EP3151988A1 - Cemented carbide necking tool - Google Patents

Cemented carbide necking tool

Info

Publication number
EP3151988A1
EP3151988A1 EP14736027.5A EP14736027A EP3151988A1 EP 3151988 A1 EP3151988 A1 EP 3151988A1 EP 14736027 A EP14736027 A EP 14736027A EP 3151988 A1 EP3151988 A1 EP 3151988A1
Authority
EP
European Patent Office
Prior art keywords
cemented carbide
necking tool
necking
carbide
tool according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14736027.5A
Other languages
German (de)
French (fr)
Other versions
EP3151988B1 (en
Inventor
Stephen A. HEWITT
Elena Tarres Puit
Victor Rimbau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandvik Intellectual Property AB
Original Assignee
Sandvik Intellectual Property AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandvik Intellectual Property AB filed Critical Sandvik Intellectual Property AB
Priority to PL14736027T priority Critical patent/PL3151988T3/en
Priority to PT147360275T priority patent/PT3151988T/en
Publication of EP3151988A1 publication Critical patent/EP3151988A1/en
Application granted granted Critical
Publication of EP3151988B1 publication Critical patent/EP3151988B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00Tools as parts of machines covered by this subclass
    • B21D37/01Selection of materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D51/00Making hollow objects
    • B21D51/16Making hollow objects characterised by the use of the objects
    • B21D51/26Making hollow objects characterised by the use of the objects cans or tins; Closing same in a permanent manner
    • B21D51/2615Edge treatment of cans or tins
    • B21D51/2638Necking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D41/00Application of procedures in order to alter the diameter of tube ends
    • B21D41/04Reducing; Closing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D51/00Making hollow objects
    • B21D51/16Making hollow objects characterised by the use of the objects
    • B21D51/26Making hollow objects characterised by the use of the objects cans or tins; Closing same in a permanent manner
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/10Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on titanium carbide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides

