EP3707304A1 - Fabric printable medium - Google Patents
Fabric printable mediumInfo
- Publication number
- EP3707304A1 EP3707304A1 EP18907030.3A EP18907030A EP3707304A1 EP 3707304 A1 EP3707304 A1 EP 3707304A1 EP 18907030 A EP18907030 A EP 18907030A EP 3707304 A1 EP3707304 A1 EP 3707304A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fabric
- image
- printable medium
- base substrate
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 206
- 239000010410 layer Substances 0.000 claims abstract description 153
- 239000000758 substrate Substances 0.000 claims abstract description 100
- 229920000642 polymer Polymers 0.000 claims abstract description 90
- 230000005012 migration Effects 0.000 claims abstract description 76
- 238000013508 migration Methods 0.000 claims abstract description 76
- 239000000945 filler Substances 0.000 claims abstract description 48
- 239000011230 binding agent Substances 0.000 claims abstract description 46
- 239000012757 flame retardant agent Substances 0.000 claims abstract description 41
- 230000004888 barrier function Effects 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 35
- 230000000979 retarding effect Effects 0.000 claims abstract description 32
- 239000002245 particle Substances 0.000 claims abstract description 27
- 239000011247 coating layer Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims description 69
- 229920002635 polyurethane Polymers 0.000 claims description 65
- 239000004814 polyurethane Substances 0.000 claims description 65
- 229920001577 copolymer Polymers 0.000 claims description 62
- -1 polyurethane-acrylic Polymers 0.000 claims description 38
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 33
- 229910052698 phosphorus Inorganic materials 0.000 claims description 33
- 239000011574 phosphorus Substances 0.000 claims description 32
- 238000000576 coating method Methods 0.000 claims description 27
- 229920000728 polyester Polymers 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 238000007639 printing Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 21
- 239000008199 coating composition Substances 0.000 claims description 21
- 230000006855 networking Effects 0.000 claims description 21
- 229920000058 polyacrylate Polymers 0.000 claims description 21
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 15
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 239000003822 epoxy resin Substances 0.000 claims description 12
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 229920000570 polyether Polymers 0.000 claims description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 11
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 9
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical group C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 9
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 239000002174 Styrene-butadiene Substances 0.000 claims description 8
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 7
- 239000011115 styrene butadiene Substances 0.000 claims description 7
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 5
- 229920002292 Nylon 6 Polymers 0.000 claims description 5
- 229920006243 acrylic copolymer Polymers 0.000 claims description 5
- HNPDNOZNULJJDL-UHFFFAOYSA-N ethyl n-ethenylcarbamate Chemical compound CCOC(=O)NC=C HNPDNOZNULJJDL-UHFFFAOYSA-N 0.000 claims description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 229920003986 novolac Polymers 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 150000004684 trihydrates Chemical class 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000835 fiber Substances 0.000 description 40
- 239000000976 ink Substances 0.000 description 32
- 239000004816 latex Substances 0.000 description 28
- 229920000126 latex Polymers 0.000 description 28
- 239000000126 substance Substances 0.000 description 23
- 239000000839 emulsion Substances 0.000 description 20
- 239000007787 solid Substances 0.000 description 20
- 229920002451 polyvinyl alcohol Polymers 0.000 description 18
- 150000001412 amines Chemical class 0.000 description 17
- 238000012360 testing method Methods 0.000 description 15
- 239000000178 monomer Substances 0.000 description 14
- 239000000049 pigment Substances 0.000 description 14
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 13
- 230000006870 function Effects 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 229920001451 polypropylene glycol Polymers 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 229920002125 Sokalan® Polymers 0.000 description 12
- 125000001931 aliphatic group Chemical group 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 description 11
- 125000003118 aryl group Chemical group 0.000 description 11
- 239000012530 fluid Substances 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 10
- 239000003086 colorant Substances 0.000 description 9
- 230000009477 glass transition Effects 0.000 description 9
- 229910052736 halogen Inorganic materials 0.000 description 9
- 239000012948 isocyanate Substances 0.000 description 9
- 150000002513 isocyanates Chemical class 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 229920002994 synthetic fiber Polymers 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- 150000002367 halogens Chemical class 0.000 description 8
- 229920005862 polyol Polymers 0.000 description 8
- 150000003077 polyols Chemical class 0.000 description 8
- 239000012209 synthetic fiber Substances 0.000 description 8
- 239000004753 textile Substances 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000008107 starch Substances 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
- 239000004793 Polystyrene Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000004848 polyfunctional curative Substances 0.000 description 6
- 229920002223 polystyrene Polymers 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 108010010803 Gelatin Proteins 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000008273 gelatin Substances 0.000 description 5
- 229920000159 gelatin Polymers 0.000 description 5
- 235000019322 gelatine Nutrition 0.000 description 5
- 235000011852 gelatine desserts Nutrition 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 5
- 229920000867 polyelectrolyte Polymers 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- 108010073771 Soybean Proteins Proteins 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000001934 delay Effects 0.000 description 4
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- 239000006185 dispersion Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 238000007667 floating Methods 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 239000005056 polyisocyanate Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000009974 thixotropic effect Effects 0.000 description 4
- 239000003981 vehicle Substances 0.000 description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 108010076119 Caseins Proteins 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- 240000002989 Euphorbia neriifolia Species 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
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- 229920000877 Melamine resin Polymers 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 229940105329 carboxymethylcellulose Drugs 0.000 description 3
- 239000005018 casein Substances 0.000 description 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 3
- 235000021240 caseins Nutrition 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
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- 125000004122 cyclic group Chemical group 0.000 description 3
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- 210000002268 wool Anatomy 0.000 description 3
- DJKGDNKYTKCJKD-BPOCMEKLSA-N (1s,4r,5s,6r)-1,2,3,4,7,7-hexachlorobicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound ClC1=C(Cl)[C@]2(Cl)[C@H](C(=O)O)[C@H](C(O)=O)[C@@]1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-BPOCMEKLSA-N 0.000 description 2
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- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 2
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- NOEQXGATUUVXRW-UHFFFAOYSA-N n-butan-2-ylprop-2-enamide Chemical compound CCC(C)NC(=O)C=C NOEQXGATUUVXRW-UHFFFAOYSA-N 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- HILCQVNWWOARMT-UHFFFAOYSA-N non-1-en-3-one Chemical compound CCCCCCC(=O)C=C HILCQVNWWOARMT-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 238000005935 nucleophilic addition reaction Methods 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229940078492 ppg-17 Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical group OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 229960001196 thiotepa Drugs 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- AFFZTFNQQHNSEG-UHFFFAOYSA-N trifluoromethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(F)(F)F AFFZTFNQQHNSEG-UHFFFAOYSA-N 0.000 description 1
- ZESXUEKAXSBANL-UHFFFAOYSA-N trifluoromethyl prop-2-enoate Chemical compound FC(F)(F)OC(=O)C=C ZESXUEKAXSBANL-UHFFFAOYSA-N 0.000 description 1
- KVMPUXDNESXNOH-UHFFFAOYSA-N tris(1-chloropropan-2-yl) phosphate Chemical compound ClCC(C)OP(=O)(OC(C)CCl)OC(C)CCl KVMPUXDNESXNOH-UHFFFAOYSA-N 0.000 description 1
- ADDGAKQSFRASOV-UHFFFAOYSA-N undec-1-en-3-one Chemical compound CCCCCCCCC(=O)C=C ADDGAKQSFRASOV-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5221—Polymers of unsaturated hydrocarbons, e.g. polystyrene polyalkylene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5271—Polyesters; Polycarbonates; Alkyd resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/628—Compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/001—Special chemical aspects of printing textile materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/002—Locally enhancing dye affinity of a textile material by chemical means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5228—Polyalkenyl alcohols, e.g. PVA
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5235—Polyalkenyl halides, e.g. PVC
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
Definitions
- Inkjet printing technology has expanded its application to large format high-speed, commercial and industrial printing, in addition to home and office usage, because of its ability to produce economical, high quality, multi-colored prints.
- This technology is a non-impact printing method in which an electronic signal controls and directs droplets or a stream of ink that can be deposited on a wide variety of medium substrates.
- Inkjet printing technology has found various applications on different substrates including, for examples, cellulose paper, metal, plastic, fabric and the like. The substrate plays a key role in the overall image quality and permanence of the printed images.
- Textile printing has various applications including the creation of signs, banners, artwork, apparel, wall coverings, window coverings, upholstery, pillows, blankets, flags, tote bags, etc. It is a growing and evolving area and is becoming a trend in the visual communication market. As the area of textile printing continues to grow and evolve, the demand for new printable mediums increases.
- Figure 1 and Figure 2 are a cross-sectional view of the fabric printable medium according to some examples of the present disclosure.
- Figure 3 is a flowchart illustrating a method for producing the fabric printable medium according to one example of the present disclosure.
- Figure 4 is a flowchart illustrating a method for producing printed images according to one example of the present disclosure.
- a weight range of about 1 wt % to about 20 wt % should be interpreted to include not only the explicitly recited concentration limits of 1 wt % to 20 wt %, but also to include individual concentrations such as 2 wt %, 3 wt %, 4 wt %, and sub-ranges such as 5 wt % to 15 wt %, 10 wt % to 20 wt %, etc. All percentages are by weight (wt %) unless otherwise indicated.
- image refers to marks, signs, symbols, figures, indications, and/or appearances deposited upon a material or substrate with either visible or an invisible ink composition. Examples of an image can include characters, words, numbers, alphanumeric symbols, punctuation, text, lines, underlines, highlights, and the like.
- the present disclosure is drawn to a fabric printable medium, with an image-side and a back-side, comprising a fabric base substrate; an image-receiving coating layer, applied on the image-side of printable medium, comprising a first and a second crosslinked polymeric network; a fire retarding barrier layer, applied to the back-side of the printable medium, comprising polymeric binders and filler particles with flame retardancy properties; and, at least, a migration control finish layer comprising a film-formable polymer and a flame retardant agent, at a coat-weight ranging from about 0.5 to 10 gsm.
