EP3638438A1 - Die casting furnace system with ultrasonic unit for improved molten metal quality - Google Patents
Die casting furnace system with ultrasonic unit for improved molten metal qualityInfo
- Publication number
- EP3638438A1 EP3638438A1 EP18818914.6A EP18818914A EP3638438A1 EP 3638438 A1 EP3638438 A1 EP 3638438A1 EP 18818914 A EP18818914 A EP 18818914A EP 3638438 A1 EP3638438 A1 EP 3638438A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- die casting
- unit
- dosing
- molten material
- set forth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
- B22D1/002—Treatment with gases
- B22D1/005—Injection assemblies therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
- B22D1/007—Treatment of the fused masses in the supply runners
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/20—Accessories: Details
- B22D17/30—Accessories for supplying molten metal, e.g. in rations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D18/00—Pressure casting; Vacuum casting
- B22D18/04—Low pressure casting, i.e. making use of pressures up to a few bars to fill the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/02—Use of electric or magnetic effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/04—Influencing the temperature of the metal, e.g. by heating or cooling the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/20—Measures not previously mentioned for influencing the grain structure or texture; Selection of compositions therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D37/00—Controlling or regulating the pouring of molten metal from a casting melt-holding vessel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D39/00—Equipment for supplying molten metal in rations
- B22D39/003—Equipment for supplying molten metal in rations using electromagnetic field
- B22D39/006—Electromagnetic conveyors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D39/00—Equipment for supplying molten metal in rations
- B22D39/06—Equipment for supplying molten metal in rations having means for controlling the amount of molten metal by controlling the pressure above the molten metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/005—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like with heating or cooling means
- B22D41/01—Heating means
- B22D41/015—Heating means with external heating, i.e. the heat source not being a part of the ladle
Definitions
- the present disclosure relates generally to a system and method for an improved quality of molten metal in a die casting holding furnace unit.
- Traditional dosing furnaces are closed holding furnaces with a spout for direct metal (e.g., liquid or molten metal) delivery into a cold chamber die casting machine.
- Traditional dosing furnaces are designed so the entire furnace has to pressurize for each cycle of the machine. When the metal level in the dosing furnace is pressurized, all of the metal in the dosing furnace physically moves upward. After a shot, the dosing furnace is depressurized and the metal returns to a lowest level. This type of oscillation can generate dross, sludge, oxides, etc.
- current dosing furnaces use porous plugs at the bottom of the dosing unit in order to degas or remove hydrogen from the metal (e.g., aluminum).
- a die casting furnace system includes a die casting holding furnace unit defining a cavity for holding a molten metal.
- the die casting furnace system also includes a dosing unit disposed or positioned within the cavity and defining a dosing area disposed in fluid communication with the cavity for receiving the molten material during a
- An ultrasonic unit is operably coupled with the dosing area and is configured to introduce a vibration into the received molten material for facilitating the removal of gases from the received molten material prior to the molten material traveling into a die casting machine.
- the ultrasonic unit By utilizing the die casting furnace system with a small dosing unit disposed inside of the die casting holding furnace unit, the ultrasonic unit operates with the optimum volume of molten metal (such as aluminum) in order to allow for the highest possible metal quality directly before the molten metal is introduced into the die casting machine.
- the present system also obtains the best combination of metal cleanliness and accuracy in a die casting furnace system by using the combination of ultrasonic unit with a dosing unit disposed within a cavity of the die casting furnace unit. The ultrasonic unit thus provides a large improvement in the melt quality of metal.
- the amount of dross and/or hydrogen is reduced more than five times. Accordingly, the combination of a finitely sized dosing unit in combination with the ultrasonic unit advantageously provides for a lower hydrogen content, higher density, lower porosity number, and higher tensile properties of the treated molten metal relative to the prior art systems.
