EP3694708A1 - Display modules with quasi-static and dynamic impact resistance - Google Patents
Display modules with quasi-static and dynamic impact resistanceInfo
- Publication number
- EP3694708A1 EP3694708A1 EP18796207.1A EP18796207A EP3694708A1 EP 3694708 A1 EP3694708 A1 EP 3694708A1 EP 18796207 A EP18796207 A EP 18796207A EP 3694708 A1 EP3694708 A1 EP 3694708A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- μηι
- cover element
- gpa
- display module
- mpa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
- B32B17/10045—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10082—Properties of the bulk of a glass sheet
- B32B17/10119—Properties of the bulk of a glass sheet having a composition deviating from the basic composition of soda-lime glass, e.g. borosilicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10128—Treatment of at least one glass sheet
- B32B17/10137—Chemical strengthening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
Definitions
- the disclosure generally relates to bendable display modules and articles, particularly bendable display modules including a glass-containing cover.
- flexible electronic devices can provide thin, lightweight and flexible properties that offer opportunities for new applications including curved displays and wearable devices.
- Many of these flexible electronic devices incorporate flexible substrates for holding and mounting the electronic components of these devices.
- Metal foils have some advantages including thermal stability and chemical resistance, but suffer from high cost and a lack of optical transparency.
- Polymeric foils have some advantages including low cost and impact resistance, but suffer from marginal optical transparency, lack of thermal stability, limited hermeticity and cyclic fatigue performance.
- Some of these electronic devices also can make use of flexible displays.
- Optical transparency and thermal stability are often desirable properties for flexible display applications.
- flexible displays should have high fatigue and puncture resistance, including resistance to failure at small bend radii, particularly for flexible displays that have touch screen functionality and/or can be folded. Further, flexible displays should be easy to bend and fold by the consumer, depending on the intended application for the display.
- Some flexible glass and glass-containing materials offer many desirable properties for flexible and foldable substrate and display applications.
- efforts to harness glass materials for these applications have been difficult to date.
- glass substrates can be manufactured to very low thickness levels ( ⁇ 25 ⁇ ) to achieve smaller and smaller bend radii. These "thin" glass substrates suffer from limited puncture resistance.
- thicker glass substrates > 150 ⁇ can be fabricated with better puncture resistance, but these substrates lack suitable fatigue resistance and mechanical reliability upon bending.
- these flexible glass materials are employed as cover elements in modules that also contain electronic components (e.g., thin film transistors ("TFTs”), touch sensors, etc.), additional layers (e.g., polymeric electronic device panels) and adhesives (e.g., epoxies, optically clear adhesives ("OCAs”)), interactions between these various components and elements can lead to increasingly complex stress states that exist during use of the module within an end product, e.g., an electronic display device.
- These complex stress states can lead to increased stress levels and/or stress concentration factors experienced by the cover elements.
- these cover elements can be susceptible to cohesive and/or delamination failure modes within the module. Further, these complex interactions can lead to increased bending forces to bend and fold the cover element by the consumer.
- a display module includes: a cover element having a thickness from about 25 ⁇ to about 200 ⁇ and a cover element elastic modulus from about 20 GPa to about 140 GPa, the cover element further comprising a component having a glass composition, a first primary surface, and a second primary surface; and a stack comprising: (a) a substrate comprising a component having a glass composition and a thickness from about 100 ⁇ to 1500 ⁇ , and (b) a first adhesive joining the stack to the second primary surface of the cover element, the first adhesive comprising an elastic modulus from about 0.001 GPa to about 10 GPa and a thickness from about 5 ⁇ to about 50 ⁇ .
- a display module includes: a cover element having a thickness from about 25 ⁇ to about 200 ⁇ and a cover element elastic modulus from about 20 GPa to about 140 GPa, the cover element further comprising a component having a glass composition, a first primary surface, and a second primary surface; and a stack comprising: (a) a substrate comprising a component having a glass composition and a thickness from about 100 ⁇ to 1500 ⁇ , and (b) a first adhesive joining the stack to the second primary surface of the cover element, the first adhesive comprising an elastic modulus from about 0.001 GPa to about 10 GPa and a thickness from about 5 ⁇ to about 50 ⁇ .
- the display module comprises an impact resistance characterized by a tensile stress of less than about 4000 MPa at the first primary surface of the cover element and a tensile stress of less than about 12000 MPa at the second primary surface of the cover element upon an impact to the cover element in a Pen-Drop Test.
- a display module includes: a cover element having a thickness from about 25 ⁇ to about 200 ⁇ and a cover element elastic modulus from about 20 GPa to about 140 GPa, the cover element further comprising a component having a glass composition, a first primary surface, and a second primary surface; and a stack comprising: (a) a substrate comprising a component having a glass composition and a thickness from about 100 ⁇ to 1500 ⁇ , and (b) a first adhesive joining the stack to the second primary surface of the cover element, the first adhesive comprising an elastic modulus from about 0.001 GPa to about 10 GPa and a thickness from about 5 ⁇ to about 50 ⁇ .
- the display module comprises an impact resistance
- the display module comprises a stiffness of about 750 N/mm or more, as measured during the Quasi-Static Indentation Test.
- Embodiment 1 A display module, comprising: a cover element having a thickness from about 25 ⁇ to about 200 ⁇ and a cover element elastic modulus from about 20 GPa to about 140 GPa, the cover element further comprising a component having a glass composition, a first primary surface, and a second primary surface; and
- a stack comprising:
- a substrate comprising a component having a glass composition and a thickness from about 100 ⁇ to 1500 ⁇
- the display module comprises an impact resistance characterized by a tensile stress of less than about 4700 MPa at the second primary surface of the cover element upon an impact to the cover element in a Quasi-Static Indentation Test.
- Embodiment 2 The display module according to Embodiment 1 , wherein the display module comprises an impact resistance characterized by a tensile stress of less than about 3200 MPa at the second primary surface of the cover element upon an impact to the cover element in a Quasi-Static Indentation Test.
- Embodiment 3 The display module according to Embodiment 2 or Embodiment 3, wherein the first adhesive further comprises a thickness from about 5 ⁇ to about 25 ⁇ , and the cover element further comprises a thickness from about 50 ⁇ to about 150 ⁇ .
- Embodiment 4 The display module according to any one of Embodiments 1-3, wherein the first adhesive comprises one or more of an epoxy, a urethane, an acrylate, an acrylic, a styrene copolymer, a polyisobutylene, a polyvinyl butyral, an ethylene vinyl acetate, sodium silicate, an optically clear adhesive (OCA), a pressure sensitive adhesive (PSA), polymeric foam, a natural resin, or a synthetic resin.
- the first adhesive comprises one or more of an epoxy, a urethane, an acrylate, an acrylic, a styrene copolymer, a polyisobutylene, a polyvinyl butyral, an ethylene vinyl acetate, sodium silicate, an optically clear adhesive (OCA), a pressure sensitive adhesive (PSA), polymeric foam, a natural resin, or a synthetic resin.
- OCA optically clear adhesive
- PSA pressure sensitive adhesive
- Embodiment 5 The display module according to any one of Embodiments 1-4, wherein the stack further comprises:
- an interlayer having a thickness from about 25 ⁇ to about 200 ⁇ and an interlayer elastic modulus from about 20 GPa to about 140 GPa, the interlayer further comprising a component having a glass composition; and (d) a second adhesive joining the interlayer to the substrate, the second adhesive comprising an elastic modulus from about 0.001 GPa to about 10 GPa and a thickness from about 5 ⁇ to about 50 ⁇ .
- Embodiment 6 The display module according to Embodiment 5, wherein the display module comprises an impact resistance characterized by a tensile stress of less than about 4200 MPa at the second primary surface of the cover element upon an impact to the cover element in a Quasi-Static Indentation Test.
- Embodiment 7 The display module according to Embodiment 6, wherein each of the first and second adhesives further comprises a thickness from about 5 ⁇ to about 25 ⁇ , and each of the cover element and the interlayer further comprises a thickness from about 75 ⁇ to about 150 ⁇ .
