EP3806646A1 - Gelatin-free gelled confectionery and method for preparing such a confectionery - Google Patents

Gelatin-free gelled confectionery and method for preparing such a confectionery

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Publication number
EP3806646A1
EP3806646A1 EP19742439.3A EP19742439A EP3806646A1 EP 3806646 A1 EP3806646 A1 EP 3806646A1 EP 19742439 A EP19742439 A EP 19742439A EP 3806646 A1 EP3806646 A1 EP 3806646A1
Authority
EP
European Patent Office
Prior art keywords
confectionery
gelatin
waxy starch
branched maltodextrins
starch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19742439.3A
Other languages
German (de)
French (fr)
Inventor
Sylvie Lagache
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roquette Freres SA
Original Assignee
Roquette Freres SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roquette Freres SA filed Critical Roquette Freres SA
Publication of EP3806646A1 publication Critical patent/EP3806646A1/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/42Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/0002Processes of manufacture not relating to composition and compounding ingredients
    • A23G3/0004Processes specially adapted for manufacture or treatment of sweetmeats or confectionery
    • A23G3/0019Shaping of liquid, paste, powder; Manufacture of moulded articles, e.g. modelling, moulding, calendering
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/02Apparatus specially adapted for manufacture or treatment of chewing gum
    • A23G4/04Apparatus specially adapted for manufacture or treatment of chewing gum for moulding or shaping
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/10Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • A23L29/35Degradation products of starch, e.g. hydrolysates, dextrins; Enzymatically modified starches
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Definitions

  • the present invention relates to a new gelled confectionery, more particularly a soft candy or a chewy dough comprising a gelatinizing agent and a soluble fiber giving the said bungs their excellent chewability, in terms of hardness and elasticity.
  • the present invention also relates to a process for preparing such a confectionery.
  • Confectionery products are numerous. They all have in common the cooking of sugar and its mixing with other ingredients to obtain different specialties and flavors.
  • gelled confectionery means chewing pastes and jellies, which form part of the tender articles compared to boiled sweets, as well as caramels, toffees, fudges, lozenges (fondants), fondants and fodder traditionally containing gelatin.
  • confectionery products are in particular made up of sugars or polyols, sweetening agents, fat, emulsifying agents, flavorings, colorings, mineral and / or organic acids and / or bases and their salts and one or more thickening hydrocolloids and / or gelling agents of plant or animal origin such as gum arabic, gelatin, pectin, carrageenans, alginates, celluloses and starch.
  • Soft gums include more particularly jellies and gums ("jelly beans”, “wine gums”), traditionally prepared on the basis of gelatin and / or starch used as a gelling agent and providing the elasticity required for these tender, textured articles. elastic to plastic.
  • the chews are obtained by cooking a mixture of sugar and glucose syrup to which a small amount of fat has been added.
  • the terracotta is then aerated to lighten it by one of the processes well known by confectioners such as, for example, drawing, threshing, possibly under pressure, mixing under pressure, extrusion.
  • Caramels, toffees, fudges, lozenges and fillings traditionally containing gelatin are also concerned by the present invention.
  • composition of caramels, toffees, fudges can vary to a large extent depending on the intensity of color and taste as well as the texture desired.
  • the residual humidity of such products varies between 3 and 10%, sucrose between 30 and 60%, invert sugar between 1 and 10%, glucose syrup (expressed as dry) between 20 and 50%, materials fat between 1 and 15%, lactose between 1 and 6% and milk proteins between 0.75 and 15%.
  • Hard caramels have a residual humidity of 3 to 4% and a hard and smooth texture, while soft / toffed caramels have a relative humidity of 7 to 10% and a soft and chewable texture, and fudges have a moisture content 7 to 9% residual for a tender but short texture.
  • caramels soft or hard
  • toffees whether or not accompanied by a qualifier, are reserved for confectionery prepared by cooking sugar, glucose (or invert sugar), edible fats (butyric fat , vegetable fat and / or animal fat) and milk proteins, the fats and milk proteins must be in proportion such that the finished product contains at least 6% fat and 6% dry matter from milk.
  • Fat forages are all mixtures obtained from sugar, or any other mass sweetener such as polyols, and vegetable and / or animal fats, which traditionally contain milk proteins and which are intended to be used as filling filling in confectionery, pastry, bakery, biscuit and all other food fields.
  • mass sweetener such as polyols
  • vegetable and / or animal fats which traditionally contain milk proteins and which are intended to be used as filling filling in confectionery, pastry, bakery, biscuit and all other food fields.
  • Such examples are, for example, praline fatty fillings, fancy “chocolate” fatty fillings.
  • the gelatin used in all these gelled confectionery is an animal protein extracted, after partial hydrolysis, from raw materials rich in collagen extracted from the skin, bones, cartilage, ligaments, etc.
  • gelatin produced from fish, but it represents only a very small percentage of the gelatin food produced today in Europe (less than 3%).
  • gelatin When ready to use, gelatin is a translucent solid, transparent or slightly yellow, with a characteristic odor and taste. Gelatin is widely used in the confectionery sector. It is its elasticity which is very appreciated because it gives a very particular sensation to chewing.
  • gelatin has had poor press. Following the emergence of spongiform encephalitis in cattle, the use of gelatin in food preparations is today very controversial.
  • Gelatin also has a high cost price which can hinder its use, especially for emerging countries.
  • gelatin is a protein very sensitive to pH conditions and extreme temperatures (very acidic pH, very high temperatures) in which it tends to degrade, thus losing its gelling properties.
  • amylose acts as a gelling agent, that amylopectin gives elasticity to the products but gels more slowly and increases viscosity much more than amylose, that amylose gives opaque gels while amylopectin gives transparent products.
  • the confectionery products prepared according to the teaching of this patent application EP 2,919,589 A maintain a texture, chewability, duration in the mouth and palatability at least similar, or even improved compared to confectionery products traditionally comprising gelatin.
  • the gelatin can be partially or completely substituted.
  • the confectionery gelled comprising a waxy pregelatinized starch with at least one other ingredient chosen from branched maltodextrins (marketed by the Applicant under the trade name NUTRIOSE Âź), sorbitol and glycerin, in particular proportions.
  • NUTRIOSE Âź branched maltodextrins
  • a confectionery comprising from 50 to 75%, preferably from 56 to 62% of branched maltodextrins, which moreover made it possible to qualify the gelled confectionery thus obtained of " high in fiber ”.
  • the person skilled in the confectionery industry therefore deduces from the teaching of this document, that for an optimized rate of pregaxatinized waxy starch used as a gelatin substitute in gelled confectionery, ie at a value between 4 and 8% by weight relative to the total weight of the confectionery, it was preferable to choose a rate of incorporation of branched maltodextrins of between 2 and 10%, and preferably from 4 to 8% by weight relative to the total weight of the confectionery.
  • a first object of the invention therefore relates to a gelatin-free gelatin confectionery comprising:
  • the gelled confectionery according to the invention thus has a satisfactory texture with in particular an optimal balancing between the hardness properties and the elasticity properties.
  • a second subject of the invention relates to a premix consisting of pregaxatinized waxy starch and branched maltodextrins, said premix being characterized in that it comprises a weight ratio of pregaxatinized waxy starch / branched maltodextrins of 1 to 8.
  • the premix according to the invention finds a very particular use in the manufacture of gelled confectionery free from gelatin.
  • a third subject of the invention relates to a process for the preparation of gelatin-free gelatin confectionery comprising the steps of:
  • a first object of the invention therefore relates to a gelatin-free gelatin confectionery comprising:
  • gelled confectionery exhibits good firmness while preserving the elasticity required for chewing.
  • the hardness and elasticity measurements are carried out at a temperature of 20 ° C. on an INSTRON 5966 texturometer with a “finger punch” type geometry and by imposing a deformation at 30% of the height of the sample for 2 minutes and a test speed of 10 mm / min.
  • the expression “gelled confectionery” must be interpreted as designating all the confectionery products usually containing gelatin. These include hard gums, soft gums, chews, liquorice, jellies, pastilles, fruit pastes, caramels, toffees, fondants, fudges and fillings, lozenges , as well as inclusions for ice creams or pastries, or even all confectionery of the same type called pharmaceutical and containing an active ingredient for example. All these items are part of the tender items compared to boiled sugars.
  • gelled confectionery is chews very appreciated by consumers for their property of high chewability making them approach a chewing gum or a chewing gum.
  • the expression “waxy starch” designates all the varieties of starch containing an amylopectin content greater than or equal to 80%, preferably greater than or equal to 90% and even more preferably, greater or less equal to 95%.
  • said waxy starch comes from one or more botanical varieties chosen from corn, rice, potato, wheat and any mixtures thereof.
  • the botanical varieties can be wild or hybrid and therefore have undergone genetic modifications to modify their genome.
  • pregaxatinized waxy starch and “precooked waxy starch” are used interchangeably to designate any waxy starch which has undergone a heat treatment in the presence of water, so that it almost loses its entire structure. granular and that it becomes soluble in cold water.
  • pregaxatinized waxy starch or precooked starch is meant within the meaning of the invention a state in which the starch is almost no longer in a granular state, that is to say in a state where it is not no longer in a state in semi-crystalline granules characteristic of the state in which it is naturally present in the organs and reserve tissues of higher plants, in particular in cereal seeds, legume seeds, potato tubers or cassava, roots, bulbs, stems and fruit.
  • This semi-crystalline state is mainly due to the macromolecules of amylopectin, one of the two main constituents of starch.
  • the waxy starch can be used in the form of pregelatinized waxy starch or also in the form of native waxy starch, the gelatinization then taking place during the manufacturing process of the gelled confectionery.
  • the gelatinization of waxy starch can be obtained prior to the preparation of the gelled confectionery by the supply of a waxy pregelatinized starch or during the preparation as such.
  • the choice of gelatinizing waxy starch before its use or during the confectionery manufacturing process is based on the choice of cooker used in the cooking step.
  • the person skilled in the art may advantageously prefer to use waxy starch in its native form, and to cook it, for example in the presence of other confectionery ingredients such as described below, in order to burst the grain of starch while concentrating the syrup until the dry extract necessary for a satisfactory texture.
  • the waxy pregelatinized starches according to the present invention can for example be obtained by hydrothermal treatment of gelatinization of native starches, in particular by steam cooking, jet-cooker cooking, drum cooking, cooking in kneader / extruder or microwave systems then drying , for example in an oven, by hot air on a fluidized bed, on a rotary drum, by atomization, by extrusion or by lyophilization.
  • Such starches generally have a solubility in demineralized water at 20 ° C. of more than 5%, and more generally between 10 and 100%, and a starch crystallinity level of less than 15%, generally less than 5%, and most often less than 1%, or even zero. Examples include products manufactured and marketed by the Applicant under the brand name PREGEFLO Âź.
  • the gelled confectionery according to the invention also comprises from 0.5% to 1.5% of branched maltodextrins.
  • the gelled confectionery comprises from 0.5% to 1% of branched maltodextrins, and very particularly approximately 1% of branched maltodextrins. The percentages are expressed in dry weight relative to the total weight of the confectionery.
  • branched maltodextrins within the meaning of the invention means the specific maltodextrins identical to those described in patent EP 1,006,128 B1 of which the Applicant is the holder.
  • branched maltodextrins have the advantage of being a source of indigestible fibers beneficial for metabolism and intestinal balance.
  • said branched maltodextrins can have: between 15 and 50% of glucosidic linkages 1-6, preferably between 22% and 45%, more preferably between 20% and 40%, and even more preferably between 25% and 35%,
  • the branched maltodextrins of the gelled confectionery have between 15% and 35% of glycosidic bonds 1-6, a reducing sugar content of less than 20%, an average molecular mass by weight MW of between 4000 and 6000 g / mole, and a number average molecular mass Mn of between 250 and 4500 g / mole.
  • branched maltodextrins described in the above-mentioned application can also be used in accordance with the invention. These are, for example, branched maltodextrins of high molecular weight having a reducing sugar content of at most 5 and a number-average molecular mass Mn of between 2000 and 4500 g / mole. Branched maltodextrins of low molecular weight having a reducing sugar content of between 5 and 20% and a number average molecular mass Mn of less than 2000 g / mole can also be used.
  • the branched maltodextrin is derived from the range NUTRIOSE Âź which is a complete range of soluble fibers known for their benefits which are manufactured and marketed by the Applicant.
  • the products in the NUTRIOSE Âź range are derivatives of partially hydrolyzed wheat starch or corn starch, which contain up to 85% fiber. This richness in fibers makes it possible to increase digestive tolerance, to improve calorie management, to prolong the release of energy and to obtain a lower sugar level.
  • the NUTRIOSE Âź range is one of the best tolerated fibers available on the market. It shows a higher digestive tolerance, allowing better incorporation than other fibers, which represents real nutritional benefits.
  • branched maltodextrins as NUTRIOSEÂź Âź in jelly confectionery of the present invention are numerous.
  • the branched maltodextrins of this range also present a significant technical interest. Indeed, they are made up of long polymeric carbohydrate chains and therefore play a role of texturing agent in confectionery.
  • Tg glass transition temperature
  • the gelled confectionery according to the invention thus comprises an intermediate hardness of 6 to 8 N and an average elasticity of 7% to 9% and thus exhibits good firmness while preserving the elasticity required for chewing.
  • the gelled confectionery according to the invention thus comprises a ratio by weight of waxy pregelatinized starch / branched maltodextrins of 1 to 8.
  • the ratio by weight of waxy pregelatinized starch / branched maltodextrins is between 2 and 6, more preferably from 3 to 5, and more particularly, it is approximately 4.
  • Another particularly advantageous property of the present invention is that the various constituents used, namely pregaxatinized waxy starch and branched maltodextrins, do not need to be hydrated before their incorporation, unlike gelatin. Their use is therefore simpler.
  • gelatin hydration step was a critical step in the confectionery manufacturing process because it involves a significant risk of introducing bacteria into the preparations.
  • gelatin is an excellent support for the development of bacteria.
  • the gelled confectionery according to the present invention therefore also turns out to be more hygienic since they are less loaded with bacteria.
  • the gelled confectionery according to the invention also comprises a regulating or depressant agent for water activity chosen from sorbitol, glycerin and mixtures thereof.
