EP3334851A1 - Method for producing a corrosion protection layer for thermal insulation layers made of hollow aluminum oxide balls and glass layer and component as well as material mixture - Google Patents
Method for producing a corrosion protection layer for thermal insulation layers made of hollow aluminum oxide balls and glass layer and component as well as material mixtureInfo
- Publication number
- EP3334851A1 EP3334851A1 EP16784424.0A EP16784424A EP3334851A1 EP 3334851 A1 EP3334851 A1 EP 3334851A1 EP 16784424 A EP16784424 A EP 16784424A EP 3334851 A1 EP3334851 A1 EP 3334851A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- aluminum
- corrosion protection
- protection layer
- component according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
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- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
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- C23C10/26—Solid state diffusion of only metal elements or silicon into metallic material surfaces using liquids, e.g. salt baths, liquid suspensions more than one element being diffused
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
Definitions
- the invention relates to the protection of a thermal barrier coating against corrosion comprising hollow aluminum oxide spheres and further comprising a glassy outermost protective layer.
- the object is achieved by a method according to claim 1 with a component according to claim 2.
- FIGS 1, 2, 3 schematically Schichtsys ⁇ inventive systems with a corrosion protection layer.
- the inventive step is the application of a layer of aluminum particles, in particular by a slurry.
- Semi-metal in particular boron, silicon or germanium applied by spraying a slurry.
- Aluminum particles / Zirkonoxidpelle can one
- Particle layer can be between 5 and 150 ⁇ . This layer is optimally applied as a slip. But other methods are possible. By a suitable
- Coating system consisting of base material,
- Adhesive layer and TBC are formed from the
- the titanium group oxides increase the mechanical compatibility and the resistance to CMAS attack.
- a second optional layer has the composition of a low-melting, viscous glass whose
- Melting point is preferably lower or in the range of the melting point of the diffusing metal in the underlying layer.
- the glass is especially in
- Substantially S1O 2 and preferably contains for the
- melting point relevant accompanying elements such as Magnesium (Mg), calcium (Ca) or boron (B) and / or
- the glass can also be formed during the heat treatment in an oxygen-containing atmosphere from a silazane, siloxane or silicone polymer as a precursor. These precursors can be used to adjust the shrinkage and
- oxidation of the aluminum particles can be performed by the additional layer of glass without the pure aluminum particles running along the surface of the system clogging component holes during aging.
- the "hiking" of the aluminum particles can be performed by the additional layer of glass without the pure aluminum particles running along the surface of the system clogging component holes during aging.
- Aluminum / Titanium group metal particles (which belong to a
- Blockage of the cooling air bores can lead to
- the SiO 2 layer will then largely delaminate during operation due to brittleness and the actual protective layer may take over the protective effect.
- the inventive step is the composition and application of the aluminum / titanium group metal particles in
- Clog cooling air holes during removal The use of polymer masking may alternatively be performed. Boron enhances the chemical bonding of the additional layer.
- FIG. 1 shows a layer system 1 according to the invention which has a substrate 4.
- the substrate 4 is in particular metallic, wherein it has in particular ⁇ a special nickel or cobalt-based superalloy.
- an optional metallic adhesion promoter ⁇ mid layer 7 is present on the substrate 4 .
- this is one
- Coating layer in particular based on NiCoCrAlY.
- an oxide layer (TGO) is formed during the further coating or by deliberate oxidation or at least during operation, which is not shown here in detail.
- a ceramic thermal barrier coating 10 is present on this thermally grown oxide layer (TGO) or on the metallic adhesion promoter layer 7, a ceramic thermal barrier coating 10 is present.
- This may be single-layered, in particular of zirconium oxide or double-layered with zirconium oxide and a pyrochlore or "DVC" layers.
- Alumina particularly of alumina hollow spheres 14 ( Figure 1), but optionally as the outermost one
- a layer of aluminum particles, in particular with grain sizes of lym to 50ym applied, in particular by a slip, vapor deposition, sputtering, etc . This layer may have a layer thickness between some
- Additions to aluminum (Al) are preferred: in particular at least one element Z selected from the group I boron (B), gallium (Ga) and / or germanium (Ge) and / or
- Corrosion layer (13 13 ⁇ ⁇ , 13 ⁇ ⁇ ⁇ ) applied and / or oxidized as a material mixture or is oxidized.
