EP3399011A1 - Compositions appropriées pour le nettoyage de toilettes comprenant des liants non hydrauliques - Google Patents
Compositions appropriées pour le nettoyage de toilettes comprenant des liants non hydrauliques Download PDFInfo
- Publication number
- EP3399011A1 EP3399011A1 EP17169474.8A EP17169474A EP3399011A1 EP 3399011 A1 EP3399011 A1 EP 3399011A1 EP 17169474 A EP17169474 A EP 17169474A EP 3399011 A1 EP3399011 A1 EP 3399011A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- composition according
- composition
- acid
- toilet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 119
- 239000011230 binding agent Substances 0.000 title claims abstract description 25
- 238000004140 cleaning Methods 0.000 title claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 15
- 239000003205 fragrance Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000002304 perfume Substances 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 8
- 238000009472 formulation Methods 0.000 claims abstract description 4
- 239000013042 solid detergent Substances 0.000 claims abstract description 4
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 4
- -1 C20 alkanes Chemical class 0.000 claims description 64
- 150000001298 alcohols Chemical class 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 20
- 239000002736 nonionic surfactant Substances 0.000 claims description 19
- 239000003945 anionic surfactant Substances 0.000 claims description 17
- 102000004190 Enzymes Human genes 0.000 claims description 15
- 108090000790 Enzymes Proteins 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 13
- 150000007513 acids Chemical class 0.000 claims description 13
- 239000004599 antimicrobial Substances 0.000 claims description 13
- 239000003086 colorant Substances 0.000 claims description 13
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 12
- 235000019658 bitter taste Nutrition 0.000 claims description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 8
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 8
- 239000010440 gypsum Substances 0.000 claims description 8
- 229910052602 gypsum Inorganic materials 0.000 claims description 8
- 239000004571 lime Substances 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 7
- 239000004568 cement Substances 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 5
- 239000000920 calcium hydroxide Substances 0.000 claims description 5
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- IQYKECCCHDLEPX-UHFFFAOYSA-N chloro hypochlorite;magnesium Chemical compound [Mg].ClOCl IQYKECCCHDLEPX-UHFFFAOYSA-N 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- 239000004570 mortar (masonry) Substances 0.000 claims description 5
- 239000004573 non-hydraulic lime Substances 0.000 claims description 5
- 239000002694 phosphate binding agent Substances 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 4
- 238000005260 corrosion Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- DUFKCOQISQKSAV-UHFFFAOYSA-N Polypropylene glycol (m w 1,200-3,000) Chemical compound CC(O)COC(C)CO DUFKCOQISQKSAV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- 244000005700 microbiome Species 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 46
- 239000003921 oil Substances 0.000 description 42
- 235000019198 oils Nutrition 0.000 description 41
- 125000000217 alkyl group Chemical group 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 24
- 125000004432 carbon atom Chemical group C* 0.000 description 17
- 235000014113 dietary fatty acids Nutrition 0.000 description 17
- 239000000194 fatty acid Substances 0.000 description 17
- 229930195729 fatty acid Natural products 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 17
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 150000002191 fatty alcohols Chemical class 0.000 description 15
- 229940088598 enzyme Drugs 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 14
- 239000007787 solid Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- 229940083542 sodium Drugs 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 150000003871 sulfonates Chemical class 0.000 description 10
- 150000002170 ethers Chemical class 0.000 description 9
- 244000089742 Citrus aurantifolia Species 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- NNKXWRRDHYTHFP-HZQSTTLBSA-N (r)-[(2s,4s,5r)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methanol;hydron;dichloride Chemical compound Cl.Cl.C([C@H]([C@H](C1)C=C)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OC)C=C21 NNKXWRRDHYTHFP-HZQSTTLBSA-N 0.000 description 7
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000000314 lubricant Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 6
- 230000000845 anti-microbial effect Effects 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 6
- 239000003240 coconut oil Substances 0.000 description 6
- 238000007046 ethoxylation reaction Methods 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 6
- 229920000151 polyglycol Polymers 0.000 description 6
- 239000010695 polyglycol Substances 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 239000001096 (4-ethenyl-1-azabicyclo[2.2.2]octan-7-yl)-(6-methoxyquinolin-4-yl)methanol hydrochloride Substances 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 125000002947 alkylene group Chemical group 0.000 description 5
- 229960004106 citric acid Drugs 0.000 description 5
- 235000015165 citric acid Nutrition 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 229960001811 quinine hydrochloride Drugs 0.000 description 5
- 238000007493 shaping process Methods 0.000 description 5
- 150000003505 terpenes Chemical class 0.000 description 5
- QRYRORQUOLYVBU-VBKZILBWSA-N Carnosic acid Natural products CC([C@@H]1CC2)(C)CCC[C@]1(C(O)=O)C1=C2C=C(C(C)C)C(O)=C1O QRYRORQUOLYVBU-VBKZILBWSA-N 0.000 description 4
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
- DUAGQYUORDTXOR-GPQRQXLASA-N Gentiopicrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@H]1[C@H](C=C)C2=CCOC(=O)C2=CO1 DUAGQYUORDTXOR-GPQRQXLASA-N 0.000 description 4
- DUAGQYUORDTXOR-WULZUDSJSA-N Gentiopicrin Natural products O([C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1)[C@H]1[C@@H](C=C)C=2C(C(=O)OCC=2)=CO1 DUAGQYUORDTXOR-WULZUDSJSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- ZIKZPLSIAVHITA-UHFFFAOYSA-N Nomilinic acid Natural products CC(=O)OC(CC(O)=O)C1(C)C(C(C)(C)O)CC(=O)C(C23OC2C(=O)O2)(C)C1CCC3(C)C2C=1C=COC=1 ZIKZPLSIAVHITA-UHFFFAOYSA-N 0.000 description 4
- REFJWTPEDVJJIY-UHFFFAOYSA-N Quercetin Chemical compound C=1C(O)=CC(O)=C(C(C=2O)=O)C=1OC=2C1=CC=C(O)C(O)=C1 REFJWTPEDVJJIY-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 229910021538 borax Inorganic materials 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 4
- 239000002738 chelating agent Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 229960005150 glycerol Drugs 0.000 description 4
- 229930182470 glycoside Natural products 0.000 description 4
- 150000002338 glycosides Chemical class 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229960003975 potassium Drugs 0.000 description 4
- 235000007686 potassium Nutrition 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- 235000010339 sodium tetraborate Nutrition 0.000 description 4
- 239000008247 solid mixture Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- AKYHKWQPZHDOBW-UHFFFAOYSA-N (5-ethenyl-1-azabicyclo[2.2.2]octan-7-yl)-(6-methoxyquinolin-4-yl)methanol Chemical compound OS(O)(=O)=O.C1C(C(C2)C=C)CCN2C1C(O)C1=CC=NC2=CC=C(OC)C=C21 AKYHKWQPZHDOBW-UHFFFAOYSA-N 0.000 description 3
