EP3310498A1 - Coating of composite wood panels with aminoplast resin films fitted with an abrasion-resistant, easy-clean and hydrophobic surface - Google Patents
Coating of composite wood panels with aminoplast resin films fitted with an abrasion-resistant, easy-clean and hydrophobic surfaceInfo
- Publication number
- EP3310498A1 EP3310498A1 EP16747447.7A EP16747447A EP3310498A1 EP 3310498 A1 EP3310498 A1 EP 3310498A1 EP 16747447 A EP16747447 A EP 16747447A EP 3310498 A1 EP3310498 A1 EP 3310498A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sol
- equipment
- coating
- abrasion
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
- C23C18/1208—Oxides, e.g. ceramics
- C23C18/1216—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1229—Composition of the substrate
- C23C18/1233—Organic substrates
- C23C18/1237—Composite substrates, e.g. laminated, premixed
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1254—Sol or sol-gel processing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1262—Process of deposition of the inorganic material involving particles, e.g. carbon nanotubes [CNT], flakes
- C23C18/127—Preformed particles
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1295—Process of deposition of the inorganic material with after-treatment of the deposited inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/06—Metal coatings applied as liquid or powder
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
Definitions
- the invention relates to the finishing of Aminoplastharzfilmen with an abrasion-resistant, easy clean and hydrophobic surface for the coating of wood-based panels that are used for the production of floor panels or find application in furniture.
- Aminoplast resin films are melamine, formaldehyde condensation resins or mixed resins of urea and melamine, which are end condensed under pressure and temperature or spatially crosslinked.
- Melamine resin films are used in the coating of HDF (High Density Fibreboards), which are then processed into floor panels.
- HDF High Density Fibreboards
- printed decor papers made of high-grade cellulose are impregnated with melamine resin, which are then precondensed in the drying zone of an impregnating channel.
- the decorative papers are pressed together with impregnated overlay papers from 20 to 45 g / m2 in a hydraulic heating press.
- the overlay is used for
- Coating of decorative films and other highly stressed surfaces It consists of high-quality, high-grade paper, which is impregnated with melamine resin and additionally contains defined amounts of mineral fillers, such as corundum.
- hard materials can be added directly to the melamine impregnating resin for paper surface coating.
- the over- laypapier added directly to the papermaking a certain amount of corundum the raw paper mass, this eliminates the Korundismeischung in resin impregnation.
- EP 0732449 AI a process for the production of decorative paper for use in the production of abrasion-resistant laminates is described.
- the resin is mixed with abrasion-resistant mineral components such as corundum.
- DE 195 29 987 A1 describes a process for the preparation of highly abrasion-resistant coating layers on solid support material.
- This lacquer layer is produced by means of synthetic resin lacquers, such as acrylic resin, polyester resin or polyurethane resin lacquer, whereby a wear-inhibiting agent is scattered on the lacquer layers prior to hardening.
- EP 1070688 Al a surface-coated hard material is described with a certain hardness. This hard material is added as a wear-inhibiting agent in the paint layers.
- the production of synthetic corundum is usually carried out in an electric arc furnace, wherein the starting material alumina or bauxite is melted at about 2000 ° C. In this process, the product is produced in blocks, which are comminuted after cooling and then processed into a granulation.
- the melamine resin films are pressed together with the overlay films in so-called hydraulic heating presses with corresponding press plates, which can be textured, frosted or glossy, under pressure and temperature.
- the melamine resin flocks are finally condensed and form irreversible, hard surfaces.
- the corundum particles are located after pressing on the surfaces of the coated wood-based panels.
- the press plates used are usually made of hard chrome steels of provenance AISI 410, AISI 630 with a hardness of 38-42 HRC. However, it is also possible to use brass sheets MS 64 with a hardness of 130 HB.
- the metal surfaces are provided with a chromium coating, which is carried out electrochemically in a chromic acid bath with Cr (VI) compounds.
- the chrome coatings should have functional properties, therefore, hard chromium layers are over 20 ⁇ , sought.
- the decorative and / or overlay papers after impregnation with an amino-plastharz receives an additional sol-gel coating, which is enriched with nanostructured tungsten or molybdenum disulfide, wherein the nanostructures of the metal disulphides are formed in the form of fullerene-like nanoparticles and nanotubes.