- Figure 1 is a cross-sectional side view of a die casting holding furnace system including a dosing unit illustrated during a refilling cycle;
- Figure 2 is a cross-sectional side view of the die casting holding furnace system illustrating a dosing cycle
- Figure 3A is a cross-sectional side view of the die casting holding furnace system illustrating an ultrasonic unit operably coupled with the dosing unit;
- Figure 3B is a magnified view of a portion of Figure 3 A illustrating a probe of the ultrasonic unit positioned within a molten metal in the dosing unit for introducing a degassing agent and generating cavitation bubbles;
- Figure 4 is a cross-sectional side view of the die casting holding furnace system illustrating an automatic grain refining unit operably coupled with the dosing unit;
- Figure 5A is a cross-sectional side view of the die casting holding furnace system illustrating an automated feed unit for a metal matrix composite (MMC) operably coupled with the ultrasonic unit; and
- Figure 5B is a magnified view of a portion of Figure 5 A illustrating the probe of the ultrasonic unit positioned within the molten metal for introducing the degassing agent as well as ceramic particles received from the automated feed unit.
- MMC metal matrix composite
- a die casting holding furnace system 100 known as a dual chamber fumace, is generally illustrated in Figures 1 -5.
- the die casting holding furnace system 100 includes a die casting holding fumace unit 102 defining a cavity 103 having a first storage capacity for holding a molten metal or molten material 104.
- the molten metal 104 may include aluminum, Al-Si-Mg alloy (300 series aluminum), or other metal or alloys.
- Fumace unit 102 is a closed holding furnace with a launder system to a die casting machine shot sleeve 106 for dispensing molten metal 106 from the die casting holding fumace unit 102 through the shot sleeve 104 to a die casting machine 108.
- a dosing unit 110 is disposed or positioned within the cavity 103 and defines a dosing area 112 disposed in fluid communication with the cavity 103 for receiving the molten metal 104 during a refilling cycle.
- Figure 1 illustrates the die casting holding fumace system 100 during this refilling cycle, in which a pressure, such as 60 millibars (mbar), is reduced or removed from being applied to the dosing area 112, causing the dosing area 112 to be filled with molten metal 104.
- a pressure such as 60 millibars (mbar)
- mbar millibar
- the dosing area 112 defined by the dosing unit 110 has a second storage capacity that is smaller than the first storage capacity of the cavity 103 of the die casting fumace unit 102. As will be explained in more detail below, this smaller or finite size of dosing area 112 relative to the cavity 103 of the die casting furnace unit 102 provides for optimized processing of the molten metal 104 received during the refilling cycle before its introduction into the die casting machine 108.
- the dosing area 112 has an inlet 113 disposed in fluid communication with the cavity 103 for receiving the molten metal 104 from the die casting holding furnace unit 102 and an outlet 114 disposed in fluid communication with the shot sleeve 106.
- a check valve 115 such as a one-way ball valve, is disposed in the inlet 113 for allowing molten metal 104 to pass through the inlet 113 during the refilling cycle while preventing the molten metal 104 from returning to the cavity 103 once received within the dosing area 112.
- Figure 2 illustrates the die casting holding furnace system 100 during a dosing cycle.
- the dosing cycle begins with a positive pressure produced inside the dosing unit 110, such as reapplication of the 60 mbar described above, so that the check valve 115 is closed and the molten metal 104 is discharged through the shot sleeve 106 and into the die casting machine 108.
- a specific quantity of molten metal 104 is transported into the die casting machine 108, the dosing process terminates by reducing or relieving the pressure applied to the dosing unit 110.
- the specific quantity of molten metal 104 may be a predetermined amount.
- the level of molten metal 104 in the dosing unit 110 is at a lower level than the level of molten metal 104 before the dosing cycle began.
- the die casting holding furnace system 100 is ready for the refilling cycle to begin. As shown in Figure 1, the refilling cycle operates until the level of molten metal 104 within the dosing area 112 again returns to the specified level and the die casting holding furnace system 100 is ready for another dosing cycle to begin.
- the die casting holding furnace system 100 includes an ultrasonic unit 116 operably coupled with the dosing area 112 and configured to introduce a vibration into the molten metal 104 received within the dosing area 112 after a refilling cycle.
- the ultrasonic unit 116 facilitates the removal of gases from the received molten metal 104 prior to being dispensed to the shot sleeve 106.
- the ultrasonic unit 116 includes a probe 117 attached to the holding furnace unit 102 and extending downwardly to be positioned within the molten metal 104 disposed or received in the dosing area 112.
