EP3632700B1 - Digitally printing structured wear protection film - Google Patents
Digitally printing structured wear protection film Download PDFInfo
- Publication number
- EP3632700B1 EP3632700B1 EP18198350.3A EP18198350A EP3632700B1 EP 3632700 B1 EP3632700 B1 EP 3632700B1 EP 18198350 A EP18198350 A EP 18198350A EP 3632700 B1 EP3632700 B1 EP 3632700B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- wear protection
- lacquer
- top layer
- decoration
- containing top
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000007639 printing Methods 0.000 title claims description 15
- 239000004922 lacquer Substances 0.000 claims description 57
- 239000000463 material Substances 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 32
- 238000005034 decoration Methods 0.000 claims description 30
- 229920003023 plastic Polymers 0.000 claims description 22
- 239000004033 plastic Substances 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 18
- 230000005855 radiation Effects 0.000 claims description 18
- 238000006073 displacement reaction Methods 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 150000001252 acrylic acid derivatives Polymers 0.000 claims description 4
- 230000005670 electromagnetic radiation Effects 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 3
- 230000001360 synchronised effect Effects 0.000 claims description 3
- 230000000295 complement effect Effects 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 57
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- 239000000758 substrate Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 5
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- 239000000123 paper Substances 0.000 description 4
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
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- 239000011120 plywood Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000002347 wear-protection layer Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 2
- HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 description 2
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
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- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
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- 239000004926 polymethyl methacrylate Substances 0.000 description 2
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- 229920000915 polyvinyl chloride Polymers 0.000 description 2
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- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 2
- 150000003866 tertiary ammonium salts Chemical class 0.000 description 2
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- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- OQKRYWDLQFOOLV-UHFFFAOYSA-N 1-ethenoxy-2-ethoxyethane prop-2-enoic acid Chemical compound C(C=C)(=O)O.C(C)OCCOC=C OQKRYWDLQFOOLV-UHFFFAOYSA-N 0.000 description 1
- KHOUKKVJOPQVJM-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OCC(CO)(CO)CO KHOUKKVJOPQVJM-UHFFFAOYSA-N 0.000 description 1
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 244000060020 Chamaerops excelsa Species 0.000 description 1
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- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 244000208876 Washingtonia filifera Species 0.000 description 1
- 235000006574 Washingtonia filifera Nutrition 0.000 description 1
- 229920001587 Wood-plastic composite Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
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- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
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- 238000009413 insulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
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- 238000006557 surface reaction Methods 0.000 description 1
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- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/02—Superimposing layers
- B44C3/025—Superimposing layers to produce ornamental relief structures
Definitions
- the present invention relates to a method for producing a structured wear protection film, a structured wear protection film, the use of a structured wear protection film and a decorative panel with a structured wear protection film.
- Structured surfaces for wear protection are known per se and are used in particular to protect decorative panels.
- EP 2 740 610 A1 , EP 2 730 429 A1 and WO 2018/078043 A1 relate to methods for producing a structured wear protection layer.
- decorative panel is to be understood as meaning wall, ceiling, door or floor panels which have a decoration applied to a carrier plate.
- Decorative panels are used in a variety of ways both in the area of interior design of rooms and for the decorative cladding of buildings, for example in trade fair construction.
- One of the most common areas of application for decorative panels is their use as floor covering, to cover ceilings, walls or doors.
- the decor panels often have a decor and a surface structure that is intended to imitate a natural material.
- wear or cover layers are generally applied above the decorative layer.
- a surface structure imitating a decorative template is introduced into such wear or cover layers, so that the surface of the decorative panel has a Has haptically perceptible structure, which is adapted to its shape and pattern of the applied decor in order to obtain a replica of a natural material that is as true to the original as possible, also with regard to the haptics.
- a disadvantage of such methods can be that in particular the formation of small and locally limited structures, such as pores, is only possible with great difficulty.
- the exact alignment of the embossing tools relative to the decor can cause problems.
- variations in the structure can only be implemented with great effort and, for example, small production series are comparatively uneconomical, since embossing tools have to be manufactured and exchanged for each series.
- embossing tools have to be manufactured and exchanged for each series.
- structured wear protection film is to be understood in the context of the invention as a film that can be applied to panels or other material, has haptically perceptible structures and protects against wear.
- wear protection base film is to be understood in the context of the invention as a film that can be applied to panels or other material, does not have to have any special structuring and can serve as a substrate for applying structures.
- malleable is to be understood as meaning a material which is plastically deformable, that is to say changes its shape through the action of force.
- the material can be liquid or solid, for example.
- digital printing process is to be understood in the context of the invention as a computer-controlled direct printing process.
- the term “hardening” is to be understood as meaning that the malleable material loses its malleability.
- a liquid moldable material can be solidified.
- a plastically deformable solid can be converted into an elastically deformable solid, for example by hardening.
- the material can partially lose its malleability, that is to say lose its malleability at certain points, for example on the surface. It can also be understood to mean that the malleability is only reduced and the material does not become completely non-malleable. It can also be understood as complete hardening.
- An above-described method for producing a wear protection film thus serves in particular for the improved production of structured surfaces for wear protection.
- a wear protection base film provides a substrate on which structuring can take place.
- a moldable, lacquer-containing cover layer By applying a moldable, lacquer-containing cover layer to at least a partial area of the wear protection base film, a structurable layer is provided which is held by the wear protection base film and can therefore be easily shaped and nevertheless can be guided through the process with the wear protection base film.
- the partial structuring of the lacquer-containing top layer with a digital printing process for generating a structure of the lacquer-containing top layer makes it possible to obtain a structuring of the lacquer-containing top layer that is particularly true to detail. Since no embossing tools have to be used in the digital printing process, the wear protection base film as a substrate can provide sufficient stability for the structuring.
- the introduced structure By subsequently hardening the now structured, lacquer-containing top layer, the introduced structure is fixed so that it remains essentially unchanged even when a force is applied.
- the wear protection base film and / or the moldable, lacquer-containing top layer has a plastic composition, preferably an acrylate-based plastic composition, in particular a polyurethane-modified acrylate plastic composition.
- the moldable, lacquer-containing top layer has the plastic composition in an as yet uncured form, so that the top layer can be molded, and that the wear protection base film has the plastic composition in an at least partially cured form, so that it can be used as a substrate for the moldable lacquer-containing top layer can serve.
- the structured wear protection film is flexible overall and at the same time has particularly good protective properties, such as stability, scratch resistance, heat resistance, water resistance and the like.
- the plastic composition can contain a dipropylene glycol diacrylate, preferably in an amount of> 0 to ⁇ 15% by weight based on the plastic composition, and a reaction product of pentaerythritol, epichlorohydrin and acrylic acid, preferably in an amount of ⁇ 2 to ⁇ 15% by weight based on the plastic composition.
- the plastic composition can additionally have a catalyst, preferably in an amount of 1 to 10% by weight based on the plastic composition.
- the catalyst can preferably be a tertiary ammonium salt, in particular a tertiary ammonium salt selected from the group consisting of tetrabutlyammonium bromide, methyltrioctylammonium chloride, benzyltriethylammonium chloride, hexadecyltrimethylammonium bromide and mixtures thereof.
- the catalyst can be tetrabutylammonium bromide.
- the plastic composition can additionally have a photoinitiator, preferably in an amount of 0.1 to 2% by weight, based on the plastic composition.
- the photoinitiator can be a phosphine oxide, preferably an aromatic phosphine oxide, in particular phenylbis (2,4,6-trimethylbenzoyl) phosphine oxide.
- the moldable, lacquer-containing cover layer and the wear protection base film both have the same plastic composition.
- the formable, lacquer-containing cover layer and the wear protection base film consist essentially of the same material after the lacquer-containing cover layer has hardened.
- the visual impression of the structured wear protection film is improved, since the wear protection base film and the lacquer-containing top layer also have the same optical properties after curing and thus unwanted light refraction between the two layers can be avoided.
- the wear protection base film and / or the mouldable lacquer-containing top layer has hard materials, preferably in an amount between 5% by weight and 40% by weight, the hard materials preferably having an average grain diameter between 10% and 40% by weight ⁇ m and 250 ⁇ m.
- hard materials is understood to mean materials which have sufficient hardness.
- the hard materials can have a Mohs hardness of at least 8, preferably at least 9.
- suitable hard materials are titanium nitride, titanium carbide, silicon nitride, silicon carbide, boron carbide, tungsten carbide, tantalum carbide, aluminum oxide (corundum), zirconium oxide, zirconium nitride or mixtures of these.
- the structured wear protection film can be particularly resistant to abrasion.
- Hard materials in the wear protection base film enable abrasion protection over the entire surface of the structured wear protection film.
- Hard materials in the mouldable lacquer-containing top layer enable abrasion protection of the Structure after hardening of the lacquer-containing top layer. As a result, it can be achieved that the structure becomes less blunted by stress.
- the formable lacquer-containing top layer has a thickness of ⁇ 1 ⁇ m to 5 mm, preferably ⁇ m 10 ⁇ m to 200 ⁇ m, in particular bis 50 ⁇ m to 60 ⁇ m. It can be provided that the lacquer-containing top layer is applied in an application amount of ⁇ 50 g / m 2 to ⁇ 100 g / m 2 , preferably ⁇ 60 g / m 2 to ⁇ 80 g / m 2 , for example 70 g / m 2 , is applied.
- the formable lacquer-containing cover layer has a material curable by electromagnetic radiation, in particular a material curable by UV radiation and / or IR radiation
- a material curable by electromagnetic radiation is understood to mean a material in which a chemical reaction can be set in motion by electromagnetic radiation, whereby the material becomes harder.
- this chemical reaction can be a polymerization or a crosslinking reaction.
- the partial structuring of the lacquer-containing top layer is carried out with a digital printing process by spraying on a displacement ink with an inkjet process.
- the term “spraying on” is understood to mean that a material is applied as an aerosol jet to a substrate in the form of particles and / or drops.
- the term “displacement ink” is understood to mean an ink, for example a liquid, solution or suspension, which when it strikes a moldable material partially displaces it.
- the term “inkjet method” is understood to mean a method in which an ink is applied in a matrix via one or more nozzles.
- the moldable, lacquer-containing cover layer is structured by the impact of the displacement ink.
- the impact of a drop or particle can create depressions such as craters or valleys, at the bottom of which the ink remains. Due to the displacement during the formation of the depression, a wall can also arise around the depression, which represents an elevation.
- the displacement ink consists essentially of an ink composition selected from the group consisting of acrylate-based plastic, polyurethane-modified acrylate plastic, water, organic solvent or mixtures thereof.
- the ink composition comprises an ethoxyethyl acrylate, preferably 2- (2-ethoxyethoxy) ethylene acrylate, preferably in an amount of 20 to 40% by weight, based on the ink composition.
