EP3237590B1 - Unit dose fabric softener - Google Patents

Unit dose fabric softener Download PDF

Info

Publication number
EP3237590B1
EP3237590B1 EP14824326.4A EP14824326A EP3237590B1 EP 3237590 B1 EP3237590 B1 EP 3237590B1 EP 14824326 A EP14824326 A EP 14824326A EP 3237590 B1 EP3237590 B1 EP 3237590B1
Authority
EP
European Patent Office
Prior art keywords
composition
unit dose
weight
fabric conditioner
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP14824326.4A
Other languages
German (de)
French (fr)
Other versions
EP3237590A1 (en
Inventor
Jr. Charles John Schramm
Katie Truong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=52282999&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP3237590(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of EP3237590A1 publication Critical patent/EP3237590A1/en
Application granted granted Critical
Publication of EP3237590B1 publication Critical patent/EP3237590B1/en
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043—Liquid or thixotropic (gel) compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3738—Alkoxylated silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • Unit dose products provide convenience to consumers to be able to quickly and easily add a desired amount of product to laundry.
  • One such product is fabric conditioner.
  • a problem with encapsulated fragrances is that they are typically supplied in a suspension with more than 50 weight % water. This water creates instability in the water soluble pouch that contains the product.
  • EP 1 431 383 A1 discloses a unit dose fabric treatment product comprising a nonaqueous liquid fabric treatment composition contained in a single compartment watersoluble pouch.
  • WO 2011/149475 A1 discloses a composition comprising an esterquat that is a quaternized reaction product of an alkanol amine and a fatty acid having a ratio of fatty acid to alkanol amine of 1.5 to 1.75, wherein 45 to 75% by weight of the fatty acids are saturated.
  • US 2008/0076698 A1 discloses a fabric softening composition comprising a cationic or non-ionic softening compound, a water dispersible cross-linked cationic polymer, acrylamide, a difunctional vinyl addition monomer cross-linking agent, a non-confined fragrance oil, an effective amount of at least one fabric or skin beneficiating ingredient encapsulated within a first polymer material.
  • US 5,525,245 discloses a clear fabric softener microemulsion composition comprising a combination of diester quaternary ammonium surfactants, diamido ammonium surfactants and selected organic solvents.
  • a unit dose fabric conditioner according to the present invention is defined in claim 1.
  • a method of laundering fabric with the unit dose fabric conditioner according to the present invention is defined in claim 14.
  • ranges are used as shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range. In the event of a conflict in a definition in the present disclosure and that of a cited reference, the present disclosure controls.
  • the cationic softener can be any cationic softener.
  • the cationic softener is an esterquat, tallow esterquat, triolyeyl esterquat, and diolyeyl esterquat.
  • the esterquat is diolyel esterquat.
  • the tallow esterquat is described in WO2011149475 .
  • the esterquats can be represented by the following structure: wherein R 4 represents an aliphatic hydrocarbon group having from 8 to 22 carbon atoms, R 2 and R 3 represent (CH 2 ) s -R 5 where R 5 represents an alkoxy carbonyl group containing from 8 to 22 carbon atoms, benzyl, phenyl, (C 1 -C 4 ) - alkyl substituted phenyl, OH or H; R1 represents (CH 2 ) t R 6 where R 6 represents benzyl, phenyl, (C 1 -C 4 ) - alkyl substituted phenyl, OH or H; q, s, and t, each independently, represent an integer from 1 to 3; and X - is a softener compatible anion.
  • the composition contains encapsulated fragrance.
  • the encapsulated fragrance can be supplied as a suspension containing water.
  • the encapsulated fragrance can be included in the composition in an amount of 1 to 10% by weight of the composition.
  • the water soluble pouch can be any material that is typically used for making a unit dose film. These materials include, but are not limited to polyvinyl alcohol.
  • the thickness of the film that makes the pouch can be any desired thickness. In certain embodiment, the thickness is 25 to 150 microns. The thickness is chosen based on the desired dissolvability of the film.
  • Composition 1 is a unit dose fabric conditioner comprising a fabric conditioner composition contained within a water soluble pouch, wherein the composition is liquid at 25°C and comprises:
  • any of the preceding unit dose fabric conditioners can be used in a laundry process to condition fabrics.
  • the unit dose can be added to the wash cycle, the rinse cycle, or both.
  • Liquid at 25°C refers to the ordinary definition of a liquid in which the material conforms to the shape of the container that it is in.
  • liquid at 25°C refers to a material that is liquid and when added to the composition, the composition has a viscosity of 200 to 1000 or 200 to 800 mPas as measured above.
  • compositions can contain any typical additive, such as coloring agents, pH adjusting agents, preservatives, antifoams, and silicones.
  • compositions were prepared as detailed in the tables below.
  • the compositions were prepared by mixing of the materials.
  • compositions A to X were able to disperse the esterquat and fragrance capsules.
  • the alkoxylated alcohol C 9 -C 11 alkoxylated alcohol with an average of 8EO
  • the dispersing polymer water soluble cross-linked cationic polymer
  • PEG 400 and PEG 600 were tested in place of the polyol. Dispersability was not observed with these PEGs.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Fats And Perfumes (AREA)