- the present disclosure also relates to a method for forming said fabric printable medium and to the printing method using said fabric printable medium.
- the fabric printable medium is a printable recording medium (or printable media) that provide printed images that have outstanding print durability and excellent scratch resistance while maintaining good jettability (i.e. printing performance).
- the fabric printable medium has good flame resistance properties.
- scratch resistance it is meant herein that the composition is resistant to any modes of scratching which include, scuff and abrasion.
- scuff it is meant herein damages to a print due to dragging something blunt across it (like brushing fingertips along printed image). Scuffs do not usually remove colorant but they do tend to change the gloss of the area that was scuffed.
- the fabric printable medium described herein is a coated printable media that can be printed at speeds needed for commercial and other printers such as, for example, HP Latex printers such as 360, 560, 1500, 3200 and 3600 (HP Inc., Palo Alto, CA, USA).
- HP Latex printers such as 360, 560, 1500, 3200 and 3600 (HP Inc., Palo Alto, CA, USA).
- the image printed on the fabric printable medium of the present disclosure exhibits excellent printing qualities and durability. By using coating compositions, in combination with fabric substrate, the printing process is more accurate and the printed image is more permanent. The resultant printed fabric will also be able to provide fire/flame resistance or inhibition to the fabric.
- the present disclosure refers to a fabric printable medium comprising a fabric base substrate and coating compositions applied to said fabric base substrate.
- the coating compositions also called treatment compositions, once applied on the fabric base substrate, form thin layers onto the fabric base surface.
- Figure 1 and Figure 2 schematically illustrate some examples of the fabric printable medium (100) as described herein.
- Figure 3 is a flowchart illustrating an example of a method for producing the fabric printable medium.
- Figure 4 is a flowchart illustrating an example of printing method comprising obtaining a fabric printable medium as described therein and applying an ink composition onto said fabric printable medium to form a printed image.
- the fabric printable medium (100) encompasses a fabric base substrate, or supporting base substrate or bottom supporting substrate (110), and several coating layers: at least a migration control finish layer (120), an image-receiving coating layer (130) and fire retarding barrier layer (140).
- the fabric printable medium has two surfaces: a first surface, which is coated with image-receiving layer, which might be referred to as the“image receiving side”, “image surface” or“image side” (101) (i.e. where the image will be printed) and a second surface, the opposite surface, which might be referred to as the“back surface” or“back-side” (102).
- the fabric printable medium (100) encompasses a fabric base substrate (110), a migration control finish layer (120) and an image- receiving coating layer (130) applied on the image-side (101) of the printable media (100).
- a fire retarding barrier layer (140) is applied on the back-side (102) of the printable media (100).
- the fabric printable medium (100) encompasses a fabric base substrate (110) with migration control finish layers (120) that are applied on both sides (on the image and on the back-side) of the fabric printable medium (100).
- the image-receiving coating layer (130) is applied over said migration control finish layer (120) on the image-side (101) of the printable media (100).
- the fire retarding barrier layer (140) is applied, over the migration control finish layer (120), on the back-side (102) of the printable media (100).
- FIG. 3 An example of a method (200) for forming a fabric printable medium in accordance with the principles described herein, by way of illustration and not limitation, is shown in Figure 3.
- such method encompasses providing (210) a fabric base substrate with an image-side and a back-side; applying (220) a migration control finish layer on at least one side of the fabric base substrate; applying (230) an image-receiving coating layer over the migration control finish layer on the image of the fabric base substrate; and applying (240) a fire retarding barrier layer on the back-side of the fabric base substrate in order to obtain (250) the fabric printable medium.
- An example of a printing method in accordance with the principles described herein, by way of illustration and not limitation, is shown in Figure 4.
- Figure 4 illustrates examples of the printing method (300) that encompasses: providing a fabric printable medium (310) as described herein, applying an ink composition onto said a printable medium (320) and obtaining a printed article (330).
- a fabric printable medium (100) of the present disclosure is a fabric media that comprises a fabric base substrate (110).
- the fabric base substrate (110) can also be called bottom supporting substrate or fabric supporting substrate.
- the word“supporting” also refers to a physical objective of the substrate that is to carry the coatings layer and the image that is going to be printed.
- fabric substrates useful in present disclosure include substrates that have fibers that may be natural and/or synthetic.
- fabric as used to mean a textile, a cloth, a fabric material, fabric clothing, or another fabric product.
- fabric structure is intended to mean a structure having warp and weft that is one of woven, non-woven, knitted, tufted, crocheted, knotted, and pressured, for example.
- warp refers to lengthwise or longitudinal yams on a loom
- weft refers to crosswise or transverse yams on a loom.
- fabric substrate does not include materials commonly known as any kind of paper (even though paper can include multiple types of natural and synthetic fibers or mixture of both types of fibers).
- the paper thereon is defined as the felted sheet, roll and other physical forms that are made of various plant fibers (like trees or mixture of plant fibers) with synthetic fibers by laid down on a fine screen from a water suspension.
- fabric substrates include both textiles in its filament form, in the form of fabric material, or even in the form of fabric that has been crafted into finished article (clothing, blankets, tablecloths, napkins, bedding material, curtains, carpet, shoes, etc.).
- the fabric base substrate has a woven, knitted, non-woven or tufted fabric structure.
- the fabric base substrate comprises wool, cotton, silk, linen, jute, flax, hemp, rayon, corn starch, tapioca, sugarcane, polyvinyl chloride, polyester, polyamide, polyimide, polyacrylic, polyacrylic polypropylene, polyethylene, polyurethane, polystyrene, polyaramid, polytetrafluoroethylene, polyethylene terephthalate, fiberglass, polytrimethylene, polycarbonate, polyester terephthalate, polybutylene terephthalate, or a combination thereof.
- the fabric base substrate is woven, knitted, non-woven or tufted and comprises natural or synthetic fibers selected from the group consisting of wool, cotton, silk, rayon, thermoplastic aliphatic polymers, polyesters, polyamides, polyimides, polypropylene, polyethylene, polystyrene, polytetrafluoroethylene, fiberglass, polycarbonates polytrimethylene terephthalate, polyethylene terephthalate and polybutylene terephthalate.
- the fabric base substrate is a synthetic polyester fiber.
- the fabric base substrate (110) has a basis weight that is ranging from about 50 gsm to about 400 gsm. In some other examples, the basis weight of the fabric substrate can range from about 100 gsm to about 300 gsm.
- the fabric base substrate can be a woven fabric where warp yams and weft yarns are mutually positioned at an angle of about 90°.
- This woven fabric includes, but is not limited to, fabric with a plain weave structure, fabric with twill weave structure where the twill weave produces diagonal lines on a face of the fabric, or a satin weave.
- the fabric base substrate can be a knitted fabric with a loop structure including one or both of warp-knit fabric and weft-knit fabric.
- the weft-knit fabric refers to loops of one row of fabric are formed from the same yam.
- the warp-knit fabric refers to every loop in the fabric structure that is formed from a separate yarn mainly introduced in a longitudinal fabric direction.
- the fabric base substrate can also be a non-woven product, for example a flexible fabric that includes a plurality of fibers or filaments that are one or both of bonded together and interlocked together by a chemical treatment process (e.g., a solvent treatment), a mechanical treatment process (e.g., embossing), a thermal treatment process, or a combination of two or more of these processes.
- a chemical treatment process e.g., a solvent treatment
- a mechanical treatment process e.g., embossing
- a thermal treatment process e.g., a thermal treatment process, or a combination of two or more of these processes.
- the fabric base substrate can include one or both of natural fibers and synthetic fibers. Natural fibers that may be used include, but are not limited to, wool, cotton, silk, linen, jute, flax or hemp.
- Additional fibers that may be used include, but are not limited to, rayon fibers, or those of thermoplastic aliphatic polymeric fibers derived from renewable resources, including, but not limited to, cornstarch, tapioca products, or sugarcanes. These additional fibers can be referred to as“natural” fibers.
- the fibers used in the fabric base substrate includes a combination of two or more from the above-listed natural fibers, a combination of any of the above-listed natural fibers with another natural fiber or with synthetic fiber, a mixture of two or more from the above-listed natural fibers, or a mixture of any thereof with another natural fiber or with synthetic fiber.
- the synthetic fiber that may be used in the fabric base substrate can be a polymeric fiber including, but not limited to, polyvinyl chloride (PVC) fibers, PVC-free fibers made of polyester, polyamide, polyimide, polyacrylic, polypropylene, polyethylene, polyurethane, polystyrene, polyaramid (e.g., Kevlar ® ) polytetrafluoroethylene (Teflon ® ) (both trademarks of E. I. du Pont de Nemours Company), fiberglass, polytrimethylene, polycarbonate, polyethylene terephthalate or polybutylene terephthalate.
- PVC polyvinyl chloride
- PVC-free fibers made of polyester, polyamide, polyimide, polyacrylic, polypropylene, polyethylene, polyurethane, polystyrene, polyaramid (e.g., Kevlar ® ) polytetrafluoroethylene (Teflon ® ) (both trademarks
- the fibers include a combination of two or more of the above-listed polymeric fibers, a combination of any of the above-listed polymeric fibers with another polymeric fiber or with natural fiber, a mixture of two or more of the above-listed polymeric fibers, or a mixture of any of the above-listed polymeric fibers with another polymer fiber or with natural fiber.
- the synthetic fiber includes modified fibers from above-listed polymers.
- modified fibers refers to one or both of the polymeric fiber and the fabric as a whole having underwent a chemical or physical process such as, but not limited to, one or more of a copolymerization with monomers of other polymers, a chemical grafting reaction to contact a chemical functional group with one or both the polymeric fiber and a surface of the fabric, a plasma treatment, a solvent treatment, for example acid etching, and a biological treatment, for example an enzyme treatment or antimicrobial treatment to prevent biological degradation.
- PVC-free means no polyvinyl chloride (PVC) polymer or vinyl chloride monomer units in the substrate.
