a glass containing zinc phosphate or bismuth phosphate and furthermore at least one, preferably two, three or more
- Contain active ingredient compositions which comprise one or more fragrances and / or one or more fragrance scavengers as active ingredients.
- thermoplastic in particular thermoplastic
- Deformation of the carrier materials in the course of one or more applications will result in a change in the carrier material surface, in particular a change in the size of the
- Dosing devices characterized in that at least one polymeric carrier material has a melting or softening point between 40 and 125 ° C, preferably between 60 and 100 ° C, particularly preferably a melting point of 70 to 90 ° C and in particular between 73 and 80 ° C ( preferred method of determination for the
- Carrier materials are insoluble in water.
- the active substance compositions can in principle all, and / or depending on the chemical and physical properties of the carrier materials realizable physical states Take spatial forms.
- Active ingredient compositions as a gel.
- At least one of the active substance compositions is in the form of a solid. Active ingredient compositions in the form of individual blocks comprising an entire active ingredient composition are used with particular preference.
- the active substance compositions can preferably be in particulate form, the active substance compositions in which the carrier material comprises at least one of the
- Active ingredient compositions are in particle form, these particles preferably having an average diameter of 0.5 to 20 mm, preferably 1 to 10 mm and in particular 3 to 6 mm, are particularly preferred.
- Active ingredient compositions which comprise at least one colored active ingredient composition are particularly preferably used.
- the coloring of at least one of the active ingredient compositions enables an optical differentiation of these compositions to be achieved and the multiple use of these different compositions can be clarified in a simple manner.
- the dyes are also suitable as an indicator, in particular as a consumption indicator for the colored active ingredient compositions.
- Preferred dyes the selection of which is not difficult for the person skilled in the art, have a high storage stability and insensitivity to the other ingredients of the agents and to light, and no pronounced substantivity to the substrates to be treated with the dye-containing agents, such as glass, ceramics or plastic tableware, to be precise stain.
- the suitable concentration of the colorant in cleaning agents is typically a few 10 3 to 10 4 % by weight.
- the form of the detergent is characterized in that the at least one active ingredient D is selected from the group of fragrances, preferably linalyl acetate, dihydromyrcenol, citronellonitrile, menthyl acetate,
- Zinc ricinoleate Dyes, glass corrosion inhibitors, antimicrobial agents, germicides or fungicides and mixtures thereof, preferably mixtures of at least one fragrance scavenger, preferably with one, two, three or more fragrances and / or at least one dye.
- Fragrance compounds e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. However, are preferred
- perfume oils can also contain natural fragrance mixtures as are available from plant sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil.
- a fragrance In order to be perceptible, a fragrance must be volatile, whereby in addition to the nature of the functional groups and the structure of the chemical compound, the molar mass also plays an important role. Most odoriferous substances have molecular weights of up to about 200 daltons, while molecular weights of 300 daltons and more are an exception. Due to the different volatility of odoriferous substances, the smell of a perfume or fragrance composed of several odoriferous substances changes during evaporation, whereby the odor impressions are described in "top note” (top note), “heart or middle note” (middle note or body ) and “base note” (end note or dry out). Since the smell is largely based on the intensity of the smell, the top note of a perfume or
- more volatile fragrances can be bound to certain fixatives, for example, which prevents them from evaporating too quickly.
- fixatives for example, which prevents them from evaporating too quickly.
- the fragrances can be processed directly, but it can also be advantageous to apply the fragrances to carriers which ensure a long-lasting fragrance due to a slower fragrance release.
- Cyclodextrins for example, have proven themselves as such carrier materials, the Cyclodextrin-perfume complexes can also be coated with other auxiliaries.
- fragrances are linalyl acetate, dihydromyrcenol,
- Citronellonitrile menthyl acetate, methylphenylbutanol and / or eucalyptol and mixtures thereof.
- the known ricenolates in particular the zinc ricenoleates, can be used, for example, as scent catchers (or, as is also used synonymously below, odor neutralizers or fragrance neutralizers, agents against malodour or bad odors). Also preferred are 2-menthyl-5-cyclohexylpentanol and 1-cyclohexylethanol.
