EP3797213A1 - Secteur angulaire d'aubage de turbomachine a etancheite perfectionnee - Google Patents
Secteur angulaire d'aubage de turbomachine a etancheite perfectionneeInfo
- Publication number
- EP3797213A1 EP3797213A1 EP19740611.9A EP19740611A EP3797213A1 EP 3797213 A1 EP3797213 A1 EP 3797213A1 EP 19740611 A EP19740611 A EP 19740611A EP 3797213 A1 EP3797213 A1 EP 3797213A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sector
- block
- angular
- sectors
- crown
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/001—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between stator blade and rotor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/08—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator
- F01D11/12—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part
- F01D11/127—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part with a deformable or crushable structure, e.g. honeycomb
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2250/00—Geometry
- F05D2250/10—Two-dimensional
- F05D2250/18—Two-dimensional patterned
- F05D2250/182—Two-dimensional patterned crenellated, notched
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2250/00—Geometry
- F05D2250/10—Two-dimensional
- F05D2250/18—Two-dimensional patterned
- F05D2250/183—Two-dimensional patterned zigzag
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2250/00—Geometry
- F05D2250/20—Three-dimensional
- F05D2250/28—Three-dimensional patterned
- F05D2250/283—Three-dimensional patterned honeycomb
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2260/00—Function
- F05D2260/30—Retaining components in desired mutual position
- F05D2260/36—Retaining components in desired mutual position by a form fit connection, e.g. by interlocking
Definitions
- the invention relates to an angular sector of a turbomachine vane, in particular an angular sector of a vane such as a rectifier equipping a compressor or such as a distributor equipping a turbine of the turbomachine.
- the gas turbine engines comprise, in known manner, fixed internal blade crowns, which are mounted in external casings of a primary flow stream of the engine and which are interposed axially between mobile compressor blade wheels or between mobile turbine blade wheels of these engines.
- Each fixed rotor ring is mounted with a dynamic seal around a compressor or turbine rotor.
- each ring of fixed blades has internally a block of abradable material which is intended to cooperate with wiper seals integral in rotation of the associated compressor rotor or turbine to allow to ensure gas tightness.
- Part of the gas is nevertheless likely to creep between the fixed blades and the moving blades of the compressor or turbine rotors, in the opposite direction of the main flow circulating in the primary flow vein.
- Fixed internal blade crowns are rectifiers when interposed between compressor wheels, or constitute distributors when interposed between turbine wheels.
- the fixed blade crowns are often made in the form of an assembly of angular sectors which are juxtaposed with each other. next to the others until forming an entire crown of fixed blades. These crowns thus reveal an inter-sector clearance that allows for recirculation passages for gases, no longer around the feet of the angular sectors, but between them.
- the difficulty in ensuring a satisfactory level of sealing lies in the fact that the angular sectors of the crown move because of the mechanical and thermal deformations occurring during the operation of the engine.
- the clearance between the sectors and the leakage rate vary during the operation of the engine.
- the hot play during operation of the engine must also never be zero because contact between the platforms of the sectors may cause ovalization of the casing which is external to the fixed blade and / or matting of the surfaces in contact, this which could increase drastically the stresses exerted on the fixed blade, with the consequence in particular a postponement of these constraints on the outer casing of the engine which receives the fixed blade.
- a postponement of these constraints may have the consequence of causing an ovalization of the outer casing and of significantly modifying the radial clearances between this casing and the neighboring mobile blades, with a very negative impact for the engine in terms of service life.
- the sealing between two adjacent adjacent fixed crown crown sectors is ensured by tongue-and-groove sealing systems interposed between these sectors in order to limit leaks between sectors.
- These sealing systems can be used to seal fixed rotor crown sectors placed in the primary flow vein, and also, in the case of a double-flow motor, to seal sectors. fixed crown crown placed in the vein of secondary flow.
- tabs are housed between two adjacent sectors in housings that have been machined in the sectors.
- the tabs make it possible to hinder the flow of gases passing through the inter-sector clearance.
- an angular sector of the blade crown comprises, with respect to the axis of the ring gear, a radially outer platform substantially in the form of an angular section of a cylinder, a radially inner platform in the form of an angular section of a cylinder, at least two vanes extending between said platforms, a foot connected to the inner platform and at least one block of abradable honeycomb material extending inside the foot.