- the fabric base substrate contains both natural fiber and synthetic polymeric fiber.
- the amount of synthetic polymeric fibers can represent from about 20 % to about 90 % of the total amount of fiber.
- the amount of natural fibers can represent from about 10 % to about 80 % of amount of fiber.
- the fabric base substrate may further contain additives including, but not limited to, one or more of colorant (e.g., pigments, dyes, tints), antistatic agents, brightening agents, nucleating agents, antioxidants, UV stabilizers, fillers and lubricants, for example.
- colorant e.g., pigments, dyes, tints
- antistatic agents e.g., antistatic agents, brightening agents, nucleating agents, antioxidants, UV stabilizers, fillers and lubricants
- the fabric base substrate may be pre-treated in a solution containing the substances listed above before applying the coating composition.
- the additives and pre-treatments are included to improve various properties of the fabric.
- the present disclosure relates to a fabric printable medium (100), with a back-side and an image-side, comprising a fabric base substrate (110); an image-receiving coating layer (130), applied on the image-side of printable medium; a fire retarding barrier layer (140) applied to the back-side of the printable medium and, at least, a migration control finish layer (120).
- the migration control finish layer can be applied to the image-side only, directly on the fabric base substrate.
- the image-receiving coating layer will then be deposited above the migration control finish layer.
- the migration control finish layer is applied at a coat-weight ranging from about 0.5 to 10 gsm (gram per square meter).
- the migration control finish layer can be applied to the image-side and to the back-side of the media, directly on the fabric base substrate.
- the fire retarding barrier layer will then be deposited above the migration control finish layer on the back-side of the media.
- the migration control finish layer When the migration control finish layer is applied to the image-side only, directly on the fabric base substrate, the layer is deposited on the fabric base substrate using coating technology.
- the migration control finish layer can be applied to the fabric base surface by any coating technology such as floating knife coater, knife over roll coater and knife over blanket coater, for examples.
- the migration control finish layer When coated on the fabric base substrate, the migration control finish layer will form a continuous layer on outmost surface of the fabric substrate in one example. Alternatively, the migration control finish layer will form a“semi-continuous” layer with not completely coverage on the fabric surface.
- the function of the migration control finish layer is to physically block the image receiving coating composition from penetrating along the z-direction in the fabric base substrate, when it is only applied on the image receiving side of the media.
- the migration control finish layer can be functionalized as a blocking layer that prevent the composition of the fire retarding barrier layer being pushed into the fabric during coating processing. As a result of this filling effect, the different layers will form a composite and will make the fabric printing media stiffer.
- the migration control finish layer When the migration control finish layer is applied to the image-side only, directly on the fabric base substrate, by coating method, the migration control finish layer will have a coat- weight ranging from about 2 to about 10 gsm. When the migration control finish layer is applied to the image-side only, directly on the fabric base substrate and below the image-receiving coating, it will have a coat-weigh ranging from about 2 to about 10 gsm, or it will have a coat- weight above 5 gsm (gram per square meter).
- the migration control finish layer When the migration control finish layer is applied on both the image-side and the back side of the fabric base substrate, the migration control finish layer will have a coat-weight ranging from about 0.5 to about 5 gsm. In some other examples, when the migration control finish layer is applied on both the image-side and on the back-side of the fabric base substrate, the migration control finish layer has a coat-weight ranging from about 1 to 2 gsm.
- the migration control finish layer comprises a film-formable polymer and a flame retardant agent.
- the migration control finish layer comprises a film-formable polymer, a flame retardant agent and a physical networking agent.
- the migration control finish layer comprises a film-formable polymer, a flame retardant agent and a physical networking agent when it is applied, to the image-side only, directly on the fabric base substrate and below the image-receiving coating, with a coat-weigh ranging from about 2 to about 10 gsm.
- the migration control finish layer comprises a film-formable polymer.
- the film- formable polymer refers to a polymer, or polymeric binder, that is water-soluble or water- dispersible either in a form of emulsion by means of emulsion polymerization, or by means of a dispersant to form stable polymer particles in the aqueous solvent.
- the term“film-formable” refers to fact that the polymer particles, when dried out, collapse and form a thin film.
- film-formable polymers are, polystyrene-butadiene emulsion, acrylonitrile butadiene latex, starch, gelatin, casein, soy protein polymer, carboxy-methyl cellulose, hydroxyethyl cellulose, acrylic emulsion, vinyl acetate emulsion, vinylidene chloride emulsion, polyester emulsion, polyvinyl pyrroilidene, polyvinyl alcohol, styrene butadiene emulsions, or a combination thereof.
- the film-formable polymer can include starch and the starch can be an oxidized starch, cationized starch, esterified starch, enzymatically denatured starch, and combinations thereof.
- the film-formable polymer can be a soybean protein.
- the polymeric binder can include polyvinyl alcohol.
- Exemplary PVA’s can include Kuraray Poval ® 235, Mowiol ® 6-98, Mowiol ® 40-88, and Mowiol ® 20-98 (all available from Kurary America Inc., Houston Texas).
- the film-formable polymer can be an acrylic type of polymer.
- the film-formable polymer can be selected from the group consisting of acrylonitrile-butadiene polymer, acrylic polymer and polyurethane or polyurethane-acrylic polymer.
- the film formable polymer is a commercial available acrylic polymer such as those branded as PrintRite ® DP375, PrintRite ® DP594, PrintRite ® DP595, PrintRite ® DP2003, PrintRite ® DP969l, and PrintRite ® DP96l55 from Lubrizol.
- the film formable polymer can also be a polyurethane or polyurethane-acrylic hybrid film-formable polymer such as those available under the tradename Sancure ® such as Sancure ® 20025F or Sancure ® 13094HS from Lubrizol.
- the film-formable polymer can provide interface function between the image receiving layers and the fabric base substrate.
- the film-formable polymer can also provide blocking functions to prevent the printing ink from penetrating into the z-direction of the fabric substrate so that a high ink volume can be kept on the surface of printing media to ensure a vivid image.
- the average molecular weight (Mw) of the film-formable polymer can vary.
- the average molecular weight of the polymeric binder can range from 5,000 Mw to 200,000 Mw.
- the average molecular weight can vary from 10,000 Mw to about 200,000 Mw.
- the average molecular weight can vary from 20,000 Mw to 100,000 Mw.
- the average molecular weight can vary from 100,000 Mw to 200,000 Mw.
- the film-formable polymer can have a weight average molecular weight from 5,000 Mw to 200,000 Mw and can include polystyrene-butadiene emulsion, acrylonitrile butadiene latex, starch, gelatin, casein, soy protein polymer, carboxy- methyl cellulose, hydroxyethyl cellulose, acrylic emulsion, vinyl acetate emulsion, vinylidene chloride emulsion, polyester emulsion, polyvinyl pyrrolidone, polyvinyl alcohol, styrene butadiene emulsions, or combination thereof.
- the film-formable polymer can be present in an amount ranging from about 10 wt % to about 95 wt % by total weight of the migration control finish layer.
- the film- formable polymers have a glass transition temperature (Tg) of which is in the range of about -20 °C to about 40 °C
- the migration control finish layer comprises a flame retardant agent.
- the flame retardant agent can be a water-soluble or a water-dispersible flame retardant agent or filler particles with flame retardancy properties.
- flame retardant agent it is meant herein any substance that inhibits or reduces flammability or delays their combustion of the media containing it.
- the flame retardant agent can include a mineral powder, an organo-halogenated compound, a polymeric brominated compound, a metal and phosphorus containing composition, a phosphorus containing composition, a nitrogen containing composition, a halogen, an organophosphate, or combination thereof.
- the filler particles with flame retardancy properties can be solid particles in the room temperature having flame retardancy properties.
- the“fillers” also refers to the solid powder package that include a solid powder in the room temperature which has lower or limited flame retardancy properties in one example, or has no capability of flame retardancy properties in another example.
- the“filler package” or also called“filler” comprises a solid particle compounds and a flame retardant agent either in solid or liquid state in room temperature.
- fillers are, for example, but not limited to, an organo-halogenated compound, a polymeric brominated compound, a metal oxide and phosphorus containing composition, a phosphorus and halogen containing composition, a phosphorus continuing composition, a nitrogen containing composition, a halogen, an organophosphate, or a combination thereof.
- the fillers with flame retardancy properties can include a mineral compound.
- Exemplary mineral compounds can include aluminum hydroxide, magnesium hydroxide, huntite (magnesium calcium carbonate), hydromangesite (hydrated magnesium carbonate), phosphorus, red phosphorus, boehmite (aluminum oxide hydroxide), boron compounds, or combinations thereof.
- the flame retardant in filler package can include either a liquid or a solid flame retardant such as organohalogenated compound.
- organohalogenated compounds can include organobromines, organochlorines, decabromodiphenyl ether, decabromodiphenyl ethane, and combinations thereof.
- either the filler or the flame retardant agent can include a polymeric brominated compound.
- Exemplary polymeric brominated compounds can include brominated polystyrenes, brominated carbonate oligomers, brominated epoxy oligomers, tetrabro-mophthalic anhydride, tetrabromo-bisphenol A, hexabromocyclododecane, chlorendic acid, ethers of chlorendic acid, chlorinated paraffins, and combinations thereof.
- either the filler or the flame retardant agent can include a metal and phosphorus containing composition.
- Example metal and phosphorus containing compositions can include aluminum diethylphosphinate, calcium diethylphosphinate, and combinations thereof.
- either the filler or the flame retardant agent can include a phosphorus and a halogen containing composition.
- Exemplary phosphorus and halogen containing compositions can include tris(2,3-dibromopropyl) phosphate, chlorinated organophosphates, tris(l,3-dichloro- 2-propyl) phosphate, tetrekis(2-chloroethyl) dicloro-isopentyldiphosphate, tris (1,3- dichloroisopropyl) phosphate, tris(2-chloroisopropyl) phosphate, and combinations thereof.
- either the filler or the flame retardant agent can include a phosphorus containing composition.