Description

    BACKGROUND
  • Unit dose products provide convenience to consumers to be able to quickly and easily add a desired amount of product to laundry. One such product is fabric conditioner. To improve on fabric conditioners, it would be desirable to add encapsulated fragrances that can be delivered during the wash. A problem with encapsulated fragrances is that they are typically supplied in a suspension with more than 50 weight % water. This water creates instability in the water soluble pouch that contains the product. Also, there is a need to disperse fragrance capsules to obtain a more evenly distributed deposition of the fragrance capsules on fabric. Also, there is a need to disperse the fabric conditioner throughout the wash.
    EP 1 431 383 A1 discloses a unit dose fabric treatment product comprising a nonaqueous liquid fabric treatment composition contained in a single compartment watersoluble pouch.
    WO 2011/149475 A1 discloses a composition comprising an esterquat that is a quaternized reaction product of an alkanol amine and a fatty acid having a ratio of fatty acid to alkanol amine of 1.5 to 1.75, wherein 45 to 75% by weight of the fatty acids are saturated.
    US 2008/0076698 A1 discloses a fabric softening composition comprising a cationic or non-ionic softening compound, a water dispersible cross-linked cationic polymer, acrylamide, a difunctional vinyl addition monomer cross-linking agent, a non-confined fragrance oil, an effective amount of at least one fabric or skin beneficiating ingredient encapsulated within a first polymer material.
    US 5,525,245 discloses a clear fabric softener microemulsion composition comprising a combination of diester quaternary ammonium surfactants, diamido ammonium surfactants and selected organic solvents.
    • BRIEF SUMMARY
  • It has been found that a combination of a polyol, alkoxylated alcohol, and dispersing polymer allows for incorporation of encapsulated fragrance slurries into unit dose fabric conditioners to disperse the encapsulated fragrance and fabric conditioner active during laundering.
  • A unit dose fabric conditioner according to the present invention is defined in claim 1.
  • A method of laundering fabric with the unit dose fabric conditioner according to the present invention is defined in claim 14.
  • Further areas of applicability of the present invention will become apparent from the detailed description provided hereinafter. It should be understood that the detailed description and specific examples, while indicating the preferred embodiment of the invention, are intended for purposes of illustration only and are not intended to limit the scope of the invention.
    • DETAI LED DESCRIPTION
  • The following description of the preferred embodiment(s) is merely exemplary in nature and is in no way intended to limit the invention, its application, or uses.
  • As used throughout, ranges are used as shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range. In the event of a conflict in a definition in the present disclosure and that of a cited reference, the present disclosure controls.
  • Unless otherwise specified, all percentages and amounts expressed herein and elsewhere in the specification should be understood to refer to percentages by weight. The amounts given are based on the active weight of the material.
  • The cationic softener can be any cationic softener. In certain embodiments, the cationic softener is an esterquat, tallow esterquat, triolyeyl esterquat, and diolyeyl esterquat. In one embodiment, the esterquat is diolyel esterquat. In one embodiment, the tallow esterquat is described in WO2011149475 .
  • The esterquats can be represented by the following structure:
    Figure imgb0001
     wherein R4 represents an aliphatic hydrocarbon group having from 8 to 22 carbon atoms, R2 and R3 represent (CH2)s-R5 where R5 represents an alkoxy carbonyl group containing from 8 to 22 carbon atoms, benzyl, phenyl, (C1-C4) - alkyl substituted phenyl, OH or H; R1 represents (CH2)t R6 where R6 represents benzyl, phenyl, (C1-C4) - alkyl substituted phenyl, OH or H; q, s, and t, each independently, represent an integer from 1 to 3; and X- is a softener compatible anion.
