EP3862587A1

EP3862587A1 - Sliding member

Info

Publication number: EP3862587A1
Application number: EP21155147.8A
Authority: EP
Inventors: Hideyuki Nakajima
Original assignee: Daido Metal Co Ltd
Current assignee: Daido Metal Co Ltd
Priority date: 2020-02-06
Filing date: 2021-02-04
Publication date: 2021-08-11
Anticipated expiration: 2041-02-04
Also published as: JP7335179B2; EP3862587B1; JP2021124178A; DK3862587T3; CN113217544A; US20210246944A1; US11441607B2; CN113217544B

Abstract

Provided is a sliding member (1) for a thrust bearing. The sliding member includes a back-metal layer (2) and a sliding layer (3), and has a partially annular shape. In a center line region of the sliding layer, the sliding layer (3) includes a synthetic resin (4) and has a sliding surface (30). The sliding layer (3) has a linear expansion coefficient KS in a direction parallel to a circumferential direction of the sliding member, a linear expansion coefficient KJ in a direction parallel to a radial direction of the sliding member, and a linear expansion coefficient KT in a direction perpendicular to the sliding surface (30), and the linear expansion coefficients KS, KJ, and KT satisfy the following relations (1) and (2): Relation (1): 1.1 ≤ KS/KJ ≤ 2; and Relation (2): 1.3 ≤ KT/{(KS + KJ)/2} ≤ 2.5.

Description

Technical Field

The present invention relates to a sliding member for a thrust bearing, and specifically relates to a sliding member that has a partially annular shape and includes a back-metal layer and a sliding layer including a synthetic resin composition. The present invention also relates to a thrust bearing including the sliding member.

Related Art

A thrust bearing has been used as a thrust bearing for a rotating shaft of an exhaust turbine, a large-sized power generator or the like. Such thrust bearing is configured that a plurality of bearing-pad-shaped sliding members having a partially annular shape are arranged in a circumferential direction to face a thrust collar surface of the rotating shaft. In such a tilting pad thrust bearing, the sliding members having a partially annular shape are supported so that the sliding members can slightly swing by a pivot with respect to the thrust collar surface of the shaft member. During steady operation of the exhaust turbine, the large-sized power generator or the like, a lubricant flows between the thrust collar surface of the shaft member and a sliding surface of the sliding member as the shaft member is rotated. At this time, the sliding member swings, and a gap between the sliding surface and the thrust collar surface of the shaft member is gradually reduced in a rotation direction. Thus, dynamic pressure is generated due to a wedge effect, and the lubricant forms a fluid film. The fluid film supports an axial load of the rotating shaft. In general, a swing center of a sliding member having a partially annular shape is located in a center portion of a circumferential direction and a center portion of a radial direction of the sliding member having the partially annular shape. A pressure distribution of the fluid film becomes maximum at the swing center of the sliding member having a partially annular shape (see JP 2015-94373A , paragraph [0020] and Fig. 2, for example).
As a sliding member of such a thrust bearing, a sliding member is known in which a sliding layer including a resin composition is coated on a back-metal layer made of metal (see JP 2001-124062A , for example). For example, JP 10-204282A , JP 2016-079391A and JP 2013-194204A describe a sliding layer including a resin composition in which fibrous particles such as glass fiber particles, carbon fiber particles or intermetallic compound fiber particles are dispersed in a synthetic resin to enhance a strength of the sliding layer.
Furthermore, JP 2018-146060A describes a method of manufacturing a resin composition sheet, including cooling the sheet in a forming mold and periodically changing a drawing speed of a drawing roll.

Summary of the Invention

During steady operation of the exhaust turbine, the large-sized power generator or the like, a fluid film of oil or the like is formed between the shaft member and the sliding member to prevent direct contact between the surface of the shaft member and the sliding surface the sliding member. However, during operation, in particular when the shaft rotates with a high speed, a centrifugal force has a large influence on the fluid film. In the vicinity of the swing center (in the vicinity of a center portion of the circumferential direction and a center portion of the radial direction of the sliding member having a partially annular shape), the pressure of the fluid film is maximum and a resin composition near the sliding surface is pressed by the pressure of the fluid film. Thus, the resin composition is elastically deformed in an outer diameter direction of the sliding member.
It was found that, in this case, if the resin composition of the sliding layer is thermally expanded, due to frictional heat generated by sliding, in an almost isotropic manner in an in-plane direction of the sliding surface, damage such as a crack that extends in a substantially circumferential direction is highly likely to occur on the surface of the sliding layer, when the resin composition is elastically deformed due to the pressure of the fluid film.
Furthermore, another problem has been found that, when an amount of thermal expansion of the resin composition of the sliding layer is approximately same between the in-plane direction of the sliding surface and a direction perpendicular to the sliding surface (thickness direction), shear failure is more likely to occur at an interface between the back-metal layer made of metal and the sliding layer.
Thus, an object of the present invention is to overcome the disadvantages of the conventional technique and provide a sliding member that is less likely to be subjected to damage such as a crack on a surface of a sliding layer and shear failure between the sliding layer and a back-metal layer, during the operation of a bearing device
According to an aspect of the present invention, provided is a sliding member for a thrust bearing. The sliding member includes a back-metal layer and a sliding layer on the back-metal layer, and has a partially annular shape. The sliding layer includes a synthetic resin and has a sliding surface. In a center line region of the sliding layer, the sliding layer has a linear expansion coefficient KS in a direction parallel to a circumferential direction of the sliding member, a linear expansion coefficient KJ in a radial direction of the sliding member, and a linear expansion coefficient KT in a direction perpendicular to the sliding surface, and KS, KJ, and KT satisfy the following relations (1) and (2): $1.1 \leq KS / KJ \leq 2;$
and $1.3 \leq KT / \{(KS + KJ) / 2\} \leq 2.5.$
According to an embodiment of the present invention, KS and KJ of the sliding layer preferably satisfy the following relation (3): $1.1 \leq KS / KJ \leq 1.7.$
According to an embodiment of the present invention, the synthetic resin preferably includes one or more selected from polyether ether ketone, polyether ketone, polyether sulfone, polyamidimide, polyimide, polybenzimidazole, nylon, phenol, epoxy, polyacetal, polyphenylene sulfide, polyethylene, and polyetherimide.
According to an embodiment of the present invention, the sliding layer preferably further includes 1 to 20 volume % of one or more solid lubricants selected from graphite, molybdenum disulfide, tungsten disulfide, boron nitride, and polytetrafluoroethylene.
According to an embodiment of the present invention, the sliding layer preferably further includes 1 to 10 volume % of one or more fillers selected from CaF₂, CaCO₃, talc, mica, mullite, iron oxide, calcium phosphate, potassium titanate, and Mo₂C.
According to an embodiment of the present invention, the sliding layer preferably further includes 1 to 35 volume % of one or more types of fibrous particles selected from glass fiber particles, ceramic fiber particles, carbon fiber particles, aramid fiber particles, acrylic fiber particles, and polyvinyl alcohol fiber particles.
According to an embodiment of the present invention, the back-metal layer preferably has a porous metal portion on a surface which is an interface between the back-metal layer and the sliding layer.
According to another aspect of the present invention, provided is a thrust bearing including a plurality of the sliding members described above.
A configuration and advantages of the present invention are described in detail below with reference to the accompanying drawings. The drawings illustrate embodiments merely for illustration purpose, and the present invention is not limited to the embodiments.

