EP3732260A1 - Double-sided reversible adhesive structure - Google Patents
Double-sided reversible adhesive structureInfo
- Publication number
- EP3732260A1 EP3732260A1 EP18830192.3A EP18830192A EP3732260A1 EP 3732260 A1 EP3732260 A1 EP 3732260A1 EP 18830192 A EP18830192 A EP 18830192A EP 3732260 A1 EP3732260 A1 EP 3732260A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- structures
- adhesion
- adhesive
- projections
- object according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10688—Adjustment of the adherence to the glass layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/08—Interconnection of layers by mechanical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
- B32B7/14—Interconnection of layers using interposed adhesives or interposed materials with bonding properties applied in spaced arrangements, e.g. in stripes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
- C09J2301/1242—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape the opposite adhesive layers being different
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/31—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive effect being based on a Gecko structure
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
Definitions
- the invention relates to an object having at least two Oberflä surfaces, each having at least one surface capable of dry adhesion, and methods for switchable Adnosi on with such objects.
- the molecular adhesion between two objects can be enhanced or controlled by fiber-like surface structures.
- This principle is known as gecko effect. If a structured elastomer surface is pressed with a certain pressure force against a comparatively flat surface, van der Waals interactions can form.
- the reverible liability ie the possibility of switching attachment and detachment, is also known from nature.
- the gecko realizes the detachment by "peeling" its adhesive fibers, this is often not possible for technical structures and usually only makes sense if shear adhesion, ie adhesion, should be used in the direction of the substrate / Obj ektoberflache. In the case of so-called normal adhesion, ie an adhesion force perpendicular to the object surface, the detachment must be initiated differently.
- the strength of the adhesion and also the type of detachment can be controlled by the structure of the dry-adhesive structure on the upper surface. This allows in contrast to normal adhesive joints targeted control of adhesion forces.
- E is the modulus of elasticity
- I is the area inertia model
- L is the length (height) of the projection
- n is a factor in front of the mechanical clamping of the Projection.
- the object of the invention is to provide a structure which allows the selective handling of objects, in particular the targeted detachment.
- the object is achieved by an object which, at least on two surfaces each one capable of dry adhesion Has surface, wherein the two surfaces differ in at least one adhesive parameter.
- At least one of the surfaces has a structure encompassing vertical projections.
- both surfaces have structures comprising vertical projections.
- the dry adhesion surfaces are preferably arranged on different sides of the object.
- Preferred is a Anord voltage, so that according to the use of each of the surfaces can be contacted individually.
- at least two of the surfaces are arranged on different side surfaces of the object.
- the two surfaces can be parallel ge opposite or have an angle. In the case of a win angle, it is preferably an acute angle of less than 60 °, in particular less than 30 °.
- the surfaces may also be concave or convex ge arched. This can be varied according to the application who the.
- Adhesion parameters are understood to mean not only the adhesion force brought about by the structure, but also the force required to detach the structure.
- structures may be removable under different conditions, for example by Euler buckling. Due to the buckling of the structure at high contact pressure, the Euler buckling reduces the adhesion force and dissolves the structure with less tensile force from the surface. Such a structure has therefore depending on the contact pressure two different adhesive forces.
- the adhesive force is usually high, i. the surface adheres firmly to the structure. If the contact pressure exceeds the value for the Euler buckling, the adhesion of the structure is reduced significantly and it can be replaced with much lower tensile force.
- the adhesive force of the two surfaces is preferably controlled so that the adhesive force at normal adhesion of a surface is higher than that of the other surfaces. This will result in contacting the two surfaces of the object with two surfaces preferred the surface with the lower adhesion again peeled off.
- the existing at replacement adhesive force can be reduced, for example, by triggering the Euler buckling or shear stress.
- the structure of at least one surface is chosen so that it can be triggered by a higher contact pressure, by Euler buckling.
- the remaining after the Euler buckling adhesive force is lower than the adhesive force of the other structure. This can be preferentially replaced by triggering the Euler buckling this surface.
- the structure with the higher adhesive force the structure which has the lower contact pressure for triggering the Euler buckling.
- the adhesive force of this surface is preferably lower than the other surface. As a result, this area is preferably replaced before.
- the replacement via Euler buckling is preferred.