- the additional enrichment of the fullerene-like nanoparticles of z For example, tungsten disulfide in the sol-gel mixture, surfaces with additional high release and sliding effect after curing of the films. This prevents abrasion on the press plate surfaces and improves the tribological properties of the composite layers.
- the resulting from the sol-gel process surface layers of, for example, AI2O3, T1O2 or S1O2 produce the hardness of the surfaces of the later coated wood-based panels, which in addition creates an easy clean and hydrophobic surface.
- the sol-gel process is a wet chemical process for the production of ceramic and hybrid organic-inorganic materials. It is possible to produce thin layers but also small particles and fibers, aerogels and xerogels and also monolithic materials via the sol-gel process. Basically, the sol-gel process describes two typical stages that go through each product.
- a sol which consists of finely dispersed colloidal particles of about 1 nm to 100 nm in size in a liquid or dispersed oligomers, which consist of branched macromolecules.
- a so-called precursor is used, which are metal alkoxides or metal salts dissolved in water or in another liquid.
- M polyvalent metal ions
- a metal hydroxide forms even in the presence of H2O even when the solvent evaporates, even at low temperatures Network. This then contains numerous MOH groups and is therefore hydrophilic and antistatic.
- the gel forms a xerogel, which changes into a solid and compact form as a result of further temperature supply. It comes through the H2O cleavage to metal oxide groups and the surfaces are hard and scratch-resistant.
- the deposition or the application of thin layers on the impregnated decorative or overlay papers, also referred to as a substrate in the further description, can be carried out with the aid of a plurality of coating methods.
- dip-coating, spin coating is applicable, but it has proved suitable for one-sided surface application to coat by means of a doctor blade or to apply with a transfer roller.
- the substrate is coated with the liquid sol.
- the solvent evaporates, thereby greatly increasing the concentration of the particles, which, by binding the particles together, leads to the formation of a gel and thus to a solid but still porous layer.
- This layer also called xerogel, still contains slight amounts of the solvent.
- tempering which takes place in the subsequent drying zone of the impregnation, already forms the solid phase of the metal oxide from the sol-gel process and in the further course of the final condensation of the impregnating resins in the press under pressure and temperature, the entire hard layer of metal oxides educated.
- metal oxides are to be made.
- metal compounds the metals aluminum, zirconium, titanium and silicon have been found. With the help of their oxidic compounds, very good sol-gel layers can be achieved. In the further course, two sol-gel layers are described, which of the AI2O3 and SiO2
- Starting material for the preparation of AI2O3 may be, for example, a Yoldas sol.
- the first step of the process is the hydrolysis of aluminum alkoxide, it takes z.
- aluminum tri-sec-butoxide Al (OCH (CH3) C2H5) 3 and hydrolyzed in a large excess of water at about 85 ° C. This results in an aluminum hydroxide slurry which is subsequently converted to a clear sol or colloidal solution by the addition of a small amount of nitric acid HNO3. If you want to work after the Yoldas process with a lower stoichiometric water content, so you mix z.
- Another sol could be prepared from a boehmite powder which is commercially available.
- Silica esters may be used in the preparation of S1O2 gels, for example a tetraethyl orthosilicate TEOS is used as precursor.
- TEOS tetraethyl orthosilicate
- the designation of such hybrid organic-inorganic layers of organically modified silica are also often referred to as ormosils.
- Various materials can be used for the preparation of ormosil layers, in particular one starts from different silanes.
- the subsequent mechanical behavior of the sol-gel layers depends on the chemical structure and its concentration in the sol. For example, a silane of the formula (OC 2 H 5) 3 Si (CH 2) 3-CH (O) CH 2 3-
- Glycidoxypropyltrimethoxysilane also known under the brand name Dynasylan® or GLYMO use. If the hardness of the layers is to be increased, then nano-particles of S1O2 or Al2O3 can additionally be introduced. On the surface of the colloidal, amorphous SiO 2 particles located OH groups can react with the silane used and thus embed the particles in the layer matrix. It is also possible to prepare layers of organically modified S1O2 having a hydrophilic or hydrophobic or dirt-repellent effect.
- the preparation for the inorganic fullerene-like tungsten disulphide particles then follows, both preparations being brought together.
- Inorganic fullerene-like nanoparticles and nanotubes have particle diameters of 10 to 25 nm. Nanotubes have diameters of 10 to 25 nm and lengths from 200 to 300 nm.