Brief Description of the Drawings

Fig. 1 shows a cross section of a sliding member according to an embodiment of the present invention.
Fig. 2 shows a cross section of a sliding member according to another embodiment of the present invention.
Fig. 3 is a schematic diagram of an embodiment of the sliding member according to the present invention.
Fig. 4 is a schematic diagram showing an image of a molecular chain (bent structure) of a resin.
Fig. 5 is a view showing a flow of resin.
Fig. 6 shows a VI-VI cross section of a resin sheet in Fig. 5.
Fig. 7 is a plan view of a sliding surface of the sliding member for showing a center line region.

Detailed Description of the Embodiment

Fig. 3 schematically shows an embodiment of a sliding member 1 having a partially annular shape according to the present invention. The sliding member 1 has a flat shape, and a surface of the flat shape has a shape obtained by cutting an annular ring (hereinafter referred to as "original annular ring") along two lines extending in a radial direction, that is, a partially annular shape. The partially annular shape preferably has a center angle of 25° to 60°, but the center angle of the partially annular shape is not limited to these angles. The sliding member 1 is configured such that a sliding layer 3 is formed on a back-metal layer 2 having a flat and partially annular shape. A surface of the sliding layer 3 having a partially annular shape is a sliding surface 30.
Herein, a "circumferential direction" of the partially annular shape is a direction corresponding to a circumferential direction of the original annular ring, and a "radial direction" of the partially annular shape is a direction corresponding to a radial direction of the original annular ring. The circumferential direction of the partially annular shape is also referred to as "S direction", and the radial direction of the partially annular shape is also referred to as "J direction". Furthermore, a thickness direction of the partially annular shape, that is, a direction perpendicular to the surface (sliding surface 30) of the partially annular shape is referred to as "vertical direction" (T direction). Furthermore, an imaginary radial line that passes through a circumferential center of the partially annular shape is referred to as "center axis" or "center line". When the sliding member 1 is used as a bearing, a shaft member which is a counter member slides in the "circumferential direction", and thus the "circumferential direction" is a sliding direction.
Next, a "center line region" of the sliding layer 3 is described. Fig. 7 is a plan view of the sliding layer 3 of the sliding member 1 viewed from the sliding surface 30 side. The sliding surface 30 has the same partially annular shape as the sliding member 1, and a center axis 34 can be defined as described above. When a circumferential angle is defined as an angle formed by two straight lines extending in the radial direction, a region between two imaginary radial lines 35 separated from each other by a circumferential angle (θ1) of ±3° with respect to the center axis 34 (an angle formed by the radial lines 35, i.e., the circumferential angle is 6°) is defined as "center line region 31". That is, the "center line region 31" is a region surrounded by the two imaginary radial lines 35 and an outer periphery and an inner periphery of the sliding layer 3.
The "center line region 31" is not limited to the sliding surface 30, and includes a volume of a portion extending along the entire thickness of the sliding layer 3.
Fig. 1 schematically shows a cross section of the sliding member 1 according to the present invention. The sliding member 1 includes the sliding layer 3 including a synthetic resin 4 on the back-metal layer 2. The surface of the sliding layer 3 (on a side opposite to the back-metal layer) functions as the sliding surface 30. The cross section shown in Fig. 1 is a cross section of the sliding member 1 in a direction perpendicular to the sliding surface 30.
The synthetic resin 4 preferably includes one or more selected from polyether ether ketone, polyether ketone, polyether sulfone, polyamidimide, polyimide, polybenzimidazole, nylon, phenol, epoxy, polyacetal, polyphenylene sulfide, polyethylene, and polyetherimide.
The sliding layer 3 may further include 1 to 20 volume % of one or more solid lubricants selected from graphite, molybdenum disulfide, tungsten disulfide, boron nitride, and polytetrafluoroethylene. The solid lubricant preferably has an average grain size of 0.5 to 20 µm. The sliding layer including the solid lubricant can have better sliding properties. The sliding layer 3 may further include 1 to 10 volume % of one or more fillers selected from CaF₂, CaCO₃, talc, mica, mullite, iron oxide, calcium phosphate, and Mo₂C (molybdenum carbide). The filler preferably has an average grain size of 0.1 to 10 µm. The sliding layer including the filler can have higher wear resistance.
The sliding layer 3 may further include 1 to 35 volume % of fibrous particles dispersed in the synthetic resin 4. The fibrous particles are preferably one or more types of fibrous particles selected from glass fiber particles, ceramic fiber particles, carbon fiber particles, aramid fiber particles, acrylic fiber particles, polyvinyl alcohol fiber particles. The sliding layer including the fibrous particles can have higher strength.
The fibrous particles may have an average grain size of 0.1 to 25 µm (the grain size of each of the fibrous particles is a diameter of a perfect circle having an area equal to an area of the fibrous particle measured in cross-sectional observation, i.e., "equivalent circle diameter"). When the sliding member is used in a bearing device configured such that a high load is applied to the sliding layer, the sliding layer preferably includes fibrous particles having an average grain size of not less than 0.1 µm and less than 5 µm and a major axis length of not more than 15 µm. If the sliding layer includes fibrous particles having a major axis length of more than 15 µm, in some cases, a crack occurs in the large fibrous particles having a major axis length of more than 15 µm and exposed on the sliding surface, and the fibrous particles fall into a gap between the sliding surface and a surface of the shaft member, resulting in damage to the sliding surface. On the other hand, in the case of the sliding layer including fibrous particles having a major axis length of not more than 15 µm, even when the fibrous particles are exposed on the sliding surface, a crack is less likely to occur in the fibrous particles.
The back-metal layer 2 may be made of an Fe alloy such as hypoeutectoid steel or stainless steel, or a Cu alloy.
The sliding layer 3 preferably has a thickness (i.e., a distance in a direction perpendicular to the sliding surface 30 from the sliding surface 30 to an interface 7 between the sliding layer 3 and the back-metal layer 2) of 0.5 to 6 mm.
In the center line region 31 of the sliding layer 3, the sliding layer 3 has a linear expansion coefficient KS in the "circumferential direction" (S direction) of the sliding member 1, a linear expansion coefficient KJ in the "radial direction" (J direction) of the sliding member 1, and a linear expansion coefficient KT in the "vertical direction" (T direction) perpendicular to the sliding surface 30, and KS, KJ, and KT of the sliding layer 3 satisfy the following relations (1) and (2): $1.1 \leq KS / KJ \leq 2;$
and $1.3 \leq KT / \{(KS + KJ) / 2\} \leq 2.5.$