- silicon (Si) and / or magnesium (Mg) can be applied and / or be present in the material mixture.
- Ge / Ga means: germanium and / or gallium, ie Ge, Ga or Ge + Ga.
- This layer should prevent the penetration of the CMAS (CMAF) layer and react with the CMAS (CMAF).
- CMAF CMAS
- the alumina thus applied has a lower coefficient of expansion, and in conjunction with the nickel (Ni) originating from the compressor abradable, part of the alumina breaks off. The remaining layer then protects against the penetration of liquid deposits.
- the inventive step is also in the application of the different particle sizes of the alumina
- the glass can in particular represent silicon oxide, in particular S1O 2 .
- zirconium (Zr) reduces the viscosity of the CMAS and prevents or
- At least one element from the group boron (B), gallium (Ga) and / or germanium (Ge) and optionally silicon (Si) is additionally present.
- alumina / zirconia or over the metallic aluminum / zirconium or over aluminum and an element Z may be a glass layer as explained above
- the heat treatment for the formation of alumina or alumina / zirconia or alumina and oxide of the element Z may be effected by a first use of the component or by an upstream heat treatment prior to the first use or after being placed in a machine for a
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102015221751.5A DE102015221751A1 (en) | 2015-11-05 | 2015-11-05 | Process for the preparation of a corrosion protection layer for thermal insulation layers of hollow aluminum oxide spheres and outermost glass layer and component and material mixture |
PCT/EP2016/074278 WO2017076583A1 (en) | 2015-11-05 | 2016-10-11 | Method for producing a corrosion protection layer for thermal insulation layers made of hollow aluminum oxide balls and glass layer and component as well as material mixture |
Publications (1)
Publication Number | Publication Date |
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EP3334851A1 true EP3334851A1 (en) | 2018-06-20 |
Family
ID=57178394
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16784424.0A Ceased EP3334851A1 (en) | 2015-11-05 | 2016-10-11 | Method for producing a corrosion protection layer for thermal insulation layers made of hollow aluminum oxide balls and glass layer and component as well as material mixture |
Country Status (6)
Country | Link |
---|---|
US (1) | US20180305824A1 (en) |
EP (1) | EP3334851A1 (en) |
KR (1) | KR102161752B1 (en) |
CN (1) | CN108350560A (en) |
DE (1) | DE102015221751A1 (en) |
WO (1) | WO2017076583A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113511802B (en) * | 2021-04-20 | 2022-12-20 | 成都光明光电股份有限公司 | Softening gasket for glass product production and manufacturing method thereof |
CN114210968B (en) * | 2021-12-17 | 2024-05-28 | 武汉苏泊尔炊具有限公司 | Corrosion resistant material, method of preparing the same, and cookware including the corrosion resistant material |
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US4588655A (en) * | 1982-06-14 | 1986-05-13 | Eutectic Corporation | Ceramic flame spray powder |
JPS63274751A (en) * | 1987-05-01 | 1988-11-11 | Toyota Motor Corp | Ceramic thermally sprayed member |
US5080977A (en) * | 1990-07-31 | 1992-01-14 | United States Of America, As Represented By The Administrator, Nat'l. Aero. And Space Admin. | Composite thermal barrier coating |
WO1994016859A1 (en) * | 1993-01-25 | 1994-08-04 | University Of Cincinnati | Combustible slurry for joining metallic or ceramic surfaces or for coating metallic, ceramic and refractory surfaces |
US5338577A (en) * | 1993-05-14 | 1994-08-16 | Kemira, Inc. | Metal with ceramic coating and method |
JP2845144B2 (en) * | 1994-02-10 | 1999-01-13 | 住友金属工業株式会社 | Hot-dip metal bath immersion member and method for producing the same |
