EP3853018A1 - Ballistic resistant insulated glazing units - Google Patents

Ballistic resistant insulated glazing units

Info

Publication number
EP3853018A1
EP3853018A1 EP19773063.3A EP19773063A EP3853018A1 EP 3853018 A1 EP3853018 A1 EP 3853018A1 EP 19773063 A EP19773063 A EP 19773063A EP 3853018 A1 EP3853018 A1 EP 3853018A1
Authority
EP
European Patent Office
Prior art keywords
laminated pane
glass sheets
pane
thickness
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19773063.3A
Other languages
German (de)
French (fr)
Inventor
Louis DELLIEU
Perrine LEYBROS
Julien JEANFILS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Glass Europe SA
Original Assignee
AGC Glass Europe SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AGC Glass Europe SA filed Critical AGC Glass Europe SA
Publication of EP3853018A1 publication Critical patent/EP3853018A1/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B32B17/10045Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet
    • B32B17/10055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet with at least one intermediate air space
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10128Treatment of at least one glass sheet
    • B32B17/10137Chemical strengthening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10174Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10743Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B5/00Doors, windows, or like closures for special purposes; Border constructions therefor
    • E06B5/10Doors, windows, or like closures for special purposes; Border constructions therefor for protection against air-raid or other war-like action; for other protective purposes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0407Transparent bullet-proof laminatesinformative reference: layered products essentially comprising glass in general B32B17/06, e.g. B32B17/10009; manufacture or composition of glass, e.g. joining glass to glass C03; permanent multiple-glazing windows, e.g. with spacing therebetween, E06B3/66