- the probe 117 is configured to generate the vibration, and additionally provide a degassing agent 118 within the dosing area 112 to interact with the molten metal 104 prior to the molten metal 104 traveling into the die casting machine 108.
- the degassing agent 118 functions to remove gases, such as hydrogen, from the molten metal 104 to provide a purification of the molten metal 104 entering the die casting machine 108.
- the dosing area 110 has a defined or finite storage capacity that is smaller than the cavity 103 of the holding furnace unit 102.
- the ultrasonic unit 114 in combination with this finite storage capacity of the dosing area 112 provides for improved purification of the molten metal 104 because the ultrasonic unit is only treating molten metal 104 disposed within the dosing unit 110, and thus is more appropriately sized to efficiently and effectively degas the molten metal 104.
- the degassing agent includes both carrier gas
- Cavitation bubbles 122 can transport gases with them as they move throughout the molten metal 104, including to the surface of the molten metal 104. However, without any assistance, the cavitation bubbles 122 may collapse before reaching the surface. Thus, the carrier gas 120 can used to transport the cavitation bubbles 122 and dissolved gasses throughout the molten metal 104.
- the high-intensity ultrasonic vibration generated from the probe 117 of the ultrasonic unit 114 breaks up the carrier gas 120 bubbles as well as creates large numbers of cavitation bubbles 122.
- the carrier gas 120 bubbles can survive in the molten metal 104 because they do not dissolve in the molten metal 104.
- the carrier gas 120 collects cavitation bubbles 122 containing dissolved gases and transports them uniformly throughout the molten metal 104, thereby improving degassing efficiency.
- the ultrasonic vibration also creates smaller degassing agent bubbles, which allows for more surface area while degassing the molten metal 104.
- the ultrasonic unit 116 operates with the molten metal 104, the molten metal 104 travels through the die casting machine shot sleeve 106 toward and into the die casting machine 108.
- the die casting holding furnace system 100 includes an automated grain refining unit 130 operably coupled with the dosing area 112 to introduce grain refiner 128 into the received molten metal 104.
- the grain refining unit 130 includes a wire rod 132 positioned in the dosing unit 110 as molten metal 104 refills the dosing area 112 to introduce the grain refiner 128. This step is performed between die cast machine (DCM) cycles.
- DCM die cast machine
- the grain refining unit 130 adds grain refiner 128 into the dosing unit 110 for direct contact with the molten metal 104.
- Grain refiner 128 can be a chemical, such as SiC or T1B2, added to the molten metal 104 or alloy to check grain growth.
- the die casting holding furnace system 100 includes an automated metal matrix composite (MMC) feed unit 134 operably coupled with the ultrasonic unit 116 and configured to provide the ultrasonic unit 116 with ceramic particles 136.
- MMC metal matrix composite
- the ultrasonic unit 116 then releases both the degassing agent 118 and the ceramic particulates 136 into the molten metal 104 via the probe 117.
- the ceramic particles 136 feed directly into the ultrasonic wave for
- the ceramic particles 136 may comprise SiC, B4C, nano alumina (AI2O3) decorated aluminum, or S1O2 ceramic composite material or other suitable material.
- the ultrasonic assist provided by the automated MMC feed unit 134 includes an electromagnetic pump 138 used for both Lorentz force stirring and Joule heating.
- the electromagnetic pump 138 applies an alternating magnetic field (either single phase or multiphase) to a conductor to induce electric currents in the conductor, wherein the magnetic field acts as a nonintrusive stirring device, and passes electric currents through the conductor to produce heat.
- the electromagnetic pump 138 is a pump that moves molten metal 104 (i.e., liquid metal or any electrically conductive liquid) using electromagnetism.
- the ultrasonic vibration with degassing agent provided by the ultrasonic unit 116 in combination with the finite storage capacity of the dosing area 112 allows for a large improvement in the melt quality of the metal.
- this combination accounts for a reduction of more than five times the amount of dross as compared to Argon rotary degassing. It also provides for a reduction in the amount of hydrogen as compared to other systems.
- Table 1 is a comparison of various properties of 250 kg of a degassed Al-Si-Mg alloy after different degassing methods are used on the alloy.
