EP3596194A1 - Complex capsule-in-capsule detergent - Google Patents
Complex capsule-in-capsule detergentInfo
- Publication number
- EP3596194A1 EP3596194A1 EP18722251.8A EP18722251A EP3596194A1 EP 3596194 A1 EP3596194 A1 EP 3596194A1 EP 18722251 A EP18722251 A EP 18722251A EP 3596194 A1 EP3596194 A1 EP 3596194A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- range
- capsule
- phase
- sodium
- foil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002775 capsule Substances 0.000 title claims abstract description 73
- 239000003599 detergent Substances 0.000 title claims abstract description 44
- 239000011888 foil Substances 0.000 claims abstract description 55
- 239000008384 inner phase Substances 0.000 claims abstract description 44
- 239000008385 outer phase Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 102000004190 Enzymes Human genes 0.000 claims abstract description 25
- 108090000790 Enzymes Proteins 0.000 claims abstract description 25
- 239000012071 phase Substances 0.000 claims abstract description 25
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 23
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 23
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims abstract description 23
- 108010010803 Gelatin Proteins 0.000 claims abstract description 9
- 239000013543 active substance Substances 0.000 claims abstract description 9
- 229920000159 gelatin Polymers 0.000 claims abstract description 9
- 239000008273 gelatin Substances 0.000 claims abstract description 9
- 235000019322 gelatine Nutrition 0.000 claims abstract description 9
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 9
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims abstract description 8
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 claims abstract description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 47
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 39
- 235000019441 ethanol Nutrition 0.000 claims description 37
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 32
- 150000001298 alcohols Chemical class 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 29
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 26
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims description 25
- 229940088598 enzyme Drugs 0.000 claims description 24
- 239000007791 liquid phase Substances 0.000 claims description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 20
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 239000003205 fragrance Substances 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 20
- 239000004382 Amylase Substances 0.000 claims description 18
- 102000013142 Amylases Human genes 0.000 claims description 18
- 108010065511 Amylases Proteins 0.000 claims description 18
- 108091005804 Peptidases Proteins 0.000 claims description 18
- 239000004365 Protease Substances 0.000 claims description 18
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 235000019418 amylase Nutrition 0.000 claims description 18
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 18
- 229960002989 glutamic acid Drugs 0.000 claims description 18
- 229940045872 sodium percarbonate Drugs 0.000 claims description 18
- 239000001509 sodium citrate Substances 0.000 claims description 16
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000000975 dye Substances 0.000 claims description 14
- 235000011187 glycerol Nutrition 0.000 claims description 13
- 229930182470 glycoside Natural products 0.000 claims description 13
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 13
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 230000003287 optical effect Effects 0.000 claims description 12
- 108010059892 Cellulase Proteins 0.000 claims description 11
- 229940106157 cellulase Drugs 0.000 claims description 11
- -1 2-aminoethanol compound Chemical class 0.000 claims description 10
- 108010059820 Polygalacturonase Proteins 0.000 claims description 10
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- 108010093305 exopolygalacturonase Proteins 0.000 claims description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- 159000000000 sodium salts Chemical class 0.000 claims description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 10
- 235000011152 sodium sulphate Nutrition 0.000 claims description 10
- 102100032487 Beta-mannosidase Human genes 0.000 claims description 9
- 108010055059 beta-Mannosidase Proteins 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 9
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 150000002169 ethanolamines Chemical class 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N monoethanolamine hydrochloride Natural products NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 7
- 239000003755 preservative agent Substances 0.000 claims description 6
- 239000004367 Lipase Substances 0.000 claims description 5
- 102000004882 Lipase Human genes 0.000 claims description 5
- 108090001060 Lipase Proteins 0.000 claims description 5
- 239000007963 capsule composition Substances 0.000 claims description 5
- 235000019421 lipase Nutrition 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 230000002335 preservative effect Effects 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 4
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 3
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000007844 bleaching agent Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims 2
- POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 claims 2
- 238000007789 sealing Methods 0.000 abstract 1
- 238000007666 vacuum forming Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 28
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 9
- WQZGKKKJIJFFOK-UHFFFAOYSA-N alpha-D-glucopyranose Natural products OCC1OC(O)C(O)C(O)C1O WQZGKKKJIJFFOK-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- PSYBGEADHLUXCS-UHFFFAOYSA-N Isocil Chemical compound CC(C)N1C(=O)NC(C)=C(Br)C1=O PSYBGEADHLUXCS-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 150000002338 glycosides Chemical class 0.000 description 5
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
Definitions
- the two-phase laundry agents currently available on the market are constructed such that the components are placed in separate chambers which undergo dissolution/activation simultaneously, independently of each other.
