EP3300874B1 - Method for manufacturing a paint roller - Google Patents

Method for manufacturing a paint roller Download PDF

Info

Publication number
EP3300874B1
EP3300874B1 EP17187310.2A EP17187310A EP3300874B1 EP 3300874 B1 EP3300874 B1 EP 3300874B1 EP 17187310 A EP17187310 A EP 17187310A EP 3300874 B1 EP3300874 B1 EP 3300874B1
Authority
EP
European Patent Office
Prior art keywords
calcium carbonate
polypropylene
compound
adhesive
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP17187310.2A
Other languages
German (de)
French (fr)
Other versions
EP3300874A3 (en
EP3300874A2 (en
Inventor
Chandra Sekar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/435,946 external-priority patent/US20100282400A1/en
Application filed by Individual filed Critical Individual
Publication of EP3300874A2 publication Critical patent/EP3300874A2/en
Publication of EP3300874A3 publication Critical patent/EP3300874A3/en
Application granted granted Critical
Publication of EP3300874B1 publication Critical patent/EP3300874B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • B29C63/04Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like
    • B29C63/08Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like by winding helically
    • B29C63/10Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like by winding helically around tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/0032Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/02Rollers ; Hand tools comprising coating rollers or coating endless belts
    • B05C17/0207Rollers ; Hand tools comprising coating rollers or coating endless belts characterised by the cover, e.g. cover material or structure, special surface for producing patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/02Rollers ; Hand tools comprising coating rollers or coating endless belts
    • B05C17/0215Rollers ; Hand tools comprising coating rollers or coating endless belts the coating roller itself, i.e. not only its cover being deformable, e.g. to allow proper coating of non-plane surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/56Winding and joining, e.g. winding spirally
    • B29C53/58Winding and joining, e.g. winding spirally helically
    • B29C53/581Winding and joining, e.g. winding spirally helically using sheets or strips consisting principally of plastics material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • B29C63/04Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like
    • B29C63/08Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like by winding helically
    • B29C63/10Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like by winding helically around tubular articles
    • B29C63/105Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like by winding helically around tubular articles continuously
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4855Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by their physical properties, e.g. being electrically-conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/52Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive
    • B29C65/524Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive by applying the adhesive from an outlet device in contact with, or almost in contact with, the surface of the part to be joined
    • B29C65/525Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive by applying the adhesive from an outlet device in contact with, or almost in contact with, the surface of the part to be joined by extrusion coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53Joining single elements to tubular articles, hollow articles or bars
    • B29C66/532Joining single elements to the wall of tubular articles, hollow articles or bars
    • B29C66/5326Joining single elements to the wall of tubular articles, hollow articles or bars said single elements being substantially flat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/504Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/545Perforating, cutting or machining during or after moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D23/00Producing tubular articles
    • B29D23/001Pipes; Pipe joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/0032Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions
    • B29D99/0035Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions rollers or cylinders having an axial length of several times the diameter, e.g. for embossing, pressing, or printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31CMAKING WOUND ARTICLES, e.g. WOUND TUBES, OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31C3/00Making tubes or pipes by feeding obliquely to the winding mandrel centre line
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/48Preparation of the surfaces
    • B29C2063/483Preparation of the surfaces by applying a liquid
    • B29C2063/485Preparation of the surfaces by applying a liquid the liquid being an adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2793/00Shaping techniques involving a cutting or machining operation
    • B29C2793/009Shaping techniques involving a cutting or machining operation after shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0012Combinations of extrusion moulding with other shaping operations combined with shaping by internal pressure generated in the material, e.g. foaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • B29C48/151Coating hollow articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/56Winding and joining, e.g. winding spirally
    • B29C53/58Winding and joining, e.g. winding spirally helically
    • B29C53/60Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels
    • B29C53/607Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels having driving means for advancing the wound articles, e.g. belts, rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/0065Heat treatment
    • B29C63/0069Heat treatment of tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16Fillers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2009/00Layered products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/32Wheels, pinions, pulleys, castors or rollers, Rims
    • B29L2031/328Paint rollers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

