EP3848441A1 - Poly(2-vinylpyridine) carboxyméthylée comme principe actif facilitant l'élimination des saletés - Google Patents
Poly(2-vinylpyridine) carboxyméthylée comme principe actif facilitant l'élimination des saletés Download PDFInfo
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- EP3848441A1 EP3848441A1 EP20215522.2A EP20215522A EP3848441A1 EP 3848441 A1 EP3848441 A1 EP 3848441A1 EP 20215522 A EP20215522 A EP 20215522A EP 3848441 A1 EP3848441 A1 EP 3848441A1
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- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 1
- 125000002951 idosyl group Chemical class C1([C@@H](O)[C@H](O)[C@@H](O)[C@H](O1)CO)* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- 150000002584 ketoses Chemical class 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- IJFXRHURBJZNAO-UHFFFAOYSA-N meta--hydroxybenzoic acid Natural products OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical class COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 150000002772 monosaccharides Chemical group 0.000 description 1
- 235000021290 n-3 DPA Nutrition 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920001515 polyalkylene glycol Chemical group 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 235000014438 salad dressings Nutrition 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- RYMZZMVNJRMUDD-HGQWONQESA-N simvastatin Chemical compound C([C@H]1[C@@H](C)C=CC2=C[C@H](C)C[C@@H]([C@H]12)OC(=O)C(C)(C)CC)C[C@@H]1C[C@@H](O)CC(=O)O1 RYMZZMVNJRMUDD-HGQWONQESA-N 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- DPUOLQHDNGRHBS-MDZDMXLPSA-N trans-Brassidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-MDZDMXLPSA-N 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- the washing performance-enhancing effect of the active ingredients to be used according to the invention occurs in the next washing process, even if, if desired, a detergent without an active ingredient to be used according to the invention is used again.
- a detergent without an active ingredient to be used according to the invention is used again.
- the active ingredient essential to the invention is added in the fabric softener cycle, in particular for machine laundry.
- the use according to the invention in the context of a laundry aftertreatment process can accordingly take place in such a way that the soil-releasing active ingredient of the washing liquor is removed is added separately, which is used after the wash cycle carried out using a detergent, or it is incorporated as a component of the laundry aftertreatment agent, in particular a fabric softener.
- the detergent used before the laundry aftertreatment agent can also contain an active ingredient to be used according to the invention, but can also be free of this.
- the relative molecular weight of the homopolymers of unsaturated carboxylic acids is generally between 5000 g / mol and 200,000 g / mol, that of the copolymers between 2000 g / mol and 200,000 g / mol, preferably 50,000 g / mol to 120,000 g / mol, based on the free acid .
- a particularly preferred acrylic acid-maleic acid copolymer has a relative molecular weight of 50,000 g / mol to 100,000 g / mol.
- these polyesters composed as described above can also be end-group-capped, with possible end groups being alkyl groups with 1 to 22 carbon atoms and esters of monocarboxylic acids.
- the end groups bonded via ester bonds can be based on alkyl, alkenyl and aryl monocarboxylic acids having 5 to 32 carbon atoms, in particular 5 to 18 carbon atoms.
- polyester-active soil-releasing polymers are preferably water-soluble, the term "water-soluble" having a solubility of at least 0.01 g, preferably at least 0.1 g of the polymer per liter of water at room temperature and pH 8 should be understood.
- polymers used with preference have a solubility of at least 1 g per liter, in particular at least 10 g per liter, under these conditions.
- the fatty acids and the triethanolamine can generally be used in a molar ratio of 1.1: 1 to 3: 1.
- a use ratio of 1.2: 1 to 2.2: 1, preferably 1.5: 1 to 1.9: 1 has proven to be particularly advantageous.
- the esterquats used with preference are technical mixtures of mono-, di- and triesters with one average degree of esterification of 1.5 to 1.9 and are derived from technical C 16/18 tallow or. Palm fatty acid (iodine number 0 to 40).
