EP3135778B1 - Method and device for reaction control - Google Patents
Method and device for reaction control Download PDFInfo
- Publication number
- EP3135778B1 EP3135778B1 EP15183169.0A EP15183169A EP3135778B1 EP 3135778 B1 EP3135778 B1 EP 3135778B1 EP 15183169 A EP15183169 A EP 15183169A EP 3135778 B1 EP3135778 B1 EP 3135778B1
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- European Patent Office
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- inert gas
- reaction chamber
- reactant
- openings
- chamber
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- 238000006243 chemical reaction Methods 0.000 title claims description 43
- 238000000034 method Methods 0.000 title claims description 19
- 239000011261 inert gas Substances 0.000 claims description 47
- 230000003647 oxidation Effects 0.000 claims description 38
- 238000007254 oxidation reaction Methods 0.000 claims description 38
- 229910000831 Steel Inorganic materials 0.000 claims description 33
- 239000010959 steel Substances 0.000 claims description 33
- 230000001590 oxidative effect Effects 0.000 claims description 32
- 239000007800 oxidant agent Substances 0.000 claims description 30
- 239000000376 reactant Substances 0.000 claims description 30
- 238000000137 annealing Methods 0.000 claims description 17
- 238000000605 extraction Methods 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 238000006557 surface reaction Methods 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 230000001276 controlling effect Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 238000005246 galvanizing Methods 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000013980 iron oxide Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/561—Continuous furnaces for strip or wire with a controlled atmosphere or vacuum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B9/00—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
- F27B9/04—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity adapted for treating the charge in vacuum or special atmosphere
- F27B9/045—Furnaces with controlled atmosphere
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B9/00—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
- F27B9/14—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment
- F27B9/145—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving along a serpentine path
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D7/00—Forming, maintaining, or circulating atmospheres in heating chambers
- F27D7/06—Forming or maintaining special atmospheres or vacuum within heating chambers
Definitions
- the invention relates to a device and a method for controlling the surface reaction on steel sheets transported in a continuous galvanizing or annealing line.
- High strength steel grades generally comprise high contents of elements like silicon, manganese and chromium (respectively typically between 0.5 and 2%; 1.5 and 6%, 0.3 and 1% in wt) making them difficult to coat because an oxide layer of those elements is formed during the annealing preceding the dipping in the galvanizing bath. This oxide layer harms the wetting ability of the steel surface when submerged in the bath. As a result, uncoated areas and a poor adhesion of the coating are obtained.
- a well-known method to improve the wetting of these steel grades consists in fully oxidizing the steel surface in a specific chamber when the steel has a temperature typically between 600 and 750°C.
- the resulting oxide layer comprises a high amount of iron oxides which are then reduced during the end of heating and holding section of the annealing furnace and the following thermal treatment.
- the target is to obtain an oxide thickness between around 50 and 300nm, what corresponds to an iron oxide below 2gr/m 2 .
- this oxidation can be performed in a direct fired furnace running the combustion with air excess.
- Another way consists in making this oxidation in a dedicated chamber located in the middle of the annealing furnace and supplied with a mixture of nitrogen and an oxidant. Such implementation is described in the patent EP 2 010 690 B1 and in figure 1 .
- the oxidation section is separated from the other parts of the annealing furnace by seals to minimize the introduction of the oxidant in the first and final sections.
- the formation of the oxide layer must be carefully controlled to avoid the formation of too thick or too thin layers.
- the reduction in the final part of the furnace can be incomplete due to lack of time. It is also known that, in that case, the oxide can stick to the furnace rolls and generate defects.
- the oxide layer is not efficient enough since the oxidation of the alloying elements cannot be inhibited sufficiently and thereby the wetting in the liquid metal bath is not sufficiently improved.
- the formation of the oxide layer is guided by three main parameters: strip temperature, oxygen concentration in the atmosphere of the chamber and the transport of that oxygen to the steel surface. Because the edges of the sheet have not the same boundary conditions and turbulence as the center of the sheet, the transport of the oxidant to the edge is different. Similarly to higher edge cooling in the processing line, the oxidation of the edge used to be higher. The width impacted by this over oxidation is in the range from 1 to 10cm, depending on the design of the oxidizing chamber and on the process parameters used.
