EP3187635A1 - Weicher vliesstoff - Google Patents

Weicher vliesstoff Download PDF

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Publication number
EP3187635A1
EP3187635A1 EP15003696.0A EP15003696A EP3187635A1 EP 3187635 A1 EP3187635 A1 EP 3187635A1 EP 15003696 A EP15003696 A EP 15003696A EP 3187635 A1 EP3187635 A1 EP 3187635A1
Authority
EP
European Patent Office
Prior art keywords
nonwoven
nonwoven web
nonwoven fabric
web according
embossed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15003696.0A
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English (en)
French (fr)
Inventor
Mehmet Fatih Erguney
Kemaloglu Sebnem Dogan
Eylem CANBOLAT
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hayat Kimya Sanayi AS
Original Assignee
Hayat Kimya Sanayi AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hayat Kimya Sanayi AS filed Critical Hayat Kimya Sanayi AS
Priority to EP15003696.0A priority Critical patent/EP3187635A1/de
Priority to PCT/TR2016/050564 priority patent/WO2017131597A1/en
Publication of EP3187635A1 publication Critical patent/EP3187635A1/de
Withdrawn legal-status Critical Current

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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00Making patterns or designs on fabrics
    • D06C23/04Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping

Definitions

  • the present invention relates to a nonwoven fabric (2) of improved softness which is provided with an embossed portion (14) and a non-embossed portion (16).
  • the embossed portion (14) comprising an embossed pattern of geometric structures (4) formed as unit patterns of circularly shaped geometric structures, each formed by unit shaped emboss structures are having round edges and uniform dimensions. Said geometric structures of circularly shaped forms are intersecting with each other at the non-embossed intersection points (20) and unit shaped emboss structures have uniform dimensions.
  • Nonwoven fabrics are one of the oldest and simplest textile fabrics. Nonwoven fabrics can be produced by a variety of known processes other than weaving or knitting.
  • Nonwoven products produced by known techniques are used in various applications such as; disposable and medical applications, hygiene products, diapers, incontinence pads, feminine hygiene articles or nappies.
  • the nonwoven fabric properties depend on following particulars to a great extent,
  • the emboss patterns mainly effect the properties of the produced nonwoven fabric such as, softness, strength, elongation or pilling properties.
  • Various emboss patterns are applied on nonwoven webs to improve these kinds of properties.
  • Fabric properties of nonwovens range from crisp to that soft touch to harsh, impossible to tear to extremely weak.
  • EP2479331 discloses a method of using high crystalline polypropylene mixed with low crystalline polypropylene as raw material with reduced fiber denier to obtain enhanced softness of spun bond nonwoven fabrics. But using reduced denier can cause problems. For example; increased hydrophobicity of the web can be a result of reduced denier and this may cause problem with regard to used areas of nonwoven fabrics such as top sheet. This application does not express the effect of embossing structure on softness of nonwoven fabric which is a cost saving application to obtain soft surfaces.
  • US4333979 is related to light weight nonwoven webs, that have embossed patterns composed of fused bond areas covering a specific range of web surface with specified frequency of bond areas and web thickness.
  • the pattern that used in this invention is shown in FIG. 5 .
  • This approach does not provide a solution to pilling of nonwoven surface. Additionally, this approach doesn't have the desired strength and robustness of the fabric which leads to deformations; sometimes of irreversible nature.
  • EP2554731 discloses a nonwoven fabric having embossed and non-embossed portions that defines the structure of emboss line patterns. It limits the distance of emboss lines and non-embossed portion.
  • the shape of the emboss pattern improved in this invention is related with angle shaped structures as shown in FIG. 6 . It expresses the softness effect of rhombus shaped emboss pattern but relates to the problems of lower strength of the nonwoven and lack of shape preservation.
  • the present invention overcomes above mentioned problems.
  • mechanically and physically improved nonwoven fabrics are produced.
  • Nonwoven fabrics that have softer surfaces and improved resistance to pilling are obtained without losing the strength of the fabric.
  • less weight of fiber is used that is formed by using polymer which makes the present application cost effective.
  • the present invention provides a nonwoven fabric (2) formed from continuous thermoplastic filaments comprising polymer based master batch. Furthermore an embossed pattern of adjacent closed geometric structures of circularly shaped forms (4) is providing softness and bulk while retaining strength and improving pilling resistance.