Definitions

  • the present invention relates to security insulated glazing units.
  • Safety glazing and projectile / ballistic resistant glazing are classes of optically transparent window products designed to protect occupants of buildings, transport vehicles, etc., from penetration by projectiles such as, but not limited to, windblown objects, bullets, and the like.
  • projectiles such as, but not limited to, windblown objects, bullets, and the like.
  • the outside surface of the window pane, the face receiving the incoming projectile is generally referred to as the attack face, and the innermost surface of the window pane closest to the occupants of the building, vehicle, etc., is referred to as the protective side.
  • BRG products are typically constructed from several layers of glass and/or plastics or polymers.
  • Conventional glass materials used for ballistic laminates include soda lime glass and borosilicate glass which are typically manufactured using a float process.
  • BRG window panes are very thick and heavy, and the overall thickness, number of glass, plastic, and/or interlayer sheets, and the specific weight (e.g. mass per unit area) of the construction can be varied to resist various threat levels.
  • threat levels are generally a function of the type of projectile, the mass of the projectile and its construction, and velocity obtained from the explosive charge in the respective cartridge as well as the impact of one or more projectiles (typically three projectiles) within a predetermined area.
  • Exemplary international ballistic standards include the European Standard (EN) 1063: 1999 Security Glazing Ballistic Standard.
  • the ballistic class additionally receives the rating "NS”. If glass splinters emerge on the protected side of the impact-resistant glass after the ballistic test explained in the standard, "S" is added to the test result.
  • Each conventional BRG construction has its advantages and disadvantages depending upon the respective constituent layers.
  • all glass constructions are generally durable (not susceptible to scratching or UV attack) and are clear with little visual distortion; however, all glass constructions are heavy and are generally the thickest constructions.
  • Acrylic constructions are relatively light but are not durable or optically clear without distortion.
  • Glass clad polycarbonate structures are generally lighter than all glass but suffer from optical visual distortions, and the polycarbonate layer is easily scratched.
  • the polycarbonate layer is usually treated with an anti- scratch surface coating if exposed on a surface of the respective laminate structure.
  • an additional UV coating is applied to stop detrimental yellowing of the polycarbonate material occurring with prolonged exposure to UV rays.
  • Such coatings generally increase the expense of polycarbonate -based BRG constructions.
  • conventional acrylic and polycarbonate layers are susceptible to chemical degradation, e.g., methanol, toluene, acetone, methylene chloride, and gasoline. Defects caused by such chemical degradation range from cracking to tacky surfaces and/or sheer layer destruction, each of which negatively affects optical transparency and threat protection performance of a respective window pane.
  • CT chemically tempered
  • a laminated glazing“5:15:15:15:15:5” (where means a layer of interlayer and the number is the thickness of the glass layer - This example is a 6 glass layers with 5 interlayers) is BR6 NS certified according to the test made regarding cited norms.
  • the double glazing 4:4/15/5:15:15:15:15:5 (where means a layer of interlayer, 715/” a gap of 15mm maintained by the spacer and the number is the thickness of the glass layer) is naturally BR6 NS certified without any complementary test.
  • the invention relates to an improved insulated glazing unit configured for resisting to a projectile (6) with an kinetic impact energy, E, comprised between 3100 J and 3350 J (3100 J ⁇ E ⁇ 3350 J), extending along a plane, P, defined by a longitudinal axis, x, and a vertical axis, y, comprising :
  • a front laminated pane, F facing the projectile, having a total thickness, ZF, and comprising m glass sheets f, each having a sheet thickness, Zf, bonded by m-1 polymer interlayers, each having a polymer thickness, Zfi, wherein m is a positive integer greater than or equal to 2 (m>2),
  • a back laminated pane B having a total thickness, ZB, comprising at least n glass sheets, each having a sheet thickness, Zb, bonded by n- 1 polymer interlayers, each having a polymer thickness, Zbi, wherein n is a positive integer greater than or equal to 2 and
  • the thicknesses are measured in the direction normal to the plane, P.
  • the total thickness of the front laminated pane, ZF equals the sum of the thicknesses of the m glass sheets and the m-1 polymer interlayers and the total thickness of the back laminated pane, ZB, equals the sum of the thicknesses of the n glass sheets and the n-1 polymer interlayers.
  • the invention relates also to a process to produce an insulated glazing unit according to a first aspect of the invention.
  • the solution as defined in the first aspect of the present invention is based on both panes can participate to the projectile resistance performance of the IGU.
  • the front and back panes of the IGU play two different role :
  • Front laminated pane (facing to the projectile) is dedicated for highly slowing down the bullet and absorbing the major part of its kinetic impact energy.
  • An interlayer cushion is a polymer interlayer with a thickness of at least 1.5 mm.
  • the standard thickness of one layer is 0.76 mm in some cases this thickness of 0.76 mm can be obtained by two thin layers of 0.38 mm.
  • several interlayers can be layered to obtain the desired thickness.
  • the insulated glazing unit is assumed to be resistant against a projectile with a given kinetic impact energy if the glazing does not have any "through" holes, from the front to the back.
  • the kinetic impact energy for a BR7 is the same than the one for a BR6 with a perforating element.
  • a second block or pane must be employed, the Back laminated pane and must exhibit at least one of the two following characteristics high rigidity or high stress at failure.
  • the first alternative will ensure that the second bloc will not admit a deformation which could lead to its breakage.
  • the second alternative will allow the second bloc to admit a bigger deformation than the one allowed in the first alternative without breakage. This second alternative leads to the decrease of the laminated thickness and requires to work with tempered glass.
  • the total thickness of the back laminated assembly, ZB is at most 0.4 of the sum of the total thickness of the front laminated pane, ZF, and the total thickness of the back laminated pane, ZB (ZB ⁇ 0.4 * (ZF + ZB)) and in that at least 2 glass sheets of the back laminated pane, ZB, are tempered.
  • the total thickness of the back laminated assembly, ZB is at most 0.3 of the sum of the total thickness of the front laminated pane, ZF, and the total thickness of the back laminated pane, ZB (ZB ⁇ 0.3 * (ZF + ZB)) and more preferably, the total thickness of the back laminated assembly, ZB, is at most 0.2 of the sum of the total thickness of the front laminated pane, ZF, and the total thickness of the back laminated pane, ZB (ZB ⁇ 0.2 * (ZF + ZB)). This allows to facilitate transport, handling, mounting,...
  • the thickness of a laminated pane is the sum of the thicknesses of the glass sheets added to the thicknesses of the interlayers.
  • Glass sheet comprised in a laminated pane can have a different thickness such as polymer interlayers.
  • Glass sheets of the IGU of the present invention within laminated assemblies can be chosen among all flat glass technologies, among them: float clear, extra-clear or coloured glass.
  • the term “glass” is herein understood to mean any type of glass or equivalent transparent material, such as a mineral glass.
  • the mineral glasses used may be irrespectively one or more known types of glass such as soda-lime-silica, aluminosilicate or borosilicate, crystalline and polycrystalline glasses.
  • the glass pane can be obtained by a floating process, a drawing process, a rolling process or any other process known to manufacture a glass pane starting from a molten glass composition.
  • the glass sheets can optionally be edge-ground.
  • the glass pane according to the invention is a pane of soda-lime-silica glass, aluminosilicate glass or borosilicate glass.
  • films such as low emissivity films, solar control films (a heat ray reflection films), anti-reflective films, anti- fog films, preferably a heat ray reflection film or a low emissivity film, can be provided on at least one of the inner sheet faces and/or outer sheet faces of the laminated panes.
  • Laminated panes within the IGU of the present invention may typically comprise from 2 to 10 glass sheets corresponding to m and n, positive integers, preferably from 2 to 7 glass sheets and at least corresponding layers of polymer interlayers (m-1 and n-1).
  • the polymer interlayer to be used in the present invention typically comprises a material selected from the group consisting ethylene vinyl acetate (EVA), polyisobutylene (PIB), polyvinyl butyral (PVB), polyurethane (PU), polyvinyl chlorides (PVC), polyesters, copolyesters, polyacetals, cyclo olefin polymers (COP), ionomers and/or an ultraviolet activated adhesive, and others known in the art of manufacturing glass laminates. Blended materials using any compatible combinations of these materials can be suitable as well.
  • EVA ethylene vinyl acetate
  • PIB polyisobutylene
  • PVB polyvinyl butyral
  • PU polyurethane
  • PVC polyvinyl chlorides
  • polyesters copolyesters
  • COP cyclo olefin polymers
  • ionomers and/or an ultraviolet activated adhesive and others known in the art of manufacturing glass laminates.
  • Blended materials using any compatible combinations of these materials
  • the at least one polymer interlayer comprises a material selected from the group consisting of ethylene vinyl acetate, and/or polyvinyl butyral, more preferably polyvinyl butyral.
  • the polymer interlayer is also designated as a“bonding interlayer” since the polymer interlayer and the glass pane form a bond that results in adhesion between the glass pane and the polymer interlayer.
  • the polymer interlayer to be used in the present invention is a transparent or translucent polymer interlayer.
  • the polymer interlayer may be coloured or patterned.
  • Typical thicknesses (measured in the direction normal to the plane, P) for the at least one polymer interlayer are 0.3 mm to 3.5 mm, preferably 0.75 mm to 1.75 mm.
  • Commercially available polymer interlayers are polyvinyl butyral (PVB) layers of 0.38 mm, 0.76 mm, 1.52 mm, 2.28 m and 3.04 mm. To achieve the desired thickness, one or more of those layers can be used.