Definitions

  • the present invention relates to a cemented carbide necking tool having lower density, higher hardness, and closer thermal expansion to tool steel for applications in the can manufacturing industry.
  • Cemented carbide which is produced using modern powder metallurgical processes, offers a unique combination of strength, hardness and toughness.
  • Cemented carbide as used herein, is defined as a hard, carbide phase, 70 to 97 wt-% of the composite and a binder phase.
  • Cemented carbides include standard WCCo, Cermets and hybrids. Tungsten carbide (WC) is the most common hard phase and cobalt (Co) the most common binder phase. These two materials form the basic cemented carbide structure. From this basic concept many other types of cemented carbide have been developed. In addition to WC-Co
  • TiC titanium carbide
  • TaC tantalum carbide
  • NbC niobium carbide
  • the cobalt binder phase can be alloyed with or completely replaced by nickel (Ni), chromium (Cr), iron (Fe), molybdenum (Mo) or alloys of these elements.
  • the resulting physical and chemical properties can be tailored to ensure maximum resistance to wear, deformation, fracture, corrosion, oxidation and other damaging effects.
  • the available unique composition of cemented carbide makes it an ideal tool material for forming and stamping in the can making process.
  • An example of a known die 10 is illustrated in Fig. 1.
  • Typical necking dies work with knock out that is normally made of tool steel due to reduced cost.
  • the match gap of the knock out and necking dies must be kept as constant as possible during start up and running conditions of the necker machine, therefore the closer the thermal expansion of the necking die to the tool steel the better.
  • EP2439294 assigned to the assignee of the present invention, discloses a cemented carbide punch used for the manufacturing of metal beverage cans.
  • the particular disclosed cemented carbide has a hard phase of WC and a binder phase based on Co and Ni.
  • the composition comprises, in wt-%, from 50 to 70 WC, from 15 to 30 TiC (titanium carbide) and from 12 to 20 Co +Ni.
  • the punch application is particularly suited to this particular composition as the weight of the punch can be lowered and production speeds increased.
  • WO2008079083 discloses a cemented carbide punch used in cold forming and drawing operations, particularly in the manufacture of beverage cans.
  • the cemented carbide is essentially, in wt %: 70-90 WC; 2-8 TiC, 1-9 NbC, 0-3 TaC and 5-20 binder phase of Co with an addition of Cr and possibly one or more of the elements selected from Ni, Fe and Mo. More particularly the binder composition is, also in wt %: 10-98 Co, 0-50 Ni, 2-15 Cr, 0-50 Fe and 0-10 Mo.
  • grades with binder content in the range of 3 to 10 wt % and grain sizes below 1 ⁇ have the highest hardness and compressive strength, combined with high wear resistance and high reliability against breakage.
  • grade can be defined as tungsten carbide (WC) in combination with a binder phase of cobalt (Co) and/or nickel (Ni), and any other single or combination of carbide phases (TiC, Ta/NbC etc.).
  • the binder phase of cemented carbides is susceptible to wet corrosion resulting in wear problems. Accordingly, sub-micron carbide grains combined with the appropriate binder have been used in WC-Co carbide punches.
  • a necking tool for manufacturing of metal beverage cans the necking tool being a cemented carbide containing in wt % of 18 - 63WC; 21 - 30 TiC; 0 - 27 TiN; 0 - 12 NbC; 0 - 2 Cr 3 C 2 ; 8 - 14 Co and 0 - 6 Ni.
  • a necking tool for manufacturing of metal beverage cans the necking tool being a cemented carbide including in wt % of less than 63 WC; 21 TiC; 2 Cr3C2; 8 Co; and less than 6 Ni.
  • a necking tool for manufacturing of metal beverage cans the necking tool being a cemented carbide including in wt % of 18 WC; less than 30 TiC; less than 27 TiN; less than 12 NbC, and 14 Co.
  • Fig. 1 is a perspective view of a known necking die used in manufacturing metal beverage cans.
  • Fig. 2 is a SEM image of a first necking tool material according to the present disclosure.
  • Fig. 3 is a SEM image of a second necking tool material according to the present disclosure.
  • Fig. 4 is a SEM image of the porosity level of Sample B of Fig. 3.
  • the present invention relates to cemented carbide including hybrids and cermets for necking applications in the can manufacturing industry.
  • the advantages associated with these new materials can be seen in higher hardness, lower density, and closer thermal expansion to a tool steel knock-out and enhanced toughness compared to existing ceramic material used for necking dies
  • Cemented carbide grades with the compositions in wt % according to Table 1 below were produced according to known methods.
  • the cemented carbide samples were prepared from powders forming the hard constituents and powders forming the binder, which were wet milled together, dried, pressed into bodies desired shape and sintered.
  • the comparative sample contains in wt% less than about 88 WC; about 12 Co; and about 1 Cr 3 C2, preferably 87.5% WC, 12%Co and 0.5 Cr 3 C 2 . Moreover, the comparative sample has a medium carbide grain size, a corrosion resistance on a subjective scale of 1 to 10 of about 3, a wear resistance on a subjective scale of 1 to 10 of about 5, a compressive strength of about 4600 MPa, and a fracture toughness, per the Palmqvist method, of about 16 MPa m 1 / 2 .
  • Both Sample A and B have a grain size from 0.5 ⁇ to 1 ⁇ .
  • the binder content for both samples is approximately 14%.
  • the necking tool is made of a cemented carbide including in wt % of 18 - 63 WC; less than 30 TiC; 0 - 27 TiN; 0 - 12 NbC; 0 - 2 Cr 3 C 2 ; 8 - 14 Co; and 0 - 6 Ni.
  • the necking tool is made of cemented carbide including in wt % less than 63 WC, and more preferably 62.8 WC; 21 TiC; 2 Cr3C2; 8 Co and more preferably 8.3 Co; and less than 6 Ni and more preferably 5.7 Ni.
  • the binder phase consists of Co and Ni and has a content of approximately 14 wt %.
  • the necking tool is made of a cemented carbide including in wt-%, of 18 WC, and more preferably, 18.08 WC; less than 30 TiC, and more preferably 29.66 TiC; less than 27 TiN, and more preferably 26.46 TiN; less than 12 NbC, and more preferably 11.63; and 14 Co and more preferably 14.17 Co.
  • Sample B utilizes N to inhibit grain growth. Moreover, the Ti grains are spherical and the Co binder well distributed. Also, as shown in Fig. 4, the optical micrograph shows A02/A04 type porosity levels.
  • Samples A and B have a much higher hardness, of 1450 and 1650 respectively and a much lower density, of less than 10 g/cm 3 , than the comparative H12N, of 9.86 and of 6.62 respectively, and closer thermal expansion, of 7.13 and of 7.49, to known tool steel.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Mounting, Exchange, And Manufacturing Of Dies (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

A necking tool for manufacturing of metal beverage cans, the necking tool being a cemented carbide comprising in wt % of 18 - 63WC; 21 - 30 TiC; 0 - 27 TiN; 0 - 12 NbC; 0 - 2 Cr3C2; 8 - 14 Co and 0 - 6 Ni.

