EP3178337A1 - Schutzhandschuh mit innenhandschuhlebensdaueranzeige - Google Patents
Schutzhandschuh mit innenhandschuhlebensdaueranzeige Download PDFInfo
- Publication number
- EP3178337A1 EP3178337A1 EP15198547.0A EP15198547A EP3178337A1 EP 3178337 A1 EP3178337 A1 EP 3178337A1 EP 15198547 A EP15198547 A EP 15198547A EP 3178337 A1 EP3178337 A1 EP 3178337A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- glove
- indicator
- protective
- layer
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000001681 protective effect Effects 0.000 title claims abstract description 99
- 239000010410 layer Substances 0.000 claims abstract description 78
- 239000011241 protective layer Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 8
- 230000000149 penetrating effect Effects 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 38
- 230000008859 change Effects 0.000 claims description 22
- UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 claims description 21
- 238000003618 dip coating Methods 0.000 claims description 16
- 239000004816 latex Substances 0.000 claims description 14
- 229920000126 latex Polymers 0.000 claims description 14
- 239000007793 ph indicator Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 238000010017 direct printing Methods 0.000 description 6
- 238000007669 thermal treatment Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000013043 chemical agent Substances 0.000 description 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 210000004247 hand Anatomy 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- 241000147041 Guaiacum officinale Species 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 239000003251 chemically resistant material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 210000003811 finger Anatomy 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229940091561 guaiac Drugs 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
- 229940012189 methyl orange Drugs 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000001558 permutation test Methods 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0024—Gloves with accessories
- A41D19/0031—Whistles or other warning devices
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0024—Gloves with accessories
- A41D19/0027—Measuring instruments, e.g. watch, thermometer
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0006—Gloves made of several layers of material
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/001—Linings
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
- A41D19/0082—Details
Definitions
- the protective gloves for process industries are constructed to assure people safety under harsh chemical, mechanical and electrical conditions.
- the glove suppliers provide a big product catalog, where different types of gloves are recommended for different type of chemicals to be handled. Depending on the application and chemical products to which they are exposed, the gloves may have a different type of material and a different thickness of the layers from which they are made of.
- the gloves In many countries, such as European countries, the gloves have to pass mechanical (EN 388), thermal (EN511), and chemical standards, such as a European standards (EN 374-2, EN 374-3) before they are sent to the market.
- the gloves should comply with the standard EN 420, which specifies general criteria for comfort, size, dexterity, labeling, and heavy metal content and pH content.
- EN 420 specifies general criteria for comfort, size, dexterity, labeling, and heavy metal content and pH content.
- Each standard defines exact test and acceptance conditions for the gloves exposed to critical mechanical, thermal, chemical agents.
- Standard EN-374-2 characterizes the permeability features of the gloves and it specifies a method for testing the protective gloves resistance to permeation of chemical products (penetration).
- Standard EN374-3 includes the standard EN 374-2 requirements, and in addition, requires that the protective glove pass the performance level 2 of chemical resistance for at least three chemical products (like, methanol, sulfuric acid 96%, 40% sodium hydroxide, tetrahydrofuran, acetone, carbon disulfide, ethyl acetate, etc.)
- This performance level 2 for chemical resistance means that the permeation time (test made according to the standard) should be higher than or equal to 30 minutes, when the glove is exposed continuously to that chemical.
- a catalog of gloves for chemical protection during handling of acids and alkalis would include as suitable the latex gloves which can be used in harsh applications for food and beverage industry where cleaning with high concentrated cleaning agents are the most used.
- latex gloves meet the above standard and they are also accompanied by a wide list of permeation data.
- their use in the field is made most of the time without keeping clear evidence of the time of use during their lifetime, and so in many cases they can be used for a much shorter time with respect to their designed lifetime.
- the suppliers themselves may be conservative in specifying the level of performance, which means that even if the real level of performance may be 4, the supplier would specify 3, which is lower than 4.