- the tabs interposed between two sectors are embedded in the mass of the two adjacent feet of the two sectors and in housing vis-à-vis the inner and outer platforms adjacent to the two sectors.
- the tabs can not be arranged over the entire radial thickness of the foot. As a result, there remains between the gaming sectors through which the gases can circulate.
- the invention proposes to take advantage of the existing block of abradable material arranged inside the inner platform to provide a seal directly between transverse end walls of two adjacent angular sectors.
- the invention proposes an angular sector of a fixed turbomachine rotor crown, in particular a stator or a distributor, said sector extending at a determined angle around an axis of the fixed crown of blades. and comprising, with respect to the axis of said fixed crown ring, a radially outer platform, a radially inner platform, at least two vanes which extend between said platforms, and at least one block of abradable nest material, bees that extend internally to the inner platform between transverse ends of the sector.
- the block of abradable honeycomb material for example comprises a radially inner radial sealing face which is configured to cooperate with wipers of a labyrinth seal carried by a rotor of the turbomachine.
- this angular sector is characterized in that the block of abradable material comprises at least one transverse end wall which is shaped according to a toothed profile comprising at least one radially extending tooth extending over a whole. radial thickness of said block.
- the block of abradable material extends to the inner platform
- each at least one tooth protrudes transversely from said block and is made of said abradable honeycomb material of said block,
- the toothed profile has, in section in a plane perpendicular to the radial direction, a sawtooth shape
- the toothed profile has, in section in a plane perpendicular to the radial direction, a crenellated form
- the toothed profile comprises a single tooth shaped as a tenon
- the single tooth formed as a tenon extends from one of the axial ends of the block
- the abradable honeycomb material of the block comprises tubular cells oriented radially.
- the invention also relates to an assembly of two adjacent angular sectors of the type described above, characterized in that said at least one transverse end wall formed according to a tooth profile of said adjacent angular sectors are facing each other, and in that said toothed profiles are complementary.
- the invention relates to a fixed turbomachine rotor crown comprising a plurality of angular sectors of fixed rotor crown, characterized in that it comprises a predetermined number of sectors whose juxtaposition forms the entire crown of blading fixed, in that each angular sector comprises two opposite transverse end walls which are shaped according to toothed profiles each comprising at least one radially oriented tooth and in that each angular sector is assembled with each of the angular sectors which are adjacent in an assembly of the type described above.
- FIG. 1 is a schematic sectional view of a turbomachine according to the state of the art
- FIG. 2 is a sectional detail view of a turbine of the turbomachine of FIG. 1,
- FIG. 3 is a sectional detail view of a compressor of the turbomachine of FIG. 1,
- FIG. 4 is a perspective view of an assembly of angular sectors of vane according to the invention.
- FIG. 5A is a sectional view of a crown crown sector according to the state of the art
- FIG. 5B is a sectional view of a sector of a blade crown according to the invention.
- FIG. 6 is a diagrammatic sectional view of a first tooth profile of a block of abradable material of a sector of a crown of blading according to the invention
- FIG. 7 is a diagrammatic cross-sectional view of a second tooth profile of a block of abradable material of a crown crown sector according to the invention.
- FIG. 8 is a diagrammatic sectional view of a third tooth profile of a block of abradable material of a sector of a crown of blading according to the invention.
- FIG. 9 is a schematic sectional view of a fourth tooth profile of a block of abradable material of a blade crown sector according to the invention.
- axial direction By axial direction, will be designated by extension any direction parallel to an axis A of a turbomachine, and by radial direction any direction perpendicular and extending radially relative to the axial direction.
- FIG. 1 shows a turbomachine 10 of axis A of the double flow type.
- a turbomachine 10 here a turbojet engine 10
- LP low pressure compressor
- HP high pressure compressor
- HP high pressure turbine
- LP low pressure turbine
- exhaust nozzle 24 The rotor of the HP compressor 16 and the rotor of the HP turbine 20 are connected by an HP high pressure shaft 26 and form with it a high pressure body.
- the rotor of the LP compressor 14 and the rotor of the LP low pressure turbine 22 are connected by an LP shaft 28 and form with it a low pressure body.