- Embodiment 8 The display module according to any one of Embodiments 5-7, wherein each of the first and second adhesives comprises one or more of an epoxy, a urethane, an acrylate, an acrylic, a styrene copolymer, a polyisobutylene, a polyvinyl butyral, an ethylene vinyl acetate, sodium silicate, an optically clear adhesive (OCA), a pressure sensitive adhesive (PSA), polymeric foam, a natural resin, or a synthetic resin.
- OCA optically clear adhesive
- PSA pressure sensitive adhesive
- Embodiment 9 A display module, comprising:
- cover element having a thickness from about 25 ⁇ to about 200 ⁇ and a cover element elastic modulus from about 20 GPa to about 140 GPa, the cover element further comprising a component having a glass composition, a first primary surface, and a second primary surface;
- a stack comprising:
- a substrate comprising a component having a glass composition and a thickness from about 100 ⁇ to 1500 ⁇
- a first adhesive joining the stack to the second primary surface of the cover element, the first adhesive comprising an elastic modulus from about 0.001 GPa to about 10 GPa and a thickness from about 5 ⁇ to about 50 ⁇ , wherein the display module comprises an impact resistance characterized by a tensile stress of less than about 4000 MPa at the first primary surface of the cover element and a tensile stress of less than about 12000 MPa at the second primary surface of the cover element upon an impact to the cover element in a Pen Drop Test.
- Embodiment lO The display module according to Embodiment 9, wherein the display module comprises an impact resistance characterized by a tensile stress of less than about 4000 MPa at the first primary surface of the cover element and a tensile stress of less than about 9000 MPa at the second primary surface of the cover element upon an impact to the cover element in a Pen Drop Test.
- Embodiment 1 l The display module according to Embodiment 10, wherein the first adhesive further comprises a thickness from about 5 ⁇ to about 25 ⁇ , and the cover element further comprises a thickness from about 50 ⁇ to about 150 ⁇ .
- Embodiment 12 The display module according to any one of Embodiments 9-11 , wherein the first adhesive comprises one or more of an epoxy, a urethane, an acrylate, an acrylic, a styrene copolymer, a polyisobutylene, a polyvinyl butyral, an ethylene vinyl acetate, sodium silicate, an optically clear adhesive (OCA), a pressure sensitive adhesive (PSA), polymeric foam, a natural resin, or a synthetic resin.
- the first adhesive comprises one or more of an epoxy, a urethane, an acrylate, an acrylic, a styrene copolymer, a polyisobutylene, a polyvinyl butyral, an ethylene vinyl acetate, sodium silicate, an optically clear adhesive (OCA), a pressure sensitive adhesive (PSA), polymeric foam, a natural resin, or a synthetic resin.
- OCA optically clear adhesive
- PSA pressure sensitive adhesive
- Embodiment 13 The display module according to any one of Embodiments 9-12, wherein the stack further comprises:
- an interlayer having a thickness from about 25 ⁇ to about 200 ⁇ and an interlayer elastic modulus from about 20 GPa to about 140 GPa, the interlayer further comprising a component having a glass composition;
- Embodiment 14 The display module according to Embodiment 13 , wherein the display module comprises an impact resistance characterized by a tensile stress of less than about 4000 MPa at the first primary surface of the cover element and a tensile stress of less than about 1 1000 MPa at the second primary surface of the cover element upon an impact to the cover element in a Pen Drop Test.
- Embodiment 15 The display module according to Embodiment 14, wherein each of the first and second adhesives further comprises a thickness from about 5 ⁇ to about 25 ⁇ , and each of the cover element and the interlayer further comprises a thickness from about 50 ⁇ to about 150 ⁇ .
- Embodiment 16 The display module according to any one of Embodiments 13-15, wherein each of the first and second adhesives comprises one or more of an epoxy, a urethane, an acrylate, an acrylic, a styrene copolymer, a polyisobutylene, a polyvinyl butyral, an ethylene vinyl acetate, sodium silicate, an optically clear adhesive (OCA), a pressure sensitive adhesive (PSA), polymeric foam, a natural resin, and a synthetic resin.
- OCA optically clear adhesive
- PSA pressure sensitive adhesive
- a display module comprising:
- cover element having a thickness from about 25 ⁇ to about 200 ⁇ and a cover element elastic modulus from about 20 GPa to about 140 GPa, the cover element further comprising a component having a glass composition, a first primary surface, and a second primary surface;
- a stack comprising:
- a substrate comprising a component having a glass composition and a thickness from about 100 ⁇ to about 1500 ⁇
- a first adhesive joining the stack to the second primary surface of the cover element, the first adhesive comprising an elastic modulus from about 0.001 GPa to about 10 GPa and a thickness from about 5 ⁇ to about 50 ⁇ , wherein the display module comprises an impact resistance characterized by a tensile stress of less than about 4700 MPa at the second primary surface of the cover element upon an impact to the cover element in a Quasi-Static Indentation Test, and
- the display module comprises a stiffness of about 750 N/mm or more, as measured during the Quasi-Static Indentation Test.
- Embodiment 18 The display module according to Embodiment 17, wherein the display module comprises an impact resistance characterized by a tensile stress of less than about 3200 MPa at the second primary surface of the cover element upon an impact to the cover element in a Quasi-Static Indentation Test, and further wherein the display module comprises a stiffness of about 1000 N/mm or more, as measured during the Quasi-Static Indentation Test.
- Embodiment 19 The display module according to Embodiment 18, wherein the first adhesive further comprises a thickness from about 5 ⁇ to about 25 ⁇ , and the cover element further comprises a thickness from about 50 ⁇ to about 150 ⁇ .
- Embodiment 20 The display module according to Embodiment 19, wherein the first adhesive comprises one or more of an epoxy, a urethane, an acrylate, an acrylic, a styrene copolymer, a polyisobutylene, a polyvinyl butyral, an ethylene vinyl acetate, sodium silicate, an optically clear adhesive (OCA), a pressure sensitive adhesive (PSA), polymeric foam, a natural resin, or a synthetic resin.
- OCA optically clear adhesive
- PSA pressure sensitive adhesive
- polymeric foam a natural resin, or a synthetic resin.
- a display module comprising:
- cover element having a thickness from about 25 ⁇ to about 200 ⁇ and a cover element elastic modulus from about 20 GPa to about 140 GPa, the cover element further comprising a component having a glass composition, a first primary surface, and a second primary surface;
- a stack comprising:
- the display module comprises at least one of:
- an impact resistance characterized by a tensile stress of less than about 4700 MPa at the second primary surface of the cover element upon an impact to the cover element in a Quasi- Static Indentation Test
- an impact resistance characterized by a tensile stress of less than about 4000 MPa at the first primary surface of the cover element and a tensile stress of less than about 12000 MPa at the second primary surface of the cover element upon an impact to the cover element in a Pen Drop Test;
- FIG. 1A is a cross-sectional view of a three-layer display module according to some aspects of the disclosure.
- FIG. IB is a cross-sectional view of a five-layer display module according to some aspects of the disclosure.
- FIG. 2 depicts a display module within a Pen Drop Test apparatus for measuring quasi-static and dynamic impact resistance, according to some aspects of the disclosure.
- FIG. 3 A is a plot of the maximum principal stress at the second primary surface of the cover element of a display module vs. load subjected to the module in a modeled Quasi- Static Indentation Test up to a peak load of 60 N, according to some aspects of the disclosure.
- FIG. 3B is a plot of load vs. deformation for a display module subjected to a modeled Quasi-Static Indentation Test up to a peak load of 60 N, according to some aspects of the disclosure.
- FIG. 4 is a plot of peak failure load for a portion of the modules schematically depicted in FIG. 3A and tested in a Quasi-Static Indentation Test.
- FIG. 5 A is a plot of the maximum principal stress at the second primary surface of the cover element of a display module vs. distance from the impact location, as modeled in a Pen Drop Test with a pen drop height of 25 cm, according to some aspects of the disclosure.