- the adhesive force can also be influenced by the surface of the two surfaces available for adhesion, preferably by the projections present on the surface.
- a structure according to the invention comprises at least 10 protrusions, particularly preferably at least 20, in particular at least 50 protrusions.
- pillars projections
- pillars projections
- end face pointing away from the surface. With this face, the projections come into contact with the surface to which they are to adhere.
- the projections of each structure of the invention are columnar removablebil det. This means that it is preferably formed perpendicular to the surface projections having a stem and an end face, wherein the stem and the end face may have any cross-section (for example, circular, oval, rectangular, square, rhombic, hexagonal , pentagonal, etc.).
- the projections are formed so that the perpendicular right projection of the end face on the base of the jump ahead with the base surface forms an overlap surface, where at the overlap surface and the projection of the overlap surface on the end face a body span, which lies completely within the projection ,
- the overlap area comprises at least 50% of the base area, preferably at least 70% of the base area, particularly preferably the overlapping area comprises the entire base area.
- the projections are therefore preferably not inclined be.
- the end face is paral lel aligned with the base surface and the surface. If the faces are not aligned parallel to the surface and therefore have different vertical heights, the vertical height of the face is considered to be the vertical height of the face.
- the end face of the projections is larger than the base surface.
- the stem of the projection has an aspect ratio of height to diameter of 0.2 to 100, preferably from 0.5 to 20, particularly preferably between 2 and 5, based on its mean diameter.
- the aspect ratio for at least one of the structures is preferably selected as a function of the structure and of the material such that the detachment by the Euler buckling is possible for a specific contact pressure.
- the average diameter is understood to be the diameter of the circle which has the same area as the corresponding cross section of the projection, averaged over the entire height of the projection.
- the projections may have widened end faces, so-called “mushroom” structures.
- the projections kei ne broadened faces.
- the end faces of the projections may themselves be structured to increase their surface area.
- the average vertical height of the end face is considered as the vertical height of the projections.
- the vertical height of all projections in a range of 1 ym to 10 mm, preferably 1 ym to 5 mm, in particular 1 ym to 2 mm, preferably in a range of 10 ym to 2 mm.
- the base area of the surface corresponds to a circle with a diameter between 0.1 ym to 5 mm, preferably 0.1 ym and 2 mm, in particular before given to 1 ym and 500 ym, more preferably between 1 ym and 100 ym.
- the base is a circle having a diameter between 0.3 ym and 2 mm, preferably 1 ym and 100 ym.
- the average diameter of the strains is preferably between 0.1 .mu.m to 5 mm, preferably 0.1 .mu.m and 2 mm, in particular preferably between 1 .mu.m and 100 .mu.m.
- the height and the median diameter are adjusted according to the preferred aspect ratio.
- the surface of the end face of a projection at least 1.01 times, preferably at least 1.5 times as large as the area of the base of a projection. It may be greater by a factor of 1.01 to 20 or, for example, be 1.05 to 2 times larger in example.
- the end face is between 5% and 100% larger than the base area, particularly preferably between 10% and 50% of the base area.
- the broadening of the end face of a projection means that such a projection is verbrei tert in the region of the end face.
- This broadening which is also associated with a Verbreite tion of the diameter in the affected area, preferably affects only the portion immediately in front of the front surface and the face itself. It could be so ben ben, as if on a projection with a certain diam ser At the end a flat body with a small thickness WUR de laid, such as a disc on a cylinder.
- the widening can also have a conical shell shape aufwei sen, so that the broadening increases towards the end face.
- the broadening relates to a maximum of 20% of the vertical height, preferably a maximum of 10% of the vertical height, in particular a maximum of 2% of the vertical height, in relation to the total vertical height of a projection.
- a maximum of 20% of the vertical height preferably a maximum of 10% of the vertical height, in particular a maximum of 2% of the vertical height, in relation to the total vertical height of a projection.
- the distance between two projections is less than 2 mm, in particular less than 1 mm.
- the projections are preferably arranged periodically periodically.
- the elastic modulus of the protrusions is preferably 50 kPa to 3 GPa.
- the modulus of elasticity is preferably 50 kPa to 5 GPa, in particular 100 kPa to 1 GPa, particularly preferably 500 kPa to 100 MPa. Whether a particularly high or low modulus of elasticity is advantageous may also depend on whether the corresponding structure is to be suitable for Euler buckling.
