EP3587664A1 - Fabric for paper machines or cellulose dewatering machines, use of the same and use of monofilaments comprising or consisting of a partially aromatic polyamide for producing fabrics for paper machines or cellulose dewatering machines - Google Patents
Fabric for paper machines or cellulose dewatering machines, use of the same and use of monofilaments comprising or consisting of a partially aromatic polyamide for producing fabrics for paper machines or cellulose dewatering machines Download PDFInfo
- Publication number
- EP3587664A1 EP3587664A1 EP19175689.9A EP19175689A EP3587664A1 EP 3587664 A1 EP3587664 A1 EP 3587664A1 EP 19175689 A EP19175689 A EP 19175689A EP 3587664 A1 EP3587664 A1 EP 3587664A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- threads
- covering
- monofilaments
- paper
- partially aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006012 semi-aromatic polyamide Polymers 0.000 title claims abstract description 21
- 239000004744 fabric Substances 0.000 title claims description 93
- 229920002678 cellulose Polymers 0.000 title description 7
- 239000001913 cellulose Substances 0.000 title description 7
- 229920006024 semi-aromatic copolyamide Polymers 0.000 claims description 25
- 229920006117 poly(hexamethylene terephthalamide)-co- polycaprolactam Polymers 0.000 claims description 18
- 125000003118 aryl group Chemical group 0.000 claims description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 6
- 229920006017 homo-polyamide Polymers 0.000 claims description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 150000003951 lactams Chemical class 0.000 claims 1
- 239000010410 layer Substances 0.000 description 49
- 238000005299 abrasion Methods 0.000 description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 description 10
- 239000005020 polyethylene terephthalate Substances 0.000 description 10
- 230000008901 benefit Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004952 Polyamide Substances 0.000 description 5
- 239000004734 Polyphenylene sulfide Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 229920002647 polyamide Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920000069 polyphenylene sulfide Polymers 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 229920006018 co-polyamide Polymers 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- -1 polyethylene terephthalate Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 239000004760 aramid Substances 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 239000004954 Polyphthalamide Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229920003469 Ultramid® T Polymers 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920000140 heteropolymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 1
- 229920000889 poly(m-phenylene isophthalamide) Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920006375 polyphtalamide Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/48—Suction apparatus
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/0027—Screen-cloths
- D21F1/0036—Multi-layer screen-cloths
- D21F1/0045—Triple layer fabrics
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D11/00—Double or multi-ply fabrics not otherwise provided for
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/58—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads characterised by the coefficients of friction
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/0027—Screen-cloths
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/0027—Screen-cloths
- D21F1/0036—Multi-layer screen-cloths
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/10—Wire-cloths
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F7/00—Other details of machines for making continuous webs of paper
- D21F7/08—Felts
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F7/00—Other details of machines for making continuous webs of paper
- D21F7/08—Felts
- D21F7/083—Multi-layer felts
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F7/00—Other details of machines for making continuous webs of paper
- D21F7/08—Felts
- D21F7/086—Substantially impermeable for transferring fibrous webs
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/006—Making patterned paper
Definitions
- the invention relates to a covering for paper machines or pulp dewatering machines and the use of such.
- Large paper machines usually consist of three so-called lots, namely a forming section, a press section and a dryer section when viewed in the direction of the paper web.
- the forming section is used to form the paper web from the paper pulp and a first mechanical dewatering of the paper web thus formed.
- the press section the paper web is passed between press rollers, in which it is exposed to high pressures and is thereby further mechanically dewatered.
- the paper web is then fed to the dryer section, in which the paper web is guided over heated drying cylinders, as a result of which the paper web is thermally dewatered.
- the paper web is guided through the paper machine by means of belts which are adapted to the requirements of the respective lot and against which the paper web lies and which also serve to transfer the paper web from one lot to the next.
- So-called forming fabrics are used in the forming section. Examples of such and their guidance through a paper machine go from the EP 2 067 895 B1 and the state of the art discussed therein. Press felts are used in the press section, for which examples the EP 1 452 639 B1 can be removed. So-called dryer fabrics are used in the dryer section, which are designed in particular as dry fabrics consisting of warp and weft threads. Examples of such dryer fabrics and for guiding the dryer fabrics through the dryer section of a paper machine can be the EP 1 002 155 B1 . EP 1 507 041 B1 . EP 1 558 807 B1 . EP 1 857 588 A1 and EP 1 054 097 B1 be removed.
- transfer belts can be used, which transfer the paper web through one or more presses pass the press section together with the associated press felt and, after detaching the press felt, guide it from the paper web to a point where the paper web is usually detached from the transfer belt with the aid of a suction roller and taken over by a dryer fabric circulating in the dryer section.
- Examples of the guidance of transfer belts in the press section of a paper machine are, in particular Figures 1 to 3 the EP 0 576 115 A1 refer to.
- threads made of polyamide are used in paper machine clothing.
- a transfer belt for paper machines which has a carrier fabric with weft threads made from aromatic polyamide.
- This material is distinguished by a comparatively low degree of water absorption, as a result of which an increase in the expansion of the tape in the width direction can be reduced on account of the high water absorption of a paper-side nonwoven fabric made of hydrophilic fibers.
- the US 2006/0275604 A1 discloses a paper machine felt with yarns, fibers or filaments that have polyamide and / or polyester in their polymer matrix, thereby ensuring a comparatively high abrasion resistance.
- a covering for paper or pulp dewatering machines comprising or consisting of monofilaments comprising or consisting of a partially aromatic polyamide.
- partially aromatic polyamide can be used to obtain monofilaments, the use of which in fabrics for paper or pulp dewatering machines leads to a combination of excellent product properties.
- the monofilaments of the covering according to the invention consist of or comprise a partially aromatic copolyamide, which has proven to be very particularly suitable.
- at least some of the monofilaments of the covering according to the invention consist of or comprise a partially aromatic homo-polyamide.
- at least part of the Monofilaments consists of a combination of partially aromatic homo- and partially aromatic copolyamide or comprises such a combination.
- a partially aromatic copolyamide is one which has both aromatic and aliphatic components, as is the case for PA6T / 6, for example, which comes from the range offered by the manufacturer BASF under the brand name Ultramid® T.
- PA6T / 6 for example, which comes from the range offered by the manufacturer BASF under the brand name Ultramid® T.
- the material is easier to process than is the case for aromatic polyamides which contain only aromatic components.
- monofilaments can be spun from partially aromatic copolyamide, which are characterized in particular by low water absorption, high dimensional stability, high thermal and mechanical strength, high abrasion resistance and good processability, and to optimize their use in fabrics of the type mentioned Results with comparable moderate costs.
- the fabrics according to the invention are distinguished on the one hand by a slight (water-related) change in shape, since the monofilaments made from partially aromatic copolyamide absorb water only to a comparatively small and significantly slower extent and thus have a shape-stabilizing effect. Furthermore, using these monofilaments, due to the high mechanical stability, there is only a slight flattening at offset points of the fabric. As a result, a problem known to the applicant in the case of coverings of a conventional type, especially sieving with monofilaments made of PET-TPU and in particular on the machine side, is reliably avoided. Furthermore, it has been shown that the monofilaments made from partially aromatic copolyamide are characterized by a particularly good positioning relative to the other threads in the fabric in a covering. They also have a high load capacity compared to cleaning units, such as high-pressure spray pipes, and excellent chemical resistance. It continues to be a particularly low one Abrasion is guaranteed, which offers a considerable advantage, particularly on the machine side, of a covering.
- monofilaments made from partially aromatic copolyamide can also be an excellent alternative to filaments made from PET and, above all, a significantly cheaper alternative to threads made from polyphenylene sulfide (PPS) in particular form in dryer fabrics.
- PPS polyphenylene sulfide
- Further advantageous properties of partially aromatic copolyamide are a comparatively high glass transition temperature, a comparatively high melting point, in particular of about 295 ° C., constant mechanical properties, high strength and rigidity, very good toughness, good spring properties.
- the monofilaments which can be used in the context of the present invention can, for example, consist of a material or comprise such a material as is shown in FIG EP 2 860 220 A1 or in the EP 2 857 456 A1 is disclosed, the content of which is hereby incorporated by reference.