- Activated carbon and / or cyclodextrins and / or zeolites, preferably acid-modified zeolites, can also be used with particular preference.
- Zinc ricinoleate alone or in combination with one or more of the above-mentioned fragrances and / or scent scavengers is particularly preferred, since it also has a positive effect on the inhibition of glass corrosion during the rinsing process.
- Fragrances and / or fragrance scavengers antimicrobial agents are used.
- bacteriostatics and bactericides fungistatics and fungicides, etc.
- Important substances from these groups are, for example, benzalkonium chlorides, alkylarlylsulfonates, halophenols and
- Phenol mercuric acetate although these compounds can also be dispensed with entirely.
- the active substances can be contained in the active substance preparations in any amounts.
- dosing devices are particularly preferred in which the proportion by weight of the active ingredient (s) is 1 to 70% by weight, preferably 10 to 60% by weight, particularly preferably 20 to 50% by weight, in particular 30 to 40% by weight, is based in each case on the total weight of the active ingredient composition (s).
- active ingredient compositions can be present separately from one another or next to one another in the packaging means of the detergent form.
- the different active ingredient compositions can preferably be side by side, that is to say in direct contact with one another, in the
- an active ingredient composition D in particular comprising fragrances and / or scent scavengers
- formic acid is used as an acidifying agent in preparation C.
- the formic acid itself has a slightly pungent smell, which is noticeable to sensitive consumers. Due to the separate storage of the Active ingredient composition and the release of the at least one active ingredient D, in particular if it is one or more fragrances, in particular those preferred above, and / or one or more fragrance scavengers, in particular, for example, zinc ricinoleate, does not occur during the dishwashing process or in the period between the cleaning cycles an unpleasant smell inside the dishwasher.
- Another object of the present application is a cleaning agent supply form, comprising
- a cleaning agent preparation A according to the invention in an amount sufficient to carry out an automatic dishwashing process at least twice, preferably at least four times and in particular at least eight times;
- Active ingredient composition in a for the at least twice, preferably at least four times and in particular at least eight times, a machine
- Dishwashing method sufficient amount, which contains at least one carrier material, preferably a water-insoluble carrier material, and at least one active ingredient D;
- Another object of the present application is a detergent dosing system comprising
- a cleaning agent preparation A according to the invention in an amount sufficient to carry out an automatic dishwashing process at least twice, preferably at least four times and in particular at least eight times;
- Active ingredient composition in one for at least two, preferably at least four and in particular at least eight times a machine
- Dishwashing method sufficient amount, which contains at least one carrier material, preferably a water-insoluble carrier material, and at least one active ingredient D;
- the cartridges described above are the
- Such a metering device can be connected to the cartridge, for example, by means of an adhesive, snap-in, snap or plug connection. Filling the cartridge is simplified, for example, by separating the cartridge and the metering device. Alternatively, the detachable
- Such an exchange can be indicated, for example, when the cleaning program is changed or after the cartridge has been completely emptied.
- a particularly preferred subject matter of this application is a detergent dosing system comprising
- a cleaning agent supply form comprising an amount of cleaning agent preparations A, B and C or A, B, C and D sufficient for carrying out an automatic dishwashing process at least twice, preferably at least four times and in particular at least eight times; b) a dispenser detachably connected to the form of the detergent.
- the present application furthermore relates to a detergent dosing system comprising
- a cleaning agent supply form comprising an amount of cleaning agent preparations A, B and C or A, B, C and D sufficient for carrying out an automatic dishwashing process at least twice, preferably at least four times and in particular at least eight times; b) a dosing device that is permanently connected to the form of the detergent
- compositions, a cartridge and a dosing device detachably connected to the cartridge are present in a common outer packaging, the filled cartridge and the dosing device being particularly preferably contained separately from one another in the outer packaging.
- the outer packaging is used for storage, transport and presentation of the form of cleaning agent according to the invention and protects it from dirt, shock and impact.