  • polyvinyl butyral polymer interlayers are preferably used.
  • Polyvinyl butyral or PVB is a resin known for applications that require strong binding, optical clarity, adhesion to many surfaces, toughness and flexibility. It is prepared from polyvinyl alcohol by reaction with butyraldehyde. Trade names for PVB-films include KB PVB, Saflex, GlasNovations, WINLITE, S-Lec, Trosifol and EVERLAM.
  • the bonding process takes place under heat and pressure also designated as autoclave process which is well known in the art.
  • the PVB interlayer becomes optically clear and binds the two panes of glass together. Once sealed together, the laminate behaves as a single unit and looks like normal glass.
  • the polymer interlayer of PVB is tough and ductile, so brittle cracks will not pass from one side of the laminate to the other.
  • Another process known in the art and preferred for the present invention is the autoclave free laminated glass production. This process reduces kinetic impact energy costs but has the drawback of limiting the types. Autoclave free oven makes preferentially EVA and dedicated PVB laminated glass. In such case, to achieve the desired thickness and security requirements, one or more of those autoclave free polymer interlayers can be used.
  • the usual process for such autoclave free interlayers is the vacuum bag process
  • the distance, D is equal to or greater than 6mm (D>6 mm), preferably equal to or greater than 9mm (D > 9mm).
  • the distance, D is equal to or lower than 25 mm (D ⁇ 25 mm), preferably equal to or lower than 20 mm (D ⁇ 20 mm), more preferably equal to or lower than 15 mm (D ⁇ 15 mm).
  • D is typically comprised between 6 mm and 25 mm (6 mm ⁇ D ⁇ 25 mm), preferably between 9 mm and 20 mm (9 mm ⁇ D ⁇ 20 mm), more preferably between 9 mm and 15 mm (9 mm ⁇ D ⁇ 15 mm).
  • the back laminated pane has an outer pane face coupled to a third glass pane along the periphery of the insulating glazing unit via a peripheral spacer bar, creating an insulating cavity sealed by a peripheral edge seal.
  • At least one glass sheet of the front laminated pane is tempered and preferably chemically tempered.
  • at least one of tempered glass sheets of back laminated pane is placed at the opposite face from the face facing the projectile and in a more preferred embodiment, at least one of tempered glass sheets of back laminated pane is placed at the opposite face from the face facing the projectile to maximize the total performance of the laminated assembly.
  • the invention relates also to a process to manufacture an insulated glazing unit comprising a front laminated pane facing the projectile and comprising at least m glass sheets bonded by at least m-1 polymer interlayers, m is a positive integer greater or equal to 2, a back laminated pane comprising at least n glass sheets bonded by at least n-1 interlayers, n is a positive integer greater or equal to 2 and a spacer maintaining a distance, D, between the front laminated pane and the back laminated pane.
  • the process comprises a step to assembly the front laminated pane and the back laminated pane with a spacer to maintain a distance D between laminated panes, and the thickness of the back laminated pane is at most 1/2 of the total thickness of the front laminated pane and preferably 1/3 of the total thickness of the front laminated pane and more preferably 1/4 of the total thickness of the front laminated pane, and at least 2 glass sheets of the back laminated pane are tempered.
  • FIG. 1 is a schematic view of a glazing panel according to an exemplifying embodiment of the present invention.
  • FIG. 1 shows an insulated glazing unit (10) configured to resist to a projectile (6) with an kinetic impact energy, E, comprised between 3100 J and 3350 J (3100 J ⁇ E ⁇ 3350 J), extending along a plane, P, defined by a longitudinal axis, X, and a vertical axis, y, comprising :
  • a front laminated pane, F facing the projectile, having a total thickness, ZF, and comprising m glass sheets, f, each having a sheet thickness, Zf, bonded by m-1 polymer interlayers, fi, each having a polymer thickness, Zfi, wherein m is a positive integer greater than or equal to 2 (m>2)
  • a back laminated pane B having a total thickness, ZB, comprising at least n glass sheets, each having a sheet thickness, Zb, bonded by n- 1 polymer interlayers, bi, each having a polymer thickness, Zbi, wherein n is a positive integer greater than or equal to 2 and c.
  • a spacer, S maintaining a distance, D, between the front laminated pane F and the back laminated pane, B, wherein the thicknesses are measured in the direction normal to the plane, P, in the axis, z.
  • the total thickness of the front laminated pane, ZF equals the sum of the thicknesses of the m glass sheets and the m-1 polymer interlayers
  • the total thickness of the back laminated pane, ZB equals the sum of the thicknesses of the n glass sheets and the n-1 polymer interlayers
  • the front glass pane comprises four glass sheets (f 1 , f2, f3, f4) and three interlayers (fi 1 , fi2, fi3).
  • the thickness of each glass sheet is respectively Zf1 , Zf2, Zf3 and Zf4.
  • the thickness of each polymer interlayer is respectively Zfi 1 , Zfi2 and Zfi3.
  • the total thickness of the front laminated pane, ZF Zf1 + Zfi 1 + Zf2 + Zfi2 + Zf3 + Zfi3 + Zf4.
  • the back laminated pane comprises three glass sheets (b1 , b2, b3) and two interlayers (bi 1 , bi2).
  • each glass sheet is respectively Zb1 , Zb2 and Zb3.
  • the thickness of each polymer interlayer is respectively Zbi 1 and Zbi2.
  • the total thickness of the front laminated pane, ZB Zb1 + Zbi1 + Zb2 + Zbi2 + Zb3.
  • each thickness of each glass sheet , Zf1 , Zf2, Zf3, Zf4, Zb1 , Zb2 and Zb3, can be different and each thickness of each polymer interlayer, Zfi 1 , Zfi2, Zfi3, Zbi 1 and Zbi2, can be different independently the number of glass sheet used (m or n).
  • glass sheet b1 or b2 is tempered and glass sheet b3 is tempered.
  • Glass sheet b3 is the glass sheet of the back laminated assembly placed at the opposite face from the face (f1a) facing the projectile (6).
  • At least glass sheets b2 and b3 are tempered meaning the furthest away from the projectile two glass sheets when the back laminated pane comprises three glass sheets understood that the back laminated pane is not limited in term of number of glass sheets
  • the back laminated pane comprises two to five glass sheets (2 ⁇ n ⁇ 5) and more preferably at most four glass sheets (n ⁇ 4).
  • all glass sheets of the back laminated pane can be tempered.
  • At least one glass sheet of the front laminated pane is tempered and preferably, the closest glass sheet, f 1 , from the projectile.
  • Examples E1 to E7 are classified BR6 NS according to standard EN 1063.
  • Glass sheets and polymer interlayers have different thicknesses (respectively Zfl , Zf2, Zf3, Zf4, Zf5, Zfi1 , Zfi2, Zfi3, Zfi4, Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E1.
  • ZB 0.27 * (ZF + ZB).
  • Example E2 is an IGU according to the invention.
  • Glass sheets and polymer interlayers have different thicknesses (respectively Zf 1 , Zf2, Zf3, Zf4, Zf5 Zfi1 , Zfi2, Zfi3, Zfi4 Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E2.
  • the thickness of the front laminated pane is 43.04 mm and the back laminated pane is 17.52 mm.
  • ZB 0.29 * (ZF + ZB).
  • Example E3 comparative example
  • the comparative example E3 has to be thicker and heavier than E1 or E2.
  • Another advantage of the IGU according to the invention is to provide a thinner IGU. Thus, handling, transportation and manipulations are facilitated. Installers can mount assemblies according to the invention in an easier way to reduce risk of breakage, pain and falls.
  • Glass sheets and polymer interlayers have different thicknesses (respectively Zf 1 , Zf2, Zf3, Zf4, Zfi1 , Zfi2, Zfi3, Zb1 , Zb2, Zb3, Zb4, Zbi1 , Zbi2, Zbi3 and Zbi4) as shown in Table 1 at the corresponding line in the column E3.
  • the thickness of the front laminated pane is 32.28 mm and the back laminated pane is 32.28 mm.
  • ZB 0.50 * (ZF + ZB).
  • Example 3 is heavier than the structure of the examples E1 or E2 according to the invention with same performances such as BR6 NS.
  • Examples E4 is an IGU according to the invention.
  • Glass sheets and polymer interlayers have different thicknesses (respectively Zf 1 , Zf2, Zf3, Zf4, Zf5 Zfi1 , Zfi2, Zfi3, Zfi4 Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E4.
  • the thickness of the front laminated pane is 49.32 mm and the back laminated pane is 19.52 mm.
  • ZB 0.28 * (ZF + ZB).
  • Example E5 - comparative example [0080] To obtain same performances (BR6 NS) as the example E4, the comparative example E5 has to be thicker and heavier than E4.
  • Glass sheets and polymer interlayers have different thicknesses
  • Examples E6 is an IGU according to the invention.
  • Glass sheets and polymer interlayers have different thicknesses (respectively Zf1 , Zf2, Zf3, Zf4, Zfi1 , Zfi2, Zfi3, Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E4.
  • the thickness of the front laminated pane is 32.28 mm and the back laminated pane is 19.52 mm.
  • ZB 0.38 * (ZF + ZB).
  • Example E7 - comparative example [0088] To obtain same performances (BR6 NS) as the example E6, the comparative example E7 has to be thicker and heavier than E6.
  • Glass sheets and polymer interlayers have different thicknesses (respectively Zfl , Zf2, Zf3, Zf4, Zf5, Zfi1 , Zfi2, Zfi3, Zfi4, Zb1 , Zb2, Zb3, Zb4, Zbi 1 , Zbi2 and Zbi3) as shown in Table 1 at the corresponding line in the column E3.
  • the thickness of the front laminated pane is 36.56 mm and the back laminated pane is 28.28 mm.
  • ZB 0.44*(ZF + ZB).
  • Another advantage of the IGU according to the invention is to provide a thinner IGU. Thus, handling, transportation and manipulations are facilitated. Installers can mount assemblies according to the invention in an easier way to reduce risk of breakage, pain and falls. [0092] There are known solutions to improve the example E3 but all these solutions have an overcost and/or aesthetic problems.
  • a layer of polycarbonate laminated with poly-urethane layer can be added to the assembly.
  • polycarbonate suffers from several drawbacks such as bad aesthetic durability (yellowness), high cost, processing problem with glass assembly and the thermal expansion coefficient is so different from the one of the glass than delaminations can occur.
  • Another advantage of the IGU according to the invention is to provide a thinner IGU. Thus, handling, transportation and manipulations are facilitated. Installers can mount assemblies according to the invention in an easier way to reduce risk of breakage, pain and falls.
  • IGUs according to the present invention are thinner than other known IGU with same performances even if it exists an overcost for the tempering.
  • Table 1 Examples - configurations and thicknesses