  • the confectionery comprises from 0.1% to 15% of a regulating or depressant agent for water activity, preferably from 1% to 8%, even more preferably 2% to 6 %, the percentages being expressed by weight in dry weight relative to the total weight of the confectionery.
  • Water activity or aw (“activity water”) represents the amount of free water available within a food for possible subsequent biochemical reactions. It does not represent the water content (or humidity) but the availability of this water.
  • the gelled confectionery of the present invention has the particularity of having an aw lower than the aw traditionally measured in gelled confectionery usually containing gelatin.
  • the gelled confectionery can also comprise glucose syrups.
  • glucose syrups are the hydrolysis products of starch having a DE (dextrose equivalent) greater than 20.
  • DE dexextrose equivalent
  • starch hydrolysis means any acid or enzymatic hydrolysis process starch from legumes, cereals or tubers. Various hydrolysis processes are known and have been generally described on pages 51 1 and 512 of the book Encyclopedia of Chemical Technology by Kirk-Othmer, 3rd Edition, Vol. 22, 1978.
  • the gelled confectionery also comprises one or more sweeteners.
  • Various sweeteners can be used, such as sugars or polyols, in the form of powder or syrup.
  • the sugars are chosen from the group consisting of monosaccharides, disaccharides, trisaccharides, oligo and polysaccharides such as, for example, glucose syrups, glucose-fructose, fructose-glucose, glucose syrups rich in maltose, sucrose , fructose, maltose, trehalose, mannose, dextrose, tagatose or isomaltulose, alone or as a mixture between them.
  • monosaccharides such as, for example, glucose syrups, glucose-fructose, fructose-glucose, glucose syrups rich in maltose, sucrose , fructose, maltose, trehalose, mannose, dextrose, tagatose or isomaltulose, alone or as a mixture between them.
  • the polyols are preferably chosen from the group consisting of maltitol, mannitol, erythritol, xylitol, iditol, maltitol syrups, isomalt, lactitol, hydrogenated glucose syrups, alone or as a mixture between them.
  • We can also use any kind intense sweeteners such as, for example, saccharin, aspartame or acesulfame K, used alone or in synergistic mixtures.
  • sorbitol is not used as a sweetening agent in the confectionery according to the invention.
  • the sweetening agent preferably represents 25% to 85%, preferably from 40% to 85%, and even more preferably from 60% to 85% by weight relative to the total weight of the gelled confectionery.
  • the gelled confectionery can comprise one or more compounds chosen from non-reducing sugars, fats, emulsifying agents, preserving agents, bulking agents, foaming agents, gelling agents, agents humectants, acidifiers, natural or synthetic flavors, flavor enhancers, vitamins, pharmaceutical active ingredients, minerals such as calcium, magnesium and other food supplements such as DHA, natural or synthetic colors, salts, acids, or various elements intended either to improve the quality, or to flavor the composition such as dried fruits, candied fruits, dried or otherwise processed fruits (pressed, concentrated, powdered), as well as fruit purees, fruit pulps, which are generally present in said confectionery at a level of 0 to 30% by weight relative to the total weight of the confectionery.
  • a second subject of the invention relates to a premix consisting of pregaxatinized waxy starch and branched maltodextrins, said premix being characterized in that it comprises a weight ratio of pregaxatinized waxy starch / branched maltodextrins of 1 to 8.
  • the weight ratio of pregaxatinized waxy starch / branched maltodextrins is from 2 to 6, more preferably from 3 to 5, and very particularly, it is approximately 4.
  • the premix according to the invention finds a very particular use in the manufacture of gelled confectionery free from gelatins as described above.
  • a third object of the invention relates to a process for the preparation of gelatin-free gelatin confectionery comprising the steps of:
  • Waxy pregelatinized starch and branched maltodextrins are as defined above.
  • the sweeteners are also as defined above and preferably represent from 25% to 85%, more preferably from 40% to 85%, and more preferably still from 60% to 85% by dry weight relative to the total weight of the final product. .
  • the first step of the process according to the invention therefore consists in preparing a mixture based on waxy starch, branched maltodextrins, at least one sweetener and water.
  • the waxy starch of the mixture is a native starch, that is to say a waxy starch always having its granular structure.
  • the cooker used in the step of cooking the mixture is adapted by a person skilled in the art so that the gelatinization of waxy starch occurs during said cooking step.
  • the waxy starch of the mixture is a pregelatinized waxy starch, that is to say a starch which has undergone a heat treatment in the presence of water so that it almost entirely loses its granular structure and that it becomes soluble in cold water.
  • the pregaxatinized waxy starch is supplied in premix with the branched maltodextrins.
  • the premix thus comprises a weight ratio of pregaxatinized waxy starch / branched maltodextrins of from 1 to 8.
  • the weight ratio of pregaxatinized waxy starch / branched maltodextrins is of from 2 to 6, more preferably of 3 to 5, and more particularly, it is approximately 4.
  • the method according to the invention comprises, after the step of shaping the cooked mixture, a step of recovering said gelled confectionery.
  • the preparation process also further includes a step of adding glucose syrup to the mixture comprising pregaxatinized waxy starch and branched maltodextrins.
  • the method according to the invention may also comprise a step of adding to the mixture of a regulating or depressant agent of the water before the cooking step.
  • a regulating or depressant agent of the water we will then advantageously take sorbitol, incorporated into the recipe at a rate of 2 to 3% by dry weight relative to the total weight of the final product.
  • the method according to the invention makes it possible to dispense with a prior hydration step characteristic of the gelling confectionery manufacturing processes.
  • the preparation process according to the invention also comprises a step of cooking the mixture comprising waxy starch, branched maltodextrins, at least one sweetener and water.
  • the cooking step can be carried out on double-envelope cookers at atmospheric pressure, under partial or total vacuum or under pressure, or continuously on high-pressure cookers such as tubular exchangers, plate exchangers or “jet cookers”. ".
  • the “jet-cooker” can include one or more steam injectors, which changes the cooking times. The injection of live steam into the product ensures rapid and uniform dispersion of heat and ingredients.
  • the tubular exchanger requires a homogeneous dispersion of all the ingredients before cooking, the cooking times are longer and the intensity less strong (cooker scraped surface or cooking screw - atmospheric).
  • the sweeteners For continuous production, it is preferable to disperse the sweeteners, pregaxatinized waxy starch, the branched maltodextrins and the regulating agent in a mixing tank, preheat this mixture to around 70-80 ° C to dissolve the sweeteners, cook the mixture on a high-pressure cooker at a temperature between 100 and 150 ° C depending on the desired texture and the type of confection prepared, then add the fatty matter, the emulsifier the abundant agent (s), the flavors, the colors, the active ingredients, and intense sweeteners.
  • the method according to the invention comprises a step of adding fat after the cooking step.
  • the method comprises a step of adding one or more compounds chosen from non-reducing sugars, fats, emulsifying agents, preserving agents, abundant agents, foaming agents, agents gelling agents, humectants, acidifiers, natural or synthetic flavors, flavor enhancers, vitamins, pharmaceutical active ingredients, minerals such as calcium, magnesium and other food supplements such as DHA, natural or synthetic colors , salts, acids, or various elements intended either to improve the quality or to flavor the composition such as dried fruits, candied fruits, dried or otherwise processed fruits (pressed, concentrated, powdered), as well as fruit purees, fruit pulps.
  • the method comprises a step of adding one or more compounds chosen from emulsifying agents and acids.
  • the confectionery obtained is shaped and fluffed.
  • the fat may be added before if an emulsion is produced beforehand.
  • the objective is to produce gummy confectionery of the chewing paste type containing sugar according to the present invention but not containing gelatin.
  • chewing pastes were produced by incorporating, with each new test, variable proportions of pregaxatinized waxy starch and branched maltodextrins, and measurements of the elasticity and hardness of the chewing pastes thus obtained were carried out.
  • the branched maltodextrins used are NUTRIOSE Âź FM06.
  • the glucose syrup used is the C4280S glucose syrup sold by the company
  • the fat used is Copra 24/26 fat.
  • Sucroesters are sucrose and fatty acid esters obtained by transesterification of methyl esters and sucrose, used as non-ionic emulsifiers for fatty substances, and marketed by the company StĂ©arinerie Dubois (Boulogne, France).
  • the previous mixture at a determined temperature and at atmospheric pressure to obtain a mixture of 90-94% dry matter.
  • the cooking temperature is between 105 and 150 ° C. It is also possible to cook the previous mixture under vacuum at a pressure of -0.5 bar. Mix well during the cooking step to prevent the mixture from burning.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Nutrition Science (AREA)
  • Dispersion Chemistry (AREA)
  • Confectionery (AREA)
  • Jellies, Jams, And Syrups (AREA)

Abstract

The present invention relates to a novel gelatin-free gelled confectionery comprising 2 % to 4 % of pregelatinized waxy starch and 0.5 % to 1.5 % of branched maltodextrins, wherein the percentages are expressed in dry weight relative to the total weight of the final product. The invention also relates to a method for preparing such a confectionery.

Description

CONFISERIE GELIFIEE EXEMPTE DE GELATINE ET  GELATINE FREE GEL CONFECTIONERY AND
PROCEDE DE PREPARATION D’UNE TELLE CONFISERIE  PROCESS FOR PREPARING SUCH A CONFECTIONERY
DOMAINE DE L’INVENTION FIELD OF THE INVENTION
La prĂ©sente invention concerne une nouvelle confiserie gĂ©lifiĂ©e, plus particuliĂšrement un bonbon tendre ou une pĂąte Ă  mĂącher comprenant un agent gĂ©latinisant et une fibre soluble procurant aux dits bondons leur excellente masticabilitĂ©, en termes de duretĂ© et d’élasticitĂ©.  The present invention relates to a new gelled confectionery, more particularly a soft candy or a chewy dough comprising a gelatinizing agent and a soluble fiber giving the said bungs their excellent chewability, in terms of hardness and elasticity.
La prĂ©sente invention concerne Ă©galement un procĂ©dĂ© de prĂ©paration d’une telle confiserie.  The present invention also relates to a process for preparing such a confectionery.
ARRIERE-PLAN TECHNOLOGIQUE TECHNOLOGICAL BACKGROUND
Les produits de confiserie sont nombreux. Ils ont tous en commun la cuisson du sucre et son mĂ©lange avec d’autres ingrĂ©dients pour obtenir des spĂ©cialitĂ©s et des parfums diffĂ©rents.  Confectionery products are numerous. They all have in common the cooking of sugar and its mixing with other ingredients to obtain different specialties and flavors.
On entend par confiserie gélifiée au sens de la présente invention les pùtes à mùcher et les gelées, qui font partie des articles tendres par rapport aux sucres cuits, ainsi que les caramels, toffées, fudges, les lozenges (« pastilles »), les fondants et les fourrages contenant traditionnellement de la gélatine.  For the purposes of the present invention, the term "gelled confectionery" means chewing pastes and jellies, which form part of the tender articles compared to boiled sweets, as well as caramels, toffees, fudges, lozenges (fondants), fondants and fodder traditionally containing gelatin.
Ces confiseries sont notamment constituĂ©es de sucres ou polyols, d’agents Ă©dulcorants, de matiĂšre grasse, d’agents Ă©mulsifiants, d’arĂŽmes, de colorants, d’acides et/ou de bases minĂ©rales et/ou organiques et leurs sels et d’un ou plusieurs hydrocolloĂŻdes Ă©paississants et/ou gĂ©lifiants d’origine vĂ©gĂ©tale ou animale tels que la gomme arabique, la gĂ©latine, la pectine, les carraghĂ©nanes, les alginates, les celluloses et l’amidon.  These confectionery products are in particular made up of sugars or polyols, sweetening agents, fat, emulsifying agents, flavorings, colorings, mineral and / or organic acids and / or bases and their salts and one or more thickening hydrocolloids and / or gelling agents of plant or animal origin such as gum arabic, gelatin, pectin, carrageenans, alginates, celluloses and starch.
Il n'existe pas de définitions précises de ces différentes confiseries gélifiées, que l'on peut classer arbitrairement en gommes dures et gommes tendres.  There are no precise definitions of these different gelled confectionery products, which can be arbitrarily classified into hard gums and soft gums.
Les gommes tendres regroupent plus particuliÚrement les gelées et les gommes ("jelly beans", "wine gums"), traditionnellement préparées à base de gélatine et/ou amidon employée comme agent gélifiant et apportant l'élasticité requise pour ces articles tendres, de texture élastique à plastique.  Soft gums include more particularly jellies and gums ("jelly beans", "wine gums"), traditionally prepared on the basis of gelatin and / or starch used as a gelling agent and providing the elasticity required for these tender, textured articles. elastic to plastic.
Les pĂątes Ă  mĂącher sont obtenues par cuisson d’un mĂ©lange de sucre et de sirop de glucose auxquels a Ă©tĂ© ajoutĂ©e une faible quantitĂ© de matiĂšre grasse.  The chews are obtained by cooking a mixture of sugar and glucose syrup to which a small amount of fat has been added.
La masse cuite est ensuite aĂ©rĂ©e pour l’allĂ©ger par l’un des procĂ©dĂ©s bien connu des confiseurs comme par exemple l’étirage, le battage, Ă©ventuellement sous pression, le mixage sous pression, l’extrusion.  The terracotta is then aerated to lighten it by one of the processes well known by confectioners such as, for example, drawing, threshing, possibly under pressure, mixing under pressure, extrusion.
C’est cette aĂ©ration et la prĂ©sence de matiĂšres grasses qui donnent aux pĂątes Ă  mĂącher leur texture caractĂ©ristique. Les caramels, toffĂ©es, fudges, lozenges et fourrages contenant traditionnellement de la gĂ©latine sont Ă©galement concernĂ©s par la prĂ©sente invention. It is this ventilation and the presence of fat that gives chewy cheeses their characteristic texture. Caramels, toffees, fudges, lozenges and fillings traditionally containing gelatin are also concerned by the present invention.
La composition des caramels, toffĂ©es, fudges peut varier dans une large mesure en fonction de l’intensitĂ© de couleur et de goĂ»t ainsi que de la texture recherchĂ©es.  The composition of caramels, toffees, fudges can vary to a large extent depending on the intensity of color and taste as well as the texture desired.
