EP3371080A1 - Method and device for removing defects on a stationary web of a packaging material - Google Patents
Method and device for removing defects on a stationary web of a packaging materialInfo
- Publication number
- EP3371080A1 EP3371080A1 EP16785477.7A EP16785477A EP3371080A1 EP 3371080 A1 EP3371080 A1 EP 3371080A1 EP 16785477 A EP16785477 A EP 16785477A EP 3371080 A1 EP3371080 A1 EP 3371080A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- web
- packaging material
- roller
- guiding
- predetermined position
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000005022 packaging material Substances 0.000 title claims abstract description 132
- 238000000034 method Methods 0.000 title claims abstract description 31
- 230000007547 defect Effects 0.000 title claims abstract description 30
- 238000005520 cutting process Methods 0.000 claims abstract description 18
- 230000008439 repair process Effects 0.000 claims abstract description 15
- 239000002699 waste material Substances 0.000 claims abstract description 12
- 238000007789 sealing Methods 0.000 claims description 7
- 230000006698 induction Effects 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 description 10
- 239000011111 cardboard Substances 0.000 description 4
- 239000011087 paperboard Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000005030 aluminium foil Substances 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 238000003908 quality control method Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 235000021056 liquid food Nutrition 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000008162 cooking oil Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019990 fruit wine Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H26/00—Warning or safety devices, e.g. automatic fault detectors, stop-motions, for web-advancing mechanisms
- B65H26/02—Warning or safety devices, e.g. automatic fault detectors, stop-motions, for web-advancing mechanisms responsive to presence of irregularities in running webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H21/00—Apparatus for splicing webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2403/00—Power transmission; Driving means
- B65H2403/90—Machine drive
- B65H2403/94—Other features of machine drive
- B65H2403/942—Bidirectional powered handling device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2701/00—Handled material; Storage means
- B65H2701/10—Handled articles or webs
- B65H2701/19—Specific article or web
- B65H2701/1944—Wrapping or packing material
Definitions
- consumer packages of a disposable nature are commonly used for packaging and transporting liquid foods, such as, for example, milk.
- disposable packages of this type are often made of a laminated packaging material comprising a base layer of paper or cardboard and outer liquid-tight layer of polyethylene.
- a supplementary material layer of this kind is an aluminium foil between the paper or cardboard layer and one of the two outer liquid-tight layers.
- Consumer packages of this sort are nowadays very often produced with the aid of modern rational packaging machines of the sort which, from a web or from prefabricated blanks of the packaging material, both form, fill and also seal finished packages.
- Formed, filled and sealed consumer packages are produced from a web, for example, by the web firstly being transformed into a tube by joining together of the two longitudinal edges of the web into a longitudinal liquid-tight sealing joint (normally an overlap sealing joint).
- the tube is continuously filled with the particular food, for example milk, and is divided into connected pillow- shaped pack units by repeated transversal heat sealings of the tube transversely to the longitudinal axis of the tube below the fill product level of the tube.
- the filled pillow-shaped pack units are separated from one another by cuts in the transverse seals and may subsequently be given the desired geometric shape by means of at least one further forming and heat sealing operation.
- a laminated packaging material of the sort which is described above is produced on an industrial scale from a roll of a wide web of paper or cardboard.
- a web which is unwound from the roll is led to a first work station where one side of the web, by suitable printing technology, is provided with a recurring pattern of an aesthetic and/or informative nature.
- the web is also provided with a likewise recurring pattern of weakening lines facilitating folding (so called fold lines).
- fold lines weakening lines facilitating folding
- the web provided with print and fold lines is led onward to a
- the packaging material is also provided with at least one further layer of a material having such barrier properties, for example an aluminium foil, on one side of the packaging material between the paper or cardboard layer and one of the two outer liquid-tight coatings.
- packaging material web is divided up into individual partial webs, which are wound into finished packaging rolls in order to produce the formed, filled and sealed packaging containers.
- the packaging rolls are subjected to a quality control in which the packaging material is repaired by removing parts with defects, such as possible areas of missed polymer coating, pinholes in material layers, defective aluminium foil, wrinkles, spots, creasing defects or printing defects.