- the ink composition esterifies an ethoxylated polyol with acrylic acid, preferably 1,1,1-trimethylolpropane ethoxylate triacrylate, preferably in an amount of 20 to 40% by weight, based on the ink composition.
- the ink composition has a urethane acrylate, preferably in an amount of 10 to 20% by weight, based on the ink composition.
- the ink composition has pentaerythritol acrylic acid ester, preferably in an amount of ⁇ 5 to 10% by weight, based on the ink composition. It can also be provided that the ink composition has amine-modified acrylic oligomers, in particular reaction products of tripropylene glycol diacrylate with diethylamine, preferably in an amount of von 5 to 10% by weight, based on the ink composition.
- the displacement ink is hardened when the lacquer-containing top layer is hardened and is crosslinked with the lacquer-containing top layer.
- the displacement ink is evaporated when the lacquer-containing top layer is hardened.
- a drop speed, a drop volume and a position of the sprayed displacement ink are varied according to a three-dimensional digital template.
- the drop speed By varying and controlling the drop speed, it can advantageously be achieved that structures with different depths can be produced. In addition, it is achieved that structures with different wall sharpness are generated. It can therefore be varied in particular whether the structure has sharp or blunt edges.
- the drop volume By varying the drop volume, the depth of the structure can also be varied.
- the width of depressions in particular can be varied.
- the position By varying the position, it is possible to set where the depressions and elevations are. As a result, overall control over the structuring is achieved, so that a desired structure can be generated in accordance with a three-dimensional digital template.
- the term “three-dimensional digital template” is understood to mean a template that reproduces a structure in three dimensions, it being possible for the template to be stored, for example, in the form of a CAD model on a digital medium.
- the digital template is generated on the basis of a decoration, the digital template providing complementary depressions and elevations corresponding to the feel of the decoration.
- the curing is carried out with UV radiation with a wavelength in a range from ⁇ 10 nm to 450 nm, preferably from 200 nm to 410 nm.
- the curing is carried out in a first curing step with UV radiation in a range from Supplier 315 nm to 450 nm, preferably 380 nm to 410 nm, and in a second curing step with UV Radiation is carried out in a range from ⁇ 10 nm to ⁇ 250 nm, preferably from ⁇ 170 nm to ⁇ 225 nm.
- the surface is hardened particularly strongly. This also enables a particularly high chemical resistance to be achieved. In addition, it can thereby be achieved that good curing is made possible even without photoinitiators or with only a small amount of photoinitiator. Furthermore, hardening with only a small amount of heat input can thereby be made possible.
- the lacquer-containing top layer is irradiated in the second curing step with UV radiation from a radiation source with a power of 5 to 30 W / cm.
- the volume between the UV radiation source and the lacquer-containing top layer has an inert gas atmosphere.
- an inert gas for example N 2 or a noble gas
- there is essentially no oxygen is exposed to direct UV radiation between the UV radiation source and the top layer containing paint.
- drying can be carried out with particularly short wavelengths. It can be achieved that the UV radiation is absorbed comparatively less. In addition, it can be achieved that the UV radiation does not cause any reactions in the air, such as the reaction to ozone. In addition, undesired surface reactions can be avoided, so that a particularly stable surface is created.
- the hardening begins less than 5 s, preferably less than 2 s, in particular less than 0.5 s, after structuring.
- the moldable, lacquer-containing cover layer is pre-cured prior to structuring.
- the viscosity of the paint-containing top layer can be adapted.
- the structuring can be generated in a particularly true-to-detail manner.
- This can also be understood to mean that hardening is set in motion shortly before structuring, so that during structuring the structures formed achieve a hardness that is sufficient to avoid subsequent deliquescence before final hardening.
- the structuring can be applied directly in synchronism with a decoration.
- the structuring can be aligned directly with the digital printing process in such a way that the structuring is generated synchronously with the decor.
- a “carrier” can in particular be understood to mean a layer serving as a core or as a base layer in a finished panel, which can in particular have a natural material such as a wood material, a fiber material or a material comprising a plastic.
- the carrier can add suitable stability to a panel or contribute to it.
- Wood-based materials within the meaning of the invention are, in addition to solid wood materials, also materials such as, for example, cross-laminated timber, glued laminated timber, rod plywood, veneer plywood, laminated veneer lumber, veneer strips and flexible plywood.
- wood-based materials for the purposes of the invention also include chipboard materials such as chipboard, extruded boards, coarse chipboard (Oriented Structural Board, OSB) and chipboard wood as well as wood fiber materials such as wood fiber insulation boards (HFD), medium-hard and hard fiber boards (MB, HFH), and in particular medium-density Fibreboard (MDF) and to understand high density fibreboard (HDF).
- chipboard materials such as chipboard, extruded boards, coarse chipboard (Oriented Structural Board, OSB) and chipboard wood as well as wood fiber materials such as wood fiber insulation boards (HFD), medium-hard and hard fiber boards (MB, HFH), and in particular medium-density Fibreboard (MDF) and to understand high density fibreboard (HDF).
- Modern wood-based materials such as wood-polymer materials (Wood Plastic Composite, WPC), sandwich panels made of a light core material such as foam, rigid foam or paper honeycomb and a layer of wood applied to it, as well as wood-based chipboard bonded mineral, e.g. with cement, form wood-based materials within the meaning of the invention.
- WPC Wood Plastic Composite
- sandwich panels made of a light core material such as foam, rigid foam or paper honeycomb and a layer of wood applied to it, as well as wood-based chipboard bonded mineral, e.g. with cement, form wood-based materials within the meaning of the invention.
- Cork also represents a wood material in the sense of the invention.
- Plastics that can be used in the production of corresponding panels or the carrier are, for example, thermoplastics such as polyvinyl chloride, polyolefins (e.g. polyethylene (PE), polypropylene (PP), polyamides (PA), polyurethanes (PU), polystyrene (PS)) , Acrylonitrile-butadiene-styrene (ABS), polymethyl methacrylate (PMMA), polycarbonate (PC), polyethylene terephthalate (PET), polyetheretherketone (PEEK) or mixtures or co-polymers of these.
- the plastics can contain conventional fillers, for example calcium carbonate (chalk) Aluminum oxide, silica gel, quartz powder, wood flour, gypsum, etc. They can also be colored in a known manner.
- the carrier can in particular be a web-like carrier or a plate-shaped carrier.
- a “web-like carrier” can be understood to mean a carrier which, for example in its manufacturing process, has a web-like length and thus a length that is significantly greater than its thickness or width and the length of which can be greater than 15 meters, for example.
- a “plate-shaped carrier” can furthermore be understood in the context of the present invention as a carrier which is formed from the web-like carrier by separation and is in the form of a plate. Furthermore, the plate-shaped carrier can already predetermine the shape and / or size of the panel to be produced. However, the plate-shaped carrier can also be provided as a large plate.
- the invention is a carrier whose dimensions exceed the dimensions of the final decorative panels by a multiple and which is divided into a corresponding plurality of decorative panels in the course of the manufacturing process, for example by sawing, laser or water jet cutting.
- the large plate can correspond to the web-shaped carrier.
- a decoration can for example be applied to the carrier, for example by a printing process.
- a suitable printing substrate can also be provided on the carrier.
- the decoration is applied in such a way that, for example, an already printed fiber layer, such as a paper layer, or an already printed film, such as for example made of polyethylene, polypropylene or polyvinyl chloride, is applied to the carrier .
- fiber materials is understood to mean materials such as paper and nonwovens based on vegetable, animal, mineral or artificial fibers, as well as cardboard.
- fiber materials made from vegetable fibers in addition to paper and nonwovens made from cellulose fibers, panels made from biomass such as straw, corn stalks, bamboo, leaves, algae extracts, hemp, cotton or oil palm fibers.
- animal fiber materials are keratin-based materials such as wool or horsehair.
- mineral fiber materials are mineral wool or glass wool.
- the decoration can also be provided with a lacquer-containing layer, which is located between the wear protection base film and the decoration after the wear protection base film has been applied.
- the invention also proposes a structured wear protection film.
- a structured wear protection film is provided, produced according to the method according to the invention, comprising a wear protection base film with a lacquer-containing top layer applied and fixed to at least a portion of the wear protection base foil, the lacquer-containing top layer having structures produced by the digital printing process.
- a wear protection film it can be achieved that a material to be protected is protected from wear.
- the film can already be applied to a material to be protected or it can be present individually.
- the film for example in contrast to an exclusively directly applied wear protection layer, can be applied flexibly to a material to be protected. As a result, such a film can advantageously also be produced independently of the material to be protected.
- the invention also proposes the use of a structured wear protection film according to the invention.
- a structured wear protection film is provided to protect a decorative panel, the decorative panel having a carrier and a decoration on at least a partial area of the carrier and the structured wear protection film being applied to the decoration, the structuring of the lacquer-containing film when the structured wear protection film is applied Cover layer is at least partially aligned synchronously with the decor.
- This means that the structured wear protection film is only applied to a decorative panel after production.
- the at least partially synchronous alignment of the structuring of the wear protection film with respect to the decoration can be implemented, for example, with alignment marks.
- the use according to the invention advantageously means that the production of protected decorative panels has greater flexibility.
- the structured wear protection film according to the invention also prevents the panel from being deformed due to possible shrinkage during the hardening of wear protection layers directly on the panel.
- the invention also proposes a decorative panel with a structured wear protection film.
- a decorative panel with a structured wear protection film having a carrier, with a decoration applied to at least a partial area and a structured wear protection film according to the invention applied to the decoration, and the structures of the structured wear protection film being synchronous with the decoration at least in partial areas.
- a suitable printing substrate can also be provided between the carrier and the decoration.
- the decoration can also be provided with a lacquer-containing layer, which is located between the wear protection film and the decoration.
- the decorative panel is well protected against wear and at the same time has a particularly detailed structuring, the haptic perception of which corresponds to the visual perception of a decor, so that a particularly high-quality overall impression is created.
Landscapes
- Laminated Bodies (AREA)
Description
Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung einer strukturierten Verschleißschutzfolie, eine strukturierte Verschleißschutzfolie, die Verwendung einer strukturierten Verschleißschutzfolie und ein Dekorpaneel mit strukturierter Verschleißschutzfolie.The present invention relates to a method for producing a structured wear protection film, a structured wear protection film, the use of a structured wear protection film and a decorative panel with a structured wear protection film.
Strukturierte Oberflächen zum Verschleiß schutz sind an sich bekannt und werden insbesondere zum Schutz von Dekorpaneelen verwendet werden.Structured surfaces for wear protection are known per se and are used in particular to protect decorative panels.