- FIG. 5B is a plot of the maximum principal stress at the first primary surface of the cover element of a display module vs. distance from the impact location, as modeled in a Pen Drop Test with a pen drop height of 25 cm, according to some aspects of the disclosure.
- FIGS. 6A & 6B are plots of the maximum principal stress and deformation, respectively, at the second primary surface of the cover element of a display module vs. time from impact, as modeled in a Pen Drop Test with a pen drop height of 25 cm, according to some aspects of the disclosure.
- FIG. 7 is a bar chart of the maximum principal stress at the second primary surface of the cover element of the display modules depicted in FIGS. 3A-6B, along with the percentage increase of each of these stress values over the lowest maximum principal stress observed in the samples.
- substantially is intended to note that a described feature is equal or approximately equal to a value or description.
- a “substantially planar” surface is intended to denote a surface that is planar or approximately planar.
- substantially is intended to denote that two values are equal or approximately equal.
- substantially may denote values within about 10% of each other, such as within about 5% of each other, or within about 2% of each other.
- the display modules and articles of the disclosure offer unexpectedly high quasi-static and dynamic impact resistance. These modules attain these impact resistance levels through design of the thickness of the adhesives and cover element, along with the number of layers within the module. Further, the enhancement to the impact resistance attributes associated with these modules can also contribute to mechanical reliability and puncture resistance. With regard to mechanical reliability, the display modules of the disclosure are configured to avoid failures in their glass-containing cover elements upon flexing, bending or other deformations to the module.
- the display module may be used as one or more of: a cover on the user-facing portion of a foldable electronic display device, a location in which puncture resistance is particularly desirable; a substrate module, disposed internally within the device itself, on which electronic components are disposed; or elsewhere in a display device.
- the display modules of the disclosure may be used in a device not having a display, but one in which a glass or glass-containing layer is used for its beneficial properties and is folded or otherwise bent, in a similar manner as in a foldable display, to a tight bend radius.
- the puncture resistance is particularly beneficial when the display module is used on the exterior of the device, at a location in which a user will interact with it.
- the display modules and articles in the disclosure can obtain some or all of the foregoing advantages through control of the material properties and thicknesses the cover element, adhesives and interlayers employed within the modules.
- these display modules can exhibit enhanced impact resistance, as characterized by reduced tensile stresses at the primary surfaces of the cover element that are measured in a modeled or actual Quasi-Static Indentation or dynamic Pen Drop Test, through increased thickness of the interlayer, increased elastic modulus of the interlayer and/or increased elastic modulus of the first adhesive.
- These lower tensile stresses associated with quasi-static and dynamic loading can lead to improved module reliability, particularly in terms of failure resistance of the cover element as the module is subjected to application-driven impact evolutions.
- the embodiments and concepts in the disclosure provide a framework for those with ordinary skill to design display modules to reduce tensile stresses at the primary surfaces of the cover element, which can contribute to the reliability,
- a display module 100a is depicted in exemplary form as a three-layer module, according to some aspects of the disclosure.
- the module 100a includes a cover element 50, first adhesive 10a, and substrate 60. Further, a stack 90a is referenced that includes the adhesive 10a and the substrate 60. Further, cover element 50 has a thickness 52, a first primary surface 54 and a second primary surface 56.
- Thickness 52 can range from about 25 ⁇ to about 200 ⁇ , for example from about 25 ⁇ to about 175 ⁇ , from about 25 ⁇ to about 150 ⁇ , from about 25 ⁇ to about 125 ⁇ , from about 25 ⁇ to about 100 ⁇ , from about 25 ⁇ to about 75 ⁇ , from about 25 ⁇ to about 50 ⁇ , from about 50 ⁇ to about 175 ⁇ , from about 50 ⁇ to about 150 ⁇ , from about 50 ⁇ to about 125 ⁇ , from about 50 ⁇ to about 100 ⁇ , from about 50 ⁇ to about 75 ⁇ , from about 75 ⁇ to about 175 ⁇ , from about 75 ⁇ to about 150 ⁇ , from about 75 ⁇ to about 125 ⁇ , from about 75 ⁇ to about 100 ⁇ , from about 100 ⁇ to about 175 ⁇ , from about 100 ⁇ to about 150 ⁇ , from about 100 ⁇ to about 125 ⁇ , from about 125 ⁇ to about 175 ⁇ , from about 100 ⁇ to about 150 ⁇ , from about 100 ⁇
- thickness 52 can range from about 25 ⁇ to 150 ⁇ , from about 50 ⁇ to 100 ⁇ , or from about 60 ⁇ to 80 ⁇ .
- the thickness 52 of the cover element 50 can also be set at other thicknesses or thickness ranges between the foregoing ranges.
- Some aspects of the display modules 100a incorporate a cover element 50 with a relatively lower thickness, e.g., from about 75 ⁇ to about 125 ⁇ , compared to the thicknesses of other glass cover elements employed in such electronic device applications.
- cover elements 50 with relatively lower thickness values unexpectedly provides an enhanced degree of resistance to quasi-static and dynamic impacts, as manifested in a reduced tensile stresses observed at the first and second primary surfaces 54, 56 of the cover element 50 upon an impact in a Quasi-Static Indentation or a Pen Drop Test.
- the display module 100a depicted in FIG. 1A includes a cover element 50 with a cover element elastic modulus from about 20 GPa to 140 GPa, for example from about 20 GPa to about 120 GPa, from about 20 GPa to about 100 GPa, from about 20 GPa to about 80 GPa, from about 20 GPa to about 60 GPa, from about 20 GPa to about 40 GPa, from about 40 GPa to about 120 GPa, from about 40 GPa to about 100 GPa, from about 40 GPa to about 80 GPa, from about 40 GPa to about 60 GPa, from about 60 GPa to about 120 GPa, from about 60 GPa to about 100 GPa, from about 60 GPa to about 80 GPa, from about 80 GPa to about 120 GPa, from about 80 GPa to about 100 GPa, and from about 100 GPa to about 120 GPa.
- the cover element 50 may be a component having a glass composition or include at least one component having a glass composition. In the latter case, the cover element 50 can include one or more layers that include glass-containing materials, e.g., element 50 can be a polymer/glass composite configured with second phase glass particles in a polymeric matrix. In some aspects, the cover element 50 is a glass element characterized by an elastic modulus from about 50 GPa to about 100 GPa, or any elastic modulus value or range of values between these limits.
- the cover element elastic modulus is about 20 GPa, 30 GPa, 40 GPa, 50 GPa, 60 GPa, 70 GPa, 80 GPa, 90 GPa, 100 GPa, 110 GPa, 120 GPa, 130 GPa, 140 GPa, or any elastic modulus value or range of values between these values.
- the cover element 50 can include a glass layer.
- the cover element 50 can include two or more glass layers.
- the thickness 52 reflects the sum of the thicknesses of the individual glass layers making up the cover element 50.
- the thickness of each of the individual glass layers is 1 ⁇ or more.
- the cover element 50 employed in the module 100a can include three glass layers, each having a thickness of about 8 ⁇ , such that the thickness 52 of the cover element 50 is about 24 ⁇ .
- the cover element 50 could include other non-glass layers (e.g., compliant polymer layers) sandwiched between multiple glass layers.
- the cover element 50 can include one or more layers that include glass- containing materials, e.g., element 50 can be a polymer/glass composite configured with second phase glass particles in a polymeric matrix.
- a display module 100a including a cover element 50 comprising a glass material can be fabricated from alkali-free aluminosilicate, borosilicate, boroaluminosilicate, and silicate glass compositions.
- the cover element 50 can also be fabricated from alkali- containing aluminosilicate, borosilicate, boroaluminosilicate, and silicate glass compositions.
- alkaline earth modifiers can be added to any of the foregoing compositions for the cover element 50.