- a repair line of the conventional sort has a rotatable horizontal shaft at its one end and a corresponding rotatable horizontal shaft at its other end. Between the rotatable shafts, the repair line has a repair station, in which detected defects are to be removed and treated on a stationary web of the packaging material. Since a packaging material can quite often be beset with a number of production faults and these production faults, in turn, can be found at randomly spread points on one and the same packaging material, this means that a web of the packaging material which is led through the repair station can be subjected to several repair operations, each at a different position along the web of the packaging material roll, where defective packaging material is removed in connection with the quality control. Between the repair operations at stand-still of the web, the web needs to spooled at high speed forward to the next position for a repair operation.
- a roll of packaging material When a roll of packaging material is to be checked and repaired, it is suspended from the horizontal rotatable shaft at one end of the repair line. A web of the packaging material is unwound from the suspended roll and is manually advanced for winding onto the horizontal rotatable shaft at the other end of the repair line. En route to the rotatable shaft at the other end, the web is first led through a device for controlling the axial stress of the web and onward from the device through the work station in which detected production faults are to be treated on the web.
- Such manual pulling of the web along a U-shaped loop through the known roller arrangement is complicated, labour- intensive and time-consuming whenever a new roll has to be checked and repaired.
- the actual repairing of the web is made by manually cutting the web at two places before and after the portion of the in the web of a packaging material having defaults, removing the part between the cuts, and then manually splicing the ends together to form a continuous web of a packaging material again.
- An object of the invention is therefore to eliminate the mentioned drawbacks and provide a device of the sort described in the introduction, which device enables a significantly easier and less time-consuming and labour-intensive method for repairing web of a packaging material.
- a method for removing defects on a stationary web of a packaging material comprising: moving said web of packaging material through a repair line from a first rotatable roller to a second rotatable roller in a first direction, cutting off said web of packaging material at a first predetermined position, guiding said web of packaging material of said first roller into a second direction, preferably by changing the position of a guiding cylinder, wasting said web of packaging material of said first roller by movement in said second direction to a waste station, cutting off said web of packaging material of said first roller at a second predetermined position, guiding said web of packaging material of said first roller back into said first direction, preferably by changing the position of the guiding roller back to its initial position, and splicing said web of packaging material of said first roller back together with said web of
- the automated method reduces labor needs and makes the method faster. Costs are thereby saved in two ways, both by reducing labor costs and by reducing the number of devices needed for removing defects in webs of packaging material. Human errors are also avoided, providing a higher degree of certainty that all errors in a web of packaging material have been removed. Better process control of the splices is also achieved such that the register of packages is kept intact, i.e. the splice may be positioned at a position of the web corresponding to exactly one package such that only one package will end up having a splice.
- the method may further comprise the step of stopping said web of packaging material from moving in said first direction before the step of cutting off said web of packaging material at said first predetermined position.
- the method may further comprise the step of stopping the web of packaging material from moving in said second direction before the step of cutting off said web of packaging material at said second predetermined position.
- Cutting is easier to perform and the position of the cut will be more precise if the web of packaging material is stopped before it is cut at the first
- the method according to the invention may further comprise the step of rewinding said web of packaging material of said second roller from said second roller onto a third rotatable roller. Since the web of packaging material has to be used in the right direction when used in a packaging machine as e.g. a filling machine for the print of the web of packaging material to be in the correct orientation on the package, the web of packaging material rolled onto the second roll has to be re-winded onto the third roll before it can be distributed further and finally used to make packages.
- the method according to the invention may further comprise, as a first step, the step of receiving information regarding said defects of said web of packaging material from a control unit.
- An inline quality control device may e.g. be used at an earlier stage in a factory for web of packaging material for scanning the web of packaging material for errors. The lengthwise location of the errors may thus be logged and stored together with the identification of the reel with web of packaging material. If errors are detected, the reel will be moved to a device for removing defects and the method described herein will be applied to the web of packaging material.
- the method according to the invention may further comprise the step of controlling the tension of said web of packaging material in a longitudinal direction of said web of packaging material by means of a tension control device.
- Tension control is important so that the web of a packaging material is not damaged during the repairing operation.