- the structures preferably differ on the opposite surfaces at least in the contact pressure necessary to trigger the Euler buckling.
- the structures on the opposing surfaces differ in at least one of the following properties selected from structure, in particular number of Vorsprün ge, diameter and / or height, and modulus of elasticity. This also leads to the change of the pressure required for Euler buckling pressure. The difference can be adjusted according to the application.
- the ratio of the moduli of elasticity is greater than 2, preferably greater than 5, so that the forces necessary for buckling forces sufficiently differ.
- the triggering of the Euler buckling required contact pressure differs by at least a factor of 2, before given by at least a factor of 5.
- the materials of the projections can be chosen freely according to the requirements by the skilled person.
- the protrusions may comprise, for example, the following materials: epoxy- and / or silicone-based elastomers, thermoplastic elastomers (TPE), polyurethanes, epoxy resins, acrylate systems, methacrylate systems, polyacrylates as homo- and copolymers, polymethacrylates as homo- and copolymers (PMMA, AMMA acrylic nitrile / methyl methacrylate), polyurethane (meth) acrylates, silicones, silicone resins, rubber such as R rubber (NR natural rubber, IR poly-isoprene rubber, BR butadiene rubber, SBR styrene-butadiene rubber, CR chloroprene rubber, NBR nitrile - Rubber) M rubber (EPM ethen
- elastomers approved for use in the packaging, pharmaceutical and food industries by the EU in accordance with EU-VO No. 10/2011 of 14.01.2011, published on 15.01.2011
- FDA or silicone-free UV-curable resins the PVD and CVD process engineering This is Po
- polyurethane (meth) acrylates for polyurethane methacrylates, polyurethane acrylates, and mixtures and / or copolymers thereof.
- thermoplastic elastomers which can be based on different polymers, for example thermoplastic copolyamides (TPA), thermoplastic polyesters terelastomers / thermoplastic copolyesters (TPEs), thermoplastic elastomers based on olefins (TPO), predominantly PP / EPDM (PP: polypropylene) , Styrene block copolymers (TPS) such as SBS, SEBS, SEPS, SEEPS and MBS) or thermoplastic elastomers Urethane base (TPU), z. Elastollan, Desmopan, Texin or Utechllan, and thermoplastic vulcanizates (TPV).
- TPA thermoplastic copolyamides
- TPEs thermoplastic polyesters terelastomers / thermoplastic copolyesters
- TPO thermoplastic elastomers based on olefins
- TPS Styrene block copolymers
- SBS SBS
- SEPS SEPS
- epoxy- and / or silicone-based elastomers Preference is given to epoxy- and / or silicone-based elastomers, polyurethane (meth) acrylates, polyurethanes, silicones, silicone resins (such as UV-curable PDMS), thermoplastic urethanes (TPU), polyurethane (meth) acrylates or rubber (such as EPM, EPDM).
- polyurethane (meth) acrylates such as UV-curable PDMS
- silicone resins such as UV-curable PDMS
- TPU thermoplastic urethanes
- PMMA polyurethane (meth) acrylates or rubber (such as EPM, EPDM).
- the structures also have a backing layer on which the projections are arranged. This is preferably made of the same material as the projections.
- the object itself can be made of any materials. On its surface at least the two structures are arranged.
- the two opposing structures are preferably net angeord on two mutually parallel side surfaces of the object.
- the two structures each cover over 50%, preferably over 70% of the respective side surface of the object.
- the distance of the two side surfaces is smaller than the smallest diameter of the two surfaces covered by the structures, in particular the ratio of smallest diameter and distance is at least
- the object is an adhesive pad which has one of the aforementioned structures on both sides.
- both structures are arranged in each case on the front and back of a flat body, preferably with egg ner thickness of at least 0.1 mm, preferably at least 0.2 mm, in particular at least 0.5 mm.
- the maximum thickness may be up to 2 cm, preferably up to 1 cm, in particular up to 6 mm.
- the body decouples the two structures arranged on it, so that an Euler buckling of one structure does not affect the other structure.
- This can be achieved, for example, by the thickness of the body and / or by its modulus of elasticity.
- both structures can be arranged on both sides of a plate made of a material having a modulus of elasticity higher by a factor> 100, for example a plate made of plastic or metal.