- An inner indicator glove formed of multiple layers including a protective layer having a top surface and a bottom surface, the bottom surface facing a hand of a user when wearing the inner indicator glove, and an indicator layer supported by the top surface of the protective layer and positioned to contact protective glove when the inner indicator glove is inserted into the protective glove, wherein the indicator layer is formed of a material that changes color when exposed to a solution penetrating the protective glove.
- a method of forming an inner indicator glove including dip coating a hand shaped former into a bath to form a protectivelayer having a thickness that provides a selected protection time less than a protection time of a protective glove and forming an indicator layer on the protective layer, the indicator forming an outer layer of the inner indicator glove.
- a method includes inserting an inner indicator glove into a protective glove, wherein the inner indicator glove has an indicator layer positioned to change color responsive to an end of service life of the protective glove, using the protective glove with the inserted inner indicator glove, viewing the change of color of the indicator layer, and discontinuing use of the protective glove.
- FIG. 1 is a representation of a protective glove 100 to be used in conjunction with an inner indicator glove 110 that fits inside of protective glove 100.
- the protective glove may be formed of latex or other protective material, like nitrile, chloroprene (e.g. Neoprene, butyl, polyvinyl chloride (PVC), PU, CSM, Fluoro elastomer (e.g. Viton).
- chloroprene e.g. Neoprene, butyl, polyvinyl chloride (PVC), PU, CSM, Fluoro elastomer (e.g. Viton).
- PVC polyvinyl chloride
- PU polyvinyl chloride
- CSM Fluoro elastomer
- Viton Fluoro elastomer
- the inner indicator glove 110 is introduced into the outer protective glove (G2G - glove to glove).
- the inner indicator glove 110 is designed to indicate the permeation of harsh chemicals through the outer glove and to assure hand protection for a minimum amount of time, such as at least 10 minutes of work (performance level 1).
- FIG. 2 is a cross section view of a portion 200 of the inner protective glove 110.
- the inner protective glove 110 in one embodiment is thin and flexible, comprising two layers, a top layer 210 and a bottom layer 220, strongly adhering one to the other, being stacked together during a fabrication process.
- Thebottom layer 220 is formed of protective material having a thickness suitable for ensuring protection of a hand for a specified amount of time following failure of the protective glove 100, such as 10 minutes. Other times, such as 5 minutes, 15 minutes, or any other time may be selected. Note that the protective bottom layer 220 may be quite a bit thinner than the thickness of the protective glove 100.
- Top layer 210 of the inner indicator glove is made of a material which changes its color due to the pH of the liquid permeating through the outer glove.
- a color changing layer can be made of universal pH indicator, and may thus respond to any type of chemical, either acid or base and its mixture.
- a good example for such universal pH indicator is the bromophenol blue. According to the color change of the bromophenol blue exposed to the liquid, a yellow color is obtained for pH smaller than 3, multiple colors for pH between 3 and 4.6 (real pH indicator in this pH range) and blue color for pH greater than 4.6.
- the advantage of bromophenol blue is that it has the largest change in color hue, when the concentration of the observedsample increases or decreases.
- top layer 220 of the inner indicator glove 110 immersed only in the acidbaths
- a color changing layer top layer 220
- methyl orange C 14 H 14 N 3 NaO 3 S
- phenolphthalein which is colorless below 8.2 and pink above that value up to a pH ofabout 13.
- the phenolphthalein becomes colorless.
- the bottom layer 220 of the inner glove which isin contact with the skin, it is made of a chemically resistant material like latex, butyl, CSM/neoprene, etc.
- Such an inner indicator glove 110 with continuous color change top layer 220 above the entire hand has the advantage of identification of the startingleakage area without any harmful effect of on the skin of the user, while the outer protective glove itself has been safely used during itsmaximum service life, without any concerns related to its use in the last period of use.
- Determining that the inner indicator glove 110 has changed color may be done in several different ways.
- the user may simply remove the outer protective glove 100 and visually inspect the inner indicator glove 110 for color changes.
- a transparent or at least partially transparent or translucent patch may be provided on an alternative outer protective glove 300 as indicated at 310 in FIG. 3 .