Definitions

  • US 2002/0077234 A1 discloses a thermoplastic tubular structure comprising a stationary mandrel, a first and second feeder for feeding a first and a second strip to a mandrel at a first location and second location respectively, and a third feeder for feeding a cover strip to the mandrel at a third location, the third location being downstream of the second location.
  • a transport system adapted to wind and advance the strips as they are being fed to the mandrel is used to helically wind the fed strips around the mandrel.
  • a head for dispensing a width of a liquefied thermoplastic material is also disclosed. The head is oriented to dispense the width of the liquefied thermoplastic material on at least part of a winding of the first strip and part of a winding of the second strip.
  • a cutter is used for cutting the thermoplastic tubular structure into predetermined sizes.
  • Figure 1 shows a diagrammatic representation of a paint roller manufacturing apparatus 100.
  • a strip of material 145 comprising polypropylene is wrapped helically about a mandrel 140 held on a base 150. The mandrel may be cooled by a cooler (not shown).
  • An adhesive 135 comprising polypropylene is applied to an outer surface of the strip 145 by applicator 130.
  • a cover 125 is wrapped around the mandrel 150 over the first strip 145 and the adhesive 135.
  • a helical belt 120 driven by rollers 120a, 120b applies a compressive force on the cover material and advances the tubular assembly 115 down the mandrel 150.
  • a flyaway saw 105 cuts the tubular assembly into lengths 110 that can be used, or cut and used to produce finished paint rollers.
  • the adhesive 135 is a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. In an example the adhesive compound comprises at least 25% but not more than 45% calcium carbonate. In an example the adhesive compound comprises at least 25% but not more than 33% calcium carbonate. In an example, the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 should be selected and/or processed to be relatively non-abrasive to the processing equipment.
  • the applicator 130 applies a compound adhesive 135 formed by a twin screw extruder sufficient for compounding the calcium carbonate with polypropylene (not shown) from a supply of polypropylene resin in pellet form and a supply of calcium carbonate.
  • a twin screw extruder the calcium carbonate should be relatively non-abrasive to a extruder.
  • the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 should be used in a relatively fine, powdered form.
  • the calcium carbonate may have a median particle size of 3 micrometers or less.
  • the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 may be surface treated.
  • the cost by weigh of calcium carbonate is expected to be lower than the cost by weigh of polypropylene, thus the use of a compounded adhesive 135 as described will reduce the cost of manufacturing paint rollers.
  • the adhesive 135 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to have higher thermal conductivity that an adhesive made from polypropylene alone. Accordingly, an adhesive 135 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to cool and set faster than an adhesive made from polypropylene alone. As a result of the higher thermal conductivity, when the apparatus 100 is operated using an adhesive 135 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, it is expected that the apparatus will operate at higher overall throughput than it would when using an adhesive 135 comprising more than 95% polypropylene.
  • the strip 145 is made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. In an example, the strip 145 comprises at least 25% but not more than 45% calcium carbonate. In an example, the strip 145 comprises at least 25% but not more than 33% calcium carbonate.
  • the calcium carbonate compounded with the polypropylene to form the strip 145 should be a relatively fine, powdered form of calcium carbonate.
  • the calcium carbonate compounded with the polypropylene to form the strip 145 should have a median particle size of 3 micrometers or less.
  • the calcium carbonate compounded with the polypropylene to form the strip 145 may be surface treated.
  • the cost by weigh of calcium carbonate is expected to be lower than the cost by weigh of polypropylene, thus the use of a strip 135 made from a compound of polypropylene and calcium carbonate will reduce the cost of manufacturing paint rollers made therewith.
  • the strip 145 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to have higher thermal conductivity that an adhesive made from polypropylene alone. Because of the higher thermal conductivity using a strip 145 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, rather than a strip 145 made from more than 95% polypropylene, it is anticipated that the adhesive 135 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using a strip 145 comprising more than 95% polypropylene.
  • the cover 125 has a fabric backing and a pile outer surface such as knitted or woven cover materials; such a fabric backing of the cover 125 comprises interstitial pores into which adhesive 135 may flow, especially when compressed by the belt 120.
  • the cover is made from a microfiber material; such a microfiber cover 125 also comprises interstitial pores into which adhesive 135 may flow, especially when compressed by the belt 120.
  • the cover 125 has a pile or microfiber outer surface and a smooth or uniformly imprinted backing formed from polypropylene.
  • the cover 125 has a pile or microfiber outer surface and a smooth or uniformly imprinted backing formed from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. In an example, the cover 125 comprises at least 25% but not more than 45% calcium carbonate. In an example, the cover 125 comprises at least 25% but not more than 33% calcium carbonate.
  • the calcium carbonate compounded with the polypropylene to form the backing of the cover 125 should be a relatively fine, powdered form of calcium carbonate.
  • the calcium carbonate compounded with the polypropylene to form the backing of the cover 125 should have a median particle size of 3 micrometers or less.
  • the calcium carbonate compounded with the polypropylene to form the backing of the cover 125 may be surface treated.
  • the cost by weigh of calcium carbonate is expected to be lower than the cost by weigh of polypropylene, thus the use of the backing of the cover 125 made from a compound of polypropylene and calcium carbonate will reduce the cost of manufacturing paint rollers made therewith.
  • the backing of the cover 125 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to have higher thermal conductivity that an adhesive made from polypropylene alone. Because of the higher thermal conductivity using a cover 125 having a backing made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, rather than a backing made from more than 95% polypropylene, it is anticipated that the adhesive 135 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using a cover 125 having a backing comprising more than 95% polypropylene.
  • Apparatus 100 may be operated according to an example using an adhesive 135 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a strip 145 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 250 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight.
  • the percentage of calcium carbonate used in the compound forming the adhesive 135, the strip 145 and the cover 250 backing may be the same, or may differ from one-another.
  • the calcium carbonate When compounding of polypropylene and calcium carbonate in any compound of between 5% and 50% calcium carbonate by weight, the calcium carbonate is not expected to melt. As discussed above, the resulting compounds are expected to have higher thermal conductivity. Variation in the amount of calcium carbonate are within the scope of the disclosure, and thus, it will be apparent to one of skill in the art that to some degree thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in the compound.
  • the compounds of polypropylene and calcium carbonate used in the adhesive 135, strip 145 and/or cover 125 are expected to have achieve other characteristics that, when compared to using polypropylene alone, are expected to include increased stiffness. Increased stiffness may give a paint roller a firmer or stiffer feel, which may improve its performance as a paint roller. Moreover, in many cases, stiffer or firmer paint rollers are sold at a higher price. It will be apparent to one of skill in the art that to some degree, stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in the compound.
  • Figure 2 shows an apparatus 200 for forming the composite paint roller cover 250 having a compound backing.
  • the roller 220 is urged toward the frame 230 by a spring, by gravity or by other means that will be apparent to persons skilled in the art.
  • a layer of compound adhesive 210 is dispensed by an applicator 205 onto a roller 220, and runs between the roller 220 and a frame 230, such as a tenter frame, or between the roller 220 and another roller (not shown).
  • the layer of compound adhesive 210 dispensed onto roller 220 may be between 254 micrometers (0.010") and 508 micrometers (0.020").
  • the compound adhesive 210 is a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight.
  • the adhesive compound comprises at least 25% but not more than 45% calcium carbonate.
  • the adhesive compound comprises at least 25% but not more than 33% calcium carbonate.
  • the calcium carbonate should be relatively non-abrasive to the processing machinery.
  • the cover material 215 is advanced along the frame 205 with its pile side down, and moved beneath the roller 220.
  • the cover material 215 may have a pile side and a fabric backing - the fabric backing being porous and having interstitial spaces sufficient to permit penetration of the compound adhesive 210.
  • the roller-side of the compound adhesive 210 may be smoothed or uniformly imprinted (e.g., embossed) by the roller 220 as it passed underneath, thus forming a uniform or smooth adhesive layer surface 225.
  • the roller 220 applies a compressive force to urge the compound adhesive 210 towards the cover material 215.
  • the compressive force is sufficient to force the compound adhesive 210 into the interstitial spaces within the fabric backing of the cover material 215.
  • the resulting composite sheet material 235 may be cut by a cutter 240 to trim away advances the tubular assembly 310 down the mandrel 350.
  • a flyaway saw 305 may cut the tubular assembly 310 into lengths (not shown) that can be used, or further cut and used to produce finished paint rollers.
  • the applicator 330 applies a compound adhesive 335 formed by a twin screw extruder sufficient for compounding the calcium carbonate with polypropylene (not shown) from a supply of polypropylene resin in pellet form and a supply of calcium carbonate.
  • a twin screw extruder the calcium carbonate should be relatively non-abrasive to a extruder.
  • Apparatus 300 may be operated according to an example using an adhesive 335 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a strip 345 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a second strip 348 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 325 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight.
  • the percentage of calcium carbonate used in the compound forming the adhesive 335, the strip 345, the second strip 348 and the cover 325 backing may be the same, or may differ from one-another.
  • thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds.
  • stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • Figure 4 shows a paint roller manufacturing apparatus 400.
  • a strip of material 448 comprising polypropylene is wrapped helically about a mandrel 440 held on a base 450.
  • the mandrel may be cooled by a cooler (not shown).
  • a second strip of material 445 comprising polypropylene is wrapped helically about the first strip 448.
  • the heaters 460, 455 which may employ heating elements or heat by open flame, heat the outer surface (vis-à-vis the wrapping about the mandrel) of strips 448, 445 respectively.
  • the heat produced by the heaters 460 is sufficient to cause the outer surface of the strips 448, 445 to become tacky, or to liquefy, or to become molten.
  • a cover 415 is also helically wrapped around the mandrel 440 over the outer surface of the second strip 445.
  • a helical belt drive 420 applies an inwardly compressive force on the cover material 415 and advances the assembly down the mandrel 440.
  • a flyaway saw 405 may cut the assembly into lengths (not shown) that can be used, or further cut and used to produce finished paint rollers.
  • Apparatus 400 may be operated according to an example using a strip 448 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a second strip 445 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 415 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight.
  • the percentage of calcium carbonate used in the compound forming the strips 448, 445 and the cover 415 backing may be the same, or may differ from one-another.
  • thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds.
  • stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • FIG. 5 shows an apparatus 500 suitable for making paint rollers with a preformed core.
  • the apparatus 500 comprises a rotating mandrel 510, a carriage 560 running on a stationary track 570 and supporting a cover material guide 550, and a heater 530.
  • a preformed core 540 comprising polypropylene is placed about the mandrel 510.
  • the heater 530 is activated, thereby heat softening the outer surface of the preformed core in an amount sufficient to bond to the backing of the cover 520.
  • the cover 520 is wrapped helically about the core by the rotation of the mandrel and the movement of the carriage 560.
  • the rotation of the mandrel 510 and the movement of the carriage 560 are such that the cover 520 is wrapped about substantially all of the preformed core 540.
  • Apparatus 500 may be operated according to an example using a preformed core 540 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 520 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight.
  • a preformed core 540 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight and/or using a cover 520 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight.
  • the percentage of calcium carbonate used in the compound forming the core 540 and the cover 520 backing may be the same, or may differ from one-another.
  • thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds.
  • stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight in lieu of polypropylene may be used in making paint rollers.
  • other methods for the manufacture of the same will be apparent to persons of skill in the art.
  • Benefits of certain examples include: control of thermal conductivity in the component materials leading to faster throughput and/or faster set times; and control of material characteristics such as stiffness for manufacture of harder, more expensive paint rollers.
  • non-refined calcium carbonate in combination with polypropylene e.g., calcium carbonate that has not been surface treated
  • the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 may be a non-refined calcium carbonate.
  • the non-refined calcium carbonate is used in a relatively fine, powdered form.
  • the calcium carbonate may have a median particle size of 3 micrometres or less.
  • a twin screw extruder (not shown) may be used to compound non- refined calcium carbonate and polypropylene together to form the compound adhesive 135.
  • the twin screw extruder may accept a supply of polypropylene resin in pellet form and a separate supply of calcium carbonate.
  • the raw materials required to make a compounded adhesive comprising 5% calcium carbonate by weight is approximately $1.3503 per kilogram ($0.6125 per pound); the raw materials required to make a compounded adhesive comprising 50% calcium carbonate by weight is approximately $0.804 per kilogram ($0.365 per pound); and the raw materials required to make a compounded adhesive comprising 60% calcium carbonate by weight is approximately $0.68 per kilogram ($0.31 per pound). While the process of compounding the materials itself has a cost, the large factors in savings are: (i) the disparity between the cost of the polypropylene resin and the calcium carbonate; and (ii) the percentages of calcium carbonate that can be used.
  • adhesive 135 is a compound of polypropylene and calcium carbonate having between 50% and 66% calcium carbonate by weight.
  • an adhesive compound 135 comprises at least 55% but not more than 65% calcium carbonate.