Die Dokumente
Unter dem Begriff Dekorpaneel sind im Sinne der Erfindung Wand-, Decken, Tür- oder Bodenpaneele zu verstehen, welche ein auf eine Trägerplatte aufgebrachtes Dekor aufweisen. Dekorpaneele werden dabei in vielfältiger Weise sowohl im Bereich des Innenausbaus von Räumen, als auch zur dekorativen Verkleidung von Bauten, beispielsweise im Messebau verwendet. Eine der häufigsten Einsatzbereiche von Dekorpaneelen ist deren Nutzung als Fußbodenbelag, zum Verkleiden von Decken, Wänden oder Türen. Die Dekorpaneele weisen dabei vielfach ein Dekor und eine Oberflächenstrukturierung auf, welche einen Naturwerkstoff imitieren soll.In the context of the invention, the term decorative panel is to be understood as meaning wall, ceiling, door or floor panels which have a decoration applied to a carrier plate. Decorative panels are used in a variety of ways both in the area of interior design of rooms and for the decorative cladding of buildings, for example in trade fair construction. One of the most common areas of application for decorative panels is their use as floor covering, to cover ceilings, walls or doors. The decor panels often have a decor and a surface structure that is intended to imitate a natural material.
Zum Schutz der aufgebrachten Dekorschicht sind in der Regel Verschleiß- oder Deckschichten oberhalb der Dekorschicht aufgebracht. Vielfach ist es vorgesehen, dass in solche Verschleiß- oder Deckschichten eine eine Dekorvorlage imitierende Oberflächenstrukturierung eingebracht ist, so dass die Oberfläche des Dekorpaneels eine haptisch wahrnehmbare Struktur aufweist, welche ihrer Form und ihrem Muster dem aufgebrachten Dekor angepasst ist, um so eine möglichst originalgetreue Nachbildung eines natürlichen Werkstoffes auch hinsichtlich der Haptik zu erhalten.To protect the applied decorative layer, wear or cover layers are generally applied above the decorative layer. In many cases it is provided that a surface structure imitating a decorative template is introduced into such wear or cover layers, so that the surface of the decorative panel has a Has haptically perceptible structure, which is adapted to its shape and pattern of the applied decor in order to obtain a replica of a natural material that is as true to the original as possible, also with regard to the haptics.
Bei dem Ausbilden von strukturierten Verschleißschutzoberflächen mit Lacken wird die Struktur dabei in bekannter Weise durch Prägewerkzeuge eingebracht.When structured wear protection surfaces are formed with lacquers, the structure is introduced in a known manner by means of embossing tools.
Nachteilig an derartigen Verfahren kann es sein, dass insbesondere das Ausbilden von kleinen und lokal begrenzten Strukturen, wie etwa von Poren nur schwer möglich ist. Darüber hinaus kann die genaue Ausrichtung der Prägewerkzeuge relativ zum Dekor Probleme bereiten. Zudem sind Variationen der Struktur nur aufwendig realisierbar und es sind beispielsweise kleine Produktionsserien vergleichsweise unwirtschaftlich, da Prägewerkzeuge für jede Serie hergestellt und ausgetauscht werden müssen. Weiterhin kann nachteilig sein, dass bei einer derartigen Strukturierung erhebliche Kräfte notwendig sein können, weswegen die Strukturierung einen stabilen Untergrund benötigt und deswegen üblicherweise direkt auf dem Dekorpaneel durchgeführt wird. Dadurch können sich insbesondere Einschränkungen in der Prozessführung ergeben.A disadvantage of such methods can be that in particular the formation of small and locally limited structures, such as pores, is only possible with great difficulty. In addition, the exact alignment of the embossing tools relative to the decor can cause problems. In addition, variations in the structure can only be implemented with great effort and, for example, small production series are comparatively uneconomical, since embossing tools have to be manufactured and exchanged for each series. Furthermore, it can be disadvantageous that considerable forces can be necessary with such a structuring, which is why the structuring requires a stable base and is therefore usually carried out directly on the decorative panel. This can result in particular restrictions in process management.
Die Herstellung von strukturierten Oberflächen zum Verschleißschutz kann deswegen unter Umständen noch Verbesserungspotential bieten.The production of structured surfaces for wear protection may therefore still offer potential for improvement.
Es ist daher die Aufgabe der vorliegenden Erfindung, verbesserte Mittel für strukturierte Oberflächen zum Verschleißschutz bereitzustellen, welche die aus dem Stand der Technik bekannten Probleme zumindest teilweise überwinden.It is therefore the object of the present invention to provide improved means for structured surfaces for wear protection which at least partially overcome the problems known from the prior art.
Gelöst wird diese Aufgabe durch ein Verfahren zur Herstellung einer strukturierten Verschleißschutzfolie gemäß Anspruch 1 sowie ferner durch eine strukturierte Verschleißschutzfolie gemäß Anspruch 13, die Verwendung einer Strukturierten Verschleißschutzfolie gemäß Anspruch 14 und ein Dekorpaneel mit strukturierter Verschleißschutzfolie gemäß Anspruch 15. Bevorzugte Ausgestaltungen der Erfindung sind in den abhängigen Ansprüchen angegeben.This object is achieved by a method for producing a structured wear protection film according to claim 1 and also by a structured wear protection film according to claim 13, the use of a structured one Wear protection film according to claim 14 and a decorative panel with structured wear protection film according to claim 15. Preferred embodiments of the invention are given in the dependent claims.
Mit der Erfindung wird ein Verfahren zur Herstellung einer strukturierten Verschleißschutzfolie vorgeschlagen. Das Verfahren weist die Verfahrensschritte auf:
- a. Bereitstellen einer Verschleißschutzgrundfolie,
- b. Aufbringen einer formbaren lackhaltigen Deckschicht auf zumindest einen Teilbereich der Verschleißschutzgrundfolie,
- c. Zumindest teilweises Strukturieren der lackhaltigen Deckschicht mit einem Digitaldruckverfahren zum Erzeugen einer Strukturierung der lackhaltigen Deckschicht, und
- d. Zumindest teilweises Härten der lackhaltigen Deckschicht.
- a. Provision of a wear protection base film,
- b. Applying a formable, lacquer-containing top layer to at least a partial area of the wear protection base film,
- c. At least partial structuring of the lacquer-containing cover layer with a digital printing process to produce a structure for the lacquer-containing cover layer, and
- d. At least partial hardening of the lacquer-containing top layer.
Es hat sich in überraschender Weise gezeigt, dass dann, wenn mit einem Digitaldruckverfahren eine Struktur in einer formbaren lackhaltigen Deckschicht auf einer Verschleißschutzfolie erzeugt wird, eine besonders detailgetreue Strukturierung der Verschleißschutzoberfläche erhalten werden kann. Zudem hat sich gezeigt, dass sich die Struktur auf verschiedene Arten dabei besonders einfach relativ zu einem Dekor ausrichten lässt. Außerdem wird eine wirtschaftliche Herstellung kleiner Serien ermöglicht, da keine Prägewerkzeuge angefertigt werden müssen, und es werden Einschränkungen in der Prozessführung reduziert, da kein besonders stabiler Untergrund erforderlich ist.It has surprisingly been shown that when a structure is produced in a formable, lacquer-containing cover layer on a wear protection film using a digital printing process, a particularly detailed structuring of the wear protection surface can be obtained. In addition, it has been shown that the structure can be aligned particularly easily relative to a decor in various ways. In addition, an economical production of small series is made possible, since no embossing tools have to be made, and restrictions in process management are reduced, since a particularly stable substrate is not required.
Unter dem Begriff "strukturierte Verschleißschutzfolie" ist dabei im Sinne der Erfindung eine Folie zu verstehen, die aufbringbar auf Paneele oder anderen Werkstoff sein kann, haptisch wahrnehmbare Strukturen aufweist und gegen Verschleiß schützt.The term “structured wear protection film” is to be understood in the context of the invention as a film that can be applied to panels or other material, has haptically perceptible structures and protects against wear.
Unter dem Begriff "Verschleißschutzgrundfolie" ist dabei im Sinne der Erfindung eine Folie zu verstehen, die aufbringbar auf Paneele oder anderen Werkstoff sein kann, keine besondere Strukturierung aufweisen muss und als Substrat zur Aufbringung von Strukturen dienen kann.The term "wear protection base film" is to be understood in the context of the invention as a film that can be applied to panels or other material, does not have to have any special structuring and can serve as a substrate for applying structures.
Unter dem Begriff "formbar" ist dabei im Sinne der Erfindung ein Material zu verstehen, welches plastisch verformbar ist, also durch Krafteinwirkung seine Form ändert. Dabei kann das Material beispielsweise flüssig oder fest sein.In the context of the invention, the term “malleable” is to be understood as meaning a material which is plastically deformable, that is to say changes its shape through the action of force. The material can be liquid or solid, for example.
Unter dem Begriff "Digitaldruckverfahren" ist im Sinne der Erfindung ein computergesteuertes Direktdruckverfahren zu verstehen.The term “digital printing process” is to be understood in the context of the invention as a computer-controlled direct printing process.
Unter dem Begriff "Härten" ist dabei im Sinne der Erfindung zu verstehen, dass das formbare Material seine Formbarkeit verliert. Beispielsweise kann ein flüssiges formbares Material verfestigt werden. Ein plastisch verformbarer Feststoff kann sich beispielsweise durch Härten in einen elastisch verformbaren Feststoff umwandeln. Dabei kann bei einem zumindest teilweisen Härten das Material teilweise seine Formbarkeit verlieren, also seine Formbarkeit an bestimmten Stellen verlieren, beispielsweise an der Oberfläche. Es kann außerdem darunter verstanden werden, dass die Formbarkeit nur verringert wird und das Material nicht vollständig unformbar wird. Es kann darunter auch ein vollständiges Härten verstanden werden.In the context of the invention, the term “hardening” is to be understood as meaning that the malleable material loses its malleability. For example, a liquid moldable material can be solidified. A plastically deformable solid can be converted into an elastically deformable solid, for example by hardening. In the event of at least partial hardening, the material can partially lose its malleability, that is to say lose its malleability at certain points, for example on the surface. It can also be understood to mean that the malleability is only reduced and the material does not become completely non-malleable. It can also be understood as complete hardening.
Ein vorbeschriebenes Verfahren zur Herstellung einer Verschleißschutzfolie dient somit insbesondere der verbesserten Herstellung strukturierter Oberflächen zum Verschleißschutz.An above-described method for producing a wear protection film thus serves in particular for the improved production of structured surfaces for wear protection.