- These documents show, in particular, an impact-modified polyamide molding compound made from partially aromatic copolyamide, for example PA6T / 6, and an olefinic copolymer for adjusting the impact strength, which can be used to obtain the covering according to the invention.
- plastic threads made of partially aromatic polyamide, in particular copolyamide, formed as monofilaments form part of a covering for a paper machine or cellulose dewatering machine.
- copolyamide of known dimensions is a co-polymer (also known as a heteropolymer), that is to say a polymer which is composed of two or more monomers.
- the counterpart to copolymers are also known dimensions, homopolymers, which are polymers which are composed of only one type of monomer.
- PA6 polyamide 6
- PA6.6 polyamide 6.6
- PA6.10 polyamide 6.10
- aromatic homo-polyamides such as polyaramide poly (m-phenylene isophthalamide), which likewise do not fall into the group of partially aromatic copolyamides.
- a covering has in particular longitudinal threads extending in a running direction and transverse threads extending transversely thereto, which then some or all of them can be given by monofilaments made of or with partially aromatic polyamide, in particular partially aromatic copolyamide. At least part of the transverse threads is preferably given by monofilaments made of such a material, for example PA6T / 6.
- the longitudinal threads which are primarily the force-absorbing threads, can be made of polyester, as is known from conventional coverings, which is characterized by an even higher tensile strength. Of course, however, these can also consist at least in part of partially aromatic polyamide, in particular copolyamide.
- all threads of a covering are formed by these monofilaments. This can be particularly advantageous, in particular, in the event that the covering according to the invention is designed as a press felt or also a dryer fabric and is used.
- the covering according to the invention has only one fabric layer or also a plurality of fabric layers. If several layers are present, only one of the layers can have monofilaments with or made from partially aromatic polyamide, in particular copolyamide, or this applies to several, if necessary all, layers of the covering, the individual layer (s) again only partially or can be formed entirely from monofilaments of this material. Is z. If, for example, a machine-side fabric layer is provided, it is preferred that at least the machine-side fabric layer comprises or consists of monofilaments with or made from a partially aromatic polyamide, in particular copolyamide. Then a particularly high abrasion resistance is ensured, especially on the particularly stressed machine side.
- the machine-side fabric layer has longitudinal threads extending in a running direction and transverse threads extending transversely to the longitudinal threads, it is preferably provided that at least some of the cross-threads of the machine-side fabric layer are monofilaments made from a partially aromatic polyamide, in particular copolyamide.
- the covering according to the invention can be designed, for example, as a forming fabric or a drying fabric and can be used in this function in particular in a paper machine. It is also possible that the covering according to the invention is designed as a press felt or transfer belt and is used accordingly. It should be noted that the structure of the fabric according to the invention is identical to that of a corresponding type of fabric known from the prior art, and the only difference may be that at least part of the fabric is covered by monofilaments with or made from partially aromatic polyamide, in particular Co Polyamide is formed.
- the partially aromatic copolyamide used in particular is preferably one which is characterized by a base of hexamethylenediamine and terephthalic acid and caprolactam.
- the PA6T / 6 already mentioned is particularly preferably used.
- Another object of the invention is the use of a fabric according to the invention in a paper machine or pulp dewatering machine.
- the invention preferably relates to the use of monofilaments with or made from partially aromatic polyamide, in particular copolyamide PA6T / 6, for the production of fabrics for paper machines or cellulose dewatering machines.
- the Figure 1 shows in a cross section - that is transverse to the intended direction of travel - a section of a first embodiment of a fabric according to the invention in a schematic representation, which is given specifically by a forming wire 1 for use in the forming area of a paper machine.
- the forming fabric 1 is a double-layer fabric with an upper, paper-side fabric layer 2 and a lower, machine-side fabric layer 3.
- Both fabric layers 2, 3 comprise longitudinal or warp threads - which are exemplified in the figure with 4 and 5, respectively - In the thread count ratio of 1: 1, wherein a longitudinal thread 4 of the paper-side fabric layer 2 is arranged exactly above a longitudinal thread 5 in the machine-side fabric layer 3.
- the longitudinal threads 4, 5 thus lie one above the other in pairs.
- the diameter of the longitudinal threads 4 in the paper layer 2 is 0.11 mm and the diameter of the longitudinal threads 5 in the machine layer 3 is 0.18 mm. They consist of polyethylene terephthalate (PET). The number of longitudinal threads is 58 per cm in the transverse direction.
- paper-side transverse or weft threads 6, 7 are integrated with the longitudinal threads 4 to form a plain weave. At right angles to the plane of the drawing, adjacent to each other paper-side transverse threads 6, 7 on top of each other.
- the cross threads 6, 7 on the paper side are made of polyethylene terephthalate (PET) and they have a diameter of 0.11 mm.
- Machine-side transverse threads 8 are integrated exclusively into the machine-side longitudinal threads 5, of which only one can be seen in the figure.
- the machine-side transverse threads 8 each form floats going over five longitudinal threads 5 - designated by way of example with 9 - on the machine side of the forming fabric 1 and then bind each with a single machine-side longitudinal thread 5.
- the machine-side floats 9 represent abrasion material to protect the machine-side longitudinal threads 5, which are subject to high tensile stress.
- the diameter of the machine-side transverse threads 8 is 0.22 mm.
- the machine-side transverse threads 8 are given by monofilaments made from partially aromatic copolyamide, specifically PA6T / 6. A section of the polymer chain of PA6T / 6 can be Figure 9 be removed. It should be emphasized that the proportions and the order shown therein can vary.
- the fabric layers 2, 3 are connected by pairs of two binding transverse threads 10, 11 each lying side by side in the longitudinal direction. They have a diameter of 0.11 mm and are made of PET. They bind in the paper-side fabric layer 2 one after the other alternately on the top and bottom with paper-side longitudinal threads 4, then run between the two fabric layers 2, 3 over three longitudinal threads 4 and 5 and then bind with a single longitudinal thread 5 in the machine-side fabric layer 3, before floating again between the two fabric layers 2 and 3.
- the paired binding transverse threads 10 and 11 each have the same weave repeat, but are shifted relative to one another in the transverse direction - ie in their longitudinal direction - in such a way that the weave patterns in the paper-side fabric layer 2 complement one another so that they together form a canvas pattern there form analogously to the paper-side transverse threads 6, 7. In this way, an almost uniform canvas pattern is created on the paper side of the forming wire 1, which provides a high fiber retention.
- the longitudinal thread filling degree of the paper-side fabric layer 2 is 31%, the total filling degree of paper-side and machine-side longitudinal threads 4, 5 82%.
- the number of cross threads is 108 per cm in the longitudinal direction of the forming fabric 1. This creates a high degree of openness and thus a good drainage effect despite high fiber retention.
- the forming fabric 1 corresponds to that which in the single figure also goes back to the applicant EP 2 067 895 B1 is shown and its advantages are explained in more detail therein.
- the monofilaments of this type due to the low water absorption of the monofilaments of this type, it is characterized by a slight change in shape, due to the high mechanical stability there is at most a slight flattening at offset points, and the monofilaments are well positioned relative to the remaining threads in the fabric (" Stacking "), there is a high load-bearing capacity compared to cleaning units such as high-pressure spray pipes and there is a particularly high abrasion resistance of the monofilaments, so there is at most little abrasion on the roll side. Due to the high dimensional stability, the disadvantageous occurrence of "edge curling" is completely avoided or at least greatly reduced.
- the Figure 2 shows in a cross section a section of a second embodiment of a fabric according to the invention, which is also designed as a forming screen 12 for a paper machine and the structure of which in Figure 1 who also goes back to the applicant EP 2 899 311 B1 forming fabric shown is the same.
- the forming fabric 12 Figure 2 is also multi-layer, specifically comprises a paper layer and a machine-side fabric layer 13, 14.
- the paper-side fabric layer 13 has paper-side longitudinal threads - in the Figure 2 designated 15 by way of example - which extend in the running direction of the screen 12, as well as transverse transverse threads 16, 17 oriented to the paper, both of which have a round cross section.
- the paper-side transverse threads comprise transverse binding threads 16 and transverse threads 17 which do not form any transverse binding threads. These two types of threads 16, 17 alternate in the direction of the paper-side longitudinal threads 15.
- the paper-side transverse threads 16, 17 are in principle woven in a plain weave.