GĂ©nĂ©ralement, l’humiditĂ© rĂ©siduelle de tels produits varie entre 3 et 10 %, le saccharose entre 30 et 60 %, le sucre inverti entre 1 et 10 %, le sirop de glucose (exprimĂ© sur sec) entre 20 et 50 %, les matiĂšres grasses entre 1 et 15 %, le lactose entre 1 et 6 % et les protĂ©ines laitiĂšres entre 0,75 et 15 %.  Generally, the residual humidity of such products varies between 3 and 10%, sucrose between 30 and 60%, invert sugar between 1 and 10%, glucose syrup (expressed as dry) between 20 and 50%, materials fat between 1 and 15%, lactose between 1 and 6% and milk proteins between 0.75 and 15%.
Technologiquement, il est possible de classer ces spécialités en trois groupes principaux en fonction de leur teneur en humidité résiduelle et de leur texture.  Technologically, it is possible to classify these specialties into three main groups according to their residual moisture content and their texture.
Les caramels durs ont une humidité résiduelle de 3 à 4 % et une texture dure et lisse, alors que les caramels mous/toffées ont une humidité relative de 7 à 10 % et une texture tendre et masticable, et les fudges ont une teneur en humidité résiduelle de 7 à 9 % pour une texture tendre mais courte.  Hard caramels have a residual humidity of 3 to 4% and a hard and smooth texture, while soft / toffed caramels have a relative humidity of 7 to 10% and a soft and chewable texture, and fudges have a moisture content 7 to 9% residual for a tender but short texture.
Les appellations « caramels (tendres ou durs) » et « toffĂ©es », accompagnĂ©es ou non d’un qualificatif, sont rĂ©servĂ©es Ă  des confiseries prĂ©parĂ©es par cuisson du sucre, de glucose (ou de sucre inverti), de matiĂšres grasses alimentaires (graisse butyrique, graisse vĂ©gĂ©tale et/ou graisse animale) et de protĂ©ines laitiĂšres, les matiĂšres grasses et les protĂ©ines laitiĂšres devant ĂȘtre en proportion telles que le produit fini contienne au minimum 6 % de matiĂšres grasses et 6 % de matiĂšres sĂšches provenant du lait.  The names “caramels (soft or hard)” and “toffees”, whether or not accompanied by a qualifier, are reserved for confectionery prepared by cooking sugar, glucose (or invert sugar), edible fats (butyric fat , vegetable fat and / or animal fat) and milk proteins, the fats and milk proteins must be in proportion such that the finished product contains at least 6% fat and 6% dry matter from milk.
Les fourrages gras sont tous les mĂ©langes obtenus Ă  partir de sucre, ou de tout autre Ă©dulcorant de masse comme par exemple les polyols, et de matiĂšres grasses vĂ©gĂ©tales et/ou animales, qui contiennent traditionnellement des protĂ©ines laitiĂšres et qui sont destinĂ©s Ă  ĂȘtre utilisĂ©s comme garniture de remplissage en confiserie, pĂątisserie, boulangerie, biscuiterie et tout autre domaine alimentaire. De tels exemples sont par exemple des fourrages gras pralinĂ©s, des fourrages gras fantaisie « chocolat ».  Fat forages are all mixtures obtained from sugar, or any other mass sweetener such as polyols, and vegetable and / or animal fats, which traditionally contain milk proteins and which are intended to be used as filling filling in confectionery, pastry, bakery, biscuit and all other food fields. Such examples are, for example, praline fatty fillings, fancy “chocolate” fatty fillings.
La gélatine utilisée dans toutes ces confiseries gélifiées est une protéine animale extraite, aprÚs hydrolyse partielle, de matiÚres premiÚres riches en collagÚne extrait de la peau, des os, des cartilages, des ligaments, etc.  The gelatin used in all these gelled confectionery is an animal protein extracted, after partial hydrolysis, from raw materials rich in collagen extracted from the skin, bones, cartilage, ligaments, etc.
Il existe Ă©galement de la gĂ©latine produite Ă  partir de poissons, mais elle ne reprĂ©sente qu’un trĂšs faible pourcentage de la gĂ©latine alimentaire fabriquĂ©e aujourd’hui en Europe (moins de 3%).  There is also gelatin produced from fish, but it represents only a very small percentage of the gelatin food produced today in Europe (less than 3%).
Une fois prĂȘte Ă  l’emploi, la gĂ©latine est une substance solide translucide, transparente ou lĂ©gĂšrement jaune, possĂ©dant une odeur et un goĂ»t caractĂ©ristiques. La gĂ©latine est trĂšs utilisĂ©e dans le domaine de la confiserie. C’est son Ă©lasticitĂ© qui est trĂšs apprĂ©ciĂ©e car elle procure une sensation trĂšs particuliĂšre Ă  la mastication. When ready to use, gelatin is a translucent solid, transparent or slightly yellow, with a characteristic odor and taste. Gelatin is widely used in the confectionery sector. It is its elasticity which is very appreciated because it gives a very particular sensation to chewing.
Elle prĂ©sente, en outre, d’excellentes aptitudes Ă  libĂ©rer les arĂŽmes d’oĂč son intĂ©rĂȘt pour fabriquer de savoureuses confiseries. Enfin, elle est capable d’absorber cinq Ă  six fois son poids en eau. Elle est donc trĂšs utilisĂ©e car elle possĂšde de nombreux atouts fonctionnels. Elle est utilisĂ©e comme agent gĂ©lifiant en prioritĂ©, mais Ă©galement comme agent Ă©paississant, stabilisant, Ă©mulsifiant, liant et agent moussant dans les confiseries aĂ©rĂ©es.  It also has excellent ability to release aromas, hence its interest in making tasty confectionery. Finally, it is able to absorb five to six times its weight in water. It is therefore widely used because it has many functional advantages. It is used as a gelling agent in priority, but also as a thickening, stabilizing, emulsifying, binding and foaming agent in aerated confectionery.
Depuis de nombreuses annĂ©es la gĂ©latine n’a guĂšre bonne presse. Suite Ă  l’émergence de l’encĂ©phalite spongiforme chez les bovins, l’utilisation de la gĂ©latine dans des prĂ©parations alimentaires est aujourd’hui trĂšs controversĂ©e.  For many years gelatin has had poor press. Following the emergence of spongiform encephalitis in cattle, the use of gelatin in food preparations is today very controversial.
De plus, dans le milieu de la confiserie, il n’y a que la gĂ©latine issue de peaux de porcs qui est utilisĂ©e, ce qui peut Ă©galement poser des problĂšmes par rapport Ă  certaines croyances ou religions.  In addition, in the confectionery industry, only gelatin from pigskins is used, which can also cause problems in relation to certain beliefs or religions.
Enfin, les vĂ©gĂ©tariens et vĂ©gĂ©taliens refusent Ă©galement de consommer tous produits issus d’animaux et boycottent par consĂ©quent toutes les confiseries contenant de la gĂ©latine.  Finally, vegetarians and vegans also refuse to consume any animal products and therefore boycott all confectionery containing gelatin.
De plus, en raison de son goût et de son odeur particuliÚre, son utilisation contraint trÚs souvent les industriels à utiliser des arÎmes afin de masquer sa présence et ses inconvénients olfactifs.  In addition, because of its particular taste and smell, its use very often forces manufacturers to use aromas in order to mask its presence and its olfactory drawbacks.
La gélatine a également un prix de revient élevé qui peut constituer un frein à son utilisation, notamment pour les pays émergents.  Gelatin also has a high cost price which can hinder its use, especially for emerging countries.
De plus, la gĂ©latine est une protĂ©ine trĂšs sensible aux conditions de pH et de tempĂ©ratures extrĂȘmes (pH trĂšs acides, tempĂ©ratures trĂšs Ă©levĂ©es) dans lesquelles elle a tendance Ă  se dĂ©grader, perdant ainsi ses propriĂ©tĂ©s gĂ©lifiantes.  In addition, gelatin is a protein very sensitive to pH conditions and extreme temperatures (very acidic pH, very high temperatures) in which it tends to degrade, thus losing its gelling properties.
De trĂšs nombreux travaux de recherche ont Ă©tĂ© menĂ©s afin de proposer des solutions plus ou moins complexes pour substituer en totalitĂ© ou en partie la gĂ©latine dans la fabrication des confiseries gĂ©lifiĂ©es, notamment les gĂ©lifiĂ©s gommes. On connaĂźt en particulier des confiseries gĂ©lifiĂ©es Ă  base d’amidons divers.  Numerous research studies have been carried out in order to propose more or less complex solutions to completely or partially replace gelatin in the manufacture of gelled confectionery, in particular gelled gums. Known gelled confectionery products based on various starches are known in particular.
L’homme du mĂ©tier sait par ailleurs que seule l’amylose joue le rĂŽle de gĂ©lifiant, que l’amylopectine confĂšre l’élasticitĂ© aux produits mais gĂ©lifie plus lentement et augmente beaucoup plus la viscositĂ© que l’amylose, que l’amylose donne des gels opaques alors que l’amylopectine donne des produits transparents.  Those skilled in the art also know that only amylose acts as a gelling agent, that amylopectin gives elasticity to the products but gels more slowly and increases viscosity much more than amylose, that amylose gives opaque gels while amylopectin gives transparent products.
Il a alors Ă©tĂ© proposĂ© dans les documents EP 252.306 B1 et EP 360.046 B1 de mĂ©langer diffĂ©rents amidons riches en amylose, modifiĂ©s ou non, de maniĂšre Ă  en conjuguer les propriĂ©tĂ©s. Ces solutions nĂ©cessitent des mĂ©langes de plusieurs amidons et ne sont pas forcĂ©ment simples Ă  mettre en Ɠuvre industriellement parlant. Le document EP 1.342.417 A, dont la Demanderesse est titulaire, dĂ©crit une confiserie gĂ©lifiĂ©e contenant un amidon waxy en association avec des carraghĂ©nanes. Les confiseries obtenues sont de qualitĂ© satisfaisante mais n’égalent pas les propriĂ©tĂ©s des confiseries obtenues avec de la gĂ©latine, et la solution proposĂ©e impose l’utilisation de carraghĂ©nanes qui sont chers. It was then proposed in documents EP 252,306 B1 and EP 360,046 B1 to mix different starches rich in amylose, modified or not, so as to combine their properties. These solutions require mixtures of several starches and are not necessarily simple to implement industrially speaking. Document EP 1,342,417 A, of which the Applicant is the holder, describes a gelled confectionery containing a waxy starch in association with carrageenans. The confectionery obtained is of satisfactory quality but does not match the properties of the confectionery obtained with gelatin, and the proposed solution requires the use of carrageenans which are expensive.
Par ailleurs, si cette solution apporte des rĂ©sultats satisfaisants pour les gĂ©lifiĂ©s gommes, elle ne l’est pas pour les pĂątes Ă  mĂącher.  Furthermore, if this solution brings satisfactory results for gum gums, it is not for chewy pastes.
Le document EP 1.645.196 B dont la demanderesse est Ă©galement titulaire dĂ©crit des confiseries gĂ©lifiĂ©es Ă  base d’amidon de lĂ©gumineuse fluidifiĂ© et stabilisĂ© prĂ©sentant une teneur en amylose bien particuliĂšre.  Document EP 1,645,196 B, of which the applicant is also the holder, describes gelled confectionery products based on fluidized and stabilized legume starch having a very specific amylose content.
Enfin, le document EP 2.919.589 A dont la demanderesse est Ă©galement titulaire dĂ©crit l’utilisation d’un amidon waxy prĂ©gĂ©latinisĂ© pour remplacer la gĂ©latine dans les confiseries gĂ©lifiĂ©es, tout en conservant les qualitĂ©s organoleptiques, en particulier gustatives, olfactives, visuelles et tactiles, au moins Ă©quivalentes voire supĂ©rieures, Ă  celles des confiseries traditionnelles contenant de la gĂ©latine.  Finally, document EP 2,919,589 A, of which the applicant is also the holder, describes the use of a waxy pregelatinized starch to replace gelatin in gelled confectionery, while retaining the organoleptic qualities, in particular gustatory, olfactory, visual and tactile , at least equivalent or even superior, to that of traditional confectionery containing gelatin.
C’est ainsi que les confiseries prĂ©parĂ©es selon l’enseignement de cette demande de brevet EP 2.919.589 A conservent une texture, une masticabilitĂ©, une durĂ©e en bouche et une palatabilitĂ© au moins similaires, voire amĂ©liorĂ©es par rapport aux confiseries comprenant traditionnellement de la gĂ©latine. La gĂ©latine peut ĂȘtre substituĂ©e en partie ou en totalitĂ©.  Thus, the confectionery products prepared according to the teaching of this patent application EP 2,919,589 A maintain a texture, chewability, duration in the mouth and palatability at least similar, or even improved compared to confectionery products traditionally comprising gelatin. The gelatin can be partially or completely substituted.
De maniÚre préférentielle, il est recommandé de préparer cette confiserie gélifiée comprenant un amidon waxy prégélatinisé avec au moins un autre ingrédient choisi parmi les maltodextrines branchées (commercialisées par la société Demanderesse sous le nom de marque NUTRIOSEŸ), le sorbitol et la glycérine, dans des proportions particuliÚres. Preferably, it is recommended to prepare the confectionery gelled comprising a waxy pregelatinized starch with at least one other ingredient chosen from branched maltodextrins (marketed by the Applicant under the trade name NUTRIOSE Ÿ), sorbitol and glycerin, in particular proportions.
Toujours dans cette demande de brevet EP 2.919.589 A, les meilleures recettes de confiseries gĂ©lifiĂ©es proposĂ©es par la sociĂ©tĂ© Demanderesse, procurant aux dits bondons leur excellente masticabilitĂ©, en termes de duretĂ© et d’élasticitĂ©, Ă©taient obtenues par la combinaison :  Still in this patent application EP 2,919,589 A, the best gelled confectionery recipes offered by the Applicant company, providing said bungs with excellent chewability, in terms of hardness and elasticity, were obtained by the combination:
de 2 % Ă  10 %, de façon encore plus prĂ©fĂ©rĂ©e 4 % Ă  8 % d’amidon waxy prĂ©gĂ©latinisĂ©,  from 2% to 10%, even more preferably 4% to 8% of pregelatinized waxy starch,
de préférence de 2% à 10%, de façon encore plus préférée 4% à 8% de maltodextrines branchées,  preferably from 2% to 10%, even more preferably 4% to 8% of branched maltodextrins,
les pourcentages étant exprimés en poids par rapport au poids total de la confiserie. the percentages being expressed by weight relative to the total weight of the confectionery.