- the invention also relates to a method for selective adhesion for an object according to the invention.
- the first surface is contacted with a first surface and the second surface with a second surface. It does not have to contact the entire area who the. It is contacted as large an area as is needed for Adotrosi on. Therefore, only parts of the surfaces can be contacted.
- the contacting may include pressing to improve adhesion. However, without triggering the Euler buckling.
- the two contacted surfaces do not have to be the same size. It is also possible to contact several surfaces simultaneously on one surface, for example if several objects are to adhere to the surface simultaneously by adhesion.
- the contacting takes place in a direction perpendicular to the surface and surface.
- the main component of the adhesive force between a surface and surface is perpendicular to the surface and surface (Nor malhaftung).
- At least one of the contacted surfaces is moved away from the object until one of the two surfaces is detached from the object.
- the path is moved perpendicular to the contacted surfaces.
- the movement can also be caused by the movement Be only one of the surfaces.
- the Euler buckling is additionally brought about by a contact pressure for this structure which is sufficient for one of the structures.
- the adhesive force of this fa ce is greatly reduced, which leads to the preferred detachment of contacted on this surface surface.
- the inven tion proper object could be configured, for example, as a Haftpad.
- a stamp or gripper contacts the first surface and the object according to the invention thus adheres to the stamp or gripper, which can now contact the other surface of the object objects. If the adhesive force to the article is greater than the adhesive force to the punch or gripper, objects can be easily picked up and stored. To detach the object according to the invention from the punch or gripper, a higher contact pressure can then be exerted, so that the Euler kinking occurs on the contact surface with the punch or gripper.
- the Euler buckling can be used to hold objects.
- the inven tion proper object could adhere to one or more objects, which are received by different punches or grippers.
- the dry adhesive bond to the articles is then stronger than the bond to the stamp or gripper. Only with increased contact pressure and thus brought about Euler buckling the objects are detached from the object of the invention.
- area information always includes all - not mentioned - intermediate values and all imaginable subintervals.
- Fig. 1 Schematic representation of an object with opposing structures, which differ in the height (length) of the projections (Example 1), the diameter (Example 2) or the modulus of elasticity (Example 3) the.
- FIG. 3 Schematic representation for the preparation of the double-sided reversible adhesive structures
- Fig. 5 controlled detachment of the object according to the invention
- Fig. 6 adhesive force as a function of a structure according to Example 1 of Figure 1;
- FIG. 7 adhesive force as a function of a structure according to example 2 of FIG. 1.
- Fig. 1 shows in the upper part of various examples of ob jects with two opposing structures, which have klalenar term projections, which in turn have slightly widened faces (mushrooms).
- the structures differ in the height of their projections (Li other than L 2 ).
- the diameter of the projections is different (Di is not D 2 ).
- the modulus of elasticity of the structures is different (Ei not equal to E 2 ).
- FIG. 2 shows the behavior of the object depicted in FIG. 1 (below) with different loads.
- both structures of the object are contacted with a surface.
- contact pressure an external pressure on the object perpendicular to the contact surfaces
- both structures are pressed together (path is negative).
- an adhesive force can be measured ("pull" in Figure 2) until the object comes off. This behavior is shown in Figure 2 by the solid line.
- FIG. 3 shows a possibility for producing double-sided adhesive structures.
- An uncrosslinked, liquid polymer pre-polymer
- the casting mold contains inserts that serve as a template (negative mold) for the adhesive structures.
- the double-sided adhesive structure is removed from the mold.
- FIG. 4 shows the measuring arrangement for determining the adhesion forces as a function of the penetration depth.
- the adhesion is measured on both sides against glass substrates.
- a glass substrate (un ten) is mounted on a tilting table for aligning the adhesive to the substrate surfaces.
- the upper substrate is brought into contact and pressed with a defined penetration depth.
- the contact force (compressive force) is recorded.
- the substrates are pulled apart and the adhesive force (tensile force) is determined.
- FIG. 5 shows how this principle can be exploited with the object on FIG.
- a structure according to Example 1 of Figure 1 is used, ie the projections on the two sides differ in their height.
- the contact pressure also referred to as penetration depth
- the detachment takes place (at the same contacted Oberflä surfaces).
- the contact pressure which does not lead to an Euler buckling ( Figure 5 left column)
- the structure is removed in the Auseinan, which has a lower adhesive force.