- the machine-side fabric layer 14 consists of machine-side longitudinal threads - designated 18 by way of example - and machine-side transverse threads 19, of which in the Figure 2 only one is recognizable.
- the machine-side transverse threads 19 run in such a way that they form floats 20 on the machine side, which each run under five adjacent longitudinal threads 18 on the machine side. Between the floats 20, the machine-side transverse threads 19 bind a machine-side longitudinal thread 18 in a crank 21. Both the machine-side transverse threads 19 and the machine-side longitudinal threads 18 each have a circular cross section.
- the ratio of the paper-side longitudinal threads 15 and the machine-side longitudinal threads 18 is again 1: 1.
- the transverse binding thread 16 binds with a paper-side longitudinal thread 15a, by running over its paper side, then from the paper-side fabric layer 13 to the machine-side fabric layer 14 through an almost vertical course, that is to say in the thickness direction of the screen 12, and with the machine-side fabric layer 14 binds with two adjacent longitudinal threads 18a and 18b by overlapping them on the machine side.
- the two machine-side longitudinal threads 18a, 18b lie next to the offset 21.
- the transverse binding thread 16 then runs back to the paper-side fabric layer 13 and binds with a paper-side longitudinal thread 15b.
- the paper-side longitudinal threads 15a, 5b are separated from one another only by a paper-side longitudinal thread 15c.
- the Figure 2 shows only one binding point 22.
- the number of binding points 22 can be selected depending on the requirement of a sufficiently strong connection of the two fabric layers 13, 14. Further explanations, including the advantages of the specific structure of the forming fabric 12, can be found in the EP 2 899 311 B1 be removed.
- the machine-side transverse threads 19 are - just like in the first exemplary embodiment - given by monofilaments made of partially aromatic copolyamide, specifically PA6T / 6, whereby the same advantages compared to the previously known embodiment are achieved, which already apply to the first embodiment Figure 1 have been explained.
- FIG 3 shows a third embodiment of a covering according to the invention, specifically a schematically illustrated wet press felt 23, which is intended for use in the press section of a paper machine.
- the carrier 24 can be seen from the wet press felt 23.
- the fiber layers embedding the carrier 24 are omitted.
- the carrier 24 is only partially shown here. He sits in shape to the left of a lying U - in Figure 3 indicated by dashed lines - away, so that the carrier 24 overall represents a lying U.
- the extent of the U is adapted to the respective installation conditions in the paper machine.
- the structure of the wet press felt 23 is the same as that in FIGS Figures 1 and 2 who also goes back to the applicant EP 1 452 639 B1 shown wet press felt.
- the carrier 24 consists of an inner carrier layer 25 and an outer carrier layer 26. Both carrier layers 25, 26 are designed as fabrics which are produced in a continuous weaving process by circular weaving.
- the fabrics have transverse threads - designated by way of example 27 or 28 - which formed the warp threads during the weaving process, and longitudinal threads 29, 30 as weft threads.
- the longitudinal threads 29, 30 are parts of a single continuous thread due to their property as weft threads.
- the transverse threads 27, 28 bind with the longitudinal threads 29, 30 in such a way that the two carrier layers 25, 26 have no connection to one another via the surface, i.e. the transverse threads 27 do not bind into the carrier layer 26 and the transverse threads 28 do not bind into the carrier layer 25 and the longitudinal threads 29, 30 remain in the respective carrier layer 25 or 26 over the entire length of the carrier 24.
- every second longitudinal thread 29, 30 forms seam loops 33, 34 which protrude beyond the ends 31, 32. This results in a plurality of seam loops 33, 34 perpendicular to the plane of the drawing (see reference numbers 17 and 19 in Figure 2 the WO 00/09802 and the reference numerals 20 and 22 in the Figures 2 to 5 the US 5,015,220 ).
- the longitudinal threads 29, 30, which each run between two longitudinal threads 29, 30 forming seam loops 33, 34, are led back in a short way without forming seam loops.
- One row of seam loops 33 is connected to the other row of seam loops 34 - as shown - have been brought into a comb-like overlap so that a push-through channel 35 is formed perpendicular to the plane of the drawing.
- a plug wire 36 By pushing a plug wire 36 through the push-through channel 35, the seam loops 33, 34 and thus the ends 31, 32 of the carrier 24 are coupled to one another, so that an endless carrier 24 and thus also an endless wet press felt 23 is created.
- the coupling takes place after the wet press felt 23 has been drawn into the press section of the paper machine.
- the binding transverse threads 37, 38, 39, 40 are shown reinforced in order to make their course clear compared to the course of the other transverse threads 27, 28. While the other transverse threads 27, 28 bind with the longitudinal threads 29, 30 in a plain weave each exclusively in the carrier layer 25 or the carrier layer 26, the binding transverse threads 37, 38, 39, 40 run in such a way that they alternately bind in both carrier layers 25, 26 , in each case by a longitudinal thread 29 in one carrier layer 25 and - offset by two longitudinal threads 29, 30 - by a longitudinal thread 30 in the other carrier layer 26. Through this course of the binding transverse threads 37, 38, 39, 40, the seam loops 33, 34 closed on the carrier side.
- All threads 27, 28, 29, 30, 37, 38, 39, 40 of the wet press felt 23 from the Figures 3 and 4 are given by monofilaments made from partially aromatic copolyamide, specifically from PA6T / 6, whereby a wet press felt with the excellent properties already discussed above in connection with the previous exemplary embodiments is obtained. It is characterized in particular by excellent dimensional stability in both the length and width directions, high thermal resistance and high mechanical resistance, especially against pressure loads, and particularly high abrasion resistance.
- a fourth embodiment of a covering according to the invention is shown, which is a dryer fabric 41.
- the dryer fabric 41 has broad flat transverse threads on the paper side - designated 42 by way of example - which are bound in by longitudinal thread pairs - designated 43 by way of example, each longitudinal thread pair 43 consisting of two longitudinal threads - designated 44, 45 by way of example, which run identically within a pair of longitudinal threads 43.
- the longitudinal thread pairs 43 bind with the flat transverse threads 42 in the manner of a plain weave, ie they bind a flat transverse thread 42 on the paper side and the subsequent flat transverse thread 42 on the machine side and then the subsequent flat transverse thread 42 again on the paper side.
- the incorporation of the longitudinal threads 44, 45 with the flat transverse threads 42 is even clearer Fig. 6 refer to.
- the longitudinal threads 44, 45 of the longitudinal thread pairs 43 form in the version below the dash-dotted line on the front edge 48 of the drying wire 41 large loops - designated 49 for example - and small loops - labeled 50 for example.
- the large loops 49 alternate with small loops 50.
- the version above the dash-dotted line forms only large loops 49. It goes without saying that two different types of end edges 48 are to be shown by this illustration, but that only one loop version is present for a dryer fabric.
- the large loops 49 form loop eyelets 51, these loops 49 being able to overlap with corresponding large loops on the other end edge of the drying wire 41 in such a way that all loop eyelets 51 are aligned and thus form a channel through which in a manner known per se Plug wire for connecting the front edges 48 can be pushed to form a so-called plug wire seam.
- a longitudinal thread 44 of a pair of longitudinal threads 43 is woven back after the loop formation in such a way that it forms the adjacent longitudinal thread 52 of the adjacent longitudinal thread pair 53.
- the longitudinal thread 45 of the pair of longitudinal threads 43 ie the loop formation makes it the adjacent longitudinal thread 54 of the adjacent pair of longitudinal threads 55. This results in only a slight twisting of the loops 49, 50 and a very uniform product image of the dryer fabric 41 on the paper side.
- all of the threads 42, 44, 45, 46, 47 of the drying wire 41 are from the Figures 5 and 6 by monofilaments made from partially aromatic copolyamide, specifically from PA6T / 6.
- monofilaments made from partially aromatic copolyamide specifically from PA6T / 6.
- PA6T / 6 PA6T / 6
- the dryer fabric 41 consists of monofilaments made of partially aromatic copolyamide, or has them, it is also distinguished by the advantages compared to the prior art, already discussed in connection with the previous embodiments, in particular by good hydrolysis stability and compared to the prior art Technology significantly higher abrasion resistance - especially compared to dryer fabrics made of PPS.