Voire mĂȘme, il Ă©tait recommandĂ© de choisir, dans un mode de rĂ©alisation avantageux, une confiserie comprenant de 50 Ă  75 %, de prĂ©fĂ©rence de 56 Ă  62 % de maltodextrines branchĂ©es, ce qui permettait par ailleurs de qualifier la confiserie gĂ©lifiĂ©e ainsi obtenue de « riche en fibres ». L’homme du mĂ©tier de la confiserie dĂ©duit ainsi de l’enseignement de ce document, que pour un taux optimisĂ© d’amidon waxy prĂ©gĂ©latinisĂ© utilisĂ© comme substitut de gĂ©latines dans les confiseries gĂ©lifiĂ©es, i.e. Ă  une valeur comprise entre 4 et 8 % en poids par rapport au poids total de la confiserie, il fallait de prĂ©fĂ©rence choisir un taux d’incorporation de maltodextrines branchĂ©es compris entre 2 et 10 %, et de prĂ©fĂ©rence de 4 Ă  8 % en poids par rapport au poids total de la confiserie. Even, it was recommended to choose, in an advantageous embodiment, a confectionery comprising from 50 to 75%, preferably from 56 to 62% of branched maltodextrins, which moreover made it possible to qualify the gelled confectionery thus obtained of " high in fiber ”. The person skilled in the confectionery industry therefore deduces from the teaching of this document, that for an optimized rate of pregaxatinized waxy starch used as a gelatin substitute in gelled confectionery, ie at a value between 4 and 8% by weight relative to the total weight of the confectionery, it was preferable to choose a rate of incorporation of branched maltodextrins of between 2 and 10%, and preferably from 4 to 8% by weight relative to the total weight of the confectionery.
Aucune Ă©tude d’impact, quant Ă  l’acceptabilitĂ© d’une confiserie gĂ©lifiĂ©e sans gĂ©latine avait Ă©tĂ© menĂ©e pour un taux d’incorporation en maltodextrines branchĂ©es infĂ©rieur Ă  2 %.  No impact study on the acceptability of a gummy confectionery without gelatin had been carried out for a incorporation rate in branched maltodextrins of less than 2%.
Bien que satisfaisantes, toutes les voies proposĂ©es et dĂ©crites dans l’art antĂ©rieur pour remplacer en totalitĂ© ou en partie la gĂ©latine dans des confiseries gĂ©lifiĂ©es ne permettent pas complĂštement d'obtenir des textures comparables aux confiseries gĂ©lifiĂ©es standard contenant de la gĂ©latine.  Although satisfactory, all the methods proposed and described in the prior art for replacing all or part of the gelatin in gelled confectionery do not completely make it possible to obtain textures comparable to standard gelled confectionery containing gelatin.
Il existe donc encore un besoin pour une recette alternative permettant de remplacer totalement la gélatine dans les confiseries gélifiées et de conférer une texture en bouche présentant une dureté et une élasticité optimales.  There is therefore still a need for an alternative recipe making it possible to completely replace gelatin in gelled confectionery and to impart a texture in the mouth having optimal hardness and elasticity.
Il est ainsi du mĂ©rite de la sociĂ©tĂ© Demanderesse d’avoir identifiĂ© que de faibles quantitĂ©s de maltodextrines branchĂ©es et d’amidon waxy prĂ©gĂ©latinisĂ© permettaient d’obtenir une telle confiserie gĂ©lifiĂ©e prĂ©sentant une texture satisfaisante avec un Ă©quilibrage optimal entre la duretĂ© et l’élasticitĂ© obtenues, c'est-Ă -dire une confiserie gĂ©lifiĂ©es prĂ©sentant une bonne fermetĂ© tout en prĂ©servant l’élasticitĂ© requise pour la mastication.  It is therefore to the credit of the Applicant company to have identified that small amounts of branched maltodextrins and pregelatinized waxy starch made it possible to obtain such a gelled confectionery having a satisfactory texture with an optimal balance between the hardness and the elasticity obtained. , that is to say a gelled confectionery presenting a good firmness while preserving the elasticity required for chewing.
RESUME DE L’INVENTION SUMMARY OF THE INVENTION
Un premier objet de l’invention concerne donc une confiserie gĂ©lifiĂ©e exempte de gĂ©latine comprenant :  A first object of the invention therefore relates to a gelatin-free gelatin confectionery comprising:
de 2 % Ă  4 % d’amidon waxy prĂ©gĂ©latinisĂ©,  from 2% to 4% of pregaxatinized waxy starch,
de 0,5 % à 1 ,5 % de maltodextrines branchées,  from 0.5% to 1.5% of branched maltodextrins,
les pourcentages étant exprimés en poids sec par rapport au poids total du produit final.  the percentages being expressed in dry weight relative to the total weight of the final product.
La confiserie gĂ©lifiĂ©e selon l’invention prĂ©sente ainsi une texture satisfaisante avec notamment un Ă©quilibrage optimal entre les propriĂ©tĂ©s de duretĂ© et les propriĂ©tĂ©s d’élasticitĂ©. The gelled confectionery according to the invention thus has a satisfactory texture with in particular an optimal balancing between the hardness properties and the elasticity properties.
Un second objet de l’invention concerne un prĂ©-mĂ©lange constituĂ© d’amidon waxy prĂ©gĂ©latinisĂ© et de maltodextrines branchĂ©es, ledit prĂ©-mĂ©lange Ă©tant caractĂ©risĂ© en ce qu’il comprend un ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es compris de 1 Ă  8. Le prĂ©-mĂ©lange selon l’invention trouve une utilisation toute particuliĂšre dans la fabrication de confiseries gĂ©lifiĂ©es exemptes de gĂ©latine. Un troisiĂšme objet de l’invention concerne un procĂ©dĂ© de prĂ©paration de confiseries gĂ©lifiĂ©es exemptes de gĂ©latine comprenant les Ă©tapes de : A second subject of the invention relates to a premix consisting of pregaxatinized waxy starch and branched maltodextrins, said premix being characterized in that it comprises a weight ratio of pregaxatinized waxy starch / branched maltodextrins of 1 to 8. The premix according to the invention finds a very particular use in the manufacture of gelled confectionery free from gelatin. A third subject of the invention relates to a process for the preparation of gelatin-free gelatin confectionery comprising the steps of:
prĂ©paration d’un mĂ©lange comprenant :  preparation of a mixture comprising:
o de 2 % à 4 % d’amidon waxy,  o from 2% to 4% of waxy starch,
o de 0,5 % à 1 ,5 % de maltodextrines branchées,  o from 0.5% to 1.5% of branched maltodextrins,
o au moins un Ă©dulcorant et de l’eau,  o at least one sweetener and water,
cuisson dudit mĂ©lange Ă  une tempĂ©rature comprise entre 100 et 150°C jusqu’à l’obtention de la matiĂšre sĂšche voulue,  baking said mixture at a temperature between 100 and 150 ° C until the desired dry matter is obtained,
mise en forme du mélange cuit de maniÚre à obtenir lesdites confiseries gélifiées.  shaping of the cooked mixture so as to obtain said gelled confectionery.
DESCRIPTION DETAILLEE DETAILED DESCRIPTION
Un premier objet de l’invention concerne donc une confiserie gĂ©lifiĂ©e exempte de gĂ©latine comprenant :  A first object of the invention therefore relates to a gelatin-free gelatin confectionery comprising:
de 2 % Ă  4 % d’amidon waxy prĂ©gĂ©latinisĂ©,  from 2% to 4% of pregaxatinized waxy starch,
de 0,5 % à 1 ,5 % de maltodextrines branchées,  from 0.5% to 1.5% of branched maltodextrins,
les pourcentages étant exprimés en poids sec par rapport au poids total du produit final.  the percentages being expressed in dry weight relative to the total weight of the final product.
Contrairement Ă  l’enseignement de la demande de brevet EP 2.919.589 A, la sociĂ©tĂ© Demanderesse a maintenant trouvĂ© qu’il n’est plus nĂ©cessaire de prĂ©fĂ©rer utiliser entre 2 % et 10 %, de prĂ©fĂ©rence de 4 Ă  8 % en poids de maltodextrines branchĂ©es pour obtenir une texture satisfaisante de la confiserie gĂ©lifiĂ©e sans gĂ©latine dans des recettes comprenant moins de 4 % en poids d’amidon waxy prĂ©gĂ©latinisĂ©. Contrary to the teaching of patent application EP 2,919,589 A, the Applicant company has now found that it is no longer necessary to prefer to use between 2% and 10%, preferably from 4 to 8% by weight of branched maltodextrins to obtain a satisfactory texture of gelled confectionery without gelatin in recipes comprising less than 4% by weight of waxy pregelatinized starch.
En effet, de maniĂšre surprenante, de faibles quantitĂ©s de maltodextrines branchĂ©es et d’amidon waxy prĂ©gĂ©latinisĂ© permettent d’obtenir une confiserie gĂ©lifiĂ©e prĂ©sentant une texture satisfaisante et surtout un Ă©quilibrage optimal entre la duretĂ© et l’élasticitĂ©.  Indeed, surprisingly, small amounts of branched maltodextrins and pregelatinized waxy starch make it possible to obtain a gelled confectionery having a satisfactory texture and above all an optimal balance between hardness and elasticity.
Cet Ă©quilibrage optimal de la duretĂ© et de l’élasticitĂ© de la confiserie gĂ©lifiĂ©e selon l’invention se traduit ainsi par une duretĂ© comprise de 6 Ă  8 N et une Ă©lasticitĂ© comprise de 7 % Ă  9 %.  This optimal balancing of the hardness and the elasticity of the gelled confectionery according to the invention thus results in a hardness of 6 to 8 N and an elasticity of 7 to 9%.
Avec de telles propriĂ©tĂ©s, la confiserie gĂ©lifiĂ©e prĂ©sent une bonne fermetĂ© tout en prĂ©servant l’élasticitĂ© requise pour la mastication.  With such properties, gelled confectionery exhibits good firmness while preserving the elasticity required for chewing.
Les mesures de duretĂ© et de l’élasticitĂ© sont rĂ©alisĂ©es Ă  une tempĂ©rature de 20°C sur un texturomĂštre INSTRON 5966 avec une gĂ©omĂ©trie type « poinçon doigt » et en imposant une dĂ©formation Ă  30 % de la hauteur de l’échantillon pendant 2 minutes et une vitesse de test Ă  10 mm/min.  The hardness and elasticity measurements are carried out at a temperature of 20 ° C. on an INSTRON 5966 texturometer with a “finger punch” type geometry and by imposing a deformation at 30% of the height of the sample for 2 minutes and a test speed of 10 mm / min.
Selon la prĂ©sente invention, l’expression « confiserie gĂ©lifiĂ©e » doit ĂȘtre interprĂ©tĂ©e comme dĂ©signant toutes les confiseries contenant habituellement de la gĂ©latine. Il s’agit entre autre des gommes dures, des gommes tendres, des pĂątes Ă  mĂącher, des rĂ©glisses, des gelĂ©es, des pastilles, des pĂątes de fruits, des caramels, des toffĂ©es, des fondants, des fudges et des fourrages, des lozenges, ainsi que des inclusions pour crĂšmes glacĂ©es ou pĂątisseries, ou encore toutes les confiseries du mĂȘme type dites pharmaceutiques et contenant un principe actif par exemple. Tous ces articles font partie des articles tendres par rapport aux sucres cuits. According to the present invention, the expression “gelled confectionery” must be interpreted as designating all the confectionery products usually containing gelatin. These include hard gums, soft gums, chews, liquorice, jellies, pastilles, fruit pastes, caramels, toffees, fondants, fudges and fillings, lozenges , as well as inclusions for ice creams or pastries, or even all confectionery of the same type called pharmaceutical and containing an active ingredient for example. All these items are part of the tender items compared to boiled sugars.
Dans un mode prĂ©fĂ©rĂ© de la prĂ©sente invention, les confiseries gĂ©lifiĂ©es sont des pĂątes Ă  mĂącher trĂšs apprĂ©ciĂ©es par les consommateurs pour leur propriĂ©tĂ© de masticabilitĂ© importante les faisant se rapprocher d’un chewing gum ou d’une gomme Ă  mĂącher.  In a preferred embodiment of the present invention, gelled confectionery is chews very appreciated by consumers for their property of high chewability making them approach a chewing gum or a chewing gum.
Au sens de la prĂ©sente invention, l’expression « amidon waxy » dĂ©signe toutes les variĂ©tĂ©s d’amidon contenant une teneur en amylopectine supĂ©rieure ou Ă©gale Ă  80 %, de prĂ©fĂ©rence supĂ©rieure ou Ă©gale Ă  90 % et de façon encore plus prĂ©fĂ©rĂ©e, supĂ©rieure ou Ă©gale Ă  95 %.  Within the meaning of the present invention, the expression “waxy starch” designates all the varieties of starch containing an amylopectin content greater than or equal to 80%, preferably greater than or equal to 90% and even more preferably, greater or less equal to 95%.
Au sens de la prĂ©sente invention, ledit amidon waxy est issu d’une ou plusieurs variĂ©tĂ©s botaniques choisies parmi le maĂŻs, le riz, la pomme de terre, le blĂ© et leurs mĂ©langes quelconques. Les variĂ©tĂ©s botaniques peuvent ĂȘtre, selon la prĂ©sente invention, sauvages ou hybrides et donc avoir subis des modifications gĂ©nĂ©tiques pour modifier leur gĂ©nome.  Within the meaning of the present invention, said waxy starch comes from one or more botanical varieties chosen from corn, rice, potato, wheat and any mixtures thereof. According to the present invention, the botanical varieties can be wild or hybrid and therefore have undergone genetic modifications to modify their genome.