- the invention further relates to a device for removing defects on a stationary web of a packaging material, comprising a first rotatable roller and a second rotatable roller, said web of packaging material being wound from said first roller to said second roller in a first direction, a guiding unit adapted to guide said web of packaging material of said first roller between said first direction and a second direction, preferably by means of a moveable guiding cylinder forming part of the guiding unit, a cutting device adapted to cut off said web of packaging material at a first predetermined position and at a second predetermined position, a wasting station arranged along second direction and adapted to collect said web of packaging material being cut off between said first predetermined position and said second predetermined position, and
- a splicing unit adapted to splice said web of packaging material of said first roller back together with said web of packaging material of said second roller, wherein said device is automated.
- the device according to the invention may further comprise at least one tension control device, or dancer roller as they are called, adapted to provide a pressure onto said web of packaging material in a normal direction to the web of packaging material surfaces in order to provide a tension of the web of packaging material between said first rotatable roller and said second rotatable roller.
- at least one tension control device or dancer roller as they are called, adapted to provide a pressure onto said web of packaging material in a normal direction to the web of packaging material surfaces in order to provide a tension of the web of packaging material between said first rotatable roller and said second rotatable roller.
- the device may further comprise a third roller, said web of packaging material being wound from said second roller to said third roller so as to rewind said web of packaging material, and a control unit arranged to control the device.
- the splicing unit of the device may comprise an induction sealing device for sealing the open ends together in the splicing unit.
- Fig. 1 is a schematic view of a device for removing defects on a stationary web of a packaging material.
- Fig. 2 is a schematic view of a device for removing defects on a stationary web of a packaging material where the web of a packaging material is cut and fed to waste station.
- Fig. 3 is a schematic view of a tension control device adapted to be placed in the device of Fig. 1 and Fig. 2 in some embodiments.
- Fig. 4 is a block diagram showing a method for removing defects on a stationary web of a packaging material.
- Fig. 1 shows a device for removing defects on a stationary web of a packaging material.
- a reel 102 of stationary web of a packaging material 106 is placed on a first rotatable roller 121 .
- the leading edge of the stationary web 106 is pulled by a robotic arm (not shown) to the second rotatable roller 122.
- the reel 102 of stationary web of a packaging material 106 is spooled from the first rotatable roller 121 into a second reel 104 on the second rotatable roller 122.
- the stationary web 106 is bent around a present pull- and break arrangement 1 10, whichcomprises a first guiding cylinder 1 12 and a second guiding cylinder 1 14, both being arranged to rotate around a first rotational axis 1 1 6 and a second rotational axis 1 18 respectively.
- a present pull- and break arrangement 1 10 whichcomprises a first guiding cylinder 1 12 and a second guiding cylinder 1 14, both being arranged to rotate around a first rotational axis 1 1 6 and a second rotational axis 1 18 respectively.
- at least one of the guiding cylinders 1 12, 1 14 are moveble such that the web path can be changed depending on the position of the at least one guiding roller 1 12, 1 14.
- the operative position of the pull- and break arrangement 1 10 is such that the web is guided along an S-shaped path through the arrangement 1 10.
- the first guiding cylinder 1 12 is arranged above the second guiding cylinder 1 14.
- the web is guided below and around about half the second cylinder on the far side thereof, as seen from the first reel 102 before following the second cylinder around about half its circumference before continuing towards a doctoring station 108 and the second reel 122.
- the first guiding cylinder 1 12 is illustrated in full lines while various positions for the second guiding cylinder 1 14 are shown in dotted lines.
- a position P1 corresponding to the position as shown in Fig. 1 ; i.e. an "operative position” for guiding the web 106 towarsd the second reel 122.
- position P2 which corresponds to an "engagement position" which is more of an intermediate position passed when moving between the other positions.
- the first guiding cylinder 1 12 is arranged to rotate around a first axis 1 1 6.
- the second guiding cylinder 1 14 is arranged to rotate around a second axis 1 18.
- the first and the second guiding cylinders are arranged in parallel, i.e. having parallel rotational axes. In one or more embodiments both guiding cylinders 1 12, 1 14 are suspended from one side axial thereof only, basically
- each cylinder having one end attached to a constructional arrangement while the second end is free.
- the second guiding cylinder 1 14 has been arranged in the waste position P3.