- exemplary phosphorus containing compositions can include phosphates, phosphonates, phoshpinates, and combinations thereof.
- the phosphorus containing composition can have different oxidations states.
- the phosphorus containing composition can be a closed ring structure such as FR-102 ® (available from Shanghai Xusen Non-Halogen Smoke Suppressing Fire Retardants Co. Ltd, China) and Aflammit ® (available from Thor, Germany).
- the phosphorus containing composition can be a water-soluble phosphorus containing compound.
- Exemplary water-soluble phosphorus containing compositions can include, a phosphonate ester with one or two, closed 4 to 6 member phosphorus containing ring structures.
- the water-soluble phosphorus containing composition can be 5-ethyl-2-methyl-l,3,2,-dioxaphosphoranian-5-yl)methyl dimethyl phosphonate P oxide.
- the water-soluble phosphorus containing composition can be bis[(-ethyl-2-methyl-l,3,2-dioxaphosphorinan-5-yl)methyl] methyl phosphonate P,P’- dioxide.
- either the filler or the flame retardant agent can include a nitrogen containing composition.
- Exemplary nitrogen containing compositions can include melamines, melamine derivatives, melamine, melamine cyanurate, melamine polyphosphate, melem (heptazine derivative), melon (heptazine derivative), and combinations.
- either the filler or the flame retardant agent can be a combination of a phosphorus containing compound, a nitrogen containing compound, and/or a halogen.
- the flame retardant can include a phosphorus and a nitrogen containing composition.
- Exemplary phosphorus and nitrogen containing compositions can include ammonium polyphosphate (APP), poly 4,4-diaminodiphenyl methane spirocyclic pentaerythritol bisphosphonate (PDSPB), l,4-di(di ethoxy thiophosphamide benzene (DTPAB), and combinations.
- APP ammonium polyphosphate
- PDSPB poly 4,4-diaminodiphenyl methane spirocyclic pentaerythritol bisphosphonate
- DTPAB l,4-di(di ethoxy thiophosphamide benzene
- either the filler or the flame retardant agent
- the organophosphate can include aliphatic phosphate; aliphatic phosphonate; aromatic phosphonate; aliphatic organophosphate; aromatic organophosphate; polymeric organophosphate with 2 or 3 oxygen atoms attached to the central phosphorus and combinations.
- the flame retardant agents are selected from the group consisting of phosphorus-containing compounds, nitrogen-containing compounds, organophosphate compounds, alumina trihydrate and calcium carbonate. In some other examples, the flame retardant agents are selected from the group consisting of phosphorus-containing compounds, nitrogen-containing compounds, organophosphate compounds, alumina trihydrate and calcium carbonate. In yet some other examples, the flame retardant agents are selected from the group consisting of phosphorus-containing compounds and nitrogen-containing compounds. The flame retardant, either in solid state or in liquid state, can also be selected from the group consisting of phosphorus-containing compounds, nitrogen-containing compounds, organophosphate compounds, alumina trihydrate and calcium carbonate.
- Examples of commercially available flame retardant agents include FR102 ® (available from Shanghai Xusen Co Ltd) or Aflammit ® PE and Aflammit ® MSG (both available from Thor), Exolit ® AP compounds (available from Clariant), solid Aflammit ® powder compounds (available from Thor), Disflamoll ® DPK (available from Lanxess), Phoslite B compounds (available from Italmatch Chemicals), or SpaceRite ® S-3 (J.M.Huber Corp).
- FR102 ® available from Shanghai Xusen Co Ltd
- Aflammit ® PE and Aflammit ® MSG both available from Thor
- Exolit ® AP compounds available from Clariant
- solid Aflammit ® powder compounds available from Thor
- Disflamoll ® DPK available from Lanxess
- Phoslite B compounds available from Italmatch Chemicals
- SpaceRite ® S-3 J.M.Huber Corp.
- the flame retardant agent is present, in the migration control finish layer (120), in an amount representing from about 5 to about 50 wt % by total weigh of the migration control finish layer. In some other examples, the flame retardant agent is present, in the migration control finish layer (120), in an amount representing from about 7 wt % to about 40 wt %, or from about 8 wt % to about 30 wt % by total weigh of the migration control finish layer.
- the migration control finish layer comprises a film-formable polymer, a flame retardant agent and a physical networking agent when it is applied, to the image-side only, directly on the fabric base substrate and below the image-receiving coating.
- the migration control finish layer When applied to the image-side only, directly on the fabric base substrate and below the image- receiving coating, the migration control finish layer will have a coat-weight ranging from about 2 to 10 gsm, or from about 3 to 10 gsm or from above 5 gsm.
- the physical networking agent can be a chemical that promotes physical bonding with the polymeric binder to form a gel-like solution.
- A“gel-like solution” can have a low solids content (from about 0.1 wt% to about 30 wt%) and a high viscosity (> 15,000 cps) at low shear stress (4 rpm) when measured by a Brookfield viscometer (Brookfield AMETEK, Massachusetts) at 25°C.
- a gel-like solution can behave like a non-flowable, semi solid gel, but is able to de-bond at higher shear forces, e.g., 100 rpms or greater, to yield a low viscosity fluid, e.g., less than 5,000 cps.
- the migration control finish layer can have a solid content from 0.1 wt% to 20 wt% and a viscosity from 5,000 cps to 30,000 cps as measured at 4 rpm. In another example, the migration control finish layer can have a solid content from 5 wt% to 30 wt% and a viscosity from 3,000 cps to 15,000 cps as measured at 4 rpm.
- the composite which constructs the migration control finish layer can have thixotropic behavior.
- thixotropic behavior refers to fluids that are non-Newtonian fluids, i.e. which can show a shear stress-dependent change in viscosity.
- non-Newtonian refers herein to fluid having a viscosity that is dependent on an applied force such as shear or thermal forces. For example, shear thinning fluids decrease in viscosity with increasing rate of shear. The stronger the thixotropic characteristic of the chemical fluid of the water barrier layer when it undergoes shear stress, the lower the viscosity of the chemical fluid.
- the viscosity can be re-built up. Without being limited to any theory, it is believed that such thixotropic behavior reduces the penetration of the composition into the fabric substrate and helps retain the composition at the top surface of the substrate.
- the fluid becomes thin under shear force when applied by a coating application head (such as a blade coating head).
- a coating application head such as a blade coating head.
- the physical networking agents are high molecular weight polymers, i.e. having a molecular weight ranging from about 300,000 to about 1,000,000.
- the physical networking agents can be copolymers of acrylates, copolymers with acrylate based polyelectrolyte backbone, copolymers with polyester backbone, or copolymers with polyurethane based copolymer backbone.
- the physical networking agent is selected from the group consisting of copolymers of acrylates, copolymers with acrylate based polyelectrolyte backbone, copolymers with polyester backbone, and copolymers with polyurethane based copolymer backbone.
- the physical networking agent is a copolymer of acrylates, such as a copolymer of methacrylic acid and ethyl acrylate ester; a copolymer having with an acrylate based polyelectrolyte backbone and a weight average molecular weight from about 300,000 Mw to about 1,000,000 Mw; a copolymer having a polyester backbone and a weight average molecular weight from about 300,000 Mw to about 1,000,000 Mw; a copolymer having a polyurethane backbone and a weight average molecular weight from about 300,000 Mw to about 1,000,000 Mw; or a combination thereof.
- acrylates such as a copolymer of methacrylic acid and ethyl acrylate ester
- the physical networking agent can include an acrylate copolymer, a polyethylene glycol copolymer, a polyurethane copolymer, an isophorone diisocyanate, or a combination thereof and the physical networking agent can have a weight average molecular weight from 300,000 Mw to 1,000,000 Mw.
- the physical networking agents which are part of the barrier layer, are high molecular weight copolymers of acrylates (i.e. having a molecular weight ranging from about 300,000 to about 1,000,000) such as copolymer of methacrylic acid and ethyl acrylate ester.
- Examples of such compounds include Acusol ® 8l0A, Acusol L ® 830, Acusol ® 835, ACUSOL ® 842 (supplied by Rohm Haas/Dow Co); or Alcogum ® Ll l, Alcogum ® L12, Alcogum ® L51, Alcogum ® L31 and Alcogum ® L52 (available from Akzo Nobel Co) and Sterocoll ® FS from BASF.
- the physical networking agents of the barrier layer are high molecular weight copolymers with acrylate based polyelectrolyte backbone.
- Such high molecular weight copolymers with acrylate based polyelectrolyte backbone can be, for examples, acrylate acid copolymers, grafted pendant with long-chain hydrophobic groups in addition to acid groups in backbone distributed throughout the polymer chain.
- examples of such polymers that are commercially available include Texicryl ® l3-3 l7, Texicryl ® l3-3 l3, Texicryl ® l3-308, and Texicryl ® 13-312 (all available from Scott Bader Group).
- the physical networking agents of the barrier layer are high molecular weight copolymers with polyester backbone.
- Such high molecular weight copolymers with polyester backbone can be, for examples, polyethylene glycol copolymers, grafted pendant with long-chain hydrophobic groups in addition to polar groups in backbone distributed throughout the polymer chain.
- examples of such polymers that are commercially available include Rheovis ® PE from BASF.
- the physical networking agents of the barrier layer are high molecular weight copolymers with polyurethane based copolymer backbone.
- Such high molecular weight copolymers with polyurethane based copolymer backbone can be, for examples, as polyethylene glycol and isophorone diisocyanate, which can be end-capped with long-chain alkanol in addition to backbone distributed throughout the polymer chain.
- Examples of such polymers that are commercially available include Acusol ® 880, Acusol ® 882 (from Rohm Haas).
- the physical networking agent is an aqueous anionic dispersion of an ethyl acrylate-carboxylic acid copolymer such as Sterocoll ® FS (available from BASF).
- the fabric printable medium (100) of the present disclosure includes an image- receiving layer (130).