Dans la prĂ©sente invention, les termes « amidon waxy prĂ©gĂ©latinisĂ© » et « amidon waxy prĂ©cuit » sont utilisĂ©s indiffĂ©remment pour dĂ©signer tout amidon waxy ayant subi un traitement thermique en prĂ©sence d’eau, de sorte qu’il perde dans sa quasi-totalitĂ© sa structure granulaire et qu’il devienne soluble dans l’eau froide.  In the present invention, the terms “pregaxatinized waxy starch” and “precooked waxy starch” are used interchangeably to designate any waxy starch which has undergone a heat treatment in the presence of water, so that it almost loses its entire structure. granular and that it becomes soluble in cold water.
Ainsi, par amidon waxy prĂ©gĂ©latinisĂ© ou amidon prĂ©cuit, on entend au sens de l’invention un Ă©tat dans lequel l’amidon n’est quasiment plus dans un Ă©tat granulaire, c'est-Ă -dire dans un Ă©tat oĂč il n’est plus dans un Ă©tat en granules semi-cristallins caractĂ©ristiques de l’état dans lequel il est naturellement prĂ©sent dans les organes et tissus de rĂ©serve des vĂ©gĂ©taux supĂ©rieurs, en particulier dans les graines de cĂ©rĂ©ales, les graines de lĂ©gumineuses, les tubercules de pomme de terre ou de manioc, les racines, les bulbes, les tiges et les fruits. Cet Ă©tat semi-cristallin est essentiellement dĂ» aux macromolĂ©cules d’amylopectine, l’un des deux constituants principaux de l’amidon.  Thus, by pregaxatinized waxy starch or precooked starch, is meant within the meaning of the invention a state in which the starch is almost no longer in a granular state, that is to say in a state where it is not no longer in a state in semi-crystalline granules characteristic of the state in which it is naturally present in the organs and reserve tissues of higher plants, in particular in cereal seeds, legume seeds, potato tubers or cassava, roots, bulbs, stems and fruit. This semi-crystalline state is mainly due to the macromolecules of amylopectin, one of the two main constituents of starch.
Dans la confiserie gĂ©lifiĂ©e selon l’invention, l’amidon waxy peut ĂȘtre mis en Ɠuvre sous forme d’amidon waxy prĂ©gĂ©latinisĂ© ou Ă©galement sous forme d’amidon waxy natif, la gĂ©latinisation intervenant alors pendant le processus de fabrication de la confiserie gĂ©lifiĂ©e.  In the gelled confectionery according to the invention, the waxy starch can be used in the form of pregelatinized waxy starch or also in the form of native waxy starch, the gelatinization then taking place during the manufacturing process of the gelled confectionery.
En effet, la gĂ©latinisation de l’amidon waxy peut ĂȘtre obtenue prĂ©alablement Ă  la prĂ©paration de la confiserie gĂ©lifiĂ©e par la fourniture d’un amidon waxy prĂ©gĂ©latinisĂ© ou lors de la prĂ©paration en tant que telle. Le choix de gĂ©latiniser l’amidon waxy prĂ©alablement Ă  son utilisation ou pendant le procĂ©dĂ© de fabrication de confiseries repose sur le choix du cuiseur mis en Ɠuvre dans l’étape de cuisson. In fact, the gelatinization of waxy starch can be obtained prior to the preparation of the gelled confectionery by the supply of a waxy pregelatinized starch or during the preparation as such. The choice of gelatinizing waxy starch before its use or during the confectionery manufacturing process is based on the choice of cooker used in the cooking step.
L’utilisation de cuiseurs Ă  pression atmosphĂ©riques ou avec des temps cours de cuisson permet la prĂ©paration d’amidon waxy prĂ©gĂ©latinisĂ© en tant que tel directement incorporable dans la confiserie.  The use of atmospheric pressure cookers or with cooking times allows the preparation of pregaxatinized waxy starch as such directly incorporated into confectionery.
Mais certains cuiseurs ne pouvant pas fonctionner avec de hautes viscositĂ©s (comme par exemple les Ă©changeurs Ă  plaques), on ajoute alors l’amidon waxy dĂ©jĂ  cuit (prĂ©gel).  But some cookers cannot work with high viscosities (such as plate heat exchangers), so add the already cooked waxy starch (pregel).
De ce fait, si le type de cuiseur le permet, l’homme du mĂ©tier peut avantageusement prĂ©fĂ©rer d’utiliser l’amidon waxy sous sa forme native, et procĂ©der Ă  sa cuisson, par exemple en prĂ©sence des autres ingrĂ©dients de la confiserie tels que dĂ©crits ci-aprĂšs, afin d’éclater le grain d’amidon tout en concentrant le sirop jusqu’à l’extrait sec nĂ©cessaire pour une texture satisfaisante.  Therefore, if the type of cooker allows it, the person skilled in the art may advantageously prefer to use waxy starch in its native form, and to cook it, for example in the presence of other confectionery ingredients such as described below, in order to burst the grain of starch while concentrating the syrup until the dry extract necessary for a satisfactory texture.
Les amidons waxy prĂ©gĂ©latinisĂ©s selon la prĂ©sente invention peuvent par exemple ĂȘtre obtenus par traitement hydrothermique de gĂ©latinisation d’amidons natifs, en particulier par cuisson vapeur, cuisson jet-cooker, cuisson sur tambour, cuisson dans des systĂšmes de malaxeur/extrudeuse ou microonde puis sĂ©chage, par exemple en Ă©tuve, par air chaud sur lit fluidisĂ©, sur tambour rotatif, par atomisation, par extrusion ou encore par lyophilisation.  The waxy pregelatinized starches according to the present invention can for example be obtained by hydrothermal treatment of gelatinization of native starches, in particular by steam cooking, jet-cooker cooking, drum cooking, cooking in kneader / extruder or microwave systems then drying , for example in an oven, by hot air on a fluidized bed, on a rotary drum, by atomization, by extrusion or by lyophilization.
De tels amidons prĂ©sentent gĂ©nĂ©ralement une solubilitĂ© dans l’eau dĂ©minĂ©ralisĂ©e Ă  20°C supĂ©rieure Ă  5 %, et plus gĂ©nĂ©ralement comprise entre 10 et 100 %, et un taux de cristallinitĂ© en amidon infĂ©rieur Ă  15 %, gĂ©nĂ©ralement infĂ©rieur Ă  5 %, et le plus souvent infĂ©rieur Ă  1 %, voire nul. A titre d’exemple, on peut citer les produits fabriquĂ©s et commercialisĂ©s par la Demanderesse sous le nom de marque PREGEFLOÂź. Such starches generally have a solubility in demineralized water at 20 ° C. of more than 5%, and more generally between 10 and 100%, and a starch crystallinity level of less than 15%, generally less than 5%, and most often less than 1%, or even zero. Examples include products manufactured and marketed by the Applicant under the brand name PREGEFLO Âź.
La confiserie gĂ©lifiĂ©e selon l’invention comprend Ă©galement de 0,5 % Ă  1 ,5 % de maltodextrines branchĂ©es. De prĂ©fĂ©rence, la confiserie gĂ©lifiĂ©e comprend de 0,5 % Ă  1 % de maltodextrines branchĂ©es, et tout particuliĂšrement environ 1 % de maltodextrines branchĂ©es. Les pourcentages sont exprimĂ©s en poids sec par rapport au poids total de la confiserie.  The gelled confectionery according to the invention also comprises from 0.5% to 1.5% of branched maltodextrins. Preferably, the gelled confectionery comprises from 0.5% to 1% of branched maltodextrins, and very particularly approximately 1% of branched maltodextrins. The percentages are expressed in dry weight relative to the total weight of the confectionery.
On entend par maltodextrines branchĂ©es au sens de l’invention, les maltodextrines spĂ©cifiques identiques Ă  celles dĂ©crites dans le brevet EP 1.006.128 B1 dont la Demanderesse est titulaire.  The term “branched maltodextrins” within the meaning of the invention means the specific maltodextrins identical to those described in patent EP 1,006,128 B1 of which the Applicant is the holder.
Ces maltodextrines branchĂ©es ont l’avantage de reprĂ©senter une source de fibres indigestibles bĂ©nĂ©fiques pour le mĂ©tabolisme et pour l’équilibre intestinal.  These branched maltodextrins have the advantage of being a source of indigestible fibers beneficial for metabolism and intestinal balance.
Selon la présente invention, lesdites maltodextrines branchées peuvent présenter : - entre 15 et 50 % de liaisons glucosidiques 1-6, préférentiellement entre 22 % et 45 %, plus préférentiellement entre 20 % et 40 %, et encore plus préférentiellement entre 25 % et 35 %, According to the present invention, said branched maltodextrins can have: between 15 and 50% of glucosidic linkages 1-6, preferably between 22% and 45%, more preferably between 20% and 40%, and even more preferably between 25% and 35%,
- une teneur en sucres réducteurs inférieure à 20 %, préférentiellement comprise entre 2 % et 20 %, plus préférentiellement entre 2,5 % et 15 %, et encore plus préférentiellement entre 3,5 % et 10 %,  a reducing sugar content of less than 20%, preferably between 2% and 20%, more preferably between 2.5% and 15%, and even more preferably between 3.5% and 10%,
- un indice de polymolécularité inférieur à 5, préférentiellement compris entre 1 et 4, plus préférentiellement entre 1 ,5 et 3, et  a polymolecularity index less than 5, preferably between 1 and 4, more preferably between 1, 5 and 3, and
- une masse moléculaire moyenne en nombre Mn inférieure à 4500 g/mole, préférentiellement comprise entre 400 et 4500 g/mole, plus préférentiellement entre 500 et 3000 g/mole, encore préférentiellement entre 700 et 2800 g/mole, encore plus préférentiellement comprise entre 1000 et 2600 g/mole.  a number average molecular mass Mn of less than 4500 g / mole, preferably between 400 and 4500 g / mole, more preferably between 500 and 3000 g / mole, even more preferably between 700 and 2800 g / mole, even more preferably between 1000 and 2600 g / mole.
Selon un mode de réalisation particulier, les maltodextrines branchées de la confiserie gélifiée présentent entre 15 % et 35 % de liaisons glycosidiques 1-6, une teneur en sucres réducteurs inférieure à 20 %, une masse moléculaire moyenne en poids MW comprise entre 4000 et 6000 g/mole, et une masse moléculaire moyenne en nombre Mn comprise entre 250 et 4500 g/mole.  According to a particular embodiment, the branched maltodextrins of the gelled confectionery have between 15% and 35% of glycosidic bonds 1-6, a reducing sugar content of less than 20%, an average molecular mass by weight MW of between 4000 and 6000 g / mole, and a number average molecular mass Mn of between 250 and 4500 g / mole.
Certaines sous-familles de maltodextrines branchĂ©es dĂ©crites dans la susdite demande peuvent aussi ĂȘtre utilisĂ©es conformĂ©ment Ă  l’invention. Il s’agit par exemple de maltodextrines branchĂ©es de hauts poids molĂ©culaires prĂ©sentant une teneur en sucres rĂ©ducteurs au plus Ă©gale Ă  5 et une masse molĂ©culaire moyenne en nombre Mn comprise entre 2000 et 4500 g/mole. Les maltodextrines branchĂ©es de bas poids molĂ©culaires prĂ©sentant une teneur en sucres rĂ©ducteurs comprise entre 5 et 20 % et une masse molĂ©culaire moyenne en nombre Mn infĂ©rieure Ă  2000 g/mole peuvent Ă©galement ĂȘtre employĂ©es.  Certain subfamilies of branched maltodextrins described in the above-mentioned application can also be used in accordance with the invention. These are, for example, branched maltodextrins of high molecular weight having a reducing sugar content of at most 5 and a number-average molecular mass Mn of between 2000 and 4500 g / mole. Branched maltodextrins of low molecular weight having a reducing sugar content of between 5 and 20% and a number average molecular mass Mn of less than 2000 g / mole can also be used.
Selon un mode particuliÚrement avantageux de la présente invention, la maltodextrine branchée est issue de la gamme NUTRIOSEŸ qui est une gamme complÚte de fibres solubles reconnues pour leurs bienfaits qui sont fabriquées et commercialisées par la Demanderesse. According to a particularly advantageous mode of the present invention, the branched maltodextrin is derived from the range NUTRIOSE Ÿ which is a complete range of soluble fibers known for their benefits which are manufactured and marketed by the Applicant.
Les produits de la gamme NUTRIOSEŸ sont des dérivés d'amidon de blé ou de maïs partiellement hydrolysés, qui contiennent jusqu'à 85 % de fibre. Cette richesse en fibres permet d'augmenter la tolérance digestive, d'améliorer la gestion de calorie, de prolonger le dégagement d'énergie et d'obtenir un taux de sucre inférieur. De plus, la gamme NUTRIOSEŸ est l'une des fibres les mieux tolérées disponibles sur le marché. Elle montre une tolérance digestive plus élevée, permettant une meilleure incorporation que d'autres fibres, ce qui représente de vrais avantages alimentaires. The products in the NUTRIOSE Ÿ range are derivatives of partially hydrolyzed wheat starch or corn starch, which contain up to 85% fiber. This richness in fibers makes it possible to increase digestive tolerance, to improve calorie management, to prolong the release of energy and to obtain a lower sugar level. In addition, the NUTRIOSE Ÿ range is one of the best tolerated fibers available on the market. It shows a higher digestive tolerance, allowing better incorporation than other fibers, which represents real nutritional benefits.
Les intĂ©rĂȘts des maltodextrines branchĂ©es comme le NUTRIOSEÂź dans la confiserie gĂ©lifiĂ©e de la prĂ©sente invention sont multiples. Outre l’aspect nutritif et l’apport de fibres trĂšs bien tolĂ©rĂ©es par l’organisme, les maltodextrines branchĂ©es de cette gamme prĂ©sentent Ă©galement un intĂ©rĂȘt technique non nĂ©gligeable. En effet, elles sont constituĂ©es de longues chaĂźnes polymĂ©riques glucidiques et jouent donc un rĂŽle d’agent texturant dans les confiseries. The interests of the branched maltodextrins as NUTRIOSEÂź Âź in jelly confectionery of the present invention are numerous. In addition to the nutritional aspect and the supply of fibers very well tolerated by the body, the branched maltodextrins of this range also present a significant technical interest. Indeed, they are made up of long polymeric carbohydrate chains and therefore play a role of texturing agent in confectionery.