- using ultrasonic degassing on 250 kg of an Al-Si-Mg alloy results in a molecular hydrogen content of 0.17 cmVg, a density of 2.706 g/cm 3 , a porosity number of 1-2, and tensile properties of a Unified Thread Standard (UTS) of 245 MPa (force per unit area) and 5.1% El (elongation).
- UTS Unified Thread Standard
- UTS Unified Thread Standard
- El elongation
- a low-cost and more effective grain refiner 128, such as
- SiC is introduced to the molten metal 104 via the dosing unit 110.
- the grain refiner SiC is less expensive than a more commonly used T1B2 master alloy and is more effective at grain refinement.
- a SiC and/or B4C ceramic composite material is added to the small dosing until the material becomes an in-situ MMC. This composite can have improved strength and modulus. The composite, however, may have lower ductility.
- Table 2 is a comparison of the density characteristics of the in-situ MMC as ceramic composite material is added to the small dosing. For example, as the amount of ceramic composite material is added, the density of the MMC increases (i.e., from 2.65 g/cm 3 with none added to 2.82 g/cm 3 with the ceramic composite material constituting 15% of the MMC).
- Table 3 is a comparison of the hardness characteristics of the in-situ MMC as ceramic composite material is added to the small dosing. For example, as the amount of ceramic composite material is added, the hardness of the MMC increases (i.e., from 62 HBW with none added to 72 HBW with the ceramic composite material constituting 15% of the MMC).
- Table 4 is a comparison of the tensile modulus characteristics of the in-situ
- the MMC as ceramic composite material is added to the small dosing.
- the tensile modulus of the MMC increases (i.e., from 75 GPa with none added to 125.25 GPa with the ceramic composite material constituting 15% of the MMC).
- Table 5 is a comparison of the tensile properties of the in-situ MMC as ceramic composite material is added to the small dosing. For example, as the amount of ceramic composite material is added, the force per unit area of the MMC increases (i.e., from 205 UTS with none added to 260 UTS with the ceramic composite material constituting 15% of the MMC) and the elongation of the MMC decreases (i.e., from 15% El with none added to 13% El with the ceramic composite material constituting 15% of the MMC).
- the die casting holding furnace system 100 having the combination of the dosing unit 110 and the ultrasonic unit 116 as described in this disclosure has various beneficial results.
- One beneficial result is ultra clean molten metal 104, such as molten aluminum.
- Another benefit is its dosing accuracy within +1-1%.
- the dosing is accurate when the dosing area 112 is both being refilled with molten metal 104 and pressurized simultaneously. This is unlike conventional systems that have issues pressurizing the system due the proportional valve getting confused during the refilling, changing metal level of the furnace, etc.
- Another benefit is better temperature control of the dosing metal.
- the die casting holding furnace system 100 allows for small additions of grain refiner 128, for example T1B2 and/or S1O2, to be added directly to the molten metal 104, resulting in homogeneous distribution due to ultrasonic wave.
- the die casting holding furnace system 100 also allows for small additions of ceramic particulates 136 to be added directly to the molten metal 104, resulting in homogeneous distribution due to ultrasonic wave that creates an in-situ MMC material.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Continuous Casting (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762520940P | 2017-06-16 | 2017-06-16 | |
| PCT/US2018/037686 WO2018232201A1 (en) | 2017-06-16 | 2018-06-15 | Die casting furnace system with ultrasonic unit for improved molten metal quality |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP3638438A1 true EP3638438A1 (en) | 2020-04-22 |
| EP3638438A4 EP3638438A4 (en) | 2020-12-09 |
| EP3638438B1 EP3638438B1 (en) | 2022-01-19 |