  • the materials of the invention can be used for disposable products such as diapers, sanitary napkins or any kinds of hygiene products.
  • the present invention relates to a nonwoven fabric comprising an embossed portion and a non-embossed portion. There is provided a nonwoven fabric with improved softness and pilling resistance by using known technologies.
  • Total process includes;
  • Nonwoven fabrics typified by spun bond or melt blown nonwoven fabrics are usually partially thermo bonded via an embossing roll in order to prevent the falling-off of fibers which form the nonwoven fabric and by this way to improve the strength of the fabric.
  • spun bonded or melt blown webs are bonded by thermal bonding with application of hot calender.
  • Emboss roll is used as hot calender which has specific design pattern to obtain embossed patterns on nonwoven web. By the way, strong nonwoven fabric is obtained.
  • an improved embossing design is applied on nonwoven fabric (2).
  • Said embossing design pattern is concerning geometric structures of circularly shaped forms (4).
  • the nonwoven fabric (2) having emboss structures of being partially thermo bonded non-continuous lines gives excellent softness to a nonwoven fabric comparing to having an emboss pattern formed nonwoven by a continuous emboss line.
  • Emboss pattern that is formed by non-continuous emboss lines as dotted emboss lines (8) are round shaped and superior in softness to a nonwoven fabric having an emboss pattern formed as angled such as triangle, square, rhombic or rectangular.
  • polyethylene coating can be applied on polypropylene webs to obtain improved softness but it causes pilling and lack of strength. So high weight fibers are used to achieve targeted strength.
  • Nonwoven fabrics which use polypropylene as fiber former prevents pilling of fibers comparing to polyethylene coated fibers.
  • thermo bonded polypropylene fiber having specified bonding areas gives an excellent strength to nonwoven fabric that is equivalent or higher as conventional nonwoven fabrics. Besides the weight of the fiber used is reduced as an important economical factor.
  • the present invention relates to a nonwoven fabric (2) comprising an embossed portion (14) and a non-embossed portion (16).
  • the present invention provides improvements in continuous fibers bonded thermoplastic webs, concerning specific embossed patterns.
  • nonwoven fabric states that in the present invention, fibers are held together by a process of bonding to form a nonwoven fabric.
  • the term of fiber is referring to the structure that is used to form nonwoven fabric in the present invention.
  • fabric is referring to web of fibers that are finished by embossing with bonding techniques such as hot calendaring, in the present invention.
  • engraving depth is referring to the depth of the pin, which goes inside the web by embossing to form the embossed portion, in the present invention.
  • the nonwoven fabric properties depend on different criteria such as; type of fiber that is used as raw material, the technology used to arrange the fibers, bonding processes that allow holding fibers together, emboss structure of pattern that applied on nonwoven web structure by the known techniques.
  • Non-limiting examples of polymer materials suitable for forming nonwoven fiber such as; rayon, nylon, wool or cotton can be used as natural fabrics and polyesters or acrylics as synthetic fibers.
  • synthetic fibers such as polypropylene, polyethylene, polyester, or polyurethane are used for cost consideration, ease of processing, and for new and more exacting applications.
  • Nonwoven webs can be produced by different methods of production such as; wet bonded, dry bonded, filament formation spun bonded, or melt blown techniques. Using one method or combination of different methods are also possible in production of multi-layer nonwoven webs such as; SSS, SMS, SMMS or SSMS. (S: Spun bond, M: Melt blown)
  • Nonwoven fibers that are produced by different known methods can be bonded by using different techniques of bonding process and/or bonding agents for getting fibers together to avoid falling off the fibers.
  • Non-limiting examples can be applied on bonding of web some of which are; mechanical bonding, chemical bonding or thermal bonding.
  • the most preferred bonding technique is thermal bonding as applying heat and pressure by using hot calender such as; using decorative emboss roll for area bonding, point bonding or embossing.
  • Especially continuous filament webs are bonded by thermal bonding using hot calendering emboss roll.
  • Embossing nonwoven web structure is one of the critical applications to enhance the mechanical performance of nonwoven fabric.