- the outer packaging is used for storage, transport and presentation of the form of cleaning agent according to the invention and protects it from dirt, shock and impact.
- Outer packaging should be made at least partially transparent.
- the dosing system according to the invention consists of the basic components of a cartridge filled with the cleaning agent according to the invention and a dosing device which can be coupled to the cartridge and which in turn is formed from further assemblies, such as, for example, component carrier, actuator, closure element, sensor, energy source and / or control unit.
- the metering system according to the invention is movable. Movable in the sense of this application means that the metering system is not inextricably linked to a water-carrying device such as a dishwasher or the like, but rather can be removed from a dishwasher by the user or positioned in a dishwasher, i.e. can be handled independently
- the metering device is not releasably connected to a water-carrying device such as a dishwasher or the like for the user and only the cartridge is movable.
- the preparations to be dosed can have a pH between 2 and 14, in particular 2 and 12, depending on the intended use, all components of the dosing system that come into contact with the preparations should have an appropriate acid and / or alkali resistance. Furthermore, these components should be largely chemically inert, for example against nonionic surfactants, enzymes and / or fragrances, through a suitable choice of material.
- a cartridge in the sense of this application is understood to mean a packaging material which is suitable for enveloping or holding together flowable or scatterable preparations and which can be coupled to a dispenser for dispensing the preparation.
- a cartridge can also comprise a plurality of chambers which are different from one another
- compositions can be filled. It is also conceivable for a plurality of containers to be arranged to form a cartridge unit.
- the cartridge has at least one outlet opening, which is arranged in such a way that the preparation can be released from the container under the force of gravity in the use position of the metering device.
- At least one second chamber is provided for receiving at least one second flowable or scatterable preparation, the second chamber having at least one outlet opening which is arranged in such a way that product release from the second chamber caused by gravity is in the use position of the metering device is effected.
- the arrangement of a second chamber is particularly advantageous when preparations are stored in the separate containers, which are usually not stable with one another, such as bleaching agents and enzymes.
- At least one of the chambers for dispensing active substances) D is one
- Fragrance or in particular an odor neutralizer to the environment, designed so that it has openings through which the washing liquor and / or the air can flow.
- the cartridge is formed in one piece.
- the cartridges can be formed inexpensively in one production step, in particular by means of suitable blow molding processes.
- the chambers of a cartridge can be separated from one another, for example, by webs or material bridges.
- the cartridge can also be formed in several pieces by components that are injection molded and then joined together. Furthermore, it is conceivable that the cartridge is formed in such a way that at least one chamber, preferably all chambers, can be removed individually from the dosing device or inserted into the dosing device. This makes it possible to replace a chamber that has already been emptied if the consumption of a preparation from one chamber varies, while the others, which may still be filled with preparation, remain in the metering device. In this way, a targeted and needs-based refilling of the individual chambers or their preparations can be achieved.
- the chambers of a cartridge can be fixed to one another by suitable connection methods, so that a container unit is formed.
- the chambers can be detachable or non-detachable by means of a suitable positive, non-positive or material connection
- connection types from the group of snap-in connections, Velcro connections, press connections, fusion connections, adhesive connections, welded connections, soldered connections, screw connections,
- the fixation can also be formed by a shrink tube (so-called sleeve), which is pulled over the entire or sections of the cartridge in a heated state and firmly encloses the chambers or the cartridge in the cooled state.
- a shrink tube so-called sleeve
- the bottom of the chambers can be inclined in a funnel shape towards the discharge opening.
- the inner wall of a chamber can be formed by a suitable choice of material and / or surface configuration in such a way that a slight material adhesion of the preparation to the inner one
- Chamber wall is realized. This measure can also further optimize the residual emptiness of a chamber.
- the chambers of a cartridge can have the same or different filling volumes.
- the ratio of the container volumes is preferably 5: 1, in a configuration with three chambers preferably 4: 1: 1, whereby this
- Configurations are particularly suitable for use in dishwashers.
- the cartridge preferably has 3, 4, 5 or 6 chambers.