In other words, in the center line region 31 of the sliding layer 3, the linear expansion coefficient KS of the sliding layer in the "circumferential direction" (S direction) of the sliding member is 1.1 to 2 times the linear expansion coefficient KJ of the sliding layer in the "radial direction" (J direction) of the sliding member, and the linear expansion coefficient KT of the sliding layer in the "vertical direction" (T direction) perpendicular to the sliding surface is 1.3 to 2.5 times an average value of the linear expansion coefficient KS of the sliding layer in the "circumferential direction" (S direction) of the sliding member and the linear expansion coefficient KJ of the sliding layer in the "radial direction" (J direction) of the sliding member.
The linear expansion coefficients KS, KJ, and KT of the sliding layer 3 are each an average linear expansion coefficient at a temperature of 23°C to 100°C.
The linear expansion coefficient KS in the "circumferential direction" (S direction) of the sliding member is preferably 1.1 to 1.7 times the linear expansion coefficient KJ in the "radial direction" (J direction) of the sliding member (i.e., 1.1 ≤ KS/KJ ≤ 1.7).
It is known that synthetic resins have a large amount of thermal expansion. A synthetic resin is composed of a large number of molecular chains (high polymers) by which a large number of resin molecules are linked together, and the molecular chains of the resin are merely connected by the Van der Waals force and weakly bonded to each other. Thus, when the temperature increases, a gap (distance) between the molecular chains is greatly increased. On the other hand, an amount of thermal expansion in a longitudinal direction of the molecular chains of the resin connected by a covalent bond is small. When an external force applied to the synthetic resin causes breakage, breakage mainly occurs between the weakly bonded molecular chains of the resin, and the molecular chain itself is less likely to be broken.
A swing center of the sliding member 1 having a partially annular shape is located in the vicinity of a center portion of the circumferential direction and a center portion of the radial direction of the sliding member 1. During operation of a bearing device, high pressure of a fluid film on which a centrifugal force acts is applied to a portion of the sliding surface 30 of the sliding layer 3 near the swing center. Accordingly, an external force generated by the pressure of the fluid film is largest near the swing center, and the external force is most applied in the radial direction (i.e., center axis direction) due to an influence of the centrifugal force generated in the fluid film. Thus, the synthetic resin 4 of the sliding layer 3 near the center axis 34 is elastically deformed in the radial direction J. Furthermore, the shaft member is rotated at a high speed, and this causes a temperature of the fluid film to increase, and accordingly, a temperature of the sliding layer 3 of the sliding member 1 also becomes high. At this time, if an amount of thermal expansion of the synthetic resin 4 of the sliding layer 3 in the radial direction J of the sliding member 1 having a partially annular shape is large near the center axis 34 of the sliding layer 3, a large gap is generated between molecular chains (linear portions 42) of the synthetic resin, and the external force due to the pressure of the fluid film is more likely to cause breakage. Thus, damage such as a crack that extends in a substantially circumferential direction from the broken portion as a starting point may occur on the surface of the sliding layer.
In the center line region 31 of the sliding layer 3 of the sliding member 1 of the present invention, the linear expansion coefficient KS of the sliding layer in the "circumferential direction" (S direction) of the sliding member is 1.1 to 2 times the linear expansion coefficient KJ of the sliding layer in the "radial direction" (J direction) of the sliding member, and the linear expansion coefficient KT of the sliding layer in the "vertical direction" (T direction) perpendicular to the sliding surface 30 is 1.3 to 2.5 times the average value of the linear expansion coefficient KS of the sliding layer in the "circumferential direction" (S direction) of the sliding member and the linear expansion coefficient KJ of the sliding layer in the "radial direction" (J direction) of the sliding member. This leads to a large amount of thermal expansion of the sliding layer 3 in the circumferential direction (S direction) and the vertical direction (T direction) and prevention of thermal expansion of the sliding layer 3 in the radial direction (J direction). Thus, even when an external force in the center axis direction (radial direction, S direction) is applied from the fluid film to the sliding surface 30, a crack that extends in a substantially circumferential direction is less likely to occur on the sliding surface 30.
If an amount of thermal expansion of the sliding layer 3 in an in-plane direction (the circumferential direction S and the radial direction J) of the sliding surface 30 is large, shearing stress is generated, due to a difference in the amount of thermal expansion, at the interface between the sliding layer 3 and the back-metal layer 2 made of metal, and shear failure may occur between the sliding layer 3 and the back-metal layer 2.
In the sliding layer 3 of the sliding member 1 of the present invention, the linear expansion coefficient KT of the sliding layer in the "vertical direction" (T direction) perpendicular to the sliding surface 30 is 1.3 to 2.5 times the average value of the linear expansion coefficient KS of the sliding layer in the "circumferential direction" (S direction) of the sliding member and the linear expansion coefficient KJ of the sliding layer in the "radial direction" (J direction) of the sliding member. This leads to a large amount of thermal expansion of the sliding layer 3 in the "vertical direction" (T direction) and prevention of thermal expansion of the sliding layer 3 in a direction parallel to the sliding surface 30. Thus, shear failure is less likely to occur between the sliding layer 3 and the back-metal layer 2.
An anisotropy of thermal expansion of the sliding layer 3 is presumably caused by orientation of the molecular chains of the resin molecules. As shown in Fig. 4, a molecular chain 41 of the resin molecule in the synthetic resin 4 of the sliding layer 3 has a bent structure (bent crystal) having a plurality of linear portions 42. In a longitudinal direction L1 of the linear portion 42, thermal expansion is less likely to occur. In a direction L2 orthogonal to the longitudinal direction of the linear portion 42, a gap is formed between the linear portions 42, and thus thermal expansion is more likely to occur. The anisotropy of thermal expansion of the sliding layer 3 of the sliding member 1 of the present invention is presumably caused by the fact that, in the center line region 31 of the sliding layer 3, a ratio of the molecular chains 41 of the resin in the sliding layer 3 that are oriented in the longitudinal direction L1 of the linear portion 42 is different between the "radial direction" (J direction) side, the "circumferential direction" (S direction) side, and the "vertical direction" (T direction) side. The anisotropy of thermal expansion of the sliding layer 3 is generated during manufacture of a resin composition sheet (described later).
A different configuration from above-described configuration of the present invention has the following problems.