Family
ID=64659382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP18818914.6A Active EP3638438B1 (en) | 2017-06-16 | 2018-06-15 | Die casting furnace system with ultrasonic unit for improved molten metal quality |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20200094315A1 (en) |
| EP (1) | EP3638438B1 (en) |
| CN (1) | CN110769952A (en) |
| WO (1) | WO2018232201A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12096775B2 (en) * | 2020-04-17 | 2024-09-24 | Advanced Biological Marketing, Inc. | Method of stable formulation of microbial and microbe derived products and use of same |
| CN111889651A (en) * | 2020-07-02 | 2020-11-06 | 蚌埠正峰电子科技有限公司 | High-low pressure fixing and forming system of electromagnetic pump |
| CN113976860A (en) * | 2021-09-26 | 2022-01-28 | 贵州克莱因科技有限公司 | Full-automatic casting system and method for aluminum electrolysis anode |
| EP4479206A1 (en) * | 2022-02-14 | 2024-12-25 | Pyrotek, Inc. | Casting furnace |
| CN115722635A (en) * | 2022-11-18 | 2023-03-03 | 清华大学 | Die casting method by means of ultrasonic metal melt treatment |
| CN118218557B (en) * | 2024-03-14 | 2025-06-10 | 大连理工大学 | Reverse wire feeding system and method for grain refiner for high-pressure die casting |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9323248D0 (en) * | 1993-11-11 | 1994-01-05 | Hi Tec Metals R & D Ltd | A casting apparatus and method |
| US6796362B2 (en) * | 2000-06-01 | 2004-09-28 | Brunswick Corporation | Apparatus for producing a metallic slurry material for use in semi-solid forming of shaped parts |
| US7279128B2 (en) * | 2002-09-13 | 2007-10-09 | Hi T.E.Q., Inc. | Molten metal pressure pour furnace and metering valve |
| JP4615300B2 (en) * | 2004-11-25 | 2011-01-19 | 株式会社トウネツ | Holding furnace for low pressure casting |
| KR100682372B1 (en) * | 2006-05-26 | 2007-02-16 | 주식회사 퓨쳐캐스트 | High Temperature Chamber Die Casting Apparatus of Reaction Solid / Semi-Molten Magnesium Alloy and Manufacturing Method Using Magnesium Alloy in Semi-Molten State |
| JP5031268B2 (en) * | 2006-05-29 | 2012-09-19 | 東芝機械株式会社 | Hot water supply control device |
| US8337746B2 (en) * | 2007-06-21 | 2012-12-25 | Cooper Paul V | Transferring molten metal from one structure to another |
| CN101181736B (en) * | 2007-12-07 | 2011-05-18 | 华中科技大学 | Semi solid rheoforming method for metal parts and device therefor |
| JP5068836B2 (en) * | 2010-03-24 | 2012-11-07 | ジヤトコ株式会社 | Casting apparatus and casting method |
| US8870999B2 (en) * | 2011-11-04 | 2014-10-28 | GM Global Technology Operations LLC | Apparatus and method for degassing cast aluminum alloys |
| JP5772683B2 (en) * | 2012-03-30 | 2015-09-02 | トヨタ自動車株式会社 | Casting method and casting apparatus |
| CN103071777B (en) * | 2012-12-27 | 2016-04-13 | 南昌航空大学 | A kind of Vacuum Differential Pressure Casting manufacturing process based on ultrasonic vibration |
| CN104399938A (en) * | 2014-11-05 | 2015-03-11 | 镁联科技(芜湖)有限公司 | Metal melting and conveying device |
| RU2702522C2 (en) * | 2014-11-05 | 2019-10-08 | Констеллиум Иссуар | Method of using tubular sonotrode |
| CN104928542B (en) * | 2015-05-19 | 2017-05-03 | 江苏大学 | Preparation method for 6X82-matrix composites for automobile control arms |
| CN204953868U (en) * | 2015-07-16 | 2016-01-13 | 陈伟 | Hot water stove is given in pressurization |
| US9981310B2 (en) * | 2015-09-01 | 2018-05-29 | GM Global Technology Operations LLC | Degassing and microstructure refinement of shape casting aluminum alloys |
-
2018
- 2018-06-15 WO PCT/US2018/037686 patent/WO2018232201A1/en not_active Ceased
- 2018-06-15 EP EP18818914.6A patent/EP3638438B1/en active Active
- 2018-06-15 CN CN201880040112.6A patent/CN110769952A/en active Pending
- 2018-06-15 US US16/612,991 patent/US20200094315A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN110769952A (en) | 2020-02-07 |
| US20200094315A1 (en) | 2020-03-26 |
| EP3638438A4 (en) | 2020-12-09 |
| EP3638438B1 (en) | 2022-01-19 |
| WO2018232201A1 (en) | 2018-12-20 |
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