- the first chamber contains an alkaline cleaning preparation
- the second chamber contains an enzymatic preparation
- the third chamber contains a rinse aid, the volume ratio of the chambers being approximately 4: 1: 1.
- the fourth chamber contains the at least one
- Active ingredient composition comprising the at least one active ingredient D and a carrier material, preferably a water-insoluble carrier material.
- a dosing chamber can be formed in or on a chamber in the direction of flow of the preparation in front of the outlet opening.
- the metering chamber determines the amount of preparation that is to be released into the environment when preparation is released from the chamber. This is particularly advantageous if the closure element of the metering device, which causes the preparation to be dispensed from a chamber into the environment, can only be put into a dispensing and a closed state without checking the dispensing quantity. Through the The dosing chamber then ensures that a predefined amount of preparation is released without an immediate feedback of the dispensed preparation quantity.
- the metering chambers can be formed in one piece or in several pieces.
- one or more chambers each have a chamber opening that can be closed in a liquid-tight manner in addition to an outlet opening.
- This chamber opening makes it possible, for example, to refill the preparation stored in this chamber.
- ventilation options can be provided in particular in the head region of the cartridge, in order to ensure pressure compensation when the filling level of the chambers falls between the interior of the cartridge chambers and the surroundings.
- These ventilation options can be designed, for example, as a valve, in particular a silicone valve, micro-openings in the cartridge wall or the like.
- cartridge chambers are not to be ventilated directly, but rather via the metering device or no ventilation, e.g. If flexible containers, such as bags, are provided, this has the advantage that when the container is elevated
- the cartridge usually has a filling volume of ⁇ 5,000 ml, in particular ⁇ 1,000 ml, preferably ⁇ 500 ml, particularly preferably ⁇ 250 ml, very particularly preferably ⁇ 50 ml.
- the cartridge can take any shape. For example, it can be cube-shaped, spherical or plate-like.
- the shape of the cartridge and the metering device can in particular be designed in such a way that they ensure as little loss of useful volume as possible, in particular in a dishwasher.
- the dosing device based on the dishes to be cleaned in dishwashers.
- this can be plate-shaped, approximately in the dimensions of a plate.
- the metering device can be positioned in a space-saving manner, for example in the lower basket of the dishwasher will.
- the correct positioning of the dosing unit is immediately intuitive for the user due to the plate-like shape.
- the cartridge preferably has a ratio of height: width: depth between 5: 5: 1 and 50: 50: 1, particularly preferably of about 10: 10: 1.
- the “slim” design of the dosing device and the cartridge makes it possible, in particular, to position the device in the lower cutlery basket of a dishwasher in the receptacles provided for plates. This has the advantage that the preparations dispensed from the dosing device go directly into the washing liquor and cannot adhere to other items to be washed.
- Customary household dishwashers are usually designed in such a way that the arrangement of larger items to be washed, such as pans or large plates, is provided in the lower basket of the dishwasher.
- the dosing system is dimensioned such that the dosing system can only be positioned in the receptacles provided for the lower basket.
- the width and the height of the metering system can be chosen in particular between 150 mm and 300 mm, particularly preferably between 175 mm and 250 mm.
- the dosing unit in a cup shape with an essentially circular or square base area.
- the cartridge In order to protect heat-sensitive components of a preparation in a cartridge from exposure to heat, it is advantageous to manufacture the cartridge from a material with a low thermal conductivity.
- a further possibility for reducing the influence of heat on a preparation in a chamber of the cartridge is to isolate the chamber by means of suitable measures, e.g. through the use of thermal insulation materials such as styrofoam, which completely or partially enclose the chamber or the cartridge in a suitable manner.
- the cartridge has an RFID label that at least contains information about the contents of the cartridge and that can be read out by the sensor unit.
- This information can be used to select a dosing program stored in the control unit. This can ensure that an optimal dosing program is always used for a specific preparation. It can also be provided that, in the absence of an RFID label or an RFID label with an incorrect or incorrect identifier, the metering device does not dose and instead generates an optical or acoustic signal that the user is aware of the error points out. In order to rule out misuse of the cartridge, the cartridges can also have structural elements which correspond to corresponding elements of the metering device according to the
- Control unit are transmitted, whereby a control of the metering device can be carried out which is coordinated with the content of the corresponding container.