  • Embossing process is the final step in nonwoven fabric production process since it enables to produce a product which is soft, aesthetically decorated and high in bulk. Depending on the embossed bonding area, and emboss structure, physical and mechanical properties of the nonwoven fabrics are changed.
  • spun bond process is widely used to produce nonwoven fabrics.
  • Typical spun bond process components are a polymer feed, an extruder, a quenching system, a drawing and deposition system, a web formation, a bonding and a winding system.
  • spun bonded production requires the steps;
  • a melt solution of a fiber forming polymer or a mixture of polymers is extruded through a system providing spinnerets under a high velocity current of air. Said formed fibers are deposited on to a conveyor belt to form a web. The belt than carries the web to a bonding stage where consolidation of web occurs to form nonwoven fabric.
  • Spun bonded fabrics tend to have low bulk and high strength that allows their use in many industrial applications.
  • the nonwoven fabrics of the present invention have strong webs, low elongation and filament diameter in the range of 1-3 deniers and more specifically 1,5-2 denier. Small denier is preferred because, homogen distribution of filaments are required to form web structures which is preferred to be used as top sheet or other water and air pervious layers of hygiene articles.
  • melt blown process is one of the widely used processes to produce nonwoven fabrics in which the production steps are quite similar to spun bonded webs.
  • extruded polymers pass through the holes in a spinneret into a high velocity current of air.
  • melt blown method from spunbond method is an increased force of air current used which breaks the filaments rather than just drawing them to produce fibers of varying lengths.
  • Melt blown fibers have smaller diameters.
  • the fiber size is influenced by, process air volume, throughput, temperature, number of holes of spinneret and type of polymer resin. By applying higher process air temperature then melting temperature of the used polymer endless filaments can be obtained by melt blown process.
  • Melt blown fabrics have, filament diameter in the range of 1-3 denier, more specifically 1-1,5 denier. Melt blown filament denier is smaller than others which allow producing hydrophobic such as liquid and air impervious web structure. Nonwoven fabrics produced by this technique are preferably used as back sheet or as cuffs of diapers or hygiene articles.
  • Thermal bonding in which the fibers bond together when heated under pressure, may require a bonding agent.
  • melt blown method comprises the steps;
  • Bicomponent multilayer fibers can be used to produce a bonded fabric with one of the components being thermoplastic to facilitate heat bonding and the other component having the property that will enhance the quality of final fabric area density in the process is controlled by the speed of conveyor belt.
  • the created product is relatively stiff and dense which is not desired to be used in hygiene articles. There is a need to have softer products which are strong enough.
  • Nonwoven products produced by using spun bond or melt blown processes are used in various applications.
  • Nonwoven products are widely used in medical, hygiene and technical fields such as; medical applications, masks, hygienic products, diapers, incontinence pads, feminine hygiene articles or nappies, bedding, filtration or clothing.
  • a fiber which forms the nonwoven fabric (2) is selected from natural or synthetic fibers; specifically cotton as natural fiber and thermoplastic polymers as synthetic fibers are preferred as raw material, more specifically polypropylene based polymer mixture having 25 to 27 g/10 min melt flow index (MFI) at 230 °C, is selected for the production of nonwoven fabric in the present invention.
  • MFI melt flow index
  • the polymer can be used singly or in combination of one or more species. It can include an antistatic agent, flame retardant, synthetic oil, a coloring inhibitor, a lubricant, a dye, a softening agent, a plasticizer or a pigment.
  • any known technology is applied to form nonwoven fibers, such as wet bonded, dry bonded, spun bonded or melt blown techniques.
  • more specifically spun bond or melt blown technology is applied to obtain desired fibers.
  • the present invention is specifically including a multi-layer nonwoven fabric, consisting of at least three layers which are stacked together with known techniques, wherein each of two outer nonwoven fiber layers of multi-layer nonwoven fabric are formed of a spun bond nonwoven fibers and one middle layer can be formed of a melt blown nonwoven fiber or spun bonded fiber.
  • a multi-layer nonwoven fabric consisting of at least three layers which are stacked together with known techniques, wherein each of two outer nonwoven fiber layers of multi-layer nonwoven fabric are formed of a spun bond nonwoven fibers and one middle layer can be formed of a melt blown nonwoven fiber or spun bonded fiber.