Abstract

The present invention discloses an insulated glazing unit configured for resisting to a projectile (6) with an kinetic impact energy, E, comprised between 3150 J and 3300 J, extending along a plane, P, defined by a longitudinal axis, x, and a vertical axis, y, comprising a front laminated pane, F, facing the projectile, having a total thickness, ZF, and comprising m glass sheets, f, each having a sheet thickness, Zf, bonded by m-1 polymer interlayers, fi, each having a polymer thickness, Zfi, wherein m is a positive integer greater than or equal to 2 (m≥2), a back laminated pane B, having a total thickness, ZB, comprising at least n glass sheets, each having a sheet thickness, Zb, bonded by n-1 polymer interlayers, bi, each having a polymer thickness, Zbi, wherein n is a positive integer greater than or equal to 2 and a spacer, S, maintaining a distance, D, between the front laminated pane F and the back laminated pane, B; wherein the thicknesses are measured in the direction normal to the plane, P, in the axis, z, wherein the total thickness of the front laminated pane, ZF, equals the sum of the thicknesses of the m glass sheets and the m-1 polymer interlayers, and wherein the total thickness of the back laminated pane, ZB, equals the sum of the thicknesses of the n glass sheets and the n-1 polymer interlayers wherein ZB ≤ 1/3*(ZF + ZB) and at least 2 glass sheets of the back laminated pane (B) are tempered.

