EP3704084A4 - Adsorbent for contaminant removal from c4 hydrocarbons - Google Patents

Adsorbent for contaminant removal from c4 hydrocarbons Download PDF

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Publication number
EP3704084A4
EP3704084A4 EP18874582.2A EP18874582A EP3704084A4 EP 3704084 A4 EP3704084 A4 EP 3704084A4 EP 18874582 A EP18874582 A EP 18874582A EP 3704084 A4 EP3704084 A4 EP 3704084A4
Authority
EP
European Patent Office
Prior art keywords
adsorbent
hydrocarbons
contaminant removal
contaminant
removal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP18874582.2A
Other languages
German (de)
French (fr)
Other versions
EP3704084A1 (en
EP3704084B1 (en
Inventor
Stephen R. CASKEY
Munish Kumar Sharma
Jayant K. Gorawara
Pijus Kanti ROY
Frank S. Modica
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Publication of EP3704084A1 publication Critical patent/EP3704084A1/en
Publication of EP3704084A4 publication Critical patent/EP3704084A4/en
Application granted granted Critical
Publication of EP3704084B1 publication Critical patent/EP3704084B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/082—X-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28071—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1025—Natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
EP18874582.2A 2017-11-03 2018-10-31 Adsorbent for contaminant removal from c4 hydrocarbons Active EP3704084B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/802,766 US10744492B2 (en) 2017-11-03 2017-11-03 Adsorbent for contaminant removal from C4 hydrocarbons
PCT/US2018/058344 WO2019089684A1 (en) 2017-11-03 2018-10-31 Adsorbent for contaminant removal from c4 hydrocarbons

Publications (3)

Publication Number Publication Date
EP3704084A1 EP3704084A1 (en) 2020-09-09
EP3704084A4 true EP3704084A4 (en) 2021-08-04
EP3704084B1 EP3704084B1 (en) 2024-02-28

Family

ID=66333355

Family Applications (1)

Application Number Title Priority Date Filing Date
EP18874582.2A Active EP3704084B1 (en) 2017-11-03 2018-10-31 Adsorbent for contaminant removal from c4 hydrocarbons

Country Status (3)

Country Link
US (1) US10744492B2 (en)
EP (1) EP3704084B1 (en)
WO (1) WO2019089684A1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020147377A1 (en) * 2000-12-08 2002-10-10 Kanazirev Vladislav I. Composite adsorbents for purifying hydrocarbon streams
WO2017053501A1 (en) * 2015-09-23 2017-03-30 Uop Llc Process for purifying hydrocarbon streams using low reactivity adsorbents

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3402996A (en) * 1966-12-19 1968-09-24 Grace W R & Co Ion exchange of crystalline zeolites
US3992471A (en) 1974-08-12 1976-11-16 Uop Inc. Process for the separation of 1,3-butadiene by selective adsorption on a zeolite adsorbent
CA2128562A1 (en) 1993-08-16 1995-02-17 William Hertl Modified large pore zeolites for trapping alkenes
US6124517A (en) 1997-03-10 2000-09-26 Bp Amoco Corporation Olefin purification by adsorption of acetylenics and regeneration of adsorbent
FR2792850B1 (en) 1999-04-29 2001-07-13 Air Liquide HIGH MACROPOROSITY ADSORBENT FOR USE IN A GAS ADSORPTION PROCESS, IN PARTICULAR A PSA PROCESS
DE60129626T2 (en) 2000-04-20 2008-05-21 Tosoh Corp., Shinnanyo Process for purifying a gas mixture containing hydrogen
EP1633475B1 (en) 2003-06-06 2010-06-23 Zeochem AG Method for sulfur compounds removal from contaminated gas and liquid streams
US7326821B2 (en) * 2003-06-16 2008-02-05 Exxonmobil Chemical Patents Inc. Removal of oxygenate from an olefin stream
TWI277648B (en) 2004-07-29 2007-04-01 China Petrochemical Technology A cracking catalyst for hydrocarbons and its preparation
DE102008046155B4 (en) * 2008-03-03 2017-01-26 Chemiewerk Bad Köstritz GmbH Process for producing an adsorbent granulate
US8888993B2 (en) 2010-07-30 2014-11-18 Chevron U.S.A. Inc. Treatment of a hydrocarbon feed
KR20120108542A (en) 2011-03-24 2012-10-05 한국에너지기술연구원 Adsorbent for removing sulfur compounds in c4 hydrocabon mixture from fluidized catalytic cracking process and preparation method thereof
US9024104B2 (en) 2012-06-19 2015-05-05 Uop Llc Methods for removing weakly basic nitrogen compounds from a hydrocarbon stream using basic molecular sieves
US8609911B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-44 aluminosilicate zeolite
FR3006608B1 (en) 2013-06-10 2021-01-01 Ifp Energies Now ADSORBANT BASED ON A ZEOLITH AND A CLAY RICH IN SILICA AND PROCESS FOR PURIFYING HYDROCARBON LOADS CONTAINING UNSATURATED MOLECULES
TWI659778B (en) 2014-04-09 2019-05-21 美商Ｗ Ｒ 康格雷氏公司 Improved zeolite particles for adsorption and / or desorption of gases and liquids, and application and manufacturing method thereof
US9517983B2 (en) 2014-07-16 2016-12-13 Basf Corporation Regeneration loop clean-up

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020147377A1 (en) * 2000-12-08 2002-10-10 Kanazirev Vladislav I. Composite adsorbents for purifying hydrocarbon streams
WO2017053501A1 (en) * 2015-09-23 2017-03-30 Uop Llc Process for purifying hydrocarbon streams using low reactivity adsorbents

Also Published As

Publication number Publication date
EP3704084A1 (en) 2020-09-09
WO2019089684A1 (en) 2019-05-09
EP3704084B1 (en) 2024-02-28
US20200023341A1 (en) 2020-01-23
US10744492B2 (en) 2020-08-18

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