- the present invention relates to a continuous annealing furnace for annealing steel strips comprising a reaction chamber wherein the steel strips are transported vertically, said chamber comprising openings supplied with a reactant, also called reactant openings, located at the top or at the bottom of the reaction chamber, wherein the reaction chamber further comprises other openings supplied with an inert gas, also called inert gas openings, said inert gas openings being located on the lateral sides of the reaction chamber.
- a reactant also called reactant openings
- the furnace according to the invention further discloses at least one or a suitable combination of the following features:
- the invention also relates to a method for controlling a surface reaction on a steel strip running vertically through the reaction chamber of the furnace as described above, comprising a step of injecting laterally an inert gas in the reaction chamber and a step of injecting a reactant upstream of the inert gas flow in said chamber.
- the method according to the invention further discloses at least one or a suitable combination of the following features:
- the invention also relates to a steel strip obtained by the method as described above wherein the steel strip has at the exit of the oxidation chamber an oxide layer with an increase of the mass per surface area between the value at the center of the strip and the maximum value at the edge of the strip inferior to 15% and preferably inferior to 10%.
- the invention aims to provide a device and a method to control the surface reaction of the edges of a sheet without mechanical system.
- the surface reaction can be any reaction that can occur in a section of an annealing furnace like a reduction reaction or a nitriding reaction, the section being supplied with the appropriate reactant. Indeed, the problem of formation of layers with a different thickness on the edges of the sheet exists regardless of the type of reactant.
- the method and the device are hereafter illustrated for a surface reaction occurring in an oxidation chamber supplied with an oxidant.
- the annealing furnace comprises an oxidation chamber provided with means for modulating the oxygen concentration of the atmosphere in the regions close to the edges of the sheet.
- the oxidation chamber according to the invention can be used in a continuous galvanizing line and in a continuous annealing line without hot-dip galvanizing facilities. In this latter case, the uncoated steel sheet can be further pickled to remove the oxide layer formed during annealing.
- the method according to the invention consists in injecting an inert gas with a defined flow and temperature through the sides of the oxidation chamber.
- the oxidation chamber 2 comprises lateral openings 3 for injecting the inert gas in addition to transversal openings 4 for injecting the oxidant medium, also called oxidant.
- the level of the oxidant transversally injected can be either increased or decreased in the edge area depending on the dilution rate resulting from the lateral injection of inert gas.
- the oxidation chamber can further comprise openings for extracting the fluid at the opposite side of the transversal openings in order to avoid an overpressure inside the chamber.
- the lateral openings of the chamber can be in the form of holes and one, two or more than two holes can be provided in each lateral side of the chamber.
- the openings can be in the form of slots or any form appropriate for injecting a gas.
- the oxidation chamber can be provided with means for separately controlling the flow of inert gas on each lateral side.
- the transversal openings for injecting the oxidant gas through the chamber are preferably located at the top of the chamber for reasons explained below.
- An opening is located on each side of the sheet.
- the transversal openings 4 are in the form of slots but they can have other shapes according to other embodiments.
- the opening 4 can be provided with reinforcement 6 to keep the opening geometry constant as represented in figure 4 .
- the chamber comprises extraction openings 7 to reduce the pressure inside the chamber when the fluid is not recycled.
- extraction openings 7 can be in the form of slots on each side of the sheet as shown in figure 5 or be round, square or rectangular openings as represented in figure 6 .
- the chamber further comprises rolls or similar sealing system at its entry and exit to separate the atmosphere of this chamber from the rest of the annealing furnace and so to minimize the flow of the oxidant in the other parts of the furnace.
- rolls or similar sealing system at its entry and exit to separate the atmosphere of this chamber from the rest of the annealing furnace and so to minimize the flow of the oxidant in the other parts of the furnace.
- the chamber is heat insulated but if required some heating devices can be added to compensate for heat losses.
- typical dimensions of the oxidation chamber are the following. It is between 3 and 5m long with a width that it is about 150mm wider than the maximal strip width to run. A typical design is 2m wide for a maximal strip width of 1850mm.