If in the center line region 31 of the sliding layer 3, the linear expansion coefficient KS of the sliding layer in the "circumferential direction" (S direction) is larger than the linear expansion coefficient KJ of the sliding layer in the "radial direction" (J direction) but is less than 1.1 times the linear expansion coefficient KJ, the effect of preventing thermal expansion of the sliding layer in the "radial direction" (J direction) is insufficient, and a crack is more likely to occur on the sliding surface.
If in the center line region 31 of the sliding layer 3, the linear expansion coefficient KS of the sliding layer in the "circumferential direction" (S direction) exceeds 2 times the linear expansion coefficient KJ of the sliding layer in the "radial direction" (J direction), due to an excessively large amount of thermal expansion of the sliding layer in the "circumferential direction" (S direction), a crack that extends in a substantially radial direction may occur on the sliding surface.
If in the center line region 31 of the sliding layer 3, the linear expansion coefficient KT in the "vertical direction" (T direction) perpendicular to the sliding surface is larger than the average value of the linear expansion coefficient KS in the "circumferential direction" (S direction) of the sliding member and the linear expansion coefficient KJ in the "radial direction" (J direction) of the sliding member but is less than 1.3 times the average value of the linear expansion coefficient KS and the linear expansion coefficient KJ, the effect of preventing thermal expansion of the sliding layer in a direction parallel to the sliding surface is insufficient, and thus a crack is more likely to occur on the sliding surface, and shear failure is more likely to occur between the sliding layer 3 and the back-metal layer 2. Furthermore, if in the sliding layer 3, the linear expansion coefficient KT in the "vertical direction" (T direction) perpendicular to the sliding surface exceeds 2.5 times the average value of the linear expansion coefficient KS in the "circumferential direction" (S direction) of the sliding member and the linear expansion coefficient KJ in the "radial direction" (J direction) of the sliding member, due to an excessively large amount of thermal expansion of the sliding layer in the "vertical direction" (T direction), a crack may occur inside the sliding layer.
Unlike the configuration of the present invention, in a case of a sliding member in which isotropic thermal expansion occurs throughout a sliding layer, during operation of a bearing device, a resin composition near a surface of the sliding layer of the sliding member is thermally expanded in the same manner in the circumferential direction and in the radial direction, and during elastic deformation in the radial direction due to an external force from a fluid film, a crack occurs between molecular chains of a resin of the sliding layer. Thus, damage such as a crack is more likely to occur on the surface of the sliding layer, and due to a difference in the amount of thermal expansion between the sliding layer and a back-metal layer, damage such as shear failure is more likely to occur at an interface between the sliding layer and the back-metal layer.

