EP3371131A4 - Process and system for making cyclopentadiene and/or dicyclopentadiene - Google Patents

Process and system for making cyclopentadiene and/or dicyclopentadiene Download PDF

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Publication number
EP3371131A4
EP3371131A4 EP16862670.3A EP16862670A EP3371131A4 EP 3371131 A4 EP3371131 A4 EP 3371131A4 EP 16862670 A EP16862670 A EP 16862670A EP 3371131 A4 EP3371131 A4 EP 3371131A4
Authority
EP
European Patent Office
Prior art keywords
dicyclopentadiene
making cyclopentadiene
cyclopentadiene
making
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16862670.3A
Other languages
German (de)
French (fr)
Other versions
EP3371131A1 (en
Inventor
Larry L. Iaccino
Kevin C.P. LEUNG
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP3371131A1 publication Critical patent/EP3371131A1/en
Publication of EP3371131A4 publication Critical patent/EP3371131A4/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C07C2/52—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
    • C07C2603/68—Dicyclopentadienes; Hydrogenated dicyclopentadienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP16862670.3A 2015-11-04 2016-10-07 Process and system for making cyclopentadiene and/or dicyclopentadiene Withdrawn EP3371131A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562250678P 2015-11-04 2015-11-04
EP16153725 2016-02-02
PCT/US2016/056030 WO2017078900A1 (en) 2015-11-04 2016-10-07 Process and system for making cyclopentadiene and/or dicyclopentadiene

Publications (2)

Publication Number Publication Date
EP3371131A1 EP3371131A1 (en) 2018-09-12
EP3371131A4 true EP3371131A4 (en) 2018-10-17

Family

ID=55304865

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16862670.3A Withdrawn EP3371131A4 (en) 2015-11-04 2016-10-07 Process and system for making cyclopentadiene and/or dicyclopentadiene

Country Status (5)

Country Link
EP (1) EP3371131A4 (en)
JP (1) JP6643497B2 (en)
CN (1) CN108349835B (en)
CA (1) CA3004320C (en)
WO (1) WO2017078900A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110420608B (en) * 2019-08-23 2024-03-08 镇海石化建安工程股份有限公司 Depolymerization system with winding tube type heat exchanger
JPWO2022138860A1 (en) * 2020-12-24 2022-06-30

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438404A (en) * 1948-01-20 1948-03-23 Sun Oil Co Treatment of hydrocarbons
US2438400A (en) * 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
DE2535809A1 (en) * 1974-08-13 1976-03-04 Shell Int Research Cyclic 5C hydrocarbons from n-pentane feeds - by contact with hydrogen on a platinum-silica catalyst
JPS6210025A (en) * 1985-07-08 1987-01-19 Nippon Zeon Co Ltd Production of high-purity dicyclopentadiene
WO1989004818A1 (en) * 1987-11-17 1989-06-01 Mobil Oil Corporation A dehydrogenation and dehydrocyclization catalyst, its synthesis and use
US4886926A (en) * 1988-06-24 1989-12-12 Mobil Oil Corporation Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials
JP2001247490A (en) * 2000-03-03 2001-09-11 Nippon Petrochem Co Ltd Method for producing dicyclopentadiene
US20030100809A1 (en) * 2001-09-29 2003-05-29 Baoliang Tian Process for separating C5 cuts obtained from a petroleum cracking process
US20090062446A1 (en) * 2007-09-04 2009-03-05 General Electric Company Composition and associated method
RU2463284C1 (en) * 2011-05-04 2012-10-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" Method of producing dicyclopentadiene
US20130153456A1 (en) * 2011-12-15 2013-06-20 General Electric Company Containment case and method of manufacture
WO2013176712A1 (en) * 2012-05-25 2013-11-28 Exxonmobil Chemical Patents Inc. Dicyclopentadiene based resin compositions and articles manufactured therefrom

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438401A (en) * 1946-02-26 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
JPH03501942A (en) * 1987-11-17 1991-05-09 モービル　オイル　コーポレーシヨン Dehydrogenation and dehydrocyclization catalysts, their synthesis and applications
RU2186051C1 (en) * 2000-10-30 2002-07-27 Центр по разработке эластомеров Казанского государственного технологического университета Method for production of dicyclopentadiene from c5 fraction of pyrolysis hydrocarbons
CN1162380C (en) * 2001-10-12 2004-08-18 中国石油化工股份有限公司 Separation method of cracked C5 fraction
CN100441554C (en) * 2005-01-28 2008-12-10 中国石油化工股份有限公司 Method of utilizing cracked, C5 fraction
CN101450886A (en) * 2007-12-07 2009-06-10 中国石油化工股份有限公司 Method for preparing dicyclopentadiene by carbon 5 fraction
US20110178349A1 (en) * 2010-01-20 2011-07-21 Anzick Robert Kenneth Method of treating a hydrocarbon stream comprising cyclopentadiene and one or more diolefins
CN102951985A (en) * 2011-08-17 2013-03-06 中国石油化工股份有限公司 Method for separation of C5 fraction and preparation of cyclopentadiene

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438400A (en) * 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438404A (en) * 1948-01-20 1948-03-23 Sun Oil Co Treatment of hydrocarbons
DE2535809A1 (en) * 1974-08-13 1976-03-04 Shell Int Research Cyclic 5C hydrocarbons from n-pentane feeds - by contact with hydrogen on a platinum-silica catalyst
JPS6210025A (en) * 1985-07-08 1987-01-19 Nippon Zeon Co Ltd Production of high-purity dicyclopentadiene
WO1989004818A1 (en) * 1987-11-17 1989-06-01 Mobil Oil Corporation A dehydrogenation and dehydrocyclization catalyst, its synthesis and use
US4886926A (en) * 1988-06-24 1989-12-12 Mobil Oil Corporation Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials
JP2001247490A (en) * 2000-03-03 2001-09-11 Nippon Petrochem Co Ltd Method for producing dicyclopentadiene
US20030100809A1 (en) * 2001-09-29 2003-05-29 Baoliang Tian Process for separating C5 cuts obtained from a petroleum cracking process
US20090062446A1 (en) * 2007-09-04 2009-03-05 General Electric Company Composition and associated method
RU2463284C1 (en) * 2011-05-04 2012-10-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" Method of producing dicyclopentadiene
US20130153456A1 (en) * 2011-12-15 2013-06-20 General Electric Company Containment case and method of manufacture
WO2013176712A1 (en) * 2012-05-25 2013-11-28 Exxonmobil Chemical Patents Inc. Dicyclopentadiene based resin compositions and articles manufactured therefrom

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
See also references of WO2017078900A1 *
V. SH. FEL'DBLYUM ET AL: "Cyclization and dehydrocyclization of C5 hydrocarbons over platinum nanocatalysts and in the presence of hydrogen sulfide", DOKLADY. CHEMISTRY, vol. 424, no. 2, February 2009 (2009-02-01), RU, pages 27 - 30, XP055267350, ISSN: 0012-5008, DOI: 10.1134/S0012500809020025 *

Also Published As

Publication number Publication date
CN108349835A (en) 2018-07-31
CA3004320C (en) 2021-03-09
EP3371131A1 (en) 2018-09-12
CN108349835B (en) 2021-10-29
CA3004320A1 (en) 2017-05-11
JP2018537523A (en) 2018-12-20
WO2017078900A1 (en) 2017-05-11
JP6643497B2 (en) 2020-02-12

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