- UNWRHVZXVVTASG-UHFFFAOYSA-N 1,3-dichloro-1,3,5-triazinane-2,4,6-trione;sodium Chemical compound [Na].ClN1C(=O)NC(=O)N(Cl)C1=O UNWRHVZXVVTASG-UHFFFAOYSA-N 0.000 description 3
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 3
- 239000001606 7-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-5-hydroxy-2-(4-hydroxyphenyl)chroman-4-one Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920000858 Cyclodextrin Polymers 0.000 description 3
- 239000001576 FEMA 2977 Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229930013930 alkaloid Natural products 0.000 description 3
- USMNOWBWPHYOEA-UHFFFAOYSA-N alpha-thujone Natural products CC1C(=O)CC2(C(C)C)C1C2 USMNOWBWPHYOEA-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 229940024606 amino acid Drugs 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- LOUPRKONTZGTKE-UHFFFAOYSA-N cinchonine Natural products C1C(C(C2)C=C)CCN2C1C(O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000002070 germicidal effect Effects 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
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- 239000010410 layer Substances 0.000 description 3
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- 239000000463 material Substances 0.000 description 3
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 3
- DFPMSGMNTNDNHN-ZPHOTFPESA-N naringin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1O[C@H]1[C@H](OC=2C=C3O[C@@H](CC(=O)C3=C(O)C=2)C=2C=CC(O)=CC=2)O[C@H](CO)[C@@H](O)[C@@H]1O DFPMSGMNTNDNHN-ZPHOTFPESA-N 0.000 description 3
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- 239000004328 sodium tetraborate Substances 0.000 description 3
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- PZHWYURJZAPXAN-ILOFNVQHSA-N (+)-absinthin Chemical compound C([C@H]1[C@H](C)C(=O)O[C@@H]11)C[C@](C)(O)[C@@H]2[C@H]3[C@@H]4[C@H]5[C@@](C)(O)CC[C@H]6[C@H](C)C(=O)O[C@@H]6C5=C(C)[C@@H]4[C@]21C(C)=C3 PZHWYURJZAPXAN-ILOFNVQHSA-N 0.000 description 2
- USMNOWBWPHYOEA-XKSSXDPKSA-N (+)-beta-thujone Chemical compound O=C([C@H]1C)C[C@@]2(C(C)C)[C@@H]1C2 USMNOWBWPHYOEA-XKSSXDPKSA-N 0.000 description 2
- 229930007107 (+)-beta-thujone Natural products 0.000 description 2
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- 229930007105 (-)-alpha-thujone Natural products 0.000 description 2
- DBOVHQOUSDWAPQ-UHFFFAOYSA-N (4aS)-6c-[O2-(3,5,3'-trihydroxy-biphenyl-2-carbonyl)-beta-D-glucopyranosyloxy]-5t-vinyl-(4ar)-4,4a,5,6-tetrahydro-3H-pyrano[3,4-c]pyran-1-one Natural products OC1C(O)C(CO)OC(OC2C(C3C(C(OCC3)=O)=CO2)C=C)C1OC(=O)C1=C(O)C=C(O)C=C1C1=CC=CC(O)=C1 DBOVHQOUSDWAPQ-UHFFFAOYSA-N 0.000 description 2
- ZNOVTXRBGFNYRX-STQMWFEESA-N (6S)-5-methyltetrahydrofolic acid Chemical compound C([C@@H]1N(C=2C(=O)N=C(N)NC=2NC1)C)NC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 ZNOVTXRBGFNYRX-STQMWFEESA-N 0.000 description 2
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 2
- OHBQPCCCRFSCAX-UHFFFAOYSA-N 1,4-Dimethoxybenzene Chemical compound COC1=CC=C(OC)C=C1 OHBQPCCCRFSCAX-UHFFFAOYSA-N 0.000 description 2
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- 235000019831 pentapotassium triphosphate Nutrition 0.000 description 1
- ATGAWOHQWWULNK-UHFFFAOYSA-I pentapotassium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ATGAWOHQWWULNK-UHFFFAOYSA-I 0.000 description 1
- LQPLDXQVILYOOL-UHFFFAOYSA-I pentasodium;2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O LQPLDXQVILYOOL-UHFFFAOYSA-I 0.000 description 1
- QPTMDBQLCWRDCK-UHFFFAOYSA-I pentasodium;[2-[bis[[hydroxy(oxido)phosphoryl]methyl]amino]ethyl-(phosphonatomethyl)amino]methyl-hydroxyphosphinate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].OP([O-])(=O)CN(CP(O)([O-])=O)CCN(CP(O)([O-])=O)CP([O-])([O-])=O QPTMDBQLCWRDCK-UHFFFAOYSA-I 0.000 description 1
- OSBMVGFXROCQIZ-UHFFFAOYSA-I pentasodium;[bis(phosphonatomethyl)amino]methyl-hydroxyphosphinate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].OP([O-])(=O)CN(CP([O-])([O-])=O)CP([O-])([O-])=O OSBMVGFXROCQIZ-UHFFFAOYSA-I 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 150000007875 phellandrene derivatives Chemical class 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940100595 phenylacetaldehyde Drugs 0.000 description 1
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical class OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 239000001738 pogostemon cablin oil Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- FJGQHLDAFYBROH-UHFFFAOYSA-N propane-1,2,3-triol;sulfo hydrogen sulfate Chemical compound OCC(O)CO.OS(=O)(=O)OS(O)(=O)=O FJGQHLDAFYBROH-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000006337 proteolytic cleavage Effects 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- ZMQAAUBTXCXRIC-UHFFFAOYSA-N safrole Chemical compound C=CCC1=CC=C2OCOC2=C1 ZMQAAUBTXCXRIC-UHFFFAOYSA-N 0.000 description 1
- 239000010670 sage oil Substances 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 230000024053 secondary metabolic process Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Natural products C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 239000011684 sodium molybdate Substances 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 229940083982 sodium phytate Drugs 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- FMYOMWCQJXWGEN-WYRLRVFGSA-M sodium;(2r,3r,4s,5r,6r)-2,3,4,5,6,7-hexahydroxyheptanoate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O)C([O-])=O FMYOMWCQJXWGEN-WYRLRVFGSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- ZIJKGAXBCRWEOL-UHFFFAOYSA-N sucrose octaacetate Chemical compound CC(=O)OC1C(OC(C)=O)C(COC(=O)C)OC1(COC(C)=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(COC(C)=O)O1 ZIJKGAXBCRWEOL-UHFFFAOYSA-N 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 229940113082 thymine Drugs 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- FYZXEMANQYHCFX-UHFFFAOYSA-K tripotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [K+].[K+].[K+].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O FYZXEMANQYHCFX-UHFFFAOYSA-K 0.000 description 1
- FEFAREAYTNHYNP-UHFFFAOYSA-K tripotassium;[bis[[hydroxy(oxido)phosphoryl]methyl]-oxidoazaniumyl]methyl-hydroxyphosphinate Chemical compound [K+].[K+].[K+].OP([O-])(=O)C[N+]([O-])(CP(O)([O-])=O)CP(O)([O-])=O FEFAREAYTNHYNP-UHFFFAOYSA-K 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 229940117565 trisodium dicarboxymethyl alaninate Drugs 0.000 description 1
- 229940048198 trisodium hedta Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- WHNXAQZPEBNFBC-UHFFFAOYSA-K trisodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O WHNXAQZPEBNFBC-UHFFFAOYSA-K 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 229940117960 vanillin Drugs 0.000 description 1
- WJUFSDZVCOTFON-UHFFFAOYSA-N veratraldehyde Chemical compound COC1=CC=C(C=O)C=C1OC WJUFSDZVCOTFON-UHFFFAOYSA-N 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D9/022—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of solid substances introduced in the bowl or the supply line
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D2009/024—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing using a solid substance
Definitions
- the present invention relates to compositions suitable for lavatory cleaning, in particular useable as solid rimblocks, comprising at least one surfactant, at least one filler and at least one non-hydraulic binding agent. Furthermore, to a toilet cleaning system comprising the composition of the present invention and a release device. Moreover, to the use of a non-hydraulic binding agent in sanitary cleaning compositions, for stabilizing the shape of a toilet rimblock or for increasing child-safety of a toilet rimblock or solid detergent.