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102020200175.8A DE102020200175A1 (de) | 2020-01-09 | 2020-01-09 | Carboxymethylierte Poly(2-Vinylpyridine) als schmutzablösevermögende Wirkstoffe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3848441A1 true EP3848441A1 (fr) | 2021-07-14 |
Family
ID=73855828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20215522.2A Withdrawn EP3848441A1 (fr) | 2020-01-09 | 2020-12-18 | Poly(2-vinylpyridine) carboxyméthylée comme principe actif facilitant l'élimination des saletés |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP3848441A1 (fr) |
| DE (1) | DE102020200175A1 (fr) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2977341A (en) * | 1955-04-13 | 1961-03-28 | American Cyanamid Co | Polymers of vinyl pyridinium betaines |
| US4000093A (en) | 1975-04-02 | 1976-12-28 | The Procter & Gamble Company | Alkyl sulfate detergent compositions |
| US4136038A (en) | 1976-02-02 | 1979-01-23 | The Procter & Gamble Company | Fabric conditioning compositions containing methyl cellulose ether |
| EP0213729A1 (fr) | 1985-07-29 | 1987-03-11 | Unilever Plc | Compositions détergentes |
| EP0213730A1 (fr) | 1985-07-29 | 1987-03-11 | Unilever Plc | Composition détergente avec des propriétés adoucissantes de tissus |
| US5869442A (en) * | 1997-09-19 | 1999-02-09 | Isp Investments Inc. | Fabric softening compositions with dye transfer inhibitors for improved fabric appearance |
| WO1999015614A1 (fr) * | 1997-09-19 | 1999-04-01 | Isp Investments Inc. | Polymeres de complexion tinctoriale soluble dans l'eau utilises comme inhibiteurs de transfert pigmentaire dans un detergent a lessive ou des compositions d'assouplissement de tissus |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5863880A (en) * | 1997-09-19 | 1999-01-26 | Isp Investments Inc. | Laundry detergent compositions containing water soluble dye complexing polymers |
-
2020
- 2020-01-09 DE DE102020200175.8A patent/DE102020200175A1/de not_active Withdrawn
- 2020-12-18 EP EP20215522.2A patent/EP3848441A1/fr not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2977341A (en) * | 1955-04-13 | 1961-03-28 | American Cyanamid Co | Polymers of vinyl pyridinium betaines |
| US4000093A (en) | 1975-04-02 | 1976-12-28 | The Procter & Gamble Company | Alkyl sulfate detergent compositions |
| US4136038A (en) | 1976-02-02 | 1979-01-23 | The Procter & Gamble Company | Fabric conditioning compositions containing methyl cellulose ether |
| EP0213729A1 (fr) | 1985-07-29 | 1987-03-11 | Unilever Plc | Compositions détergentes |
| EP0213730A1 (fr) | 1985-07-29 | 1987-03-11 | Unilever Plc | Composition détergente avec des propriétés adoucissantes de tissus |
| US5869442A (en) * | 1997-09-19 | 1999-02-09 | Isp Investments Inc. | Fabric softening compositions with dye transfer inhibitors for improved fabric appearance |
| WO1999015614A1 (fr) * | 1997-09-19 | 1999-04-01 | Isp Investments Inc. | Polymeres de complexion tinctoriale soluble dans l'eau utilises comme inhibiteurs de transfert pigmentaire dans un detergent a lessive ou des compositions d'assouplissement de tissus |
Non-Patent Citations (2)
| Title |
|---|
| BILLING MARK ET AL: "Sulfo-and carboxybetaine-containing polyampholytes based on poly(2-vinyl pyridine)s: Synthesis and solution behavior", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 104, 28 September 2016 (2016-09-28), pages 40 - 48, XP029787053, ISSN: 0032-3861, DOI: 10.1016/J.POLYMER.2016.09.081 * |
| BILLING, M.ELTER, J. K.SCHACHER, F. H., POLYMER, vol. 104, 2016, pages 40 - 48 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102020200175A1 (de) | 2021-07-15 |
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