Description

Description
Ballistic resistant insulated glazing units
Technical Field
[0001] The present invention relates to security insulated glazing units. Background Art
[0002] The overall terrorist threat to the security of the population has increased over recent years and remains on a sharp upward trajectory. Therefore, there is an increasing demand for a safer environment. Taking this on board, the security glazing industry needs to respond to a demand for large building fagade security.
[0003] Safety glazing and projectile / ballistic resistant glazing (BRG) are classes of optically transparent window products designed to protect occupants of buildings, transport vehicles, etc., from penetration by projectiles such as, but not limited to, windblown objects, bullets, and the like. [0004] In exemplary window products, the outside surface of the window pane, the face receiving the incoming projectile, is generally referred to as the attack face, and the innermost surface of the window pane closest to the occupants of the building, vehicle, etc., is referred to as the protective side.
[0005] BRG products are typically constructed from several layers of glass and/or plastics or polymers. Conventional glass materials used for ballistic laminates include soda lime glass and borosilicate glass which are typically manufactured using a float process.
[0006] Other conventional glass materials used for ballistic laminates include crystalline materials such as aluminum oxy-nitride (ALON), spinel, sapphire, and glass-ceramic materials (GC). Multiple glass and/or plastic layers are typically bonded together in a lamination process using polymeric or adhesive interlayer materials to form a BRG window pane. Conventional BRG window panes are very thick and heavy, and the overall thickness, number of glass, plastic, and/or interlayer sheets, and the specific weight (e.g. mass per unit area) of the construction can be varied to resist various threat levels. These threat levels are generally a function of the type of projectile, the mass of the projectile and its construction, and velocity obtained from the explosive charge in the respective cartridge as well as the impact of one or more projectiles (typically three projectiles) within a predetermined area. Exemplary international ballistic standards include the European Standard (EN) 1063: 1999 Security Glazing Ballistic Standard.
[0007] While dealing with projectile-resistant security glazing for building applications, the European standard to fulfil is EN 1063. The glazing is assumed to be resistant against a given projectile if the glazing does not have any "through" holes, from the front to the back. The procedure for certification requires the definition of an attack face. This is the face of the projectile resistant glazing, marked by the manufacturer and/or supplier, as designed to face the ballistic. The certified glazing are rated in two categories‘S’ and‘NS’ stand for‘Splinters’ and‘No Splinters’.
[0008] If no glass splinters emerge on the protective side after the ballistic test explained in the standard, the ballistic class additionally receives the rating "NS". If glass splinters emerge on the protected side of the impact-resistant glass after the ballistic test explained in the standard, "S" is added to the test result.
[0009] Each conventional BRG construction has its advantages and disadvantages depending upon the respective constituent layers. For example, all glass constructions are generally durable (not susceptible to scratching or UV attack) and are clear with little visual distortion; however, all glass constructions are heavy and are generally the thickest constructions. Acrylic constructions are relatively light but are not durable or optically clear without distortion.
[0010] Glass clad polycarbonate structures are generally lighter than all glass but suffer from optical visual distortions, and the polycarbonate layer is easily scratched. Thus, the polycarbonate layer is usually treated with an anti- scratch surface coating if exposed on a surface of the respective laminate structure. Furthermore, an additional UV coating is applied to stop detrimental yellowing of the polycarbonate material occurring with prolonged exposure to UV rays. Such coatings generally increase the expense of polycarbonate -based BRG constructions. It should also be noted that conventional acrylic and polycarbonate layers are susceptible to chemical degradation, e.g., methanol, toluene, acetone, methylene chloride, and gasoline. Defects caused by such chemical degradation range from cracking to tacky surfaces and/or sheer layer destruction, each of which negatively affects optical transparency and threat protection performance of a respective window pane.
[0011] As a good alternative, chemically tempered (CT) glass can be employed within BRG for achieving lighter and thinner structure. Indeed, including such kind of reinforced glass within a projectile-resistant composition allows to render the laminate much more flexible and resistant against the bullet impact. As a consequence, less glass are required to fully stop the bullet.
[0012] While dealing with a projectile-resistant insulated glazing unit (IGU), it is common use to use a certified projectile-resistant single glazing unit (SGU) and to put it as the protective face of the IGU. In those instances when a bullet resistant glass component is used as the non-attack face of an insulating glass unit then there is no need to test. The classification of the insulating glass unit shall be the same as the glass component used (EN 1279-5).
[0013] As an example, a laminated glazing“5:15:15:15:15:5” (where means a layer of interlayer and the number is the thickness of the glass layer - This example is a 6 glass layers with 5 interlayers) is BR6 NS certified according to the test made regarding cited norms. The double glazing 4:4/15/5:15:15:15:15:5 (where means a layer of interlayer, 715/” a gap of 15mm maintained by the spacer and the number is the thickness of the glass layer) is naturally BR6 NS certified without any complementary test. [0014] In this configuration, only the back pane participate to the BR performance of the IGU.
[0015] While in full agreement with the existing standards, this approach doesn’t allow to achieve thin projectile resistant IGU. Summary of invention
[0016] It is an object of the present invention to alleviate these problems, and to provide an insulated glazing unit which leads to a reduction of the weight and the thickness of the unit and to a cost reduction.
[0017] According to a first aspect of the invention, the invention relates to an improved insulated glazing unit configured for resisting to a projectile (6) with an kinetic impact energy, E, comprised between 3100 J and 3350 J (3100 J < E < 3350 J), extending along a plane, P, defined by a longitudinal axis, x, and a vertical axis, y, comprising :
a. a front laminated pane, F, facing the projectile, having a total thickness, ZF, and comprising m glass sheets f, each having a sheet thickness, Zf, bonded by m-1 polymer interlayers, each having a polymer thickness, Zfi, wherein m is a positive integer greater than or equal to 2 (m>2),
b. a back laminated pane B, having a total thickness, ZB, comprising at least n glass sheets, each having a sheet thickness, Zb, bonded by n- 1 polymer interlayers, each having a polymer thickness, Zbi, wherein n is a positive integer greater than or equal to 2 and
c. a spacer, S, maintaining a distance, D, between the front laminated pane F and the back laminated pane, B; [0018] The thicknesses are measured in the direction normal to the plane, P. The total thickness of the front laminated pane, ZF, equals the sum of the thicknesses of the m glass sheets and the m-1 polymer interlayers and the total thickness of the back laminated pane, ZB, equals the sum of the thicknesses of the n glass sheets and the n-1 polymer interlayers. [0019] The invention relates also to a process to produce an insulated glazing unit according to a first aspect of the invention.
[0020] The solution as defined in the first aspect of the present invention is based on both panes can participate to the projectile resistance performance of the IGU. In this context, the front and back panes of the IGU play two different role :
[0021] Front laminated pane (facing to the projectile) is dedicated for highly slowing down the bullet and absorbing the major part of its kinetic impact energy.
[0022] It is usually made of a plurality of thick glass with a so-called interlayer cushion at the end to efficiently absorb the remaining bullet kinetic impact energy. For this part, using tempered glass is not necessary since only a consequent amount of glass is needed to stop the bullet. An interlayer cushion is a polymer interlayer with a thickness of at least 1.5 mm. In case of the use of a PVB interlayer, the standard thickness of one layer is 0.76 mm in some cases this thickness of 0.76 mm can be obtained by two thin layers of 0.38 mm. To obtain a thicker PVB interlayer, several interlayers can be layered to obtain the desired thickness.
[0023] The insulated glazing unit is assumed to be resistant against a projectile with a given kinetic impact energy if the glazing does not have any "through" holes, from the front to the back. An IGU able to resist against a projectile with a given kinetic impact energy, E, comprised between 3100 J and 3350 J (3100 J < E < 3350 J), according to standard EN 1063, will be classified BR6 or BR7. The kinetic impact energy for a BR7 is the same than the one for a BR6 with a perforating element. [0024] At this stage, the bullet can be mainly stopped but a splitting behaviour of the protective face can occur. To stop the inertia of the first pane, a second block or pane must be employed, the Back laminated pane and must exhibit at least one of the two following characteristics high rigidity or high stress at failure. [0025] The first alternative will ensure that the second bloc will not admit a deformation which could lead to its breakage. The second alternative will allow the second bloc to admit a bigger deformation than the one allowed in the first alternative without breakage. This second alternative leads to the decrease of the laminated thickness and requires to work with tempered glass.
[0026] The solution as defined in the first aspect of the present invention that the total thickness of the back laminated assembly, ZB, is at most 0.4 of the sum of the total thickness of the front laminated pane, ZF, and the total thickness of the back laminated pane, ZB (ZB < 0.4*(ZF + ZB)) and in that at least 2 glass sheets of the back laminated pane, ZB, are tempered.
[0027] In a preferred embodiment to minimize the weight of the laminated assembly, the total thickness of the back laminated assembly, ZB, is at most 0.3 of the sum of the total thickness of the front laminated pane, ZF, and the total thickness of the back laminated pane, ZB (ZB < 0.3*(ZF + ZB)) and more preferably, the total thickness of the back laminated assembly, ZB, is at most 0.2 of the sum of the total thickness of the front laminated pane, ZF, and the total thickness of the back laminated pane, ZB (ZB < 0.2*(ZF + ZB)). This allows to facilitate transport, handling, mounting,...