The back-metal layer 2 may have a porous metal portion 5 at the interface between the back-metal layer 2 and the sliding layer 3. Fig. 2 schematically shows a circumferential cross section of an example of the sliding member 1 including the back-metal layer 2 having the porous metal portion 5. The porous metal portion 5 provided on the surface of the back-metal layer 2 can improve bonding strength between the sliding layer and the back-metal layer. This is due to an anchor effect by impregnating into pores of the porous metal portion with the composition constituting the sliding layer. The anchor effect can enhance a bonding force between the back-metal layer and the sliding layer.
The porous metal portion can be formed by sintering a metal powder made of Cu, a Cu alloy, Fe, an Fe alloy or the like on a surface of a metal plate or strip or the like. The porous metal portion may have a porosity of approximately 20 to 60%. The porous metal portion may have a thickness of approximately 50 to 500 µm. In this case, the sliding layer coated on a surface of the porous metal portion may have a thickness of approximately 0.5 to 6 mm. The dimensions described above are merely examples. The present invention is not limited to the above values, and the dimensions may be changed to other dimensions.
The sliding member 1 may be used, for example, in a thrust bearing. For example, this bearing includes a housing having an annular recessed portion. A plurality of the sliding members are arranged in the circumferential direction in the annular recessed portion, and the sliding members support a thrust collar surface of a counter shaft which is a shaft member . The partially annular shape (curvature, size, and the like) of the sliding member is designed to match the annular recessed portion and the shaft member. However, the sliding member may also be used in a bearing having a different configuration or for other sliding applications.
The present invention also encompasses a thrust bearing including a plurality of the sliding members.
The above sliding member is described in detail below referring to a manufacturing process.

(1) Preparation of synthetic resin raw material particles

A raw material of the synthetic resin may be one or more selected from polyether ether ketone, polyether ketone, polyether sulfone, polyamidimide, polyimide, polybenzimidazole, nylon, phenol, epoxy, polyacetal, polyphenylene sulfide, polyethylene, and polyetherimide. Optionally, fibrous particles, a solid lubricant, a filler, or the like may be dispersed in the synthetic resin.

(2) Manufacture of synthetic resin sheet

A synthetic resin sheet is produced from the above raw material and the like with use of a melt-kneading machine, a supplying mold, a sheet forming mold, and a cooling roll.

"Melt-kneading machine"

The synthetic resin raw material particles and raw materials of other optional materials (fibrous particles, solid lubricant, filler, and the like) are mixed while being heated at a temperature of 230°C to 390°C with use of the melt-kneading machine to produce a resin composition in a molten state. The synthetic resin raw material particles include a plurality of resin molecules having a structure in which a molecular chain is bent to have a plurality of linear portions. The resin molecules entangled with each other are disentangled by the melt-kneading process. The resin composition is extruded under constant pressure from the melt-kneading machine.

"Supplying mold"

A certain amount of resin composition extruded from the melt-kneading machine is constantly supplied to the sheet forming mold via the supplying mold. The supplying mold includes a heating heater for heating the resin composition passing through the supplying mold at a temperature of 385°C to 400°C to maintain the resin composition in a molten state.

"Sheet forming mold"

The resin composition is formed into a sheet shape by the sheet forming mold. The resin composition in a molten state supplied from the supplying mold to the sheet forming mold is formed into a sheet shape, and is gradually cooled naturally while being moved toward an outlet side in the sheet forming mold to form a sheet in a semi-molten state.

"Cooling roll"

The resin composition sheet in a semi-molten state is drawn from the "sheet forming mold" while being continuously brought into contact with the cooling roll to be cooled. The cooling roll includes at least a pair of rolls (upper roll and lower roll) that move the resin composition sheet while pressing the resin composition sheet from both sides, i.e., an upper surface side and a lower surface side. After being drawn from the cooling roll, the resin composition sheet in a semi-molten state becomes a sheet in a completely solid state. A temperature of the cooling roll can be controlled by an electric heater incorporated in the roll. Furthermore, the cooling roll can be rotationally driven by being controlled by an electric motor. The resin composition sheet has a thickness, for example, of 1 to 7 mm. The resin composition sheet in a solid state is cut into a size corresponding to that of a back metal used at a later-described coating step.

(3) Back metal

The back-metal layer may be a metal plate made of an Fe alloy such as hypoeutectoid steel or stainless steel, Cu, a Cu alloy, or the like. A porous metal portion may be formed on a surface of the back-metal layer, i.e., an interface between the back-metal layer and the sliding layer. In that case, the porous metal portion may have the same composition as the back-metal layer. Alternatively, the porous metal portion may have a different composition from the back-metal layer or may be made of a different material from the back-metal layer.