  • an adhesive compound 135 is a compound of polypropylene and calcium carbonate having approximately 60% calcium carbonate by weight.
  • an adhesive 335 is a compound of polypropylene and calcium carbonate having at least 50%, but less than 60% calcium carbonate by weight.
  • an adhesive compound 335 is a compound of polypropylene and calcium carbonate having approximately 56% calcium carbonate by weight.
  • Polypropylene resin 6823MZ-US in pellet form used to create adhesive first used for the further testing had a melt flow index ("MFI") of approximately 32.
  • MFI melt flow index
  • the 32 MFI resin was compounded with a 60% mixture of calcium carbonate to form the compound adhesive 135.
  • the resulting compound adhesive 135 had an MFI of approximately 14.4.
  • the compound adhesive could be extruded through applicator 130, the low MFI appeared to cause the extruded to struggle, and the extruded material was highly viscous.
  • the paint rollers resulting from the foregoing compound appeared to be substantially stronger when non-refined calcium carbonate was used rather than surface treated calcium carbonate.
  • Polypropylene resin 4920WZ-US was tried. Polypropylene resin 4920WZ-US in pellet form used to create adhesive next used for the further testing had a melt flow index ("MFI") of approximately 105.
  • MFI melt flow index
  • the 105 MFI resin was compounded with a 60% mixture of calcium carbonate to form the compound adhesive 135.
  • the resulting compound adhesive 135 had an MFI of approximately 28.8.
  • the compound adhesive 135 was extruded through applicator 130 without substantial stress on the extruder as the compounded adhesive 135 was of appropriate viscosity for use with the applicator 130.
  • the 105 MFI resin was compounded with a 56% mixture of calcium carbonate to form the compound adhesive 335.
  • the resulting compound adhesive 335 had an MFI of approximately 32.
  • the compound adhesive 335 was extruded through applicator 330 without substantial stress on the extruder as the compounded adhesive 335 was of appropriate viscosity for use with the applicator 330.
  • the paint rollers resulting from the foregoing compound appeared to be substantially stronger when non-refined calcium carbonate was used rather than surface treated calcium carbonate.
  • the use of a polypropylene resin having a higher MFI, such as an MFI of approximately 120, with 60% calcium carbonate would have achieved acceptable results.
  • strip material 145, 345, 348, 445, 448 can be manufactured using a compound of polypropylene and calcium carbonate.
  • a strip 145, 345, 348, 445, 448 is cut lengthwise from a sheet material (not shown) that is manufactured using a compound of polypropylene and calcium carbonate.
  • the thickness of the sheet material is determined by successive rollers. Because rollers are used to control thickness, the MFI of the polypropylene / calcium carbonate compound may be substantially lower than that of the MFI required for use a compound adhesives 135, 335.
  • 4.1 MFI polypropylene resin 3462-US is compounded with approximate 60% by weight of calcium carbonate.
  • the resulting polypropylene / calcium carbonate compound having an MFI of approximately 2, can be run through successive rollers to reach a desired thickness. Almost any desired strip thickness can be attained.
  • a sheet of polypropylene / calcium carbonate compound material having thickness of approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) can be cut longitudinally into one or more strip 145, 345, 348, 445, 448.
  • the calcium carbonate used in manufacturing sheet material which can be cut into strips is non-refined calcium carbonate.
  • an apparatus 200 is shown for forming the composite paint roller cover 250 having a compound backing.
  • a layer of compound adhesive 210 is dispensed by an applicator 205.
  • the layer of compound adhesive 210 dispensed may be dispensed onto roller 220 or directly onto cover material 215.
  • the layer of compound adhesive 210 is between 254 micrometers (0.010") and 508 micrometers (0.020").
  • the compound adhesive 210 is a compound of polypropylene and calcium carbonate having at least 50%, and not more than 66% calcium carbonate by weight.
  • the MFI of polypropylene / calcium carbonate compound may be varied by changing using a polypropylene resin having a higher or lower MFI, as well as by varying the ratio of calcium carbonate.
  • polypropylene resin having a higher MFI will cause the polypropylene / calcium carbonate compound to have a higher MFI when using the same ratio of calcium carbonate.
  • the MFI of the resulting compound can be lowered by reducing the percentage of calcium carbonate used in the polypropylene / calcium carbonate compound.
  • the cover material 215 has a pile side and a fabric backing - the fabric backing being porous and having interstitial spaces sufficient to permit penetration of compound adhesive 210.
  • the compound adhesive 210 has an MFI higher than 2.
  • the compound adhesive 210 has an MFI between 14 and 105.
  • an MFI of in or around the mid 70's is desired to permit the compound 210 to properly permeate the fabric backing of the cover material 215.
  • MFI polypropylene resin is compounded with 25% calcium carbonate by weight.
  • the apparatus comprises an applicator 205 that applies a compound adhesive 210 formed by a twin screw extruder sufficient for compounding calcium carbonate with polypropylene (not shown) from a supply of polypropylene resin in pellet form and a supply of calcium carbonate to produce a compound that includes at least 50% calcium carbonate by weight.
  • a compound adhesive 210 formed by a twin screw extruder sufficient for compounding calcium carbonate with polypropylene (not shown) from a supply of polypropylene resin in pellet form and a supply of calcium carbonate to produce a compound that includes at least 50% calcium carbonate by weight.
  • a strip 145 comprises polypropylene, and has a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the strip 145 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the strip 145 may be of another suitable thickness.
  • the strip 145 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the strip 145 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The strip 145 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a strip made from polypropylene alone, or than a strip made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight.
  • adhesive 135 comprises polypropylene, and is applied in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the layer of adhesive 135 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the layer of adhesive 135 is another suitable thickness.
  • the adhesive 135 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the adhesive 135 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The adhesive 135 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than an adhesive made from polypropylene alone, or than an adhesive made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight.
  • an adhesive 135 made from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight it is anticipated that it will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using an adhesive 135 comprising more than 50% polypropylene.
  • the backing of composite cover 125 comprises polypropylene, and the backing comprising polypropylene is in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil).
  • the backing layer of the composite cover material 125 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick.
  • the backing of the composite cover material 125 is another suitable thickness.
  • the backing of the composite cover material 125 is formed from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the backing of the composite cover material 125 is formed from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The backing of the composite cover material 125 formed from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a backing made from polypropylene alone, or than a backing made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight.
  • the following table presents illustrative paint rollers that can be formed using the methods disclosed herein.
  • the "Cover” column refers to the cover material 125 used
  • the "Adhesive” column refers to the adhesive 135 used
  • the "Strip” column refers to the strip 145 used in the example.
  • the entry reflects the thickness in micrometers (mil), and the percentage of calcium carbonate (by weight) compounded with polypropylene to form the component.
  • the thickness in micrometers (mil) for the "Cover” column reflects the thickness of the layer 135 used to form the composite cover material 125 - the "Cover” column entries showing a thickness of 0 reflect the use of a cover material rather than a composite cover material.
  • Example B 1 0 / 0% 254 ⁇ m (10 mil) / 60% 508 ⁇ m (20 mil) / 60%
  • Example B2 254 ⁇ m (10 mil) / 0% 254 ⁇ m (10 mil) / 60% 508 ⁇ m (20 mil) / 60%
  • Example B3 254 ⁇ m (10 mil) / 25% 254 ⁇ m (10 mil) / 60% 508 ⁇ m (20 mil) / 60%
  • Example A1 and B1 each make paint rollers of the same thickness, however, the characteristics of the paint roller B1 are substantially improved when compared to those of A1.
  • the B1 paint roller feels firmer and is of higher quality than the A1 paint roller.
  • the 762 micrometers (30 mil) thick B1 paint roller uses only 40% of the polypropylene used to manufacture the A1 paint roller (excluding any polypropylene in the cover material).
  • Example A2 and B2 each make paint rollers of the same thickness, however, the characteristics of the paint roller B2 are substantially improved when compared to those of A2.
  • the B2 paint roller feels firmer and is of higher quality than the A2 paint roller.
  • the 1016 micrometers (40 mil) thick B2 paint roller uses only 55% of the polypropylene used to make the A2 paint roller (excluding any polypropylene in the cover material).
  • the B1 paint roller compares favorably to the A2 paint roller while using only as much as 30% as much polypropylene.
  • B3 paint roller is the most superior of all of these example rollers, and it uses less than half as much polypropylene as the A2 roller, and just over half as much as the A1 roller.
  • strips 345, 348 comprises polypropylene, and each have a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, strips 345, 348 are each approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, strips 345, 348 may be of another suitable thickness. It is not necessary that each of the strips 345, 348 are the same thickness.
  • At least one strip 345, 348 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, at least one strip 345, 348 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. A strip 345, 348 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a strip made from polypropylene alone, or than a strip made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight.
  • adhesive 335 comprises polypropylene, and is applied in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the layer of adhesive 335 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the layer of adhesive 335 is another suitable thickness.
  • the adhesive 335 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the adhesive 335 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The adhesive 335 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than an adhesive made from polypropylene alone, or than an adhesive made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight.
  • an adhesive 335 made from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight it is anticipated that it will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using an adhesive 335 comprising more than 50% polypropylene.
  • the backing of cover 325 comprises polypropylene, and the backing comprising polypropylene is in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil).
  • the backing layer of the composite cover material 325 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick.
  • the backing of the composite cover material 325 is another suitable thickness.
  • the backing of the composite cover material 325 is formed from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the backing of the composite cover material 325 is formed from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The backing of the composite cover material 325 formed from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a backing made from polypropylene alone, or than a backing made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight.
  • the following table presents illustrative paint rollers that can be formed using the methods disclosed herein.
  • the "Cover” column refers to the cover material 325 used
  • the "Adhesive” column refers to the adhesive 335 used
  • the "Strip 1" column refers to the strip 345 used
  • the "Strip 2" column refers to the strip 348 used in the example.
  • the entry reflects the thickness in micrometers (mil), and the percentage of calcium carbonate (by weight) compounded with polypropylene to form the component.
  • the thickness in micrometers (mil) for the "Cover” column reflects the thickness of the layer 335 used to form the composite cover material 325 - the "Cover” column entries showing a thickness of 0 reflect the use of a cover material rather than a composite cover material.
  • Example C1 and D1 each make paint rollers of the same thickness, however, the characteristics of the paint roller D1 are substantially improved when compared to those of C1.
  • the D1 paint roller feels firmer and is of higher quality than the C1 paint roller.
  • the 1016 micrometers (40 mil) thick core of the D1 paint roller uses only 42% of the polypropylene used to manufacture the C1 paint roller (excluding any polypropylene in the cover material).
  • Example D2 forms a paint roller with very good properties and firmness. This roller compares favorably to Example D1 due to its extra 254 micrometers (10 mil) thickness. Moreover, Example D2 compare favorably not only to Example C1, but to Example C2 having a core of the same thickness (1270 micrometers (50 mil)), and even to Example C3, despite Example C3 having a core of 1778 micrometers (70 mil) and using substantially more than twice as much polypropylene. Example D3 makes an even better paint roller, while Example D4 makes an excellent quality paint roller. Notably, while Example D4 is the same core thickness as example C3, it uses only about 46% as much polypropylene.
  • Example C4 provides approximately the same qualities as the single strip, 1016 micrometers (40 mil) core roller of Example A2, while the latter roller uses only about 37% as much polypropylene. Also, notably, the two-strip 1270 micrometers (50 mil) core Example D2 provides a much stronger roller than the two-strip 1524 micrometers (60 mil) core roller made according to Example C4.
  • one or both of the strips 445, 448 can be made from a compound of polypropylene and calcium carbonate having at least 50%, but not more than about 66% calcium carbonate by weight.
  • the cover 415 may having a backing made of a compound of polypropylene and calcium carbonate having at least 50% but not more than 66% calcium carbonate by weight.
  • the percentage of calcium carbonate used in the compound forming the strips 448, 445 and the cover 415 backing may be the same, or may differ from one-another.
  • the strips 445, 448 are made from a compound of polypropylene and calcium carbonate having approximately 60% calcium carbonate, and the cover 415 has a backing made of a compound of 105 MFI polypropylene and non-refined calcium carbonate having approximately 25% calcium carbonate by weight.
  • Apparatus 500 may be operated according to an example using a preformed core 540 made of a compound of polypropylene and calcium carbonate having at least 50%, but not more than 66% calcium carbonate by weight; and/or using a cover 520 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 66% calcium carbonate by weight.
  • the percentage of calcium carbonate used in the compound forming the core 540 and the cover 520 backing may be the same, or may differ from one-another.
  • the core 540 is made of a compound of polypropylene and calcium carbonate comprising approximately 60% calcium carbonate by weight
  • the cover backing is made of a compound of polypropylene and calcium carbonate comprising approximately 25% calcium carbonate by weight.
  • thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds.
  • stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • Benefits of certain methods disclosed herein include: control of thermal conductivity in the component materials leading to faster throughput and/or faster set times; and control of material characteristics such as stiffness for manufacture of harder, more expensive paint rollers.