  • one of the preferred multilayer nonwoven is SSS formed nonwoven fabric.
  • spun bond nonwoven fibers having the diameter in the range of 1-3 denier are obtained by adjusting the line speed in the range of 700 to 750 m/min.
  • the line speed is more than 750 m/min low weighted webs are obtained that can be useless in preferred usage are, and when the speed is less than 700 m/min high weighted webs are obtained which is not cost effective.
  • the line speed is adjusted to 720 m/min more specifically, that allows obtaining lighter web structures having improved properties.
  • nonwoven fibers formed by known methods can be bonded with known methods of thermal bonding, mechanical or chemical bonding.
  • fibers are more specifically thermal bonded by adjusting the temperature and pressure during embossing.
  • the temperature of emboss roll is set in the range of 130-175 °C and more preferably it is adjusted to 140 °C and the pressure applied by emboss roll is set in the range of 50-110 N/mm and more preferably it is adjusted to 90 N/mm.
  • the nonwoven fabric is formed by aforementioned emboss roll conditions
  • embossing temperature is higher than 175 °C
  • formed fibers are fused together and it is impossible to separate them.
  • the applied embossing pressure is higher than 110 N/mm formed web structures are deformed in emboss points as such that they cannot be used efficiently.
  • the engraving depth of the pins of emboss roll can be in the range of 0,3 to 0,6 mm.
  • the web can be deformed and have unwanted holes on it.
  • a nonwoven fabric have embossed (14) and non-embossed portions (16) that form bonding and nonbonding areas.
  • the bonding area is in the range of 12-18%. Higher bonding area than 18 % cause stiffness and low bonding area than 12 % decreases the strength of the nonwoven layer. The specific range enhances the softness of the surface without losing the fabrics strength and by improving the pilling resistance of the fabric. The most preferred bonding area in the present invention is 14 %.
  • a nonwoven fabric (2) having an embossed portion of geometric structure of circularly shaped forms (4) is obtained wherein the forms can have round, oblong or polygonal shapes.
  • more specifically round shaped embossed portion which has the diameter in the range of 12-16 mm is preferred because of enhancing the softness and pilling resistance of nonwoven fabric with excellent effect in strength.
  • a nonwoven fabric having embossed structures which can be in the range of 10-50 figures/cm 2 , preferably 15-30 figures/cm 2 and more preferably 24 figures/cm 2 .
  • geometric structure of circularly shaped formed embossed pattern (4) is formed by dotted embossed lines (8) having round shape edges.
  • the dotted emboss lines (8) have more specifically oblong shape within the range of 0,5-2 mm length and in the range of 0,1-1 mm width dimensions, which enhance softness of nonwoven fabric and provide an excellent feel to the touch.
  • nonwoven fabric in the present invention have embossed pattern of circularly shaped forms (4) intersecting with each other at least four intersection points (20) wherein the intersection points (20) are not embossed.
  • the nonwoven fabric (2) have a circularly shaped embossed pattern (4) wherein the diameter of circularly shaped form (6) is 15 mm.
  • the nonwoven fabric (2) have embossed (14) and non-embossed portions (16), wherein the embossed portions are formed by dotted emboss lines (8) by oblong shaped emboss structures (18); having 1,2 mm length of emboss line (10) and 0, 55 mm width of emboss line (12).
  • the nonwoven fabric is having intersection points (20) of embossed patterns, wherein the intersection points (20) are not embossed.
  • Example 1 Process for preparing nonwoven fabric referring to the pattern shown as FIG. 1
  • Nonwoven fabric having embossed pattern of circularly shaped form (4) as shown in FIG. 1 is prepared by the following steps;
  • the product prepared as Example 1 has specific properties as shown at Table 1.
  • Example 2 Process for preparing nonwoven fabric referring to pattern as shown at FIG. 3
  • Nonwoven fabric having embossed pattern structure as shown in FIG 3 is prepared by repeating the same procedure of Example 1.
  • the obtained nonwoven web is formed by SSS process that is having 11,2 g/m 2 fabric weight.
  • the product has specific properties as shown at Table 1.
  • Example 3 Process for preparing nonwoven fabric referring to the pattern shown as FIG. 4
  • Nonwoven fabric having embossed pattern structure as shown in FIG 4 is prepared by repeating the same procedure of Example 1.
  • the obtained nonwoven web is formed by SSS process that is having 11,8 g/m 2 fabric weight.
  • the product has specific properties as shown at Table 1.
  • Tissue Softness Analyzer used as softness measurement equipment.
  • TSA is generally used for the measurements of paper softness.