- the patch 310 is sufficiently transparent to allowa user to see the color of the inner indicator glove without removing the outer glove.
- the activation mechanism causing the inner indicator glove to produce a visible indication results in a flow of an indicator solution comprising vapors and liquids the external glove is exposed to, to an external surface of the protective glove.
- an indicator solution comprising vapors and liquids the external glove is exposed to, to an external surface of the protective glove.
- nanopores which are filled with air, and these nanopores are at the origin of the liquid permeation process. This means that the liquid molecules can diffuse inside the protective glove via those pores and after a certain time they can penetrate the entire thickness of the protective glove, reaching the inner indicator glove. This time is called the breakdown time of the protective glove in a certain solution. The breakdown time of a protective glove will depend on its thickness, the magnitude of the permeating liquid molecule and the size of the nanopores.
- the solution from the nanopores will start to dissolve the color changing indicator layer 210 containing bromophenol blue in one embodiment in the inner indicator glove 110, acting as a pH indicator or dye. This dye will start diffusing back along the nanopores via concentration gradient and capillary forces, through the protective glove 100 until visible at the outer surface of the protective glove 100.
- a background color of white for the protective glove 110 may provide for maximum contrast of the indication color.
- the color will be changed according to the overall pH of the liquid in the pores after glove exposure to both acids and bases, and solvents, i.e., the solution.
- the first fabrication process is similar to a traditional dip coating process used for the protective glove.
- a second process is a hybrid approach where the chemically resistant layer is made by dip coating while the color changing layer is made by direct printing.
- the third process is an all-printing process, where both color changing layer and the chemically resistive layer are made by a method of direct printing.
- This G2G concept can be applied to all types of chemically protective gloves.
- a universal inner indicator glove can be used forall type of gloves dedicated to acid/base/solvent combinations.
- the hand shaped former is in the shape of a typical glove, having portions corresponding to an arm, palm area, four fingers and a thumb. Different HSFs may be used for each hand and multiple HSFs may be used of varying sizes corresponding to different sizes of hands and protective gloves.
- a thermaltreatment is made for the solid state consolidation of the film.
- the gloves are peeled off from the HSF,and thus the last deposited layer on the glove will be the layer in contact with the skin.
- the glove is not reversed when peeling it off from the HSF, or may be turned inside out after peeling off. This allows the inner indicator glove to be formed by first forming the latex protective layer followed by the indicator layer.
- the same size HSF may be used to form both the protective glove 100 and the inner indicator glove 110 such that a tight fit of the inner indicator glove 110 into the protective glove 100 is obtained.
- a tight fit ensures better tactile feel and dexterity for the user in utilizing the combined gloves.
- a tight fit may also promote better migration of color from the inner indicator glove to the outside of the protective glove for viewing by a user.
- a slightly smaller size HSF may be used for the inner indicator glove formation.
- An automated factory for fabrication of all printed inner indicator gloves utilizing moving the HSF on a line from one location to another, and at each location, the HSF will receive the required process as described above.