- the second guiding cylinder 1 14 is in contact with the first guiding cylinder 1 12, with the intermediate of the web 106, and the tangent of the contact, i.e. nip, is directed downwards, enabling guiding of the web 106 in an alternative direction.
- the web 106 is directed towards a waste assembly schematically indicated by the recycling bin.
- Wasting of packaging material may be the first operation after threading of a web.
- the second guiding cylinder 1 14 is moved from the position P4, to position P2, and then to the waste position P3.
- One other example could be that the second guiding cylinder 1 14 is moved from the first position P1 directly to the waste position P3. No matter the scenario the present arrangement nevertheless enables the second guiding cylinder 1 14 to assume the position P3.
- the device of the invention further comprises a control unit 125, controlling the automated process of the entire device for removing defects on a stationary web of a packaging material.
- Fig. 3 illustrates a tension control device 201 .
- a stoppage of the web can generally be performed without major problems, but, on the other hand, problems and disruptions quite often arise in connection with the restart of the web after each stoppage and standstill. Problems and disruptions of this sort are at least partially associated with the fact that a moving web 106 of a packaging material cannot be stopped instantaneously, but rather that a slowdown and stoppage of the web, due to inherent inertia and other dynamic effects, takes place after a continuous retardation process, during which a growing accumulation or loop of the slowing web is formed in conjunction with or immediately before the repair station 108.
- the repair line of Fig. 1 and Fig. 2 may be equipped with a tension control device 201 according to the invention for controlling axial forces upon a web and keeping these at a level below this ultimate tensile strength.
- the tension control device 201 may e.g. be placed before the pull-and-brake device 1 10 shown in Fig. 1 and Fig. 2, i.e. at a position between the first reel 121 and the pull- and break assembly 1 10.
- the tension control device 201 has a first cylinder 204, which is rotatable about a first horizontal shaft, a second cylinder 205, which is rotatable about a second horizontal shaft, and a third rotatable cylinder 203, which is rotatable about a third horizontal shaft.
- the third rotatable cylinder 203 is movable, in response to axial forces acting upon the web at any moment, between a lower position and an upper position along an arc-shaped motional path (shown in dashed representation) in the vertical plane between the two first and second rotatable cylinders 204 and 205, the arc being defined by the end of the arm 202 that the third cylinder 203 is attached to.
- the third rotatable cylinder 203 is biased with a freely adjustable force which acts in the direction of the motion of the third cylinder from the lower position.
- a counterforce can be produced in a known manner with both pneumatic and hydraulic and mechanical means which act directly upon the fourth rotatable shaft. In order to avoid rupture of the web due to excessively strong pulls and axial forces upon the web, as is described above, this counterforce must be set at a value below the particular ultimate tensile strength of the web.
- the counterforce can be set at a value amounting to just one tenth (1 /10) of this, such as 1800-2000 N, in order thus to enable the third cylinder to be displaced, if the web is acted upon by axial forces, already far below the ultimate tensile strength of the web.
- Fig. 4 illustrates the automated method for removing defects on a stationary web of a packaging material performed by the device of Figs. 1 -3.
- the device receives information regarding defects of the web of packaging material from a control unit indicating to the device where defects are present on the packaging material.
- the packaging material is moved from a first rotatable roller to a second rotatable roller and stopped from moving in first direction at a position corresponding to the information received regarding locations of defects.
- the web of packaging material is then cut off at that first predetermined position, as indicated by the position of the cutting knife 124 in Figs. 1 or 2.
- the cutting knife 124 is preferably a sharp tool being moveable across the width of the web 106 for separating the web into a leading end, and a trailing end.
- the web of packaging material is thereafter guided into a second direction to a waste by changing the position of the second guiding roller 1 14..
- the web of packaging material of said first roller containing defect is thereby moved in the second direction into a waste station.
- the web of packaging material is stopped from moving into the waste station in the second direction.
- the web of packaging material is cut off at that second predetermined position where defects are no longer present. This may e.g. be performed by moving the cutting knife 124 towards the right in Fig. 2, such that it engages at a position upstream the pull- and break assembly 1 10, and activating the cutting knife 124 thus providing a lateral cut across the width of the web 106.