La prĂ©sence des maltodextrines branchĂ©es permet donc encore d’augmenter l’élasticitĂ© du produit final. Ainsi, la durabilitĂ© de la masticabilitĂ© est augmentĂ©e par la prĂ©sence de ces longues chaĂźnes qui modifient la texture du produit. Leur caractĂšre branchĂ© diminue considĂ©rablement et avantageusement leur tendance Ă  rĂ©trograder, ce qui reprĂ©sente un avantage pour les confiseries gĂ©lifiĂ©es oĂč l’absence de rĂ©trogradation est nĂ©cessaire, en particulier lors d’un stockage prolongĂ©.  The presence of branched maltodextrins therefore further increases the elasticity of the final product. Thus, the durability of the chewability is increased by the presence of these long chains which modify the texture of the product. Their trendy nature considerably and advantageously reduces their tendency to demote, which is an advantage for gelled confectionery where the absence of demotion is necessary, in particular during prolonged storage.
La prĂ©sence de maltodextrines branchĂ©es permet Ă©galement d’augmenter la tempĂ©rature de transition vitreuse ou Tg de la partie amorphe de ladite confiserie. Cette augmentation de la Tg permet de rigidifier la structure au sein de la confiserie et permet par consĂ©quent d’apporter une bonne tenue Ă  la masticabilitĂ©.  The presence of branched maltodextrins also makes it possible to increase the glass transition temperature or Tg of the amorphous part of said confectionery. This increase in Tg makes it possible to stiffen the structure within the confectionery and consequently makes it possible to provide good resistance to chewability.
Comme il sera exemplifiĂ© ci-aprĂšs, la sociĂ©tĂ© Demanderesse a dĂ©montrĂ© qu’un taux d’incorporation de maltodextrine branchĂ© de 0,5 Ă  1 ,5 %, plus prĂ©fĂ©rentiellement de l’ordre de 1 %, avec de 2 Ă  4 % d’amidon waxy prĂ©gĂ©latinisĂ©, suffisait pour obtenir un Ă©quilibrage optimal entre la duretĂ© et l’élasticitĂ©. La confiserie gĂ©lifiĂ©e selon l’invention comprend ainsi une duretĂ© intermĂ©diaire comprise de 6 Ă  8 N et une Ă©lasticitĂ© moyenne comprise de 7 % Ă  9 % et prĂ©sente ainsi une bonne fermetĂ© tout en prĂ©servant l’élasticitĂ© requise pour la mastication.  As will be exemplified below, the Applicant company has demonstrated that a rate of incorporation of branched maltodextrin from 0.5 to 1.5%, more preferably of the order of 1%, with from 2 to 4% d waxy pregelatinized starch was enough to achieve an optimal balance between hardness and elasticity. The gelled confectionery according to the invention thus comprises an intermediate hardness of 6 to 8 N and an average elasticity of 7% to 9% and thus exhibits good firmness while preserving the elasticity required for chewing.
La confiserie gĂ©lifiĂ©e selon l’invention comprend ainsi un ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es compris de 1 Ă  8. De prĂ©fĂ©rence, le ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es est compris de 2 Ă  6, de prĂ©fĂ©rence encore de 3 Ă  5, et tout particuliĂšrement, il est d’environ 4.  The gelled confectionery according to the invention thus comprises a ratio by weight of waxy pregelatinized starch / branched maltodextrins of 1 to 8. Preferably, the ratio by weight of waxy pregelatinized starch / branched maltodextrins is between 2 and 6, more preferably from 3 to 5, and more particularly, it is approximately 4.
Une autre propriĂ©tĂ© particuliĂšrement intĂ©ressante de la prĂ©sente invention est que les diffĂ©rents constituants utilisĂ©s, Ă  savoir l’amidon waxy prĂ©gĂ©latinisĂ© et les maltodextrines branchĂ©es, n’ont pas besoin d’ĂȘtre hydratĂ©s avant leur incorporation, Ă  la diffĂ©rence de la gĂ©latine. Leur utilisation est donc plus simple.  Another particularly advantageous property of the present invention is that the various constituents used, namely pregaxatinized waxy starch and branched maltodextrins, do not need to be hydrated before their incorporation, unlike gelatin. Their use is therefore simpler.
Par ailleurs, cette Ă©tape d’hydratation de la gĂ©latine Ă©tait une Ă©tape critique du procĂ©dĂ© de fabrication des confiseries car elle comporte un risque important d’introduction de bactĂ©ries dans les prĂ©parations. En effet, la gĂ©latine est un excellent support de dĂ©veloppement des bactĂ©ries.  Furthermore, this gelatin hydration step was a critical step in the confectionery manufacturing process because it involves a significant risk of introducing bacteria into the preparations. In fact, gelatin is an excellent support for the development of bacteria.
Les confiseries gĂ©lifiĂ©es selon la prĂ©sente invention se trouvent donc ĂȘtre Ă©galement plus hygiĂ©niques car moins chargĂ©es en bactĂ©ries.  The gelled confectionery according to the present invention therefore also turns out to be more hygienic since they are less loaded with bacteria.
Selon un mode de rĂ©alisation particulier, la confiserie gĂ©lifiĂ©e selon l’invention comprend Ă©galement un agent rĂ©gulateur ou dĂ©presseur d’activitĂ© de l’eau choisis parmi le sorbitol, la glycĂ©rine et leurs mĂ©langes. Selon ce mode de rĂ©alisation, la confiserie comprend de 0,1 % Ă  15 % d'un agent rĂ©gulateur ou dĂ©presseur d'activitĂ© de l'eau, de prĂ©fĂ©rence de 1 % Ă  8 %, de façon encore plus prĂ©fĂ©rĂ©e 2 % Ă  6 %, les pourcentages Ă©tant exprimĂ©s en poids en poids sec par rapport au poids total de la confiserie. According to a particular embodiment, the gelled confectionery according to the invention also comprises a regulating or depressant agent for water activity chosen from sorbitol, glycerin and mixtures thereof. According to this embodiment, the confectionery comprises from 0.1% to 15% of a regulating or depressant agent for water activity, preferably from 1% to 8%, even more preferably 2% to 6 %, the percentages being expressed by weight in dry weight relative to the total weight of the confectionery.
L'activitĂ© de l'eau ou aw (« activity water ») reprĂ©sente la quantitĂ© d'eau libre disponible au sein d'un aliment pour d'Ă©ventuelles rĂ©actions biochimiques ultĂ©rieures. Elle ne reprĂ©sente pas la teneur en eau (ou humiditĂ©) mais bien la disponibilitĂ© de cette eau.  Water activity or aw (“activity water”) represents the amount of free water available within a food for possible subsequent biochemical reactions. It does not represent the water content (or humidity) but the availability of this water.
De plus, elle détermine directement les propriétés physiques, mécaniques, chimiques et microbiologiques de nombreuses substances, telles en entre autre que la fluidité, la coagulation, la cohésion et l'électricité statique. La capacité de conservation des aliments, la stabilité des couleurs, du goût, la teneur en vitamines, l'arÎme et les conditions favorables à la formation de moisissures et à la croissance des microbes sont directement influencés par la valeur aw. Ainsi, le fait de rajouter un agent régulateur, notamment le sorbitol, permet de baisser l'aw dans les confiseries gélifiées de la présente invention, et permet donc de préserver la texture élastique et la masticabilité desdites confiseries en stabilisant l'eau qu'elles contiennent.  In addition, it directly determines the physical, mechanical, chemical and microbiological properties of many substances, such as fluidity, coagulation, cohesion and static electricity, among others. The storage capacity of food, the stability of colors, taste, vitamin content, aroma and conditions favorable to the formation of molds and the growth of microbes are directly influenced by the aw value. Thus, the fact of adding a regulating agent, in particular sorbitol, makes it possible to lower the aw in the gelled confectionery of the present invention, and therefore makes it possible to preserve the elastic texture and the chewability of said confectionery by stabilizing the water they contain.
En effet, les confiseries gélifiées de la présente invention possÚdent la particularité d'avoir une aw inférieure à l'aw traditionnellement mesurée dans des confiseries gélifiées contenant habituellement de la gélatine.  Indeed, the gelled confectionery of the present invention has the particularity of having an aw lower than the aw traditionally measured in gelled confectionery usually containing gelatin.
Selon un autre mode de rĂ©alisation particulier, la confiserie gĂ©lifiĂ©e peut Ă©galement comprendre des sirops de glucose. Au sens de la prĂ©sente invention, les sirops de glucose sont les produits d’hydrolyse de l’amidon possĂ©dant un DE (dextrose Ă©quivalent) supĂ©rieur Ă  20. On entend par « hydrolyse de l’amidon » tout procĂ©dĂ© d'hydrolyse acide ou enzymatique d'amidon de lĂ©gumineuses, de cĂ©rĂ©ales ou de tubercules. Divers procĂ©dĂ©s d'hydrolyse sont connus et ont Ă©tĂ© dĂ©crits de maniĂšre gĂ©nĂ©rale aux pages 51 1 et 512 de l'ouvrage Encyclopedia of Chemical Technology de Kirk-Othmer, 3Ăšme Edition, Vol. 22, 1978.  According to another particular embodiment, the gelled confectionery can also comprise glucose syrups. Within the meaning of the present invention, glucose syrups are the hydrolysis products of starch having a DE (dextrose equivalent) greater than 20. The term “starch hydrolysis” means any acid or enzymatic hydrolysis process starch from legumes, cereals or tubers. Various hydrolysis processes are known and have been generally described on pages 51 1 and 512 of the book Encyclopedia of Chemical Technology by Kirk-Othmer, 3rd Edition, Vol. 22, 1978.
Selon un autre mode de rĂ©alisation particulier, la confiserie gĂ©lifiĂ©e comprend Ă©galement un ou plusieurs Ă©dulcorants. Divers Ă©dulcorants peuvent ĂȘtre utilisĂ©, tels que sucres ou polyols, sous forme de poudre ou de sirop.  According to another particular embodiment, the gelled confectionery also comprises one or more sweeteners. Various sweeteners can be used, such as sugars or polyols, in the form of powder or syrup.
Les sucres sont choisis dans le groupe constitué par les monosaccharides, les disaccharides, les trisaccharides, les oligo et polysaccharides comme par exemple les sirops de glucose, de glucose-fructose, de fructose-glucose, les sirops de glucose riches en maltose, le saccharose, le fructose, le maltose, le tréhalose, le mannose, le dextrose, le tagatose ou l'isomaltulose, seuls ou en mélange entre eux.  The sugars are chosen from the group consisting of monosaccharides, disaccharides, trisaccharides, oligo and polysaccharides such as, for example, glucose syrups, glucose-fructose, fructose-glucose, glucose syrups rich in maltose, sucrose , fructose, maltose, trehalose, mannose, dextrose, tagatose or isomaltulose, alone or as a mixture between them.
Les polyols sont préférentiellement choisis dans le groupe constitué par le maltitol, le mannitol, l'érythritol, le xylitol, l'iditol, les sirops de maltitol, l'isomalt, le lactitol, les sirops de glucose hydrogénés, seuls ou en mélange entre eux. On peut également utiliser toute sorte d'édulcorants intenses comme par exemple la saccharine, l'aspartame ou l'acésulfame K, utilisés seuls ou en mélanges synergiques. Avantageusement, le sorbitol n'est pas utilisé en tant qu'agent édulcorant dans la confiserie selon l'invention. The polyols are preferably chosen from the group consisting of maltitol, mannitol, erythritol, xylitol, iditol, maltitol syrups, isomalt, lactitol, hydrogenated glucose syrups, alone or as a mixture between them. We can also use any kind intense sweeteners such as, for example, saccharin, aspartame or acesulfame K, used alone or in synergistic mixtures. Advantageously, sorbitol is not used as a sweetening agent in the confectionery according to the invention.
L'agent édulcorant représente de préférence 25 % à 85%, de préférence de 40 % à 85%, et plus préférentiellement encore de 60 % à 85% en poids par rapport au poids total de la confiserie gélifiée.  The sweetening agent preferably represents 25% to 85%, preferably from 40% to 85%, and even more preferably from 60% to 85% by weight relative to the total weight of the gelled confectionery.
Selon un autre mode de réalisation particulier, la confiserie gélifiée peut comprendre un ou plusieurs composés choisis parmi les sucres non réducteurs, les matiÚres grasses, les agents émulsifiants, les agents conservateurs, les agents foisonnants, les agents moussants, les agents gélifiants, les agents humectants, les acidifiants, les arÎmes naturel ou synthétiques, les exhausteurs de goût, les vitamines, les actifs pharmaceutiques, les minéraux tels que calcium, magnésium et autres suppléments alimentaires tels que par exemple le DHA, les colorants naturels ou synthétiques, les sels, les acides, ou divers éléments destinés soit à améliorer la qualité, soit à aromatiser la composition tels que les fruits secs, les fruits confits, les fruits séchés ou autrement transformés (pressés, concentrés, en poudre), ainsi que les purées de fruits, pulpes de fruits, qui sont généralement présents dans ladite confiserie à hauteur de 0 à 30% en poids par rapport au poids total de la confiserie.  According to another particular embodiment, the gelled confectionery can comprise one or more compounds chosen from non-reducing sugars, fats, emulsifying agents, preserving agents, bulking agents, foaming agents, gelling agents, agents humectants, acidifiers, natural or synthetic flavors, flavor enhancers, vitamins, pharmaceutical active ingredients, minerals such as calcium, magnesium and other food supplements such as DHA, natural or synthetic colors, salts, acids, or various elements intended either to improve the quality, or to flavor the composition such as dried fruits, candied fruits, dried or otherwise processed fruits (pressed, concentrated, powdered), as well as fruit purees, fruit pulps, which are generally present in said confectionery at a level of 0 to 30% by weight relative to the total weight of the confectionery.