- Solid lavatory cleaning compositions are known for a long time.
- There are two main categories of (in-bowl) lavatory cleaning composition namely self-adhesive "cageless" gels and solid rimblocks which require a hanger.
- the solid rimblock with hanger can be divided into two types namely compositions which are surrounded by the cage and "cageless” solid compositions which are applied via a hanger (stick) into the toilet bowl and stick to the hanger but are neither surrounded by the cage nor self-adhesive. Children can reach such "cageless" solid compositions under certain circumstances in the toilet bowl. When unattended, little children tend to test objects with their mouth.
- one object of the present invention is to provide a composition which has improved child safety when used as a "cageless” solid rimblock.
- Another object of the present invention is the provision of a composition which additionally does not crack and additionally provides evenly dissolution when used as a "cageless" solid rimblock.
- the inventors of the present invention have surprisingly found that the addition of at least one non-hydraulic binding agent to a lavatory cleaning composition can solve the above described drawbacks of common solid "cageless" rimblocks.
- the present invention relates to:
- the composition described herein comprises at least one anionic surfactant, preferably at least one anionic surfactant and at least one non-ionic surfactant, more preferably at least one anionic surfactant selected from sulfonates, or sulfates or combinations thereof, even more preferred at least one anionic surfactant selected from sulfonates, or sulfates, and at least one non-ionic surfactant selected from alcohol alkoxylates, alkyl polyglycosides, fatty acid alkanolamides, alkylamine oxides, or alkylglucamides or combinations thereof.
- the composition described herein comprises as component ii) at least one filler selected from sulfate and carbonate fillers, preferably at least one filler selected from sodium sulfate, calcium sulfate, sodium carbonate, or calcium carbonate or combinations thereof, more preferably sodium sulfate.
- the composition described herein comprises as component iii) at least one non-hydraulic binding agent selected from clay; gypsum, like calcium sulfate dehydrate; non-hydraulic lime; amorphous calcium oxide; amorphous magnesium oxide; fireclay mortar; magnesium oxychloride cement; white lime; phosphate binder; soluble glass; or slaked lime or combinations thereof; preferably comprises at least one non-hydraulic binding agent selected from gypsum, like calcium sulfate dehydrate; non-hydraulic lime; amorphous calcium oxide; amorphous magnesium oxide; fireclay mortar; magnesium oxychloride cement; white lime; phosphate binder; soluble glass; or slaked lime or combinations thereof; more preferably comprises gypsum.
- component iv) has a bitterness value of from 1,000 to 200,000, preferably iv) comprises at least one bittering agent selected from glycosides, isoprenoids, alcaloids, or amino acids; more preferably iv) comprises flavonoids such as quercetin and naringin, iridoid glycosides such as aucubin, secoiridoid glycosides such as amarogentin, dihydrofoliamentin, gentiopicroside, gentiopicrin, swertiamarin, sweroside, gentioflavosid, centaurosid, metafolin, harpagoside, centapicrine, sailicin, and condurangin, sesquiterpene lactones such as absinthin, artabsin, cnicin, lactucin, lactucopicrin, and salonitenolid, monoterpene ketones (thujones) such as ⁇ -thujone and
- component v) comprises at least one solvent selected from water, alcohols, C5 to C20 alkanes, glycols like diethylene glycol and dipropylen glycol, and glycerol.
- component vi) comprises at least one additive selected from acids, bases, antimicrobial agents, thickening agents, corrosion inhibitors, flush regulators, enzymes, microorganisms, biofilm reducing agents, limescale reducing agents, pigments, colorants, or dyes or combinations thereof; preferably vi) comprises at least one additive selected from acids, antimicrobial agents, pigments, colorants, or dyes, more preferably vi) comprises at least one additive selected from acids, and colorants or combinations thereof.
- the composition comprises as component i) 19 to 84 wt.-%, preferably 30 to 70 wt.-%, anionic surfactants and 1 to 15 wt.-%, preferably 3 to 10 wt.-%, non-ionic surfactants, based on the total weight of the composition; preferably these anionic surfactants are sulfonates and the nonionic surfactants are alcohol alkoxylates; more preferably these anionic surfactants are olefinic sulfonates and alkyl benzene sulfonates and the nonionic surfactants are fatty alcohol ethoxylates, most preferably C14 to C16 olefinic sulfonates are present in 5 to 50, or 10 to 30 wt.-%, or 15 to 20 wt.-% and the C10 to C13 alkyl benzene sulfonates are present in 20 to 40 wt.-%, more preferably 20 to 35 w
- the at least one solvent v) comprises water and water is present in 0.1 to 10 wt.-%, preferably in 0.5 to 5 wt.-%, more preferably in 1 to 3 wt.-%, based on the total weight of the composition.
- the composition comprises less than 0.01 wt.-%, preferably less than 0.0001 wt.-%, more preferably less than 0.00001 wt.-% of titanium dioxide, based on the total weight of the composition, more preferably the composition is free of titanium dioxide.
- the present invention also relates to a toilet rimblock comprising the composition described herein. Also emcompassed is a toilet cleaning system comprising the toilet rimblock according to the invention and a release device.
- the invention is furthermore directed to the use of the composition according to any one of the embodiments described herein as a toilet rimblock formulation for cageless release devices.