- the HSF can travel through a furnace with the required temperature profile, as required by the previous printed layer.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Gloves (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15198547.0A EP3178337A1 (de) | 2015-12-08 | 2015-12-08 | Schutzhandschuh mit innenhandschuhlebensdaueranzeige |
US15/372,164 US20170156420A1 (en) | 2015-12-08 | 2016-12-07 | Protective glove with inner glove life indicator |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15198547.0A EP3178337A1 (de) | 2015-12-08 | 2015-12-08 | Schutzhandschuh mit innenhandschuhlebensdaueranzeige |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3178337A1 true EP3178337A1 (de) | 2017-06-14 |
Family
ID=54848406
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15198547.0A Withdrawn EP3178337A1 (de) | 2015-12-08 | 2015-12-08 | Schutzhandschuh mit innenhandschuhlebensdaueranzeige |
Country Status (2)
Country | Link |
---|---|
US (1) | US20170156420A1 (de) |
EP (1) | EP3178337A1 (de) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USD814120S1 (en) | 2016-03-16 | 2018-03-27 | Avent, Inc. | Protective glove |
USD814119S1 (en) * | 2016-03-16 | 2018-03-27 | Avent, Inc. | Protective glove |
USD823545S1 (en) | 2016-03-16 | 2018-07-17 | O&M Halyard, Inc. | Protective glove cuff |
USD830668S1 (en) * | 2016-08-26 | 2018-10-16 | Alexandra Cohen Curtis | Set of warming gloves and socks |
KR101926825B1 (ko) | 2018-06-26 | 2018-12-07 | 허민규 | 화학물질 감지용 피복 |
TR201815042A2 (tr) * | 2018-10-11 | 2018-11-21 | Kal Adnan | Eldi̇ven i̇çi̇ne sizan zararli ki̇myasallar ve eldi̇ven i̇çi̇nde oluşan ph deği̇şi̇kli̇ği̇nde renk deği̇şti̇rerek koruma sağlayan eldi̇ven si̇stemi̇ |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5017427A (en) * | 1986-12-08 | 1991-05-21 | The Yokohama Rubber Co., Ltd. | Laminate having indicator function |
US5133087A (en) * | 1986-12-08 | 1992-07-28 | The Yokohama Rubber Co., Ltd. | Laminate having indicator function |
US5650329A (en) * | 1990-08-23 | 1997-07-22 | Awc. Inc. | Acid indicators |
EP1637046A2 (de) * | 2004-09-21 | 2006-03-22 | Microflex Corporation | Handschuhen mit visueler Auswechsellungsanzeige |
GB2433227A (en) * | 2005-12-16 | 2007-06-20 | Regent Medical Ltd | Puncture indicating laminates |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5483697A (en) * | 1989-05-22 | 1996-01-16 | Board Of Regents The University Of Texas | Multilayer protective coverings with a sealing solution |
US5357636A (en) * | 1992-06-30 | 1994-10-25 | Dresdner Jr Karl P | Flexible protective medical gloves and methods for their use |
AT413471B (de) * | 2003-05-21 | 2006-03-15 | Semperit Ag Holding | Prophylaxeartikel |
US7829181B2 (en) * | 2005-08-31 | 2010-11-09 | Kimberly-Clark Worldwide, Inc. | Solvatochromic visual indicator and the use of the same |
AT503090B1 (de) * | 2006-01-11 | 2012-06-15 | Semperit Ag Holding | Prophylaxeartikel |
US20080057534A1 (en) * | 2006-08-31 | 2008-03-06 | Kimberly-Clark Worldwide, Inc. | Microbe-sensitive indicators and use of the same |
RU2724256C2 (ru) * | 2015-11-19 | 2020-06-22 | О энд М ХАЛЯРД ИНТЕРНЕШЕНЕЛ АНЛИМИТЕД КОМПАНИ | Перчатка с облегчающим обнаружение повреждения высоким контрастом между цветом ее внутренней стороны и цветом ее наружной стороны |
-
2015
- 2015-12-08 EP EP15198547.0A patent/EP3178337A1/de not_active Withdrawn
-
2016
- 2016-12-07 US US15/372,164 patent/US20170156420A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5017427A (en) * | 1986-12-08 | 1991-05-21 | The Yokohama Rubber Co., Ltd. | Laminate having indicator function |
US5133087A (en) * | 1986-12-08 | 1992-07-28 | The Yokohama Rubber Co., Ltd. | Laminate having indicator function |
US5650329A (en) * | 1990-08-23 | 1997-07-22 | Awc. Inc. | Acid indicators |
EP1637046A2 (de) * | 2004-09-21 | 2006-03-22 | Microflex Corporation | Handschuhen mit visueler Auswechsellungsanzeige |
GB2433227A (en) * | 2005-12-16 | 2007-06-20 | Regent Medical Ltd | Puncture indicating laminates |
Also Published As
Publication number | Publication date |
---|---|
US20170156420A1 (en) | 2017-06-08 |
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