- the lower figure shows that the upper structure of the object has dissolved. This is also the side having the shorter protrusions.
- a contact pressure is selected which leads to Euler kinking in one of the structures, the adhesion to the structure is markedly reduced, which leads to the preferred detachment of this structure
- FIG. 6 shows measured values obtained for an object according to example 1 of FIG.
- the adhesive force was measured as a function of the penetration depth.
- the double-sided structure is adhesive, with larger penetration depths low-adhesion.
- the detachment from the substrate changes from page 1 (filled dots) to page 2 (unfilled dots) with increasing depth of penetration. Points correspond to experimental data.
- the dashed line corresponds to the fitted sigmoid function for determining the asymptotic force values for the adhesive and low-adhesion area.
- FIG. 7 shows measured values obtained for an object according to example 2 of FIG.
- the adhesive force was measured as a function of the penetration depth.
- the double-sided structure is adhesive, with larger penetration depths low-adhesion.
- the detachment from the substrate changes from page 1 (filled dots) to page 2 (unfilled dots) with increasing depth of penetration. Points correspond to experimental data.
- the dashed line corresponds to the fitted sigmoid function for determining the asymptotic force values for the adhesive and low-adhesion area.
- S can vary between 0 and 1, where 0 means no switching behavior and 1 the maximum switching efficiency.
- Table 1 show that all double-sided adhesion structures have an efficiency greater than 0.5, where in some embodiments with S ⁇ 0.8 a very high
- Example 1 34.8 kPa 6, 0 kPa 0.83
- Example 1 22.7 kPa 10.6 kPa 0.53
- Example 1 28.1 kPa 13.6 kPa 0.52
- Example 2 31.8 kPa 13.5 kPa 0.58
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102017131345.1A DE102017131345A1 (en) | 2017-12-27 | 2017-12-27 | Double-sided reversible adhesive structure |
PCT/EP2018/084960 WO2019129508A1 (en) | 2017-12-27 | 2018-12-14 | Double-sided reversible adhesive structure |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3732260A1 true EP3732260A1 (en) | 2020-11-04 |
Family
ID=64959300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18830192.3A Pending EP3732260A1 (en) | 2017-12-27 | 2018-12-14 | Double-sided reversible adhesive structure |
Country Status (7)
Country | Link |
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US (1) | US11655396B2 (en) |
EP (1) | EP3732260A1 (en) |
JP (1) | JP7372918B2 (en) |
KR (1) | KR20200103725A (en) |
CN (1) | CN111511862B (en) |
DE (1) | DE102017131345A1 (en) |
WO (1) | WO2019129508A1 (en) |
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DE102014119470A1 (en) | 2014-12-22 | 2016-06-23 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Structured surface with gradual switchable adhesion |
DE102016113956A1 (en) | 2016-07-28 | 2018-02-01 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Device with a structured coating |
DE102017131347A1 (en) | 2017-12-27 | 2019-06-27 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Structure with improved adhesion |
DE102017131344A1 (en) | 2017-12-27 | 2019-06-27 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Shaped body with structured surface for reversible adhesion |
EP3948981A1 (en) | 2019-03-27 | 2022-02-09 | Grob-Werke GmbH & Co. KG | Apparatus and method for providing electrode strings and for producing electrode arrangements |
DE102020108107B3 (en) * | 2020-03-24 | 2020-10-15 | Simonswerk Gmbh | Attachment of cover plates |
DE102022212745A1 (en) | 2022-11-29 | 2024-05-29 | Robert Bosch Gesellschaft mit beschränkter Haftung | Elastomer membrane for a microfluidic cartridge, as well as embossing tool and method for its manufacture |
Family Cites Families (24)
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US6541098B2 (en) * | 2000-12-22 | 2003-04-01 | Avery Dennison Corporation | Three-dimensional flexible adhesive film structures |
US7811272B2 (en) | 2003-12-29 | 2010-10-12 | Kimberly-Clark Worldwide, Inc. | Nanofabricated gecko-like fasteners with adhesive hairs for disposable absorbent articles |