- the image-receiving layer (130), or inkjet receiving layer, will form a coating layer and is applied over the migration control finish layer (120) on the image-side of the fabric printable media.
- Such layer would act as the image-receiving layer since, during the printing process, the ink will be directly deposited on its surface.
- the image-receiving coating composition is applied to the migration control finish layer at a coat-weight ranging from about 0.1 to about 40 gsm (gram per square meter) or at a coat-weight ranging or from about 1 to 20 gsm (gram per square meter) or at a coat-weight ranging or from about 2 to 10 gsm (gram per square meter).
- the image-receiving coating composition is applied to the migration control finish layer at a thickness ranging from about 1 pm to about 50 pm with a dry coat-weight ranging from about 1 gsm to about 20 gsm.
- the image-receiving layer (130) comprises a first crosslinked polymeric network and a second crosslinked polymeric network.
- the wording“polymer network” refers herein to a polymer and/or a polymer mixture which can be self-cross-linked, by reaction of different function groups in the same molecular chain, or inter-cross-linked by reaction with another compound which has different function group.
- the image-receiving layer includes a first and a second polymeric network.
- the image- receiving layer includes a first and a second polymeric network that are crosslinked polymeric network.
- the first crosslinked polymeric network and the second crosslinked polymeric network can be either different or identical by their chemical natures.
- the image-receiving layer can further comprise filler particles.
- the filler particles can be inorganic filler particles, organic particles, particles with or without flame retardancy nature, and flame-retardants.
- the first crosslinked polymeric network can be crosslinked to itself.
- the first crosslinked polymeric network can be crosslinked to itself and to the second crosslinked polymeric network.
- the second crosslinked polymeric network can be crosslinked to itself.
- the first and second crosslinked polymeric networks can be present in the image- receiving layer in a variety of amounts.
- the first and second crosslinked polymeric networks can collectively represent from about 80 wt% to about 99 wt% of the total weight of the image- receiving layer.
- the first and second crosslinked polymeric networks can collectively represent from about 85 wt% to about 95 wt% of the total weight of the image- receiving layer.
- the first and second crosslinked polymeric networks can collectively range from about 85 wt% to about 93 wt% of the total weight of the image-receiving layer.
- the first and second crosslinked polymeric networks can be present in equal amounts. In other examples, the first and second crosslinked polymeric networks can be present in different amounts.
- the first crosslinked polymeric network and the second crosslinked polymeric network are different and independently comprises polyacrylate, polyurethane, vinyl-urethane, acrylic urethane, polyurethane-acrylic, polyether polyurethane, polyester polyurethane, polycaprolactam polyurethane, polyether polyurethane, alkyl epoxy resin, epoxy novolac resin, polyglycidyl resin, polyoxirane resin, polyamine, styrene maleic anhydride, a derivative thereof, or a combination thereof.
- the first and/or the second crosslinked polymeric networks can include a polyacrylate, polyurethane, vinyl-urethane, acrylic urethane, polyurethane-acrylic, polyether polyurethane, polyester polyurethane, polycaprolactam polyurethane, polyether polyurethane, alkyl epoxy resin, epoxy novolac resin, polyglycidyl resin, polyoxirane resin, polyamine, styrene maleic anhydride, derivative thereof, or combination thereof.
- the first and second crosslinked polymeric networks can be different polymers.
- the first and/or the second crosslinked polymeric network can include a polyacrylate based polymer.
- Exemplary polyacrylate based polymers can include polymers made by hydrophobic addition monomers include, but are not limited to, C1-C12 alkyl acrylate and methacrylate (e.g., methyl acrylate, ethyl acrylate, n-propyl acrylate, isopropyl acrylate, n-butyl acrylate, isobutyl acrylate, sec-butyl acrylate, tert-butyl acrylate, 2-ethylhexyl acrylate, octyl arylate, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, sec-butyl methacrylate, tert-butyl
- polymers made from the polymerization and/or copolymerization of alkyl acrylate, alkyl methacrylate, vinyl esters, and styrene derivatives may also be useful.
- the polyacrylate based polymer can include polymers having a glass transition temperature greater than 20°C.
- the polyacrylate based polymer can include polymers having a glass transition temperature of greater than 40°C.
- the polyacrylate based polymer can include polymers having a glass transition temperature of greater than 50°C.
- the first and/or the second crosslinked polymeric network can be formed by using self-cross-linked polyurethane polymers or cross-linkable polyglycidyl or polyoxirane resins.
- the first and/or second crosslinked polymeric network can be formed by using self-cross-linked polyurethane polymers.
- the self-cross-linked polyurethane polymer can be formed by reacting an isocyanate with a polyol.
- Exemplary isocyanates used to form the polyurethane polymer can include toluenediisocyanate, 1,6- hexamethylenediisocyanate, diphenylmethanediisocyanate, 1,3- bis(isocyanatemethyl)cyclohexane, l,4-cyclohexyldiisocyanate, p-phenylenediisocyanate, 2,2,4(2,4,4)-trimethylhexamethylenediisocyanate, 4,4'-dicychlohexylmethanediisocyanate, 3,3'- dimethyldiphenyl, 4,4'-diisocyanate, m-xylenediisocyanate, tetramethylxyl
- isocyanates can include Rhodocoat ® WT 2102 (available from Rhodia AG, Germany), Basonat ® LR 8878 (available from BASF Corporation, N. America), Desmodur ® DA, and Bayhydur ® 3100 (Desmodur ® and Bayhydur ® are available from Bayer AG, Germany). In some examples, the isocyanate can be protected from water.
- Exemplary polyols can include 1,4- butanediol; 1, 3-propanediol; l,2-ethanediol; 1, 2-propanediol; l,6-hexanediol; 2-methyl-l,3- propanediol; 2, 2-dimethyl-l, 3-propanediol; neopentyl glycol; cyclo-hexane-dimethanol; 1,2,3- propanetriol; 2-ethyl-2-hydroxymethyl-l, 3-propanediol; and combinations thereof.
- the isocyanate and the polyol can have less than three functional end groups per molecule.
- the isocyanate and the polyol can have less than five functional end groups per molecule.
- the polyurethane can be formed from a polyisocyanate having at least two isocyanate functionalities and a polyol having at least two hydroxyl or amine groups.
- Exemplary poly-isocyanates can include diisocyanate monomers and oligomers.
- the self-cross-linked polyurethane polymer can also be formed by reacting an isocyanate with a polyol, where both isocyanates and polyols have average less than three end functional groups per molecule so that the polymeric network is based on a liner polymeric chain structure.
- the polyurethane chain can have a trimethyloxysiloxane group and cross-link action can take place by hydrolysis of the function group to form silsesquioxane structure.
- the polyurethane chain can also have an acrylic function group, and the cross-link structure can be formed by nucleophilic addition to acrylate group through aceto-acetoxy functionality.
- the first and/or second crosslinked polymeric network is formed by using vinyl- urethane hybrid copolymers or acrylic-urethane hybrid polymers.
- the polymeric network includes an aliphatic polyurethane-acrylic hybrid polymer.
- NeoPac ® R-9000, R-9699 and R-9030 from Zeneca Resins
- Sancure ® AU40l0 from Lubrizol
- Hybridur ® 570 from Air Products.
- the weight average molecular weight of the polyurethane polymer used in the first and/or second crosslinked polymer can range from about 20,000 Mw to about 200,000 Mw as measured by gel permeation chromatography. In another example, the weight average molecular weight of the polyurethane polymer can range from about 40,000 Mw to about 180,000 Mw as measured by gel permeation chromatography. In yet another example, the weight average molecular weight of the polyurethane polymer can range from about 60,000 Mw to about 140,000 Mw as measured by gel permeation chromatography.
- Exemplary polyurethane polymers can include polyester based polyurethanes, U910, U938 U2101 and U420; poly ether based polyurethane, U205, U410, U500 and U400N; polycarbonate based polyurethanes, U930, U933, U915 and U911; castor oil based polyurethane, CUR21, CUR69, CUR99 and CUR991; and combinations thereof. (These polyurethanes are available from Alberdingk Boley Inc., North Carolina, USA).
- the polymeric network can include a polymeric core that is, at least, one polyurethane.
- the polyurethanes include aliphatic as well as aromatic polyurethanes.
- the polyurethane is typically the reaction products of the following components: a polyisocyanate having at least two isocyanate functionalities(— NCO) per molecule with, at least, one isocyanate reactive group such as a polyol having at least two hydroxy groups or an amine.
- Suitable poly-isocyanates include diisocyanate monomers, and oligomers.
- polyurethanes examples include aromatic polyether polyurethanes, aliphatic polyether polyurethanes, aromatic polyester polyurethanes, aliphatic polyester polyurethanes, aromatic polycaprolactam polyurethanes, and aliphatic polycaprolactam polyurethanes.
- the polyurethanes are aromatic polyether polyurethanes, aliphatic polyether polyurethanes, aromatic polyester polyurethanes, and aliphatic polyester polyurethanes.
- polyurethanes include Sancure ® 27l0 and/or Avalure ® UR445 (which are equivalent copolymers of polypropylene glycol, isophorone diisocyanate, and 2,2-dimethylolpropionic acid, having the International Nomenclature Cosmetic Ingredient name“PPG-17/PPG-34/IPDI/DMPA Copolymer”), Sancure ® 878, Sancure ® 8l5, Sancure ® l30l, Sancure ® 27l5, Sancure ® 2026, Sancure ® l8l8, Sancure ® 853, Sancure ® 830, Sancure ® 825, Sancure ® 776, Sancure ® 850, Sancure ® l2l40, Sancure ® l26l9, Sancure ® 835, Sancure ® 843, Sancure ® 898, Sancure ® 899, Sancure ® l
- NeoPac ® R-9000, R-9699, and R-9030 available from Zeneca Resins, Ohio
- Printrite ® DP376 and Sancure ® AU4010 available from Lubrizol Advanced Materials, Inc., Ohio
- Hybridur ® 570 available from Air Products and Chemicals Inc., Pennsylvania).