- the Figures 7 and 8 Finally, sections show the base fabric 56 of a fifth and a sixth embodiment of a covering according to the present invention, which are each designed as flow-through coverings for the dewatering of a paper web or of cellulose and are similar in structure to those described in FIGS Figures 1 and 2 who also goes back to the applicant DE 20 2013 104 888 U1 are shown.
- the illustrated base fabric 56 is designed as a single-layer fabric in plain weave and consists of base warp threads - denoted by example 57 - and base weft threads - denoted by example 58.
- Fig. 7 are woven into the base fabric 56 a plurality of additional warp threads - designated 59 by way of example - which are arranged next to one another at equal intervals and have an identical course. They are shown filled in black. Their course is also symmetrical to axes of symmetry, which run parallel to the base warp threads 57 and to the base weft threads 58.
- the additional warp threads 59 move back and forth by crossing two adjacent base warp threads 57 on their upper sides, running parallel to the base weft threads 58, then tying at the point of inflection - designated 60 by way of example - with a base weft thread 58 and running there parallel to the base warp threads 57, then in In the opposite direction, cross two base warp threads 57 at the top and tie with the adjacent base weft thread 58 at the next turning point 60. This creates a rectangular meandering course of the additional warp threads 59.
- additional warp threads - for example designated 61 and 62 - are woven into the base fabric, some of them different course than the additional warp threads 59 according to Fig. 7 to have.
- the course is different from that of the additional warp threads 59 according to Fig. 7 more like an arch shape.
- the additional warp thread 61 initially runs in a section parallel to the base weft yarns 58 via a base warp yarn 57. Then there is an inclined section which runs between the adjacent base warp yarn 57 and a base weft yarn 58. At the turning point 60, a section parallel to the base warp threads 57 crosses the adjacent base weft thread 58 on its underside.
- an inclined section which runs between a base warp thread 57 and a base weft thread 58.
- the additional warp thread 62 viewed in the drawing from top to bottom, first runs in a section parallel to the base weft threads 58 over a base warp thread 57. Then an inclined section follows, which runs over the adjacent base warp thread 57 and a base weft thread 58. At the turning point 60, a section parallel to the base warp threads 57 crosses the adjacent base weft thread 58 on its underside.
- an inclined section which runs over a base warp thread 57 and a base weft thread 58.
- the additional warp threads 61, 62 have regular arches.
- the adjoining additional warp threads 61, 62 form an identical thread pattern, but they can be tied in between the base weft threads 58 and the base warp threads 57 or lie on top of the base weft threads 58 and base warp threads 57 at the inclined sections which precede or follow the turning points 60.
- the additional warp threads 59, 61, 62 form a structural principle that can be implemented in an extremely varied manner, so that the base fabric 56 provided with it can be flexibly adapted to the respective requirements in the individual batches of the paper machine or pulp dewatering machine in terms of a number of properties.
- the additional warp threads 59, 61, 62 in particular allow a kind of functional separation, in that the construction of the base fabric 56 is optimally adapted to the basic requirements such as strength and dimensional stability, while other properties such as drainage, abrasion resistance, fiber retention or the like, with the help of Additional warp threads 59, 61, 62 can be optimized.
- both are in the embodiment Figure 7 as well as the embodiment Figure 8 all existing additional warp threads 59, 61, 62 of the respective covering by monofilaments made of partially aromatic copolyamide, specifically given PA6T / 6, whereby the Advantages already explained above can be achieved.
- the high thermal and mechanical resilience represents a considerable advantage in the application area of pulp dewatering, for example, where higher temperatures can prevail than in conventional paper machines.
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Abstract
Die vorliegende Erfindung betrifft eine Bespannung (1, 12, 23, 41, 56) für Papier- oder Zellstoffentwässerungsmaschinen, umfassend oder bestehend aus Monofilamenten (8, 10, 11, 16, 19, 27-30, 37-40, 42, 44-47, 59, 61, 62) mit oder aus einem teilaromatischen Polyamid.The present invention relates to a covering (1, 12, 23, 41, 56) for paper or pulp dewatering machines, comprising or consisting of monofilaments (8, 10, 11, 16, 19, 27-30, 37-40, 42, 44 -47, 59, 61, 62) with or from a partially aromatic polyamide.
Description
Die Erfindung betrifft eine Bespannung für Papiermaschinen oder Zellstoffentwässerungsmaschinen sowie die Verwendung einer solchen.The invention relates to a covering for paper machines or pulp dewatering machines and the use of such.
Große Papiermaschinen bestehen gewöhnlich aus drei sogenannten Partien, nämlich in Richtung des Verlaufs der Papierbahn gesehen aus einer Formierpartie, einer Pressenpartie und einer Trockenpartie. Die Formierpartie dient der Ausbildung der Papierbahn aus der Papierpulpe und einer ersten mechanischen Entwässerung der so gebildeten Papierbahn. In der Pressenpartie wird die Papierbahn zwischen Presswalzen hindurchgeführt, in der sie hohen Drücken ausgesetzt und hierdurch weiter mechanisch entwässert wird. Danach wird die Papierbahn der Trockenpartie zugeführt, in der die Papierbahn über beheizte Trockenzylinder geführt wird, wodurch die Papierbahn thermisch entwässert wird.Large paper machines usually consist of three so-called lots, namely a forming section, a press section and a dryer section when viewed in the direction of the paper web. The forming section is used to form the paper web from the paper pulp and a first mechanical dewatering of the paper web thus formed. In the press section, the paper web is passed between press rollers, in which it is exposed to high pressures and is thereby further mechanically dewatered. The paper web is then fed to the dryer section, in which the paper web is guided over heated drying cylinders, as a result of which the paper web is thermally dewatered.
Die Führung der Papierbahn durch die Papiermaschine erfolgt mittels an die Anforderung an die jeweilige Partie angepassten Bändern, an denen die Papierbahn anliegt und die auch der Überführung der Papierbahn von einer zur nächsten Partie dienen.The paper web is guided through the paper machine by means of belts which are adapted to the requirements of the respective lot and against which the paper web lies and which also serve to transfer the paper web from one lot to the next.
So kommen in der Formierpartie sogenannte Formiersiebe zum Einsatz. Beispiele solcher sowie deren Führung durch eine Papiermaschine gehen aus der
Weiterhin können, um die Papierbahn auch in den Bereichen zu führen, in denen keine Unterstützung insbesondere durch den Pressfilz gegeben ist, was vor allem für den Übergangsbereich zur Trockenpartie gilt, sogenannte Transferbänder (transferbelts) eingesetzt werden, die die Papierbahn durch eine oder mehrere Pressen der Pressenpartie zusammen mit dem jeweils zugehörigen Pressfilz hindurchführen und nach Ablösung des Pressfilzes von der Papierbahn bis zu einer Stelle führen, wo die Papierbahn meist unter Zuhilfenahme einer Saugwalze von dem Transferband abgelöst und von einem in der Trockenpartie umlaufenden Trockensieb übernommen wird. Beispiele für die Führung von Transferbändern in der Pressenpartie einer Papiermaschine sind insbesondere den
Es ist bekannt, dass in Papiermaschinenbespannungen Fäden aus Polyamid zum Einsatz kommen. Aus der
Die Bespannungen für Papiermaschinen bekannter Art haben sich prinzipiell bewährt. Es besteht jedoch weiterhin Bedarf an Bespannungen für Papiermaschinen bzw. Zellstoffentwässerungsmaschinen, die sich insbesondere durch gegenüber dem Stand der Technik verbesserte mechanische sowie thermische Eigenschaften auszeichnen. Es ist daher Aufgabe der vorliegenden Erfindung, eine Bespannung für Papiermaschinen oder Zellstoffentwässerungsmaschinen anzugeben, die diese Anforderungen erfüllt.The fabrics for known paper machines have proven themselves in principle. However, there is still a need for clothing for paper machines or pulp dewatering machines, which are characterized in particular by improved mechanical and thermal properties compared to the prior art. It is therefore an object of the present invention to provide a covering for paper machines or pulp dewatering machines that meets these requirements.
Diese Aufgabe wird gelöst durch eine Bespannung für Papier- oder Zellstoffentwässerungsmaschinen, umfassend oder bestehend aus Monofilamenten umfassend oder bestehend aus einem teilaromatischen Polyamid.This object is achieved by a covering for paper or pulp dewatering machines, comprising or consisting of monofilaments comprising or consisting of a partially aromatic polyamide.