  • The composition contains encapsulated fragrance. The encapsulated fragrance can be supplied as a suspension containing water. In certain embodiments, the encapsulated fragrance can be included in the composition in an amount of 1 to 10% by weight of the composition.
  • The water soluble pouch can be any material that is typically used for making a unit dose film. These materials include, but are not limited to polyvinyl alcohol. The thickness of the film that makes the pouch can be any desired thickness. In certain embodiment, the thickness is 25 to 150 microns. The thickness is chosen based on the desired dissolvability of the film.
  • Provided is Composition 1 that is a unit dose fabric conditioner comprising a fabric conditioner composition contained within a water soluble pouch, wherein the composition is liquid at 25°C and comprises:
    • a cationic fabric softening active;
    • at least 50% by weight of the composition of a C3-C12 polyol that is liquid at 25°C;
    • a C9-C15 alkoxylated alcohol having an average of 3 to 8 EO per mole and which is liquid at 25°C;
    • a dispersing polymer as defined in claim 1 for dispersing the cationic fabric softening active; and encapsulated fragrance.
      • 1.1 The unit dose fabric conditioner of any preceding Composition, wherein the water soluble pouch comprises polyvinyl alcohol.
      • 1.2 The unit dose fabric conditioner of any preceding Composition, wherein the composition further comprises free fragrance.
      • 1.3 The unit dose fabric conditioner of Composition 1.2, wherein the free fragrance is present in an amount of 0.5 to 7% by weight of the composition.
      • 1.4 The unit dose fabric conditioner of any preceding Composition, wherein the encapsulated fragrance is present in an amount of 1 to 10% by weight of the composition.
      • 1.5 The unit dose fabric conditioner of any preceding Composition, wherein the cationic fabric softening active is at least one active chosen from esterquat, tallow esterquat, triolyeyl esterquat, and diolyeyl esterquat.
      • 1.6 The unit dose fabric conditioner of any preceding Composition, wherein the cationic fabric softener is present in an amount of 10 to 30% by weight of the composition.
      • 1.7 The unit dose fabric conditioner of any preceding Composition, wherein the cationic fabric softener is liquid at 25°C.
      • 1.8 The unit dose fabric conditioner of any preceding Composition, wherein the cationic fabric softener is dioleyl esterquat.
      • 1.9 The unit dose fabric conditioner of any preceding Composition, wherein the polyol is at least one polyol chosen from glycerin, propylene glycol, diglycerol, triglycerol, and quadraglycerol.
      • 1.10 The unit dose fabric conditioner of any preceding Composition, wherein the polyol is present in an amount of 50 to 90% by weight of the composition.
      • 1.11 The unit dose fabric conditioner of any preceding Composition, wherein the polyol is present in an amount of 50 to 80% by weight of the composition.
      • 1.12 The unit dose fabric conditioner of any preceding Composition, wherein the polyol is present in an amount of 60 to 80% by weight of the composition.
      • 1.13 The unit dose fabric conditioner of any preceding Composition, wherein the polyol is present in an amount of 60 to 70% by weight of the composition.
      • 1.14 The unit dose fabric conditioner of any preceding Composition, wherein the alkoxylated alcohol is present in an amount of 2 to 8 weight % by weight of the composition.
      • 1.15 The unit dose fabric conditioner of any preceding Composition, wherein the alkoxylated alcohol is present in an amount of 6 weight % by weight of the composition.