Description

    BACKGROUND
  • US 2002/0077234 A1 discloses a thermoplastic tubular structure comprising a stationary mandrel, a first and second feeder for feeding a first and a second strip to a mandrel at a first location and second location respectively, and a third feeder for feeding a cover strip to the mandrel at a third location, the third location being downstream of the second location. A transport system adapted to wind and advance the strips as they are being fed to the mandrel is used to helically wind the fed strips around the mandrel. A head for dispensing a width of a liquefied thermoplastic material is also disclosed. The head is oriented to dispense the width of the liquefied thermoplastic material on at least part of a winding of the first strip and part of a winding of the second strip. A cutter is used for cutting the thermoplastic tubular structure into predetermined sizes.
  • FIELD OF THE INVENTION
  • According to an aspect of the present invention, there is provided a method of making a laminated paint roller as defined in claim 1. Preferred embodiments are defined in the dependent claims.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • In the accompanying drawings forming a part of this specification, and in which like reference characters are employed to designate like parts throughout the same:
    • Figure 1 is a diagrammatic representation of a paint roller manufacturing apparatus that can be used in accordance with an example of the present disclosure.
    • Figure 2 is a diagrammatic representation of an apparatus for forming a composite paint roller cover having a compound backing in accordance with an example of the present disclosure.
    • Figure 3 is a diagrammatic representation of a multi-strip laminate paint roller manufacturing apparatus that can be used in accordance with an example of the present disclosure.
    • Figure 4 is a diagrammatic representation of another paint roller manufacturing apparatus that can be used in accordance with an example of the present disclosure.
    • Figure 5 is a diagrammatic representation of yet another paint roller manufacturing apparatus that can be used in accordance with an example of the present disclosure.
    DETAILED DESCRIPTION
  • Figure 1 shows a diagrammatic representation of a paint roller manufacturing apparatus 100. A strip of material 145 comprising polypropylene is wrapped helically about a mandrel 140 held on a base 150. The mandrel may be cooled by a cooler (not shown). An adhesive 135 comprising polypropylene is applied to an outer surface of the strip 145 by applicator 130. A cover 125 is wrapped around the mandrel 150 over the first strip 145 and the adhesive 135. A helical belt 120 driven by rollers 120a, 120b applies a compressive force on the cover material and advances the tubular assembly 115 down the mandrel 150. A flyaway saw 105 cuts the tubular assembly into lengths 110 that can be used, or cut and used to produce finished paint rollers.
  • Compound Adhesive
  • In an example, the adhesive 135 is a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. In an example the adhesive compound comprises at least 25% but not more than 45% calcium carbonate. In an example the adhesive compound comprises at least 25% but not more than 33% calcium carbonate. In an example, the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 should be selected and/or processed to be relatively non-abrasive to the processing equipment.
  • In an example, the applicator 130 applies a compound adhesive 135 formed by a twin screw extruder sufficient for compounding the calcium carbonate with polypropylene (not shown) from a supply of polypropylene resin in pellet form and a supply of calcium carbonate. When using a twin screw extruder, the calcium carbonate should be relatively non-abrasive to a extruder.
  • In an example, the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 should be used in a relatively fine, powdered form. In an example, the calcium carbonate may have a median particle size of 3 micrometers or less. In an example, the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 may be surface treated.
  • The cost by weigh of calcium carbonate is expected to be lower than the cost by weigh of polypropylene, thus the use of a compounded adhesive 135 as described will reduce the cost of manufacturing paint rollers.
  • The adhesive 135 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to have higher thermal conductivity that an adhesive made from polypropylene alone. Accordingly, an adhesive 135 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to cool and set faster than an adhesive made from polypropylene alone. As a result of the higher thermal conductivity, when the apparatus 100 is operated using an adhesive 135 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, it is expected that the apparatus will operate at higher overall throughput than it would when using an adhesive 135 comprising more than 95% polypropylene.
  • Compound Strip Material
  • In an example, the strip 145 is made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. In an example, the strip 145 comprises at least 25% but not more than 45% calcium carbonate. In an example, the strip 145 comprises at least 25% but not more than 33% calcium carbonate.
  • In an example, the calcium carbonate compounded with the polypropylene to form the strip 145 should be a relatively fine, powdered form of calcium carbonate. In an example, the calcium carbonate compounded with the polypropylene to form the strip 145 should have a median particle size of 3 micrometers or less. In an example, the calcium carbonate compounded with the polypropylene to form the strip 145 may be surface treated.
  • The cost by weigh of calcium carbonate is expected to be lower than the cost by weigh of polypropylene, thus the use of a strip 135 made from a compound of polypropylene and calcium carbonate will reduce the cost of manufacturing paint rollers made therewith.
  • The strip 145 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to have higher thermal conductivity that an adhesive made from polypropylene alone. Because of the higher thermal conductivity using a strip 145 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, rather than a strip 145 made from more than 95% polypropylene, it is anticipated that the adhesive 135 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using a strip 145 comprising more than 95% polypropylene.
  • Cover Material
  • In an example, the cover 125 has a fabric backing and a pile outer surface such as knitted or woven cover materials; such a fabric backing of the cover 125 comprises interstitial pores into which adhesive 135 may flow, especially when compressed by the belt 120. In an example, the cover is made from a microfiber material; such a microfiber cover 125 also comprises interstitial pores into which adhesive 135 may flow, especially when compressed by the belt 120.
  • In an example, the cover 125 has a pile or microfiber outer surface and a smooth or uniformly imprinted backing formed from polypropylene.
  • In an example, the cover 125 has a pile or microfiber outer surface and a smooth or uniformly imprinted backing formed from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. In an example, the cover 125 comprises at least 25% but not more than 45% calcium carbonate. In an example, the cover 125 comprises at least 25% but not more than 33% calcium carbonate.
  • In an example, the calcium carbonate compounded with the polypropylene to form the backing of the cover 125 should be a relatively fine, powdered form of calcium carbonate. In an example, the calcium carbonate compounded with the polypropylene to form the backing of the cover 125 should have a median particle size of 3 micrometers or less. In an example, the calcium carbonate compounded with the polypropylene to form the backing of the cover 125 may be surface treated.
  • The cost by weigh of calcium carbonate is expected to be lower than the cost by weigh of polypropylene, thus the use of the backing of the cover 125 made from a compound of polypropylene and calcium carbonate will reduce the cost of manufacturing paint rollers made therewith.
  • The backing of the cover 125 made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight is expected to have higher thermal conductivity that an adhesive made from polypropylene alone. Because of the higher thermal conductivity using a cover 125 having a backing made from a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, rather than a backing made from more than 95% polypropylene, it is anticipated that the adhesive 135 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using a cover 125 having a backing comprising more than 95% polypropylene.
  • Use of Compounded Materials
  • Apparatus 100 may be operated according to an example using an adhesive 135 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a strip 145 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 250 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. When more than one component is made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, the percentage of calcium carbonate used in the compound forming the adhesive 135, the strip 145 and the cover 250 backing may be the same, or may differ from one-another.
  • When compounding of polypropylene and calcium carbonate in any compound of between 5% and 50% calcium carbonate by weight, the calcium carbonate is not expected to melt. As discussed above, the resulting compounds are expected to have higher thermal conductivity. Variation in the amount of calcium carbonate are within the scope of the disclosure, and thus, it will be apparent to one of skill in the art that to some degree thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in the compound.
  • The compounds of polypropylene and calcium carbonate used in the adhesive 135, strip 145 and/or cover 125 are expected to have achieve other characteristics that, when compared to using polypropylene alone, are expected to include increased stiffness. Increased stiffness may give a paint roller a firmer or stiffer feel, which may improve its performance as a paint roller. Moreover, in many cases, stiffer or firmer paint rollers are sold at a higher price. It will be apparent to one of skill in the art that to some degree, stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in the compound.
  • Figure 2 shows an apparatus 200 for forming the composite paint roller cover 250 having a compound backing. The roller 220 is urged toward the frame 230 by a spring, by gravity or by other means that will be apparent to persons skilled in the art. A layer of compound adhesive 210 is dispensed by an applicator 205 onto a roller 220, and runs between the roller 220 and a frame 230, such as a tenter frame, or between the roller 220 and another roller (not shown). The layer of compound adhesive 210 dispensed onto roller 220 may be between 254 micrometers (0.010") and 508 micrometers (0.020"). In an example, the compound adhesive 210 is a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. In an example the adhesive compound comprises at least 25% but not more than 45% calcium carbonate. In an example the adhesive compound comprises at least 25% but not more than 33% calcium carbonate. The calcium carbonate should be relatively non-abrasive to the processing machinery.
  • The cover material 215 is advanced along the frame 205 with its pile side down, and moved beneath the roller 220. The cover material 215 may have a pile side and a fabric backing - the fabric backing being porous and having interstitial spaces sufficient to permit penetration of the compound adhesive 210. As the cover material 215 and the layer of compound adhesive 210 pass between the roller 220 and the surface of the frame 230 they are urged together. The roller-side of the compound adhesive 210 may be smoothed or uniformly imprinted (e.g., embossed) by the roller 220 as it passed underneath, thus forming a uniform or smooth adhesive layer surface 225.
  • In an example, the roller 220 applies a compressive force to urge the compound adhesive 210 towards the cover material 215. In an example, the compressive force is sufficient to force the compound adhesive 210 into the interstitial spaces within the fabric backing of the cover material 215. The resulting composite sheet material 235 may be cut by a cutter 240 to trim away advances the tubular assembly 310 down the mandrel 350. A flyaway saw 305 may cut the tubular assembly 310 into lengths (not shown) that can be used, or further cut and used to produce finished paint rollers.
  • In an example, the applicator 330 applies a compound adhesive 335 formed by a twin screw extruder sufficient for compounding the calcium carbonate with polypropylene (not shown) from a supply of polypropylene resin in pellet form and a supply of calcium carbonate. When using a twin screw extruder, the calcium carbonate should be relatively non-abrasive to a extruder.
  • Apparatus 300 may be operated according to an example using an adhesive 335 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a strip 345 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a second strip 348 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 325 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. When more than one component is made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, the percentage of calcium carbonate used in the compound forming the adhesive 335, the strip 345, the second strip 348 and the cover 325 backing may be the same, or may differ from one-another.
  • Variation in the amount of calcium carbonate are within the scope of the disclosure, and thus, it will be apparent to one of skill in the art that to some degree thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds. It will be apparent to one of skill in the art that to some degree, stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • Figure 4 shows a paint roller manufacturing apparatus 400. A strip of material 448 comprising polypropylene is wrapped helically about a mandrel 440 held on a base 450. The mandrel may be cooled by a cooler (not shown). A second strip of material 445 comprising polypropylene is wrapped helically about the first strip 448. The heaters 460, 455 which may employ heating elements or heat by open flame, heat the outer surface (vis-à-vis the wrapping about the mandrel) of strips 448, 445 respectively. The heat produced by the heaters 460 is sufficient to cause the outer surface of the strips 448, 445 to become tacky, or to liquefy, or to become molten. (Although shown diagrammatically at a distance from the mandrel, in an example, the heaters 460, 455 should be placed as close as practicable to the point where the strips 448, 445 contact the mandrel.) A cover 415 is also helically wrapped around the mandrel 440 over the outer surface of the second strip 445. A helical belt drive 420 applies an inwardly compressive force on the cover material 415 and advances the assembly down the mandrel 440. A flyaway saw 405 may cut the assembly into lengths (not shown) that can be used, or further cut and used to produce finished paint rollers.