- glass compositions according to the following are suitable for a cover element 50 having one or more glass layers: S1O2 at 50 to 75% (by mol%); AI2O3 at 5 to 20%; B2O3 at 8 to 23%; MgO at 0.5 to 9%; CaO at 1 to 9%; SrO at 0 to 5%; BaO at 0 to 5%; Sn0 2 at 0.1 to 0.4%; Zr0 2 at O to 0.1%; and Na 2 0 at 0 to 10%, K 2 0 at 0 to 5%, and L12O at 0 to 10%.
- glass compositions according to the following are suitable for a cover element 50 having one or more glass layers: S1O2 at 64 to 69% (by mol%); AI2O3 at 5 to 12%; B2O3 at 8 to 23%; MgO at 0.5 to 2.5%; CaO at 1 to 9%; SrO at 0 to 5%; BaO at 0 to 5%; Sn0 2 at 0.1 to 0.4%; Zr0 2 at 0 to 0.1%; and Na 2 0 at 0 to 1 %.
- the following composition is suitable for the cover element 50: S1O2 at -67.4% (by mol%); AI2O3 at -12.7%; B2O3 at -3.7%; MgO at -2.4%; CaO at 0%; SrO at 0%; Sn0 2 at -0.1 %; and Na20 at -13.7%.
- the following composition is also suitable for a glass layer employed in the cover element 50: S1O2 at 68.9% (by mol%); AI2O3 at 10.3%; Na 2 0 at 15.2%; MgO at 5.4 %; and Sn0 2 at 0.2%.
- the cover element 50 can employ the following glass composition ("Glass 1"): S1O2 at -65% (by mol%); B2O3 at -5%; AI2O3 at -14%; Na 2 0 at -14%; and MgO at -2 mol%.
- Glass 1 glass composition
- the following composition is also suitable for a glass layer employed in the cover element 50: S1O2 at 68.9% (by mol%); AI2O3 at 10.3%; Na 2 0 at 15.2%; MgO at 5.4 %; and Sn0 2 at 0.2%.
- composition for a cover element 50 comprising a glass material including but not limited to ease of manufacturing to low thickness levels while minimizing the incorporation of flaws; ease of development of a compressive stress region to offset tensile stresses generated during bending, optical transparency; and corrosion resistance.
- the cover element 50 employed in the foldable module 100a can adopt a variety of physical forms and shapes. From a cross-sectional perspective, the element 50, as a single layer or multiple layers, can be flat or planar. In some aspects, the element 50 can be fabricated in non-rectilinear, sheet-like forms depending on the final application. As an example, a mobile display device having an elliptical display and bezel could employ a cover element 50 having a generally elliptical, sheet-like form.
- the display module 100a further includes: a stack 90a having a thickness 92a from about 100 ⁇ to 1600 ⁇ ; and a first adhesive 10a configured to join the stack 90a to the second primary surface 56 of the cover element 50, the first adhesive 10a characterized by a thickness 12a and an elastic modulus from about 0.001 GPa to about 10 GPa, for example, from about 0.001 GPa to about 8 GPa, from about 0.001 GPa to about 6 GPa, from about 0.001 GPa to about 4 GPa, from about 0.001 GPa to about 2 GPa, from about 0.001 GPa to about 1 GPa, from about 0.01 GPa to about 8 GPa, from about 0.01 GPa to about 6 GPa, from about 0.01 GPa to about 4 GPa, from about 0.01 GPa to about 2 GPa, from about 0.1 GPa to about 8 GPa, from about 0.1 GPa to about 8 GPa, from about
- the first adhesive 10a is characterized by an elastic modulus of about 0.001 GPa, 0.002 GPa, 0.003 GPa, 0.004 GPa, 0.005 GPa, 0.006 GPa, 0.007 GPa, 0.008 GPa, 0.009 GPa, 0.01 GPa, 0.02 GPa, 0.03 GPa, 0.04 GPa, 0.05 GPa, 0.1 GPa, 0.2 GPa, 0.3 GPa, 0.4 GPa, 0.5 GPa, 0.6 GPa, 0.7 GPa, 0.8 GPa, 0.9 GPa, 1 GPa, 2 GPa, 3 GPa, 4 GPa, 5 GPa, 6 GPa, 7 GPa, 8 GPa, 9 GPa, 10 GPa, or any amount or range of amounts between these elastic modulus values.
- the first adhesive 10a is characterized by a thickness 12a from about 5 ⁇ to about 60 ⁇ , for example, from about 5 ⁇ to about 50 ⁇ , from about 5 ⁇ to about 40 ⁇ , from about 5 ⁇ to about 30 ⁇ , from about 5 ⁇ to about 20 ⁇ , from about 5 ⁇ to about 15 ⁇ , from about 5 ⁇ to about 10 ⁇ , from about 10 ⁇ to about 60 ⁇ , from about 15 ⁇ to about 60 ⁇ , from about 20 ⁇ to about 60 ⁇ , from about 30 ⁇ to about 60 ⁇ , from about 40 ⁇ to about 60 ⁇ , from about 50 ⁇ to about 60 ⁇ , from about 55 ⁇ to about 60 ⁇ , from about 10 ⁇ to about 50 ⁇ , from about 10 ⁇ to about 40 ⁇ , from about 10 ⁇ to about 30 ⁇ , from about 10 ⁇ to about 20 ⁇ , from about 10 ⁇ to about 15 ⁇ , from about 20 ⁇ to about 30 ⁇ , from about 10 ⁇ to about 20 ⁇ , from about 10 ⁇ to
- first adhesive 10a characterized by a thickness 12a of about 5 ⁇ , 10 ⁇ , 15 ⁇ , 20 ⁇ , 25 ⁇ , 30 ⁇ , 35 ⁇ , 40 ⁇ , 45 ⁇ , 50 ⁇ m, 55 ⁇ , 60 ⁇ m, or any thickness or range of thicknesses between these thickness values.
- the thickness 12a of the first adhesive 10a is from about 5 ⁇ to 50 ⁇ .
- Some aspects of the display modules 100a incorporate an adhesive 10a with a relatively lower thickness, e.g., from about 5 ⁇ to about 25 ⁇ , compared to the thicknesses of conventional adhesives employed in such electronic device applications.
- the first adhesive 10a is further characterized by a Poisson's ratio from about 0.1 to about 0.5, for example, from about 0.1 to about 0.45, from about 0.1 to about 0.4, from about 0.1 to about 0.35, from about 0.1 to about 0.3, from about 0.1 to about 0.25, from about 0.1 to about 0.2, from about 0.1 to about 0.15, from about 0.2 to about 0.45, from about 0.2 to about 0.4, from about 0.2 to about 0.35, from about 0.2 to about 0.3, from about 0.2 to about 0.25, from about 0.25 to about 0.45, from about 0.25 to about 0.4, from about 0.25 to about 0.35, from about 0.25 to about 0.3, from about 0.3 to about 0.45, from about 0.3 to about 0.45, from about 0.3 to about 0.4, from about 0.3 to about 0.35, from about 0.35 to about 0.45, from about 0.35 to about 0.4, and from about 0.4 to about 0.45.
- a Poisson's ratio from about 0.1 to about 0.5
- first adhesive 10a characterized by a Poisson's ratio of about 0.1 , 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, or any Poisson's ratio or range of ratios between these values.
- the Poisson's ratio of the first adhesive 10a is from about 0.1 to about 0.25.
- the display module 100a depicted in FIG. 1A includes an adhesive 10a with certain material properties (e.g., an elastic modulus from about 0.001 GPa to 10 GPa).
- Example adhesives that can be employed as the adhesive 10a in the module 100a include optically clear adhesives ("OCAs") (e.g., Henkel Corporation LOCTITE ® liquid OCAs), epoxies, and other joining materials as understood by those with ordinary skill in the field that are suitable to join the stack 90a (e.g., the substrate 60) to the second primary surface 56 of the cover element 50.
- OCAs optically clear adhesives
- epoxies e.g., Henkel Corporation LOCTITE ® liquid OCAs
- other joining materials as understood by those with ordinary skill in the field that are suitable to join the stack 90a (e.g., the substrate 60) to the second primary surface 56 of the cover element 50.