Im Detail wird durch das Bereitstellen einer Verschleißschutzgrundfolie ein Substrat bereitgestellt, auf dem eine Strukturierung stattfinden kann. Indem eine formbare lackhaltige Deckschicht auf zumindest einen Teilbereich der Verschleißschutzgrundfolie aufgebracht wird, wird eine strukturierbare Schicht bereitgestellt, die durch die Verschleißschutzgrundfolie gehalten wird und deswegen einfach formbar sein kann und gleichwohl mit der Verschleißschutzgrundfolie durch den Prozess geführt werden kann. Durch das teilweise Strukturieren der lackhaltigen Deckschicht mit einem Digitaldruckverfahren zum Erzeugen einer Strukturierung der lackhaltigen Deckschicht kann eine besonders detailgetreue Strukturierung der lackhaltigen Deckschicht erhalten werden. Da bei dem Digitaldruckverfahren keine Prägewerkzeuge verwendet werden müssen, kann die Verschleißschutzgrundfolie als Substrat ausreichende Stabilität für die Strukturierung ermöglichen. Indem anschließend die nun strukturierte lackhaltige Deckschicht gehärtet wird, wird die eingebrachte Struktur fixiert, so dass sie auch bei Krafteinwirkung im Wesentlichen unverändert bleibt. Im Zusammenspiel der Komponenten ergeben sich somit die obengenannten Vorteile.In detail, the provision of a wear protection base film provides a substrate on which structuring can take place. By applying a moldable, lacquer-containing cover layer to at least a partial area of the wear protection base film, a structurable layer is provided which is held by the wear protection base film and can therefore be easily shaped and nevertheless can be guided through the process with the wear protection base film. The partial structuring of the lacquer-containing top layer with a digital printing process for generating a structure of the lacquer-containing top layer makes it possible to obtain a structuring of the lacquer-containing top layer that is particularly true to detail. Since no embossing tools have to be used in the digital printing process, the wear protection base film as a substrate can provide sufficient stability for the structuring. By subsequently hardening the now structured, lacquer-containing top layer, the introduced structure is fixed so that it remains essentially unchanged even when a force is applied. The above-mentioned advantages result from the interaction of the components.
In einer Ausgestaltung der Erfindung kann zudem vorgesehen sein, dass die Verschleißschutzgrundfolie und/oder die formbare lackhaltige Deckschicht eine Kunststoffzusammensetzung aufweist, bevorzugt eine Acrylat-basierte Kunststoffzusammensetzung, insbesondere eine polyurethanmodifizierte Acrylat-Kunststoffzusammensetzung. Es versteht sich, dass dabei die formbare lackhaltige Deckschicht die Kunststoffzusammensetzung in einer noch ungehärteten Form aufweist, so dass die Deckschicht formbar ist, und dass die Verschleißschutzgrundfolie die Kunststoffzusammensetzung in einer zumindest teilweise gehärteten Form aufweist, so dass sie als Substrat für die formbare lackhaltige Deckschicht dienen kann.In one embodiment of the invention, it can also be provided that the wear protection base film and / or the moldable, lacquer-containing top layer has a plastic composition, preferably an acrylate-based plastic composition, in particular a polyurethane-modified acrylate plastic composition. It goes without saying that the moldable, lacquer-containing top layer has the plastic composition in an as yet uncured form, so that the top layer can be molded, and that the wear protection base film has the plastic composition in an at least partially cured form, so that it can be used as a substrate for the moldable lacquer-containing top layer can serve.
Dadurch wird vorteilhafter Weise erreicht, dass die strukturierte Verschleißschutzfolie insgesamt flexibel ist und gleichzeitig besonders gute Schutzeigenschaften, wie Stabilität, Kratzfestigkeit, Hitzebeständigkeit, Wasserbeständigkeit und dergleichen, aufweist.This advantageously ensures that the structured wear protection film is flexible overall and at the same time has particularly good protective properties, such as stability, scratch resistance, heat resistance, water resistance and the like.
In einer bevorzugten Ausgestaltung der Erfindung kann die Kunststoffzusammensetzung ein Dipropylenglykoldiacrylat, bevorzugt in einer Menge von > 0 bis ≤ 15 Gew.-% bezogen auf die Kunststoffzusammensetzung, und ein Reaktionsprodukt aus Pentaerythrit, Epichlorhydrin und Acrylsäure, bevorzugt in einer Menge von ≥ 2 bis ≤ 15 Gew.-% bezogen auf die Kunststoffzusammensetzung, aufweisen.In a preferred embodiment of the invention, the plastic composition can contain a dipropylene glycol diacrylate, preferably in an amount of> 0 to ≤ 15% by weight based on the plastic composition, and a reaction product of pentaerythritol, epichlorohydrin and acrylic acid, preferably in an amount of ≥ 2 to ≤ 15% by weight based on the plastic composition.
In einer bevorzugten Ausgestaltung der Erfindung kann die Kunststoffzusammensetzung zusätzlich einen Katalysator aufweisen, bevorzugt in einer Menge von ≥ 1 bis ≤ 10 Gew.-% bezogen auf die Kunststoffzusammensetzung. Bevorzugt kann der Katalysator ein tertiäres Ammoniumsalz sein, insbesondere ein tertiäres Ammoniumsalz ausgewählt aus der Gruppe bestehend aus Tetrabutlyammoniumbromid, Methyltrioctylammoniumchlorid, Benzyltriethylammoniumchlorid, Hexadecyltrimethylammoniumbromid und Mischungen davon. In einer besonders bevorzugten Ausgestaltung der Erfindung kann der Katalysator Tetrabutlyammoniumbromid sein.In a preferred embodiment of the invention, the plastic composition can additionally have a catalyst, preferably in an amount of 1 to 10% by weight based on the plastic composition. The catalyst can preferably be a tertiary ammonium salt, in particular a tertiary ammonium salt selected from the group consisting of tetrabutlyammonium bromide, methyltrioctylammonium chloride, benzyltriethylammonium chloride, hexadecyltrimethylammonium bromide and mixtures thereof. In a particularly preferred embodiment of the invention, the catalyst can be tetrabutylammonium bromide.
In einer bevorzugten Ausgestaltung der Erfindung kann die Kunststoffzusammensetzung zusätzlich einen Photoinitiator aufweisen, bevorzugt in einer Menge von ≥ 0,1 bis ≤ 2 Gew.-% bezogen auf die Kunststoffzusammensetzung.In a preferred embodiment of the invention, the plastic composition can additionally have a photoinitiator, preferably in an amount of 0.1 to 2% by weight, based on the plastic composition.
In einer bevorzugten Ausgestaltung der Erfindung kann der Photoinitiator ein Phosphinoxid sein, bevorzugt ein aromatisches Phosphinoxid, insbesondere Phenylbis(2,4,6-trimethylbenzoyl)-Phosphinoxid.In a preferred embodiment of the invention, the photoinitiator can be a phosphine oxide, preferably an aromatic phosphine oxide, in particular phenylbis (2,4,6-trimethylbenzoyl) phosphine oxide.
Es kann insbesondere vorgesehen sein, dass die formbare lackhaltige Deckschicht und die Verschleißschutzgrundfolie beide die gleiche Kunststoffzusammensetzung aufweisen. Dadurch kann erreicht werden, dass die formbare lackhaltige Deckschicht und die Verschleißschutzgrundfolie nach dem Härten der lackhaltigen Deckschicht im Wesentlichen aus dem gleichen Material bestehen. Somit wird beispielsweise der optische Eindruck der strukturierten Verschleißschutzfolie verbessert, da die Verschleißschutzgrundfolie und die lackhaltige Deckschicht nach dem Härten auch die gleichen optischen Eigenschaften aufweisen und somit ungewollte Lichtbrechung zwischen den beiden Schichten vermieden werden kann.In particular, it can be provided that the moldable, lacquer-containing cover layer and the wear protection base film both have the same plastic composition. As a result, it can be achieved that the formable, lacquer-containing cover layer and the wear protection base film consist essentially of the same material after the lacquer-containing cover layer has hardened. Thus, for example, the visual impression of the structured wear protection film is improved, since the wear protection base film and the lacquer-containing top layer also have the same optical properties after curing and thus unwanted light refraction between the two layers can be avoided.
In einer weiteren Ausgestaltung der Erfindung kann vorgesehen sein, dass die Verschleißschutzgrundfolie und/oder die formbare lackhaltige Deckschicht Hartstoffe aufweist, vorzugsweise in einer Menge zwischen 5 Gew.-% und 40% Gew.-%, wobei die Hartstoffe vorzugsweise einen mittleren Korndurchmesser zwischen 10 µm und 250 µm aufweisen.In a further embodiment of the invention it can be provided that the wear protection base film and / or the mouldable lacquer-containing top layer has hard materials, preferably in an amount between 5% by weight and 40% by weight, the hard materials preferably having an average grain diameter between 10% and 40% by weight µm and 250 µm.
Unter dem Begriff "Hartstoffe" werden im Sinne der Erfindung Stoffe verstanden, die eine ausreichende Härte aufweisen. Beispielsweise können die Hartstoffe eine Härte nach Mohs von wenigstens ≥ 8, vorzugsweise wenigstens ≥ 9 aufweisen. Beispiele für geeignete Hartstoffe sind Titannitrid, Titancarbid, Siliciumnitrid, Siliciumcarbid, Borcarbid, Wolframcarbid, Tantalcarbid, Aluminiumoxid (Korund), Zirconiumoxid, Zirconiumnitrid oder Mischungen dieser.In the context of the invention, the term “hard materials” is understood to mean materials which have sufficient hardness. For example, the hard materials can have a Mohs hardness of at least 8, preferably at least 9. Examples of suitable hard materials are titanium nitride, titanium carbide, silicon nitride, silicon carbide, boron carbide, tungsten carbide, tantalum carbide, aluminum oxide (corundum), zirconium oxide, zirconium nitride or mixtures of these.
Dadurch wird vorteilhafter Weise erreicht, dass die strukturierte Verschleißschutzfolie besonders abriebfest sein kann. Hartstoffe in der Verschleißschutzgrundfolie ermöglichen dabei einen Abriebschutz über die gesamte Fläche der strukturierten Verschleißschutzfolie. Hartstoffe in der formbaren lackhaltigen Deckschicht ermöglichen einen Abriebschutz der Struktur nach dem Härten der lackhaltigen Deckschicht. Dadurch kann erreicht werden, dass die Struktur durch Beanspruchung weniger abstumpft.This advantageously means that the structured wear protection film can be particularly resistant to abrasion. Hard materials in the wear protection base film enable abrasion protection over the entire surface of the structured wear protection film. Hard materials in the mouldable lacquer-containing top layer enable abrasion protection of the Structure after hardening of the lacquer-containing top layer. As a result, it can be achieved that the structure becomes less blunted by stress.