      • 1.16 The unit dose fabric conditioner of any preceding Composition, wherein the alkoxylated alcohol is at least one alkoxylated alcohol chosen from a C9-C11 alkoxylated alcohol with an average of 8 EO, C12-C13 alkoxylated alcohol with an average of 5 EO, and C12-C13 alkoxylated alcohol with an average of 7 EO.
      • 1.17 The unit dose fabric conditioner of any preceding Composition, wherein the alkoxylated alcohol is a C9-C11 alkoxylated alcohol with an average of 8 EO.
      • 1.18 The unit dose fabric conditioner of any preceding Composition, wherein the dispersing polymer is a water soluble cross-linked cationic polymer derived from the polymerization of from 5 to 100 mole percent of cationic vinyl addition monomer, from 0 to 95 mole percent of acrylamide, and from 70 to 300 ppm of a difunctional vinyl addition monomer cross-linking agent. Examples of these types of polymers are available from SNF Floerger.
      • 1.19 The unit dose fabric conditioner of any preceding Composition, wherein the dispersing polymer is present in an amount of 0.2 to 2% by weight of the composition.
      • 1.20 The unit dose fabric conditioner of any preceding Composition, wherein the dispersing polymer is present in an amount of 0.2 to 0.5% by weight of the composition.
      • 1.21 The unit dose fabric conditioner of any preceding Composition, wherein the dispersing polymer is present in an amount of 0.3 to 0.35% by weight of the composition.
      • 1.22 The unit dose fabric conditioner of any preceding Composition, wherein the composition contains water in an amount of 0 to 10 % by weight of the composition.
      • 1.23 The unit dose fabric conditioner of Composition 1.22, wherein the amount of water is 0 to 7% by weight of the composition, and the water soluble pouch has a thickness of 35 to 40 microns.
      • 1.24 The unit dose fabric conditioner of Composition 1.22, wherein the amount of water is 0 to 9% by weight of the composition, and the water soluble pouch has a thickness of 70 to 80 microns.
      • 1.25 The unit dose fabric conditioner of any preceding Composition, wherein the composition further comprises at least one material chosen from PPG-2-myristyl ether propionate, propylene/hexene maleic terminated copolymer with a weight average molecular weight of about 800, and a polyether-alkyl-polymethyl-siloxane copolymer.
      • 1.26 The unit dose fabric conditioner of any preceding Composition, wherein the composition is non-Newtonian and has a viscosity of 200 to 1000 mPas as measured on a Brookfield LVT viscometer with spindle 4 at 12 rpm, optionally 200 to 800 mPas.
      • 1.27 The unit dose fabric conditioner of any of Compositions 1 to 1.25, wherein the composition is Newtonian and has a viscosity of 200 to 1000 mPas as measured on a Brookfield LVT viscometer with spindle 2 at 30 rpm, optionally 200 to 800 mPas.
  • Any of the preceding unit dose fabric conditioners can be used in a laundry process to condition fabrics. The unit dose can be added to the wash cycle, the rinse cycle, or both.
  • Liquid at 25°C refers to the ordinary definition of a liquid in which the material conforms to the shape of the container that it is in. In certain embodiments, liquid at 25°C refers to a material that is liquid and when added to the composition, the composition has a viscosity of 200 to 1000 or 200 to 800 mPas as measured above.
  • The compositions can contain any typical additive, such as coloring agents, pH adjusting agents, preservatives, antifoams, and silicones.
    • EXAM PLES
  • Exemplary compositions were prepared as detailed in the tables below. The compositions were prepared by mixing of the materials.
    Figure imgb0002
    Figure imgb0003
  • Each of compositions A to X was able to disperse the esterquat and fragrance capsules.
  • Without either, the alkoxylated alcohol (C9-C11 alkoxylated alcohol with an average of 8EO) or the dispersing polymer (water soluble cross-linked cationic polymer), dispersability of the esterquat and fragrance capsules was not observed.
  • PEG 400 and PEG 600 were tested in place of the polyol. Dispersability was not observed with these PEGs.