Die Anmelderin hat herausgefunden, dass aus teilaromatischem Polyamid Monofile erhalten werden können, deren Verwendung in Bespannungen für Papier- oder Zellstoffentwässerungsmaschinen zu einer Kombination hervorragender Produkteigenschaften führt.The applicant has found that partially aromatic polyamide can be used to obtain monofilaments, the use of which in fabrics for paper or pulp dewatering machines leads to a combination of excellent product properties.
Besonders bevorzugt ist vorgesehen, dass zumindest ein Teil der Monofilamente der erfindungsgemäßen Bespannung aus einem teilaromatischen Co-Polyamid besteht oder ein solches umfasst, was sich als ganz besonders geeignet erwiesen hat. Alternativ oder zusätzlich kann vorgesehen sein, dass zumindest ein Teil der Monofilamente der erfindungsgemäßen Bespannung aus einem teilaromatischen Homo-Polyamid besteht oder ein solches umfasst. Selbstverständlich ist es auch möglich, dass zumindest ein Teil der Monofilamente aus einer Kombination aus teilaromatischem Homo- und teilaromatischem Co-Polyamid besteht oder eine solche Kombination umfasst.It is particularly preferably provided that at least some of the monofilaments of the covering according to the invention consist of or comprise a partially aromatic copolyamide, which has proven to be very particularly suitable. Alternatively or additionally, it can be provided that at least some of the monofilaments of the covering according to the invention consist of or comprise a partially aromatic homo-polyamide. Of course, it is also possible that at least part of the Monofilaments consists of a combination of partially aromatic homo- and partially aromatic copolyamide or comprises such a combination.
Ein teilaromatisches Co-Polyamid ist dabei ein solches, welches sowohl aromatische als auch aliphatische Anteile aufweist, wie es beispielsweise für PA6T/6 gilt, das aus dem unter dem Markennamen Ultramid® T von dem Hersteller BASF angebotenen Sortiment stammt. Insbesondere aufgrund des Vorhandenseins beider Anteile ist das Material besser verarbeitbar, als es für aromatische Polyamide, die ausschließlich aromatische Anteile aufweisen, der Fall ist. Aus teilaromatischem Co-Polyamid können nach Erkenntnis der Anmelderin Monofile ausgesponnen werden, die sich insbesondere durch eine geringe Wasseraufnahme, eine hohe Dimensionsstabilität, eine hohe thermische sowie mechanische Belastbarkeit, eine hohe Abriebbeständigkeit sowie eine gute Verarbeitbarkeit auszeichnen und deren Einsatz in Bespannungen genannter Art zu optimierten Ergebnissen bei vergleichbar moderaten Kosten führt. Die erfindungsgemäßen Bespannungen zeichnen sich einerseits durch eine geringe (wasserbedingte) Formveränderung aus, da die Monofilamente aus teilaromatischem Co-Polyamid nur in vergleichsweise geringem und deutlich langsamerem Maße Wasser aufnehmen und somit Form-stabilisierend wirken. Weiterhin tritt unter Verwendung dieser Monofilamente aufgrund der hohen mechanischen Stabilität nur ein geringfügiges Abflachen an Kröpfungspunkten des Gewebes auf. Ein der Anmelderin bei Bespannungen konventioneller Art, vor allem Sieben mit Monofilamenten aus PET-TPU und insbesondere an der Maschinenseite, bekanntes Problem wird im Ergebnis zuverlässig vermieden. Weiterhin hat sich gezeigt, dass die Monofilamente aus teilaromatischem Co-Polyamid sich in einer Bespannung durch eine besonders gute Positionierung relativ zu den übrigen Fäden im Gewebe auszeichnen. Auch weisen sie eine hohe Belastbarkeit gegenüber Reinigungsaggregaten, etwa Hochdruckspritzrohren, und eine ausgezeichnete Chemikalienbeständigkeit auf. Es wird weiterhin ein besonders geringer Abrieb gewährleistet, was vor allem maschinenseitig an einer Bespannung einen erheblichen Vorteil bietet.A partially aromatic copolyamide is one which has both aromatic and aliphatic components, as is the case for PA6T / 6, for example, which comes from the range offered by the manufacturer BASF under the brand name Ultramid® T. In particular, due to the presence of both components, the material is easier to process than is the case for aromatic polyamides which contain only aromatic components. According to the applicant's knowledge, monofilaments can be spun from partially aromatic copolyamide, which are characterized in particular by low water absorption, high dimensional stability, high thermal and mechanical strength, high abrasion resistance and good processability, and to optimize their use in fabrics of the type mentioned Results with comparable moderate costs. The fabrics according to the invention are distinguished on the one hand by a slight (water-related) change in shape, since the monofilaments made from partially aromatic copolyamide absorb water only to a comparatively small and significantly slower extent and thus have a shape-stabilizing effect. Furthermore, using these monofilaments, due to the high mechanical stability, there is only a slight flattening at offset points of the fabric. As a result, a problem known to the applicant in the case of coverings of a conventional type, especially sieving with monofilaments made of PET-TPU and in particular on the machine side, is reliably avoided. Furthermore, it has been shown that the monofilaments made from partially aromatic copolyamide are characterized by a particularly good positioning relative to the other threads in the fabric in a covering. They also have a high load capacity compared to cleaning units, such as high-pressure spray pipes, and excellent chemical resistance. It continues to be a particularly low one Abrasion is guaranteed, which offers a considerable advantage, particularly on the machine side, of a covering.
Aufgrund der Kombination der genannten vorteilhaften Eigenschaften und einer im Vergleich zu Polyethylenterephthalat (PET) erheblich verbesserten Hydrolysestabilität können Monofilamente aus teilaromatischem Co-Polyamid auch eine hervorragende Alternative zu Filamenten aus PET und vor allem eine deutlich günstigere Alternative etwa zu Fäden aus Polyphenylensulfid (PPS) insbesondere in Trockensieben bilden. PPS wird als Alternative zu PET in Trockensieben eingesetzt, wenn die Einsatzbedingungen zu einem Polymerabbau des PET durch Hydrolyse führen können, während PPS unter diesen Bedingungen nicht geschädigt wird.Due to the combination of the mentioned advantageous properties and a significantly improved hydrolysis stability compared to polyethylene terephthalate (PET), monofilaments made from partially aromatic copolyamide can also be an excellent alternative to filaments made from PET and, above all, a significantly cheaper alternative to threads made from polyphenylene sulfide (PPS) in particular form in dryer fabrics. PPS is used as an alternative to PET in dryer fabrics if the conditions of use can lead to polymer degradation of the PET by hydrolysis, while PPS is not damaged under these conditions.
Weitere vorteilhafte Eigenschaften von teilaromatischem Co-Polyamid sind eine vergleichsweise hohe Glastemperatur, ein vergleichsweise hoher Schmelzpunkt, von insbesondere etwa 295°C, konstante mechanische Eigenschaften, hohe Festigkeit und Steifigkeit, sehr gute Zähigkeit, gute Federeigenschaften.Further advantageous properties of partially aromatic copolyamide are a comparatively high glass transition temperature, a comparatively high melting point, in particular of about 295 ° C., constant mechanical properties, high strength and rigidity, very good toughness, good spring properties.
Die Monofilamente, die im Rahmen der vorliegenden Erfindung zur Verwendung kommen können, können beispielsweise aus einem Material bestehen oder ein solches umfassen, wie es in der
Die Herstellung von Monofilen aus teilaromatischem Polyamid kann insbesondere, wie für Thermoplaste im Allgemeinen bereits hinlänglich bekannt, durch Extrusion erfolgen.The production of monofilaments from partially aromatic polyamide can, in particular, as already generally known for thermoplastics, take place by extrusion.
Es ist insbesondere vorgesehen, dass als Monofilamente ausgebildeten Kunststofffäden aus teilaromatischem Polyamid, insbesondere Co-Polyamid einen Bestandteil einer Bespannung für eine Papiermaschine bzw. Zellstoffentwässerungsmaschine bilden.In particular, it is provided that plastic threads made of partially aromatic polyamide, in particular copolyamide, formed as monofilaments form part of a covering for a paper machine or cellulose dewatering machine.