- the delay in adding the enzymes to wash causes that the enzymes released from the inner phase start affecting the articles which were already wetted with the detergent base. Due to this fact, the enzymes function significantly better.
- a process of producing the complex detergent comprises producing an inner phase comprising enzymes or percarbonate and TAED, or another component in a liquid form or a solid form, e.g. powder or granules.
- an inner phase comprising enzymes or percarbonate and TAED, or another component in a liquid form or a solid form, e.g. powder or granules.
- a membrane element for said inner phase a PVOH foil or other material which dissolves in contact with water is used.
- the time of dissolution of the smaller inner phase is delayed in relation to the time of dissolution of the outer phase by means of using a proper thickness of coating of the smaller capsule.
- the thicker the capsule coating the longer the dissolution time.
- Example 1 is presented ranges of mass concentrations of the used components of the individual phases of the complex detergent as well as examples of carrying out the invention.
- a method of producing a capsule-in-capsule (PEG + granulated enzymes)
- a method of producing a multicompartment capsule-in-capsule comprising one or more inner compartments and one outer compartment, wherein the outer compartment surrounds 100% of the outer surface of the inner compartment(s), completely surrounded with at least one layer which dissolves in contact with water, characterized in that it comprises the stages of:
- a method of producing a multicompartment capsule-in-capsule comprising one or more inner compartments and one outer compartment, wherein the outer compartment surrounds 100% of the outer surface of the inner compartment(s), completely surrounded with at least one layer which dissolves in contact with water, characterized in that it comprises the stages of:
- a complex capsule-in-capsule detergent was obtained according to Example 1
- a complex capsule-in-.capsule detergent was obtained according to Example Outer liquid phase
- a complex capsule-in-capsule detergent was obtained according to Example 3 Outer powder phase
- a complex capsule-in-capsule detergent was obtained according to Example 4 Outer powder phase
- a complex capsule-in-capsule detergent was obtained according to Example 1
- a complex capsule-in-capsule detergent was obtained according to Example 2
- a complex capsule-in-capsule detergent was obtained according to Example 4 Outer phase/powder Content [%]
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Zoology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL420843A PL420843A1 (en) | 2017-03-14 | 2017-03-14 | Complex detergent of a capsule-in-capsule type |
PCT/PL2018/000025 WO2018169421A1 (en) | 2017-03-14 | 2018-03-13 | Complex capsule-in-capsule detergent |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3596194A1 true EP3596194A1 (en) | 2020-01-22 |
EP3596194B1 EP3596194B1 (en) | 2024-02-21 |
Family
ID=62111161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18722251.8A Active EP3596194B1 (en) | 2017-03-14 | 2018-03-13 | Complex capsule-in-capsule detergent |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP3596194B1 (en) |
PL (1) | PL420843A1 (en) |
PT (1) | PT3596194T (en) |
WO (1) | WO2018169421A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11659838B2 (en) | 2021-04-01 | 2023-05-30 | Sterilex, Llc | Quat-free powdered disinfectant/sanitizer |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB202003424D0 (en) * | 2020-03-10 | 2020-04-22 | Reckitt Benckiser Calgon Bv | Composition for the removal and prevention of deposition of limescale |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10104841A1 (en) * | 2001-02-01 | 2002-09-12 | Henkel Kgaa | Capsule-in-capsule system and method for its production |
GB0305666D0 (en) * | 2003-03-12 | 2003-04-16 | Unilever Plc | A water soluble delivery product |
EP2924105A1 (en) * | 2014-03-28 | 2015-09-30 | The Procter and Gamble Company | Water soluble unit dose article |
HUE050461T2 (en) * | 2016-05-23 | 2020-12-28 | Procter & Gamble | Detergent composition comprising an encapsulated enzyme |
-
2017
- 2017-03-14 PL PL420843A patent/PL420843A1/en unknown
-
2018
- 2018-03-13 WO PCT/PL2018/000025 patent/WO2018169421A1/en unknown
- 2018-03-13 PT PT187222518T patent/PT3596194T/en unknown
- 2018-03-13 EP EP18722251.8A patent/EP3596194B1/en active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11659838B2 (en) | 2021-04-01 | 2023-05-30 | Sterilex, Llc | Quat-free powdered disinfectant/sanitizer |
Also Published As
Publication number | Publication date |
---|---|
WO2018169421A1 (en) | 2018-09-20 |
PT3596194T (en) | 2024-03-25 |
PL420843A1 (en) | 2018-09-24 |
EP3596194B1 (en) | 2024-02-21 |
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