EP3676428A1

EP3676428A1 - High temperature monofilament articles

Info

Publication number: EP3676428A1
Application number: EP18850619.0A
Authority: EP
Inventors: William Christopher Lewis; Barton Roy LEWIS; William James Lewis
Original assignee: Advanced Flexible Composites Inc
Current assignee: Advanced Flexible Composites Inc
Priority date: 2017-08-29
Filing date: 2018-08-29
Publication date: 2020-07-08
Also published as: BR112020003885A2; CA3074214A1; MX2020002173A; WO2019046369A1; US20190062959A1; EP3676428A4

Abstract

A fabricated part for a high temperature operation including a non-metallic substrate formed of a polymer fabric of woven non-absorbent polymer filament. The substrate is heat-resistant and heat set at a temperature that is above a predetermined operating temperature of an operation of the fabricated part. The heat setting pre-shrinks/heat stabilizes the material, thereby reducing failure during use in high temperature and/or wet applications. The substrate is useful as an endless belt and other applications. The invention further includes an apparatus with a heating device configured to operate at the predetermined operating temperature, and the fabricated part within or extending through the heating device.

Description

HIGH TEMPERATURE MONOFILAMENT ARTICLES

BACKGROUND OF THE INVENTION

This invention relates generally to high temperature polymer materials and, more particularly, to high temperature fabrics made from polymer filaments for use in various articles, such as belting and tray liners.

Polyphenylene sulfide (PPS) is used in chemical and heat resistant products. When PPS is drawn as a filament, whether as a monofilament or as part of a multifilament yarn, the filament will shrink at elevated operating temperatures, such as by 15% or more, depending on grade and filament manufacturing process, and application operating temperature. Furthermore PPS monofilament generally can have a 'roughness' after weaving that limits use in applications such as steam bulking and heat setting of yarns, various food applications, etc. There is a continuing need for improved monofilament materials for belting and other articles.

SUMMARY OF THE INVENTION

A general object of the invention is to provide improved polymer fabrics that can be used as a substrate with higher temperature resistance and/or dimensional stability in various fabricated parts for high temperature and/or liquid applications. The invention provides, at least in part, a fabricated part for a high temperature operation including a non-metallic substrate formed of a polymer fabric of woven non-absorbent polymer filaments, wherein the substrate is heat-resistant and heat set at a temperature that is above a predetermined operating temperature of an intended operation of the fabricated part. As used herein, references to the term "non-metal" or "non-metallic" are to be understood to refer to an element or material being devoid of metal.

In embodiments of this invention, the polymer filament includes a high temperature chain extended or cured polymer material, desirably obtained by the heat setting. "Heat setting" according to embodiments of this invention involves keeping the material at the setting temperature for a period of time such that a curing and/or crosslinking process occurs. This is discernable by a color change in the fabric and the heat set material of this invention has increased dimensional stability (little to no shrink) at the in-use temperature after being subjected to the curing temperature again.

The heat setting of the substrate according to this invention provides benefits such as pre-shrinking the polymer fabric and/or curing or chain extending the polymer material to impart higher heat resistance. Heat setting the substrate above the intended operating temperature, or the temperature of the intended use, allows for heat resistance and dimensional stability at that operating temperature. Without wishing to be bound by theory, curing PPS with heat in the presence of oxygen results in property changes that are a result of molecular chain extension and formation of molecular chain branches via an oxygen ion bonded between the aromatic rings of PPS. The curing increases the molecular weight, resulting in some thermoset- like properties, including good thermal stability, dimensional stability, and resistance to harsh chemical environments. However, PPS is a thermoplastic and does not suffer from many of the shortcomings of thermosets. For example, whereas PPS monofilament belting is known to shrink during high temperature use, the substrate and articles of this invention are pre-shrunk or thermally stabilized via the heat setting such that the product will not fail due to shrinkage or other destabilization in the operation at, for example, 212° F (100°C) and higher.

In embodiments of this invention, the substrate is formed by heat setting a polymer fabric (e.g., a fabric of polymer monofilaments or multifilaments) at the temperature that is above the predetermined operating temperature of the operation for a predetermined time period, to obtain the polymer substrate. The heat setting can be performed is any suitable method that preshrinks/thermally stabilizes the fabric and/or otherwise imparts dimensional stability. In one embodiment of this invention, the substrate is formed by winding the polymer fabric with a non-stick layer to form wound material layers, and heating the wound material layers to the heat setting temperature, such as in a batch oven, for a sufficient time. In another embodiment, the substrate is formed by calendaring the polymer fabric at or above the heat setting temperature, such as using heated calendar rolls.