In einer weiteren Ausgestaltung der Erfindung kann vorgesehen sein, dass die formbare lackhaltige Deckschicht eine Dicke von ≥ 1 µm bis ≤ 5 mm aufweist, vorzugsweise von ≥ 10 µm bis ≤ 200 µm, insbesondere von ≥ 50 µm bis ≤ 60 µm. Es kann dabei vorgesehen sein, dass die lackhaltige Deckschicht in einer Auftragsmenge von ≥ 50 g/m2 bis ≤ 100 g/m2, vorzugsweise ≥ 60 g/m2 bis ≤ 80 g/m2, beispielsweise 70 g/m2, aufgebracht wird.In a further embodiment of the invention it can be provided that the formable lacquer-containing top layer has a thickness of ≥ 1 µm to 5 mm, preferably µm 10 µm to 200 µm, in particular bis 50 µm to 60 µm. It can be provided that the lacquer-containing top layer is applied in an application amount of ≥ 50 g / m 2 to ≤ 100 g / m 2 , preferably ≥ 60 g / m 2 to ≤ 80 g / m 2 , for example 70 g / m 2 , is applied.
Dadurch wird vorteilhafter Weise erreicht, dass eine ausreichend tiefe Struktur erzeugt werden kann, so dass ein besonders guter haptischer Eindruck erreicht werden kann. Zudem wird vorteilhafterweise erreicht, dass die Härtung ausreichend schnell stattfinden kann, sodass die Struktur nicht durch etwaiges Zerfließen der formbaren Deckschicht verändert wird.This advantageously means that a sufficiently deep structure can be created so that a particularly good haptic impression can be achieved. In addition, it is advantageously achieved that the hardening can take place sufficiently quickly so that the structure is not changed by any deliquescence of the formable cover layer.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass die formbare lackhaltige Deckschicht ein durch elektromagnetische Strahlung härtbares Material aufweist, insbesondere ein durch UV-Strahlung und/oder IR-Strahlung härtbares MaterialIn one embodiment of the invention it can be provided that the formable lacquer-containing cover layer has a material curable by electromagnetic radiation, in particular a material curable by UV radiation and / or IR radiation
Dadurch wird vorteilhafter Weise erreicht, dass die Härtung besonders schnell und örtlich gezielt stattfinden kann. Unter einem durch elektromagnetische Strahlung härtbaren Material wird erfindungsgemäß ein Material verstanden, in dem durch elektromagnetische Strahlung eine chemische Reaktion in Gang gebracht werden kann, wodurch das Material härter wird. Beispielsweise kann diese chemische Reaktion eine Polymerisation oder eine Vernetzungsreaktion sein.This advantageously means that the hardening can take place particularly quickly and in a targeted manner. According to the invention, a material curable by electromagnetic radiation is understood to mean a material in which a chemical reaction can be set in motion by electromagnetic radiation, whereby the material becomes harder. For example, this chemical reaction can be a polymerization or a crosslinking reaction.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass das teilweise Strukturieren der lackhaltigen Deckschicht mit einem Digitaldruckverfahren durch Aufsprühen einer Verdrängungstinte mit einem Tintenstrahl-Verfahren durchgeführt wird.In one embodiment of the invention it can be provided that the partial structuring of the lacquer-containing top layer is carried out with a digital printing process by spraying on a displacement ink with an inkjet process.
Unter dem Begriff "Aufsprühen" wird erfindungsgemäß verstanden, dass ein Material als Aerosolstrahl auf einen Untergrund in Form von Partikeln und/oder Tropfen aufgebracht wird. Unter dem Begriff "Verdrängungstinte" wird erfindungsgemäß eine Tinte verstanden, beispielweise eine Flüssigkeit, Lösung oder Suspension, die beim Auftreffen auf ein formbares Material dieses teilweise verdrängt. Unter dem Begriff "Tintenstrahl-Verfahren" wird erfindungsgemäß ein Verfahren verstanden, in welchem über eine oder mehrere Düsen eine Tinte in einer Matrix aufgetragen wird.According to the invention, the term “spraying on” is understood to mean that a material is applied as an aerosol jet to a substrate in the form of particles and / or drops. According to the invention, the term “displacement ink” is understood to mean an ink, for example a liquid, solution or suspension, which when it strikes a moldable material partially displaces it. According to the invention, the term “inkjet method” is understood to mean a method in which an ink is applied in a matrix via one or more nozzles.
Dadurch wird vorteilhafter Weise erreicht, dass die formbare lackhaltige Deckschicht durch das Auftreffen der Verdrängungstinte strukturiert wird. Es können dabei an den Stellen, an denen die Tinte auftrifft, durch den Aufprall eines Tropfens oder Partikels Vertiefungen wie Krater oder Täler entstehen, an dessen Boden die Tinte verbleibt. Durch die Verdrängung bei der Entstehung der Vertiefung kann zudem ein Wall um die Vertiefung entstehen, der eine Erhöhung darstellt.As a result, it is advantageously achieved that the moldable, lacquer-containing cover layer is structured by the impact of the displacement ink. At the points where the ink hits, the impact of a drop or particle can create depressions such as craters or valleys, at the bottom of which the ink remains. Due to the displacement during the formation of the depression, a wall can also arise around the depression, which represents an elevation.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass die Verdrängungstinte im Wesentlichen aus einer Tintenzusammensetzung besteht ausgewählt aus der Gruppe bestehend aus, Acrylat-basiertem Kunststoff, polyurethanmodifiziertem Acrylat-Kunststoff, Wasser, organischem Lösungsmittel oder Mischungen davon. Dadurch kann vorteilhafter Weise erreicht werden, dass die Verdrängungstinte einerseits gut gesprüht werden kann und andererseits gute Verdrängungseigenschaften aufweist.In one embodiment of the invention it can be provided that the displacement ink consists essentially of an ink composition selected from the group consisting of acrylate-based plastic, polyurethane-modified acrylate plastic, water, organic solvent or mixtures thereof. As a result, it can advantageously be achieved that the displacement ink, on the one hand, can be sprayed well and, on the other hand, has good displacement properties.
In einer bevorzugten Ausgestaltung der Erfindung kann vorgesehen sein, dass die Tintenzusammensetzung ein Ethoxyethylacrylat, vorzugsweise 2-(2-Ethoxyethoxy)-ethylenacrylat, vorzugsweise in einer Menge von ≥ 20 bis ≤ 40 Gew.-%, bezogen auf die Tintenzusammensetzung, aufweist. Zusätzlich kann vorgesehen sein, dass die Tintenzusammensetzung ein ethoxyliertes Polyol verestert mit Acrylsäure, vorzugsweise 1,1,1- Trimethylolpropanethoxylattriacrylat, vorzugsweise in einer Menge von ≥ 20 bis ≤ 40 Gew.-%, bezogen auf die Tintenzusammensetzung, aufweist. Zusätzlich kann vorgesehen sein, dass die Tintenzusammensetzung ein Urethanacrylat, vorzugsweise in einer Menge von ≥ 10 bis ≤ 20 Gew.-%, bezogen auf die Tintenzusammensetzung, aufweist. Zusätzlich kann vorgesehen sein, dass die Tintenzusammensetzung Pentaerythritacrylsäureester, vorzugsweise in einer Menge von ≥ 5 bis ≤ 10 Gew.-%, bezogen auf die Tintenzusammensetzung, aufweist. Außerdem kann vorgesehen sein, dass die Tintenzusammensetzung aminmodifizierte Acryloligomere, insbesondere Reaktionsprodukte von Tripropylenglycoldiacrylat mit Diethylamin, vorzugsweise in einer Menge von ≥ 5 bis ≤ 10 Gew.-%, bezogen auf die Tintenzusammensetzung, aufweist.In a preferred embodiment of the invention it can be provided that the ink composition comprises an ethoxyethyl acrylate, preferably 2- (2-ethoxyethoxy) ethylene acrylate, preferably in an amount of 20 to 40% by weight, based on the ink composition. In addition, it can be provided that the ink composition esterifies an ethoxylated polyol with acrylic acid, preferably 1,1,1-trimethylolpropane ethoxylate triacrylate, preferably in an amount of 20 to 40% by weight, based on the ink composition. In addition, it can be provided that the ink composition has a urethane acrylate, preferably in an amount of 10 to 20% by weight, based on the ink composition. In addition, it can be provided that the ink composition has pentaerythritol acrylic acid ester, preferably in an amount of ≥ 5 to 10% by weight, based on the ink composition. It can also be provided that the ink composition has amine-modified acrylic oligomers, in particular reaction products of tripropylene glycol diacrylate with diethylamine, preferably in an amount of von 5 to 10% by weight, based on the ink composition.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass die Verdrängungstinte beim Härten der lackhaltigen Deckschicht gehärtet und mit der lackhaltigen Deckschicht vernetzt wird.In one embodiment of the invention it can be provided that the displacement ink is hardened when the lacquer-containing top layer is hardened and is crosslinked with the lacquer-containing top layer.
Dadurch wird vorteilhafter Weise erreicht, dass eine besonders stabile Strukturierung erzeugt werden kann, da sich die Verdrängungstinte mit der lackhaltigen Deckschicht verbindet.As a result, it is advantageously achieved that a particularly stable structuring can be produced, since the displacement ink bonds with the lacquer-containing top layer.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass die Verdrängungstinte beim Härten der lackhaltigen Deckschicht verdunstet wird.In one embodiment of the invention it can be provided that the displacement ink is evaporated when the lacquer-containing top layer is hardened.
Dadurch wird vorteilhafter Weise erreicht, dass besonders tiefe Strukturen ermöglicht werden, da die aufgetragene Verdrängungstinte aus den Vertiefungen wieder entfernt wird.As a result, it is advantageously achieved that particularly deep structures are made possible, since the displacing ink applied is removed again from the depressions.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass eine Tropfengeschwindigkeit, ein Tropfenvolumen und eine Position der aufgesprühten Verdrängungstinte nach einer dreidimensionalen digitalen Vorlage variiert werden.In one embodiment of the invention it can be provided that a drop speed, a drop volume and a position of the sprayed displacement ink are varied according to a three-dimensional digital template.
Durch die Variation und Kontrolle der Tropfengeschwindigkeit kann vorteilhafter Weise erreicht werden, dass Strukturen mit unterschiedlicher Tiefe erzeugt werden können. Zudem wird erreicht, dass Strukturen mit unterschiedlicher Wallschärfe erzeugt werden. Es kann also insbesondere variiert werden, ob die Struktur scharfe oder stumpfe Kanten aufweist. Durch die Variation des Tropfenvolumens kann ebenfalls die Tiefe der Struktur variiert werden. Außerdem kann insbesondere die Breite von Vertiefungen variiert werden. Durch die Variation der Position wird eingestellt, wo sich Vertiefungen und Erhöhungen befinden. Dadurch wird insgesamt eine vollständige Kontrolle über die Strukturierung erreicht, so dass eine gewünschte Struktur entsprechend einer dreidimensionalen digitalen Vorlage erzeugt werden kann. Unter dem Begriff "dreidimensionale digitale Vorlage" wird dabei erfindungsgemäß eine Vorlage verstanden, die dreidimensional eine Struktur wiedergibt, wobei die Vorlage beispielsweise in Form eines CAD-Modells auf einem digitalen Medium gespeichert vorliegen kann.By varying and controlling the drop speed, it can advantageously be achieved that structures with different depths can be produced. In addition, it is achieved that structures with different wall sharpness are generated. It can therefore be varied in particular whether the structure has sharp or blunt edges. By varying the drop volume, the depth of the structure can also be varied. In addition, the width of depressions in particular can be varied. By varying the position, it is possible to set where the depressions and elevations are. As a result, overall control over the structuring is achieved, so that a desired structure can be generated in accordance with a three-dimensional digital template. According to the invention, the term “three-dimensional digital template” is understood to mean a template that reproduces a structure in three dimensions, it being possible for the template to be stored, for example, in the form of a CAD model on a digital medium.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass die digitale Vorlage anhand eines Dekors erzeugt wird, wobei die digitale Vorlage der Haptik des Dekors entsprechende komplementäre Vertiefungen und Erhöhungen vorsieht.In one embodiment of the invention it can be provided that the digital template is generated on the basis of a decoration, the digital template providing complementary depressions and elevations corresponding to the feel of the decoration.