[0028] The thickness of a laminated pane is the sum of the thicknesses of the glass sheets added to the thicknesses of the interlayers. Glass sheet comprised in a laminated pane can have a different thickness such as polymer interlayers.
[0029] Glass sheets of the IGU of the present invention within laminated assemblies can be chosen among all flat glass technologies, among them: float clear, extra-clear or coloured glass. The term “glass” is herein understood to mean any type of glass or equivalent transparent material, such as a mineral glass. The mineral glasses used may be irrespectively one or more known types of glass such as soda-lime-silica, aluminosilicate or borosilicate, crystalline and polycrystalline glasses. The glass pane can be obtained by a floating process, a drawing process, a rolling process or any other process known to manufacture a glass pane starting from a molten glass composition. The glass sheets can optionally be edge-ground. Edge grinding renders sharp edges into smooth edges which are much safer for people who could come in contact with the insulating glazing unit, in particular with the edge of the glazing. Preferably and for reasons of lower production costs, the glass pane according to the invention is a pane of soda-lime-silica glass, aluminosilicate glass or borosilicate glass.
[0030] In some embodiments of the present invention, films such as low emissivity films, solar control films (a heat ray reflection films), anti-reflective films, anti- fog films, preferably a heat ray reflection film or a low emissivity film, can be provided on at least one of the inner sheet faces and/or outer sheet faces of the laminated panes.
[0031] Laminated panes within the IGU of the present invention may typically comprise from 2 to 10 glass sheets corresponding to m and n, positive integers, preferably from 2 to 7 glass sheets and at least corresponding layers of polymer interlayers (m-1 and n-1).
[0032] The polymer interlayer to be used in the present invention typically comprises a material selected from the group consisting ethylene vinyl acetate (EVA), polyisobutylene (PIB), polyvinyl butyral (PVB), polyurethane (PU), polyvinyl chlorides (PVC), polyesters, copolyesters, polyacetals, cyclo olefin polymers (COP), ionomers and/or an ultraviolet activated adhesive, and others known in the art of manufacturing glass laminates. Blended materials using any compatible combinations of these materials can be suitable as well. In a preferred embodiment, the at least one polymer interlayer comprises a material selected from the group consisting of ethylene vinyl acetate, and/or polyvinyl butyral, more preferably polyvinyl butyral. The polymer interlayer is also designated as a“bonding interlayer” since the polymer interlayer and the glass pane form a bond that results in adhesion between the glass pane and the polymer interlayer.
[0033] In a preferred embodiment, the polymer interlayer to be used in the present invention is a transparent or translucent polymer interlayer. However, for decorative applications, the polymer interlayer may be coloured or patterned.
[0034] Typical thicknesses (measured in the direction normal to the plane, P) for the at least one polymer interlayer are 0.3 mm to 3.5 mm, preferably 0.75 mm to 1.75 mm. Commercially available polymer interlayers are polyvinyl butyral (PVB) layers of 0.38 mm, 0.76 mm, 1.52 mm, 2.28 m and 3.04 mm. To achieve the desired thickness, one or more of those layers can be used.
[0035] To form the laminate assembly within the IGU of the present invention, polyvinyl butyral polymer interlayers are preferably used. Polyvinyl butyral (or PVB) is a resin known for applications that require strong binding, optical clarity, adhesion to many surfaces, toughness and flexibility. It is prepared from polyvinyl alcohol by reaction with butyraldehyde. Trade names for PVB-films include KB PVB, Saflex, GlasNovations, WINLITE, S-Lec, Trosifol and EVERLAM. The bonding process takes place under heat and pressure also designated as autoclave process which is well known in the art. When laminated under these conditions, the PVB interlayer becomes optically clear and binds the two panes of glass together. Once sealed together, the laminate behaves as a single unit and looks like normal glass. The polymer interlayer of PVB is tough and ductile, so brittle cracks will not pass from one side of the laminate to the other.
[0036] Another process known in the art and preferred for the present invention, is the autoclave free laminated glass production. This process reduces kinetic impact energy costs but has the drawback of limiting the types. Autoclave free oven makes preferentially EVA and dedicated PVB laminated glass. In such case, to achieve the desired thickness and security requirements, one or more of those autoclave free polymer interlayers can be used. The usual process for such autoclave free interlayers is the vacuum bag process
[0037] In one embodiment according to the invention, at least one of tempered glass sheets of the insulated glazing unit is chemically tempered to improve the bending stress of the tempered glass sheet. [0038] In a preferred embodiment, the distance, D, is equal to or greater than 6mm (D>6 mm), preferably equal to or greater than 9mm (D > 9mm). In another preferred embodiment, the distance, D, is equal to or lower than 25 mm (D < 25 mm), preferably equal to or lower than 20 mm (D < 20 mm), more preferably equal to or lower than 15 mm (D < 15 mm). Hence, the distance
D is typically comprised between 6 mm and 25 mm (6 mm < D < 25 mm), preferably between 9 mm and 20 mm (9 mm < D < 20 mm), more preferably between 9 mm and 15 mm (9 mm < D < 15 mm).
[0039] In another embodiment, the back laminated pane has an outer pane face coupled to a third glass pane along the periphery of the insulating glazing unit via a peripheral spacer bar, creating an insulating cavity sealed by a peripheral edge seal.
[0040] In a preferred embodiment, at least one glass sheet of the front laminated pane is tempered and preferably chemically tempered. [0041] In a preferred embodiment, at least one of tempered glass sheets of back laminated pane is placed at the opposite face from the face facing the projectile and in a more preferred embodiment, at least one of tempered glass sheets of back laminated pane is placed at the opposite face from the face facing the projectile to maximize the total performance of the laminated assembly.
[0042] In a preferred embodiment to ensure the protection of the user in the opposite side of the laminated assembly from the projectile, all tempered sheets of back laminated pane are placed at the opposite face from the face facing the projectile. [0043] The invention relates also to a process to manufacture an insulated glazing unit comprising a front laminated pane facing the projectile and comprising at least m glass sheets bonded by at least m-1 polymer interlayers, m is a positive integer greater or equal to 2, a back laminated pane comprising at least n glass sheets bonded by at least n-1 interlayers, n is a positive integer greater or equal to 2 and a spacer maintaining a distance, D, between the front laminated pane and the back laminated pane.
[0044] The process comprises a step to assembly the front laminated pane and the back laminated pane with a spacer to maintain a distance D between laminated panes, and the thickness of the back laminated pane is at most 1/2 of the total thickness of the front laminated pane and preferably 1/3 of the total thickness of the front laminated pane and more preferably 1/4 of the total thickness of the front laminated pane, and at least 2 glass sheets of the back laminated pane are tempered. [0045] It is noted that the invention relates to all possible combinations of features recited in the claims.
[0046] The following description relates to an architectural window unit but it’s understood that the invention may be applicable to others fields like automotive.. Brief description of drawings
[0047] This and other aspects of the present invention will now be described in more detail, with reference to the appended drawings showing various exemplifying embodiments of the invention which are provided by way of illustration and not of limitation. The drawings are a schematic representation and not true to scale. The drawings do not restrict the invention in any way. More advantages will be explained with examples.
[0048] FIG. 1 is a schematic view of a glazing panel according to an exemplifying embodiment of the present invention.
Description of embodiments [0049] With reference to FIG. 1 , a first embodiment of the present invention is described.
[0050] FIG. 1 shows an insulated glazing unit (10) configured to resist to a projectile (6) with an kinetic impact energy, E, comprised between 3100 J and 3350 J (3100 J < E < 3350 J), extending along a plane, P, defined by a longitudinal axis, X, and a vertical axis, y, comprising :
a. a front laminated pane, F, facing the projectile, having a total thickness, ZF, and comprising m glass sheets, f, each having a sheet thickness, Zf, bonded by m-1 polymer interlayers, fi, each having a polymer thickness, Zfi, wherein m is a positive integer greater than or equal to 2 (m>2)
b. a back laminated pane B, having a total thickness, ZB, comprising at least n glass sheets, each having a sheet thickness, Zb, bonded by n- 1 polymer interlayers, bi, each having a polymer thickness, Zbi, wherein n is a positive integer greater than or equal to 2 and c. a spacer, S, maintaining a distance, D, between the front laminated pane F and the back laminated pane, B, wherein the thicknesses are measured in the direction normal to the plane, P, in the axis, z.
[0051] Wherein the total thickness of the front laminated pane, ZF, equals the sum of the thicknesses of the m glass sheets and the m-1 polymer interlayers, and wherein the total thickness of the back laminated pane, ZB, equals the sum of the thicknesses of the n glass sheets and the n-1 polymer interlayers.
[0052] In a particular embodiment of the fig. 1 according of the invention, the front glass pane comprises four glass sheets (f 1 , f2, f3, f4) and three interlayers (fi 1 , fi2, fi3). The thickness of each glass sheet is respectively Zf1 , Zf2, Zf3 and Zf4. The thickness of each polymer interlayer is respectively Zfi 1 , Zfi2 and Zfi3. The total thickness of the front laminated pane, ZF = Zf1 + Zfi 1 + Zf2 + Zfi2 + Zf3 + Zfi3 + Zf4. The back laminated pane comprises three glass sheets (b1 , b2, b3) and two interlayers (bi 1 , bi2). The thickness of each glass sheet is respectively Zb1 , Zb2 and Zb3. The thickness of each polymer interlayer is respectively Zbi 1 and Zbi2. The total thickness of the front laminated pane, ZB = Zb1 + Zbi1 + Zb2 + Zbi2 + Zb3.
[0053] Each thickness of each glass sheet , Zf1 , Zf2, Zf3, Zf4, Zb1 , Zb2 and Zb3, can be different and each thickness of each polymer interlayer, Zfi 1 , Zfi2, Zfi3, Zbi 1 and Zbi2, can be different independently the number of glass sheet used (m or n).
[0054] Surprisingly, to limit the weight of the structure by keeping same performances as a non-tempered laminated assembly according to norms, inventors shown that at least two glass sheets of the back laminated pane have to be tempered. The thickness of the back laminated assembly, ZB, can be reduced and limited to at most 0.5 of the sum of the thicknesses of the front and the back laminated panes (ZF + ZB).