- the first inorganic fullerene-like particles of tungsten or molybdenum disulfide were observed in thin films formed by sulfidation of WO3 and MoO3 layers, respectively, under a reducing atmosphere. Inorganic fullerenes were first produced in Israel in 1990, and the materials used were tungsten disulfide (WS2) and molybdenum disulfide (M0S2).
- fullerene-like materials such as TiS2, selenides, bromides and chlorides such as NiBr2, NiCl2, and various oxides such.
- B V2O5 and boron nitride.
- tungsten disulfide and also molybdenum disulfide was selected.
- Tungsten disulfide in the form of fullerene-like nanoparticles and nanotubes are excellent for various uses because of their physical properties and crystallographic morphology.
- fullerene-like tungsten disulphide has proven to be excellent, thus avoiding abrasion on the coated wood-based panels during later use.
- the lubricating effect of tungsten disulfide and molybdenum disulfide in a tribological contact is mainly due to the formation of a thin film of WS2 or M0S2, which forms in the contact zone on the surfaces of the rubbing bodies.
- This so-called Tribofilm allows a frictionless sliding of the surfaces against each other and thus reduces the wear of the rubbing body. Therefore, this effect is quite positive, compared to the frictional forces acting on the chromed press plate surfaces, from.
- tungsten disulfide particles are supplied as a dry powder.
- the particles are partly coalesced (aggregated) and agglomerated to form secondary particles several micrometers in diameter. If the powder thus formed is added directly to water and ethanol or to an aqueous sol, the tungsten disulfide precipitates directly due to the high mass. Therefore, the tungsten disulfide particles have to be deagglomerated before preparation in the sol-gel process and stabilized as sols in the sol.
- the use of dispersants has proved to be advantageous.
- the WS2 powder with cetyltrimethylammo- sium bromide from the company Sigma-Aldrich or Pretoctol (BASF) dispersed by means of ultrasound technology.
- the proportion of fullerene-type tungsten disulfide WS2 in the sol depends on the desired surface finish of the coated wood-based panels and the demolding properties of the pressed panels used and can be from 1 to 50%, based on solids content.
- sol-gel preparations with the dispersed WS2 particles are then applied to the surfaces of the resin-impregnated decorative or overlay patches used, as described above.
- the sol-gel coating can be carried out in the known and according to the prior art impregnated drying equipment for thermoset resin impregnations.
- the overlay paper is first impregnated with the corresponding liquid, aqueous aminoplast resin and dried in the heated drying zone to a certain moisture content and at the same time a precondensation takes place.
- the prepared sol is then applied with the fullerene-like WS2 particles and then transferred to the heated drying channel.
- the speed and channel temperature depend on the respective resin parameters that are set by the user beforehand.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Nanotechnology (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL16747447T PL3310498T3 (en) | 2015-06-20 | 2016-06-17 | Coating of composite wood panels with aminoplast resin films fitted with an abrasion-resistant, easy-clean and hydrophobic surface |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE202015004389.5U DE202015004389U1 (en) | 2015-06-20 | 2015-06-20 | Coating of wood-based panels with Aminoplastharzfilmen, which are equipped with an abrasion-resistant, easy clean and hydrophobic surface |
PCT/EP2016/064007 WO2016207072A1 (en) | 2015-06-20 | 2016-06-17 | Coating of composite wood panels with aminoplast resin films fitted with an abrasion-resistant, easy-clean and hydrophobic surface |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3310498A1 true EP3310498A1 (en) | 2018-04-25 |
EP3310498B1 EP3310498B1 (en) | 2019-05-08 |
Family
ID=53759297
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16747447.7A Active EP3310498B1 (en) | 2015-06-20 | 2016-06-17 | Coating of composite wood panels with aminoplast resin films fitted with an abrasion-resistant, easy-clean and hydrophobic surface |