US5650235A (en) * | 1994-02-28 | 1997-07-22 | Sermatech International, Inc. | Platinum enriched, silicon-modified corrosion resistant aluminide coating |
DE19680223B3 (en) * | 1995-04-03 | 2013-01-17 | General Electric Co. | Method for protecting a thermal barrier coating and corresponding component |
US6465090B1 (en) * | 1995-11-30 | 2002-10-15 | General Electric Company | Protective coating for thermal barrier coatings and coating method therefor |
US6071628A (en) * | 1999-03-31 | 2000-06-06 | Lockheed Martin Energy Systems, Inc. | Thermal barrier coating for alloy systems |
US6294261B1 (en) * | 1999-10-01 | 2001-09-25 | General Electric Company | Method for smoothing the surface of a protective coating |
US6939603B2 (en) * | 2001-03-22 | 2005-09-06 | Siemens Westinghouse Power Corporation | Thermal barrier coating having subsurface inclusions for improved thermal shock resistance |
DE10203283C5 (en) * | 2002-01-29 | 2009-07-16 | Gkn Sinter Metals Gmbh | Method for producing sintered components from a sinterable material and sintered component |
DE10251902B4 (en) * | 2002-11-07 | 2009-05-07 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for coating a substrate and coated article |
EP1484427A3 (en) * | 2003-06-06 | 2005-10-26 | General Electric Company | Top coating system for industrial turbine nozzle airfoils and other hot gas path components and related method |
US7368164B2 (en) * | 2004-06-18 | 2008-05-06 | General Electric Company | Smooth outer coating for combustor components and coating method therefor |
WO2008110161A1 (en) * | 2007-03-14 | 2008-09-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Layer system and method for the production thereof |
EP2088224A1 (en) * | 2008-01-10 | 2009-08-12 | Siemens Aktiengesellschaft | Method for manufacturing a rough layer and a layer system |
US20110151219A1 (en) * | 2009-12-21 | 2011-06-23 | Bangalore Nagaraj | Coating Systems for Protection of Substrates Exposed to Hot and Harsh Environments and Coated Articles |
EP2381005A1 (en) * | 2010-04-22 | 2011-10-26 | Siemens Aktiengesellschaft | Coating system for turbine components |
WO2012089200A1 (en) * | 2010-12-30 | 2012-07-05 | Dechema Gesellschaft Für Chemische Technik Und Biotechnologie E.V. | Method for producing a corrosion-inhibiting diffusion layer in the peripheral zone, near the surface, of a substrate that consists of a metal or a metal alloy, and layer system therefor |
EP2631321A1 (en) * | 2012-02-22 | 2013-08-28 | Siemens Aktiengesellschaft | Ceramic heat insulation layer system with external high aluminium layer and method |
US9845526B2 (en) * | 2012-04-03 | 2017-12-19 | MTU Aero Engines AG | Slip and process for producing an aluminum diffusion layer |
DE102014205491A1 (en) * | 2014-03-25 | 2015-10-01 | Siemens Aktiengesellschaft | Ceramic thermal barrier coating system with protective coating against CMAS |
DE102015206332A1 (en) * | 2015-04-09 | 2016-10-13 | Siemens Aktiengesellschaft | Process for the preparation of a corrosion protection layer for thermal insulation layers of hollow aluminum oxide spheres and outermost glass layer and component |
-
2015
- 2015-11-05 DE DE102015221751.5A patent/DE102015221751A1/en not_active Withdrawn
-
2016
- 2016-10-11 WO PCT/EP2016/074278 patent/WO2017076583A1/en active Application Filing
- 2016-10-11 KR KR1020187015446A patent/KR102161752B1/en active IP Right Grant
- 2016-10-11 EP EP16784424.0A patent/EP3334851A1/en not_active Ceased
- 2016-10-11 CN CN201680064538.6A patent/CN108350560A/en active Pending
- 2016-10-11 US US15/771,103 patent/US20180305824A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
KR102161752B1 (en) | 2020-10-05 |
US20180305824A1 (en) | 2018-10-25 |
KR20180077254A (en) | 2018-07-06 |
DE102015221751A1 (en) | 2017-05-11 |
WO2017076583A1 (en) | 2017-05-11 |
CN108350560A (en) | 2018-07-31 |
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