- the minimal distance between the casing of the oxidation chamber and the strip is from 75 to 220mm, preferably from 100 to 200mm and more preferably of 100mm.
- the steel sheet 5 passes vertically through the oxidation chamber 2.
- the sheet can move up or down depending on the global furnace layout.
- the oxidant gas composed of a mixture of N 2 and O 2 with an oxygen content between 0.01 and 8% and preferably between 0.1 and 4% in volume is injected through the transversal openings 4.
- the flow, the temperature and the concentration of the oxidant is controlled.
- the flow per side is typically comprised between 150 and 250Nm 3 /h for a slot with 10mm opening and 2m long.
- the temperature of the mixture N 2 +O 2 is between 200°C and 50°C below the strip temperature to take benefit of the buoyancy principle.
- the mixture temperature is between 580 and 600°C for a strip at 700°C.
- the transversal openings are located at the top of the chamber. Because the oxygen is not consumed in the area next to the sides of the chamber and being outside of the strip edges, the concentration of O 2 is higher in those parts resulting in a thicker oxide layer on the edges of the sheets compared to the central part of the sheet. This is especially true on narrow sheets.
- a small amount of pure inert gas like N 2 or Ar is injected downstream of the oxidant injection via the lateral openings of the chamber. The flow rate and temperature of the inert gas is controlled and adjusted depending on the strip grade, the strip width, the oxygen content and the flow of the main oxidant.
- the total flow is typically comprised between 5 and 70Nm 3 /h and preferably between 10 and 60Nm 3 /h per lateral side supplied through one or multiple openings.
- the fluid temperature is between 200°C and 50°C below the strip temperature to take again benefit of buoyancy principle.
- the target is 580 - 600°C for a strip at 700°C. Thereby, the inert gas flow also moves down.
- the following simulation illustrates the efficiency of the method and device according to the invention to evenly distribute the oxide layer through the width of the sheet.
- the mass per surface unit of the oxide layer increases from about 30%.
- the oxide uniformity is improved as shown in figure 8 .
- the increase between the value at the center of the strip and the maximum value at the edge of the strip is inferior to 10%.
- the target is an increase inferior to 15% and preferably inferior to 10% between the center of the strip and the maximum value at the edge.
- the right flow and temperature of the main oxidant and of the inert gas need to be adjusted with the strip width and quality processed.
- Each flow is controlled by control valves and flow meters. There is a temperature sensor and the temperature is reached by means of a heat exchanger using gas, electricity or other.
- the total gas injected (oxidant and inert) may be recycled or not.
- the pressure inside the chamber is controlled by means of fluid extraction in the sealing devices but can also be done by the extraction slots when the fluid is not recycled. This allows avoiding an overpressure in the chamber as well as a flow of the oxidant in the other parts of the furnace.
- the extraction flow is adjusted by control of the pressure inside the chamber versus that in the other parts of the furnace.
- a typical flow control may be done in agreement with the PID principle represented in figure 9 .
- the oxide thickness is measured across the strip width by a dedicated system installed after the oxidation section which means outside of the chamber and eventually on each side of the strip.
- the invention has been illustrated and described for an oxidation chamber with transversal openings located at the top of the chamber, the oxidant and the inert gas moving down because their temperatures are inferior to that of the strip.
- the description also covers the configuration with the transversal openings located at the bottom of the oxidation chamber.
- the extraction zones must be disposed at the top of the chamber and the inert gas and the main oxidant must be heated at a temperature superior to that of the strip in order to move up.
- the lateral openings are similarly disposed downstream of the oxidant flow.
Description
- The invention relates to a device and a method for controlling the surface reaction on steel sheets transported in a continuous galvanizing or annealing line.
- High strength steel grades generally comprise high contents of elements like silicon, manganese and chromium (respectively typically between 0.5 and 2%; 1.5 and 6%, 0.3 and 1% in wt) making them difficult to coat because an oxide layer of those elements is formed during the annealing preceding the dipping in the galvanizing bath. This oxide layer harms the wetting ability of the steel surface when submerged in the bath. As a result, uncoated areas and a poor adhesion of the coating are obtained.