Un second objet de l’invention concerne un prĂ©-mĂ©lange constituĂ© d’amidon waxy prĂ©gĂ©latinisĂ© et maltodextrines branchĂ©es, ledit prĂ©-mĂ©lange Ă©tant caractĂ©risĂ© en ce qu’il comprend un ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es compris de 1 Ă  8. De prĂ©fĂ©rence, le ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es est compris de 2 Ă  6, de prĂ©fĂ©rence encore de 3 Ă  5, et tout particuliĂšrement, il est d’environ 4. A second subject of the invention relates to a premix consisting of pregaxatinized waxy starch and branched maltodextrins, said premix being characterized in that it comprises a weight ratio of pregaxatinized waxy starch / branched maltodextrins of 1 to 8. Preferably, the weight ratio of pregaxatinized waxy starch / branched maltodextrins is from 2 to 6, more preferably from 3 to 5, and very particularly, it is approximately 4.
Le prĂ©-mĂ©lange selon l’invention trouve une utilisation toute particuliĂšre dans la fabrication de confiseries gĂ©lifiĂ©es exemptes de gĂ©latines telle que dĂ©crites prĂ©cĂ©demment.  The premix according to the invention finds a very particular use in the manufacture of gelled confectionery free from gelatins as described above.
Un troisiĂšme objet de l’invention concerne un procĂ©dĂ© de prĂ©paration de confiseries gĂ©lifiĂ©es exemptes de gĂ©latine comprenant les Ă©tapes de : A third object of the invention relates to a process for the preparation of gelatin-free gelatin confectionery comprising the steps of:
prĂ©paration d’un mĂ©lange comprenant :  preparation of a mixture comprising:
o de 2 % à 4 % d’amidon waxy,  o from 2% to 4% of waxy starch,
o de 0,5 % à 1 ,5 % de maltodextrines branchées,  o from 0.5% to 1.5% of branched maltodextrins,
o au moins un Ă©dulcorant et de l’eau,  o at least one sweetener and water,
cuisson dudit mĂ©lange Ă  une tempĂ©rature comprise entre 100 et 150°C jusqu’à l’obtention de la matiĂšre sĂšche voulue,  baking said mixture at a temperature between 100 and 150 ° C until the desired dry matter is obtained,
mise en forme du mélange cuit de maniÚre à obtenir lesdites confiseries gélifiées.  shaping of the cooked mixture so as to obtain said gelled confectionery.
Les pourcentages sont exprimĂ©s en poids sec par rapport au poids total du produit final. L’amidon waxy prĂ©gĂ©latinisĂ© et les maltodextrines branchĂ©es sont tels que dĂ©finis prĂ©cĂ©demment. The percentages are expressed in dry weight relative to the total weight of the final product. Waxy pregelatinized starch and branched maltodextrins are as defined above.
Les édulcorants sont également tels que définis précédemment et représentent de préférence de 25 % à 85 %, de préférence encore de 40 % à 85 %, et plus préférentiellement encore de 60 % à 85 % en poids sec par rapport au poids total du produit final.  The sweeteners are also as defined above and preferably represent from 25% to 85%, more preferably from 40% to 85%, and more preferably still from 60% to 85% by dry weight relative to the total weight of the final product. .
La premiĂšre Ă©tape du procĂ©dĂ© selon l’invention consiste donc Ă  prĂ©parer un mĂ©lange Ă  base d’amidon waxy, de maltodextrines branchĂ©es, d’au moins un Ă©dulcorant et de l’eau.  The first step of the process according to the invention therefore consists in preparing a mixture based on waxy starch, branched maltodextrins, at least one sweetener and water.
Selon un premier mode de rĂ©alisation, l’amidon waxy du mĂ©lange est un amidon natif, c’est-Ă -dire un amidon waxy prĂ©sentant toujours sa structure granulaire. Selon ce mode de rĂ©alisation, le cuiseur mis-en-Ɠuvre dans l’étape de cuisson du mĂ©lange est adaptĂ© par l’homme du mĂ©tier de maniĂšre Ă  ce que la gĂ©latinisation de l’amidon waxy intervienne pendant ladite Ă©tape de cuisson.  According to a first embodiment, the waxy starch of the mixture is a native starch, that is to say a waxy starch always having its granular structure. According to this embodiment, the cooker used in the step of cooking the mixture is adapted by a person skilled in the art so that the gelatinization of waxy starch occurs during said cooking step.
Selon un second mode de rĂ©alisation, l’amidon waxy du mĂ©lange est un amidon waxy prĂ©gĂ©latinisĂ©, c’est-Ă -dire un amidon ayant subi un traitement thermique en prĂ©sence d’eau de sorte qu’il perde dans sa quasi-totalitĂ© sa structure granulaire et qu’il devienne soluble dans l’eau froide.  According to a second embodiment, the waxy starch of the mixture is a pregelatinized waxy starch, that is to say a starch which has undergone a heat treatment in the presence of water so that it almost entirely loses its granular structure and that it becomes soluble in cold water.
Selon une variante de ce second mode de rĂ©alisation, l’amidon waxy prĂ©gĂ©latinisĂ© est fourni en prĂ©-mĂ©lange avec les maltodextrines branchĂ©es. Le prĂ©-mĂ©lange comprend ainsi un ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es compris de 1 Ă  8. De prĂ©fĂ©rence, le ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es est compris de 2 Ă  6, de prĂ©fĂ©rence encore de 3 Ă  5, et tout particuliĂšrement, il est d’environ 4.  According to a variant of this second embodiment, the pregaxatinized waxy starch is supplied in premix with the branched maltodextrins. The premix thus comprises a weight ratio of pregaxatinized waxy starch / branched maltodextrins of from 1 to 8. Preferably, the weight ratio of pregaxatinized waxy starch / branched maltodextrins is of from 2 to 6, more preferably of 3 to 5, and more particularly, it is approximately 4.
Selon un mode de rĂ©alisation particulier, le procĂ©dĂ© selon l’invention comprend aprĂšs l’étape de mise en forme du mĂ©lange cuit une Ă©tape de rĂ©cupĂ©ration desdites confiseries gĂ©lifiĂ©es.  According to a particular embodiment, the method according to the invention comprises, after the step of shaping the cooked mixture, a step of recovering said gelled confectionery.
Selon un autre mode de rĂ©alisation particulier, le procĂ©dĂ© de prĂ©paration comprend en outre Ă©galement une Ă©tape d’ajout de sirop de glucose au mĂ©lange comprenant l’amidon waxy prĂ©gĂ©latinisĂ© et les maltodextrines branchĂ©es.  According to another particular embodiment, the preparation process also further includes a step of adding glucose syrup to the mixture comprising pregaxatinized waxy starch and branched maltodextrins.
Selon un mode de rĂ©alisation particulier, le procĂ©dĂ© selon l’invention peut comprendre en outre une Ă©tape d’ajout au mĂ©lange d’un agent rĂ©gulateur ou dĂ©presseur de l’eau avant l’étape de cuisson. On prendra alors avantageusement du sorbitol, incorporĂ© dans la recette Ă  raison de 2 Ă  3 % en poids sec par rapport au poids total du produit final.  According to a particular embodiment, the method according to the invention may also comprise a step of adding to the mixture of a regulating or depressant agent of the water before the cooking step. We will then advantageously take sorbitol, incorporated into the recipe at a rate of 2 to 3% by dry weight relative to the total weight of the final product.
Avantageusement, par la mise en Ɠuvre d’amidon waxy de maniĂšre Ă  substituer la gĂ©latine dans la confiserie gĂ©lifiĂ©e, le procĂ©dĂ© selon l’invention permet de s’affranchir d’une Ă©tape prĂ©alable d’hydratation caractĂ©ristique des procĂ©dĂ©s de fabrication de confiseries gĂ©lifiĂ©es Ă  base de gĂ©latine. Le procĂ©dĂ© de prĂ©paration selon l’invention comprend Ă©galement une Ă©tape de cuisson du mĂ©lange comprenant l’amidon waxy, les maltodextrines branchĂ©es, au moins un Ă©dulcorant et l’eau. Advantageously, by using waxy starch so as to substitute gelatin in the gelled confectionery, the method according to the invention makes it possible to dispense with a prior hydration step characteristic of the gelling confectionery manufacturing processes. gelatin base. The preparation process according to the invention also comprises a step of cooking the mixture comprising waxy starch, branched maltodextrins, at least one sweetener and water.
La durĂ©e de l’étape de cuisson est adaptĂ©e par l’homme du mĂ©tier et dĂ©pend du matĂ©riel utilisĂ©.  The duration of the cooking step is adapted by the skilled person and depends on the material used.
L’étape de cuisson peut ĂȘtre effectuĂ©e sur des cuiseurs Ă  double enveloppe Ă  pression atmosphĂ©rique, sous vide partiel ou total ou sous pression, ou en continu sur des cuiseurs haute pression comme les Ă©changeurs tubulaires, les Ă©changeurs Ă  plaques ou les « jet-cookers ». Le « jet-cooker » peut comporter un ou plusieurs injecteurs de vapeur, ce qui modifie les temps de cuisson. L’injection de vapeur vive dans le produit assure une dispersion rapide et homogĂšne de la chaleur et des ingrĂ©dients. L’échangeur tubulaire nĂ©cessite une dispersion homogĂšne de tous les ingrĂ©dients avant cuisson, les durĂ©es de cuisson sont plus longues et l’intensitĂ© moins forte (cuiseur surface raclĂ©e ou vis de cuisson - atmosphĂ©rique).  The cooking step can be carried out on double-envelope cookers at atmospheric pressure, under partial or total vacuum or under pressure, or continuously on high-pressure cookers such as tubular exchangers, plate exchangers or “jet cookers”. ". The “jet-cooker” can include one or more steam injectors, which changes the cooking times. The injection of live steam into the product ensures rapid and uniform dispersion of heat and ingredients. The tubular exchanger requires a homogeneous dispersion of all the ingredients before cooking, the cooking times are longer and the intensity less strong (cooker scraped surface or cooking screw - atmospheric).
Selon un mode de rĂ©alisation particulier de l’invention, on peut tout Ă  fait envisager de cuire l’amidon waxy sĂ©parĂ©ment puis d’y ajouter les autres ingrĂ©dients, ou de prĂ©chauffer l’édulcorant avant d’y ajouter l’amidon waxy, par exemple sous forme d’une solution Ă  50 % de matiĂšre sĂšche.  According to a particular embodiment of the invention, it is entirely possible to cook the waxy starch separately and then add the other ingredients to it, or to preheat the sweetener before adding the waxy starch to it, by example in the form of a 50% solution of dry matter.
Pour une fabrication en continu, on prĂ©fĂšre disperser les Ă©dulcorants, l’amidon waxy prĂ©gĂ©latinisĂ©, les maltodextrines branchĂ©es et l’agent rĂ©gulateur dans une cuve de mĂ©lange, prĂ©chauffer ce mĂ©lange Ă  environ 70-80°C pour dissoudre les Ă©dulcorants, cuire le mĂ©lange sur cuiseur haute pression Ă  une tempĂ©rature comprise entre 100 et 150°C suivant la texture souhaitĂ©e et le type de confiserie prĂ©parĂ©e, puis ajouter la matiĂšre grasse, l’émulsifiant le ou les agents foisonnants, les arĂŽmes, les colorants, les principes actifs, et les Ă©dulcorants intenses.  For continuous production, it is preferable to disperse the sweeteners, pregaxatinized waxy starch, the branched maltodextrins and the regulating agent in a mixing tank, preheat this mixture to around 70-80 ° C to dissolve the sweeteners, cook the mixture on a high-pressure cooker at a temperature between 100 and 150 ° C depending on the desired texture and the type of confection prepared, then add the fatty matter, the emulsifier the abundant agent (s), the flavors, the colors, the active ingredients, and intense sweeteners.
Selon un mode de rĂ©alisation particulier, le procĂ©dĂ© selon l’invention comprend une Ă©tape d’ajout de matiĂšre grasse aprĂšs l’étape de cuisson.  According to a particular embodiment, the method according to the invention comprises a step of adding fat after the cooking step.
Selon un autre mode de rĂ©alisation particulier, le procĂ©dĂ© comprend une Ă©tape d’ajout d’un ou plusieurs composĂ©s choisis parmi les sucres non rĂ©ducteurs, les matiĂšres grasses les agents Ă©mulsifiants, les agents conservateurs, les agents foisonnants, les agents moussants, les agents gĂ©lifiants, les agents humectants, les acidifiants, les arĂŽmes naturel ou synthĂ©tiques, les exhausteurs de goĂ»t, les vitamines, les actifs pharmaceutiques, les minĂ©raux tels que calcium, magnĂ©sium et autres supplĂ©ments alimentaires tels que par exemple le DHA, les colorants naturels ou synthĂ©tiques, les sels, les acides, ou divers Ă©lĂ©ments destinĂ©s soit Ă  amĂ©liorer la qualitĂ©, soit Ă  aromatiser la composition tels que les fruits secs, les fruits confits, les fruits sĂ©chĂ©s ou autrement transformĂ©s (pressĂ©s, concentrĂ©s, en poudre), ainsi que les purĂ©es de fruits, pulpes de fruits. De prĂ©fĂ©rence, le procĂ©dĂ© comprend une Ă©tape d’ajout d’un ou plusieurs composĂ©s choisis parmi les agents Ă©mulsifiants et les acides. Selon un autre mode de rĂ©alisation particulier, AprĂšs la cuisson, la matiĂšre grasse, l’émulsifiant le ou les agents foisonnants, les arĂŽmes, colorants, acides et autres sont ajoutĂ©s dans le sirop chaud Ă  une tempĂ©rature comprise entre 60 et 90°C, le mĂ©lange est ensuite coulĂ© sur une plaque de refroidissement, et on procĂšde Ă  un Ă©tirage pendant environ une minute Ă  50- 60 battements (l’étirage est utilisĂ© pour les texture « longues, », sans amorce de cristallisation ou avec amorce pour les textures « courtes = cristallisĂ©es). According to another particular embodiment, the method comprises a step of adding one or more compounds chosen from non-reducing sugars, fats, emulsifying agents, preserving agents, abundant agents, foaming agents, agents gelling agents, humectants, acidifiers, natural or synthetic flavors, flavor enhancers, vitamins, pharmaceutical active ingredients, minerals such as calcium, magnesium and other food supplements such as DHA, natural or synthetic colors , salts, acids, or various elements intended either to improve the quality or to flavor the composition such as dried fruits, candied fruits, dried or otherwise processed fruits (pressed, concentrated, powdered), as well as fruit purees, fruit pulps. Preferably, the method comprises a step of adding one or more compounds chosen from emulsifying agents and acids. According to another particular embodiment, after cooking, the fatty matter, the emulsifier or the abundant agents, the flavors, colorings, acids and others are added to the hot syrup at a temperature between 60 and 90 ° C., the mixture is then poured onto a cooling plate, and a stretching is carried out for approximately one minute at 50-60 beats (the stretching is used for “long” textures, without primer for crystallization or with primer for textures "Short = crystallized).