- the high and low pressure bodies are traversed by a primary air flow "P” and the fan 12 produces a secondary air flow “S” which circulates in the turbojet engine 10, between a casing 11 and an outer casing 13 of the turbojet engine. in a cold flow channel 15.
- the gases from the primary flow "P” are mixed with the secondary flow "S” to produce a propulsive force, the secondary flow "S” providing the majority here of the thrust.
- the compressors BP 14 and HP 16 and the turbines HP 20 and BP 22 each respectively comprise several stages of compressor or turbine.
- the LP turbine 22 comprises several turbine blades 22a, 22b, 22c, 22d, 22e of which the vanes are carried by associated ferrules 30a, 30b, 30c, 30d, 30e which are assembled to one another by bolts 36.
- the LP turbine 22 further comprises fixed rotor crowns 32a, 32b, 32c, 32d of a diffuser 32 which are interposed between the turbine blades 22a, 22b, 22c, 22d, 22e.
- Each ring of fixed vanes 32a, 32b, 32c, 32d of diffuser is formed of an assembly of sectors 34a, 34b, 34c, 34d fixed crown of rings, assembled around the axis A of the turbomachine 360 ° so as to form a fixed rotor ring 32a, 32b, 32c, 32d complete about the axis A of the turbomachine.
- the HP compressor 16 of the turbomachine 10 may comprise a series of wheels 22a, 22b of mobile compressor blades between which are interwoven crowns 32a of fixed blades of rectifier which are themselves made in the form of an assembly of angular sectors 34a of fixed blade crowns. It will therefore be understood that the invention applies to any assembly of angular sectors 34a of fixed rotor crown 32a, whether angular sectors 34a of a rectifier for a compressor or angular sectors 34a d a diffuser for a turbine.
- a fixed compressor crown 32a consists of an assembly of angular crown sectors 34a. It can be seen that each ring of fixed blades, and in particular the ring gear 32a, is placed in the primary flow stream P forming a clearance with the adjacent compressor wheels 22a and 22b, and in particular with ferrules 30a and 30b of these wheels 22a, 22b. Part of the pressurized gases of the primary flow P, which flows from upstream to downstream, tends to creep between the shells 30a and 30b and the angular sector 34a to recirculate from downstream to upstream according to a recirculation flow rc, represented by the arrows of Figure 3, which tends to bypass the angular sector 34a.
- this recirculation flow rc is particularly penalizing.
- the recirculation flow rc tends to reduce the performance of the compressor, or similarly when it is a turbine, the performance of said turbine. This is the reason why current designs tend to minimize this recirculation flow rc by equipping the angular sector 34a with sealing means with the ferrule it surrounds.
- each sector 34a extends at a determined angle around the axis of the ring gear 32a, which corresponds to the axis A of the turbomachine previously illustrated in FIG.
- each sector 34a comprises, relative to the axis A of the ring 32a, a radially outer platform 38a, a radially inner platform 40a, at least two blades 42a which extend between said platforms 38a, 40a, a foot 43a which extends radially inwardly from the inner platform 40a and at least one block 44a of abradable honeycomb material which therefore therefore extends internally also to the inner platform 40a between ends transverse (not shown) of the angular sector 34a.
- a radially inner radial sealing face 46a is configured to cooperate with wipers 48a of a labyrinth seal 50a carried by a rotor of the turbomachine, here the ferrule 30a.
- This configuration substantially reduces the intensity of recirculation flow rc flowing between sector 34a and ferrule 30a. However, it has no influence on the recirculation flow between two adjacent sectors 34a.
- the sealing between adjacent sectors 34a is achieved by means of tabs (not shown) which are received in housings opposite the adjacent sectors 34a and which are arranged between these sectors 34a to form a barrier to the recirculation flow between sectors 34a.
- This configuration is particularly expensive because it requires making housing for the tabs in particular in the feet 43a and because it requires special mounting precautions, particularly with regard to sectors that are intended to close the entire blade during of its assembly.
- the invention proposes to simplify the sealing between the sectors 34a by taking advantage of the block 44a of abradable material already present radially inside the inner platform 40a so as to ensure a seal directly between transverse end walls of two adjacent angular sectors.