  • Apparatus 400 may be operated according to an example using a strip 448 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; using a second strip 445 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 415 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. When more than one component is made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, the percentage of calcium carbonate used in the compound forming the strips 448, 445 and the cover 415 backing may be the same, or may differ from one-another.
  • Variation in the amount of calcium carbonate are within the scope of the disclosure, and thus, it will be apparent to one of skill in the art that to some degree thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds. It will be apparent to one of skill in the art that to some degree, stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • Figure 5 shows an apparatus 500 suitable for making paint rollers with a preformed core. The apparatus 500 comprises a rotating mandrel 510, a carriage 560 running on a stationary track 570 and supporting a cover material guide 550, and a heater 530. A preformed core 540 comprising polypropylene is placed about the mandrel 510. The heater 530 is activated, thereby heat softening the outer surface of the preformed core in an amount sufficient to bond to the backing of the cover 520. The cover 520 is wrapped helically about the core by the rotation of the mandrel and the movement of the carriage 560. The rotation of the mandrel 510 and the movement of the carriage 560 are such that the cover 520 is wrapped about substantially all of the preformed core 540.
  • Apparatus 500 may be operated according to an example using a preformed core 540 made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight; and/or using a cover 520 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight. When more than one component is made of a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight, the percentage of calcium carbonate used in the compound forming the core 540 and the cover 520 backing may be the same, or may differ from one-another.
  • Variation in the amount of calcium carbonate are within the scope of the disclosure, and thus, it will be apparent to one of skill in the art that to some degree thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds. It will be apparent to one of skill in the art that to some degree, stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • In an example, a compound of polypropylene and calcium carbonate having between 5% and 50% calcium carbonate by weight in lieu of polypropylene may be used in making paint rollers. In light of this disclosure, other methods for the manufacture of the same will be apparent to persons of skill in the art.
  • Benefits of certain examples include: control of thermal conductivity in the component materials leading to faster throughput and/or faster set times; and control of material characteristics such as stiffness for manufacture of harder, more expensive paint rollers.
  • FURTHER OBSERVATIONS
  • In experimenting with various ratios and materials, several further observations have been made, and such further observations are hereinafter presented, in addition to those discussed above. Polypropylene identified as 3462-US, 4920WZ-US and 6823MZ-US from Total Petrochemicals of Houston, Texas was used for experimentation. MFI reported herein for the polypropylene resin is as understood from Total Petrochemicals literature.
  • Calcium Carbonate
  • The use of non-refined calcium carbonate in combination with polypropylene, e.g., calcium carbonate that has not been surface treated, adds strength to the resulting paint roller product when compared to a combination of refined calcium carbonate in combination with polypropylene. Thus, in an example, the calcium carbonate compounded with the polypropylene to form the compound adhesive 135 (Fig. 1) may be a non-refined calcium carbonate. In an example, the non-refined calcium carbonate is used in a relatively fine, powdered form. In an example the calcium carbonate may have a median particle size of 3 micrometres or less.
  • In an example, a twin screw extruder (not shown) may be used to compound non- refined calcium carbonate and polypropylene together to form the compound adhesive 135. The twin screw extruder may accept a supply of polypropylene resin in pellet form and a separate supply of calcium carbonate.
  • Ratio and Composition of Compound Adhesive
  • Experimentation was performed concerning the ratio of calcium carbonate - a ratio earlier thought to be preferred between 5% and 50% calcium carbonate by weight. As discussed above, the cost by weigh of calcium carbonate is generally lower than the cost by weigh of polypropylene, thus, the raw material cost of a compounded adhesive will be reduced as the ratio of calcium carbonate rises. Typically, today, the cost of polypropylene resin may be $1.41 per kilogram ($0.64 per pound), while the cost of appropriate calcium carbonate may be $0.19 per kilogram ($0.09 per pound). Using those typical costs, the raw materials required to make a compounded adhesive comprising 5% calcium carbonate by weight is approximately $1.3503 per kilogram ($0.6125 per pound); the raw materials required to make a compounded adhesive comprising 50% calcium carbonate by weight is approximately $0.804 per kilogram ($0.365 per pound); and the raw materials required to make a compounded adhesive comprising 60% calcium carbonate by weight is approximately $0.68 per kilogram ($0.31 per pound). While the process of compounding the materials itself has a cost, the large factors in savings are: (i) the disparity between the cost of the polypropylene resin and the calcium carbonate; and (ii) the percentages of calcium carbonate that can be used.
  • Experimentation was performed and acceptable results were found using a compounded adhesive 135 (see Figure 1) made from polypropylene resin with approximately 60% calcium carbonate by weight. In an example, adhesive 135 is a compound of polypropylene and calcium carbonate having between 50% and 66% calcium carbonate by weight. In an example, an adhesive compound 135 comprises at least 55% but not more than 65% calcium carbonate. In an example, an adhesive compound 135 is a compound of polypropylene and calcium carbonate having approximately 60% calcium carbonate by weight.
  • Experimentation was performed and acceptable results were found using a compounded adhesive 335 (see Figure 3) made from polypropylene resin with approximately 56% calcium carbonate by weight. In an example, an adhesive 335 is a compound of polypropylene and calcium carbonate having at least 50%, but less than 60% calcium carbonate by weight. In an example, an adhesive compound 335 is a compound of polypropylene and calcium carbonate having approximately 56% calcium carbonate by weight.
  • Polypropylene resin 6823MZ-US in pellet form used to create adhesive first used for the further testing had a melt flow index ("MFI") of approximately 32. For the further testing, the 32 MFI resin was compounded with a 60% mixture of calcium carbonate to form the compound adhesive 135. The resulting compound adhesive 135 had an MFI of approximately 14.4. Although the compound adhesive could be extruded through applicator 130, the low MFI appeared to cause the extruded to struggle, and the extruded material was highly viscous. The paint rollers resulting from the foregoing compound appeared to be substantially stronger when non-refined calcium carbonate was used rather than surface treated calcium carbonate. When the same 32 MFI resin was compounded with the same 60% mixture of calcium carbonate to form the compound adhesive 335 (see Fig. 3), it appeared that the MFI of the compound adhesive 335 was too high to permit a smooth flow from the applicator 330.
  • Polypropylene resin 4920WZ-US was tried. Polypropylene resin 4920WZ-US in pellet form used to create adhesive next used for the further testing had a melt flow index ("MFI") of approximately 105. For the next test, the 105 MFI resin was compounded with a 60% mixture of calcium carbonate to form the compound adhesive 135. The resulting compound adhesive 135 had an MFI of approximately 28.8. Using the 105 MFI resin, the compound adhesive 135 was extruded through applicator 130 without substantial stress on the extruder as the compounded adhesive 135 was of appropriate viscosity for use with the applicator 130. Again, the paint rollers resulting from the foregoing compound was substantially stronger when non-refined calcium carbonate was used rather than surface treated calcium carbonate. When the same 105 MFI resin was compounded with the same 60% mixture of calcium carbonate to form the compound adhesive 335 (see Fig. 3), it again appeared that the MFI was too high to permit a smooth flow from the applicator 330.
  • As the vendor did not have polypropylene resin available with an MFI higher than 105, for the following test, the 105 MFI resin was compounded with a 56% mixture of calcium carbonate to form the compound adhesive 335. The resulting compound adhesive 335 had an MFI of approximately 32. Using the 105 MFI resin, the compound adhesive 335 was extruded through applicator 330 without substantial stress on the extruder as the compounded adhesive 335 was of appropriate viscosity for use with the applicator 330. As before, the paint rollers resulting from the foregoing compound appeared to be substantially stronger when non-refined calcium carbonate was used rather than surface treated calcium carbonate. As an alternative to reducing ratio of calcium carbonate to 56%, the use of a polypropylene resin having a higher MFI, such as an MFI of approximately 120, with 60% calcium carbonate would have achieved acceptable results.
  • Composition of Strips
  • As with composite adhesives 135, 335, strip material 145, 345, 348, 445, 448 can be manufactured using a compound of polypropylene and calcium carbonate. In an example, a strip 145, 345, 348, 445, 448 is cut lengthwise from a sheet material (not shown) that is manufactured using a compound of polypropylene and calcium carbonate. In an example, the thickness of the sheet material is determined by successive rollers. Because rollers are used to control thickness, the MFI of the polypropylene / calcium carbonate compound may be substantially lower than that of the MFI required for use a compound adhesives 135, 335. In an example, 4.1 MFI polypropylene resin 3462-US is compounded with approximate 60% by weight of calcium carbonate. The resulting polypropylene / calcium carbonate compound, having an MFI of approximately 2, can be run through successive rollers to reach a desired thickness. Almost any desired strip thickness can be attained. In an example, a sheet of polypropylene / calcium carbonate compound material having thickness of approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) can be cut longitudinally into one or more strip 145, 345, 348, 445, 448.
  • In an example, the calcium carbonate used in manufacturing sheet material which can be cut into strips is non-refined calcium carbonate.
  • Composite Cover Material
  • Returning to Figure 2, an apparatus 200 is shown for forming the composite paint roller cover 250 having a compound backing. A layer of compound adhesive 210 is dispensed by an applicator 205. The layer of compound adhesive 210 dispensed may be dispensed onto roller 220 or directly onto cover material 215. In an example, the layer of compound adhesive 210 is between 254 micrometers (0.010") and 508 micrometers (0.020"). In an example, the compound adhesive 210 is a compound of polypropylene and calcium carbonate having at least 50%, and not more than 66% calcium carbonate by weight. The MFI of polypropylene / calcium carbonate compound may be varied by changing using a polypropylene resin having a higher or lower MFI, as well as by varying the ratio of calcium carbonate. Using polypropylene resin having a higher MFI will cause the polypropylene / calcium carbonate compound to have a higher MFI when using the same ratio of calcium carbonate. Similarly, the MFI of the resulting compound can be lowered by reducing the percentage of calcium carbonate used in the polypropylene / calcium carbonate compound. In view of the foregoing, it will be apparent to one of skill in the art how to the MFI of polypropylene / calcium carbonate compound layer 210 can be varied so as to permit it to be dispensed appropriately by an applicator 205.
  • In an example, the cover material 215 has a pile side and a fabric backing - the fabric backing being porous and having interstitial spaces sufficient to permit penetration of compound adhesive 210. In an example, the compound adhesive 210 has an MFI higher than 2. In an example, the compound adhesive 210 has an MFI between 14 and 105. In an example, an MFI of in or around the mid 70's is desired to permit the compound 210 to properly permeate the fabric backing of the cover material 215. To obtain compound adhesive 210 having an MFI in or around the mid-70's 105 MFI polypropylene resin is compounded with 25% calcium carbonate by weight.
  • In an example, the apparatus comprises an applicator 205 that applies a compound adhesive 210 formed by a twin screw extruder sufficient for compounding calcium carbonate with polypropylene (not shown) from a supply of polypropylene resin in pellet form and a supply of calcium carbonate to produce a compound that includes at least 50% calcium carbonate by weight.
  • Illustrative Paint Rollers
  • Returning to Figure 1, in an example, a strip 145 comprises polypropylene, and has a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the strip 145 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the strip 145 may be of another suitable thickness.
  • In an example, the strip 145 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the strip 145 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The strip 145 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a strip made from polypropylene alone, or than a strip made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight. Because of the higher thermal conductivity using a strip 145 made from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight, it is anticipated that the adhesive 135 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using a strip 145 comprising more than 50% polypropylene.
  • In an example, adhesive 135 comprises polypropylene, and is applied in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the layer of adhesive 135 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the layer of adhesive 135 is another suitable thickness.
  • In an example, the adhesive 135 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the adhesive 135 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The adhesive 135 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than an adhesive made from polypropylene alone, or than an adhesive made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight. Because of the higher thermal conductivity using an adhesive 135 made from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight, it is anticipated that it will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using an adhesive 135 comprising more than 50% polypropylene.