- OCA optically clear adhesive
- PSA pressure sensitive adhesive
- the stack 90 a of the foldable module 100a further includes a substrate 60 comprising a component having a glass composition, first and second primary surfaces 64, 66, and a thickness 62.
- the substrate 60 can, in some embodiments, have an elastic modulus from about 20 GPa to 140 GPa, for example from about 20 GPa to about 120 GPa, from about 20 GPa to about 100 GPa, from about 20 GPa to about 80 GPa, from about 20 GPa to about 60 GPa, from about 20 GPa to about 40 GPa, from about 40 GPa to about 120 GPa, from about 40 GPa to about 100 GPa, from about 40 GPa to about 80 GPa, from about 40 GPa to about 60 GPa, from about 60 GPa to about 120 GPa, from about 60 GPa to about 100 GPa, from about 60 GPa to about 80 GPa, from about 40 GPa to about 60 GPa, from about 60 GPa to about
- the substrate 60 may be a component having a glass composition or include at least one component having a glass composition.
- the substrate 60 can include one or more layers that include glass-containing materials, e.g., substrate 60 can be a polymer/glass composite configured with second phase glass particles in a polymeric matrix.
- the substrate is a glass element characterized by an elastic modulus from about 50 GPa to about 100 GPa, or any elastic modulus value or range of values between these limits.
- the elastic modulus of the substrate 60 is about 20 GPa, 30 GPa, 40 GPa, 50 GPa, 60 GPa, 70 GPa, 80 GPa, 90 GPa, 100 GPa, 110 GPa, 120 GPa, 130 GPa, 140 GPa, or any elastic modulus value or range of values between these values.
- the substrate 60 is substantially similar to or the same as the cover element 50 in terms of glass composition.
- the substrate 60 has a thickness 62 from about 100 ⁇ to about 1500 ⁇ , for example, from about 100 ⁇ to about 1250 ⁇ , from about 100 ⁇ to about 1000 ⁇ , from about 100 ⁇ to about 750 ⁇ , from about 100 ⁇ to about 500 ⁇ , from about 100 ⁇ to about 400 ⁇ , from about 100 ⁇ to about 300 ⁇ , from about 100 ⁇ to about 200 ⁇ , 500 ⁇ to about 1500 ⁇ , for example, from about 500 ⁇ to about 1250 ⁇ , from about 500 ⁇ to about 1000 ⁇ , from about 500 ⁇ to about 750 ⁇ , from about 750 ⁇ to about 1500 ⁇ , from about 750 ⁇ to about 1250 ⁇ , from about 750 ⁇ to about 1000 ⁇ , from about 1000 ⁇ ⁇ about 1500 ⁇ , from about 1000 ⁇ to about 1250 ⁇ , or any thickness or range of thicknesses between these thickness values.
- the display module 100a can be bent, flexed or otherwise mechanically deformed to a certain degree in certain embodiments, e.g., to a bend radii of about 10 mm or greater, or 5 mm or greater.
- suitable materials that can be employed as the substrate 60 in the module 100a include various thermoset and thermoplastic materials, e.g., polyimides, suitable for mounting electronic devices 102 and possessing high mechanical integrity and flexibility when subjected to the bending associated with the foldable electronic device module 100a.
- substrate 60 may be an organic light emitting diode (“OLED") display panel.
- OLED organic light emitting diode
- the material selected for the substrate 60 may also exhibit a high thermal stability to resist material property changes and/or degradation associated with the application environment for the module 100a and/or its processing conditions.
- the stack 90a of the display module 100a shown in FIG. 1A can also include one or more electronic devices (not shown) coupled to the substrate 60.
- These electronic devices can be conventional electronic devices employed in conventional OLED-containing display devices.
- the substrate 60 of the stack 90a can include one or more electronic devices in the form and structure of a touch sensor, polarizer, etc. , and other electronic devices, along with adhesives or other compounds for joining these devices to the substrate 60.
- the electronic devices can be located within the substrate 60 and/or on one or more of its primary surfaces 64, 66.
- a display module 100b is shown in exemplary form as a five-layer module with a stack 90a that further includes (i.e., in addition to the first adhesive 10a and the substrate 60) an interlayer 70 having a thickness 72 from about 25 ⁇ to about 200 ⁇ and an interlayer elastic modulus from about 20 GPa to about 140 GPa, the interlayer 70 further comprising a component having a glass composition; and (d) a second adhesive 10b joining the interlayer 70 to the substrate 60, the second adhesive 10b comprising an elastic modulus from about 0.001 GPa to about 10 GPa and a thickness 12b from about 5 ⁇ to about 50 ⁇ .
- the interlayer 70 can be configured with the same or similar composition, thickness and elastic modulus as the cover element 50.
- the second adhesive 10b can be configured with the same or similar composition, thickness and elastic modulus as that of the first adhesive 10a. More generally, the configuration of the display modules 100a, 100b demonstrates that display modules having any number of layers can be employed according to the principles of this disclosure.
- a pen drop test apparatus 200 is depicted.
- a Pen Drop Test was conducted with a pen drop apparatus 200 to assess the impact resistance of the display modules 100a, 100b (see FIGS. 1A & IB), as characterized by the stress state observed at the primary surfaces 54, 56 of the cover element.
- a Pen Drop Test is a dynamic test that is conducted such that the display modules 100a, 100b samples are tested with the load (i.e., from a pen dropping at a fixed height of 25 cm) imparted to the exposed surface of the cover element 50, i.e., primary surface 54.
- One tube is used according to the Pen Drop Test to guide the pen to the sample, and the tube is placed in contact with the top surface of the sample so that the longitudinal axis of the tube is substantially perpendicular to the top surface of the sample.
- Each tube has an outside diameter of 2.54 cm (1 inch), an inside diameter of 1.4 cm (nine sixteenths of an inch) and a length of 90 cm.
- ABS acrylonitrile butadiene
- the pen employed in the Pen Drop Test has a ball point tip 212 of 0.35 mm diameter, and a weight of 5.7 grams as including the cap. According to the Pen Drop Test depicted in FIG. 2, the pen is dropped with the cap attached to the top end (i.e., the end opposite the tip) so that the ball point 212 can interact with the test sample, i.e., a display module 100a, 100b.
- the Pen Drop Test as conducted with the pen drop test apparatus depicted in FIG. 2, was modeled using FEA techniques to estimate tensile stresses generated at the primary surfaces 54, 56 of the cover element 50 based on a fixed pen drop height of 25 cm.
- the pen tip 212 was modeled as a rigid body with no pen tip deformation; a quarter symmetry slice of a module 100a was employed; all interfaces in the module 100a were assumed to be perfectly bonded during the analysis, with no delamination; the aluminum support plate referenced in connection with the pen drop test apparatus 200 was modeled as a rigid body aluminum plate; firictionless contact was assumed between the module 100a and the aluminum support plate; it was assumed that the pen tip 212 did not penetrate the cover element 50 of the module 100a; the use of linear-elastic or hyper-elastic material properties for the elements of the module 100a; the use of a large deformation approach; and that the module 100a was at room temperature during the simulated testing.
- the module can exhibit an impact resistance characterized by a tensile stress of less than about 4000 MPa at the first primary surface 54 of the cover element 50 and a tensile stress of less than about 12000 MPa at the second primary surface 56 of the cover element 50 upon an impact to the cover element in a Pen Drop Test, as modeled with a pen drop height of 25 cm (see FIG. 2).
- the thickness 12a, 12b of the adhesives 10a, 10b and the thickness 52 of the cover element 50 can be adjusted to further enhance the impact resistance of the module 100a such that a tensile stress of less than about 4000 MPa at the first primary surface 54 of the cover element 50 and a tensile stress of less than about 9000 MPa at the second primary surface 56 of the cover element 50 upon an impact to the cover element in a Pen Drop Test.
- Aspects of the display modules 100a can also incorporate a first adhesive 10a with a relatively lower thickness 12a, e.g., from about 5 ⁇ to about 25 ⁇ , as compared to the thickness of conventional adhesives employed in such electronic device applications.