- A well-known method to improve the wetting of these steel grades consists in fully oxidizing the steel surface in a specific chamber when the steel has a temperature typically between 600 and 750°C. The resulting oxide layer comprises a high amount of iron oxides which are then reduced during the end of heating and holding section of the annealing furnace and the following thermal treatment. The target is to obtain an oxide thickness between around 50 and 300nm, what corresponds to an iron oxide below 2gr/m2.
- There are different ways to oxidize the steel surface before the reduction step. For example, this oxidation can be performed in a direct fired furnace running the combustion with air excess. Another way consists in making this oxidation in a dedicated chamber located in the middle of the annealing furnace and supplied with a mixture of nitrogen and an oxidant. Such implementation is described in the
patent EP 2 010 690 B1 and infigure 1 . The oxidation section is separated from the other parts of the annealing furnace by seals to minimize the introduction of the oxidant in the first and final sections. - The formation of the oxide layer must be carefully controlled to avoid the formation of too thick or too thin layers. In the first case, the reduction in the final part of the furnace can be incomplete due to lack of time. It is also known that, in that case, the oxide can stick to the furnace rolls and generate defects. In the second case, the oxide layer is not efficient enough since the oxidation of the alloying elements cannot be inhibited sufficiently and thereby the wetting in the liquid metal bath is not sufficiently improved.
- The formation of the oxide layer is guided by three main parameters: strip temperature, oxygen concentration in the atmosphere of the chamber and the transport of that oxygen to the steel surface. Because the edges of the sheet have not the same boundary conditions and turbulence as the center of the sheet, the transport of the oxidant to the edge is different. Similarly to higher edge cooling in the processing line, the oxidation of the edge used to be higher. The width impacted by this over oxidation is in the range from 1 to 10cm, depending on the design of the oxidizing chamber and on the process parameters used.
- To obtain an uniform oxide thickness, it is therefore needed to have a controllable system which can also accommodate the frequent strip width change in a continuous galvanizing line (typically from 900 to 2000cm).
- Mechanical systems can be designed with variable injection sections but this method is not industrially reliable because of the high temperature of the strip and the induced thermal expansion of the material. This becomes a real problem, knowing also that the oxidation chamber can only be used occasionally since all the steel sheets do not need such an oxidation process.
CN 103849825 ,EP-A 2960348 andBE 1014997 - The present invention will be described in even greater detail below based on the exemplary figures. The invention is not limited to the exemplary embodiments. All features described and/or illustrated herein can be used alone or combined in different combinations in embodiments of the invention. The features and advantages of various embodiments of the present invention will become apparent by reading the following detailed description with reference to the attached drawings which illustrate the following:
-
Figure 1 schematically represents an annealing furnace comprising an oxidation section according to the state of the art. -
Figure 2 schematically represents the oxidation chamber according to the invention with the lateral openings for injecting the inert gas. -
Figure 3 represents the upper part of the oxidation chamber according to the invention with the transversal openings for injecting the oxidant. -
Figure 4 represents a transversal opening of the oxidation chamber with a reinforcement according to one embodiment of the invention. -
Figure 5 represents the lower part of the oxidation chamber with extraction openings according to one embodiment of the invention. -
Figure 6 represents the lower part of the oxidation chamber with extraction openings according to another embodiment of the invention. -
Figure 7 represents the evolution of the mass per unit area of the oxide layer through the width of the strip when there is no lateral injection of inert gas. -
Figure 8 represents the evolution of the mass per unit area of the oxide layer through the width of the strip when there is a lateral injection of inert gas. -
Figure 9 represents according to the invention the control means for separately regulating the inert gas flow on each lateral side of the oxidation chamber and the control means for controlling the injection of the oxidant at the top of the oxidation chamber. - The present invention relates to a continuous annealing furnace for annealing steel strips comprising a reaction chamber wherein the steel strips are transported vertically, said chamber comprising openings supplied with a reactant, also called reactant openings, located at the top or at the bottom of the reaction chamber, wherein the reaction chamber further comprises other openings supplied with an inert gas, also called inert gas openings, said inert gas openings being located on the lateral sides of the reaction chamber.