The fabricated parts of this invention include endless belts, trays, bakeware or cookware. Exemplary endless belts include conveyor belts for, without limitation, steam treatment, article washing, oven drying, baking, or deep frying. The conveyor belts desirably include an edge material strip along or over the opposing ends and/or longitudinal edges of the belt. The edge material can be a thermoplastic, a fiber-reinforced material, or a silicone material capable of withstanding the predetermined operating temperature. Trays, such as cooking or baking sheets, can be formed from a piece of fabric and an edge material along or over all side or peripheral edges. The tray can be an insert for a cooking device designed to be placed in an oven used for dehydration, baking, or pressing. Other articles include thermoformed articles stamped from the substrate, such for cooking, washing, and/or drying food, plant material, or parts or articles (e.g., can washing).

The invention further provides an apparatus with a heating device configured to operate at a predetermined operating temperature, and a non-metallic endless belt as described above extending through the heating device. In embodiments of this invention, the heating device includes microwave, steam, and/or a heated liquid. The apparatus can be, for example, a washing apparatus, a drying oven, a deep fryer, or a yarn treatment apparatus.

Other objects and advantages will be apparent to those skilled in the art from the following detailed description taken in conjunction with the appended claims and drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

Fig. 1 is a substrate according to one embodiment of this invention.

Fig. 2 is a view of a fabric weave, according to one embodiment of this invention.

Fig. 3 representatively shows a heat setting process according to one embodiment of this invention.

Fig. 4 representatively shows a heat setting process according to another embodiment of this invention.

Fig. 5 is an endless conveyor belt, according to one embodiment of this invention.

Figs. 6 and 7 each show a belt lacing, according to embodiments of this invention.

Fig. 8 shows a tray, according to one embodiment of this invention.

Fig. 9 shows a belt according to one embodiment of this invention used in a can washing and drying apparatus.

Fig. 10 shows a belt according to one embodiment of this invention used in a deep frying apparatus.

Fig. 11 shows a belt according to one embodiment of this invention used in a yarn or other material treatment apparatus.

DETAILED DESCRIPTION OF THE INVENTION

The present invention provides a monofilament fabric having dimensional stability and temperature resistance, and method for making. The monofilament fabric is desirably woven, and can be formed as a mesh with a plurality of mesh openings between the woven monofilament strands.

Fig. 1 illustrates a substrate 20 formed from a polymer monofilament mesh fabric. Substrate 20 includes a plurality of parallel monofilament strands 22 extending between edges 30 and 32. A second plurality of monofilament strands 24 extend perpendicular to, and are woven alternatively between the strands 22 to form the base polymer fabric and the mesh openings between the individual monofilaments 22 and 24. Any suitable fabric weaving is suitable for the polymer fabric. Fig. 2 shows an alternative monofilament fabric substrate 20 where pairs of strands 24 are twisted together and around alternating sides of a corresponding one of the strands 22. Mesh opening sizes can vary, depending on need, with a tighter weaves with more strands forming smaller mesh openings.

The polymer filaments (monofilaments or multifilaments) of this invention can be formed of suitable polymer material, such as polyphenylene sulfide (PPS), polyaminde-imide (PAI), polyphenylene sulfone (PPSU), polyethersulfone (PES), polyethylene (PE), liquid-crystal polymers (LCP), and/or polyether ether ketone (PEEK). The polymer material can include additives to impart additional properties. Inclusion of chopped or milled fiberglass within the polymer materials and within the individual filaments can be used to increase strength or stiffness, thereby not requiring separate, continuous fiberglass reinforcement of the substrate or fabric as a whole. The opposing ends and/or edges 30 and 32 of the substrate 20 each include an edge material strip 36, such as formed of a thermoplastic or silicone material, and optionally fiber-reinforced, capable of withstanding the predetermined operating temperature of the intended use of the substrate 20.

In embodiments of this invention, the substrate 20 is heat set at a heat setting temperature to obtain improved stability and/or temperature resistance. Heat setting according to this invention provides benefits such as curing or chain extending of the polymer material, and/or preshrinking the polymer fabric. In embodiments of this invention, the polymer fabric of the substrate is heat set at a temperature that is greater than a predetermined operating temperature of the intended use of the resulting fabricated part including the substrate. The higher temperature preshrinks/heat stabilizes the fabric before the substrate is put into use, thereby reducing or eliminating shrinkage and rupture during use, particularly at temperatures above 180°F (82°C). In embodiments of this invention, the substrate shrinks less than 2% during treatment. However, even 1% shrinkage during use can result, for example, in an endless belt prematurely failing on the conveyor rollers.