- the polymeric network is created by using cross-linkable polyglycidyl or polyoxirane resins.
- Cross-link reaction can take place either with themselves (through catalytic homopolymerisation of oxirane function group) or with the help of a wide range of co-reactants including polyfunctional amines, acids, acid anhydrides, phenols, alcohols, and thiols.
- co-reactants including polyfunctional amines, acids, acid anhydrides, phenols, alcohols, and thiols.
- Both polyglycidyl resin and co-reactants are compatible with the chemicals that form a polymeric network before curing in liquid state.
- the term“compatible” refers here to the fact that there is no significant phase separation after mixing in the room temperature.
- the first and/or the second polymeric network comprises epoxy- functional additives.
- Epoxy-functional additives can include alkyl and aromatic epoxy resins or epoxy-functional resins, such as for example, epoxy novolac resin(s) and other epoxy resin derivatives.
- Epoxy-functional molecules can include at least one, or two or more pendant epoxy moieties. The molecules can be aliphatic or aromatic, linear, branched, cyclic or acyclic. If cyclic structures are present, they may be linked to other cyclic structures by single bonds, linking moieties, bridge structures, pyro moieties, and the like.
- Suitable epoxy functional resins are commercially available and include, without limitation, Ancarez ® AR555 (commercially available from Air Products), Ancarez ® AR550, Epi-rez ® 35l0W60, Epi- rez ® 35l5W6, or Epi-rez ® 3522W60 (commercially available from Hexion).
- the polymeric network includes epoxy resin.
- suitable aqueous dispersions of epoxy resin include Waterpoxy ® l422 (commercially available from Cognis) or Ancarez ® AR555 1422 (commercially available from Air Products).
- the polymeric network can comprise epoxy resin hardeners.
- the examples of epoxy resin hardeners that can be used herein include liquid aliphatic or cycloaliphatic amine hardeners of various molecular weights, in 100% solids or in emulsion or water and solvent solution forms. Amine adducts with alcohols and phenols or emulsifiers can also be envisioned.
- the polymeric network can include water-based polyamine as epoxy resin hardeners.
- epoxy resin hardeners can be, for examples, water-based polyfunctional amines, acids, acid anhydrides, phenols, alcohols and/or thiols.
- Other examples of commercially available polymeric networks that can be used herein includes the ingredients Araldite ® PZ 3921 and/or Aradur ® 3985 available from Huntsman.
- the image-receiving layer includes a first and/or second polymeric network that is a hybrid network created by using self-cross-linked polyurethane polymers and by using cross-linkable polyglycidyl or polyoxirane resins.
- the image receiving layer comprises a polymeric network that is created by using vinyl-urethane hybrid copolymers or acrylic-urethane hybrid polymers and water-based epoxy resins and water-based polyamines.
- the first and/or second crosslinked polymeric network can include a styrene maleic anhydride (SMA).
- SMA can include NovaCote 2000 ® (Georgia-Pacific Chemicals LLC, Georgia).
- the styrene maleic anhydride can be combined with an amine terminated polyethylene oxide (PEO); amine terminated polypropylene oxide (PPO), copolymer thereof, or a combination thereof.
- PEO polyethylene oxide
- PPO polypropylene oxide
- combining a styrene maleic anhydride with an amine terminated PEO and/or PPO can strengthen the polymeric network by crosslinking the acid carboxylate functionalities of the SMA to the amine moieties on the amine terminated PEO and/or PPO.
- the amine terminated PEO and/or PPO in one example, can include amine moieties at one or both ends of the PEO and/or PPO chain, and/or as branched side chains on the PEO and/or PPO.
- utilizing an amine terminated PEO and/or PPO in combination with a SMA can allow for the user to retain the glossy features of the SMA while eliminating the brittle nature of SMA.
- exemplary commercially available amine terminated PEO and/or PPO compounds can include Jeffamine ® XTJ-500, Jeffamine ® XTJ-502, and Jeffamine ® XTJ D-2000 (all available from Huntsman International LLC, Texas).
- a weight ratio of SMA to the amine terminated PEO and/or PPO can range from about 100: 1 to about 2.5: 1.
- a weight ratio of the SMA to the amine terminated PEO and/or PPO can range from about 90: 1 to about 10: 1.
- a weight ratio of the SMA to the amine terminated PEO and/or PPO can range from about 75 : 1 to about 25 : 1.
- the image-receiving layer might further comprise filler particles.
- filler includes inorganic compounds, organic compounds, compounds with flame retardancy nature, and flame-retardant agents.
- the amount of filler compound, in the image-receiving layer can be within the range of about 1 to about 70 wt % or within the range of about 5 to about 60 wt % or within the range of about 10 to about 50 wt % by total weight of the image-receiving layer.
- the image-receiving layer contains filler particles that have a nature of flame retardancy (or flame retardancy properties) or contains fillers and, separately, a flame-retardant agent.
- the fillers that have a nature of flame retardancy or flame retardancy properties can be considered as flame-retardant agents.
- flame-retardant agent it is meant herein any substance that inhibits or reduces flammability or delays their combustion of the media containing it.
- the filler particles can be the same, or different, as the one used in the barrier layer composition as described below.
- the fabric printable medium of the present disclosure comprises a fabric base substrate (110); a migration control finish layer (120), an image-receiving coating composition (130) and fire retarding barrier layer (140).
- the fire retarding barrier layer (140) is applied directly on the fabric base substrate, or over the migration control finish layer (120) when present on the back side of the media (102).
- fire retarding it is meant herein that the layer has the ability to inhibits or reduces flammability or delays their combustion of the media containing it.
- the fire retarding barrier layer (140) can be applied to the fabric base substrate at a dry coat-weight ranging from about 1 gsm to about 50 gsm per side. In one other example, the fire retarding barrier layer (140) is applied, to the fabric substrate, at a dry coat- weight ranging from about 10 gsm to about 20 gsm.
- the fire retarding barrier layer composition includes a polymeric binder and filler particles with flame retardancy properties.
- Other functional additives can be added to the backing coating composition, for specific property control such as, for examples, surfactant for wettability, and processing control agent such as deformer, and PH control base/acid buffer.
- the fire retarding barrier layer composition contains a polymeric binder.
- the polymeric binder can provide binding function to the fillers to form a continuous layer and adhesion function between coating layers and the fabric substrate.
- the polymeric binder can be present, in the barrier coating composition, in an amount ranging from about 10 wt % to about 70wt % by total weigh of the barrier coating composition.
- the polymeric binder can be either water a soluble, a synthetic or a natural substance or an aqueous dispersible substance like polymeric latex.
- the polymeric binder is polymeric latex.
- the polymeric binder can be a water-soluble polymer or water dispersible polymeric latex.
- the polymeric binder has a glass transition temperature (Tg) that is less than 5°C. Indeed, it is believed that polymeric binder with higher glass transition temperature (Tg) might contribute to a stiff coating and can damage the fabric “hand feeling” of the printing media.
- the polymeric binders have a glass transition temperature (Tg) ranging from - 40°C to 0 °C. In some other examples, the polymeric binders have a glass transition temperature (Tg) ranging from -20°C to -5°C. The way of measuring the glass transition temperature (Tg) parameter is described in, for example, Polymer Handbook, 3rd Edition, authored by J. Brandrup, edited by E. H. Immergut, Wiley-Interscience, 1989.
- the polymeric binders are crossed-linked binder.“Crossed-linked binder” refers to the fact that multiple polymer substances with reactive function groups can react with each other to form a between-molecular chain structure, a cross linker, a macro- molecular substance or a low molecular weight chemical with more than two function groups that can be used. Binders with“self-crosslink” capability can mean that macro-molecular chains have different reactive function groups that can be used.
- the cross-linked binders can balance both softness and mechanical strength of the coating layers.
- Suitable polymeric binders include, but are not limited to, water-soluble polymers such as polyvinyl alcohol, starch derivatives, gelatin, cellulose derivatives, acrylamide polymers, and water dispersible polymers such as acrylic polymers or copolymers, vinyl acetate latex, polyesters, vinylidene chloride latex, styrene-butadiene or acrylonitrile-butadiene copolymers.
- water-soluble polymers such as polyvinyl alcohol, starch derivatives, gelatin, cellulose derivatives, acrylamide polymers
- water dispersible polymers such as acrylic polymers or copolymers, vinyl acetate latex, polyesters, vinylidene chloride latex, styrene-butadiene or acrylonitrile-butadiene copolymers.
- Non-limitative examples of suitable binders include styrene butadiene copolymer, polyacrylates, polyvinylacetates, polyacrylic acids, polyesters, polyvinyl alcohol, polystyrene, polymethacrylates, polyacrylic esters, polymethacrylic esters, polyurethanes, copolymers thereof, and combinations thereof.
- the binder is a polymer or a copolymer selected from the group consisting of acrylic polymers or copolymers, vinyl acetate polymers or copolymers, polyester polymers or copolymers, vinylidene chloride polymers or copolymers, butadiene polymers or copolymers, styrene-butadiene polymers or copolymers and acrylonitrile-butadiene polymers or copolymers.
- the polymeric binder can include an acrylonitrile-butadiene latex.
- the binder component is a latex containing particles of a vinyl acetate-based polymer, an acrylic polymer, a styrene polymer, an SBR-based polymer, a polyester-based polymer, a vinyl chloride-based polymer, or the like.
- the binder is a polymer or a copolymer selected from the group consisting of acrylic polymers, vinyl-acrylic copolymers and acrylic-polyurethane copolymers.
- Such binders can be polyvinylalcohol or copolymer of vinylpyrrolidone.
- the copolymer of vinylpyrrolidone can include various other copolymerized monomers, such as methyl acrylates, methyl methacrylate, ethyl acrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate, ethylene, vinylacetates, vinylimidazole, vinylpyridine, vinylcaprolactams, methyl vinylether, maleic anhydride, vinylamides, vinylchloride, vinylidene chloride, dimethylaminoethyl methacrylate, acrylamide, methacrylamide, acrylonitrile, styrene, acrylic acid, sodium vinyl sulfonate, vinylpropionate, and methyl vinylketone, etc.