Claims (14)

  1. A unit dose fabric conditioner comprising a fabric conditioner composition contained within a water soluble pouch, wherein the composition is liquid at 25°C and comprises:
    a) a cationic fabric softening active;
    b) at least 50% by weight of the composition of a C3-C12 polyol that is liquid at 25°C;
    c) a C9-C15 alkoxylated alcohol having an average of 3 to 8 EO per mole and which is liquid at 25°C;
    d) a dispersing polymer for dispersing the cationic fabric softening active, wherein the dispersing polymer is a water soluble cross-linked cationic polymer derived from the polymerization of from 5 to 100 mole percent of cationic vinyl addition monomer, from 0 to 95 mole percent of acrylamide, and from 70 to 300 ppm of a difunctional vinyl addition monomer cross-linking agent; and
    e) encapsulated fragrance.
  2. The unit dose fabric conditioner of any preceding claim,
    wherein the water soluble pouch comprises polyvinyl alcohol.
  3. The unit dose fabric conditioner of any preceding claim,
    wherein the composition further comprises free fragrance, and optionally, wherein the free fragrance is present in an amount of 0.5 to 7% by weight of the composition.
  4. The unit dose fabric conditioner of any preceding claim,
    wherein the encapsulated fragrance is present in an amount of 1 to 10% by weight of the composition.
  5. The unit dose fabric conditioner of any preceding claim,
    wherein the cationic fabric softening active is at least one active chosen from esterquat, tallow esterquat, trioleyl esterquat, and dioleyl esterquat, and optionally, wherein the cationic fabric softener is present in an amount of 10 to 30% by weight of the composition.
  6. The unit dose fabric conditioner of any preceding claim,
    wherein the cationic fabric softener is liquid at 25°C, and optionally, wherein the cationic fabric softener is dioleyl esterquat.
  7. The unit dose fabric conditioner of any preceding claim,
    wherein the polyol is at least one polyol chosen from glycerin, propylene glycol, diglycerol, triglycerol, and quadraglycerol.
  8. The unit dose fabric conditioner of any preceding claim,
    wherein the polyol is present in an amount of 50 to 90% by weight of the composition, and optionally, wherein the polyol is present in an amount of 60 to 70% by weight of the composition.
  9. The unit dose fabric conditioner of any preceding claim,
    wherein the alkoxylated alcohol is present in an amount of 2 to 8 weight % by weight of the composition, and optionally, wherein the alkoxylated alcohol is present in an amount of 6 weight % by weight of the composition.
  10. The unit dose fabric conditioner of any preceding claim,
    wherein the alkoxylated alcohol is at least one alkoxylated alcohol chosen from a C9-C11 alkoxylated alcohol with an average of 8 EO, C12-C13 alkoxylated alcohol with an average of 5 EO, and C12-C13 alkoxylated alcohol with an average of 7 EO.
  11. The unit dose fabric conditioner of any preceding claim,
    wherein the dispersing polymer is present in an amount of 0.2 to 2% by weight of the composition, and optionally, wherein the dispersing polymer is present in an amount of 0.3 to 0.35% by weight of the composition.
  12. The unit dose fabric conditioner of any preceding claim,
    wherein the composition contains water in an amount of 0 to 9% by weight of the composition, and the water soluble pouch has a thickness of 70 to 80 microns, and optionally, wherein the amount of water is 0 to 7% by weight of the composition, and the water soluble pouch has a thickness of 35 to 40 microns.
  13. The unit dose fabric conditioner of any preceding claim,
    wherein the composition is non-newtonian and has a viscosity of 200 to 1000 mPas as measured on a Brookfield LVT viscometer with spindle 4 at 12 rpm, , and optionally, wherein the composition is newtonian and has a viscosity of 200 to 800 mPas as measured on a Brookfield LVT viscometer with spindle 2 at 30 rpm.
  14. Method of conditioning fabrics comprising adding the unit dose fabric conditioner of any preceding claim to laundry during at least one of wash and rinse.
EP14824326.4A 2014-12-22 2014-12-22 Unit dose fabric softener Revoked EP3237590B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2014/071828 WO2016105333A1 (en) 2014-12-22 2014-12-22 Unit dose fabric softener

Publications (2)

Publication Number Publication Date
EP3237590A1 EP3237590A1 (en) 2017-11-01
EP3237590B1 true EP3237590B1 (en) 2019-06-12

Family

ID=52282999

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14824326.4A Revoked EP3237590B1 (en) 2014-12-22 2014-12-22 Unit dose fabric softener

Country Status (8)