- the display modules 100a can also incorporate a cover element 50 with a relatively lower thickness 52, e.g., from about 75 ⁇ to about 150 ⁇ , or from about 50 ⁇ to about 150 ⁇ , as compared to the thickness of other glass-containing cover elements employed in such electronic device applications.
- a cover element 50 with a relatively lower thickness 52, e.g., from about 75 ⁇ to about 150 ⁇ , or from about 50 ⁇ to about 150 ⁇ , as compared to the thickness of other glass-containing cover elements employed in such electronic device applications.
- the tensile stresses at the first primary surface 54 of the cover element 50 can be reduced to less than about 4000 MPa, 3900 MPa, 3800 MPa, 3700 MPa, 3600 MPa, 3500 MPa, 3400 MPa, 3300 MPa, 3200 MPa, 3100 MPa, 3000 MPa, and lower.
- the tensile stresses at the second primary surface 56 of the cover element 50 can be reduced to less than about 12000 MPa, 11000 MPa, 10000 MPa, 9000 MPa, 8000 MPa, 7500 MPa, 7000 MPa, 6500 MPa, 6000 MPa, 5500 MPa, 5000 MPa, 4500 MPa, 4000 MPa, 3500 MPa, 3000 MPa, and lower.
- a pen drop test apparatus 200 is depicted.
- a "Quasi-Static Indentation Test” was conducted with a pen drop apparatus 200 to assess the impact resistance of the display modules 100a, 100b (see FIGS. 1A & IB), as characterized by the stress state observed at the primary surfaces 54, 56 of the cover element.
- a Quasi-Static Indentation Test is a quasi-static test that is conducted such that the display modules 100a, 100b samples are tested with a constant load of 60N imparted to the exposed surface of the cover element 50, i.e., primary surface 54.
- the pen employed in the Quasi-Static Indentation Test has a ball point tip 212 of 0.5 mm diameter, and a weight of 5.7 grams as including the cap.
- the pen is applied directly to the exposed surface of the cover element 50 with a constant load of 60 N or with successively higher loads, starting from 5 N, until failure.
- the Quasi-Static Indentation Test as conducted with the pen drop test apparatus depicted in FIG. 2, was modeled using FEA techniques to estimate tensile stresses generated at the primary surfaces 54, 56 of the cover element 50 based on an applied load of 60 N. Certain assumptions were made in conducting this modeling, as further understood by those with ordinary skill in the field of the disclosure.
- cover element 50 and substrate 60 were assumed to have an elastic modulus of 71 GPa and a Poisson's ratio of 0.22.
- a typical optical adhesive was assumed for the first and second adhesives, as exhibiting an elastic modulus of 0.3 GPa and a Poisson's ratio of 0.49.
- the pen tip 212 was modeled as a rigid body with no pen tip deformation; a quarter symmetry slice of a module 100a, 100b was employed; all interfaces in the module 100a, 100b were assumed to be perfectly bonded during the analysis, with no delamination; the aluminum support plate referenced in connection with the pen drop test apparatus 200 was modeled as a rigid body aluminum plate; frictionless contact was assumed between the module 100a, 100b and the aluminum support plate; it was assumed that the pen tip 212 did not penetrate the cover element 50 of the module 100a, 100b; the use of linear-elastic or hyper-elastic material properties for the elements of the module 100a, 100b; the use of a large deformation approach; and that the module 100a, 100b was at room temperature during the simulated testing.
- the module can exhibit an impact resistance characterized by a tensile stress of less than about 4700 MPa at the second primary surface 56 of the cover element 50 upon an impact to the cover element in a Quasi-Static Indentation Test, as modeled with a fixed load of 60 N (see FIG. 2).
- the thickness 12a, 12b of the adhesives 10a, 10b and the thickness 52 of the cover element 50 can be adjusted to further enhance the impact resistance of the module 100a, 100b such that a tensile stress of less than about 3200 MPa at the second primary surface 56 of the cover element 50 upon an impact to the cover element in a Quasi-Static Indentation Test.
- Aspects of the display modules 100a can also incorporate a first adhesive 10a with a relatively lower thickness 12a, e.g., from about 5 ⁇ to about 25 ⁇ , as compared to the thickness of conventional adhesives employed in such electronic device applications.
- the display modules 100a can also incorporate a cover element 50 with a relatively lower thickness 52, e.g., from about 75 ⁇ to about 150 ⁇ , or from about 50 ⁇ to about 150 ⁇ , as compared to the thickness of other glass-containing cover elements employed in such electronic device applications.
- the tensile stresses at the second primary surface 56 of the cover element 50 can be reduced to less than about 4700 MPa, 4600 MPa, 4500 MPa, 4400 MPa, 4300 MPa, 4200 MPa, 4100 MPa, 4000 MPa, 3900 MPa, 3800 MPa, 3700 MPa, 3600 MPa, 3500 MPa, 3400 MPa, 3300 MPa, 3200 MPa, 3100 MPa, 3000 MPa, and lower.
- the cover element 50 of the display module 100a, 100b can, in certain aspects of the disclosure, comprise a glass layer or component with one or more compressive stress regions (not shown) that extend from the first and/or second primary surfaces 54, 56 to a selected depth in the cover element 50.
- edge compressive stress regions (not shown) that extend from edges of the element 50 (e.g., as normal or substantially normal to primary surfaces 54, 56) to a selected depth can also be developed.
- the compressive stress region or regions (and/or edge compressive stress regions) contained in a glass cover element 50 can be formed with an ion-exchange ("IOX") process.
- a glass cover element 50 can comprise various tailored glass layers and/or regions that can be employed to develop one or more such compressive stress regions through a mismatch in coefficients of thermal expansion (“CTE”) associated with the layers and/or regions.
- CTE coefficients of thermal expansion
- the compressive stress region(s) can include a plurality of ion-exchangeable metal ions and a plurality of ion- exchanged metal ions, the ion-exchanged metal ions selected so as to produce compressive stress in the compressive stress region(s).
- the ion-exchanged metal ions have an atomic radius larger than the atomic radius of the ion-exchangeable metal ions.
- the ion-exchangeable ions are present in the glass cover element 50 before being subjected to the ion exchange process.
- Ion-exchanging ions e.g., K + ions
- K + ions can be incorporated into the glass cover element 50, replacing some of the ion-exchangeable ions within region(s) within the element 50 that ultimately become the compressive stress region(s).
- the incorporation of ion-exchanging ions, for example, K + ions, into the cover element 50 can be effected by submersing the element 50 (e.g., prior to formation of the complete module 100a) in a molten salt bath containing ion- exchanging ions (e.g., molten KNO3 salt).
- the K + ions have a larger atomic radius than the Na + ions and tend to generate local compressive stress in the glass cover element 50 wherever present, e.g., in the compressive stress region(s).
- the ion- exchanging ions can be imparted from the first primary surface 54 of the cover element 50 down to a first ion exchange depth (not shown, "DOL"), establishing an ion exchange depth- of-compression ("DOC").
- DOL first ion exchange depth
- DOC ion exchange depth- of-compression
- FSM surface stress meter
- SOC stress optical coefficient
- ASTM standard C770-16 entitled “Standard Test Method for Measurement of Glass Stress-Optical Coefficient,” the contents of which are incorporated herein by reference in their entirety.
- a second compressive stress region can be developed in the element 50 from the second primary surface 56 down to a second ion exchange depth. Compressive stress levels within the DOL that far exceed 100 MPa can be achieved with such IOX processes, up to as high as 2000 MPa.
- the compressive stress levels in the compressive stress region(s) within the cover element 50 can serve to offset tensile stresses generated in the cover element 50 upon bending of the foldable electronic device module 100a.
- the display module 100a, 100b can, in some implementations, include one or more edge compressive stress regions in the cover element 50 at edges that are normal to the first and second primary surfaces 54, 56, each defined by a compressive stress of 100 MPa or more. It should be understood that such edge compressive stress regions can be developed in the cover element 50 at any of its edges or surfaces distinct from its primary surfaces, depending on the shape or form of element 50. For example, in some implementations of display module 100a, 100b having an elliptical-shaped cover element 50, edge compressive stress regions can be developed inward from the outer edge of the element that is normal (or substantially normal) from the primary surfaces of the element.