- the cartridge is designed in particular for receiving flowable cleaning agents.
- a cartridge particularly preferably has a plurality of chambers for spatially separated accommodation of preparations of a cleaning agent which are in each case different from one another.
- the cartridge can be designed so that it is detachable or fixed in or on the
- Dishwasher can be arranged.
- control unit The control unit, sensor unit and at least one actuator required for operation are integrated in the dosing device.
- An energy source is preferably also arranged in the metering device.
- the dosing device consists of a splash-proof housing that prevents the ingress of splash water, such as when used in a
- Dishwasher can prevent inside of the dispenser.
- the dosing device comprises at least one first interface, which interacts with a corresponding interface designed in or on a water-carrying device, in particular a water-carrying household appliance, preferably a dishwasher, such that a transmission of electrical energy from the water-carrying device to the dosing device is realized.
- a water-carrying device in particular a water-carrying household appliance, preferably a dishwasher
- the interfaces are formed by plug connectors.
- the interfaces can be designed in such a way that wireless transmission of electrical energy is effected.
- a second interface is provided on the metering device and the water-carrying device, such as a dishwasher
- An adapter can be used to easily couple the dosing system to a water-bearing household appliance.
- the adapter is used for the mechanical and / or electrical connection of the dosing system to the water-bearing household appliance.
- the adapter is, preferably fixed, connected to a water-carrying line of the household appliance. However, it is also conceivable to use the adapter for positioning in or on
- the adapter makes it possible to run a dosing system for both a self-sufficient and a "build-in" version. It is also possible to design the adapter as a type of charging station for the metering system, in which, for example, the energy source of the metering device is charged or data is exchanged between the metering device and the adapter.
- the adapter can be arranged in a dishwasher on one of the inner walls of the washing chamber, in particular on the inner side of the dishwasher door.
- the adapter as such is positioned so that it is not accessible to the user in the water-conducting household appliance, so that the metering device is inserted into the adapter, for example during assembly of the household device, the adapter, the metering device and the household device being designed in this way that a cartridge can be coupled to the dosing device by the user.
- the cleaning agent supply forms according to the invention are suitable for use in dishwashing, but the use of a cleaning agent according to the invention is nevertheless
- Form of detergent or a detergent dosing system for washing dishes in a machine dishwashing method is preferred.
- the cleaning agents according to the invention are notable for particular physical and chemical stability
- the cleaning agents according to the invention are therefore particularly suitable for metering by means of a metering system located in the interior of a dishwasher.
- a dosing system located in the interior of a dishwasher.
- Such a dosing system which can be immovably integrated into the interior of the dishwasher (machine-integrated dosing device), however
- Movable in the sense of this application means that the dispensing and metering system cannot be unsolvable with a device such as a dishwasher or the like is connected, but can, for example, be removed from a dishwasher or positioned in a dishwasher.
- a movable cartridge of a dosing system provided for positioning in the interior of a dishwasher
- An example of an immovable cartridge is a container integrated immovably into the interior, for example into the side wall or the interior lining of the door of a dishwasher.
- An example of a movable cartridge is a container that the consumer places in the interior of the dishwasher and remains there throughout the course of a cleaning cycle. Such a cartridge can be integrated into the interior, for example by simply inserting it into the cutlery or crockery basket, but can also be removed from the interior of the dishwasher by the consumer.
- the detergent or the detergent combination is dosed from the cartridge into the interior of the dishwasher, as described above, preferably by means of a dosing device that can be detached from the cartridge.
- a dosing device can be connected to the cartridge by means of an adhesive, latching, snap or plug connection.
- Cartridges with an inseparably connected dosing device can of course also be used.
- Detergent reservoir for i) a dosing device immovably integrated into the interior of a dishwasher or ii) one for positioning in the interior of a
- Movable dosing device provided in the dishwasher is preferred.