Es sei angemerkt, dass es sich bei Co-Polyamid bekannter Maßen um ein Co-Polymer (auch als Heteropolymer bezeichnet) handelt, also ein Polymer, das aus zwei oder mehr Monomeren zusammengesetzt ist. Das Gegenstück zu Co-Polymeren bilden ebenfalls bekannter Maßen die Homo-Polymere, bei denen es sich um Polymere handelt, die aus nur einer Monomerart aufgebaut sind. Teilaromatische Homo-Polyamide wie Polyphthalamid PA6T (T steht für Terephthalsäure = aromatische Dicarbonsäure) zählen folglich nicht zu den teilaromatischen Co-Polyamiden. Gleiches gilt selbstverständlich für die aliphatischen Homo-Polyamide, wie etwa Polyamid 6 (PA6), Polyamid 6.6 (PA6.6) oder Polyamid 6.10 (PA6.10), und die aromatischen Homo-Polyamide wie Polyaramid Poly(m-phenylenisophthalamid), die ebenfalls nicht in die Gruppe der teilaromatischen Co-Polyamide fallen.It should be noted that copolyamide of known dimensions is a co-polymer (also known as a heteropolymer), that is to say a polymer which is composed of two or more monomers. The counterpart to copolymers are also known dimensions, homopolymers, which are polymers which are composed of only one type of monomer. Partially aromatic homo-polyamides such as polyphthalamide PA6T (T stands for terephthalic acid = aromatic dicarboxylic acid) are therefore not among the partially aromatic copolyamides. The same naturally applies to the aliphatic homo-polyamides, such as polyamide 6 (PA6), polyamide 6.6 (PA6.6) or polyamide 6.10 (PA6.10), and the aromatic homo-polyamides, such as polyaramide poly (m-phenylene isophthalamide), which likewise do not fall into the group of partially aromatic copolyamides.
Was den Anteil an teilaromatischem Polyamid, insbesondere Co-Polyamid in einer erfindungsgemäßen Bespannung angeht, ist es einerseits möglich, dass nur ein Teil sämtlicher Fäden einer Bespannung durch Monofilamente aus oder mit teilaromatischem Polyamid, insbesondere Co-Polyamid gegeben ist, diese also in Kombination mit Fäden anderer Art vorliegen.As far as the proportion of partially aromatic polyamide, especially co-polyamide in a fabric according to the invention is concerned, it is possible, on the one hand, that only a part of all the threads of a fabric is given by monofilaments made of or with partially aromatic polyamide, in particular co-polyamide, that is to say in combination with There are threads of a different kind.
Eine Bespannung weist insbesondere sich in einer Laufrichtung erstreckende Längsfäden und sich quer zu diesen erstreckende Querfäden auf, die dann zum Teil oder auch allesamt durch Monofilamente aus oder mit teilaromatischem Polyamid, insbesondere teilaromatischem Co-Polyamid gegeben sein können. Bevorzugt ist zumindest ein Teil der Querfäden durch Monofilamente aus einem solchen Material, beispielsweise PA6T/6 gegeben. Je nach Anwendung können die Längsfäden, welche in erster Linie die kraftaufnehmenden Fäden sind, - wie von konventionellen Bespannungen vorbekannt - aus Polyester gefertigt sein, welches sich durch eine noch höhere Zugfestigkeit auszeichnet. Selbstverständlich können aber auch diese zumindest zum Teil aus teilaromatischem Polyamid, insbesondere Co-Polyamid bestehen.A covering has in particular longitudinal threads extending in a running direction and transverse threads extending transversely thereto, which then some or all of them can be given by monofilaments made of or with partially aromatic polyamide, in particular partially aromatic copolyamide. At least part of the transverse threads is preferably given by monofilaments made of such a material, for example PA6T / 6. Depending on the application, the longitudinal threads, which are primarily the force-absorbing threads, can be made of polyester, as is known from conventional coverings, which is characterized by an even higher tensile strength. Of course, however, these can also consist at least in part of partially aromatic polyamide, in particular copolyamide.
Selbstverständlich ist es auch möglich, dass sämtliche Fäden einer Bespannung durch diese Monofilamente gebildet werden. Dies kann insbesondere in demjenigen Falle besonders vorteilhaft sein, dass die erfindungsgemäße Bespannung als Pressfilz oder auch Trockensieb ausgebildet ist und zum Einsatz kommt.Of course, it is also possible that all threads of a covering are formed by these monofilaments. This can be particularly advantageous, in particular, in the event that the covering according to the invention is designed as a press felt or also a dryer fabric and is used.
Weiterhin kann vorgesehen sein, dass die erfindungsgemäße Bespannung nur eine Gewebelage oder auch mehrere Gewebelagen aufweist. Sind mehrere Lagen vorhanden, kann nur eine der Lagen Monofilamente mit oder aus teilaromatischem Polyamid, insbesondere Co-Polyamid aufweisen oder aber dies gilt für mehrere, ggf. alle Lagen der Bespannung, wobei wiederum die einzelne(n) Lage(n) jeweils nur anteilig oder vollständig durch Monofilamente aus diesem Material gebildet sein können. Ist z. B. eine maschinenseitige Gewebelage vorgesehen, so gilt bevorzugt, dass zumindest die maschinenseitige Gewebelage Monofilamente mit oder aus einem teilaromatischen Polyamid, insbesondere Co-Polyamid umfasst oder aus diesen besteht. Dann ist vor allem auf der besonders beanspruchten Maschinenseite eine besonders hohe Abriebbeständigkeit sichergestellt.Furthermore, it can be provided that the covering according to the invention has only one fabric layer or also a plurality of fabric layers. If several layers are present, only one of the layers can have monofilaments with or made from partially aromatic polyamide, in particular copolyamide, or this applies to several, if necessary all, layers of the covering, the individual layer (s) again only partially or can be formed entirely from monofilaments of this material. Is z. If, for example, a machine-side fabric layer is provided, it is preferred that at least the machine-side fabric layer comprises or consists of monofilaments with or made from a partially aromatic polyamide, in particular copolyamide. Then a particularly high abrasion resistance is ensured, especially on the particularly stressed machine side.
Weist die maschinenseitige Gewebelage sich in einer Laufrichtung erstreckende Längsfäden und sich quer zu den Längsfäden erstreckende Querfäden auf, ist bevorzugt vorgesehen, dass es sich zumindest bei einem Teil der Querfäden der maschinenseitigen Gewebelage um Monofilamente aus einem teilaromatischen Polyamid, insbesondere Co-Polyamid handelt.If the machine-side fabric layer has longitudinal threads extending in a running direction and transverse threads extending transversely to the longitudinal threads, it is preferably provided that at least some of the cross-threads of the machine-side fabric layer are monofilaments made from a partially aromatic polyamide, in particular copolyamide.
Die erfindungsgemäße Bespannung kann beispielsweise als Formiersieb oder Trockensieb ausgebildet sein und in dieser Funktion insbesondere in einer Papiermaschine verwendet werden. Auch ist es möglich, dass die erfindungsgemäße Bespannung als Pressenfilz oder Transferband ausgebildet ist und entsprechend verwendet wird. Es sei angemerkt, dass die erfindungsgemäße Bespannung in ihrem Aufbau zu demjenigen von aus dem Stand der Technik vorbekannten Bespannungen entsprechender Art identisch sein und der einzige Unterschied darin bestehen kann, dass zumindest ein Teil der Bespannung durch Monofilamente mit oder aus teilaromatischem Polyamid, insbesondere Co-Polyamid gebildet wird.The covering according to the invention can be designed, for example, as a forming fabric or a drying fabric and can be used in this function in particular in a paper machine. It is also possible that the covering according to the invention is designed as a press felt or transfer belt and is used accordingly. It should be noted that the structure of the fabric according to the invention is identical to that of a corresponding type of fabric known from the prior art, and the only difference may be that at least part of the fabric is covered by monofilaments with or made from partially aromatic polyamide, in particular Co Polyamide is formed.