  • In an example, the backing of composite cover 125 comprises polypropylene, and the backing comprising polypropylene is in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the backing layer of the composite cover material 125 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the backing of the composite cover material 125 is another suitable thickness.
  • In an example, the backing of the composite cover material 125 is formed from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the backing of the composite cover material 125 is formed from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The backing of the composite cover material 125 formed from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a backing made from polypropylene alone, or than a backing made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight. Because of the higher thermal conductivity using a composite cover material 125 having a backing formed from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight, it is anticipated that the adhesive 135 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using a composite cover material 125 having a backing formed from a compound of polypropylene and calcium carbonate comprising more than 50% polypropylene.
  • The following table presents illustrative paint rollers that will be used in the discussion below.
    Cover Adhesive Strip
    Example A1 0 / 0% 254 µm (10 mil) / 0% 508 µm (20 mil) / 0%
    Example A2 254 µm (10 mil) / 0% 254 µm (10 mil) / 0% 508 µm (20 mil) / 0%
  • The following table presents illustrative paint rollers that can be formed using the methods disclosed herein. The "Cover" column refers to the cover material 125 used, the "Adhesive" column refers to the adhesive 135 used and the "Strip" column refers to the strip 145 used in the example. For each column, the entry reflects the thickness in micrometers (mil), and the percentage of calcium carbonate (by weight) compounded with polypropylene to form the component. The thickness in micrometers (mil) for the "Cover" column reflects the thickness of the layer 135 used to form the composite cover material 125 - the "Cover" column entries showing a thickness of 0 reflect the use of a cover material rather than a composite cover material.
    Cover Adhesive Strip
    Example B 1 0 / 0% 254 µm (10 mil) / 60% 508 µm (20 mil) / 60%
    Example B2 254 µm (10 mil) / 0% 254 µm (10 mil) / 60% 508 µm (20 mil) / 60%
    Example B3 254 µm (10 mil) / 25% 254 µm (10 mil) / 60% 508 µm (20 mil) / 60%
  • Example A1 and B1, each make paint rollers of the same thickness, however, the characteristics of the paint roller B1 are substantially improved when compared to those of A1. The B1 paint roller feels firmer and is of higher quality than the A1 paint roller. Moreover, the 762 micrometers (30 mil) thick B1 paint roller uses only 40% of the polypropylene used to manufacture the A1 paint roller (excluding any polypropylene in the cover material).
  • Similarly, Example A2 and B2, each make paint rollers of the same thickness, however, the characteristics of the paint roller B2 are substantially improved when compared to those of A2. The B2 paint roller feels firmer and is of higher quality than the A2 paint roller. Moreover, the 1016 micrometers (40 mil) thick B2 paint roller uses only 55% of the polypropylene used to make the A2 paint roller (excluding any polypropylene in the cover material). In fact, the B1 paint roller compares favorably to the A2 paint roller while using only as much as 30% as much polypropylene.
  • Notably the B3 paint roller is the most superior of all of these example rollers, and it uses less than half as much polypropylene as the A2 roller, and just over half as much as the A1 roller.
  • Many other variations are possible. For example, it is not necessary to use both a compound adhesive and a strip formed from compounding polypropylene and calcium carbonate. In addition, it is not necessary to use a composite cover material formed from a compound of polypropylene / calcium carbonate. The use of (i) a compound strip, (ii) compound adhesive or (ii) composite cover material formed from a compound of polypropylene / calcium carbonate, will each produce a stronger roller, with less polypropylene, than the use of same component made from non- compound polypropylene.
  • Returning now to Figure 3, in an example, strips 345, 348 comprises polypropylene, and each have a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, strips 345, 348 are each approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, strips 345, 348 may be of another suitable thickness. It is not necessary that each of the strips 345, 348 are the same thickness.
  • In an example, at least one strip 345, 348 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, at least one strip 345, 348 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. A strip 345, 348 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a strip made from polypropylene alone, or than a strip made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight. Because of the higher thermal conductivity using at least one strip 345, 348 made from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight, it is anticipated that the adhesive 335 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using strips 345, 348 comprising more than 50% polypropylene.
  • In an example, adhesive 335 comprises polypropylene, and is applied in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the layer of adhesive 335 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the layer of adhesive 335 is another suitable thickness.
  • In an example, the adhesive 335 is made from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the adhesive 335 is made from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The adhesive 335 made from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than an adhesive made from polypropylene alone, or than an adhesive made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight. Because of the higher thermal conductivity using an adhesive 335 made from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight, it is anticipated that it will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using an adhesive 335 comprising more than 50% polypropylene.
  • In an example, the backing of cover 325 comprises polypropylene, and the backing comprising polypropylene is in a layer having a thickness of between 254 micrometers (10 mil) and 1016 micrometers (40 mil). In an example, the backing layer of the composite cover material 325 is approximately 254 micrometers (10 mil), 381 micrometers (15 mil), 508 micrometers (20 mil) or 635 micrometers (25 mil) thick. In an example, the backing of the composite cover material 325 is another suitable thickness.
  • In an example, the backing of the composite cover material 325 is formed from a polypropylene / calcium carbonate compound comprising at least 50%, but not more than 66% calcium carbonate by weight. In an example, the backing of the composite cover material 325 is formed from a polypropylene / calcium carbonate compound comprising approximately 60% calcium carbonate by weight. The backing of the composite cover material 325 formed from a polypropylene / calcium carbonate compound comprising at least 50% calcium carbonate by weight, is expected to have higher thermal conductivity than a backing made from polypropylene alone, or than a backing made from a polypropylene / calcium carbonate compound comprising less than 50% calcium carbonate by weight. Because of the higher thermal conductivity using a composite cover material 325 having a backing formed from a compound of polypropylene and calcium carbonate comprising at least 50% calcium carbonate by weight, it is anticipated that the adhesive 335 will set faster, and thus, apparatus 100 will operate at higher overall throughput than it would when using a composite cover material 325 having a backing formed from a compound of polypropylene and calcium carbonate comprising more than 50% polypropylene.
  • The following tables presents illustrative paint rollers that will be used in the discussion below.
    Cover Adhesive Strip 1 Strip 2
    Example C1 0 / 0% 254 µm (10 mil) / 0% 254 µm (10 mil) / 0% 254 µm (10 mil) / 0%
    Example C2 254 µm (10 mil) / 0% 254 µm (10 mil) / 0% 254 µm (10 mil) / 0% 254 µm (10 mil) / 0%
    Example C3 254 µm (10 mil) / 0% 254 µm (10 mil) / 0% 508 µm (20 mil) / 0% 508 µm (20 mil) / 0%
    Example C4 0 / 0% 254 µm (10 mil) / 0% 508 µm (20 mil) / 0% 508 µm (20 mil) / 0%
  • The following table presents illustrative paint rollers that can be formed using the methods disclosed herein. The "Cover" column refers to the cover material 325 used, the "Adhesive" column refers to the adhesive 335 used, the "Strip 1" column refers to the strip 345 used and the "Strip 2" column refers to the strip 348 used in the example. As above, for each column, the entry reflects the thickness in micrometers (mil), and the percentage of calcium carbonate (by weight) compounded with polypropylene to form the component. The thickness in micrometers (mil) for the "Cover" column reflects the thickness of the layer 335 used to form the composite cover material 325 - the "Cover" column entries showing a thickness of 0 reflect the use of a cover material rather than a composite cover material.
    Cover Adhesive Strip 1 Strip 2
    Example D1 0 / 0% 254 µm (10 mil) / 56% 254 µm (10 mil) / 60% 254 µm (10 mil) / 60%
    Example D2 254 µm (10 mil) / 0% 254 µm (10 mil) / 56% 254 µm (10 mil) / 60% 254 µm (10 mil) / 60%
    Example D3 254 µm (10 mil) / 25% 254 µm (10 mil) / 56% 254 µm (10 mil) / 60% 254 µm (10 mil) / 60%
    Example D4 254 µm (10 mil) / 25% 254 µm (10 mil) / 56% 508 µm (20 mil) /60% 508 µm (20 mil) /60%
  • Example C1 and D1, each make paint rollers of the same thickness, however, the characteristics of the paint roller D1 are substantially improved when compared to those of C1. The D1 paint roller feels firmer and is of higher quality than the C1 paint roller. Moreover, the 1016 micrometers (40 mil) thick core of the D1 paint roller uses only 42% of the polypropylene used to manufacture the C1 paint roller (excluding any polypropylene in the cover material).
  • Example D2 forms a paint roller with very good properties and firmness. This roller compares favorably to Example D1 due to its extra 254 micrometers (10 mil) thickness. Moreover, Example D2 compare favorably not only to Example C1, but to Example C2 having a core of the same thickness (1270 micrometers (50 mil)), and even to Example C3, despite Example C3 having a core of 1778 micrometers (70 mil) and using substantially more than twice as much polypropylene. Example D3 makes an even better paint roller, while Example D4 makes an excellent quality paint roller. Notably, while Example D4 is the same core thickness as example C3, it uses only about 46% as much polypropylene.
  • As above, many other variations are possible. For example, it is not necessary to use both a compound adhesive and a strip formed from compounding polypropylene and calcium carbonate. Moreover, it is not necessary to form both strips from a compound adhesive. In addition, it is not necessary to use a composite cover material formed from a compound of polypropylene / calcium carbonate. The use of (i) a compound strip, (ii) compound adhesive or (ii) composite cover material formed from a compound of polypropylene / calcium carbonate, will each produce a stronger roller, with less polypropylene, than the use of same component made from non-compound polypropylene.
  • Further, it has been observed that the two-strip 1524 micrometers (60 mil) core roller of Example C4 provides approximately the same qualities as the single strip, 1016 micrometers (40 mil) core roller of Example A2, while the latter roller uses only about 37% as much polypropylene. Also, notably, the two-strip 1270 micrometers (50 mil) core Example D2 provides a much stronger roller than the two-strip 1524 micrometers (60 mil) core roller made according to Example C4.
  • Returning to Figure 4, in an example, one or both of the strips 445, 448 can be made from a compound of polypropylene and calcium carbonate having at least 50%, but not more than about 66% calcium carbonate by weight. Similarly, in an example, the cover 415 may having a backing made of a compound of polypropylene and calcium carbonate having at least 50% but not more than 66% calcium carbonate by weight. As discussed above, the percentage of calcium carbonate used in the compound forming the strips 448, 445 and the cover 415 backing may be the same, or may differ from one-another.
  • In an example, the strips 445, 448 are made from a compound of polypropylene and calcium carbonate having approximately 60% calcium carbonate, and the cover 415 has a backing made of a compound of 105 MFI polypropylene and non-refined calcium carbonate having approximately 25% calcium carbonate by weight.
  • Returning to Figure 5 Apparatus 500 may be operated according to an example using a preformed core 540 made of a compound of polypropylene and calcium carbonate having at least 50%, but not more than 66% calcium carbonate by weight; and/or using a cover 520 having a backing made of a compound of polypropylene and calcium carbonate having between 5% and 66% calcium carbonate by weight. When more than one component is made of a compound of polypropylene and calcium carbonate, the percentage of calcium carbonate used in the compound forming the core 540 and the cover 520 backing may be the same, or may differ from one-another. In an example, the core 540 is made of a compound of polypropylene and calcium carbonate comprising approximately 60% calcium carbonate by weight, and the cover backing is made of a compound of polypropylene and calcium carbonate comprising approximately 25% calcium carbonate by weight.
  • As discussed above variation in the amount of calcium carbonate are within the scope of the disclosure, and thus, it will be apparent to one of skill in the art that to some degree thermal conductivity can be controlled, or a desired thermal conductivity or range of thermal conductivity can be achieved by varying the percentage of calcium carbonate in one or more of the compounds. It will be apparent to one of skill in the art that to some degree, stiffness can be controlled, or a desired stiffness or range of stiffness can be achieved by varying the percentage of calcium carbonate in these compounds as well.
  • It is possible, in an example, to use a compound of polypropylene and calcium carbonate having between 50% and 60% calcium carbonate by weight in lieu of polypropylene may be used in making paint rollers. In light of this disclosure, other methods for the manufacture of the same will be apparent to persons of skill in the art.
  • Benefits of certain methods disclosed herein include: control of thermal conductivity in the component materials leading to faster throughput and/or faster set times; and control of material characteristics such as stiffness for manufacture of harder, more expensive paint rollers.