Description

CEMENTED CARBIDE NECKING TOOL
TECHNICAL FIELD AND INDUSTRIAL APPLICABILITY
[0001] The present invention relates to a cemented carbide necking tool having lower density, higher hardness, and closer thermal expansion to tool steel for applications in the can manufacturing industry.
BACKGROUND
[0002] Over 280 billion beverage cans are produced worldwide every year. During the process, the upper section of the can is reduced in a necking-in operation to accommodate a top. Dies are commonly used in the necking operation. Due to the large number of cans produced service life of the die tool is crucial.
[0003] Accordingly, the necking die material must satisfy the most demanding applications. Cemented carbide, which is produced using modern powder metallurgical processes, offers a unique combination of strength, hardness and toughness. Cemented carbide, as used herein, is defined as a hard, carbide phase, 70 to 97 wt-% of the composite and a binder phase. Cemented carbides include standard WCCo, Cermets and hybrids. Tungsten carbide (WC) is the most common hard phase and cobalt (Co) the most common binder phase. These two materials form the basic cemented carbide structure. From this basic concept many other types of cemented carbide have been developed. In addition to WC-Co
compositions, varying proportions of titanium carbide (TiC), tantalum carbide (TaC) or niobium carbide (NbC) or others can be used. In addition, the cobalt binder phase can be alloyed with or completely replaced by nickel (Ni), chromium (Cr), iron (Fe), molybdenum (Mo) or alloys of these elements.
[0004] By varying the composition, the resulting physical and chemical properties can be tailored to ensure maximum resistance to wear, deformation, fracture, corrosion, oxidation and other damaging effects. The available unique composition of cemented carbide makes it an ideal tool material for forming and stamping in the can making process. An example of a known die 10 is illustrated in Fig. 1. Typical necking dies work with knock out that is normally made of tool steel due to reduced cost. The match gap of the knock out and necking dies must be kept as constant as possible during start up and running conditions of the necker machine, therefore the closer the thermal expansion of the necking die to the tool steel the better.
[0005] EP2439294, assigned to the assignee of the present invention, discloses a cemented carbide punch used for the manufacturing of metal beverage cans. The particular disclosed cemented carbide has a hard phase of WC and a binder phase based on Co and Ni. The composition comprises, in wt-%, from 50 to 70 WC, from 15 to 30 TiC (titanium carbide) and from 12 to 20 Co +Ni. The punch application is particularly suited to this particular composition as the weight of the punch can be lowered and production speeds increased.
[0006] WO2008079083, also assigned to the assignee of the present invention, discloses a cemented carbide punch used in cold forming and drawing operations, particularly in the manufacture of beverage cans. The cemented carbide is essentially, in wt %: 70-90 WC; 2-8 TiC, 1-9 NbC, 0-3 TaC and 5-20 binder phase of Co with an addition of Cr and possibly one or more of the elements selected from Ni, Fe and Mo. More particularly the binder composition is, also in wt %: 10-98 Co, 0-50 Ni, 2-15 Cr, 0-50 Fe and 0-10 Mo.
[0007] Further, grades with binder content in the range of 3 to 10 wt % and grain sizes below 1 μηι have the highest hardness and compressive strength, combined with high wear resistance and high reliability against breakage. As used herein grade can be defined as tungsten carbide (WC) in combination with a binder phase of cobalt (Co) and/or nickel (Ni), and any other single or combination of carbide phases (TiC, Ta/NbC etc.). However, the binder phase of cemented carbides is susceptible to wet corrosion resulting in wear problems. Accordingly, sub-micron carbide grains combined with the appropriate binder have been used in WC-Co carbide punches.
[0008] However, such materials have not been previously used for necking dies.
SUMMARY [0009] In one aspect there is provided a necking tool for manufacturing of metal beverage cans, the necking tool being a cemented carbide containing in wt % of 18 - 63WC; 21 - 30 TiC; 0 - 27 TiN; 0 - 12 NbC; 0 - 2 Cr3C2; 8 - 14 Co and 0 - 6 Ni.
[0010] According to another aspect there is provided a necking tool for manufacturing of metal beverage cans, the necking tool being a cemented carbide including in wt % of less than 63 WC; 21 TiC; 2 Cr3C2; 8 Co; and less than 6 Ni.