Country Link
US (1) US10428296B2 (en)
EP (1) EP3237590B1 (en)
CN (1) CN107109300B (en)
AU (1) AU2014414847B2 (en)
BR (1) BR112017012634B1 (en)
CA (1) CA2971571A1 (en)
MX (1) MX2017007854A (en)
WO (1) WO2016105333A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106833918B (en) * 2017-01-05 2020-08-04 广东优凯科技有限公司 Quantitative fabric softening detergent
CN111073770A (en) * 2020-01-09 2020-04-28 广州市加茜亚化妆品有限公司 Washing gel bead containing cationic surfactant and preparation method thereof
WO2022100990A1 (en) * 2020-11-11 2022-05-19 Unilever Ip Holdings B.V. Concentrated non-aqueous fabric conditioners
US11981881B2 (en) * 2021-04-15 2024-05-14 Henkel Ag & Co. Kgaa Transfer of encapsulated fragrance to fabrics in dryer cycle by means of wool ball

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002699A1 (en) 2001-06-27 2003-01-09 Colgate-Palmolive Company Fabric care composition comprising fabric or skin beneficiating ingredient
EP1431383A1 (en) 2002-12-19 2004-06-23 The Procter & Gamble Company Single compartment unit dose fabric treatment product comprising pouched compositions with cationic fabric softener actives
US20050037944A1 (en) 2002-11-01 2005-02-17 Colgate-Palmolive Company Aqueous composition comprising oligomeric esterquats
WO2005073358A1 (en) 2004-01-27 2005-08-11 Colgate-Palmolive Company Aqueous composition comprising oligomeric esterquats
US20060252669A1 (en) 2005-05-06 2006-11-09 Marija Heibel Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient
EP1656440B1 (en) 2003-08-13 2008-01-23 Firmenich Sa Packaged product
US20090320212A1 (en) 2008-06-26 2009-12-31 Jodi Lee Brown Liquid Laundry Treatment Composition Comprising An Asymmetric Di-Hydrocarbyl Quaternary Ammonium Compound
US20110186467A1 (en) 2010-01-29 2011-08-04 Monosol, Llc Water-soluble film having improved dissolution and stress properties, and packets made therefrom

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001081521A2 (en) * 2000-04-26 2001-11-01 Colgate-Palmolive Company Spherical compacted unit dose softener
US6258767B1 (en) 2000-04-26 2001-07-10 Colgate-Palmolive Co. Spherical compacted unit dose softener
US20030104969A1 (en) 2000-05-11 2003-06-05 Caswell Debra Sue Laundry system having unitized dosing
WO2002000001A2 (en) 2000-06-30 2002-01-03 Ingenium Pharmaceuticals Ag HUMAN G PROTEIN-COUPLED RECEPTOR IGPcR20, AND USES THEREOF
US6864223B2 (en) 2000-12-27 2005-03-08 Colgate-Palmolive Company Thickened fabric conditioners
KR100437470B1 (en) * 2001-01-31 2004-06-23 삼성전자주식회사 Semiconductor device having a flash memory cell and fabrication method thereof
US6492315B1 (en) 2002-07-31 2002-12-10 Colgate-Palmolive Company Unit dose nonaqueous liquid softener disposed in water soluble container
US7304026B2 (en) * 2004-04-15 2007-12-04 Colgate-Palmolive Company Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient
US7674758B2 (en) 2004-10-22 2010-03-09 The Procter & Gamble Company Fabric softening compositions comprising free fatty acid
JP2013522273A (en) * 2010-03-16 2013-06-13 ジヤンセン・フアーマシユーチカルズ・インコーポレーテツド Methods and intermediates for the preparation of macrocyclic protease inhibitors of HCV
US8865640B2 (en) 2010-05-28 2014-10-21 Colgate-Palmolive Company Fatty acid chain saturation in alkanol amine based esterquat
EP2646532A1 (en) * 2010-12-03 2013-10-09 Unilever PLC Fabric conditioners
JP2017529461A (en) * 2014-07-23 2017-10-05 ザ プロクター アンド ギャンブル カンパニー Treatment composition