- non-hydraulic binding agent in sanitary cleaning compositions for stabilizing the shape of a toilet rimblock and the use of a non-hydraulic binding agent for increasing child-safety of a toilet rimblock or solid detergent.
- Suitable anionic surfactants for use in the composition may include, but are not limited to, aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates, and aliphatic sulfonates such as alkane sulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates and lignin sulfonates.
- aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates
- aliphatic sulfonates such as alkane sulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates and lig
- the anionic surfactants preferably comprise fatty alcohol sulfates and/or fatty alcohol ether sulfates, in particular the fatty alcohol sulfates, in a preferred embodiment of the present invention.
- Fatty alcohol sulfates are products from sulfating reactions on corresponding alcohols
- fatty alcohol ether sulfates are products of sulfating reactions on alkoxylated alcohols.
- alkoxylated alcohols are generally understood by the person skilled in the art to mean the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably with the longer chain alcohols.
- n moles of ethylene oxide react with one mole of alcohol to form, depending on the reaction conditions, a complex mixture of addition products with different degrees of ethoxylation.
- Another embodiment of the alkoxylation consists in the use of mixtures of the alkylene oxides, preferably a mixture of ethylene oxide and propylene oxide.
- Preferred fatty alcohol ether sulfates are the sulfates of low-ethoxylated fatty alcohols with 1 to 4 ethylene oxide units (EO), in particular 1 to 2 EO, for example 1.3 EO.
- Exemplary useful anionic surfactants which may be used in the composition of the invention can be broadly described as the water-soluble salts, particularly the alkali metal salts, of organic sulfuric acid reaction products having in their molecular structure an alkyl or alkaryl radical containing from about 8 to about 22 carbon atoms and a radical selected from the group consisting of sulfonic acid and sulfuric acid ester radicals (Included in the term alkyl is the alkyl portion of higher acyl radicals).
- Suitable examples of the anionic surfactants which can be employed in the present invention are the sodium or potassium alkyl sulfates, especially those obtained by sulfating the higher alcohols (C8 to C18 carbon atoms) produced by reducing the glycerides of tallow or coconut oil; sodium or potassium alkyl benzene sulfonates, in which the alkyl group contains from about 9 to about 15 carbon atoms, (the alkyl radical can be a straight or branched aliphatic chain); paraffin sulfonate surfactants having the general formula RSO 3 M, wherein R is a primary or secondary alkyl group containing from about 8 to about 22 carbon atoms (preferably 10 to 18 carbon atoms) and M is an alkali metal, e.g., sodium, lithium or potassium; sodium alkyl glyceryl ether sulfonates, especially those ethers of the higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monogly
- the anionic surfactants comprise one or more linear alkyl benzene sulfonate surfactant wherein the alkyl portion contains 8 to 16 carbon atoms, and most preferably about 11 to 13 carbon atoms.
- a further preferred class of anionic surfactants are alpha olefin sulfonates, as well as salts thereof, e.g., alkali metal salts. Preferred are C9 to C22 alpha olefin sulfonates, particularly C12 to C18 as well as blends of two or more thereof.
- the solid block compositions necessarily include an alpha olefin sulfonate anionic surfactant. Toluene and isopropylenbzene sulfonates are particularly preferred.
- any hydrophobic compound having a carboxy, hydroxy, amido, or amino group with a hydrogen group attached to the nitrogen can be condensed with an alkylene oxide, especially ethylene oxide or with the polyhydration product thereof, a polyalkylene glycol, especially polyethylene glycol, to obtain a water soluble or water dispersible nonionic surfactant compound.
- nonionic surfactants comprise alkoxylates such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers, and fatty acid polyglycol esters or mixtures thereof.
- Ethylene oxide/propylene oxide block polymers, fatty acid alkanolamides and fatty acid polyglycol ethers may be comprised as well.
- Another important class of nonionic surfactants that may be comprised are the polyol surfactants and in particular the glycol surfactants, such as alkyl polyglycosides and fatty acid glucamides.
- the alkyl polyglycosides are particularly preferred, in particular the alkyl polyglucosides as well as above all the fatty alcohol alkoxylates (fatty alcohol polyglycol ethers).
- Preferred alcohol ethoxylates include the condensation products of aliphatic alcohols with 1 to 60 moles of an alkylene oxide, especially ethylene oxide.
- the alkyl chain of the aliphatic alcohol can either be straight or branched, primary or secondary, and generally contains from about 8 to about 22 carbon atoms.
- Examples of such ethoxylated alcohols include the condensation product of myristyl alcohol condensed with about 10 moles of ethylene oxide per mole of alcohol and the condensation product of about 9 moles of ethylene oxide with coconut alcohol (a mixture of fatty alcohols with alkyl chains varying in length from about 10 to 14 carbon atoms).
- Other examples are those C6 to C22 straight-chain alcohols having 3 to 6 moles of ethylene oxide.
- alcohol ethoxylates are C10 oxo-alcohol ethoxylates available from BASF under the Lutensol® ON tradenamelike Lutensol® ON 30; Lutensol® ON 50; Lutensol® ON 60; Lutensol® ON 65; Lutensol® ON 66; Lutensol® ON 70; Lutensol® ON 80; and Lutensol® ON 110.
- ethoxylated alcohols include the Neodol® 91 series non-ionic surfactants available from Shell Chemical Company which are described as C9 to C11 ethoxylated alcohols, like Neodol® 91-2.5, Neodol® 91-6, and Neodol® 91-8.
- Neodol® 91-2.5 have been described as having about 2.5 EO; Neodol® 91-6 has been described as having about 6 EO; and Neodol® 91-8 has been described as having about 8 EO.
- ethoxylated alcohols include the Rhodasurf® DA series non-ionic surfactants available from Rhodia which are described to be branched isodecyl alcohol ethoxylates, like Rhodasurf® DA-530 having 4 moles EO; Rhodasurf® DA-630 having 6 moles EO; and Rhodasurf® DA-639 is a 90% solution of DA-630.
- ethoxylated alcohols include those from Tomah Products (Milton, Wl) under the Tomadol®.
- a further class of useful nonionic surfactants include primary and secondary linear and branched alcohol ethoxylates, such as those based on C6 to C18 alcohols which further include an average of from 2 to 80 moles of ethoxylation per mol of alcohol. These examples include the Genapol® UD like Genapol® UD 030 with 3 EO; Genapol® UD 050 with 5 EO; Genapol® UD 070 with 7 EO; Genapol® UD 080 with 8 EO; Genapol® UD 088 with 8 EO; and Genapol® UD 110 with 11 EO.
- Exemplary useful nonionic surfactants include the condensation products of a secondary aliphatic alcohols containing 8 to 18 carbon atoms in a straight or branched chain configuration condensed with 5 to 30 moles of ethylene oxide, like commercially available under the trade name of Tergitol®. Examples include Tergitol 15-S-12 having 9 EO, or Tergitol 15-S-9 which having 12 EO.