[0011] In yet another aspect there is provided a necking tool for manufacturing of metal beverage cans, the necking tool being a cemented carbide including in wt % of 18 WC; less than 30 TiC; less than 27 TiN; less than 12 NbC, and 14 Co.
[0012] These and other objects, features, aspects, and advantages of the present invention will become more apparent from the following detailed description of the preferred embodiment relative to the accompanied drawings, in which:
BRIEF DESCRIPTION OF THE DRAWINGS
[0013] Fig. 1 is a perspective view of a known necking die used in manufacturing metal beverage cans.
[0014] Fig. 2 is a SEM image of a first necking tool material according to the present disclosure.
[0015] Fig. 3 is a SEM image of a second necking tool material according to the present disclosure.
[0016] Fig. 4 is a SEM image of the porosity level of Sample B of Fig. 3.
DETAILED DESCRIPTION
[0017] The present invention relates to cemented carbide including hybrids and cermets for necking applications in the can manufacturing industry. The advantages associated with these new materials can be seen in higher hardness, lower density, and closer thermal expansion to a tool steel knock-out and enhanced toughness compared to existing ceramic material used for necking dies
[0018] Cemented carbide grades with the compositions in wt % according to Table 1 below were produced according to known methods. The cemented carbide samples were prepared from powders forming the hard constituents and powders forming the binder, which were wet milled together, dried, pressed into bodies desired shape and sintered.
Table 1
[0019] A known cemented carbide, Sandvik grade H12N, (Sandvik AB,
Sandviken, SE), used in the can tooling industry, was used as the comparative sample. The comparative sample contains in wt% less than about 88 WC; about 12 Co; and about 1 Cr3C2, preferably 87.5% WC, 12%Co and 0.5 Cr3C2. Moreover, the comparative sample has a medium carbide grain size, a corrosion resistance on a subjective scale of 1 to 10 of about 3, a wear resistance on a subjective scale of 1 to 10 of about 5, a compressive strength of about 4600 MPa, and a fracture toughness, per the Palmqvist method, of about 16 MPa m1/2. [0020] Example
[0021] Two cemented carbide bodies according to the present disclosure were prepared and characterized (Samples A and B) as shown in Table 1. The samples were analyzed by electron microscopy. The SEM micrograph of Sample A is shown in Fig. 2 and Sample B is shown in Fig. 3. As shown, it can be seen that the morphology and distribution of the hard and matrix phases are uniform.
[0022] Both Sample A and B have a grain size from 0.5 μπι to 1 μηι. The binder content for both samples is approximately 14%. Preferably, 6 to 18% Co/Ni.
[0023] According to one aspect, the necking tool is made of a cemented carbide including in wt % of 18 - 63 WC; less than 30 TiC; 0 - 27 TiN; 0 - 12 NbC; 0 - 2 Cr3C2; 8 - 14 Co; and 0 - 6 Ni.
[0024] According to another aspect, the necking tool is made of cemented carbide including in wt % less than 63 WC, and more preferably 62.8 WC; 21 TiC; 2 Cr3C2; 8 Co and more preferably 8.3 Co; and less than 6 Ni and more preferably 5.7 Ni. Accordingly, the binder phase consists of Co and Ni and has a content of approximately 14 wt %.
[0025] In another aspect, the necking tool is made of a cemented carbide including in wt-%, of 18 WC, and more preferably, 18.08 WC; less than 30 TiC, and more preferably 29.66 TiC; less than 27 TiN, and more preferably 26.46 TiN; less than 12 NbC, and more preferably 11.63; and 14 Co and more preferably 14.17 Co.
[0026] Referring to Table 1 and as can be seen in Fig. 3, Sample B utilizes N to inhibit grain growth. Moreover, the Ti grains are spherical and the Co binder well distributed. Also, as shown in Fig. 4, the optical micrograph shows A02/A04 type porosity levels.
[0027] Other properties were measured according to standards used in the cemented carbide industry as shown in Table 2 below.
Table 2
[0028] As can be seen, Samples A and B have a much higher hardness, of 1450 and 1650 respectively and a much lower density, of less than 10 g/cm3, than the comparative H12N, of 9.86 and of 6.62 respectively, and closer thermal expansion, of 7.13 and of 7.49, to known tool steel.
[0029] Although the present invention has been described in relation to particular embodiments thereof, many other variations and modifications and other uses will become apparent to those skilled in the art. It is preferred therefore, that the present invention be limited not by the specific disclosure herein, but only by the appended claims.