Une fois l’étirage effectuĂ©, on procĂšde Ă  la mise en forme et au papillonnage des confiseries obtenues.  Once the stretching has been carried out, the confectionery obtained is shaped and fluffed.
Selon ce mode de rĂ©alisation, En premiĂšre alternative, la matiĂšre grasse peut-ĂȘtre ajoutĂ©e avant si une Ă©mulsion est rĂ©alisĂ©e au prĂ©alable.  According to this embodiment, As a first alternative, the fat may be added before if an emulsion is produced beforehand.
En seconde alternative, Ă  la place de l’étirage, on peut rĂ©aliser un mĂ©lange vigoureux dans un pĂ©trin afin d’amorcer la cristallisation (texture courte).  As a second alternative, instead of stretching, a vigorous mixture can be made in a kneading machine in order to initiate crystallization (short texture).
L’invention sera encore mieux comprise Ă  la lecture de l’exemple qui suit, lequel se veut illustratif et non limitatif en faisant seulement Ă©tat de certains modes de rĂ©alisation et de certaines propriĂ©tĂ©s avantageuses selon l’invention. The invention will be better understood on reading the example which follows, which is intended to be illustrative and non-limiting, only reporting on certain embodiments and certain advantageous properties according to the invention.
Exemple : PrĂ©paration de confiseries gĂ©lifiĂ©es selon l’invention Example: Preparation of gelled confectionery according to the invention
L’objectif est de rĂ©aliser des confiseries gĂ©lifiĂ©es de type pĂątes Ă  mĂącher contenant du sucre selon la prĂ©sente invention mais ne contenant pas de gĂ©latine. The objective is to produce gummy confectionery of the chewing paste type containing sugar according to the present invention but not containing gelatin.
Dans cet exemple, des pĂątes Ă  mĂącher ont Ă©tĂ© rĂ©alisĂ©es en incorporant Ă  chaque nouvel essai des proportions variables en amidon waxy prĂ©gĂ©latinisĂ© et en maltodextrines branchĂ©es, et des mesures d’élasticitĂ© et de duretĂ© des pĂątes Ă  mĂącher ainsi obtenues ont Ă©tĂ© effectuĂ©es. In this example, chewing pastes were produced by incorporating, with each new test, variable proportions of pregaxatinized waxy starch and branched maltodextrins, and measurements of the elasticity and hardness of the chewing pastes thus obtained were carried out.
A - Formulations des différentes confiseries gélifiées A - Formulations of the various gelled confectionery
Les formulations utilisées pour les 10 essais sont présentées dans le tableau 1 ci- dessous. The formulations used for the 10 tests are presented in Table 1 below.
L’amidon waxy prĂ©gĂ©latinisĂ© utilisĂ© est le PREGEFLOÂź C100. The pregelatinized waxy starch used is PREGEFLO Âź C100.
Les maltodextrines branchées utilisées sont des NUTRIOSEŸ FM06. The branched maltodextrins used are NUTRIOSE Ÿ FM06.
Le sirop de glucose utilisé est le sirop de glucose C4280S commercialisé par la société The glucose syrup used is the C4280S glucose syrup sold by the company
Demanderesse. Applicant.
La matiĂšre grasse utilisĂ©e est de la graisse de Coprah 24/26. Les sucroesters sont des esters de saccharose et d’acides gras obtenus par transestĂ©rification d’esters mĂ©thyliques et de saccharose, utilisĂ©s comme agents Ă©mulsifiants non ioniques des matiĂšres grasses, et commercialisĂ©s par la sociĂ©tĂ© StĂ©arinerie Dubois (Boulogne, France). The fat used is Copra 24/26 fat. Sucroesters are sucrose and fatty acid esters obtained by transesterification of methyl esters and sucrose, used as non-ionic emulsifiers for fatty substances, and marketed by the company StĂ©arinerie Dubois (Boulogne, France).
Tableaux 1  Tables 1
B - Procédé de préparation de la confiserie gélifiée : B - Process for preparing gelled confectionery:
- Verser l’eau potable froide dans une cuve, - Pour cold drinking water into a tank,
- Introduire sous agitation Ă©nergique l’amidon waxy prĂ©gĂ©latinisĂ© et le NUTRIOSEÂź,- Introduce, with vigorous stirring, waxy pregelatinized starch and NUTRIOSE Âź ,
- AprĂšs dispersion et vĂ©rification de l’absence de grumeaux, introduire toujours sous agitation le sirop de glucose, - After dispersing and checking for the absence of lumps, always add the glucose syrup with stirring,
- Puis terminer par l’ajout du saccharose.  - Then finish by adding sucrose.
- Cuire le mĂ©lange prĂ©cĂ©dent est Ă  tempĂ©rature dĂ©terminĂ©e et Ă  pression atmosphĂ©rique pour obtenir un mĂ©lange Ă  90-94% de matiĂšres sĂšches. GĂ©nĂ©ralement la tempĂ©rature de cuisson se situe entre 105 et 150°C. Il est Ă©galement possible de cuire le prĂ©cĂ©dent mĂ©lange sous vide Ă  une pression de -0,5 bar. Bien mĂ©langer pendant l’étape de cuisson afin d’éviter que le mĂ©lange ne brĂ»le.  - Cook the previous mixture at a determined temperature and at atmospheric pressure to obtain a mixture of 90-94% dry matter. Generally the cooking temperature is between 105 and 150 ° C. It is also possible to cook the previous mixture under vacuum at a pressure of -0.5 bar. Mix well during the cooking step to prevent the mixture from burning.
- Introduire aprĂšs l’étape de cuisson la matiĂšre grasse fondue Ă  50-60°C ou non fondue avec l’émulsifiant. Bien mĂ©langer.  - Introduce after the cooking step the fat melted at 50-60 ° C or not melted with the emulsifier. Mix well.
- Une fois la masse refroidie en dessous des 80°C, ajouter l’acide citrique, puis l’arîme.  - Once the mass has cooled below 80 ° C, add the citric acid, then the aroma.
- Couler la pĂąte Ă  mĂącher sur une table Ă  refroidissement jusqu’à ĂȘtre Ă  une tempĂ©rature comprise entre 50 et 60°C.  - Pour the chewy dough on a cooling table until it is between 50 and 60 ° C.
- Etirer la pĂąte Ă  mĂącher pendant 1 minute (50 Ă  60 battements) pour obtenir une bonne aĂ©ration. L’aĂ©ration peut Ă©galement ĂȘtre obtenue dans un foisonneur sous pression (1 Ă  2 bars) dans un procĂ©dĂ© de fabrication en continu.  - Stretch the chewy dough for 1 minute (50 to 60 beats) to obtain good ventilation. Aeration can also be obtained in a pressure blower (1 to 2 bars) in a continuous manufacturing process.
- Laisser la pĂąte Ă  mĂącher aĂ©rĂ©e au repos pour son refroidissement (entre 45°C et 55°C) et afin qu’elle reprenne de la texture.  - Leave the aerated chewing dough to rest for cooling (between 45 ° C and 55 ° C) and so that it regains its texture.
- Former, découper, et éventuellement, emballer les confiseries.  - Form, cut, and possibly pack the confectionery.
C - MĂ©thodes de mesure C - Measurement methods
Pour ces diffĂ©rents essais, les mesures ont Ă©tĂ© rĂ©alisĂ©es sur TexturomĂštre INSTRON en suivant les spĂ©cificitĂ©s du constructeur pour faire les mesures de duretĂ© et d’élasticitĂ©, de la maniĂšre suivante: For these different tests, the measurements were carried out on an INSTRON texturometer following the manufacturer's specifications to make the hardness and elasticity measurements, as follows:
D - RĂ©sultats D - Results
Les résultats sont présentés dans le tableau 2 suivant : Tableau 2. The results are presented in Table 2 below: Table 2.
Prenant en considĂ©ration le fait que les confiseries sans gĂ©latines selon l’invention sont de qualitĂ© satisfaisante et un Ă©quilibre optimal pour des valeurs de duretĂ© intermĂ©diaire comprise entre 6 et 8 N, et des valeurs d’élasticitĂ© moyenne comprise entre 7 et 9 %, on en dĂ©duit que pour des teneurs de 0,5 Ă  1 ,5 %, plus prĂ©fĂ©rentiellement d’environ 1 % de NUTRIOSEÂź, il est nĂ©cessaire d’introduire un taux de 2 % Ă  4 % d’amidon waxy prĂ©gĂ©latinisĂ©. Taking into consideration the fact that the candies without gelatins according to the invention are of satisfactory quality and an optimal balance for intermediate hardness values between 6 and 8 N, and average elasticity values between 7 and 9%, we deduced that for concentrations of 0.5 to 1, 5%, more preferably from about 1% NUTRIOSE Âź, it is necessary to introduce a rate of 2% to 4% of pregelatinized waxy starch.

Claims

REVENDICATIONS
1. Confiserie gélifiée exempte de gélatine comprenant : 1. Gelatin-free gelatin confectionery comprising:
de 2 % Ă  4 % d’amidon waxy prĂ©gĂ©latinisĂ©,  from 2% to 4% of pregaxatinized waxy starch,
de 0,5 % à 1 ,5 % de maltodextrines branchées,  from 0.5% to 1.5% of branched maltodextrins,
les pourcentages étant exprimés en poids sec par rapport au poids total du produit final.  the percentages being expressed in dry weight relative to the total weight of the final product.
2. Confiserie selon la revendication 2, caractĂ©risĂ©e en ce qu’elle comprend environ 1 % de maltodextrines, le pourcentage Ă©tant exprimĂ© en en poids sec par rapport au poids sec total du produit final. 2. Confectionery according to claim 2, characterized in that it comprises approximately 1% of maltodextrins, the percentage being expressed in dry weight relative to the total dry weight of the final product.
3. PrĂ©-mĂ©lange constituĂ© d’amidon waxy prĂ©gĂ©latinisĂ© et maltodextrines branchĂ©es, ledit prĂ©mĂ©lange Ă©tant caractĂ©risĂ© en ce qu’il comprend un ratio en poids d’amidon waxy prĂ©gĂ©latinisĂ©/maltodextrines branchĂ©es compris de 1 Ă  8. 3. Premix consisting of pregaxatinized waxy starch and branched maltodextrins, said premix being characterized in that it comprises a weight ratio of pregaxatinized waxy starch / branched maltodextrins of 1 to 8.
4. PrĂ©-mĂ©lange constituĂ© d’amidon waxy prĂ©gĂ©latinisĂ© et maltodextrines branchĂ©es selon la revendication 3, caractĂ©risĂ© en ce que ledit ratio est compris de 3 Ă  5. 4. Premix consisting of pregelatinized waxy starch and branched maltodextrins according to claim 3, characterized in that said ratio is from 3 to 5.
5. PrĂ©-mĂ©lange constituĂ© d’amidon waxy prĂ©gĂ©latinisĂ© et maltodextrines branchĂ©es selon la revendication 4, caractĂ©risĂ© en ce que ledit ratio est d’environ 4. 5. Pre-mixture consisting of pregaxatinized waxy starch and branched maltodextrins according to claim 4, characterized in that said ratio is approximately 4.
6. Utilisation du prĂ©-mĂ©lange selon l’une des revendications 3 Ă  5, pour la fabrication d’une confiserie exempte de gĂ©latine. 6. Use of the premix according to one of claims 3 to 5, for the manufacture of a gelatin-free confectionery.
7. Procédé de préparation de confiseries gélifiées exemptes de gélatine comprenant les étapes de : 7. Process for the preparation of gelatin-free candy confectionery comprising the steps of:
prĂ©paration d’un mĂ©lange comprenant :  preparation of a mixture comprising:
o de 2 % à 4 % d’amidon waxy,  o from 2% to 4% of waxy starch,
o de 0,5 % à 1 ,5 % de maltodextrines branchées,  o from 0.5% to 1.5% of branched maltodextrins,
o au moins un Ă©dulcorant et de l’eau,  o at least one sweetener and water,
cuisson dudit mĂ©lange Ă  une tempĂ©rature comprise entre 100 et 150°C jusqu’à l’obtention de la matiĂšre sĂšche voulue,  baking said mixture at a temperature between 100 and 150 ° C until the desired dry matter is obtained,
mise en forme du mélange cuit de maniÚre à obtenir lesdites confiseries gélifiées  shaping of the cooked mixture so as to obtain said gelled confectionery
8. ProcĂ©dĂ© de prĂ©paration de confiseries gĂ©lifiĂ©es exemptes de gĂ©latine selon la revendication 7, caractĂ©risĂ© en ce que l’amidon waxy du mĂ©lange est un amidon waxy prĂ©gĂ©latinisĂ©. 8. A method of preparing gelatin-free gelatin confectionery according to claim 7, characterized in that the waxy starch of the mixture is a pregaxatinized waxy starch.
EP19742439.3A 2018-06-15 2019-06-14 Gelatin-free gelled confectionery and method for preparing such a confectionery Pending EP3806646A1 (en)

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FR1855289A FR3082390B1 (en) 2018-06-15 2018-06-15 GELATIN FREE GELATIN CONFECTIONERY AND PROCESS FOR PREPARING SUCH A CONFECTIONERY
PCT/FR2019/051445 WO2019239073A1 (en) 2018-06-15 2019-06-14 Gelatin-free gelled confectionery and method for preparing such a confectionery

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WO1997000620A1 (en) * 1995-06-23 1997-01-09 Cerestar Usa, Inc. Natural gum replacer
FR2786775B1 (en) 1998-12-04 2001-02-16 Roquette Freres BRANCHED MALTODEXTRINS AND THEIR PREPARATION PROCESS
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FR2997818B1 (en) 2012-11-14 2015-10-23 Roquette Freres GELIFIED CONFECTIONERY AND PROCESS FOR PREPARING SUCH CONFECTIONERY
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CA3101725A1 (en) 2019-12-19

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