(4) Coating and forming step

The resin composition sheet is bonded to one surface of the back-metal layer or the porous metal portion of the back metal. At that time, the resin composition sheet is placed so that the direction in which the resin composition sheet has been drawn at the sheet forming step is parallel to a center axis of a partially annular shape of an end product. Subsequently, the composition is formed by pressure pressing into a shape for use, for example, a partially annular shape. Then, the sliding layer and the back metal are processed or cut so that the composition has a uniform thickness.
Next, a method of controlling the anisotropy of the linear expansion coefficient is described. The anisotropy of the linear expansion coefficient is controlled by controlling a rotational speed of the cooling roll in the process of manufacturing a resin composition sheet. Specifically, the rotational speed of the cooling roll is set so that a ratio V₂/V₁ is 0.8 to 0.9, where V₁ represents a speed at which the sheet in a semi-molten state is extruded from the sheet forming mold, and V₂ represents a speed of the sheet in a completely solidified state drawn from the cooling roll. The ratio of 0.8 to 0.9 is a ratio between v₁ and v₂ (v₂/v₁ = V₂/V₁ = 0.8 to 0.9), where v₁ represents a volume per unit time of the resin composition sheet extruded from the sheet forming mold by pressure from the supplying mold and supplied to the cooling roll, and v₂ represents a volume per unit time of the resin composition sheet drawn from the cooling roll. Due to a difference between the volume v₁ of the resin composition sheet supplied to the cooling roll and the volume v₂ of the resin composition sheet drawn from the cooling roll, a resin sump 15 of the semi-molten resin composition is formed at an inlet of the upper cooling roll.
The resin sheet in a semi-molten state is solidified while being brought into contact with the cooling roll to be cooled. The speed of the cooling roll is set to be lower than the speed at which the resin composition in a semi-molten state is extruded from the mold. Thus, the resin composition in a semi-molten state that has not been completely solidified tends to be accumulated (hereinafter referred to as "resin sump") at the inlet of the upper cooling roll. Fig. 5 schematically shows this state. A resin composition sheet 20 is extruded in a direction (extrusion direction 10) from the right side toward the left side of Fig. 5. An arrow 11 indicates a flow of semi-molten resin composition. The semi-molten resin composition 11 flowing from a sheet forming mold 12 (from the right side of Fig. 5) forms a certain amount of resin sump 15 on an inlet side of an upper cooling roll 13. The resin composition 11 in a semi-molten state (hereinafter referred to as "semi-molten resin composition") that forms the resin sump 15 is pushed into the resin composition sheet while being rotated in the same direction as the extrusion direction and accumulated. A part of the semi-molten resin composition 11 pushed into the resin composition sheet is spread and flows toward both ends in a width direction of the resin composition sheet and starts to be solidified (Fig. 6). It has been found that when the molten resin flows, the longitudinal directions of the linear portions of the molecular chains of the resin are more likely to be oriented in the flow direction. Thus, the longitudinal directions of the linear portions of the molecular chains of the resin are more likely to be oriented also in the width direction of the resin composition sheet (direction perpendicular to the extrusion direction 10).
In a conventional technique, the speed of the cooling roll is set to the same speed as the speed at which the resin composition in a semi-molten state is extruded from the mold. In this case, the semi-molten resin composition flowing from the sheet forming mold constantly flows in a single direction toward an outlet side of the cooling roll without forming a resin sump on the inlet side of the cooling roll. Thus, the longitudinal directions of the linear portions of the molecular chains of the resin are mainly oriented in the extrusion direction of the resin composition sheet and are less likely to be oriented in the width direction of the resin composition sheet.
Furthermore, JP 2018-146060A discloses that a resin composition sheet is manufactured by performing cooling in a forming mold and periodically changing a drawing speed of a drawing roll. When a resin composition sheet is manufactured in this manner, the longitudinal directions of linear portions of molecular chains of the resin are more likely to be mainly oriented in a thickness direction of the resin composition sheet.
Next, a method of measuring the linear expansion coefficient of the sliding layer is described. From the sliding layer, a rectangular-parallelepiped-shaped specimen having a size of 4 mm × 5 mm (measurement direction) × 10 mm is produced to measure, in the center line region 31 of the sliding layer 3, the linear expansion coefficient KS of the sliding layer in a direction parallel to the circumferential direction and the linear expansion coefficient KJ of the sliding layer in a direction parallel to the radial direction. Furthermore, from the sliding layer, a rectangular-parallelepiped-shaped specimen having a size of 5 mm × 5 mm × 4 mm (measurement direction) is produced to measure, in the center line region 31 of the sliding layer 3, the linear expansion coefficient KT of the sliding layer in a direction perpendicular to the sliding surface. Then, in the specimens, the linear expansion coefficients KS, KJ, and KT can be measured under conditions shown in Table 1 with use of a thermal expansion measuring device (TMA/SS7100: manufactured by SII). These linear expansion coefficients are an average linear expansion coefficient in a test temperature range.
The specimens are obtained at arbitrary positions in the center line region 31. Table 1

Test load (compressive load) 4 kPa

Temperature increasing rate 5 °C/minute

Measurement atmosphere Nitrogen (100ml/minute)

Test temperature range 23 to 100°C

Examples

Examples 1 to 6 of the sliding member including the back-metal layer and the sliding layer according to the present invention and Comparative Examples 11 to 14 were produced in the following manner. Table 2 shows composition of the sliding layer of the sliding members of Examples and Comparative Examples.

Table 2

Sample		Composition (volume %)							Linear expansion Coefficient (×10⁵/°C)			KS/KJ	KT/ ((KS+KJ)/2)	Sliding test results
		PEEK	PEK	Ceramic fibers	Carbon fibers	Graphite	PTFE	CaF2	KS	KJ	KT			Conditions 1		Conditions 2
		PEEK	PEK	Ceramic fibers	Carbon fibers	Graphite	PTFE	CaF2	KS	KJ	KT			Presence of cracks	Presence of shear failure at interface	Presence of cracks	Presence of shear failure at interface
Examples	1	100							6.8	3.6	6.8	1.9	1.3	Not present	Not present	Present	Not present
	2	100							4.9	3.3	7.9	1.5	1.9	Not present	Not present	Not present	Not present
	3	100							3.6	3.2	8.6	1.1	2.5	Not present	Not present	Not present	Not present
	4		100						5	3.6	7.7	1.4	1.8	Not present	Not present	Not present	Not present
	5	78			20		2		4.6	2.8	6.3	1.6	1.7	Not present	Not present	Not present	Not present
	6	78		15		5		2	4.3	2.9	6.4	1.5	1.8	Not present	Not present	Not present	Not present
Comparative Examples	11	100							77	3.7	6.3	2.1	1.1	Present	Not present	-	-
	12	100							3.3	3.3	8.7	1.0	2.6	Present	Not present	-	-
	13	80		15		5		2	2.9	4.3	6.4	0.7	1.8	Present	Not present	-	-
	14	78			20		2		4.7	7.7	3.8	0.6	0.6	Present	Present	-	-