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002699A1 (en) 2001-06-27 2003-01-09 Colgate-Palmolive Company Fabric care composition comprising fabric or skin beneficiating ingredient
US20050037944A1 (en) 2002-11-01 2005-02-17 Colgate-Palmolive Company Aqueous composition comprising oligomeric esterquats
EP1431383A1 (en) 2002-12-19 2004-06-23 The Procter & Gamble Company Single compartment unit dose fabric treatment product comprising pouched compositions with cationic fabric softener actives
EP1656440B1 (en) 2003-08-13 2008-01-23 Firmenich Sa Packaged product
WO2005073358A1 (en) 2004-01-27 2005-08-11 Colgate-Palmolive Company Aqueous composition comprising oligomeric esterquats
US20060252669A1 (en) 2005-05-06 2006-11-09 Marija Heibel Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient
US20090320212A1 (en) 2008-06-26 2009-12-31 Jodi Lee Brown Liquid Laundry Treatment Composition Comprising An Asymmetric Di-Hydrocarbyl Quaternary Ammonium Compound
US20110186467A1 (en) 2010-01-29 2011-08-04 Monosol, Llc Water-soluble film having improved dissolution and stress properties, and packets made therefrom

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SHILPI MISHRA ET AL.: "Ester Quats : The Novel Class of cationic fabric softeners", JOURNAL OF OLEO SCIENCE , J. OLEO SCI., vol. 56, no. 6, 2007, pages 269 - 276, XP002526224

Also Published As

Publication number Publication date
US20170342347A1 (en) 2017-11-30
EP3237590A1 (en) 2017-11-01
CN107109300B (en) 2020-04-17
CN107109300A (en) 2017-08-29
WO2016105333A1 (en) 2016-06-30
BR112017012634A2 (en) 2018-04-10
AU2014414847B2 (en) 2018-02-01
CA2971571A1 (en) 2016-06-30
AU2014414847A1 (en) 2017-06-08
US10428296B2 (en) 2019-10-01
BR112017012634B1 (en) 2021-09-28
MX2017007854A (en) 2017-09-19

Similar Documents

Publication Publication Date Title
EP2931868B1 (en) Fabric conditioning composition
EP2638139B1 (en) Fabric conditioners containing soil releasing polymer
JP7024082B2 (en) Fabric softener composition with improved viscosity stability
EP3237590B1 (en) Unit dose fabric softener
AU2012397240B2 (en) Fabric conditioner containing an amine functional silicone
NO20110720L (en) Thickened plastic softener mixture
AU2011375735B2 (en) Fabric wrinkle reduction composition
EP2751247B1 (en) Method for providing fast dry to fabric
CN104169410A (en) Fabric softener compositions
US20160024426A1 (en) Fabric and/or home care compositions
CN111448301A (en) Transparent fabric care compositions
US10570354B2 (en) Fabric softener active compositions
EP3383987B1 (en) Fabric softening compositions
CN101379177B (en) Fabric conditioning compositions
EP2931857B1 (en) Esterquat composition having high triesterquat content
EP3390602B1 (en) Fabric softener active compositions
EP2751246B1 (en) Method for ease of ironing
EP3418353B1 (en) Fabric softener active compositions
JP6049193B2 (en) Textile softener
EP3418354B1 (en) Fabric softener active compositions

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20170607

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20180604

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20190103

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1142555

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190615

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602014048340

Country of ref document: DE

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20190612

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190912

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190913

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190912

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1142555

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190612

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191014

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191012

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20191226

Year of fee payment: 6

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602014048340

Country of ref document: DE

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

26 Opposition filed

Opponent name: UNILEVER PLC

Effective date: 20200311

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

26 Opposition filed

Opponent name: HENKEL AG & CO. KGAA

Effective date: 20200312

RDAF Communication despatched that patent is revoked

Free format text: ORIGINAL CODE: EPIDOSNREV1

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20200102

Year of fee payment: 6

Ref country code: DE

Payment date: 20191231

Year of fee payment: 6

REG Reference to a national code

Ref country code: DE

Ref legal event code: R064

Ref document number: 602014048340

Country of ref document: DE

Ref country code: DE

Ref legal event code: R103

Ref document number: 602014048340

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200224

PG2D Information on lapse in contracting state deleted

Ref country code: IS

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20191231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

REG Reference to a national code

Ref country code: FI

Ref legal event code: MGE

27W Patent revoked

Effective date: 20200503

GBPR Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state

Effective date: 20200503

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191222

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191231

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191231

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20141222

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190612

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191222