If the operating temperature of the final product is too close to, or higher than, the heat setting temperature, then the substrate fabric will likely still shrink, neck, distort, and/or sometimes even elongate during use. The heat setting temperature is above the glass transition temperature of the polymer, and in embodiments of this invention the heat setting temperature is least 15° over the predetermined operating temperature, and preferably at least 25°, and desirably at least 50° over the predetermined operating temperature. For embodiments including PPS monofilament, the heat setting temperature is desirably 212°F (100°C) or above, more desirably at least 250°F (121°C), for at least 15 minutes, and preferably at least 30 minutes, and desirably at least one hour. Heat setting can be performed by any suitable heating apparatus. In embodiments of this invention, the heat setting is done in combination with a process to further provide stability and/or reduce roughness. Fig. 3 illustrates heat setting according to embodiments of this invention. Monofilament fabric web 20 is calendared against one or more pairs of heated calendar rolls 40. In the embodiment of Fig. 3, the rolls 40 are within an oven 42, such as an oven able to reach a temperature of at least 50° over the intended operating temperature. Any suitable heated calendar roll can be used, such as one or more heated rolls or pairs of rolls. The fabric can also be first heat set, for example in an oven, and then calendared at least once after heat set on heated calendar rolls at or above the heat setting temperature.

Fig. 4 illustrated an alternative heat setting method that also provides stability and/or reduces roughness. In Fig. 4, an interleaf non-stick film or fabric 52, such as made from polytetrafluoroethylene (PTFE), is layered between layers of the monofilament fabric 20 wrapped tightly around roll 50. The wrapped layers are secured about the roll, such as with PTFE tapes to hold the tightness and shape, and placed in an oven at room temperature. The oven is heated to the heat set temperature above the operating temperature for a necessary time, such as near or to the melting point for about 30 minutes. The resulting mesh material has improved stability, decreased roughness, and improved temperature resistance at the operating temperature. One or more monofilament fabrics can be wound about the roll 50, with two fabric sheets 20 being shown in Fig. 4.

After heat setting, the monofilament fabric can be further processed according to the intended use. The mesh can be spliced or cut into the necessary length/shape, and include necessary edge materials, such as described above in Fig. 1. In some embodiments of this invention, coating materials can be applied to the monofilaments or the heat set mesh, such as a silicon, fluoropolymer and/or fluoroelastomer (e.g., PFA, MFA, PTFE, or FEP) coating to provide further non-stick properties. Other exemplary coatings include quartz or silicone polyesters to provide release properties. The coating materials can be applied as additives in the monofilament material, and/or applied before or after the heat treatment, such as by spray coating, dipping, curtain coating, and/or roller coating, and then cured as needed.

The monofilament fabric/mesh of this invention is useful in forming many articles for use. In embodiments of this invention, the monofilament fabric can be formed into conveyor belts, such as shown in Fig. 5. The fabric can be cut and spliced to form endless belt 60, that when assembled around rollers 62 can convey objects 64. As shown in Figs. 6 and 7, the opposing longitudinal ends and edges of the belt can include an edge material strip 66, such as W formed of a thermoplastic or silicone material. The ends 65 of the belt 60 can includes an attachment mechanism for connecting the opposing ends together, such as with an overlapping and connected ends, a male to female connection mechanism, the lacing 68 shown in Fig. 6, or the alternative spiral lacing 70 shown in Fig. 7.

In addition to an endless belt, the monofilament fabric/mesh can be cut and edged as needed to form a sheet, tray, or other fabricated part. Fig. 8 illustrates a representative sheet or tray 80, useful as a food support made from the substrate of this invention. The food support 80 is formed from the substrate of this invention, and includes a mesh fabric 82, with an edge material 84 covering all four sides. Various shapes and configuration are available for food support, such as a flat sheet or with raised 'basket' edges as shown in Fig. 8.

The food support 80, which can be formed, for example, as a cooking basket/tray or a planar cooking sheet, and is useful for placing and removing food items from, and holding food items while in, an oven. The food support of this invention is desirably durable for multiple heating cycles, high temperature and water/oil resistant, easy to clean, stain resistant, and dissipates heat quickly; all while desirably not having any or much effect on the cooking of food. The food support can include a tight weave as a more solid bottom substrate sheet, such as to prevent liquids from dripping on heating elements, or a more open mesh substrate sheet to allow hot air through. The thickness of the substrate and/or the size of the mesh openings provide the ability to cook different food items and provide, for example, the desired food browning, toasting and/or heating characteristics.