- Most preferred fatty alcohol alkoxylates are unbranched or branched, saturated or unsaturated C8 to C22 alcohols alkoxylated with ethylene oxide (EO) and/or propylene oxide (PO) with a degree of alkoxylation 2 to 30, preferably ethoxylated C12 to 22 fatty alcohols with a degree of ethoxylation of 10 to 30, preferably 12 to 28, particularly 20 to 28, particularly preferably 25, for example C16 to 18 fatty alcohol ethoxylates containing 25 EO.
- EO ethylene oxide
- PO propylene oxide
- Alkyl polyglycosides are surfactants that can be obtained by the reaction of sugars and alcohols using appropriate methods of preparative organic chemistry, whereby according to the method of preparation, one obtains a mixture of monoalkylated, oligomeric or polymeric sugars. They are for example commercially available under the trade name Pluronics® (ex. BASF).
- the compounds are formed by condensing ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol.
- the molecular weight of the hydrophobic portion of the molecule is of the order of 950 to 4,000 and preferably 200 to 2,500 g/mol. The measurement can be performed via GPC with polystyrene standards.
- polyoxyethylene radicals of the hydrophobic portion tends to increase the solubility of the molecule as a whole so as to make the surfactant water-soluble.
- these surfactants are in liquid form at 25°C and particularly satisfactory surfactants are available as those marketed as Pluronics(R) L62 and Pluronics(R) L64.
- Preferred alkyl polyglycosides are the alkyl polyglucosides, wherein the alcohol is particularly preferably a long-chain fatty alcohol or a mixture of long-chain fatty alcohols with branched or unbranched C8 to C18 alkyl chains and the degree of oligomerization (DP) of the sugar is between 1 and 10, advantageously 1 to 6, particularly 1.1 to 3, most preferably 1.1 to 1.7, for example C8 to 10 alkyl-1.5-glucoside (DP of 1.5).
- DP degree of oligomerization
- Their preparation is known to the skilled person. Exemplary methods can be found in K. Hill, W. von Rybinski, G. Stoll "Alkyl Polyglycosides, Technology, Properties and Applications", VCH, 1996 .
- Fatty alcohol ethoxylates are preferably employed in amounts of 0.1 to 20 wt.-%, particularly preferably 4 to 12 wt.-%, and particularly preferably from 7 to 9 wt.-%, based on the total weight of the composition.
- Additional nonionic surfactants such as fatty acid monoalkanolamides and/or alkyl polyglycosides, may be included in amounts of 0.1 to 10 wt.-%, preferably 2 to 6 wt.-%, based on the total weight of the composition.
- the nonionic surfactants can comprise polyalkylene oxide condensates of alkyl phenols.
- These compounds include the condensation products of alkyl phenols having an alkyl group containing from about 6 to 12 carbon atoms in either a straight chain or branched chain configuration with an alkylene oxide, especially an ethylene oxide, the ethylene oxide being present in an amount equal to 5 to 25 moles of ethylene oxide per mole of alkyl phenol.
- the alkyl substituent in such compounds can be derived, for example, from polymerized propylene, diisobutylene and the like.
- Examples of compounds of this type include nonyl phenol condensed with about 9.5 moles of ethylene oxide per mole of nonyl phenol; dodecylphenol condensed with about 12 moles of ethylene oxide per mole of phenol; dinonyl phenol condensed with about 15 moles of ethylene oxide per mole of phenol and diisooctyl phenol condensed with about 15 moles of ethylene oxide per mole of phenol.
- the nonionic surfactants can alternatively be alkoxylated alkanolamides, preferably C8 to C24 alkyl di(C2 to C3 alkanol amides), as described in WO 2007148054 A1 .
- the nonionic surfactants preferably comprise nonionic amine oxide surfactants.
- exemplary amine oxides include: A) Alkyl di (lower alkyl) amine oxides in which the alkyl group has about 10 to 20, and preferably 12 to 16 carbon atoms, and can be straight or branched chain, saturated or unsaturated. The lower alkyl groups include between 1 and 7 carbon atoms.
- Examples include lauryl dimethyl amine oxide, myristyl dimethyl amine oxide, and those in which the alkyl group is a mixture of different amine oxide, dimethyl cocoamine oxide, dimethyl (hydrogenated tallow) amine oxide, and myristyl/palmityl dimethyl amine oxide;
- composition according to the invention may also comprise cationic surfactants and/or amphoteric surfactants.
- a cationic surfactant may be incorporated as a germicide or as a detersive surfactant in the composition of the present invention, particularly when a bleach constituent is absent from the solid block composition.
- Cationic surfactants are per se, well known, and exemplary useful cationic surfactants may be one or more of those described for example in McCutcheon 's Functional Materials, Vol.2, 1998 ; Kirk- Othmer, Encyclopedia of Chemical Technology, 4th Ed., Vol. 23, pp. 481-541 (1997 ).
- preferred cationic surfactants are those which provide a germicidal effect to the concentrate compositions, and especially preferred are quaternary ammonium compounds and salts thereof.
- Exemplary quaternary ammonium salts include the alkyl ammonium halides such as cetyl trimethyl ammonium bromide, alkyl aryl ammonium halides such as octadecyl dimethyl benzyl ammonium bromide, N-alkyl pyridinium halides such as N-cetyl pyridinium bromide, and the like.
- quaternary ammonium salts include those in which the molecule contains either amide, ether or ester linkages such as octyl phenoxy ethoxy ethyl dimethyl benzyl ammonium chloride, N-(laurylcocoaminoformyhnethyl)-pyridinium chloride, and the like.
- Suitable filler include any soluble inorganic alkali, alkaline earth metal salt or hydrate thereof, for example, chlorides such as sodium chloride, magnesium chloride and the like, carbonates and bicarbonates such as sodium carbonate, sodium bicarbonate and the like, sulfates such as magnesium sulfate, copper sulfate, sodium sulfate, zinc sulfate and the like, borax, borates such as sodium borate and the like.
- chlorides such as sodium chloride, magnesium chloride and the like
- carbonates and bicarbonates such as sodium carbonate, sodium bicarbonate and the like
- sulfates such as magnesium sulfate, copper sulfate, sodium sulfate, zinc sulfate and the like
- borax borates such as sodium borate and the like.
- compositions can further optionally include 0.1 to 15 wt.-%, preferably 0.5 to 5 wt.-% of a non-salt filler material, based on the total weight of the composition.
- a non-salt filler material based on the total weight of the composition.
- Such fillers are typically particulate solid water-insoluble materials which may be based on inorganic materials such as talc, titanium dioxide or silica, particulate organic polymeric materials such as finely comminuted water insoluble synthetic polymers.
- non-hydraulic binding agents Typical for non-hydraulic binding agents is that hardening takes place only at air and not in water. In contrast to that hydraulic binders, like cement, harden even underwater.