- binders include, but are not limited to, polyvinyl alcohols and water-soluble copolymers thereof, e.g., copolymers of polyvinyl alcohol and poly(ethylene oxide) or copolymers of polyvinyl alcohol and polyvinylamine; cationic polyvinyl alcohols; aceto-acetylated polyvinyl alcohols; polyvinyl acetates; polyvinyl pyrrolidones including copolymers of polyvinyl pyrrolidone and polyvinyl acetate; gelatin; silyl-modified polyvinyl alcohol; styrene-butadiene copolymer; acrylic polymer latexes; ethylene-vinyl acetate copolymers; polyurethane resin; polyester resin; and combination thereof.
- the binder is carboxylated styrene-butadiene copolymer binder. Such binder can be find commercially under the tradename Genflow ® and Acry
- the polymeric binder may have an average molecular weight (Mw) of about 5,000 to about 200,000. In another example, the average molecular weight of the polymeric binder can vary from 10,000 Mw to about 200,000 Mw. In yet another example, the average molecular weight of the polymeric binder can vary from 20,000 Mw to 100,000 Mw. In a further example, the average molecular weight of the polymeric binder can vary from 100,000 Mw to 200,000 Mw.
- Mw average molecular weight
- the polymeric binder can have a weight average molecular weight from 5,000 Mw to 200,000 Mw and can include polystyrene-butadiene emulsion, acrylonitrile butadiene latex, starch, gelatin, casein, soy protein polymer, carboxy-methyl cellulose, hydroxyethyl cellulose, acrylic emulsion, vinyl acetate emulsion, vinylidene chloride emulsion, polyester emulsion, polyvinyl pyrroilidene, polyvinyl alcohol, styrene butadiene emulsions, or combination thereof.
- the polymeric binder is a self-crosslinking aqueous acrylic dispersion such an Edolan ® AB available from Tanatex Chemicals (having a solids content of 45 % and Tg of -18 °C).
- the fire retarding barrier layer (140) contains a polymeric binder and filler particles with flame retardance function.
- the fire retarding barrier layer composition contains filler particles that have a nature of flame retardancy (or flame retardancy properties) or contains fillers and, separately, a flame-retardant agent.
- the fillers that have a nature of flame retardancy or flame retardancy properties can be considered as flame-retardant agents.
- flame- retardant agent it is meant herein any substance that inhibits or reduces flammability or delays their combustion of the media containing it.
- the filler or filler package or filler particles with flame retardancy properties or flame-retardant agent is present, in the fire retarding barrier layer, in an amount representing from about 10 to about 90 wt % by total weigh of the fire retarding barrier layer composition.
- the“fillers” can be solid particles in the room temperature having flame retardancy properties.
- the“fillers” also refers to the solid powder package that include a solid powder in the room temperature which has lower or limited flame retardancy properties in one example, or has no capability of flame retardancy properties in another example.
- the“filler package” or also called“filler” comprises a solid particle compounds and a flame-retardant agent either in solid or liquid state in room temperature.
- fillers are, for example, but not limited to, an organo-halogenated compound, a polymeric brominated compound, a metal oxide and phosphorus containing composition, a phosphorus and halogen containing composition, a phosphorus continuing composition, a nitrogen containing composition, a halogen, an organophosphate, or a combination thereof.
- the fillers present in the fire retarding barrier layer (140) can be similar or different to the fillers with flame retardancy properties, or flame-retardant agents, that are present in the migration control finish layer (120) and that are described above.
- the fabric printable medium is prepared by using several surface treatment compositions herein named a coating layer or coating composition.
- the method (200) for forming the fabric printable medium encompasses: providing (210) a fabric base substrate with an image-side and a back-side (i.e.
- a migration control finish layer comprising a film-formable polymer and a flame retardant agent, on at least one side of the fabric base substrate at a coat- weight ranging from about 0.5 to 10 gsm; applying (230) an image-receiving coating layer comprising a first and a second crosslinked polymeric network, over the migration control finish layer on the image of the fabric base substrate; and applying (240) a fire retarding barrier layer, comprising polymeric binders and filler particles with flame retardancy properties, on the back side of the fabric base substrate and then obtaining (250) the fabric printable medium.
- the migration control finish layer (120) further comprises a physical networking agent when it is applied only on the image-side (101) of the fabric base substrate (101), below the image-receiving coating. When applied only on the image-side, it will be applied at a coat- weight ranging from about 2 to about 10 gsm, or at a coat- weight ranging from about 2 to 10 gsm.
- the thickness of the finishing layer, when it forms continuous layer may be about 0.5-5 micrometers depending on the composition of the finishing solution.
- the finishing can be applied on the surface by any coating technology known in the arts such as rod coater and blend coater.
- the migration control finish layer is applied on both the image-side and on the back-side of the fabric base substrate, with coating technique, at a coat-weight ranging from about 0.5 to 5 gsm.
- the migration control finish layer further comprises a physical networking agent and is applied only on the image-side of the fabric base substrate, below the image-receiving coating, applied by padding coating, at a coat-weigh ranging from about 2 to about 10 gsm.
- the application of the image-receiving coating layer, the fire retarding barrier layer and of the migration control finish layer that further comprises a physical networking agent can be done by any coating process and can include a floating knife process, a knife on roll mechanism process, or a transfer coating process.
- the floating knife process can include stretching the fabric to form an even uniform surface.
- the floating knife process can further include transporting the fabric under a stationary knife blade.
- the step of applying the coating layers can include applying a foam coating.
- the foam coating can be applied using a knife-on-the roll mechanism.
- the knife-on-the roll mechanism can be followed by passing the fabric through calendaring pressure nips.
- the calendaring can be done either in room temperature or at an elevated temperature and/or pressure.
- the elevated temperature can range from 40°C to l00°C.
- the elevated pressure can range from about 100 psi to about 5,000 psi.
- the coating process can include transferring the coating composition. When the coating composition is transferred, the coating can be spread onto a release substrate to form a film. The film can then be laminated onto the fabric.
- the migration control finish layer (120) is applied on both the image- side (101) and on the back-side (102) of the fabric base substrate (110) at a coat-weight ranging from about 0.5 to 5 gsm or from about 1 to 2 gsm.
- the application can be carried out using padding procedures.
- the fabric substrate can be soaked in a bath and the excess can be rolled out. More specifically, impregnated fabric substrates (prepared by bath, spraying, dipping, etc.) can be passed through padding nip rolls under pressure.
- the impregnated fabric after nip rolling, can then be dried under heat at any functional time which is controlled by machine speed with peak fabric web temperature in the range of about 90°C to about l80°C.
- pressure can be applied to the fabric substrate after impregnating the fabric base substrate with the coating composition.
- the surface treatment is accomplished in a pressure padding operation. During such operation, the fabric base substrate is firstly dipped into a pan containing treatment coating composition and is then passed through the gap of padding rolls.
- the padding rolls (a pair of two soft rubber rolls or a metal chromic metal hard roll and a tough-rubber synthetic soft roll for instance), apply the pressure to composite-wetted textile material so that composite amount can be accurately controlled.
- the pressure, that is applied is between about 10 and about 150 PSI or, in some other examples, is between about 30 to about 70 PSI.
- the migration control finish layer (120) can be dried using box hot air dryer.
- the dryer can be a single unit or could be in a serial of 3 to 7 units so that a temperature profile can be created with initial higher temperature (to remove excessive water) and mild temperature in end units (to ensure completely drying with a final moisture level of less than 1-5 % for example).
- the peak dryer temperature can be programmed into a profile with higher temperature at begging of the drying when wet moisture is high and reduced to lower temperature when web becoming dry.
- the dryer temperature is controlled to a temperature of less than about 200°C to avoid yellowing textile, and the fabric web temperature is controlled in the range of about 90 to about l80°C.
- the operation speed of the padding/drying line is 50 yards per minute.
- the coating composition is applied to the fabric base substrate and appropriately dried, ink compositions can be applied by any processes onto the fabric printable medium.
- the ink composition is applied to the fabric printable medium via inkjet printing techniques.
- the printing method (300) encompasses obtaining (310) a fabric printable medium comprising a fabric base substrate; an image-receiving coating layer, applied on the image-side of printable medium, comprising a first and a second crosslinked polymeric network; a fire retarding barrier layer, applied to the back-side of the printable medium comprising polymeric binders and filler particles with flame retardancy properties; and, at least, a migration control finish layer comprising a film-formable polymer and a flame retardant agent, at a coat-weight ranging from about 0.5 to 10 gsm; and, then, applying (320) an ink composition onto said fabric printable medium to form a printed image.
- Said printed image will have, for instance, enhanced image quality and image permanence.
- the ink composition is an inkjet ink composition that contains one or more colorants that impart the desired color to the printed message and a liquid vehicle.
- colorant includes dyes, pigments, and/or other particulates that may be suspended or dissolved in an ink vehicle. The colorant can be present in the ink composition in an amount required to produce the desired contrast and readability.
- the ink compositions include pigments as colorants. Pigments that can be used include self-dispersed pigments and non-self-dispersed pigments. Any pigment can be used; suitable pigments include black pigments, white pigments, cyan pigments, magenta pigments, yellow pigments, or the like.
- Pigments can be organic or inorganic particles as well known in the art.
- liquid vehicle is defined to include any liquid composition that is used to carry colorants, including pigments, to a substrate.
- a wide variety of liquid vehicle components may be used and include, as examples, water or any kind of solvents.
- the ink composition, applied to the fabric printable medium is an ink composition containing latex components.
- Latex components are, for examples, polymeric latex particulates.
- the ink composition may contain polymeric latex particulates in an amount representing from about 0.5 wt % to about 15 wt % based on the total weight of the ink composition.
- the polymeric latex refers herein to a stable dispersion of polymeric micro- particles dispersed in the aqueous vehicle of the ink.