The temperature-resistant materials of this invention are also non-absorbent, non- wicking, and resistant to chemicals, steam, and wet conditions, thereby making them particularly useful in numerous applications. Exemplary uses for the belting or other articles made according to this invention include, without limitation, food processing (drying, cooking (oven or microwave)), washing and/or drying of parts or materials (e.g., cans, plant materials (hemp, tobacco, etc.)), yarn bulking/heat setting, high-temperature insulation manufacture, non-woven manufacture, textile drying/shrinking/lamination, screen printing, industrial microwave/RF application, dehydration/drying, bacon cooking, doughnut and corn dog production, pasta belting and pasta screen, extruding corn puffs, and manufacturing pet food.

Fig. 9 illustrates one exemplary use of the fabric/mesh according to this invention as a conveyor belt 92 in a can, or other article, washing and drying apparatus 90. The conveyor belt 92 carries cans 95 through a washing device 94 and then through a drying device 96, such as a hot air dryer or oven. The high temperature substrate of this invention is particularly useful in such part washing and/or drying, particularly due its non-absorbent, preshrunk properties.

Fig. 10 illustrates one exemplary use of the fabric/mesh according to this invention as a conveyor belt 102 in a deep frying apparatus 100. The conveyor belt 102 carries food items (not shown) through a deep fryer 104 filled with oil and then through any downstream device for further cooking or application of additional ingredients (e.g., toppings). The high temperature substrate of this invention is particularly useful in deep frying, or other submersed or liquid-based cooking processes (e.g., water boiling), due its non-absorbent, preshrunk properties.

Fig. 11 illustrates one exemplary use of the fabric/mesh according to this invention as a counterband 1 12 in a yarn production or treatment apparatus 1 10. Exemplary treatment apparatuses include heat setting or bulking machines available from Superba SAS (Mulhouse, France) and/or Spindelfabrik Suessen GmbH (Sussen, Germany). The counterband 1 12 extends around rollers 1 14 and between pinch rollers 116, and holds a bundle of yarn against the conveyor belt 1 18, which also can be formed of the substrate of this invention, as the bundle of yarn is treated with the oven 1 15. Traditional counterbands are formed from woven textile webbing. The monofilament fabric of this invention is particularly useful as a counterband due to resistance of the operating temperature of the oven 115. In addition, the monofilament fabric will not absorb any moisture from the heated fluid 1 17, such as steam, within the oven 1 15.

The counterband holds a bundle of yarn in place as the conveyor carries it through the oven and any yarn cooler. There are several places and mechanisms by which the yarn can become displaced or snagged, which reduces the production efficiency of the entire system. At each end of a steam chamber of the heat setting oven, there is a set of pinch rollers 116 that squeeze the yarn between the counterband 1 12 and the conveyor belt 118. The rollers 1 16 substantially seal the chamber at both ends, preventing the pressurized steam from escaping. As the rollers are constantly exposed to the steam and moisture, the counterband also keep the yarn from sticking to the rollers 1 16.

The monofilament fabrics of this invention can also be thermoformed (i.e., heat pressed) into shaped articles. Due to the temperature resistance, microwave safe, and non-stick capabilities, the monofilament materials are particular suitable for use in or forming cookware or bakeware. Exemplary thermoformed articles include, without limitation, cooking sheets, bread pans, and trays and baskets, particularly for use in high speed ovens.

The present invention is described in further detail in connection with the following examples which illustrate or simulate various aspects involved in the practice of the invention. It is to be understood that all changes that come within the spirit of the invention are desired to be protected and thus the invention is not to be construed as limited by these examples.

EXAMPLES

As a control, a fabric material was heat processed using conventional methods of running the material in a tenter frame through an infrared oven set to 210 °C (410 °F), such that the filament/yarn in the fabric did not reach the actual oven set-point temperature. This process was then followed by the material being calendared at 220 °C (428 °F) using a heated steel two roll calendar. A piece of this material 10" x 218.5" was then placed into a conventional oven set at 220 °C (428 °F) for 8 hours to simulate use. The material was a dull yellow in color after processing. When removed and measured, the material lost 3.75% in the width and 4.75% in the length and the material had changed color to a dull amber color.