- the non-hydraulic binding agent comprises a compound selected from clay; gypsum, like calcium sulfate dehydrate; non-hydraulic lime; amorphous calcium oxide; amorphous magnesium oxide; fireclay mortar; magnesium oxychloride cement; white lime; phosphate binder; soluble glass; or slaked lime; or mixtures thereof preferably wherein the non-hydraulic binding agent comprises at least one compound selected from gypsum, like calcium sulfate dehydrate; non-hydraulic lime; amorphous calcium oxide; amorphous magnesium oxide; fireclay mortar; magnesium oxychloride cement; white lime; phosphate binder; soluble glass; or slaked lime; or mixtures thereof; more preferably the non-hydraulic binding agent comprises gypsum.
- bittering agents are known in the field of cleaning products like laundry detergents or hard surface cleaning compositions.
- suitable bittering agents are disclosed in WO2014/026855 A1 and WO2014/026856 A1 to which reference is explicitly made.
- the addition of bittering agent to the composition leads to a further increase of child safety of the product.
- suitable glycosides are flavonoids such as quercetin or naringin, iridoid glycosides such as aucubin, and in particular secoiridoid glycosides such as amarogentin, dihydrofoliamentin, gentiopicroside, gentiopicrin, swertiamarin, sweroside, gentioflavosid, centaurosid, metafolin, harpagoside, and centapicrine, sailicin, or condurangin.
- flavonoids such as quercetin or naringin
- iridoid glycosides such as aucubin
- secoiridoid glycosides such as amarogentin, dihydrofoliamentin, gentiopicroside, gentiopicrin, swertiamarin, sweroside, gentioflavosid, centaurosid, metafolin, harpagoside, and centapicrine, sailicin,
- Isoprenoids are compounds which are formally derived from isoprene. Examples are in particular terpenes and terpenoids.
- isoprenoids examples include sesquiterpene lactones such as absinthin, artabsin, cnicin, lactucin, lactucopicrin, or salonitenolid, monoterpene ketones (thujones) such as alpha -thujone or beta -thujone, tetranortriterpenes (limonoids) such as deoxylimonene, deoxylimonenic acid, limonene, ichangin, isoobacunonic acid, obacunone, obacunonic acid, nomilin, or nomilinic acid, and terpenes such as marrubin, premarrubin, carnosol, carnosolic acid, or quassin.
- sesquiterpene lactones such as absinthin, artabsin, cnicin, lactucin, lactucopicrin, or salonitenolid
- monoterpene ketones such as alpha -thujone or
- Alkaloids refer to naturally occurring, chemically heterogeneous, usually alkaline, nitrogen-containing organic compounds of the secondary metabolism which act on the animal or human organism.
- suitable alkaloids include quinine hydrochloride, quinine hydrogen sulfate, quinine dihydrochloride, quinine sulfate, columbin, and caffeine.
- Suitable amino acids include threonine, methionine, phenylalanine, tryptophan, arginine, histidine, valine, and asparagic acid.
- the bitterness value is the reciprocal value of the dilution of an agent in a solvent or an extraction which barely tastes bitter.
- the at least one solvent comprises compounds selected from water, alcohols, alkyl ether, C5 to C20 alkanes, glycol like diethylene glycol and dipropylen glycol, and glycerol. In more preferred embodiments the at least one solvent comprises water.
- compositions according to the invention may comprise one or more acids and/or their salts to increase the cleaning power against lime scale and urine scale.
- Organic acids such as formic acid, acetic acid, citric acid, glycolic acid, lactic acid, succinic acid, adipic acid, malic acid, tartaric acid and gluconic acid as well as their mixtures are particularly suitable as the acids for the present invention.
- the mineral acids hydrochloric acid, sulphuric acid, phosphoric acid and nitric acid or even amido sulfonic acid or their mixtures can also be employed.
- the acids and/or their salts are preferably selected from the group consisting of citric acid, and lactic acid, any of their salts, and mixtures thereof. They are preferably employed in amounts of 0.01 to 10 wt.-%, and particularly preferably from 0.2 to 5 wt.-%, based on the total weight of the composition.
- alkalis may be included in the inventive compositions.
- ammonia and/or alkanolamines with 1 to 9 carbon atoms in the molecule can be used, preferably the ethanolamines, and especially monoethanolamine.
- the composition according to the invention comprises one or more antimicrobial agents, preferably in an amount of 0.01 to 1 wt.-%, advantageously 0.02 to 0.8.-wt %, especially 0.05 to 0.5.-wt %, particularly preferably 0.1 to 0.3 wt.-%, and most preferably 0.2 wt.-%, based on the total weight of the composition.
- antimicrobial agents does not include cationic surfactants, which however can have an antimicrobial function.
- disinfection, sanitation, antimicrobial action and antimicrobial agent have the usual technical meaning.
- disinfection in the strictest sense of medical practice means the killing of -- theoretically all -- infectious germs
- sanitation it is understood to mean the greatest possible elimination of all -- even the saprophytic germs that are normally not harmful to humans.
- degree of disinfection or sanitation depends on the antimicrobial action of the composition used which decreases with decreasing content of antimicrobial agent or increasing dilution of the composition used.
- Suitable exemplary antimicrobial agents are preferably selected from the group consisting of alcohols, amines, aldehydes, antimicrobial acids and salts thereof, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen and nitrogen acetals and formals, benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propinyl butyl carbamate, iodine, iodophores, compounds that split off active chlorine, peroxides, and mixtures thereof.
- Preferred antimicrobial agents are preferably selected from the group consisting of ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerin, undecylenic acid, citric acid, lactic acid, benzoic acid, salicylic acid, thymol, 2-benzyl-4-chlorophenol, 2,2'-methylene-bis-(6-bromo-4-chlorophenol), 2,4,4'-trichloro-2'-hydroxydiphenyl ether, N-(4-chlorphenyl)-N-(3,4-dichlorophenyl) urea, N,N'-(1,10-decanediyldi-1-pyridinyl-4-ylidene)bis-(1-octanamine)dihydrochloride, N,N'-bis-(4-chlorophenyl)-3,12-diimino
- antimicrobially active ethereal oils can also be employed that simultaneously provide a perfuming benefit.
- Particularly preferred antimicrobial agents are selected from the group consisting of salicylic acid, especially benzalkonium chloride, peroxy compounds, especially hydrogen peroxide, alkali metal hypochlorite, sodium dichloroisocyanurate, and mixtures thereof.
- Preservatives may also be incorporated in the compositions according to the invention. Essentially, the substances cited above as antimicrobial agents may also function as preservatives.
- chelating agents also known as sequestrants, are ingredients that are capable of complexing and inactivating metal ions so as to prevent their detrimental action on the stability or on the appearance of the agent, e.g. turbidity. It is important to complex the calcium and magnesium ions in hard water as they are incompatible with numerous ingredients. The complexation of the ions of heavy metals such as iron or copper also retards the oxidative decomposition of the finished composition. In addition, the chelating agents support the cleaning action.