Claims (4)

  1. A method of making a laminated paint roller comprising:
    helically winding inner (345) and outer (348) strips comprising polypropylene around a mandrel (340) so as to form a pair of helically wound strips, the strips each having an outer surface;
    advancing the wound strips along the mandrel;
    applying a layer of adhesive (335) comprising polypropylene onto the outer surface of each of the wound strips (345, 348); and
    wrapping a strip of composite cover material (250, 325) about the outer strip (348) and over the layer of adhesive, the composite cover material being formed by the steps of:
    providing a width of porous pile material having a pile side and a fabric underside; advancing the width of pile material with the fabric underside facing up;
    extruding a polypropylene-based material (210) to form a flowing layer;
    applying the smoothly flowing layer as a backing layer having a thickness of 254 micrometers (10 mils) to 508 micrometers (20 mils) on the fabric underside of the advancing width of pile material so that the layer has one side that is in contact with the fabric underside of the advancing material and another side that is not in contact with the advancing pile material, the layer being in molten form when it is applied;
    applying a compressive force (220) to the other side of the layer before the layer hardens and sets, to smooth the other side of the layer of polypropylene, and to urge the layer and the fabric underside of the pile material together, thereby forming a composite material having a smooth or uniformly imprinted non-porous side (225) and a pile side, and wherein the pile is held fast on the composite material;
    cutting (240) the width of composite material into a strip once the backing layer is no longer in molten form, thereby forming a composite cover material (250) having an inner surface comprising a smooth or uniformly imprinted non-porous polypropylene side and a pile side; and
    applying a compressive force (320) from outside of the composite cover material (235) to urge the composite cover material, the layer of adhesive and the inner (345) and outer (348) strips together.
  2. The method of making a laminated paint roller claimed in claim 1, wherein (i) extruding a backing layer, and (ii) applying a backing layer, are performed by a twin screw extruder that receives polypropylene in pellet form from a polypropylene feeder, and receives calcium carbonate from a calcium carbonate feeder.
  3. The method of claim 1, wherein the adhesive is compounded from polypropylene and calcium carbonate, the compound comprising at least 5% but not more than 66% calcium carbonate by weight.
  4. The method of claim 1, wherein at least one of the inner and outer strips comprising polypropylene comprises at least 25% but not more than 66% calcium carbonate by weight.
EP17187310.2A 2009-05-05 2010-05-05 Method for manufacturing a paint roller Active EP3300874B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US12/435,946 US20100282400A1 (en) 2009-05-05 2009-05-05 Methods for manufacturing a paint roller and component parts thereof
US12/687,028 US8142587B2 (en) 2009-05-05 2010-01-13 Methods for manufacturing a paint roller and component parts thereof
EP14183290.7A EP2810720B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller
PCT/US2010/033734 WO2010129676A2 (en) 2009-05-05 2010-05-05 Methods for manufacturing a paint roller and component parts thereof
EP10772768.7A EP2429799B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP14183290.7A Division EP2810720B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller
EP10772768.7A Division EP2429799B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller

Publications (3)

Publication Number Publication Date
EP3300874A2 EP3300874A2 (en) 2018-04-04
EP3300874A3 EP3300874A3 (en) 2018-06-20
EP3300874B1 true EP3300874B1 (en) 2021-02-17

Family

ID=43050847

Family Applications (4)

Application Number Title Priority Date Filing Date
EP10772768.7A Active EP2429799B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller
EP14193729.2A Active EP2851178B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller
EP14183290.7A Active EP2810720B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller
EP17187310.2A Active EP3300874B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller

Family Applications Before (3)

Application Number Title Priority Date Filing Date
EP10772768.7A Active EP2429799B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller
EP14193729.2A Active EP2851178B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller
EP14183290.7A Active EP2810720B1 (en) 2009-05-05 2010-05-05 Method for manufacturing a paint roller

Country Status (16)

Country Link
US (8) US8142587B2 (en)
EP (4) EP2429799B1 (en)
KR (1) KR101792063B1 (en)
CN (2) CN106891542A (en)
BR (1) BRPI1011405A2 (en)
CA (1) CA2761109C (en)
CL (1) CL2011002771A1 (en)
CR (1) CR20110584A (en)
ES (3) ES2639102T3 (en)
HK (3) HK1168322A1 (en)
HU (2) HUE033450T2 (en)
MX (1) MX2011011719A (en)
PL (3) PL2429799T3 (en)
PT (2) PT2810720T (en)
SG (2) SG10201402967UA (en)
WO (1) WO2010129676A2 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITFI20040046A1 (en) * 2004-02-24 2004-05-24 Fabio Perini MACHINE AND METHOD FOR PRODUCING CARDBOARD TUBES
US8142587B2 (en) * 2009-05-05 2012-03-27 Chandra Sekar Methods for manufacturing a paint roller and component parts thereof
CN103178663B (en) * 2013-01-31 2015-05-13 海宁永大电气新材料有限公司 Production device for protective sleeves for motor parts
US10577159B2 (en) 2017-04-07 2020-03-03 Berry Plastics Corporation Drink cup lid
CN111182818B (en) 2017-08-07 2023-07-04 贝瑞全球有限公司 Method and apparatus for thermoforming articles
US10421229B1 (en) * 2019-01-29 2019-09-24 Chandra Sekar Machine and method for paint-roller manufacturing with integrated final cutting online
US9956719B1 (en) * 2017-08-14 2018-05-01 Chandra Sekar System and method for coating paint-roller cover fabric in-line with a manufacturing process
US10596749B2 (en) 2017-08-14 2020-03-24 Chandra Sekar System and method for perforating paint-roller cover fabric
USD907997S1 (en) 2018-08-10 2021-01-19 Berry Global, Inc. Drink cup lid
US10967558B2 (en) * 2019-01-29 2021-04-06 Chandra Sekar Machine and method for paint-roller manufacturing with integrated final cutting online
US11891488B2 (en) 2019-02-06 2024-02-06 Berry Global, Inc. Polypropylene sheets and articles
EP3921154A4 (en) 2019-02-06 2023-01-25 Berry Global, Inc. Process of forming polymeric material
GB2581805B (en) * 2019-02-26 2021-11-03 Ridgway Machines Ltd Method of manufacturing reinforced pipe
USD911168S1 (en) 2019-03-05 2021-02-23 Berry Global, Inc. Drink cup lid
CN110154377B (en) * 2019-06-12 2024-03-08 上海邦临管道工程技术有限公司 Continuous glass fiber composite reinforced pipe winding machine and application method thereof
CN111483889B (en) * 2020-04-22 2021-06-15 南京溧水高新产业股权投资有限公司 Street lamp pole winding protection film and rope made of hemp device
CN112124886B (en) * 2020-11-24 2021-02-26 中材科技(成都)有限公司 Automatic feeding and discharging conveying line for hydrogen cylinder winding and curing
CN112960492B (en) * 2021-04-13 2023-04-28 宁波鑫望包装机械有限公司 Dust-binding paper roll production equipment and production process thereof