Bei dem insbesondere zum Einsatz kommenden teilaromatischen Co-Polyamid handelt es sich bevorzugt um ein solches, das sich durch eine Basis aus Hexamethylendiamin und Terephthalsäure und Caprolactam auszeichnet. Besonders bevorzugt kommt das bereits genannte PA6T/6 zum Einsatz.The partially aromatic copolyamide used in particular is preferably one which is characterized by a base of hexamethylenediamine and terephthalic acid and caprolactam. The PA6T / 6 already mentioned is particularly preferably used.
Ein weiterer Gegenstand der Erfindung ist die Verwendung einer erfindungsgemäßen Bespannung in einer Papiermaschine oder Zellstoffentwässerungsmaschine.Another object of the invention is the use of a fabric according to the invention in a paper machine or pulp dewatering machine.
Schließlich betrifft die Erfindung die Verwendung von Monofilamenten mit oder aus teilaromatischem Polyamid, insbesondere Co-Polyamid, bevorzugt PA6T/6, zur Herstellung von Bespannungen für Papiermaschinen oder Zellstoffentwässerungsmaschinen.Finally, the invention preferably relates to the use of monofilaments with or made from partially aromatic polyamide, in particular copolyamide PA6T / 6, for the production of fabrics for paper machines or cellulose dewatering machines.
In der Zeichnung ist die Erfindung anhand mehrerer Ausführungsbeispiele näher veranschaulicht. Darin zeigt
-
Figur 1 in einem Querschnitt - also quer zur vorgesehenen Laufrichtung - einen Ausschnitt einer ersten Ausführungsform einer erfindungsgemäßen, als Formiersieb ausgebildeten Bespannung, -
in einem Querschnitt einen Ausschnitt einer zweiten Ausführungsform einer erfindungsgemäßen, ebenfalls als Formiersieb ausgebildeten Bespannung,Figur 2 -
einen Längsschnitt durch eine dritte Ausführungsform einer erfindungsgemäßen, als Nasspressfilz ausgebildeten Bespannung,Figur 3 -
einen Querschnitt durch dieFigur 4Bespannung aus Figur 3 in vergrößerter Darstellung, -
eine Draufsicht auf den Endabschnitt einer vierten Ausführungsform einer erfindungsgemäßen, als Trockensieb ausgebildeten Bespannung,Figur 5 -
einen Längsschnitt durch denFigur 6Ausschnitt gemäß Figur 5 , -
eine Draufsicht auf einen Ausschnitt des Basisgewebes einer fünften Ausführungsform einer erfindungsgemäßen Bespannung, die als Bespannung zur Entwässerung einer Papierbahn oder von Zellstoff ausgebildet ist,Figur 7 -
eine Draufsicht auf einen Ausschnitt eines Basisgewebes einer sechsten Ausführungsform einer erfindungsgemäßen Bespannung, die ebenfalls als Bespannung zur Entwässerung einer Papierbahn oder von Zellstoff ausgebildet ist, undFigur 8 -
einen Ausschnitt aus der Polymerkette eines teilaromatischen Co-Polyamids PA6T/6.Figur 9
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Figure 1 in a cross-section - that is to say transversely to the intended running direction - a section of a first embodiment of a covering according to the invention, designed as a forming screen -
Figure 2 in a cross section a section of a second embodiment of a fabric according to the invention, also designed as a forming fabric, -
Figure 3 2 shows a longitudinal section through a third embodiment of a covering according to the invention, designed as a wet press felt, -
Figure 4 a cross section through the coveringFigure 3 in an enlarged view, -
Figure 5 2 shows a plan view of the end section of a fourth embodiment of a covering according to the invention, designed as a dryer fabric, -
Figure 6 a longitudinal section through the cutoutFigure 5 . -
Figure 7 2 shows a plan view of a section of the base fabric of a fifth embodiment of a covering according to the invention, which is designed as a covering for dewatering a paper web or cellulose, -
Figure 8 a plan view of a section of a base fabric of a sixth embodiment of a covering according to the invention, which is also designed as a covering for dewatering a paper web or cellulose, and -
Figure 9 a section of the polymer chain of a partially aromatic co-polyamide PA6T / 6.
Die
Der Durchmesser der Längsfäden 4 in der papierseitigen Gewebelage 2 beträgt 0,11 mm und der Durchmesser der Längsfäden 5 in der maschinenseitigen Gewebelage 3 beträgt 0,18 mm. Sie bestehen aus Polyethylenterephthalat (PET). Die Längsfadenanzahl beträgt 58 pro cm in Querrichtung.The diameter of the
In der papierseitigen Gewebelage 2 sind papierseitige Quer- bzw. Schussfäden 6, 7 unter Bildung einer Leinwandbindung mit den Längsfäden 4 eingebunden. Senkrecht zur Zeichnungsebene folgen jeweils nebeneinanderliegende papierseitige Querfäden 6, 7 aufeinander. Die papierseitigen Querfäden 6, 7 bestehen aus Polyethylenterephthalat (PET), und sie haben einen Durchmesser von 0,11 mm.In the paper-
Ausschließlich in die maschinenseitigen Längsfäden 5 sind maschinenseitige Querfäden 8 eingebunden, von denen in der Figur nur einer zu sehen ist. Die maschinenseitigen Querfäden 8 bilden jeweils über fünf Längsfäden 5 gehende Flottierungen - beispielhaft mit 9 bezeichnet - an der Maschinenseite des Formiersiebes 1 und binden dann jeweils mit einem einzigen maschinenseitigen Längsfaden 5 ein. Die maschinenseitigen Flottierungen 9 stellen Abriebmaterial zur Schonung der stark auf Zug beanspruchten maschinenseitigen Längsfäden 5 dar. Der Durchmesser der maschinenseitigen Querfäden 8 beträgt 0,22 mm. Die maschinenseitigen Querfäden 8 sind gemäß der vorliegenden Erfindung durch Monofilamente aus teilaromatischem Co-Polyamid, konkret PA6T/6 gegeben. Ein Ausschnitt aus der Polymerkette von PA6T/6 kann der
Die Gewebelagen 2, 3 werden durch Paare von zwei jeweils in Längsrichtung nebeneinander liegenden Bindequerfäden 10, 11 verbunden. Sie haben einen Durchmesser von 0,11 mm und bestehen aus PET. Sie binden in der papierseitigen Gewebelage 2 nacheinander abwechselnd oben- und untenseitig mit papierseitigen Längsfäden 4 ein, verlaufen dann zwischen den beiden Gewebelagen 2, 3 über drei Längsfäden 4 bzw. 5 und binden dann mit einem einzigen Längsfaden 5 in der maschinenseitigen Gewebelage 3 ein, bevor sie dann wieder zwischen den beiden Gewebelagen 2 und 3 flottieren. Die gepaarten Bindequerfäden 10 und 11 haben jeweils den gleichen Bindungsrapport, sind jedoch zueinander so in Querrichtung - d. h. in deren Längsrichtung - verschoben, dass sich die Bindungsmuster in der papierseitigen Gewebelage 2 ergänzen, so dass sie dort zusammen ein Leinwandmuster analog zu den papierseitigen Querfäden 6, 7 ausbilden. Auf diese Weise entsteht auf der Papierseite des Formiersiebes 1 ein nahezu uniformes Leinwandmuster, das eine hohe Faserretention bereitstellt.The fabric layers 2, 3 are connected by pairs of two binding
Der Längsfaden-Füllgrad der papierseitigen Gewebelage 2 beträgt 31%, der Gesamtfüllgrad papierseitiger und maschinenseitiger Längsfäden 4, 5 82%. Die Querfadenanzahl ist 108 pro cm in Längsrichtung des Formiersiebes 1. Hierdurch entsteht eine hohe Offenheit und damit eine gute Entwässerungswirkung trotz hoher Faserretention.The longitudinal thread filling degree of the paper-
Von seinem Aufbau her stimmt das Formiersieb 1 mit demjenigen überein, welches in der einzigen Figur der ebenfalls auf die Anmelderin zurückgehenden
Gemäß der vorliegenden Erfindung sind bei dem in
Die
Das Formiersieb 12 aus
Die papierseitige Gewebelage 13 weist papierseitige Längsfäden - in der