- the following exemplary chelating agents named according to INCI are suitable: aminotrimethylene phosphonic acid, beta-alanine diacetic acid, calcium disodium EDTA, citric acid, cyclodextrin, cyclohexanediamine tetraacetic acid, diammonium citrate, diammonium EDTA, diethylenetriamine pentamethylene phosphonic acid, dipotassium EDTA, disodium azacycloheptane diphosphonate, disodium EDTA, disodium pyrophosphate, EDTA, etidronic acid, galactaric acid, gluconic acid, glucuronic acid, HEDTA, hydroxypropyl cyclodextrin, methyl cyclodextrin, pentapotassium triphosphate, pentasodium aminotrimethylene phosphonate, pentasodium ethylenediamine tetramethylene phosphonate, pentasodium pentetate,
- compositions according to the invention can further comprise polymers. They can act, for example, to reduce the formation of lime scale as well as the propensity to resoiling.
- preferred polymers are acrylic polymers, such as those commercially available from Rhodia under the trade name Mirapol (Registered trademark).
- the composition according to the invention can comprise one or more colorants as additional ingredients. Both water-soluble as well as oil-soluble colorants can be used as the colorants. In the selection of suitable colorants one has to take care of the compatibility with other ingredients present, for example bleaching agents, and one has to ensure added colorant does not substantively stain the toilet ceramics, even after long periods of action.
- the colorants are preferably incorporated in an amount of 0.0001 to 0.1 wt %, particularly in an amount of 0.0005 to 0.05 wt %, and particularly preferably from 0.001 to 0.01 wt %.
- Water-soluble and/or water-insoluble builders can optionally be employed in the compositions according to the invention.
- water-soluble builders are preferred, as they generally have less of a tendency to leave behind insoluble residues on hard surfaces.
- Conventional builders which may be present in accordance with the invention include low molecular weight polycarboxylic acids and salts thereof, the homopolymeric and copolymeric polycarboxylic acids and salts thereof, citric acid and salts thereof, carbonates, phosphates and silicates.
- Water-insoluble builders include the zeolites, which can also be used, as well as mixtures of the above described builder substances.
- Bleaching agents may also be included to the compositions of the present invention.
- Suitable bleaching agents include peroxides, peracids and/or perborates. Particularly preferably for use herein is hydrogen peroxide.
- sodium hypochlorite is less suitable in acidic cleaning agents due to the release of poisonous chlorine gas vapor, but can be employed in cleaning agents adjusted to alkaline pH.
- a bleach activator can also be used in addition to the bleaching agent.
- Corrosion inhibitors are for example the following substances named according to INCI and can be present in the composition of the present invention: Cyclohexylamine, Diammonium Phosphate, Dilithium Oxalate, Dimethylamino Methylpropanol, Dipotassium Oxalate, Dipotassium Phosphate, Disodium Phosphate, Disodium Pyrophosphate, Disodium Tetrapropenyl Succinate, Hexoxyethyl Diethylammonium, Phosphate, Nitromethane, Potassium Silicate, Sodium Aluminate, Sodium Hexametaphosphate, Sodium Metasilicate, Sodium Molybdate, Sodium Nitrite, Sodium Oxalate, Sodium Silicate, Stearamidopropyl Dimethicone, Tetrapotassium Pyrophosphate, Tetrasodium Pyrophosphate, Triisopropanolamine.
- flush regulators act primarily to control the consumption of the agent during use in such a way that the intended lifetime is optimized.
- Solid long-chain fatty acids such as stearic acid
- fatty acid ethanolamides such as coco fatty acid monoethanolamide
- solid polyethylene glycols such as those having number average molecular weights between 10,000 and 50,000. Those can be present in the composition of the present invention.
- an adhesion inhibitor can be added to improve the processability.
- Preferred adhesion inhibitors are dolomite powder or titanium dioxide powder of fine particle size distribution. They improve the processability when shaping the product into spheres, and markedly reduces both attrition and tack.
- the agent can also comprise enzymes, for example proteases, lipases, amylases, hydrolases and/or cellulases.
- the enzymes can be added to the composition in each form established according to the prior art. These include solutions of the enzyme, advantageously as concentrated as possible, anhydrous and/or with added stabilizers.
- the enzymes can be encapsulated, for example by spray drying or extrusion of the enzyme solution together with a preferably natural polymer or in the form of capsules, for example those in which the enzyme is embedded in a solidified gel, or in those of the core-shell type, in which an enzyme-containing core is coated with a water-, air- and/or chemical-impervious protective layer.
- Further active agents for example stabilizers, emulsifiers, pigments, bleaches or colorants can be applied in additional layers.
- Such capsules are made using known methods, for example by vibratory granulation or roll compaction or by fluidized bed processes.
- these types of granulates for example with a coated polymeric film former, are dust-free and as a result of the coating are storage stable.
- enzyme stabilizers can be present in the enzyme-containing agent, in order to protect an enzyme comprised in an agent according to the invention against damage such as for example inactivation, denaturing or decomposition for example by physical effects, oxidation or proteolytic cleavage.
- enzyme stabilizers benzamidine hydrochloride, borax, boric acid, boronic acids or their salts or esters, primarily derivatives containing aromatic groups, for example substituted phenylboronic acids or their salts or esters; peptide aldehydes (olgopeptides with reduced C-terminus), amino alcohols such as mono, di, triethanolamine and mono, di, tripropanolamine and their mixtures, aliphatic carboxylic acids up to C12, such as succinic acid, other dicarboxylic acids or salts of the cited acids, end blocked fatty acid amide alkoxylates; aliphatic lower alcohols and primarily polyols, for example glycerin, ethylene glycol, propylene glycol or sorbitol, as well as reducing agents and antioxidants such as sodium sulfite and reducing sugars.
- stabilizers are known from the prior art.
- the use of combinations of stabilizers is preferred, for example the combination of polyols, boric acid and/or borax, the combination of boric acid or borate, reducing salts and succinic acid or other dicarboxylic acids or the combination of boric acid or borate with polyols or polyamino compounds and with reducing salts.
- the composition preferably comprises one or more fragrance components and/or perfume, in the following referred to fragrances as well, in an amount of 0.01 to 10 wt %, preferably 0.05 to 8 wt %, particularly preferably 0.1 to 5 wt %, based on the total weight of the composition.
- d-limonene may be utilized as the perfume component.
- the composition according to the invention comprises a perfume based on ethereal oils (also known as essential oils).
- pine-, citrus-, jasmin-, patchouly-, rose-or Ylang-Ylang-oil are exemplary oils.