Another piece of fabric 11.875" x 1142" that went through the heat setting and calendaring process above was rolled up a layer of PTFE coated fiberglass fabric between each layer of PPS monofilament fabric like displayed in figure 4. This roll was tightened so that the roll could not move during processing and then the outside of the roll was wrapped completely with fiberglass tape and placed into a conventional hot air oven at 220 °C (428 °F) for 8 hours. After removing from the oven and measured. The roll lost .1 % in length and 3.75% in the width for the first three wraps of the material (about 120") and 0% in width the remaining length of the roll (or 1020"), and the material had a dull amber color. A piece of this heat-stabilized material according to this invention was then put in the oven unsupported, without any tension, for 8 hours at 220 °C (428 °F). This material lost 0% in width and 0% in length, indicating that the material was fully heat stabilized so it can be processed without tension.

Thus, the invention provides a non-absorbent polymer fabric substrate having many uses in heated and/or wet environments. By heat setting the polymer fabric of the substrate at a temperature above the intended use temperature, the substrate is preshrunk and stabilized for belting applications at higher temperatures than generally thought.

The invention illustratively disclosed herein suitably may be practiced in the absence of any element, part, step, component, or ingredient which is not specifically disclosed herein.

While in the foregoing detailed description this invention has been described in relation to certain preferred embodiments thereof, and many details have been set forth for purposes of illustration, it will be apparent to those skilled in the art that the invention is susceptible to additional embodiments and that certain of the details described herein can be varied considerably without departing from the basic principles of the invention.

Claims

What is claimed is:

1. A fabricated part for a high temperature operation, comprising:

a non-metallic substrate formed of a polymer fabric of woven non-absorbent polymer filament, wherein the substrate is heat-resistant and heat set at a temperature that is above a predetermined operating temperature of an operation of the fabricated part.

2. The fabricated part of Claim 1 , wherein the substrate is pre-shrunk at the temperature.

3. The fabricated part of Claim 1, wherein the substrate is pre-shrunk such that the product will not further shrink or destabilize in the operation at or above 212° F.

4. The fabricated part of one of the preceding claims, wherein the polymer fabric comprises monofilament or multifilament PPS, PAI, PPSU, PES, PE, LCP, or PEEK.

5. The fabricated part of one of the preceding claims, wherein the polymer fabric is free of continuous fiber reinforcement of fiberglass, but the monofilament or multifilament includes chopped or milled fiberglass therein.

6. The fabricated part of one of the preceding claims, wherein the substrate is connected at opposing ends to form an endless belt.

7. The fabricated part of one of the preceding claims, wherein the substrate is heat set at a temperature of at least 212° for at least 15 minutes, and preferably at least 30 minutes, or at least one hour.

8. The fabricated part of one of the preceding claims, wherein the temperature is at least 15° over the predetermined operating temperature, and preferably at least 50°.

9. The fabricated part of one of the preceding claims, wherein the polymer filament comprises a high temperature chain extended or cured polymer material.

10. The fabricated part of one of the preceding claims, comprising a conveyor belt for steam treatment, article washing, oven drying, baking, or deep frying.

1 1. The fabricated part of one of the preceding claims, wherein the substrate is formed by heat setting the polymer fabric at the temperature that is above the predetermined operating temperature of the operation for a predetermined time period, to obtain the substrate.

12. The fabricated part of Claim 1 1 , wherein the substrate is further formed by winding the polymer fabric with a non-stick layer to form wound material layers, and heating the wound material layers to the heat setting temperature.

13. The fabricated part of Claim 11 , wherein the substrate is further formed by calendaring the polymer fabric at or above the heat setting temperature.

14. The fabricated part of Claim 13, wherein the calendaring is performed with heated calendar rolls.

15. The fabricated part of one of the preceding claims, further comprising a fluoropolymer or fluoroelastomer blended within the monofilament and/or coating the substrate.

16. The fabricated part of one of the preceding claims, further comprising a non-stick coating on the substrate.

17. The fabricated part of one of the preceding claims, further comprising an edge material strip along or over opposing longitudinal edges of the substrate to form an endless belt, the edge material comprising a thermoplastic, fiber-reinforced material, or silicone material capable of withstanding the predetermined operating temperature.

18. The fabricated part of one of the preceding claims, comprising a piece of fabric and an edge material along or over all side or peripheral edges.

19. The fabricated part of Claim 18 , comprising a tray insert, wherein the part is placed onto a tray in an oven used for dehydration, curing, drying, baking, or pressing.

20. An apparatus comprising a heating device configured to operate at the predetermined operating temperature, and an endless belt comprising the fabricated part according to one of the preceding claims and extending through the heating device.

21. The apparatus of Claim 20, wherein the heating device includes steam microwave, or a heated liquid.

22. The apparatus of Claim 20, wherein the apparatus is selected from a washing apparatus, a drying oven, a deep fryer, or a yarn treatment apparatus.