- any such edge compressive stress regions in the cover element 50 can be used to offset tensile stresses generated at the edges of the element through, for example, quasi-static or dynamic impact to the cover element 50 (and module 100a, 100b) across any of its edges and/or non-uniform bending of the cover element 50 at its primary surfaces 54, 46.
- any such edge compressive stress regions employed in the cover element 50 may offset adverse effects from an impact or abrasion event at or to the edges of the element 50 within the module 100a, 100b.
- the cover element 50 can comprise a core region or layer that is sandwiched by clad regions or layers, each substantially parallel to the primary surfaces 54, 56 of the element.
- the core layer is tailored to a CTE that is greater than the CTE of the clad regions or layers (e.g., by compositional control of the core and clad layers or regions).
- the CTE differences between the core region or layer and the clad regions or layers cause uneven volumetric contraction upon cooling, leading to the development of residual stress in the cover element 50 manifested in the development of compressive stress regions below the primary surfaces 54, 56 within the clad region or layers.
- the core region or layer and the clad regions or layers are brought into intimate contact with one another at high temperatures; and these layers or regions are then cooled to a low temperature such that the greater volume change of the high CTE core region (or layer) relative to the low CTE clad regions (or layers) creates the compressive stress regions in the clad regions or layers within the cover element 50.
- the CTE-related compressive stress regions reach from the first primary surface 54 down to a first CTE region depth and the second primary surface 56 to a second CTE region depth, respectively, thus establishing CTE-related DOLs for each of the compressive stress regions associated with the respective primary surfaces 54, 56 and within the clad layer or regions.
- the compressive stress levels in these compressive stress regions can exceed 150 MPa.
- the cover element 50 employs a core region and clad regions with a thickness ratio of greater than or equal to 3 for the core region thickness divided by the sum of the clad region thicknesses.
- maximizing the size of the core region and/or its CTE relative to the size and/or CTE of the clad regions can serve to increase the magnitude of the compressive stress levels observed in the compressive stress regions of the display module 100a, 100b.
- the compressive stress regions can be employed within the cover element 50 to offset tensile stresses generated in the element upon quasi-static or dynamic impacts to the display module 100a, 100b (see FIGS. 1A & IB), particularly tensile stresses that reach a maximum on one of the primary surfaces 54, 56, depending on the nature of the impact.
- the compressive stress region can include a compressive stress of about 100 MPa or more at the primary surfaces 54, 56 of the cover element 50. In some aspects, the compressive stress at the primary surfaces is from about 600 MPa to about 1000 MPa.
- the compressive stress can exceed 1000 MPa at the primary surfaces, up to 2000 MPa, depending on the process employed to produce the compressive stress in the cover element 50.
- the compressive stress can also range from about 100 MPa to about 600 MPa at the primary surfaces of the element 50 in other aspects of this disclosure.
- the compressive stress region (or regions) within the cover element 50 of the module 100a, 100b can exhibit a compressive stress from about 100 MPa to about 2000 MPa, for example, from about 100 MPa to about 1500 MPa, from about 100 MPa to about 1000 MPa, from about 100 MPa to about 800 MPa, from about 100 MPa to about 600 MPa, from about 100 MPa to about 400 MPa, from about 100 MPa to about 200 MPa, from about 200 MPa to about 1500 MPa, from about 200 MPa to about 1000 MPa, from about 200 MPa to about 800 MPa, from about 200 MPa to about 600 MPa, from about 200 MPa to about 400 MPa, from about 400 MPa to about 1500 MPa, from about 400 MPa to about 1000 MPa, from about 400 MPa to about 800 MPa, from about 400 MPa to about 600 MPa, from about 600 MPa to about 1500 MPa, from about 600 MPa to about 1000 MPa, from about 600 MPa to about 800 MPa, from about 400 MPa to about 600 MPa, from about
- the compressive stress can stay constant, decrease or increase as a function of depth from the primary surfaces down to one or more selected depths.
- various compressive stress profiles can be employed in the compressive stress region.
- the depth of each of the compressive stress regions can be set at approximately 15 ⁇ or less from the primary surfaces 54, 56 of the cover element 50.
- the depth of the compressive stress region(s) can be set such that they are approximately 1/3 of the thickness 52 of the cover element 50 or less, or 20% of the thickness 52 of the cover element 50 or less, from the first and/or second primary surfaces 54, 56.
- the display module 100a, 100b can include a cover element 50 comprising a glass material having one or more compressive stress regions with a maximum flaw size of 5 ⁇ or less at the first and/or second primary surfaces 54, 56.
- the maximum flaw size can also be held to about 2.5 ⁇ or less, 2 ⁇ or less, 1.5 ⁇ or less, 0.5 ⁇ or less, 0.4 ⁇ or less, or even smaller flaw size ranges. Reducing the flaw size in the compressive stress region of a glass cover element 50 can further reduce the propensity of the element 50 to fail by crack propagation upon the application of tensile stresses by virtue of impact-related forces to the display module 100a, 100b (see FIGS.
- module 100a, 100b can include a surface region with a controlled flaw size distribution (e.g., flaw sizes of 0.5 ⁇ or less at the first and/or second primary surfaces 54, 56) without employing one or more compressive stress regions.
- a controlled flaw size distribution e.g., flaw sizes of 0.5 ⁇ or less at the first and/or second primary surfaces 54, 56
- other implementations of the display module 100a, 100b can include a cover element 50 comprising a glass material subjected to various etching processes that are tailored to reduce the flaw sizes and/or improve the flaw distribution within the element 50. These etching processes can be employed to control the flaw distributions within the cover element 50 in close proximity to its primary surfaces 54, 56, and/or along its edges (not shown). For example, an etching solution containing about 15 vol% HF and 15 vol% HCl can be employed to lightly etch the surfaces of a cover element 50 having a glass composition.
- the time and temperature of the light etching can be set, as understood by those with ordinary skill, according to the composition of the element 50 and the desired level of material removal from the surfaces of the cover element 50. It should also be understood that some surfaces of the element 50 can be left in an un-etched state by employing masking layers or the like to such surfaces during the etching procedure. More particularly, this light etching can beneficially improve the strength of the cover element 50. In particular, cutting or singulating processes employed to section the glass structure that is ultimately employed as the cover element 50 can leave flaws and other defects within the surfaces of the element 50. These flaws and defects can propagate and cause glass breakage during the application of stresses to the module 100a, 100b containing the element 50 from the application environment and usage.
- the selective etching process by virtue of lightly etching one or more edges of the element 50, can remove at least some of the flaws and defects, thereby increasing the strength and/or fracture resistance of the lightly-etched surfaces.
- a light etching step may be performed after chemical tempering (e.g., ion exchange) of the cover element 50. Such light etching after chemical tempering may reduce any flaws introduced by the chemical tempering process itself and thus may increase the strength and/or fracture resistance of the cover element.
- 1A & IB can include any one or more of the foregoing strength-enhancing features: (a) IOX-related compressive stress regions; (b) CTE-related compressive stress regions; and (c) etched surfaces with smaller defect sizes. These strength- enhancing features can be used to offset or partially offset tensile stresses generated at the surfaces of the cover element 50 associated with the application environment, usage and processing of the display module 100a, 100b.
- the display module 100a, 100b depicted in FIGS. 1A & IB can be employed in a display, printed circuit board, housing or other features associated with an end product electronic device.
- the display module 100a, 100b can be employed in an electronic display device containing numerous thin film transistors ("TFTs") or in an LCD or OLED device containing a low-temperature polysilicon ("LTPS") backplane.
- TFTs thin film transistors
- LTPS low-temperature polysilicon
- the module 100a, 100b can be substantially transparent.
- the module 100a, 100b can have desirable impact resistance, with regard to quasi-static and dynamic impacts, as described in the foregoing paragraphs.