Dadurch wird vorteilhafter Weise erreicht, dass die haptische Wahrnehmung der Verschleißschutzfolie mit der optischen Wahrnehmung eines Dekors übereinstimmt, so dass beispielsweise ein Dekorpaneel einen besonders hochwertigen Gesamteindruck macht.This advantageously ensures that the haptic perception of the wear protection film matches the visual perception of a decor, so that, for example, a decor panel makes a particularly high-quality overall impression.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass die Härtung mit UV-Strahlung mit einer Wellenlänge in einem Bereich von ≥ 10 nm bis ≤ 450 nm, vorzugsweise von ≥ 200 nm bis ≤ 410 nm durchgeführt wird.In one embodiment of the invention it can be provided that the curing is carried out with UV radiation with a wavelength in a range from ≥ 10 nm to 450 nm, preferably from 200 nm to 410 nm.
Dadurch wird vorteilhafter Weise eine besonders schnelle und gleichmäßige Härtung erreicht.In this way, particularly rapid and uniform hardening is advantageously achieved.
In einer weiteren Ausgestaltung der Erfindung kann vorgesehen sein, dass die Härtung in einem ersten Härtungsschritt mit UV-Strahlung in einem Bereich von ≥ 315 nm bis ≤ 450 nm, vorzugsweise ≥ 380 nm bis ≤ 410 nm, durchgeführt und in einem zweiten Härtungsschritt mit UV-Strahlung in einem Bereich von ≥ 10 nm bis ≤ 250 nm, vorzugsweise von ≥ 170 nm bis ≤ 225 nm durchgeführt wird.In a further embodiment of the invention it can be provided that the curing is carried out in a first curing step with UV radiation in a range from Bereich 315 nm to 450 nm, preferably 380 nm to 410 nm, and in a second curing step with UV Radiation is carried out in a range from ≥ 10 nm to ≤ 250 nm, preferably from ≥ 170 nm to ≤ 225 nm.
Dadurch kann vorteilhafter Weise erreicht werden, dass die Oberfläche besonders stark gehärtet wird. Dadurch kann auch eine besonders hohe chemische Widerstandsfähigkeit erreicht werden. Zudem kann dadurch erreicht werden, dass eine gute Härtung auch ohne Photoinitiatoren oder mit nur einer geringen Menge von Photoinitiator ermöglicht wird. Weiterhin kann dadurch eine Härtung mit nur geringem Wärmeeintrag ermöglicht werden.As a result, it can advantageously be achieved that the surface is hardened particularly strongly. This also enables a particularly high chemical resistance to be achieved. In addition, it can thereby be achieved that good curing is made possible even without photoinitiators or with only a small amount of photoinitiator. Furthermore, hardening with only a small amount of heat input can thereby be made possible.
In einer weiteren Ausgestaltung der Erfindung kann dabei insbesondere vorgesehen sein, dass die lackhaltige Deckschicht in dem zweiten Härtungsschritt mit UV-Strahlung von einer Strahlungsquelle mit einer Leistung von ≥ 5 bis ≤ 30 W/cm bestrahlt wird.In a further embodiment of the invention, it can be provided in particular that the lacquer-containing top layer is irradiated in the second curing step with UV radiation from a radiation source with a power of 5 to 30 W / cm.
Dadurch kann vorteilhafter weise erreicht werden, dass nur wenig Wärme bei der Härtung in die lackhaltige Deckschicht eingetragen wird. Dadurch können außerdem unerwünschte Verformungen vermieden werden und die lackhaltige Deckschicht kann trotzdem ausreichen gut gehärtet werden.As a result, it can advantageously be achieved that only little heat is introduced into the lacquer-containing top layer during curing. As a result, undesired deformations can also be avoided and the lacquer-containing top layer can nevertheless be sufficiently hardened.
In einer Ausgestaltung der Erfindung kann dabei vorgesehen sein, dass bei der Härtung, insbesondere in dem zweiten Härtungsschritt, das Volumen zwischen der UV-Strahlungsquelle und der lackhaltigen Deckschicht eine Inertgasatmosphäre aufweist. Darunter ist zu verstehen, dass ein Inertgas, beispielsweise N2 oder ein Edelgas, die Luft im Bereich zwischen UV-Strahlungsquelle und lackhaltiger Deckschicht im Wesentlichen verdrängt hat. Insbesondere ist darunter zu verstehen, dass im Wesentlichen kein Sauerstoff der direkten UV-Strahlung zwischen UV-Strahlungsquelle und lackhaltiger Deckschicht ausgesetzt wird.In one embodiment of the invention it can be provided that during curing, in particular in the second curing step, the volume between the UV radiation source and the lacquer-containing top layer has an inert gas atmosphere. This is to be understood as meaning that an inert gas, for example N 2 or a noble gas, has essentially displaced the air in the area between the UV radiation source and the lacquer-containing top layer. In particular, it is to be understood that there is essentially no oxygen is exposed to direct UV radiation between the UV radiation source and the top layer containing paint.
Dadurch kann vorteilhafter Weise erreicht werden, dass mit besonders kurzen Wellenlängen getrocknet werden kann. Es kann dabei erreicht werden, dass die UV-Strahlung vergleichsweise weniger absorbiert wird. Zudem kann dabei erreicht werden, dass die UV-Strahlung keine Reaktionen in der Luft, wie beispielsweise die Reaktion zu Ozon, herbeiführt. Zudem können damit unerwünschte Oberflächenreaktionen vermieden werden, so dass eine besonders stabile Oberfläche entsteht.As a result, it can advantageously be achieved that drying can be carried out with particularly short wavelengths. It can be achieved that the UV radiation is absorbed comparatively less. In addition, it can be achieved that the UV radiation does not cause any reactions in the air, such as the reaction to ozone. In addition, undesired surface reactions can be avoided, so that a particularly stable surface is created.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass die Härtung zeitlich weniger als 5 s, vorzugsweise weniger als 2 s, insbesondere weniger als 0,5 s nach der Strukturierung beginnt.In one embodiment of the invention it can be provided that the hardening begins less than 5 s, preferably less than 2 s, in particular less than 0.5 s, after structuring.
Dadurch wird vorteilhafter Weise erreicht, dass die Strukturierung sich nicht durch ein nachträgliches Zerfließen vor der Härtung verändert.This advantageously ensures that the structuring does not change as a result of subsequent deliquescence prior to hardening.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass vor der Strukturierung die formbare lackhaltige Deckschicht vorgehärtet wird.In one embodiment of the invention, it can be provided that the moldable, lacquer-containing cover layer is pre-cured prior to structuring.
Dadurch wird vorteilhafter Weise erreicht, dass die Viskosität der lackhaltigen Deckschicht angepasst werden kann. So kann erreicht werden, dass die Strukturierung besonders detailgetreu erzeugt werden kann. Darunter kann auch verstanden werden, dass kurz vor der Strukturierung eine Härtung in Gang gesetzt wird, so dass während der Strukturierung die gebildeten Strukturen eine Härte erreichen, die ausreicht, um nachträgliches Zerfließen vor einer abschließenden Härtung zu vermeiden.This advantageously means that the viscosity of the paint-containing top layer can be adapted. In this way it can be achieved that the structuring can be generated in a particularly true-to-detail manner. This can also be understood to mean that hardening is set in motion shortly before structuring, so that during structuring the structures formed achieve a hardness that is sufficient to avoid subsequent deliquescence before final hardening.
In einer Ausgestaltung der Erfindung kann vorgesehen sein, dass das Verfahren zusätzlich die Verfahrensschritte aufweist:
- e. Bereitstellen eines Trägers, aufweisend ein Dekor auf zumindest einem Teilbereich des Trägers, und
- f. Aufbringen der Verschleißschutzgrundfolie auf das Dekor,
- e. Providing a carrier having a decoration on at least a partial area of the carrier, and
- f. applying the wear protection base film to the decor,
Dadurch wird vorteilhafter Weise erreicht, dass die Strukturierung direkt synchron zu einem Dekor aufgebracht werden kann. Beispielsweise kann anhand von Justiermarken die Strukturierung mit dem Digitaldruckverfahren direkt so ausgerichtet werden, dass die Strukturierung synchron zum Dekor erzeugt wird.As a result, it is advantageously achieved that the structuring can be applied directly in synchronism with a decoration. For example, using alignment marks, the structuring can be aligned directly with the digital printing process in such a way that the structuring is generated synchronously with the decor.
Unter einem "Träger" kann insbesondere eine in einem fertig gestellten Paneel als Kern beziehungsweise als Basislage dienende Lage verstanden werden, die insbesondere einen Naturstoff, wie etwa einen Holzwerkstoff, einen Faserwerkstoff oder einen Werkstoff umfassend einen Kunststoff aufweisen kann. Beispielsweise kann der Träger einem Paneel eine geeignete Stabilität verleihen oder zu dieser beitragen.A “carrier” can in particular be understood to mean a layer serving as a core or as a base layer in a finished panel, which can in particular have a natural material such as a wood material, a fiber material or a material comprising a plastic. For example, the carrier can add suitable stability to a panel or contribute to it.