- According to particular preferred embodiments, the furnace according to the invention further discloses at least one or a suitable combination of the following features:
- the inert gas openings are located in such a way as to be downstream of the reactant flow from the reactant openings;
- it comprises one or several inert gas openings on each lateral side of the reaction chamber;
- it comprises means for controlling the flow and the temperature of the inert gas;
- it comprises means for separately controlling the flow of the inert gas on each lateral side of the reaction chamber;
- the reaction chamber comprises extraction openings for avoiding an overpressure inside the reaction chamber, said extraction openings being located in such a way as to be downstream of the reactant flow and of the inert gas flow respectively leaving the reactant openings and the inert gas openings;
- the distance between the lateral sides of the reaction chamber and the edges of the steel strip is comprised between 75 and 220mm, preferably between 100 and 200mm and more preferably is of 100mm;
- the reaction chamber comprises a reactant opening facing each side of the steel strip;
- the reaction chamber is an oxidation chamber and the reactant is an oxidant.
- The invention also relates to a method for controlling a surface reaction on a steel strip running vertically through the reaction chamber of the furnace as described above, comprising a step of injecting laterally an inert gas in the reaction chamber and a step of injecting a reactant upstream of the inert gas flow in said chamber.
- According to particular preferred embodiments, the method according to the invention further discloses at least one or a suitable combination of the following features:
- the reaction chamber is an oxidation chamber and the reactant is an oxidant, the oxygen content of the oxidant being comprised between 0.01 and 8% and preferably between 0.1 and 4% in volume;
- the inert gas flow is comprised between 5 and 70Nm3/h and preferably between 10 and 60Nm3/h;
- the inert gas temperature is between 200 and 50°C below the steel strip temperature when the reaction of the steel strip is performed by injecting the reactant at the top of the reaction chamber and wherein the inert gas temperature is between 200 and 50°C above the steel strip temperature when the reaction of the steel strip is performed by injecting the reactant at the bottom of the reaction chamber;
- there is a step of extracting a gas comprising the inert gas and the reactant, the extracted flow being calculated based on the difference of pressure between the inside of the reaction chamber and the other parts of the furnace.
- Finally, the invention also relates to a steel strip obtained by the method as described above wherein the steel strip has at the exit of the oxidation chamber an oxide layer with an increase of the mass per surface area between the value at the center of the strip and the maximum value at the edge of the strip inferior to 15% and preferably inferior to 10%.
- The invention aims to provide a device and a method to control the surface reaction of the edges of a sheet without mechanical system. The surface reaction can be any reaction that can occur in a section of an annealing furnace like a reduction reaction or a nitriding reaction, the section being supplied with the appropriate reactant. Indeed, the problem of formation of layers with a different thickness on the edges of the sheet exists regardless of the type of reactant. As an example, the method and the device are hereafter illustrated for a surface reaction occurring in an oxidation chamber supplied with an oxidant.
- The annealing furnace comprises an oxidation chamber provided with means for modulating the oxygen concentration of the atmosphere in the regions close to the edges of the sheet. The oxidation chamber according to the invention can be used in a continuous galvanizing line and in a continuous annealing line without hot-dip galvanizing facilities. In this latter case, the uncoated steel sheet can be further pickled to remove the oxide layer formed during annealing.
- The method according to the invention consists in injecting an inert gas with a defined flow and temperature through the sides of the oxidation chamber. To this end and as shown in
figure 2 , theoxidation chamber 2 compriseslateral openings 3 for injecting the inert gas in addition totransversal openings 4 for injecting the oxidant medium, also called oxidant. In this way, the level of the oxidant transversally injected can be either increased or decreased in the edge area depending on the dilution rate resulting from the lateral injection of inert gas. In addition and as detailed below, the oxidation chamber can further comprise openings for extracting the fluid at the opposite side of the transversal openings in order to avoid an overpressure inside the chamber. - According to an embodiment of the invention, the lateral openings of the chamber can be in the form of holes and one, two or more than two holes can be provided in each lateral side of the chamber. According to other embodiments, the openings can be in the form of slots or any form appropriate for injecting a gas.
- In addition, the oxidation chamber can be provided with means for separately controlling the flow of inert gas on each lateral side.