[0055] In a preferred embodiment, glass sheet b1 or b2 is tempered and glass sheet b3 is tempered. Glass sheet b3 is the glass sheet of the back laminated assembly placed at the opposite face from the face (f1a) facing the projectile (6).
[0056] In a more preferred embodiment, at least glass sheets b2 and b3 are tempered meaning the furthest away from the projectile two glass sheets when the back laminated pane comprises three glass sheets understood that the back laminated pane is not limited in term of number of glass sheets Preferably, the back laminated pane comprises two to five glass sheets (2 < n < 5) and more preferably at most four glass sheets (n < 4).
[0057] In some embodiment, all glass sheets of the back laminated pane can be tempered.
[0058] In some embodiment, at least one glass sheet of the front laminated pane is tempered and preferably, the closest glass sheet, f 1 , from the projectile.
[0059] The person skilled in the art realizes that the present invention by no means is limited to the preferred embodiments described above or to the examples described below. On the contrary, many modifications and variations are possible within the scope of the appended claims.
Example [0060] Examples E1 , E2, E4 and E6 illustrate different embodiments of IGU of the present invention, demonstrating the required resistance to projectile (BR5). Examples E3, E5 and E7 illustrate a comparative embodiment of IGU. Configurations and thicknesses of examples are shown in Table 1.
[0061] Examples E1 to E7 are classified BR6 NS according to standard EN 1063.
[0062] Example E1
[0063] The IGU of the example E1 comprises a front laminated pane (F) and a back laminated pane (B) maintained at a distance D = 12 mm. The front laminated pane of this specific embodiment comprises five (m = 5) glass sheets (f 1 , f2, f3, f4 and f5) and four polymer interlayers (fi 1 , fi2, fi3 and fi4). The back laminated pane comprises three (n = 3) glass sheets (b1 , b2 and b3) and two interlayers (bi 1 and bi2). The two glass sheets placed at the opposite face from the face facing the projectile (b2 and b3) are tempered.
[0064] Glass sheets and polymer interlayers have different thicknesses (respectively Zfl , Zf2, Zf3, Zf4, Zf5, Zfi1 , Zfi2, Zfi3, Zfi4, Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E1. The total thickness of the front laminated pane (ZF) is the sum of thicknesses of glass sheets and polymer interlayers; ZF = Zfl + Zf2 + Zf3 + Zf4 + Zf5 + Zfi 1 + Zfi2 + Zfi3 + Zfi4 = 4 + 12 + 12 + 12 + 4 + 0.76 + 0.76 + 0.76 + 1.52 = 47.8 mm. The total sum of the back laminated glass (ZB) is the sum of thicknesses of glass sheets and polymer interlayers; ZB = Zb1 + Zb2 Zb3 + Zbi 1 + Zbi2 = 4 + 8 + 4 + 0.76 + 0.76 = 17.52 mm. The ratio of the back laminated pane is ZB/(ZF + ZB) = 17.52/(47.8 + 17.52) = 0.27. Thus, ZB = 0.27*(ZF + ZB). [0065] The IGU of example 1 allows to reduce the total weight by keeping same properties such as BR6NS.
[0066] Example E2 [0067] Examples E2 is an IGU according to the invention.
[0068] The IGU of the example E2 comprises a front laminated pane (F) and a back laminated pane (B) maintained at a distance D = 9 mm. The front laminated pane of this specific embodiment comprises five (m = 5) glass sheets (f 1 , f2, f3, f4 and f5) and four polymer interlayers (fi 1 , fi2, fi3 and fi4). The back laminated pane comprises three (n = 3) glass sheets (b1 , b2 and b3) and two interlayers (bi 1 and bi2). The two glass sheets placed at the opposite face from the face facing the projectile (b2 and b3) are tempered.
[0069] Glass sheets and polymer interlayers have different thicknesses (respectively Zf 1 , Zf2, Zf3, Zf4, Zf5 Zfi1 , Zfi2, Zfi3, Zfi4 Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E2. The thickness of the front laminated pane is 43.04 mm and the back laminated pane is 17.52 mm. The ratio between the thickness of the back laminated pane and the thickness of the back laminated pane is 0.29 (ZB/(ZF + ZB) = 17.52/(43.04 + 17.52) = 0.29). Thus, ZB = 0.29*(ZF + ZB).
[0070] Example E3 - comparative example
[0071] To obtain same performances (BR6 NS) as the examples E1 and E2, the comparative example E3 has to be thicker and heavier than E1 or E2. Another advantage of the IGU according to the invention is to provide a thinner IGU. Thus, handling, transportation and manipulations are facilitated. Installers can mount assemblies according to the invention in an easier way to reduce risk of breakage, pain and falls.
[0072] The IGU of the example E3 comprises a front laminated pane (F) and a back laminated pane (B) maintained at a distance D = 9 mm. The front laminated pane of this specific embodiment comprises four (m = 4) glass sheets (f 1 , f2, f3 and f4) and three polymer interlayers (fi 1 , fi2 and fi3). The back laminated pane comprises four (n = 4) glass sheets (b1 , b2, b3 and b4) and three interlayers (bi1 , bi2 and bi3). None of the glass sheets is tempered.
[0073] Glass sheets and polymer interlayers have different thicknesses (respectively Zf 1 , Zf2, Zf3, Zf4, Zfi1 , Zfi2, Zfi3, Zb1 , Zb2, Zb3, Zb4, Zbi1 , Zbi2, Zbi3 and Zbi4) as shown in Table 1 at the corresponding line in the column E3. The thickness of the front laminated pane is 32.28 mm and the back laminated pane is 32.28 mm. The ratio between the thickness of the back laminated pane and the thickness of the back laminated pane is 0.50 (ZB/(ZF + ZB) = 0.50). Thus, ZB = 0.50*(ZF + ZB).
[0074] Example 3 is heavier than the structure of the examples E1 or E2 according to the invention with same performances such as BR6 NS.
[0075] Example E4
[0076] Examples E4 is an IGU according to the invention.
[0077] The IGU of the example E4 comprises a front laminated pane (F) and a back laminated pane (B) maintained at a distance D = 12 mm. The front laminated pane of this specific embodiment comprises five (m = 5) glass sheets (f 1 , f2, f3, f4 and f5) and four polymer interlayers (fi 1 , fi2, fi3 and fi4). The back laminated pane comprises three (n = 3) glass sheets (b1 , b2 and b3) and two interlayers (bi 1 and bi2). The two glass sheets placed at the opposite face from the face facing the projectile (b2 and b3) are tempered.
[0078] Glass sheets and polymer interlayers have different thicknesses (respectively Zf 1 , Zf2, Zf3, Zf4, Zf5 Zfi1 , Zfi2, Zfi3, Zfi4 Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E4. The thickness of the front laminated pane is 49.32 mm and the back laminated pane is 19.52 mm. The ratio between the thickness of the back laminated pane and the thickness of the back laminated pane is 0.28 (ZB/(ZF + ZB) = 0.28). Thus, ZB = 0.28*(ZF + ZB).
[0079] Example E5 - comparative example [0080] To obtain same performances (BR6 NS) as the example E4, the comparative example E5 has to be thicker and heavier than E4.
[0081] The IGU of the example E5 comprises a front laminated pane (F) and a back laminated pane (B) maintained at a distance D = 12 mm. The front laminated pane of this specific embodiment comprises four (m = 4) glass sheets (f 1 , f2, f3 and f4) and four polymer interlayers (fi 1 , fi2 and). The back laminated pane comprises four (n = 4) glass sheets (b1 , b2, b3 and b4) and three interlayers (bi1 , bi2 and bi3). None of the glass sheets is tempered. [0082] Glass sheets and polymer interlayers have different thicknesses
(respectively Zfl , Zf2, Zf3, Zf4, Zfi1 , Zfi2, Zfi3, Zb1 , Zb2, Zb3, Zb4, Zbi1 , Zbi2 and Zbi3) as shown in Table 1 at the corresponding line in the column E3. The thickness of the front laminated pane is 36.56 mm and the back laminated pane is 28.28 mm. The ratio between the thickness of the back laminated pane and the thickness of the back laminated pane is 0.44 (ZB/(ZF + ZB) = 0.44). Thus, ZB = 0.44*(ZF + ZB).
[0083] Example E6
[0084] Examples E6 is an IGU according to the invention.
[0085] The IGU of the example E6 comprises a front laminated pane (F) and a back laminated pane (B) maintained at a distance D = 12 mm. The front laminated pane of this specific embodiment comprises four (m = 4) glass sheets (f 1 , f2, f3 and f4) and three polymer interlayers (fi1 , fi2 and). The back laminated pane comprises three (n = 3) glass sheets (b1 , b2 and b3) and two interlayers (bi1 and bi2). The two glass sheets placed at the opposite face from the face facing the projectile (b2 and b3) are tempered.
[0086] Glass sheets and polymer interlayers have different thicknesses (respectively Zf1 , Zf2, Zf3, Zf4, Zfi1 , Zfi2, Zfi3, Zb1 , Zb2, Zb3, Zbi1 and Zbi2) as shown in Table 1 at the corresponding line in the column E4. The thickness of the front laminated pane is 32.28 mm and the back laminated pane is 19.52 mm. The ratio between the thickness of the back laminated pane and the thickness of the back laminated pane is 0.38 (ZB/(ZF + ZB) = 0.38). Thus, ZB = 0.38*(ZF + ZB).
[0087] Example E7 - comparative example [0088] To obtain same performances (BR6 NS) as the example E6, the comparative example E7 has to be thicker and heavier than E6.
[0089] The IGU of the example E7 comprises a front laminated pane (F) and a back laminated pane (B) maintained at a distance D = 12 mm. The front laminated pane of this specific embodiment comprises four (m = 4) glass sheets (f 1 , f2, f3 and f4) and four polymer interlayers (fi1 , fi2 and). The back laminated pane comprises four (n = 4) glass sheets (b1 , b2, b3 and b4) and three interlayers (bi1 , bi2 and bi3). None of the glass sheets is tempered.
[0090] Glass sheets and polymer interlayers have different thicknesses (respectively Zfl , Zf2, Zf3, Zf4, Zf5, Zfi1 , Zfi2, Zfi3, Zfi4, Zb1 , Zb2, Zb3, Zb4, Zbi 1 , Zbi2 and Zbi3) as shown in Table 1 at the corresponding line in the column E3. The thickness of the front laminated pane is 36.56 mm and the back laminated pane is 28.28 mm. The ratio between the thickness of the back laminated pane and the thickness of the back laminated pane is 0.44 (ZB/(ZF + ZB) = 0.44). Thus, ZB = 0.44*(ZF + ZB).
[0091] Another advantage of the IGU according to the invention is to provide a thinner IGU. Thus, handling, transportation and manipulations are facilitated. Installers can mount assemblies according to the invention in an easier way to reduce risk of breakage, pain and falls. [0092] There are known solutions to improve the example E3 but all these solutions have an overcost and/or aesthetic problems.
[0093] For example, a layer of polycarbonate laminated with poly-urethane layer can be added to the assembly. However, polycarbonate suffers from several drawbacks such as bad aesthetic durability (yellowness), high cost, processing problem with glass assembly and the thermal expansion coefficient is so different from the one of the glass than delaminations can occur.
[0094] Another advantage of the IGU according to the invention is to provide a thinner IGU. Thus, handling, transportation and manipulations are facilitated. Installers can mount assemblies according to the invention in an easier way to reduce risk of breakage, pain and falls.
[0095] IGUs according to the present invention are thinner than other known IGU with same performances even if it exists an overcost for the tempering.
Table 1 : Examples - configurations and thicknesses