Holzwerkstoffe im Sinne der Erfindung sind dabei neben Vollholzwerkstoffen auch Materialien wie z.B. Brettsperrholz, Brettschichtholz, Stabsperrholz, Furniersperrholz, Furnierschichtholz, Furnierstreifenholz und Biegesperrholz. Darüber hinaus sind unter Holzwerkstoffen im Sinne der Erfindung auch Holzspanwerkstoffe wie z.B. Spanpressplatten, Strangpressplatten, Grobspanplatten (Oriented Structural Board, OSB) und Spanstreifenholz sowie auch Holzfaserwerkstoffe wie z.B. Holzfaserdämmplatten (HFD), mittelharte und harte Faserplatten (MB, HFH), sowie insbesondere mitteldichte Faserplatten (MDF) und hochdichte Faserplatten (HDF) zu verstehen. Auch moderne Holzwerkstoffe wie Holz-Polymer-Werkstoffe (Wood Plastic Composite, WPC), Sandwichplatten aus einem leichten Kernmaterial wie Schaumstoff, Hartschaum oder Papierwaben und einer darauf aufgebrachten Holzschicht, sowie mineralisch, z.B. mit Zement, gebundene Holzspanplatten bilden Holzwerkstoffe im Sinne der Erfindung. Auch Kork stellt dabei einen Holzwerkstoff im Sinne der Erfindung dar.Wood-based materials within the meaning of the invention are, in addition to solid wood materials, also materials such as, for example, cross-laminated timber, glued laminated timber, rod plywood, veneer plywood, laminated veneer lumber, veneer strips and flexible plywood. In addition, wood-based materials for the purposes of the invention also include chipboard materials such as chipboard, extruded boards, coarse chipboard (Oriented Structural Board, OSB) and chipboard wood as well as wood fiber materials such as wood fiber insulation boards (HFD), medium-hard and hard fiber boards (MB, HFH), and in particular medium-density Fibreboard (MDF) and to understand high density fibreboard (HDF). Modern wood-based materials such as wood-polymer materials (Wood Plastic Composite, WPC), sandwich panels made of a light core material such as foam, rigid foam or paper honeycomb and a layer of wood applied to it, as well as wood-based chipboard bonded mineral, e.g. with cement, form wood-based materials within the meaning of the invention. Cork also represents a wood material in the sense of the invention.
Kunststoffe, welche bei der Herstellung entsprechender Paneele beziehungsweise der Träger eingesetzt werden können, sind beispielsweise thermoplastische Kunststoffe, wie Polyvinylchlorid, Polyolefine (beispielsweise Polyethylen (PE), Polypropylen (PP), Polyamide (PA), Polyurethane (PU), Polystyrol (PS), Acrylnitril-Butadien-Styrol (ABS), Polymethylmethacrylat (PMMA), Polycarbonat (PC), Polyethylenterephthalat (PET), Polyetheretherketon (PEEK) oder Mischungen oder Co-Polymerisate dieser. Die Kunststoffe können übliche Füllstoffe enthalten, beispielsweise Kalziumcarbonat (Kreide), Aluminiumoxid, Kieselgel, Quarzmehl, Holzmehl, Gips. Auch können sie in bekannter Weise eingefärbt sein.Plastics that can be used in the production of corresponding panels or the carrier are, for example, thermoplastics such as polyvinyl chloride, polyolefins (e.g. polyethylene (PE), polypropylene (PP), polyamides (PA), polyurethanes (PU), polystyrene (PS)) , Acrylonitrile-butadiene-styrene (ABS), polymethyl methacrylate (PMMA), polycarbonate (PC), polyethylene terephthalate (PET), polyetheretherketone (PEEK) or mixtures or co-polymers of these. The plastics can contain conventional fillers, for example calcium carbonate (chalk) Aluminum oxide, silica gel, quartz powder, wood flour, gypsum, etc. They can also be colored in a known manner.
Der Träger kann dabei insbesondere ein bahnartiger Träger oder plattenförmiger Träger sein. Unter einem "bahnartigen Träger" kann dabei ein Träger verstanden werden, der etwa in seinem Herstellungsprozess eine bahnartige und damit im Vergleich zu seiner Dicke beziehungsweise Breite deutlich größere Länge aufweist und deren Länge beispielsweise größer als 15 Meter betragen kann.The carrier can in particular be a web-like carrier or a plate-shaped carrier. A “web-like carrier” can be understood to mean a carrier which, for example in its manufacturing process, has a web-like length and thus a length that is significantly greater than its thickness or width and the length of which can be greater than 15 meters, for example.
Unter einem "plattenförmigen Träger" kann dabei ferner im Sinne der vorliegenden Erfindung ein Träger verstanden werden, der durch Vereinzelung aus dem bahnartigen Träger geformt ist und in der Form einer Platte ausgebildet ist. Ferner kann der plattenförmige Träger bereits die Form und/oder Größe des herzustellenden Paneels vorgeben. Jedoch kann der plattenförmige Träger auch als Großplatte vorgesehen sein. Eine Großplatte im Sinne der Erfindung ist dabei insbesondere ein Träger, dessen Abmessungen die Abmessungen der letztendlichen Dekorpaneele um ein Mehrfaches überschreiten und welche im Laufe des Herstellungsverfahrens in eine entsprechende Mehrzahl von Dekorpaneelen zerteilt wird, beispielsweise durch Sägen, Laser- oder Wasserstrahlschneiden. Beispielsweise kann die Großplatte dem bahnförmigen Träger entsprechen.A “plate-shaped carrier” can furthermore be understood in the context of the present invention as a carrier which is formed from the web-like carrier by separation and is in the form of a plate. Furthermore, the plate-shaped carrier can already predetermine the shape and / or size of the panel to be produced. However, the plate-shaped carrier can also be provided as a large plate. A big record in the sense of In particular, the invention is a carrier whose dimensions exceed the dimensions of the final decorative panels by a multiple and which is divided into a corresponding plurality of decorative panels in the course of the manufacturing process, for example by sawing, laser or water jet cutting. For example, the large plate can correspond to the web-shaped carrier.
Ein Dekor kann beispielsweise auf den Träger aufgebracht sein, beispielsweise durch ein Druckverfahren. Dabei kann ferner auf dem Träger ein geeigneter Druckuntergrund vorgesehen sein. Alternativ ist es im Sinne der vorliegenden Erfindung nicht ausgeschlossen, dass das Dekor derart aufgebracht ist, dass beispielsweise eine bereits bedruckte Faserschicht, wie beispielsweise Papierschicht, oder auch eine bereits bedruckte Folie, wie beispielsweise aus Polyethylen, Polypropylen oder Polyvinylchlorid, auf den Träger aufgebracht wird.A decoration can for example be applied to the carrier, for example by a printing process. A suitable printing substrate can also be provided on the carrier. Alternatively, within the meaning of the present invention, it is not excluded that the decoration is applied in such a way that, for example, an already printed fiber layer, such as a paper layer, or an already printed film, such as for example made of polyethylene, polypropylene or polyvinyl chloride, is applied to the carrier .
Im Sinne der Erfindung sind unter dem Begriff Faserwerkstoffe Materialien wie z.B. Papier und Vliese auf Basis pflanzlicher, tierischer, mineralischer oder auch künstlicher Fasern zu verstehen, ebenso wie Pappen. Beispiele sind Faserwerkstoffe aus pflanzlichen Fasern sind neben Papieren und Vliesen aus Zellstofffasern Platten aus Biomasse wie Stroh, Maisstroh, Bambus, Laub, Algenextrakte, Hanf, Baumwolle oder Ölpalmenfasern. Beispiele für tierische Faserwerkstoffe sind keratinbasierte Materialien wie z.B. Wolle oder Rosshaar. Beispiele für mineralische Faserwerkstoffe sind Mineralwolle oder Glaswolle.For the purposes of the invention, the term fiber materials is understood to mean materials such as paper and nonwovens based on vegetable, animal, mineral or artificial fibers, as well as cardboard. Examples are fiber materials made from vegetable fibers, in addition to paper and nonwovens made from cellulose fibers, panels made from biomass such as straw, corn stalks, bamboo, leaves, algae extracts, hemp, cotton or oil palm fibers. Examples of animal fiber materials are keratin-based materials such as wool or horsehair. Examples of mineral fiber materials are mineral wool or glass wool.
Das Dekor kann zudem mit einer lackhaltigen Schicht versehen sein, die sich nach Aufbringung der Verschleißschutzgrundfolie zwischen Verschleißschutzgrundfolie und Dekor befindet.The decoration can also be provided with a lacquer-containing layer, which is located between the wear protection base film and the decoration after the wear protection base film has been applied.
Mit der Erfindung wird ferner eine strukturierte Verschleißschutzfolie vorgeschlagen.The invention also proposes a structured wear protection film.
Im Detail ist eine strukturierte Verschleißschutzfolie vorgesehen, hergestellt nach dem erfindungsgemäßen Verfahren, aufweisend eine Verschleißschutzgrundfolie mit einer zumindest auf einen Teilbereich der Verschleißschutzgrundfolie aufgebrachten und fixierten lackhaltigen Deckschicht, wobei die lackhaltige Deckschicht durch das Digitaldruckverfahren erzeugte Strukturen aufweist.In detail, a structured wear protection film is provided, produced according to the method according to the invention, comprising a wear protection base film with a lacquer-containing top layer applied and fixed to at least a portion of the wear protection base foil, the lacquer-containing top layer having structures produced by the digital printing process.
Mit einer derartigen Verschleißschutzfolie kann erreicht werden, dass ein zu schützendes Material vor Verschleiß geschützt wird. Die Folie kann dabei bereits auf ein zu schützendes Material aufgebracht sein oder einzeln vorliegen. Dabei wird vorteilhafter Weise erreicht, dass die Folie, beispielsweise im Gegensatz zu einer ausschließlich direkt aufgebrachten Verschleißschutzschicht, flexibel auf ein zu schützendes Material aufgebracht werden kann. Dadurch kann vorteilhafter Weise eine derartige Folie auch unabhängig von dem zu schützenden Material produziert werden.With such a wear protection film it can be achieved that a material to be protected is protected from wear. The film can already be applied to a material to be protected or it can be present individually. What is advantageously achieved here is that the film, for example in contrast to an exclusively directly applied wear protection layer, can be applied flexibly to a material to be protected. As a result, such a film can advantageously also be produced independently of the material to be protected.
Mit der Erfindung wird ferner die Verwendung einer erfindungsgemäßen strukturierten Verschleißschutzfolie vorgeschlagen. Im Detail ist die Verwendung einer strukturierten Verschleißschutzfolie zum Schutz eines Dekorpaneels vorgesehen, wobei das Dekorpaneel einen Träger und ein Dekor auf zumindest einem Teilbereich des Trägers aufweist und die strukturierte Verschleißschutzfolie auf das Dekor aufgebracht wird, wobei bei dem Aufbringen der strukturierten Verschleißschutzfolie die Strukturierung der lackhaltigen Deckschicht zumindest teilweise synchron zum Dekor ausgerichtet wird. Dies bedeutet, dass die strukturierte Verschleißschutzfolie erst nach der Herstellung auf ein Dekorpaneel aufgebracht wird. Die zumindest teilweise synchrone Ausrichtung der Strukturierung der Verschleißschutzfolie zum Dekor kann dabei beispielsweise mit Justiermarken realisiert werden.The invention also proposes the use of a structured wear protection film according to the invention. In detail, the use of a structured wear protection film is provided to protect a decorative panel, the decorative panel having a carrier and a decoration on at least a partial area of the carrier and the structured wear protection film being applied to the decoration, the structuring of the lacquer-containing film when the structured wear protection film is applied Cover layer is at least partially aligned synchronously with the decor. This means that the structured wear protection film is only applied to a decorative panel after production. The at least partially synchronous alignment of the structuring of the wear protection film with respect to the decoration can be implemented, for example, with alignment marks.
