EP3649139A4 - Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers - Google Patents

Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers Download PDF

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Publication number
EP3649139A4
EP3649139A4 EP18828913.6A EP18828913A EP3649139A4 EP 3649139 A4 EP3649139 A4 EP 3649139A4 EP 18828913 A EP18828913 A EP 18828913A EP 3649139 A4 EP3649139 A4 EP 3649139A4
Authority
EP
European Patent Office
Prior art keywords
benzofuranones
polyolefin compositions
stabilized polyolefin
organophosphorus stabilizers
organophosphorus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP18828913.6A
Other languages
German (de)
French (fr)
Other versions
EP3649139A1 (en
Inventor
Iii Roswell E. King
Werner Hoelzl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority claimed from PCT/US2018/040694 external-priority patent/WO2019010166A1/en
Publication of EP3649139A1 publication Critical patent/EP3649139A1/en
Publication of EP3649139A4 publication Critical patent/EP3649139A4/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/524Esters of phosphorous acids, e.g. of H3PO3
    • C08K5/526Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/103Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/105Esters; Ether-esters of monocarboxylic acids with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • C08K5/134Phenols containing ester groups
    • C08K5/1345Carboxylic esters of phenolcarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535Five-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3435Piperidines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/524Esters of phosphorous acids, e.g. of H3PO3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/527Cyclic esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/529Esters containing heterocyclic rings not representing cyclic esters of phosphoric or phosphorous acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/019Specific properties of additives the composition being defined by the absence of a certain additive
EP18828913.6A 2017-07-06 2018-07-03 Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers Pending EP3649139A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17180079 2017-07-06
US201862691193P 2018-06-28 2018-06-28
PCT/US2018/040694 WO2019010166A1 (en) 2017-07-06 2018-07-03 Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers

Publications (2)

Publication Number Publication Date
EP3649139A1 EP3649139A1 (en) 2020-05-13
EP3649139A4 true EP3649139A4 (en) 2021-05-05

Family

ID=67702079

Family Applications (1)

Application Number Title Priority Date Filing Date
EP18828913.6A Pending EP3649139A4 (en) 2017-07-06 2018-07-03 Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers

Country Status (10)

Country Link
EP (1) EP3649139A4 (en)
JP (1) JP2020526610A (en)
KR (1) KR20200027523A (en)
CN (1) CN111051322A (en)
AU (2) AU2018298021B2 (en)
BR (1) BR112020000132A2 (en)
CA (1) CA3068831A1 (en)
MX (1) MX2020000231A (en)
TW (1) TW201920427A (en)
ZA (1) ZA202000592B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200027524A (en) * 2017-07-06 2020-03-12 바스프 에스이 Stabilized polyolefin composition comprising benzofuranone and hindered phenol antioxidant
KR20210022668A (en) 2018-06-21 2021-03-03 바스프 에스이 3-phenyl-benzofuran-2-one diphosphate derivative as a stabilizer
US11309212B2 (en) * 2020-07-30 2022-04-19 Taiwan Semiconductor Manufacturing Co., Ltd. Semiconductor device structure and methods of forming the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015121445A1 (en) * 2014-02-17 2015-08-20 Basf Se 3-phenyl-benzofuran-2-one derivatives containing phosphorus as stabilizers
WO2017025431A1 (en) * 2015-08-10 2017-02-16 Basf Se 3-phenyl-benzofuran-2-one derivatives containing phosphorus as stabilizers

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5308901A (en) * 1988-07-25 1994-05-03 General Electric Company 3-9-diphosphaspiroundecane-stabilized polymer compositions
JP2001081250A (en) * 1999-07-14 2001-03-27 Mitsui Chemicals Inc Polyolefin resin composition
WO2007009916A1 (en) * 2005-07-21 2007-01-25 Ciba Specialty Chemicals Holding Inc. Stabilization of polyolefins with liquid tris-(mono-alkyl)phenyl phosphites
ES2701529T3 (en) * 2014-08-05 2019-02-22 Basf Se 3-Phenyl-benzofuran-2-one diphosphite derivatives as stabilizers
KR20200027524A (en) * 2017-07-06 2020-03-12 바스프 에스이 Stabilized polyolefin composition comprising benzofuranone and hindered phenol antioxidant
WO2019007935A1 (en) * 2017-07-06 2019-01-10 Basf Se A polyethylene pipe
KR20210022668A (en) * 2018-06-21 2021-03-03 바스프 에스이 3-phenyl-benzofuran-2-one diphosphate derivative as a stabilizer

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015121445A1 (en) * 2014-02-17 2015-08-20 Basf Se 3-phenyl-benzofuran-2-one derivatives containing phosphorus as stabilizers
WO2017025431A1 (en) * 2015-08-10 2017-02-16 Basf Se 3-phenyl-benzofuran-2-one derivatives containing phosphorus as stabilizers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2019010166A1 *

Also Published As

Publication number Publication date
ZA202000592B (en) 2021-07-28
JP2020526610A (en) 2020-08-31
EP3649139A1 (en) 2020-05-13
KR20200027523A (en) 2020-03-12
CA3068831A1 (en) 2019-01-10
CN111051322A (en) 2020-04-21
AU2022203873A1 (en) 2022-06-23
AU2018298021B2 (en) 2023-02-23
MX2020000231A (en) 2020-09-25
AU2018298021A1 (en) 2020-01-30
BR112020000132A2 (en) 2020-07-07
TW201920427A (en) 2019-06-01

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