- the invention proposes an angular sector 34a of a fixed turbomachine rotor crown of the type described above, characterized in that the block 44a of abradable material comprises at least one wall transverse end 52a which is shaped according to a toothed profile 54a1, 54a2 having at least one radially oriented tooth 56a1, 56a2 R, said at least one radial tooth 56a1, 56a2 extending along an entire radial thickness of said block 44a.
- Figure 4 shows an assembly of two angular sectors 34a fixed crown of blades.
- Each of these two fixed rotor crown angular sectors 34a has a transverse end wall 52a which faces the transverse end wall 52a of the other fixed crown crown sector 34a.
- the block 44a of one of the sectors 34a comprises a toothed profile 54a1 comprising at least one tooth 56a1 and the block 44a of the other of the sectors 34a comprises a toothed profile 54a2, complementary to the tooth profile 54a1, which comprises at least a tooth 56a1. Sealing is therefore provided in the opposite direction of the primary flow P by the cooperation of the transverse end walls 52a and their toothed profiles 54a1 and 54a2 complementary.
- the fixed rotor crown 32a comprises a predetermined number of crown sectors 34a whose juxtaposition forms the entirety of the fixed crown 32a and comprises at least two of these angular crown sectors 34a having toothed profiles. 54a1, 54a2. It will be understood that, of course, all crown sectors 34a preferably comprise toothed profiles.
- each angular sector 34a is assembled with each of the angular sectors 34a which are adjacent to it in an assembly of the type described above, and each block 44a has at its two ends opposite transverse end walls 52a which are shaped according to toothed profiles. 54a1, 54a2 intended to cooperate with the toothed profiles 54a1, 54a2 with radially oriented teeth of the adjacent blocks 44a.
- the block of abradable material 44a of the sector 34a extends to the inner platform 40a.
- This configuration has been shown in Figure 5B.
- the foot 43a has been removed and the block 44a of honeycomb material has been extended radially to the inner platform 40a so as to give a maximum height to the block 44a of honeycomb material, and in doing so, to give it maximum sealing.
- this configuration makes it possible to dispense with the installation of a conventional sealing system with tabs arranged on the foot 43a.
- each inner platform 40a has an end edge 58a which is shaped according to a toothed profile 60a1, 60a2 which is superimposed on the toothed profile 54a1, 54a2 of the block of honeycomb material 44a corresponding.
- toothed profiles 60a1, 60a2 are also complementary to one another.
- the configuration is not limiting of the invention, and the end edges 58a of the inner platforms 40a could be rectilinear.
- each tooth 56a1 or 56a2 of each block 44a can be made in different ways.
- the teeth 56a1 or 56a2 could be reported to the block 44a, provided they protrude from the block 44a.
- each tooth 56a1 or 56a2 is preferably made directly in the abradable honeycomb material of the block 44a.
- the toothed profile 54a1, 54a2 of the block of honeycomb material 44a can take different configurations depending on the desired seal.
- the number of teeth 56a1 or 56a2 will result from a compromise between the efficiency of reducing the flow rate of the recirculation flow rc and the cost of obtaining the ring 32a formed of the angular sectors 34a, this cost including the realization of these sectors 34a and their assembly.
- the toothed profile 54a1, 54a2 may have, in section in a plane perpendicular to a radial direction R, a crenellated shape, ie having substantially sectioned teeth. rectangular or square.
- the toothed profile 54a1, 54a2 may have, in section in the plane perpendicular to the radial direction R, a sawtooth form.
- the toothed profile 54a1, 54a2 of each sector 44a may comprise a tenon which is the only tooth 56a1, 56a2.
- the single tooth shaped tooth 56a1, 56a2 extends from one of the axial ends 62a1 or 62a2 of the block 44a.
- the abradable honeycomb material of the block 44a comprises tubular cells (not shown) which are oriented radially in the radial direction R. This configuration makes it possible to provide maximum resistance to the block of material 44a.
- the honeycomb material of block 44a is obtained by an additive manufacturing process. This configuration allows the formation of regular cells and a regular conformation of toothed profiles 54a1, 54a2 without risk of deterioration as could risk causing a material removal process.