Durch die erfindungsgemäße Verwendung wird vorteilhafter Weise erreicht, dass die Produktion geschützter Dekorpaneele eine größere Flexibilität aufweist. Durch das nachträgliche Aufbringen der erfindungsgemäßen strukturierten Verschleißschutzfolie wird zudem vermieden, dass sich durch mögliches Schrumpfen bei der Härtung von Verschleißschutzschichten direkt auf dem Paneel das Paneel verformt.The use according to the invention advantageously means that the production of protected decorative panels has greater flexibility. By the Subsequent application of the structured wear protection film according to the invention also prevents the panel from being deformed due to possible shrinkage during the hardening of wear protection layers directly on the panel.
Mit der Erfindung wird ferner ein Dekorpaneel mit strukturierter Verschleißschutzfolie vorgeschlagen.The invention also proposes a decorative panel with a structured wear protection film.
Im Detail ist ein Dekorpaneel mit strukturierter Verschleißschutzfolie vorgesehen, wobei das Dekorpaneel einen Träger aufweist, mit einem zumindest auf einen Teilbereich aufgebrachten Dekor und einer auf das Dekor aufgebrachten erfindungsgemäßen strukturierten Verschleißschutzfolie, und wobei die Strukturen der strukturierten Verschleißschutzfolie zumindest in Teilbereichen synchron zum Dekor sind. Dabei kann ferner zwischen dem Träger und dem Dekor ein geeigneter Druckuntergrund vorgesehen sein. Das Dekor kann zudem mit einer lackhaltigen Schicht versehen sein, die sich zwischen Verschleißschutzfolie und Dekor befindet.In detail, a decorative panel with a structured wear protection film is provided, the decorative panel having a carrier, with a decoration applied to at least a partial area and a structured wear protection film according to the invention applied to the decoration, and the structures of the structured wear protection film being synchronous with the decoration at least in partial areas. A suitable printing substrate can also be provided between the carrier and the decoration. The decoration can also be provided with a lacquer-containing layer, which is located between the wear protection film and the decoration.
Dadurch kann erreicht werden, dass das Dekorpaneel gut vor Verschleiß geschützt ist und gleichzeitig eine besonders detailgetreue Strukturierung aufweist, dessen haptische Wahrnehmung mit der optischen Wahrnehmung eines Dekors übereinstimmt, so dass ein besonders hochwertiger Gesamteindruck entsteht.It can thereby be achieved that the decorative panel is well protected against wear and at the same time has a particularly detailed structuring, the haptic perception of which corresponds to the visual perception of a decor, so that a particularly high-quality overall impression is created.
Claims (15)
- Method for producing a structured wear protection film, comprising the process steps:a. providing a wear protection base film;b. applying a moldable lacquer-containing top layer onto at least a partial area of the wear protection base film;c. at least partially structuring the lacquer-containing top layer by use of a digital printing process to create a structure of the lacquer-containing top layer; andd. at least partially curing the lacquer-containing top layer.
- Method according to claim 1, wherein the wear protection base film and/or the moldable, lacquer-containing top layer comprises an acrylate-based plastic composition, in particular a polyurethane-modified acrylate plastic composition.
- Method according to claim 1 or 2, wherein the wear protection base film and/or the moldable lacquer-containing top layer comprises hard materials, preferably in an amount between 5% by weight and 40% by weight, wherein the hard materials preferably have an average grain diameter between 10 µm and 250 µm.
- Method according to any one of the preceding claims, wherein the moldable lacquer-containing top layer has a thickness of ≥ 1 µm to ≤ 5 mm, preferably ≥ 1 µm to ≤ 200 µm, in particular ≥ 1 µm to ≤ 20 µm.
- Method according to any one of the preceding claims, wherein the moldable lacquer-containing top layer comprises a material curable by electromagnetic radiation, in particular a material that is curable by UV radiation and/or IR radiation.
- Method according to any one of the preceding claims, wherein the partial structuring of the lacquer-containing top layer by a digital printing process is carried out by spraying up a displacement ink by use of an inkjet process.
- Method according to claim 6, wherein the displacement ink consists essentially of an ink composition selected from the group consisting of acrylate-based plastic, polyurethane-modified acrylate plastic, water, an organic solvent or mixtures thereof.
- Method according to claim 6 or 7, wherein a drop speed, a drop volume and a position of the sprayed up displacement ink are varied according to a three-dimensional digital template.
- Method according to claim 8, wherein the digital template is produced on the basis of a decoration, wherein the digital template provides complementary depressions and elevations corresponding to the haptic of the decoration.
- Method according to any one of the preceding claims, wherein the curing is carried out with UV radiation with a wavelength in a range from ≥ 10 nm to ≤ 450 nm.
- Method according to any one of the preceding claims, wherein the curing is carried out in a first curing step with UV radiation in a range from ≥ 315 nm to ≤ 450 nm, preferably ≥ 380 nm to ≤ 410 nm, and in a second curing step with UV radiation in a range from ≥ 10 nm to ≤ 250 nm, preferably from ≥ 170 nm to ≤ 225 nm.
- Method according to any one of the preceding claims, additionally comprising the process steps:g. providing a carrier comprising a decoration on at least one partial area of the carrier; andh. applying the wear protection base film onto the decoration,wherein the application of the wear protection base film onto the decoration is carried out prior to the application, structuring and at least partial curing of the lacquer-containing top layer, wherein the structuring of the lacquer-containing top layer is preferably produced at least partially synchronously with the decoration.
- Structured wear protection film produced by the method according to any one of the preceding claims, comprising a wear protection base film which includes a lacquer-containing top layer applied and fixed onto at least a partial area of the wear protection base film, wherein the lacquer-containing top layer comprises structures produced by the digital printing process.
- Use of a structured wear protection film according to claim 13 for protecting a decorative panel, wherein the decorative panel comprises a carrier and a decoration on at least a partial area of the carrier, and wherein the structured wear protection film is applied onto the decoration, and wherein the structuring of the lacquer-containing top layer is aligned at least partially synchronously with the decoration when the structured wear protection film is applied.
- Decorative panel comprising a structured wear protection film, comprising a carrier with a decoration applied onto at least one partial area and a structured wear protection film according to claim 13 applied onto the decoration, wherein the structures of the structured wear protection film are at least in partial areas synchronous with the decoration.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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PL18198350T PL3632700T3 (en) | 2018-10-02 | 2018-10-02 | Digitally printing structured wear protection film |
EP18198350.3A EP3632700B1 (en) | 2018-10-02 | 2018-10-02 | Digitally printing structured wear protection film |
CA3109340A CA3109340C (en) | 2018-10-02 | 2019-06-18 | Digital-printing-structured anti-wear film |
PCT/EP2019/066017 WO2020069779A1 (en) | 2018-10-02 | 2019-06-18 | Digital-printing-structured anti-wear film |
CN201980009420.7A CN111629908B (en) | 2018-10-02 | 2019-06-18 | Abrasion resistant film constructed by digital printing process |
RU2021106702A RU2769650C1 (en) | 2018-10-02 | 2019-06-18 | Wear-resistant protective film structured with digital printing |
US16/959,751 US11014399B2 (en) | 2018-10-02 | 2019-06-18 | Digital-printing-structured anti-wear film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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EP18198350.3A EP3632700B1 (en) | 2018-10-02 | 2018-10-02 | Digitally printing structured wear protection film |
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EP3632700A1 EP3632700A1 (en) | 2020-04-08 |
EP3632700B1 true EP3632700B1 (en) | 2021-06-02 |
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EP18198350.3A Active EP3632700B1 (en) | 2018-10-02 | 2018-10-02 | Digitally printing structured wear protection film |
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US (1) | US11014399B2 (en) |
EP (1) | EP3632700B1 (en) |
CN (1) | CN111629908B (en) |
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PL (1) | PL3632700T3 (en) |
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PT3835079T (en) * | 2019-12-12 | 2023-10-30 | Akzenta Paneele Profile Gmbh | Digital printing structured wear-resistant film with adjustable gloss |
EP3974176B1 (en) * | 2020-09-24 | 2023-08-16 | Akzenta Paneele + Profile GmbH | Wear protection film for decorative panel |
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US5800904A (en) * | 1991-12-27 | 1998-09-01 | Hallman; Robert A. | Embossable surface covering with inorganic wear layer |
EP1796919B2 (en) * | 2004-12-16 | 2016-03-23 | Flooring Industries Limited, SARL | Floor panel imitating a wood pattern on its surface and method for manufacturing |
MX2009005477A (en) * | 2005-11-24 | 2009-10-26 | Kronoplus Technical Ag | Method for printing directly onto boards of wood-based material. |
US8591696B2 (en) * | 2010-11-17 | 2013-11-26 | Pergo (Europe) Ab | Method for manufacturing a surface element |
ES2661954T3 (en) * | 2012-11-07 | 2018-04-04 | Akzenta Paneele + Profile Gmbh | Procedure for the manufacture of a decorated wall or floor panel |
EP2740610B1 (en) | 2012-12-05 | 2017-02-15 | Surface Technologies GmbH & Co. KG | Anti-wear layer with ellipsoidal solid particles |
EP3060400B1 (en) * | 2013-10-23 | 2020-03-11 | Ceraloc Innovation AB | Method of forming a decorative wear resistant layer |
PL3323628T3 (en) * | 2014-02-25 | 2022-10-10 | Akzenta Paneele + Profile Gmbh | Method for producing decorative panels |
WO2016061455A1 (en) * | 2014-10-17 | 2016-04-21 | Sun Chemical Corporation | Decorative printing process |
LU92885B1 (en) * | 2015-11-25 | 2017-06-20 | Tarkett Gdl Sa | Method for producing a resilient floor covering with a printed decorative layer |
PT3315316T (en) * | 2016-10-27 | 2021-02-23 | Akzenta Paneele Profile Gmbh | Method for producing a decorated wall or floor panel |
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- 2018-10-02 EP EP18198350.3A patent/EP3632700B1/en active Active
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CA3109340A1 (en) | 2020-04-09 |
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CA3109340C (en) | 2024-01-23 |
US11014399B2 (en) | 2021-05-25 |
US20200406665A1 (en) | 2020-12-31 |
CN111629908A (en) | 2020-09-04 |
CN111629908B (en) | 2021-10-15 |
PL3632700T3 (en) | 2021-12-20 |
EP3632700A1 (en) | 2020-04-08 |
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