Claims

Claims
Claim 1. An insulated glazing unit (10) configured for resisting to a projectile (6) with a kinetic impact energy, E, comprised between 3100 J and 3350 J (3100 J £ E £ 3350 J), extending along a plane, P, defined by a longitudinal axis, x, and a vertical axis, y, comprising:
d. a front laminated pane, F, facing the projectile, having a total thickness, ZF, and comprising m glass sheets, f, each having a sheet thickness, Zf, bonded by m-1 polymer interlayers, fi, each having a polymer thickness, Zfi, wherein m is a positive integer greater than or equal to 2 (m>2),
e. a back laminated pane B, having a total thickness, ZB, comprising at least n glass sheets, each having a sheet thickness, Zb, bonded by n- 1 polymer interlayers, bi, each having a polymer thickness, Zbi, wherein n is a positive integer greater than or equal to 2 and f. a spacer, S, maintaining a distance, D, between the front laminated pane F and the back laminated pane, B; wherein the thicknesses are measured in the direction normal to the plane, P, in the axis, z, wherein the total thickness of the front laminated pane, ZF, equals the sum of the thicknesses of the m glass sheets and the m-1 polymer interlayers, and wherein the total thickness of the back laminated pane, ZB, equals the sum of the thicknesses of the n glass sheets and the n-1 polymer interlayers, characterized in that ZB < 0.4*(ZF + ZB), and in that at least 2 glass sheets of the back laminated pane (B) are tempered.
Claim 2. An insulated glazing unit according to claim 1 , wherein ZB < 0.3 *(ZF
+ ZB).
Claim 3. An insulated glazing unit according to claim 1 , wherein ZB < 0.25 *(ZF + ZB)
Claim 4. An insulated glazing unit according to any preceding claims, wherein at least one of tempered glass sheets is chemically tempered.
Claim 5. An insulated glazing unit according to any preceding claims, wherein tempered glass sheets are chemically tempered.
Claim 6. An insulated glazing unit according to any preceding claims, wherein the distance, D, is comprised between 6 mm and 25 mm (6 mm < D < 25 mm), preferably is comprised between 9 mm and 20 mm (9 mm < D < 20 mm), more preferably is comprised between 9 mm and 15 mm (9 mm < D < 15 mm).
Claim 7. An insulated glazing panel according to any preceding claims, wherein the polymer interlayer is a material selected from the group consisting of ethylene vinyl acetate, polyisobutylene, polyvinyl butyral, polyurethane, cyclo olefin polymers, ionomer, a thermoplastic material, combinations thereof and/or ultraviolet activated adhesive, preferably is polyvinyl butyral.
Claim 8. An insulating glazing unit according to any preceding claims, wherein the back laminated pane has an outer pane face coupled to a third glass pane along the periphery of the insulating glazing unit via a peripheral spacer bar, creating an insulating cavity sealed by a peripheral edge seal.
Claim 9. An insulated glazing unit according to any preceding claims, wherein at least one glass sheet of the front laminated pane is tempered and preferably chemically tempered.
Claim 10. An insulated glazing unit according to any preceding claims, wherein at least one of tempered glass sheets of back laminated pane is placed at the opposite face from the face facing the projectile.
Claim 11. An insulated glazing unit according to claim 8, wherein all tempered sheets of back laminated pane are placed at the opposite face from the face facing the projectile.
EP19773063.3A 2018-09-19 2019-09-19 Ballistic resistant insulated glazing units Pending EP3853018A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP18195556 2018-09-19
PCT/EP2019/075236 WO2020058441A1 (en) 2018-09-19 2019-09-19 Ballistic resistant insulated glazing units

Publications (1)

Publication Number Publication Date
EP3853018A1 true EP3853018A1 (en) 2021-07-28

Family

ID=63642904

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19773063.3A Pending EP3853018A1 (en) 2018-09-19 2019-09-19 Ballistic resistant insulated glazing units

Country Status (2)

Country Link
EP (1) EP3853018A1 (en)
WO (1) WO2020058441A1 (en)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT999536B (en) * 1972-09-29 1976-03-10 Glaverbel IMPACT RESISTANT GLASS
DE2542441C3 (en) * 1975-09-24 1979-10-25 Bfg Glassgroup, Paris Bulletproof double glass pane with an outer pane and a laminated safety pane
DE2901951C2 (en) * 1979-01-19 1985-02-28 Vereinigte Glaswerke Gmbh, 5100 Aachen Bullet-resistant double glazing
DE3243136A1 (en) * 1982-11-22 1984-05-24 Vereinigte Glaswerke Gmbh, 5100 Aachen Bulletproof laminated glass block for the eye slit of an armored vehicle
DE202008005366U1 (en) * 2008-04-17 2008-07-10 Sälzer Sicherheitstechnik GmbH Blast-resistant disc structure
BR112017018817B1 (en) * 2015-04-16 2022-02-15 Knauf Gips Kg BULLET-RESISTANT PLASTER WALL STRUCTURE

Also Published As

Publication number Publication date
WO2020058441A1 (en) 2020-03-26

Similar Documents

Publication Publication Date Title
AU2009246795B2 (en) Ballistic transparency
US20150202845A1 (en) Multi-layer transparent light-weight safety glazings
AU2006257867B2 (en) Transparent ceramic composite
CN108367979B (en) Laminated glass
US5645940A (en) Shatter-resistant glass having polyester layers
CN109311743B (en) Laminated glass
JP2023115054A (en) Vehicular door glass
WO2020058441A1 (en) Ballistic resistant insulated glazing units
EP3853019A1 (en) Ballistic resistant insulated glazing units
US9550343B2 (en) Laminated transparency with controlled failure and method of making the same
WO2010036219A1 (en) Anti-spall windows
JP2018123028A (en) Method for producing window glass and method for producing scatter prevention film
WO2024073703A1 (en) Solar control interlayer for laminates
WO2022162086A1 (en) Multiple glazing unit
JP2006096612A (en) Laminated glass
CN114901473A (en) Asymmetric glass laminates with composite interlayers and related methods
WO2019008466A1 (en) Multilayer laminate and method of production
WO2020083669A1 (en) Laminated assembly
WO2019243436A1 (en) Low overpressure security insulted glazing unit

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20210419

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20230607