- the invention therefore advantageously makes it possible to ensure the sealing between fixed rotor crown angular sectors 32a in a simple and effective manner, and to limit the flow rate of the recirculation flow rc between these angular sectors 32a, which makes it possible to significantly improve the performance of a compressor or a turbine equipped with such angular sectors of blade crown 32a.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1854334A FR3081499B1 (fr) | 2018-05-23 | 2018-05-23 | Secteur angulaire d'aubage de turbomachine a etancheite perfectionnee |
| PCT/FR2019/051159 WO2019224476A1 (fr) | 2018-05-23 | 2019-05-22 | Secteur angulaire d'aubage de turbomachine a etancheite perfectionnee |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3797213A1 true EP3797213A1 (fr) | 2021-03-31 |
| EP3797213B1 EP3797213B1 (fr) | 2024-07-10 |
Family
ID=62816811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19740611.9A Active EP3797213B1 (fr) | 2018-05-23 | 2019-05-22 | Assemblage de deux secteurs angulaires adjacents de couronne d'aubages fixes de turbomachine et couronne d'aubages fixes correspondante |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11686205B2 (fr) |
| EP (1) | EP3797213B1 (fr) |
| CN (1) | CN112292510B (fr) |
| CA (1) | CA3100958A1 (fr) |
| FR (1) | FR3081499B1 (fr) |
| WO (1) | WO2019224476A1 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3119649B1 (fr) * | 2021-02-05 | 2023-04-21 | Safran Aircraft Engines | Anneau interne de support d'aubes d'un redresseur de compresseur d'une turbomachine. |
| GB2606552B (en) * | 2021-05-13 | 2023-11-22 | Itp Next Generation Turbines S L | Sealing system for gas turbine engine |
| FR3127517B1 (fr) * | 2021-09-27 | 2026-02-20 | Safran | Surface de cavité de veine secondaire entre une roue fixe et une roue mobile d’une turbomachine améliorée |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2452590A1 (fr) | 1979-03-27 | 1980-10-24 | Snecma | Garniture d'etancheite amovible pour segment de distributeur de turbomachine |
| FR2552159B1 (fr) * | 1983-09-21 | 1987-07-10 | Snecma | Dispositif de liaison et d'etancheite de secteurs d'aubes de stator de turbine |
| JP4494658B2 (ja) * | 2001-02-06 | 2010-06-30 | 三菱重工業株式会社 | ガスタービンの静翼シュラウド |
| JP2008180149A (ja) * | 2007-01-24 | 2008-08-07 | Mitsubishi Heavy Ind Ltd | ガスタービンの翼構造及びガスタービン |
| US8910947B2 (en) * | 2010-03-30 | 2014-12-16 | United Technologies Corporation | Method of forming a seal element |
| US9394800B2 (en) * | 2013-01-21 | 2016-07-19 | General Electric Company | Turbomachine having swirl-inhibiting seal |
| DE102015204893B3 (de) * | 2015-03-18 | 2016-06-09 | MTU Aero Engines AG | Schutzeinrichtung für eine Strömungsmaschine |
| EP3375980B1 (fr) * | 2017-03-13 | 2019-12-11 | MTU Aero Engines GmbH | Porte-joint pour une turbomachine |
| US10774670B2 (en) * | 2017-06-07 | 2020-09-15 | General Electric Company | Filled abradable seal component and associated methods thereof |
-
2018
- 2018-05-23 FR FR1854334A patent/FR3081499B1/fr active Active
-
2019
- 2019-05-22 WO PCT/FR2019/051159 patent/WO2019224476A1/fr not_active Ceased
- 2019-05-22 US US17/056,738 patent/US11686205B2/en active Active
- 2019-05-22 EP EP19740611.9A patent/EP3797213B1/fr active Active
- 2019-05-22 CN CN201980039143.4A patent/CN112292510B/zh active Active
- 2019-05-22 CA CA3100958A patent/CA3100958A1/fr active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR3081499B1 (fr) | 2021-05-28 |
| EP3797213B1 (fr) | 2024-07-10 |
| CA3100958A1 (fr) | 2019-11-28 |
| US20210207488A1 (en) | 2021-07-08 |
| FR3081499A1 (fr) | 2019-11-29 |
| CN112292510A (zh) | 2021-01-29 |
| WO2019224476A1 (fr) | 2019-11-28 |
| CN112292510B (zh) | 2024-11-05 |
| US11686205B2 (en) | 2023-06-27 |
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Legal Events
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
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