In Examples 1 to 6 and Comparative Examples 11 to 14, PEEK (polyether ether ketone) particles or PEK (polyether ketone) particles were used as a raw material of the synthetic resin. In Example 6 and Comparative Example 13, the raw material of the synthetic resin included ceramic fibers. As the ceramic fibers, fibrous particles of potassium titanate having an average grain size of approximately 5 µm were used. In Example 5 and Comparative Example 14, the raw material of the synthetic resin included carbon fibers. As the carbon fibers, fibrous particles having an average grain size of 5 µm were used.
In Examples 5 and 6 and Comparative Examples 13 and 14, the raw material of the synthetic resin included a solid lubricant (graphite, PTFE), and raw material particles of the solid lubricant had an average grain size of 10 µm. In Example 6 and Comparative Example 13, the raw material of the synthetic resin included a filler (CaF₂), and raw material particles of the filler had an average grain size of 10 µm.
The above raw materials were weighed at a composition ratio shown in Table 2, and the compositions were pelleted in advance. The pellets were inserted into a melt-kneading machine in which a heating temperature was set at 350 to 390°C, and the pellets were sequentially passed through a supplying mold, a sheet forming mold, and a cooling roll to produce a resin composition sheet. A rotational speed of the cooling roll was set so that a ratio V₂/V₁ was 0.90 in Example 1, 0.85 in Examples 2 and 4 to 6, and 0.80 in Example 3 to produce a resin composition sheet, where V₁ represents a speed at which the sheet in a semi-molten state was extruded from the sheet forming mold, and V₂ represents a speed of the sheet in a completely solidified state drawn from the cooling roll. The rotational speed of the cooling roll was set so that the ratio V₂/V₁ was 1 in Comparative Example 11, 0.75 in Comparative Example 12, and 0.85 in Comparative Example 13 to produce a resin composition sheet. In Comparative Example 14, a resin composition sheet was produced by using the method described in JP 2018-146059A .
Next, the resin composition sheet was coated on one surface of a back-metal layer made of an Fe alloy, and was then processed into a partially annular shape. Subsequently, cutting processing was performed so that the composition on the back-metal layer had a predetermined thickness. In Examples 1 to 5 and Comparative Examples 11 to 14, the back-metal layer was made of an Fe alloy. In Example 6, the back-metal layer had a porous sintered portion made of a Cu alloy on the surface of the portion made of an Fe alloy. For the sliding members of Examples 1 to 6 and Comparative Examples 11, 12, and 14, an extrusion direction of the resin composition sheet at the sheet forming step was set to be parallel to a center axis direction of the partially annular shape. For the sliding member of Comparative Example 13, the extrusion direction of the resin composition sheet at the sheet forming step was set to be perpendicular to the center axis direction of the partially annular shape.
In the sliding members produced in Examples 1 to 6 and Comparative Examples 11 to 14, the sliding layer had a thickness of 5 mm, and the back-metal layer had a thickness of 10 mm.
In the sliding members produced in Examples and Comparative Examples, in the center line region of the sliding layer, the linear expansion coefficient KS of the sliding layer in the circumferential direction, the linear expansion coefficient KJ of the sliding layer in the radial direction, and the linear expansion coefficient KT of the sliding layer in the vertical direction were measured by the measurement method described above. These linear expansion coefficients were an average linear expansion coefficient at 23°C to 100°C. In Table 2, with regard to the measurement results of Examples and Comparative Examples, a column "KS" indicates the linear expansion coefficient KS of the sliding layer in the circumferential direction, a column "KJ" indicates the linear expansion coefficient KJ of the sliding layer in the radial direction, and a column "KT" indicates the linear expansion coefficient KT of the sliding layer in the vertical direction.
Furthermore, with regard to the measurement results of Examples and Comparative Examples, a column "KS/KJ" in Table 2 indicates a ratio (KS/KJ) between the linear expansion coefficient KS of the sliding layer in the circumferential direction and the linear expansion coefficient KJ of the sliding layer in the radial direction, and a column "KT/((KS + KJ)/2)" in Table 2 indicates a ratio (KT/(KS + KJ)/2) between the linear expansion coefficient KT of the sliding layer in the vertical direction and an average value of the linear expansion coefficient KJ of the sliding layer in the radial direction and the linear expansion coefficient KS of the sliding layer in the circumferential direction.

The plurality of sliding members formed into a partially annular shape were combined to form a thrust bearing, and the thrust bearing was subjected to a sliding test under two conditions shown in Table 3. Under conditions 2, a rotational speed of the shaft member was higher than under conditions 1. These conditions simulated a sliding state during normal operation of a bearing device. In Examples and Comparative Examples, a plurality of portions on a surface of the sliding layer in the center line region after the sliding test were measured with use of a roughness measuring device and evaluated for the presence of cracks. In a column "Presence of cracks" in Table 2, "Present" indicates that a crack having a depth of not less than 5 µm was observed on the surface of the sliding layer, and "Not present" indicates that no such crack was observed. Furthermore, a specimen of the sliding member after the sliding test was cut in a direction parallel to the center axis of the sliding member and perpendicular to the sliding surface, and the specimen was observed for the presence of "shear failure" at an interface between the sliding layer and the back metal with use of an optical microscope. In a column "Presence of shear failure at interface" in Table 2, "Present" indicates that "shear failure" was observed at the interface, and "Not present" indicates that no "shear failure" was observed at the interface.