- the display module 100a, 100b is employed in a wearable electronic device, for example, a watch, wallet or bracelet.
- a wearable electronic device for example, a watch, wallet or bracelet.
- foldable includes complete folding, partial folding, bending, flexing, discrete bends, and multiple-fold capabilities; further the device can be folded so that the display is either on the outside of the device when folded, or the inside of the device when folded.
- comparative display modules (Comp. Ex. 1) and display modules consistent with aspects of the disclosure (e.g., Exs. 1 -1 to 1-4, 2-1 and 2-2) were modeled as subjected to simulated quasi-static and dynamic impacts according to the respective Quasi- Static Indentation Test and the Pen Drop Test.
- actual Quasi-Static Indentation Tests were performed on some of the samples to obtain peak load to failure values, recognizing that actual indentation loads were varied until failure.
- FIGS. 3A-7 The results of these modeling and experimental measurements are depicted in FIGS. 3A-7. Further, the legends in these charts describe the configurations of the display modules modeled and/or tested. For example, Comp. Ex.
- the substrate 1 is configured with a glass cover element having a thickness of 100 ⁇ , a first adhesive comprising PSA material with a thickness of 100 ⁇ and a substrate containing the Glass 1 composition having a thickness of 1.1 mm.
- the substrate was modeled at a thickness of 1.1 mm, such was done to show the effects of the adhesive layer on the stack.
- the substrate need not have a thickness of 1.1 mm; instead, as noted elsewhere, the substrate may have a thickness of less than 1.1 mm, for example thicknesses as described above in connection with substrate 62, and the trends will still be similar to those observed with the 1.1 mm thick glass substrate.
- FIG. 3 A a plot is provided of the maximum principal stress at the second primary surface of the cover element of a display module vs. load subjected to the module in a modeled Quasi-Static Indentation Test up to a peak load of 60 N, according to some aspects of the disclosure.
- three-layer display modules with first adhesives having a smaller thickness from about 15 ⁇ to about 50 ⁇ (Exs. 1-1 to 1-4), as compared to the module with the largest first adhesive thickness of about 100 ⁇ (Comp. Ex. 1), demonstrate the lowest maximum principal stress levels at the second primary surface of the cover element.
- the three-layer display modules (Exs. 1-1 to 1-4)
- the relatively softer first adhesive material comprising a pressure sensitive adhesive (PSA) material facilitates localized bending of the display glass underneath the puncture tip of the testing apparatus.
- PSA pressure sensitive adhesive
- bending stresses are related to the overall stiffness of the module, it is further believed that increasing the stiffness of the module can lead to improved impact performance.
- FIG. 3B a plot is provided of load vs. deformation for display modules subjected to a modeled Quasi-Static Indentation Test up to a peak load of 60 N, previously employed to generate the results in FIG. 3 A. Further, the slope of the load vs. deformation curves in FIG. 3B is a measure of the stiff of the display module. Given the results shown earlier in FIG. 3A, it is evident that the modules with higher stiffness values, as shown in FIG. 3B, tended to perform better in terms of reduced maximum principal stresses at the second primary surface of the cover element. Put another way, the maximum tensile stress at the second primary surface of the cover element observed from the Quasi-Static Indentation Test is inversely proportional to the stiffness of the module.
- FIG. 4 a plot is provided of experimentally-determined peak failure loads for a portion of the modules schematically depicted in FIGS. 3 A and 3B and modeled with the Quasi-Static Indentation Test.
- two three-layer modules (Ex. 1 -2 and 1 - 3) and two five-layer modules (Ex. 2-1 and 2-2) were subjected to actual Quasi-Static Indentation Test with increasing applied loads (not a constant load of 60 N) to generate and average load to failure.
- Fractography analyses conducted on these samples revealed that all experienced a biaxial failure mechanism. Further, it is evident from the results shown in FIG.
- the three-layer display modules exhibited significantly higher peak loads to failure as compared to the five-layer display modules. It is believed that this result is due to the fact that the three-layer display modules are stiffer than their five-layer counterparts given the relatively lower amounts of adhesives present in these designs (i.e., one adhesive for the 3- layer modules and two adhesive layers for the 5 -layer modules).
- FIGS. 5A and 5B plots are provided of the maximum principal stress at the second primary surface and first primary surface of the cover element, respectively, of the same group of display modules depicted in FIGS. 3 A and 3B vs. distance from the impact location, as modeled in a Pen Drop Test with a pen drop height of 25 cm.
- the tensile stresses at the second primary surface of the cover element are significantly higher in magnitude relative to the tensile stresses observed at the first primary surface for the same pen drop height of 25 cm.
- the spatial variation of tensile stresses at the second and first primary surfaces of the cover element are depicted, as resulting from the simulated Pen Drop Test with a 25 cm pen drop height.
- the display modules with thinner first adhesive thickness levels e.g., Exs. 1-1 to 1-3, thicknesses from about 15 to 50 ⁇
- the three-layer display modules demonstrate lower maximum principal stress levels at both primary surfaces of the cover element compared to the five- layer display modules (Ex. 2-1 & 2-2), as resulting from the Pen Drop Test.
- FIGS. 6A & 6B plots are provided of the maximum principal stress and deformation, respectively, at the second primary surface of the cover element for the same group of display modules depicted in FIGS. 3 A and 3B vs. time from impact, as modeled in a Pen Drop Test with a pen drop height of 25 cm.
- FIGS. 6A and 6B show that the maximum tensile stress observed at the second primary surface occurs when the display module experiences its largest deformation associated with the pen drop at 25 cm. Accordingly, the maximum tensile stress observed at the second primary surface of the cover element is a function of the overall stiffness of the display module.
- FIG. 7 a bar chart is provided of the maximum principal stress at the second primary surface of the cover element of the same group of display modules depicted in FIGS. 3A-3B, along with the percentage increase of each of these stress values over the lowest maximum principal stress observed in the samples. That is, the display module with the best performance (i.e., the lowest observed maximum principal stress at the second primary surface of the cover element, -7700 MPa), Ex. 1-1 , serves as the baseline for this chart. In particular, the display module with an adhesive comprising PSA and a thickness of 15 ⁇ exhibited the best performance. The chart in FIG. 7 further demonstrates that increasing the thickness of the adhesive (e.g., Comp. Ex.
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Abstract
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| CN110223604A (en) * | 2019-05-27 | 2019-09-10 | 武汉华星光电半导体显示技术有限公司 | A kind of flexible cover plate of display panel and preparation method thereof, display device |
| CN112689789B (en) | 2019-08-19 | 2023-04-04 | 京东方科技集团股份有限公司 | Foldable display screen, manufacturing method thereof and display device |
| WO2021041035A1 (en) | 2019-08-28 | 2021-03-04 | Corning Incorporated | Bendable articles including adhesive layer with a dynamic elastic modulus |
| CN110473475B (en) * | 2019-08-30 | 2022-01-25 | 京东方科技集团股份有限公司 | Optical adhesive layer, stretching display device and preparation method of optical adhesive layer |
| CN113744630B (en) * | 2020-05-28 | 2023-06-23 | 云谷(固安)科技有限公司 | Display module, manufacturing method of display module and display device |
| US20230364888A1 (en) * | 2020-09-15 | 2023-11-16 | Corning Incorporated | Foldable apparatus |
| JP7615613B2 (en) * | 2020-10-30 | 2025-01-17 | 大日本印刷株式会社 | LAMINATE AND DISPLAY DEVICE |
| KR20220134834A (en) | 2021-03-26 | 2022-10-06 | 삼성디스플레이 주식회사 | Display module evaluation jig and display module evaluation method |
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| CN111295282A (en) | 2020-06-16 |
| JP7208986B2 (en) | 2023-01-19 |
| JP2020536773A (en) | 2020-12-17 |
| TW201923427A (en) | 2019-06-16 |
| WO2019074935A1 (en) | 2019-04-18 |
| KR102705952B1 (en) | 2024-09-11 |
| KR20200068706A (en) | 2020-06-15 |
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