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3537946A (en) * 1967-03-30 1970-11-03 Stein Hall & Co Inc Method of combining textile materials and products thereof
US4349400A (en) * 1977-05-10 1982-09-14 Maryland Cup Corporation Method for manufacturing two-piece containers from filled thermoplastic sheet material
ES1002610Y (en) * 1987-06-03 1990-02-16 Melendo Arribas Jose DEVICE TO FACILITATE THE INTERCHANGEABILITY OF THE PAINT ROLLERS
US5398409A (en) * 1989-08-15 1995-03-21 Chandr Sekar Method of making a paint roller
US5572790A (en) * 1989-08-15 1996-11-12 Sekar; Chandra Method of making a paint roller
US5195242A (en) * 1989-08-15 1993-03-23 Chandra Sekar Method of making a paint roller
US5146646A (en) * 1990-02-20 1992-09-15 Minnesota Mining And Manufacturing Company Paint applicator
US5286776A (en) * 1990-11-08 1994-02-15 Kanesi Corporation Reinforced polypropylene resin composition containing glass fiber, mica and copolymer additives
CN1077475A (en) * 1992-04-18 1993-10-20 洪重光 Multipurpose solid glue
CN1076202A (en) * 1993-04-12 1993-09-15 李福春 Plastics additive CaCO 3
US5468207A (en) * 1993-06-14 1995-11-21 Newell Operating Company Method and apparatus of manufacturing a paint roller
JP2860520B2 (en) 1993-12-14 1999-02-24 東京インキ株式会社 Low shrink adhesive composition for interlining
US6231711B1 (en) 1995-01-31 2001-05-15 The Wooster Brush Company Methods and apparatus for making paint roller covers with thermoplastic cores
US5931505A (en) * 1996-01-12 1999-08-03 Industrial Coatings Group, Inc. Casing for binders and books
SE9603918L (en) * 1996-10-28 1997-09-29 Anza Ab Method and apparatus for making woven winding paint rolls
EP0995571B1 (en) * 1998-02-27 2013-11-06 Nissha Printing Co., Ltd. Method of making an in-mold decorated article
US6199279B1 (en) * 1998-07-06 2001-03-13 The Wooster Brush Company Method for making paint roller with thermo plastic core
EP1159474A1 (en) * 1999-01-15 2001-12-05 Valtion Teknillinen Tutkimuskeskus Artificial fur and method for its manufacture
US6159134A (en) * 1999-05-04 2000-12-12 Sekar; Chandra Methods for manufacturing a paint roller with integrated core and cover
US6397425B1 (en) * 1999-08-31 2002-06-04 Gillette Canada Company Polypropylene brush body
WO2001028736A1 (en) * 1999-10-21 2001-04-26 Chandra Sekar Paint roller and method of making
US6379605B1 (en) * 1999-10-22 2002-04-30 Nan Ya Plastics Corporation Process for producing a 3-layer co-extruded biaxial-oriented polypropylene synthetic paper and transparent film for in-mold label
US6324717B1 (en) * 1999-11-29 2001-12-04 Chandra Sekar Paint roller with finished edge and method for making same
US6615490B2 (en) * 2000-01-21 2003-09-09 Newell Operating Company Method of manufacture of paint application
US6503595B1 (en) * 2000-02-22 2003-01-07 Aristech Chemical Company Carpet having syndiotactic polypropylene backing and technique for making same
JP3418369B2 (en) * 2000-06-14 2003-06-23 雅彦 勝山 Coating roller and its manufacturing method
US6544609B1 (en) * 2000-07-12 2003-04-08 Alcoa Closure Systems International, Inc. Stiff and impact resistant compositions containing poly(propylene) or poly(ethylene/propylene) and calcium carbonate for closures
DE10101664A1 (en) * 2001-01-16 2003-08-07 Josef Hefele Methods and devices for the production of flexible fabrics with grid-shaped hot melt adhesive coating
US6539999B2 (en) * 2001-02-19 2003-04-01 Newell Operating Company Apparatus and method for making variable paint roller covers
US6987148B2 (en) * 2001-11-07 2006-01-17 Indian Petrochemicals Corporation Limited High performance polyolefin blends for industrial pallets other articles and a process for the preparation thereof
US6881937B2 (en) * 2002-03-22 2005-04-19 Fort James Corporation Thermoformed food containers with enhanced rigidity
JP2004170845A (en) * 2002-11-22 2004-06-17 Sumitomo Rubber Ind Ltd Conductive rubber roller
US7785510B2 (en) * 2003-06-02 2010-08-31 Certainteed Corporation Process of and apparatus for making a shingle, and shingle made thereby
JP4445239B2 (en) * 2003-10-16 2010-04-07 株式会社クラレ Paint roller
JP2007527460A (en) * 2004-03-05 2007-09-27 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Ethylene copolymer modified oriented polypropylene
US8167782B2 (en) * 2007-02-16 2012-05-01 Linzer Products Corp. Method and apparatus for making a paint roller and product produced thereby
US7736455B2 (en) * 2008-06-26 2010-06-15 Chandra Sekar Methods for manufacturing a paint roller with grooved substrate
US7846283B2 (en) * 2008-06-26 2010-12-07 Chandra Sekar Methods for manufacturing a paint roller with perforated substrate
US7850812B2 (en) * 2009-01-08 2010-12-14 Chandra Sekar Methods for manufacturing a paint roller and component parts thereof
US8142587B2 (en) * 2009-05-05 2012-03-27 Chandra Sekar Methods for manufacturing a paint roller and component parts thereof
US8771451B2 (en) * 2009-01-08 2014-07-08 Chandra Sekar Methods for manufacturing a paint roller and component parts thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
CA2761109A1 (en) 2010-11-11
US9126369B2 (en) 2015-09-08
BRPI1011405A2 (en) 2016-03-15
KR20120027301A (en) 2012-03-21
EP2429799B1 (en) 2014-09-24
KR101792063B1 (en) 2017-11-01
EP2429799A4 (en) 2013-02-27
PL2810720T3 (en) 2017-11-30
SG175418A1 (en) 2011-12-29
US20120145311A1 (en) 2012-06-14
EP2429799A2 (en) 2012-03-21
US9586374B2 (en) 2017-03-07
EP2851178A1 (en) 2015-03-25
HUE033450T2 (en) 2017-12-28
US8142587B2 (en) 2012-03-27
EP3300874A3 (en) 2018-06-20
ES2638869T3 (en) 2017-10-24
SG10201402967UA (en) 2014-09-26
HK1208645A1 (en) 2016-03-11
US20100282401A1 (en) 2010-11-11
US9126370B2 (en) 2015-09-08
US8308884B2 (en) 2012-11-13
PT2851178T (en) 2017-10-02
CR20110584A (en) 2012-02-22
US20120085485A1 (en) 2012-04-12
US20160176139A1 (en) 2016-06-23
CL2011002771A1 (en) 2012-04-20
CA2761109C (en) 2018-01-02
EP3300874A2 (en) 2018-04-04
US20140238584A1 (en) 2014-08-28
HUE033453T2 (en) 2017-12-28
US20140238583A1 (en) 2014-08-28
HK1253379A1 (en) 2019-06-14
HK1168322A1 (en) 2012-12-28
PT2810720T (en) 2017-10-03
CN102740984B (en) 2017-05-17
US20150013886A1 (en) 2015-01-15
ES2520365T3 (en) 2014-11-11
CN106891542A (en) 2017-06-27
WO2010129676A2 (en) 2010-11-11
EP2851178B1 (en) 2017-08-23
US20120085486A1 (en) 2012-04-12
US8486211B2 (en) 2013-07-16
CN102740984A (en) 2012-10-17
EP2810720B1 (en) 2017-08-23
WO2010129676A3 (en) 2012-03-08
PL2429799T3 (en) 2015-03-31
EP2810720A2 (en) 2014-12-10
ES2639102T3 (en) 2017-10-25
EP2810720A3 (en) 2015-02-25
US9266283B2 (en) 2016-02-23
PL2851178T3 (en) 2017-11-30
US8764928B2 (en) 2014-07-01
MX2011011719A (en) 2012-02-29

Similar Documents

Publication Publication Date Title
EP3300874B1 (en) Method for manufacturing a paint roller
US8771451B2 (en) Methods for manufacturing a paint roller and component parts thereof
EP2324989B1 (en) Method for making a laminated paint roller
US8142599B2 (en) Methods for manufacturing a paint roller and component parts thereof
US20100282400A1 (en) Methods for manufacturing a paint roller and component parts thereof
EP2424800B1 (en) Method for manufacturing a laminated paint roller
US20120286448A1 (en) Methods for manufacturing a paint roller and component parts thereof
CA2664974C (en) Methods for manufacturing a paint roller and component parts thereof

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED

AC Divisional application: reference to earlier application

Ref document number: 2810720

Country of ref document: EP

Kind code of ref document: P

Ref document number: 2429799

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

RIC1 Information provided on ipc code assigned before grant

Ipc: B29C 53/60 20060101AFI20180514BHEP

Ipc: B05C 17/02 20060101ALI20180514BHEP

Ipc: B31C 3/00 20060101ALN20180514BHEP

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20181220

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20190220

REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1253379

Country of ref document: HK

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

RIC1 Information provided on ipc code assigned before grant

Ipc: B29C 63/10 20060101ALI20200813BHEP

Ipc: B29D 23/00 20060101ALN20200813BHEP

Ipc: B29C 53/60 20060101AFI20200813BHEP

Ipc: B31C 3/00 20060101ALN20200813BHEP

RIC1 Information provided on ipc code assigned before grant

Ipc: B29C 53/60 20060101AFI20200818BHEP

Ipc: B29D 23/00 20060101ALN20200818BHEP

Ipc: B29C 63/10 20060101ALI20200818BHEP

Ipc: B31C 3/00 20060101ALN20200818BHEP

INTG Intention to grant announced

Effective date: 20200901

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AC Divisional application: reference to earlier application

Ref document number: 2810720

Country of ref document: EP

Kind code of ref document: P

Ref document number: 2429799

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602010066481

Country of ref document: DE

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1360915

Country of ref document: AT

Kind code of ref document: T

Effective date: 20210315

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG9D

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20210217

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210518

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210617

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210517

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210517

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1360915

Country of ref document: AT

Kind code of ref document: T

Effective date: 20210217

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210617

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602010066481

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

26N No opposition filed

Effective date: 20211118

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210531

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210505

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210531

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20210531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210505

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210617

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20220308

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210531

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20220309

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20100505

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230316

Year of fee payment: 14

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602010066481

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20210217

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20231201