Table 3

	Conditions 1	Conditions 2
Testing device	thrust tester	thrust tester
Load
	30 MPa	30 MPa
Rotational speed	3000 r/minute	6000 r/minute
Operation time	24 hours	24 hours
Oil	VG46	VG46
Oil supply amount during operation	50 L/minute	50 L/minute
Oil supply temperature	50 °C	50 °C
Counter shaft	SUJ2	SUJ2
Shaft roughness	0.2 Ra	0.2 Ra

As shown in the results in Table 2, Examples showed no crack on the surface of the sliding layer or no shear failure at the interface was observed after the sliding test under conditions 1. As described above, this is presumably because in the center line region of the sliding layer, the sliding layer had the anisotropy of thermal expansion that satisfied the above relations (1) and (2) in the circumferential direction, the radial direction, and the vertical direction. Furthermore, in Examples 2 to 6 in which the sliding layer had the anisotropy of thermal expansion that satisfied the above relation (3), no crack was observed on the surface of the sliding layer after the sliding test even under conditions 2 under which higher pressure was applied to the sliding layer.
On the other hand, in Comparative Example 11, the ratio (KS/KJ) between the linear expansion coefficient KS of the sliding layer in the circumferential direction and the linear expansion coefficient KJ of the sliding layer in the radial direction exceeded 2. Presumably due to an excessively large amount of thermal expansion of the sliding layer in the circumferential direction, a crack occurred on the sliding surface.
On the other hand, in Comparative Example 12, the ratio (KS/KJ) between the linear expansion coefficient KS of the sliding layer in the circumferential direction and the linear expansion coefficient KJ of the sliding layer in the radial direction was less than 1.1. Presumably due to an insufficient effect of preventing thermal expansion of the sliding layer in the radial direction, a crack occurred on the sliding surface. Furthermore, in Comparative Example 12, since the ratio (KT/(KS + KJ)/2) between the linear expansion coefficient KT of the sliding layer in the vertical direction and the average value of the linear expansion coefficient KJ of the sliding layer in the radial direction and the linear expansion coefficient KS of the sliding layer in the circumferential direction exceeded 2.5 times, a crack also occurred inside the sliding layer.
In Comparative Example 13, presumably since the ratio (KS/KJ) between the linear expansion coefficient KS of the sliding layer in the circumferential direction and the linear expansion coefficient KJ of the sliding layer in the radial direction was less than 1.1, a crack occurred on the sliding layer.
In Comparative Example 14, since the ratio (KS/KJ) between the linear expansion coefficient KS of the sliding layer in the circumferential direction and the linear expansion coefficient KJ of the sliding layer in the radial direction was less than 1.1, a crack occurred on the sliding layer. Furthermore, the ratio (KT/(KS + KJ)/2) between the linear expansion coefficient KT of the sliding layer in the vertical direction and the average value of the linear expansion coefficient KJ of the sliding layer in the radial direction and the linear expansion coefficient KS of the sliding layer in the circumferential direction was less than 1.3. Presumably due to an insufficient effect of preventing thermal expansion of the sliding layer in a direction parallel to the sliding surface, shear failure occurred at the interface between the sliding layer and the back metal.

Claims

A sliding member (1) for a thrust bearing, the sliding member comprising:
a back-metal layer (2); and

a sliding layer (3) on the back-metal layer (2),

wherein the sliding member has a partially annular shape,

wherein the sliding layer (3) has a sliding surface (30), and comprises:
a synthetic resin (4);

optionally 1 to 20 volume % of one or more solid lubricants selected from graphite, molybdenum disulfide, tungsten disulfide, boron nitride, and polytetrafluoroethylene;

optionally 1 to 10 volume % of one or more fillers selected from CaF₂, CaCO₃, talc, mica, mullite, iron oxide, calcium phosphate, potassium titanate, and Mo₂C; and

optionally 1 to 35 volume % of one or more types of fibrous particles selected from glass fiber particles, ceramic fiber particles, carbon fiber particles, aramid fiber particles, acrylic fiber particles, and polyvinyl alcohol fiber particles, and

wherein, in a center line region of the sliding layer, the sliding layer (3) has a linear expansion coefficient KS in a direction parallel to a circumferential direction of the sliding member, a linear expansion coefficient KJ in a direction parallel to a radial direction of the sliding member, and a linear expansion coefficient KT in a direction perpendicular to the sliding surface (30), and the linear expansion coefficients KS, KJ and KT satisfy the following relations (1) and (2): $1.1 \leq KS / KJ \leq 2;$
and $1.3 \leq KT / \{(KS + KJ) / 2\} \leq 2.5.$
The sliding member according to claim 1, wherein the linear expansion coefficients KS and KJ of the sliding layer (3) satisfy the following relation (3): $1.1 \leq KS / KJ \leq 1.7.$
The sliding member according to claim 1 or 2, wherein the synthetic resin (4) includes one or more selected from polyether ether ketone, polyether ketone, polyether sulfone, polyamidimide, polyimide, polybenzimidazole, nylon, phenol, epoxy, polyacetal, polyphenylene sulfide, polyethylene, and polyetherimide.
The sliding member according to any one of the preceding claims, wherein the back-metal layer (2) includes a porous metal portion (5) as an interface between the back-metal layer (2) and the sliding layer (3).
A thrust bearing comprising a plurality of the sliding members (1) according to any one of the preceding claims.