- Detergent reservoir for a dishwasher is a further subject of the present application.
- a cleaning agent form according to the invention comprising a) a cleaning agent preparation A according to the invention in an amount sufficient to carry out an automatic dishwashing process at least twice, preferably at least four times and in particular at least eight times;
- Active ingredient composition in a for the at least twice, preferably at least four times and in particular at least eight times, a machine
- Dishwashing method sufficient amount, which contains at least one carrier material, preferably water-insoluble carrier material, and at least one active ingredient D;
- Receiving chambers are available as a detergent reservoir for
- a movable metering device provided for positioning in the interior of a dishwasher.
- the cleaning agents and cleaning agent combinations according to the invention are preferably used as automatic dishwashing agents.
- a partial amount a of the detergent preparation A located in the cartridge is metered into the interior of the dishwasher, a remaining amount of the detergent preparation located in the cartridge remaining in the cartridge until the end of the dishwashing process, characterized in that it
- Residual amount corresponds to at least twice, preferably at least four times and in particular at least eight times the amount of subset a; and a portion b of the detergent preparation B located in the cartridge is metered into the interior of the dishwasher, a remaining amount of the detergent preparation located in the cartridge remaining in the cartridge until the end of the dishwashing process, characterized in that it Residual amount corresponds to at least twice, preferably at least four times and in particular at least eight times the amount of subset b; and a portion c of the detergent preparation C in the cartridge is metered into the interior of the dishwasher, a residual amount of the detergent preparation in the cartridge remaining in the cartridge until the end of the dishwashing process, characterized in that it
- Residual amount corresponds to at least twice, preferably at least four times and in particular at least eight times the amount of subset c
- a partial amount d of the active ingredients D which may be present in the cartridge is metered into the interior of the dishwasher, a residual amount of the active ingredient present in the cartridge remaining in the cartridge until the end of the dishwashing process, characterized in that it
- Residual amount corresponds to at least twice, preferably at least four times and in particular at least eight times the amount of subset d and
- the invention also relates to a machine
- Dishwashing process in which the active ingredient composition is in the cartridge and through which the washing liquor and / or air flows through openings.
- fragrance (s) are released into the air in the interior of the dishwasher and, in addition to scenting the washing liquor during the dishwashing process, also leads to an odor situation that is pleasant for the consumer when opening and loading the dishwasher .
- the detergent preparation A and the detergent preparation B and the detergent preparation C are metered in
- Another preferred subject of this application is therefore a machine dishwashing process using a cleaning agent supply form according to the invention or a cleaning agent metering system according to the invention, in the course thereof
- Dishwashing process remains in the cartridge, which of the at least double, preferably corresponds to at least four times and in particular at least eight times the amount of subset a;
- Cartridge located in the dishwasher a subset b of the detergent preparation B located in the second cartridge, which is different from the cleaning agent preparation A according to the invention, is metered into the interior of the dishwasher, with a remaining amount of the cleaning agent located in this cartridge until the end of the
- Dishwashing process remains in the cartridge, which is at least double
- Dishwasher located cartridge a subset d of the cleaning agent preparations A and B according to the invention located in a further cartridge
- different detergent preparation C is metered into the interior of the dishwasher, a residual amount of the detergent in this cartridge remaining in the cartridge until the end of the dishwashing process, which corresponds to at least twice, preferably at least four times and in particular at least eight times the amount of subset d.
- the time t2 is at least 1 minute, preferably at least 2 minutes and in particular between 3 and 30 minutes, in particular between 3 and 20 minutes, before or after preferably before time t1.
- the time t2 is at least 1 minute, preferably at least 2 minutes and in particular between 3 and 30 minutes, in particular between 3 and 20 minutes, before or after preferably before time t1.
- Dishwashing method with delayed metering of the minute preferably at least 2 minutes and in particular between 3 and 30 minutes, in particular between 3 and 20 minutes, before or after, preferably after the time t1.
- the cleaning preparation B is metered into the interior at a temperature of 20-35 ° C., then the cleaning preparation A at a temperature of 30-60 ° C. and then the cleaning preparation C at a temperature below 20 ° C.