- the polymeric latex can be natural latex or synthetic latex. Synthetic latexes are usually produced by emulsion polymerization using a variety of initiators, surfactants and monomers.
- the polymeric latex can be cationic, anionic, nonionic, or amphoteric polymeric latex.
- Monomers that are often used to make synthetic latexes include ethyl acrylate; ethyl methacrylate; benzyl acrylate; benzyl methacrylate; propyl acrylate; methyl methacrylate, propyl methacrylate; iso-propyl acrylate; iso-propyl methacrylate; butyl acrylate; butyl methacrylate; hexyl acrylate; hexyl methacrylate; octadecyl methacrylate; octadecyl acrylate; lauryl methacrylate; lauryl acrylate; hydroxyethyl acrylate; hydroxyethyl methacrylate; hydroxyhexyl acrylate; hydroxyhexyl methacrylate; hydroxyoctadecyl acrylate
- the latexes are prepared by latex emulsion polymerization and have an average molecular weight ranging from about 10,000 Mw to about 5,000,000 Mw.
- the polymeric latex can be selected from the group consisting of acrylic polymers or copolymers, vinyl acetate polymers or copolymers, polyester polymers or copolymers, vinylidene chloride polymers or copolymers, butadiene polymers or copolymers, polystyrene polymers or copolymers, styrene-butadiene polymers or copolymers and acrylonitrile-butadiene polymers or copolymers.
- the latex components are on the form of a polymeric latex liquid suspension.
- Such polymeric latex liquid suspension can contain a liquid (such as water and/or other liquids) and polymeric latex particulates having a size ranging from about 20 nm to about 500 nm or ranging from about 100 nm to about 300 nm.
- a liquid such as water and/or other liquids
- polymeric latex particulates having a size ranging from about 20 nm to about 500 nm or ranging from about 100 nm to about 300 nm.
- Samples 1 to 4 are fabric printable mediums in accordance with the principles described herein.
- Samples 5 and 6 are comparative examples. Detailed structures of these samples are shown in Table 2.
- Each sample has a support base structure (110) which is a polyester fabric with plain weave having a weight of 130 gsm.
- Each samples of the present disclosure comprises, at least, a migration control finish layer, an image-receiving coating layer and a fire retarding barrier layer.
- the different formulations of the different layers are summarized in Tables 3, 4 and 5. Each number represents the Parts (by dry weight) contained in each layer composition.
- the Migration control finishing layer formulation MC- A all image receiving layers (IR A and B) and Fire retarding barrier layer (FR A and B) are applied by a Methis lab-coater equipped with an IR dryer. Blade that is used is a 90-degree flat blade.
- the Migration control finishing layer formulation MC- A is applied only to the image-side of the fabric printable medium at a coat-weight of about 5 gsm.
- the Migration control finishing layer formulation MC - B is applied by using a Mathis lab padder machine equipped with a IR dryer (as supplied by Methis Inc, Germany). The padding pressure is 50 PSI, speed setting is 0.25, and dryer temperature is l00°C, 120 °C and 90°C for each zone.
- the Migration control finishing layer formulation MC - B is applied to both the image-side and the back-side of the fabric printable medium, at a coat-weight of about 1.5 gsm.
- Image quality is evaluated using both numeric measurement method and visual evaluation method.
- the image quality of the prints is measured with Gamut, Ink bleed, Ink strike through and image gloss test.
- the Ink bleed and Ink strike through are evaluated visually from the printed samples using a scale of 1-5 (with 1 being the worst and 5 being the best).
- Gamut Measurement represents the amount of color space covered by the ink on the media sample (a measure of color richness).
- the gamut is measured on Macbeth ® TD904 (Micro Precision Test Equipment, California) (A higher value indicates better color richness).
- the image gloss is evaluated using spectrophotometer (such as the X-Rite il/iO) and single-angle gloss-meter (such as the BYK Gloss-meter).
- Image Durability is with rub resistance, coin scratch and ink transfer tests.
- Rub resistance testing is carried out using an abrasion scrub tester (per ASTM D4828 method): fabrics are printed with small patches of all available colors (cyan, magenta, yellow, black, green, red, and blue). A weight of 250 g is loaded on the test header.
- the test tip is made of acrylic resin with crock cloth.
- the test cycle speed is 25 cm/min and 5 cycles are carried out for each sample at an 8 inch length for each cycle.
- the test probe is in dry (dry rub) or wet (wet rub) mode.
- Coin scratch test is performed by exposing the various samples to be tested to a 45 degree coin scratching under a normal force of 800 g.
- the test is done in a BYK Abrasion Tester (from BYK-Gardner ETSA, Columbus, MD) with a linear, back-and-forth action, attempting to scratch off the image-side of the samples (5 cycles).
- the image durability is evaluated visually from the printed samples using a scale of 1-5 (with 1 being the worst and 5 being the best).
- Fire retardancy is evaluated by Diversified Test Lab Inc., complying with FR NFPA 701 standard and is also evaluated by Hewlett Packard’s internal test with CA 1237 standard. The printed samples are evaluated with a scale of 1-5 (with 1 being the worst and 5 being the best).
- the fabric printable medium according to the present disclosure provides several advantages over the comparative samples in terms of image quality, image durability and Fire retardancy performances. It is noted that though some comparative medium performed well in some categories, they performed poorly in others. In accordance with examples of the present disclosure, over these tests, performance is collectively better when using the fabric printable medium described herein.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/US2018/019717 WO2019164530A1 (en) | 2018-02-26 | 2018-02-26 | Fabric printable medium |
Publications (2)
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EP3707304A1 true EP3707304A1 (en) | 2020-09-16 |
EP3707304A4 EP3707304A4 (en) | 2020-11-18 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP18907030.3A Withdrawn EP3707304A4 (en) | 2018-02-26 | 2018-02-26 | Fabric printable medium |
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US (1) | US11236467B2 (en) |
EP (1) | EP3707304A4 (en) |
WO (1) | WO2019164530A1 (en) |
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KR102263132B1 (en) * | 2018-12-28 | 2021-06-10 | 주식회사 케이씨씨 | Water-soluble base coat composition |
TWM595580U (en) * | 2019-12-02 | 2020-05-21 | 大陸商達亞帆布(上海)有限公司 | Environmental protection advertising cloth of non-PVC combinable fabric structure |
BE1030726B1 (en) * | 2022-07-25 | 2024-02-19 | Grandeco Wallfashion Group Belgium Nv | FLEXIBLE WALL COVERING WITH VIRCIDUAL COATING AND METHOD FOR ITS MANUFACTURE |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
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US6326323B1 (en) | 1998-02-13 | 2001-12-04 | Komatsu Seiren Co., Ltd. | Fabric for ink-jet recording |
US6001137A (en) | 1998-02-27 | 1999-12-14 | Encad, Inc. | Ink jet printed textiles |
US6291023B1 (en) | 1998-04-22 | 2001-09-18 | Sri International | Method and composition for textile printing |
JP3923739B2 (en) | 2001-02-26 | 2007-06-06 | セーレン株式会社 | Inkjet recording fabric having flame retardancy and method for producing the same |
US20030157303A1 (en) | 2001-08-31 | 2003-08-21 | Shulong Li | Textile printing substrate |
US6936076B2 (en) | 2001-10-22 | 2005-08-30 | Milliken & Company | Textile substrate having coating containing multiphase fluorochemical, cationic material, and sorbant polymer thereon, for image printing |
US6689517B1 (en) | 2002-08-20 | 2004-02-10 | Eastman Kodak Company | Fabric imaging element |
US20050009429A1 (en) | 2003-07-08 | 2005-01-13 | Higher Dimension Medical, Inc. | Flame retardant and cut resistant fabric |
US20060040575A1 (en) | 2004-08-18 | 2006-02-23 | Kelleher Karen A | Reflective printing on flame resistant fabrics |
US20060281849A1 (en) | 2005-06-13 | 2006-12-14 | Isp Investments Inc. | Coating compositions for forming a single inkjet-receptive layer on unsubbed textiles for direct inkjet printing with dye and pigment inks thereon |
WO2009084600A1 (en) | 2007-12-28 | 2009-07-09 | Sakata Inx Corp. | Treatment solution for ink jet textile printing, ink jet textile printing method, and product printed by ink jet textile printing |
US20110275264A1 (en) | 2010-05-10 | 2011-11-10 | Mcbride Daniel T | Durable flame resistant fabrics |
US10543707B2 (en) * | 2011-04-28 | 2020-01-28 | Hewlett-Packard Development Company, L.P. | Recording media |
WO2014014453A1 (en) * | 2012-07-18 | 2014-01-23 | Hewlett-Packard Development Company, L.P. | Fabric print media |
CN105163947B (en) * | 2013-06-06 | 2017-04-05 | 惠普发展公司,有限责任合伙企业 | Cloth print medium |
US9855781B2 (en) * | 2013-07-15 | 2018-01-02 | Hewlett-Packard Development Company, L.P. | Printable medium |
EP3046775B1 (en) | 2013-09-20 | 2018-03-07 | Hewlett-Packard Development Company, L.P. | Fabric print medium |
US20160243870A1 (en) * | 2013-11-07 | 2016-08-25 | Hewlett-Packard Development Company, L.P. | Printable recording media |
WO2015142313A1 (en) | 2014-03-17 | 2015-09-24 | Hewlett-Packard Development Company, L.P. | Printable media |
WO2017196354A1 (en) | 2016-05-12 | 2017-11-16 | Hewlett-Packard Development Company, L.P. | Fabric print media |
-
2018
- 2018-02-26 US US16/767,006 patent/US11236467B2/en active Active
- 2018-02-26 EP EP18907030.3A patent/EP3707304A4/en not_active Withdrawn
- 2018-02-26 WO PCT/US2018/019717 patent/WO2019164530A1/en unknown
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US20210079591A1 (en) | 2021-03-18 |
US11236467B2 (en) | 2022-02-01 |
EP3707304A4 (en) | 2020-11-18 |
WO2019164530A1 (en) | 2019-08-29 |
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