Die maschinenseitige Gewebelage 14 besteht aus maschinenseitigen Längsfäden - beispielhaft mit 18 bezeichnet -, sowie maschinenseitigen Querfäden 19, von denen in der
An dem Bindepunkt 22 bindet der Querbindefaden 16 mit einem papierseitigen Längsfaden 15a, indem er über dessen Papierseite verläuft, dann von der papierseitigen Gewebelage 13 zu der maschinenseitigen Gewebelage 14 durch nahezu vertikalen Verlauf, also in Dickenrichtung des Siebes 12 wechselt und mit der maschinenseitigen Gewebelage 14 mit zwei benachbarten Längsfäden 18a und 18b bindet, indem er diese maschinenseitig übergreift. Die beiden maschinenseitigen Längsfäden 18a, 18b liegen neben der Kröpfung 21. Anschließend verläuft der Querbindefaden 16 wieder zu der papierseitigen Gewebelage 13 zurück und bindet mit einem papierseitigen Längsfaden 15b ein. Die papierseitigen Längsfäden 15a, 5b sind nur durch einen papierseitigen Längsfaden 15c voneinander getrennt. Die
Die maschinenseitigen Querfäden 19 sind - genau wie bei dem ersten Ausführungsbeispiel - durch Monofilamente aus teilaromatischem Co-Polyamid, konkret PA6T/6 gegeben, wodurch gegenüber der vorbekannten Ausgestaltung die gleichen Vorteile erzielt werden, die vorstehend bereits für die erste Ausführungsformaus
Der Träger 24 besteht aus einer innenseitigen Trägerlage 25 und einer außenseitigen Trägerlage 26. Beide Trägerlagen 25, 26 sind als Gewebe ausgebildet, die in einem kontinuierlichen Webprozess durch Rundweben hergestellt sind. Die Gewebe haben Querfäden - beispielhaft mit 27 bzw. 28 bezeichnet -, die beim Webprozess die Kettfäden gebildet haben, sowie Längsfäden 29, 30 als Schussfäden. Die Längsfäden 29, 30 sind aufgrund ihrer Eigenschaft als Schussfäden Teile eines einzigen durchgehenden Fadens. Die Querfäden 27, 28 binden mit den Längsfäden 29, 30 so ein, dass die beiden Trägerlagen 25, 26 über die Fläche keine Verbindung über Fäden miteinander haben, d.h. die Querfäden 27 binden nicht in die Trägerlage 26 und die Querfäden 28 nicht in die Trägerlage 25 ein und die Längsfäden 29, 30 verbleiben über die gesamte Länge des Trägers 24 in der jeweiligen Trägerlage 25 bzw. 26.The
An den stirnseitigen Enden 31, 32 des Trägers 24 bildet jeder zweite Längsfaden 29, 30 Nahtschlaufen 33, 34 aus, die über die Enden 31, 32 vorstehen. Senkrecht zur Zeichnungsebene entstehen hierdurch eine Vielzahl von Nahtschlaufen 33, 34 (vgl. insoweit die Bezugsziffern 17 und 19 in
In
Sämtliche Fäden 27, 28, 29, 30, 37, 38, 39, 40 des Nasspressfilzes 23 aus den
In den
Aus der Draufsicht gemäß
Die Längsfäden 44, 45 der Längsfadenpaare 43 bilden in der Version unterhalb der strichpunktierten Linie an der Stirnkante 48 des Trockensiebes 41 große Schlaufen - beispielhaft mit 49 bezeichnet - und kleine Schlaufen - beispielhaft mit 50 bezeichnet - aus. Die großen Schlaufen 49 wechseln sich mit kleinen Schlaufen 50 ab. Die Version oberhalb der strichpunktierten Linie bildet nur große Schlaufen 49 aus. Es versteht sich, dass durch diese Darstellung zwei verschiedene Arten von Stirnkanten 48 gezeigt werden sollen, dass jedoch bei einem Trockensieb nur eine Schlaufenversion vorhanden ist. Die großen Schlaufen 49 bilden Schlaufenösen 51 aus, wobei diese Schlaufen 49 mit entsprechenden großen Schlaufen an der anderen Stirnkante des Trockensiebes 41 so in Überlappung gebracht werden können, dass sämtliche Schlaufenösen 51 fluchten und damit einen Kanal bilden, durch den in an sich bekannter Weise ein Steckdraht zur Verbindung der Stirnkanten 48 unter Bildung einer sogenannten Steckdrahtnaht geschoben werden kann. Ein Längsfaden 44 eines Längsfadenpaares 43 wird dabei nach der Schlaufenbildung in der Weise zurückgewebt, dass er den benachbarten Längsfaden 52 des benachbarten Längsfadenpaares 53 bildet. Entsprechendes gilt für den Längsfaden 45 des Längsfadenpaares 43, d. h. durch die Schlaufenbildung wird er zum benachbarten Längsfaden 54 des benachbarten Längsfadenpaares 55. Hierdurch ergibt sich eine nur geringe Verwindung der Schlaufen 49, 50 und ein auf der Papierseite sehr gleichmäßiges Warenbild des Trockensiebes 41.The
Erfindungsgemäß sind sämtliche Fäden 42, 44, 45, 46, 47 des Trockensiebes 41 aus den
Das in den
Bei der Ausführungsform gemäß
Bei der Ausführungsform gemäß
Die Zusatzkettfäden 59, 61, 62 bilden ein strukturelles Prinzip, das sich außerordentlich vielgestaltig umsetzen lässt, so dass sich das damit versehene Basisgewebe 56 hinsichtlich einer Reihe von Eigenschaften flexibel an die jeweiligen Anforderungen in den einzelnen Partien der Papiermaschine oder Zellstoffentwässerungsmaschine anpassen lässt. Die Zusatzkettfäden 59 ,61, 62 erlauben insbesondere eine Art Funktionstrennung, indem die Konstruktion des Basisgewebes 56 in optimaler Weise an die Grundanforderungen wie beispielsweise Festigkeit und Dimensionsstabilität angepasst wird, während andere Eigenschaften, wie beispielsweise Entwässerung, Abriebfestigkeit, Faserretention oder dergleichen, mit Hilfe der Zusatzkettfäden 59, 61, 62 optimiert werden.The
Gemäß der vorliegenden Erfindung sind sowohl bei der Ausführungsform aus
Die vorstehend beschriebenen Ausführungsformen erfindungsgemäßer Bespannungen sind lediglich beispielhaft und nicht einschränkend zu verstehen. Die Verwendung von Monofilamenten aus teilaromatischen Co-Polyamid kann selbstverständlich auch bei Bespannungen anderer Ausgestaltung vorgesehen sein, wobei die bereits ausführlich erörterten, damit verbundenen Vorteile dann ebenfalls erzielt werden. Rein beispielhaft sei für weitere Ausgestaltungen von Bespannungen auf sämtliche verbleibenden Ausführungsbeispiele aus sämtlichen vorstehend genannten, ebenfalls auf die Anmelderin zurückgehenden Druckschriften verwiesen.The above-described embodiments of coverings according to the invention are to be understood only as examples and not as restrictive. The use of monofilaments made from partially aromatic copolyamide can, of course, also be provided for clothing of a different design, the advantages which have already been discussed in detail and associated with this then also being achieved. As a purely exemplary example, reference is made to all remaining exemplary embodiments from all of the above-mentioned documents, which also go back to the applicant, for further designs of coverings.
Claims (13)
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2018
- 2018-06-21 DE DE202018103522.3U patent/DE202018103522U1/en active Active
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2019
- 2019-05-21 ES ES19175689T patent/ES2836757T3/en active Active
- 2019-05-21 PT PT191756899T patent/PT3587664T/en unknown
- 2019-05-21 EP EP19175689.9A patent/EP3587664B1/en active Active
- 2019-06-17 US US16/443,068 patent/US11230808B2/en active Active
- 2019-06-21 JP JP2019115070A patent/JP2020012225A/en active Pending
- 2019-06-21 CN CN201910541493.2A patent/CN110629580B/en active Active
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Also Published As
Publication number | Publication date |
---|---|
CN110629580B (en) | 2021-10-08 |
JP2020012225A (en) | 2020-01-23 |
EP3587664B1 (en) | 2020-10-14 |
CN110629580A (en) | 2019-12-31 |
US20190390406A1 (en) | 2019-12-26 |
US11230808B2 (en) | 2022-01-25 |
DE202018103522U1 (en) | 2018-09-14 |
ES2836757T3 (en) | 2021-06-28 |
PT3587664T (en) | 2020-12-21 |
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