  • a new method is applied to observe the softness of nonwoven fabric by using Emtec Tissue Softness Analyzer.
  • Nonwoven softness analysis is performed by using TSA as following;
  • TS7 surface softness
  • TS750 bulk softness
  • HF overall softness
  • Example 1 Comparing the results of example 1 with the results of example 2 and 3, it can be seen that the best softness result is observed in Example 1 in which FIG. 1 is used as embossed pattern.
  • example 1 When the results of example 1 are compared with example 2 having emboss pattern of FIG. 3 and example 3 having emboss pattern of FIG. 4 , which are produced by using the same method of example 1, it can be seen that the overall softness of example 1 (102, 1) is higher than the results of example 2 (101, 7) and example 3 (101, 2). It shows that, the fabric of example 1 having embossed structure of FIG. 1 is softer than the fabric of example 2 and 3 as comparing examples which are having FIG. 3 and 4 .
  • the softness results of hand feel observations are also supporting TSA softness test results.
  • example 1 has very good softness which is pointed as 4, but example 2 and 3 have recognizable feeling of softness which is pointed as 3.
  • Martindale pilling test equipment is used to measure the pilling resistance of nonwoven samples.
  • the equipment is calibrated under ISO12947 standard.
  • the equipment has two parts of standard felts that are upper and lower felts. Measurement conditions are followed by using ISO139 standards. According to standards the place that is used to measure the pilling resistance of the samples is set at 20( ⁇ 2)°C and %65( ⁇ 2) humidity.
  • the test is followed under TS EN ISO 12945 standards.
  • the surface pilling is graded on the following criteria
  • Example 1 has superior pilling resistance properties when compared with other examples.
  • example 1 product By application of pilling process on the surface of example 1 product, no pilling is observed.
  • example 2 product which has the emboss pattern of FIG. 3 it is seen that the fibers are totally turned off.
  • Example 1 product is compared with example 3 product and it is observed that, the pilling resistance of example 1 is better than example 3 again.
  • Example 3 product has limited pilling resistance than example 1.
  • Tensile measurement test is applied by using Zwick strength equipment to evaluate the strength of nonwoven samples.
  • Tensile measurements at maximum force (N/5 cm) are measured with test stripe having 50mm x 250 mm dimensions, 100 mm clamp distance and 100 mm/min testing speed. The results are shown as average values of four single measurements.
  • Example 1 When the results of Example 1 are compared with other examples, it can be said that a small increase of strength which is not very effective on mechanical properties of nonwoven fabric that used in industrial applications.
  • Example 1 has nearly equivalent values to other examples.
  • MD tensile strength of example 1 is 26 N/5cm and other example's results are nearly same as example 1.
  • CD tensile strength is same as MD tensile strength values.
  • Example 1 has nearly equivalent values to other examples.
  • CD tensile strength of example 1 is 12 N/5cm and other example's results are nearly same as Example 1.
  • the polypropylene spun bonded nonwoven fabric having light weight is exhibiting excellent feeling to the touch and high softness. Additionally it is observed that the fabric shows the best resistance to pilling.
  • the nonwoven fabric as shown in FIG. 1 is particularly employed as a material for hygiene products such as diapers, femcare products or nappies as a part of top sheet, back sheet, panels, cuff, waist parts or ears of baby diapers, adult diapers, incontinence diapers, pant like diapers or feminine hygiene article ears.
  • example 1 gives the best results of nonwoven fabric. According to the test results, example 1 has superior properties and it is chosen as the product.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Nonwoven Fabrics (AREA)
EP15003696.0A 2015-12-30 2015-12-30 Weicher vliesstoff Withdrawn EP3187635A1 (de)

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Application Number Priority Date Filing Date Title
EP15003696.0A EP3187635A1 (de) 2015-12-30 2015-12-30 Weicher vliesstoff
PCT/TR2016/050564 WO2017131597A1 (en) 2015-12-30 2016-12-29 Soft nonwoven fabric

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EP15003696.0A EP3187635A1 (de) 2015-12-30 2015-12-30 Weicher vliesstoff

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DE102018128125A1 (de) * 2018-11-09 2020-05-14 Anne-Marie Henkys Fasermatte zur Entfettung von Objekten, Verwendung einer Fasermatte und Textilie aufweisend eine Fasermatte
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WO2023242399A1 (de) * 2022-06-17 2023-12-21 Reifenhäuser GmbH & Co. KG Maschinenfabrik Vliesstoff und vorrichtung zur herstellung eines vliesstoffes

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