- the web of packaging material of said first roller is again guided into the first direction by returning the second guiding roller 1 14 to its position P1 and pulling of the packaging material by the robotic arm, and is spliced back together, preferably by means of induction heating or other heat-generating device, with the web of packaging material of the second roller 122 at the first predetermined position by means of repair station 108.
- the defective parts have thus been automatically cut off and been removed and the web packaging material has been reattached.
Landscapes
- Replacement Of Web Rolls (AREA)
- Cleaning In General (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15192605 | 2015-11-02 | ||
| PCT/EP2016/075546 WO2017076678A1 (en) | 2015-11-02 | 2016-10-24 | Method and device for removing defects on a stationary web of a packaging material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3371080A1 true EP3371080A1 (en) | 2018-09-12 |
Family
ID=54476750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16785477.7A Withdrawn EP3371080A1 (en) | 2015-11-02 | 2016-10-24 | Method and device for removing defects on a stationary web of a packaging material |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20180319612A1 (en) |
| EP (1) | EP3371080A1 (en) |
| JP (1) | JP2018532661A (en) |
| CN (1) | CN108349675A (en) |
| BR (1) | BR112018008539A2 (en) |
| MX (1) | MX2018005127A (en) |
| RU (1) | RU2018120098A (en) |
| WO (1) | WO2017076678A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210379783A1 (en) * | 2018-10-15 | 2021-12-09 | 3M Innovative Properties Company | Slitter director for automated control of slit roll generation from manufactured web |
| CN111977434A (en) * | 2020-08-20 | 2020-11-24 | 上海紫华薄膜科技有限公司 | Film segmentation and splicing method |
| CN116605478B (en) * | 2023-06-08 | 2026-04-17 | 扬州通华电气有限公司 | A busbar wrapping robot |
| CN118545336B (en) * | 2024-07-22 | 2024-11-22 | 江苏新金环新材料有限公司 | Defect detection equipment for aluminum foil packaging tape |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2774364B2 (en) * | 1990-07-26 | 1998-07-09 | 王子製紙株式会社 | Splicing method and splicing device |
| US5632831A (en) * | 1994-08-04 | 1997-05-27 | Superpac, Inc. | System and method for cutting and splicing polymeric webs |
| DE69930193T2 (en) * | 1998-12-14 | 2006-07-27 | Toray Industries, Inc. | Method and device for producing plastic films |
| JP3611186B2 (en) * | 1999-05-17 | 2005-01-19 | ノーリツ鋼機株式会社 | Film feeder |
| JP3720810B2 (en) * | 2003-02-17 | 2005-11-30 | 三原菱重エンジニアリング株式会社 | Roll base paper defective part removing apparatus and defective part removing method |
| US8910689B2 (en) * | 2005-03-15 | 2014-12-16 | The Procter & Gamble Company | Apparatus for reducing downtime in web processes |
| RU2675990C1 (en) * | 2013-12-20 | 2018-12-25 | Тетра Лаваль Холдингз Энд Файнэнс С.А. | Device for controlling web tension in running material web |
| CN204162141U (en) * | 2014-10-10 | 2015-02-18 | 日东电工株式会社 | Blooming connecting device |
-
2016
- 2016-10-24 BR BR112018008539A patent/BR112018008539A2/en not_active Application Discontinuation
- 2016-10-24 MX MX2018005127A patent/MX2018005127A/en unknown
- 2016-10-24 CN CN201680063192.8A patent/CN108349675A/en active Pending
- 2016-10-24 RU RU2018120098A patent/RU2018120098A/en not_active Application Discontinuation
- 2016-10-24 EP EP16785477.7A patent/EP3371080A1/en not_active Withdrawn
- 2016-10-24 JP JP2018522632A patent/JP2018532661A/en active Pending
- 2016-10-24 WO PCT/EP2016/075546 patent/WO2017076678A1/en not_active Ceased
- 2016-10-24 US US15/772,448 patent/US20180319612A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017076678A1 (en) | 2017-05-11 |
| CN108349675A (en) | 2018-07-31 |
| US20180319612A1 (en) | 2018-11-08 |
| MX2018005127A (en) | 2018-06-06 |
| RU2018120098A (en) | 2019-12-04 |
| BR112018008539A2 (en) | 2018-10-30 |
| JP2018532661A (en) | 2018-11-08 |
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