- muscatel sage oil chamomile oil, lavender oil, clove oil, melissa oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetivert oil, olibanum oil, galbanum oil and laudanum oil and orange blossom oil, neroli oil, orange peel oil and sandalwood oil.
- Exemplary tenacious odorous substances that are advantageously utilizable in the perfume oils in the context of the present invention are the ethereal oils such as angelica root oil, aniseed oil, arnica flowers oil, basil oil, bay oil, bergamot oil, champax blossom oil, silver fir oil, silver fir cone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiacum wood oil, Indian wood oil, helichrysum oil, ho oil, ginger oil, iris oil, cajuput oil, sweet flag oil, camomile oil, camphor oil, Canoga oil, cardamom oil, cassia oil, Scotch fir oil, copaiba balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemon grass oil, limette oil, mandarin oil, melissa oil, amber seed oil, myrrh oil, clove oil,
- the higher boiling or solid fragrances of natural or synthetic origin can also be used as the tenacious fragrances or mixtures of fragrances in the perfume oils.
- These compounds include the following compounds and their mixtures: ambrettolide, alpha -amyl cinnamaldehyde, anethol, anisaldehyde, anis alcohol, anisole, methyl anthranilate, acetophenone, benzyl acetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valeriate, borneol, bornyl acetate, alpha - bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalypto
- the fragrances of higher volatility include the lower boiling fragrances of natural or synthetic origin that can be used alone or in mixtures.
- Exemplary readily volatile odoriferous substances include alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linalyl acetate and linalyl propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenyl acetaldehyde, terpinyl acetate, citral, and citronellal.
- compositions from compounds of different compositions, wherein one of the compounds is totally or partially encapsulated by one or more of the other compounds.
- the inner compound can possess a higher perfume concentration than the outer compound in order to ensure a constant fragrance impression with a diminishing sphere weight over the service life of the product.
- the inner compound may also comprise a different fragrance than the outer compound.
- other active substances can also be incorporated in different layers such that they release at different times depending on the extent of flush. This type of layered construction is also possible for compositions according to the invention.
- a toilet rimblock can be obtained by extruding the composition in a conventional extruder and subsequently cutting the extrudate into pieces of a desired size. This is a known process for the person skilled in the art.
- the toilet rimblock can as well be formed into a spherical shape in a process including the steps:
- the shaping step (d) is preferably carried out in a ball rolling machine or in a press.
- Other suitable shaping processes include casting and calendaring.
- Steps (a) and (b) can also be combined by mixing the ingredients in the extruder.
- the process steps optionally proceed at different temperatures, such that heating or cooling steps can also be interposed between the steps as necessary.
- an additional process step is carried out in which the extruded strand is provided with a lubricant.
- a sponge in the form of a roller that is permanently charged with the lubricant, is guided over the extruded strand such that the surface is completely or partially, preferably to 10 to 40%, covered with lubricant.
- the addition of lubricant improves the subsequent molding into the spherical shape.
- Suitable lubricants are especially substances that for example are added as surfactants or flush regulators in inventive formulations.
- an added lubricant is preferably selected from the group consisting of dipropylene glycol, paraffins, non-ionic surfactants, polyethylene glycols, and mixtures thereof, and especially dipropylene glycol.
- compositions were extruded and subsequently left to harden for 24 hours.
- the thus obtained rimblock of example 1 was hard enough so that only by employing strong pressure a bigger part broke away. Hand pressure was not sufficient to deform the obtained rimblock. Additionally the rimblock was flushed evenly and showed a homogenous dissolution. In contrast, the composition of comparative Example 2 was still soft after 24 hours. By employing hand pressure only the block was squeezed and it was possible to crumble the block into little pieces.
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Inorganic Chemistry (AREA)
- Epidemiology (AREA)
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- Water Supply & Treatment (AREA)
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EP17169474.8A EP3399011B1 (fr) | 2017-05-04 | 2017-05-04 | Compositions appropriées pour le nettoyage de toilettes comprenant des liants non hydrauliques |
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EP17169474.8A EP3399011B1 (fr) | 2017-05-04 | 2017-05-04 | Compositions appropriées pour le nettoyage de toilettes comprenant des liants non hydrauliques |
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EP3399011B1 EP3399011B1 (fr) | 2020-11-18 |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1535948A (en) * | 1975-05-02 | 1978-12-13 | Oreal | Water-soluble deodorant product |
US4269723A (en) * | 1978-03-21 | 1981-05-26 | Jeyes Group Limited | Process for making a lavatory cleansing block and use |
WO1992003532A1 (fr) * | 1990-08-28 | 1992-03-05 | Jeyes Limited | Nettoyage de toilettes |
EP0791047B1 (fr) | 1994-11-07 | 1998-12-23 | Henkel Kommanditgesellschaft auf Aktien | Element detergent pour toilettes a chasse d'eau |
WO2007148054A1 (fr) | 2006-06-23 | 2007-12-27 | Reckitt Benckiser Inc. | Améliorations apportées à des dispositifs de distribution, et compositions s'y rapportant |
WO2014026856A1 (fr) | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Emballage hydrosoluble doté d'un agent amérisant |
WO2014026855A1 (fr) | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Emballage hydrosoluble doté d'un agent amérisant |
-
2017
- 2017-05-04 EP EP17169474.8A patent/EP3399011B1/fr active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1535948A (en) * | 1975-05-02 | 1978-12-13 | Oreal | Water-soluble deodorant product |
US4269723A (en) * | 1978-03-21 | 1981-05-26 | Jeyes Group Limited | Process for making a lavatory cleansing block and use |
WO1992003532A1 (fr) * | 1990-08-28 | 1992-03-05 | Jeyes Limited | Nettoyage de toilettes |
EP0791047B1 (fr) | 1994-11-07 | 1998-12-23 | Henkel Kommanditgesellschaft auf Aktien | Element detergent pour toilettes a chasse d'eau |
WO2007148054A1 (fr) | 2006-06-23 | 2007-12-27 | Reckitt Benckiser Inc. | Améliorations apportées à des dispositifs de distribution, et compositions s'y rapportant |
WO2014026856A1 (fr) | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Emballage hydrosoluble doté d'un agent amérisant |
WO2014026855A1 (fr) | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Emballage hydrosoluble doté d'un agent amérisant |
US20150158645A1 (en) * | 2012-08-16 | 2015-06-11 | Henkel Ag & Co. Kgaa | Water-soluble packaging with a bittering agent |
Non-Patent Citations (4)
Title |
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"Europaischen Arzneibuch", vol. 1, 2005, pages: 278 |
K. HILL; W. VON RYBINSKI; G. STOLL: "Alkyl Polyglycosides, Technology, Properties and Applications", 1996, VCH |
KIRK- OTHMER: "Encyclopedia of Chemical Technology", vol. 23, 1997, pages: 481 - 541 |
MCCUTCHEON 'S FUNCTIONAL MATERIALS, vol. 2, 1998 |
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