US7785422B2 (en) * | 2004-01-05 | 2010-08-31 | Lewis & Clark College | Self-cleaning adhesive structure and methods |
WO2006014239A2 (en) * | 2004-07-02 | 2006-02-09 | 3M Innovative Properties Company | Dry erase article |
US20080280085A1 (en) * | 2006-06-25 | 2008-11-13 | Oren Livne | Dynamically Tunable Fibrillar Structures |
DE102006050365A1 (en) * | 2006-10-25 | 2008-04-30 | MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. | Solid body structured surface for use in e.g. transportation engineering, has characteristics of projections and/or carrier layer specifically changeable such that adhesive power of contact surface is adjustable |
WO2008076390A2 (en) | 2006-12-14 | 2008-06-26 | Carnegie Mellon University | Dry adhesives and methods for making dry adhesives |
JP2008201883A (en) | 2007-02-20 | 2008-09-04 | Nitto Denko Corp | Adhesive member having ridge-like fine structure |
US8012292B2 (en) * | 2007-05-23 | 2011-09-06 | GM Global Technology Operations LLC | Multilayer adhesive for thermal reversible joining of substrates |
US8398909B1 (en) | 2008-09-18 | 2013-03-19 | Carnegie Mellon University | Dry adhesives and methods of making dry adhesives |
US20120143228A1 (en) | 2010-08-30 | 2012-06-07 | Agency For Science Technology And Research | Adhesive structure with stiff protrusions on adhesive surface |
US20120052234A1 (en) | 2010-08-30 | 2012-03-01 | Sriram Natarajan | Adhesive structure with stiff protrusions on adhesive surface |
WO2013093652A1 (en) | 2011-12-19 | 2013-06-27 | Indian Institute Of Technology Kanpur | Composite reuseable adhesive |
DE102012011422A1 (en) * | 2012-06-08 | 2013-12-12 | Gottlieb Binder Gmbh & Co. Kg | Medical device for the care of an individual |
US20140069578A1 (en) * | 2012-09-13 | 2014-03-13 | GM Global Technology Operations LLC | Shape memory polymer which functions as a reversible dry adhesive and methods of making and using the same |
CN103937419A (en) * | 2013-01-22 | 2014-07-23 | 香港纺织及成衣研发中心有限公司 | Sticky elastic adhesive tape with micro-nano pattern surface structure |
KR20140122465A (en) * | 2013-04-10 | 2014-10-20 | 전영권 | Adhesive pad for attaching and detaching wig and method of manufacturing the same |
DE102014119470A1 (en) | 2014-12-22 | 2016-06-23 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Structured surface with gradual switchable adhesion |
DE102015103965A1 (en) | 2015-03-17 | 2016-09-22 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Composite Pillarstrukturen |
JP2016204659A (en) | 2015-04-23 | 2016-12-08 | キヤノン株式会社 | Adhesive member |
DE102016113956A1 (en) | 2016-07-28 | 2018-02-01 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Device with a structured coating |
DE102017131344A1 (en) | 2017-12-27 | 2019-06-27 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Shaped body with structured surface for reversible adhesion |
DE102017131347A1 (en) | 2017-12-27 | 2019-06-27 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Structure with improved adhesion |
DE102019130988A1 (en) | 2019-11-15 | 2021-05-20 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Adhesive system for rough surfaces |
-
2017
- 2017-12-27 DE DE102017131345.1A patent/DE102017131345A1/en not_active Withdrawn
-
2018
- 2018-12-14 CN CN201880083526.7A patent/CN111511862B/en active Active
- 2018-12-14 WO PCT/EP2018/084960 patent/WO2019129508A1/en unknown
- 2018-12-14 JP JP2020533019A patent/JP7372918B2/en active Active
- 2018-12-14 US US16/772,221 patent/US11655396B2/en active Active
- 2018-12-14 EP EP18830192.3A patent/EP3732260A1/en active Pending
- 2018-12-14 KR KR1020207020314A patent/KR20200103725A/en not_active Application Discontinuation
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WO2019129508A1 (en) | 2019-07-04 |
US20210071045A1 (en) | 2021-03-11 |
JP7372918B2 (en) | 2023-11-01 |
KR20200103725A (en) | 2020-09-02 |
US11655396B2 (en) | 2023-05-23 |
JP2021508611A (en) | 2021-03-11 |
DE102017131345A1 (en) | 2019-06-27 |
CN111511862B (en) | 2023-07-25 |
CN111511862A (en) | 2020-08-07 |
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