EP3601307A4 - Cross-coupling reaction catalysts, and methods of making and using same - Google Patents

Cross-coupling reaction catalysts, and methods of making and using same Download PDF

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Publication number
EP3601307A4
EP3601307A4 EP18775030.2A EP18775030A EP3601307A4 EP 3601307 A4 EP3601307 A4 EP 3601307A4 EP 18775030 A EP18775030 A EP 18775030A EP 3601307 A4 EP3601307 A4 EP 3601307A4
Authority
EP
European Patent Office
Prior art keywords
making
methods
cross
same
coupling reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP18775030.2A
Other languages
German (de)
French (fr)
Other versions
EP3601307A1 (en
Inventor
Nilay Hazari
Patrick MELVIN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yale University
Original Assignee
Yale University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yale University filed Critical Yale University
Publication of EP3601307A1 publication Critical patent/EP3601307A1/en
Publication of EP3601307A4 publication Critical patent/EP3601307A4/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006Palladium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086Platinum compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04Nickel compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/828Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/847Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
EP18775030.2A 2017-03-28 2018-03-27 Cross-coupling reaction catalysts, and methods of making and using same Pending EP3601307A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762477849P 2017-03-28 2017-03-28
PCT/US2018/024572 WO2018183328A1 (en) 2017-03-28 2018-03-27 Cross-coupling reaction catalysts, and methods of making and using same

Publications (2)

Publication Number Publication Date
EP3601307A1 EP3601307A1 (en) 2020-02-05
EP3601307A4 true EP3601307A4 (en) 2020-12-09

Family

ID=63676926

Family Applications (1)

Application Number Title Priority Date Filing Date
EP18775030.2A Pending EP3601307A4 (en) 2017-03-28 2018-03-27 Cross-coupling reaction catalysts, and methods of making and using same

Country Status (6)

Country Link
US (1) US20200016582A1 (en)
EP (1) EP3601307A4 (en)
JP (1) JP7326156B2 (en)
KR (1) KR102616164B1 (en)
CN (1) CN110662753A (en)
WO (1) WO2018183328A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112403525B (en) * 2020-12-03 2021-12-31 大连理工大学 Preparation method and application of metal organic framework catalyst with ligand molecule internal and external structures
CN115138396B (en) * 2021-03-30 2024-06-14 百济神州(苏州)生物科技有限公司 Catalyst system for Sonogashira coupling reaction and in-situ cyclization reaction
CN114591128B (en) * 2022-02-25 2023-08-22 南京工业大学 Direct cross-coupling method of aryl sulfide salt and aryl bromide

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016057600A1 (en) * 2014-10-08 2016-04-14 Yale University Novel precatalyst scaffolds for cross-coupling reactions, and methods of making and using same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL3154689T3 (en) 2014-06-12 2021-07-12 Johnson Matthey Public Limited Company Complexes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016057600A1 (en) * 2014-10-08 2016-04-14 Yale University Novel precatalyst scaffolds for cross-coupling reactions, and methods of making and using same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATRICK L. HOLLAND ET AL: "Monomeric Cyclopentadienylnickel Methoxo and Amido Complexes: Synthesis, Characterization, Reactivity, and Use for Exploring the Relationship between H-X and M-X Bond Energies", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 119, no. 52, 1 December 1997 (1997-12-01), US, pages 12800 - 12814, XP055743985, ISSN: 0002-7863, DOI: 10.1021/ja971829p *
SUI-SENG CHRISTINE ET AL: "Synthesis and Reactivities of Neutral and Cationic Indenyl-Palladium Complexes", ORGANOMETALLICS, AMERICAN CHEMICAL SOCIETY, vol. 25, no. 3, 21 December 2005 (2005-12-21), pages 571 - 579, XP002779901, ISSN: 0276-7333 *

Also Published As

Publication number Publication date
JP7326156B2 (en) 2023-08-15
JP2020515398A (en) 2020-05-28
EP3601307A1 (en) 2020-02-05
WO2018183328A1 (en) 2018-10-04
CN110662753A (en) 2020-01-07
KR20200013638A (en) 2020-02-07
US20200016582A1 (en) 2020-01-16
KR102616164B1 (en) 2023-12-20

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