Claims

WHAT IS CLAIMED IS:
1. A necking tool for manufacturing of metal beverage cans, the necking tool being a cemented carbide comprising in wt % of 18 - 63 WC; 21- 30 TiC, 0- 27 TiN; 0-12 NbC; 0 to 2 Cr3C2; 8 to 14 Co; and 0 to 6 Ni.
2. A necking tool according claim 1, wherein a binder content of the cemented carbide is about 14 wt %.
3. A necking tool according to any one of the preceding claims, wherein the cemented carbide has a density of less than 10 g/cm3.
4. A necking tool according to any one of the preceding claims, wherein the cemented carbide has a coefficient of thermal expansion of 7.13 lxlO-6/°C
5. A necking tool according to any of the preceding claims, wherein a binder content of the cemented carbide is 14.17 wt %.
6. A necking tool according to any of the preceding claims, wherein the cemented carbide has a coefficient of thermal expansion of 7.49 Ixl0~6/°C
7. A necking tool according to any one of the preceding claims, wherein the cemented carbide has a grade with a grain size less than 1 μηι, preferably 0.5 to 1 μιη, and more preferably 0.5 to 0.9 im.
8. Use of a necking tool according to any of the preceding claims for manufacturing a metal beverage can.
EP14736027.5A 2014-06-09 2014-06-09 Cemented carbide necking tool Active EP3151988B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL14736027T PL3151988T3 (en) 2014-06-09 2014-06-09 Cemented carbide necking tool
PT147360275T PT3151988T (en) 2014-06-09 2014-06-09 Cemented carbide necking tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2014/062073 WO2015189654A1 (en) 2014-06-09 2014-06-09 Cemented carbide necking tool

Publications (2)

Publication Number Publication Date
EP3151988A1 true EP3151988A1 (en) 2017-04-12
EP3151988B1 EP3151988B1 (en) 2018-01-17

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Country Status (12)

Country Link
EP (1) EP3151988B1 (en)
JP (1) JP6306217B2 (en)
KR (1) KR20170018831A (en)
CN (1) CN106457355A (en)
BR (1) BR112016028765A2 (en)
ES (1) ES2663710T3 (en)
MX (1) MX354805B (en)
PL (1) PL3151988T3 (en)
PT (1) PT3151988T (en)
RU (1) RU2661198C1 (en)
WO (1) WO2015189654A1 (en)
ZA (1) ZA201607886B (en)

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CN102304657B (en) * 2011-09-26 2012-10-24 四川大学 Molybdenum-free Ti (C, N)-based cermet wear resistant and corrosion resistant material and preparation method thereof
CN103540824B (en) * 2013-10-21 2015-11-18 江门市楚材科技有限公司 A kind of cermet material

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JP6306217B2 (en) 2018-04-04
RU2661198C1 (en) 2018-07-16
ES2663710T3 (en) 2018-04-16
JP2017524810A (en) 2017-08-31
BR112016028765A2 (en) 2017-08-22
CN106457355A (en) 2017-02-22
MX354805B (en) 2018-03-22
WO2015189654A1 (en) 2015-12-17
KR20170018831A (en) 2017-02-20
ZA201607886B (en) 2019-12-18
EP3151988B1 (en) 2018-01-17
PL3151988T3 (en) 2018-07-31
PT3151988T (en) 2018-03-27

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