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102018220191.9A DE102018220191A1 (en) | 2018-11-23 | 2018-11-23 | Detergent with rinse aid for automatic dosing unit |
PCT/EP2019/081767 WO2020104442A1 (en) | 2018-11-23 | 2019-11-19 | Cleaning agent with clear-rinsing agent for automatic metering unit |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3884020A1 true EP3884020A1 (en) | 2021-09-29 |
Family
ID=68731951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19812716.9A Pending EP3884020A1 (en) | 2018-11-23 | 2019-11-19 | Cleaning agent with clear-rinsing agent for automatic metering unit |
Country Status (4)
Country | Link |
---|---|
US (1) | US20210277339A1 (en) |
EP (1) | EP3884020A1 (en) |
DE (1) | DE102018220191A1 (en) |
WO (1) | WO2020104442A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019200702A1 (en) * | 2019-01-21 | 2020-07-23 | Henkel Ag & Co. Kgaa | Multi-component cleaning system |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2386129B (en) | 2002-03-06 | 2004-12-01 | Reckitt Benckiser Nv | Detergent dosing device |
EP1917342B8 (en) * | 2005-09-02 | 2013-05-15 | Henkel AG & Co. KGaA | Detergents |
DE102005062479A1 (en) | 2005-12-27 | 2007-07-05 | BSH Bosch und Siemens Hausgeräte GmbH | Dosing arrangement for adding an additive into a chamber of a household appliance comprises actuators formed as electro-active polymers for driving conveyor units |
DE102011005980A1 (en) * | 2011-03-23 | 2012-09-27 | Henkel Ag & Co. Kgaa | Dosing system for a dishwasher |
GB201409631D0 (en) * | 2014-05-30 | 2014-07-16 | Reckitt Benckiser Brands Ltd | Improved PEI composition |
-
2018
- 2018-11-23 DE DE102018220191.9A patent/DE102018220191A1/en not_active Withdrawn
-
2019
- 2019-11-19 WO PCT/EP2019/081767 patent/WO2020104442A1/en unknown
- 2019-11-19 EP EP19812716.9A patent/EP3884020A1/en active Pending
-
2021
- 2021-05-24 US US17/329,133 patent/US20210277339A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
DE102018220191A1 (en) | 2020-05-28 |
WO2020104442A1 (en) | 2020-05-28 |
US20210277339A1 (en) | 2021-09-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2446013B1 (en) | Automatic dishwashing detergent composition | |
EP2414498B1 (en) | Cleaning agent | |
EP2494021A1 (en) | Machine cleaning method | |
WO2011051417A1 (en) | Machine cleaning method | |
EP2414499A1 (en) | Cleaning agent | |
WO2020152004A1 (en) | Multi-component cleaning system | |
WO2011051415A1 (en) | Machine cleaning method | |
EP3884021A1 (en) | Multi-component cleaning system | |
EP3656839B1 (en) | Cleaning agent for automatic dosing | |
EP3884020A1 (en) | Cleaning agent with clear-rinsing agent for automatic metering unit | |
WO2011138165A1 (en) | Mechanical dishwashing and textile washing methods | |
EP2494019A1 (en) | Dishwasher detergent | |
WO2011157630A1 (en) | Automatic cleaning method | |
WO2021013686A1 (en) | Protease-containing cleaning agent for automatic metering | |
EP3914686B1 (en) | Cleaning formulation comprising a bleaching agent, for automatic dishwashing | |
EP3835397B1 (en) | Cleaning agent | |
WO2011051418A1 (en) | Machine cleaning method | |
DE102018220187A1 (en) | Low-viscosity detergent formulations for automatic dishwashing | |
DE102018220188A1 (en) | Transparent formulations for automatic dishwashing | |
DE102010030151A1 (en) | Automated cleaning method comprises dosing a liquid cleaning agent formulation comprising chlorine bleaching agent by a cleaning agent supplying mold into an inner chamber of a cleaning machine from a cartridge located in inner chamber |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20210506 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230531 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20231009 |