Country Status (13)
Country | Link |
---|---|
US (1) | US10246829B2 (en) |
EP (1) | EP3310498B1 (en) |
CN (1) | CN107750292B (en) |
BR (1) | BR112017027345A2 (en) |
CA (1) | CA2989246A1 (en) |
CL (1) | CL2017003212A1 (en) |
DE (1) | DE202015004389U1 (en) |
DK (1) | DK3310498T3 (en) |
ES (1) | ES2740815T3 (en) |
PL (1) | PL3310498T3 (en) |
RU (1) | RU2712611C2 (en) |
TR (1) | TR201910885T4 (en) |
WO (1) | WO2016207072A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019110519B4 (en) | 2019-04-23 | 2021-10-07 | Technische Universität Bergakademie Freiberg | Composition, comprising a first composition and a second composition, composition produced therefrom for coating substrate surfaces and their use and method for their production |
CN115716973B (en) * | 2022-11-25 | 2023-09-05 | 湖南大学 | Polyester resin matrix composite material with excellent antifriction performance and preparation method thereof |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19508797C1 (en) | 1995-03-15 | 1996-08-29 | Graudenz & Partner Consultatio | Process for making decorative paper for use in making abrasion resistant laminates |
DE19529987A1 (en) | 1995-08-07 | 1997-02-13 | Kunnemeyer Hornitex | Prodn. of highly abrasion resistant lacquer coatings - with wear-reducing agent, pref. metal oxide, applied before or after the lacquer |
AU2830799A (en) * | 1999-01-26 | 2000-08-18 | Kronospan Technical Company Limited | Method for producing laminate coatings, and laminate coating |
DE19933710A1 (en) | 1999-07-19 | 2001-01-25 | Daniele Casalini | Surface coated hard material |
DE102004043355B4 (en) * | 2004-09-08 | 2006-09-21 | Kronotec Ag | impregnate |
DE102007019179A1 (en) | 2007-04-20 | 2008-10-30 | Center For Abrasives And Refractories Research & Development C.A.R.R.D. Gmbh | Wear protection layer |
US20090017294A1 (en) * | 2007-07-11 | 2009-01-15 | Ppg Industries Ohio, Inc. | Coating for decorative metals with improved mar and scratch resistance and methods of application |
CN100567677C (en) * | 2007-10-31 | 2009-12-09 | 寇国模 | Composite floor surface layer, composite floor board and manufacture method thereof |
CN101234786B (en) * | 2008-02-22 | 2011-05-11 | 长安大学 | Method for preparing nano tungsten disulfide with fullerene structure |
US9115470B2 (en) * | 2011-06-28 | 2015-08-25 | The Chemours Company Tt, Llc | Treated inorganic pigments having reduced photoactivity and anti-microbial properties and their use in paper slurries |
EP2789735A1 (en) * | 2013-04-08 | 2014-10-15 | Unilin BVBA | Method for manufacturing coated panels and coated panel |
-
2015
- 2015-06-20 DE DE202015004389.5U patent/DE202015004389U1/en not_active Expired - Lifetime
-
2016
- 2016-06-17 PL PL16747447T patent/PL3310498T3/en unknown
- 2016-06-17 CN CN201680036076.7A patent/CN107750292B/en not_active Expired - Fee Related
- 2016-06-17 US US15/737,394 patent/US10246829B2/en not_active Expired - Fee Related
- 2016-06-17 WO PCT/EP2016/064007 patent/WO2016207072A1/en active Application Filing
- 2016-06-17 TR TR2019/10885T patent/TR201910885T4/en unknown
- 2016-06-17 ES ES16747447T patent/ES2740815T3/en active Active
- 2016-06-17 BR BR112017027345-4A patent/BR112017027345A2/en not_active Application Discontinuation
- 2016-06-17 EP EP16747447.7A patent/EP3310498B1/en active Active
- 2016-06-17 DK DK16747447.7T patent/DK3310498T3/en active
- 2016-06-17 CA CA2989246A patent/CA2989246A1/en not_active Abandoned
- 2016-06-17 RU RU2018102077A patent/RU2712611C2/en active
-
2017
- 2017-12-14 CL CL2017003212A patent/CL2017003212A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2016207072A1 (en) | 2016-12-29 |
PL3310498T3 (en) | 2019-10-31 |
US20180187378A1 (en) | 2018-07-05 |
ES2740815T3 (en) | 2020-02-06 |
RU2712611C2 (en) | 2020-01-29 |
DK3310498T3 (en) | 2019-08-05 |
US10246829B2 (en) | 2019-04-02 |
CN107750292A (en) | 2018-03-02 |
TR201910885T4 (en) | 2019-08-21 |
CA2989246A1 (en) | 2016-12-29 |
EP3310498B1 (en) | 2019-05-08 |
CL2017003212A1 (en) | 2018-05-04 |
RU2018102077A3 (en) | 2019-08-21 |
CN107750292B (en) | 2020-02-21 |
DE202015004389U1 (en) | 2015-07-09 |
BR112017027345A2 (en) | 2018-09-04 |
RU2018102077A (en) | 2019-07-23 |
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