- The transversal openings for injecting the oxidant gas through the chamber are preferably located at the top of the chamber for reasons explained below. An opening is located on each side of the sheet. According to an embodiment of the invention shown in
figure 3 , thetransversal openings 4 are in the form of slots but they can have other shapes according to other embodiments. In addition, theopening 4 can be provided withreinforcement 6 to keep the opening geometry constant as represented infigure 4 . - On the opposite side of the transversal openings, i.e. at the bottom of the oxidation chamber if the oxidant injection is carried out at the top, the chamber comprises
extraction openings 7 to reduce the pressure inside the chamber when the fluid is not recycled. They can be in the form of slots on each side of the sheet as shown infigure 5 or be round, square or rectangular openings as represented infigure 6 . - The chamber further comprises rolls or similar sealing system at its entry and exit to separate the atmosphere of this chamber from the rest of the annealing furnace and so to minimize the flow of the oxidant in the other parts of the furnace. For sake of simplicity, only half of the
rolls 8 being closest to the chamber are represented infigures 3 ,5 . Moreover, the chamber is heat insulated but if required some heating devices can be added to compensate for heat losses.et 6 - As an example, typical dimensions of the oxidation chamber are the following. It is between 3 and 5m long with a width that it is about 150mm wider than the maximal strip width to run. A typical design is 2m wide for a maximal strip width of 1850mm. The minimal distance between the casing of the oxidation chamber and the strip is from 75 to 220mm, preferably from 100 to 200mm and more preferably of 100mm.
- As shown in
figure 2 , thesteel sheet 5 passes vertically through theoxidation chamber 2. The sheet can move up or down depending on the global furnace layout. The oxidant gas composed of a mixture of N2 and O2 with an oxygen content between 0.01 and 8% and preferably between 0.1 and 4% in volume is injected through thetransversal openings 4. The flow, the temperature and the concentration of the oxidant is controlled. The flow per side is typically comprised between 150 and 250Nm3/h for a slot with 10mm opening and 2m long. The temperature of the mixture N2+O2 is between 200°C and 50°C below the strip temperature to take benefit of the buoyancy principle. Preferably, the mixture temperature is between 580 and 600°C for a strip at 700°C. The gas colder than the strip moves down and, for this reason, the transversal openings are located at the top of the chamber. Because the oxygen is not consumed in the area next to the sides of the chamber and being outside of the strip edges, the concentration of O2 is higher in those parts resulting in a thicker oxide layer on the edges of the sheets compared to the central part of the sheet. This is especially true on narrow sheets. To solve this problem, a small amount of pure inert gas like N2 or Ar is injected downstream of the oxidant injection via the lateral openings of the chamber. The flow rate and temperature of the inert gas is controlled and adjusted depending on the strip grade, the strip width, the oxygen content and the flow of the main oxidant. The total flow is typically comprised between 5 and 70Nm3/h and preferably between 10 and 60Nm3/h per lateral side supplied through one or multiple openings. The fluid temperature is between 200°C and 50°C below the strip temperature to take again benefit of buoyancy principle. Preferably, the target is 580 - 600°C for a strip at 700°C. Thereby, the inert gas flow also moves down. - The following simulation illustrates the efficiency of the method and device according to the invention to evenly distribute the oxide layer through the width of the sheet.
- Typical FeO formation on a 1050mm wide strip of specific composition at 700°C running at 120mpm in an oxidation chamber being three meter long and two meters wide, with an oxidant flow of 160Nm3/h per side at 600°C and comprising 1%O2 is represented in
figure 7 . On the edges of the sheet, the mass per surface unit of the oxide layer increases from about 30%. - For similar conditions but with an injection of 40Nm3/h of inert gas at 600°C on each lateral side of the chamber, the oxide uniformity is improved as shown in
figure 8 . In this case, the increase between the value at the center of the strip and the maximum value at the edge of the strip is inferior to 10%. According to the invention, the target is an increase inferior to 15% and preferably inferior to 10% between the center of the strip and the maximum value at the edge. - As already mentioned, for correct efficiency, the right flow and temperature of the main oxidant and of the inert gas need to be adjusted with the strip width and quality processed.
- Each flow is controlled by control valves and flow meters. There is a temperature sensor and the temperature is reached by means of a heat exchanger using gas, electricity or other. The total gas injected (oxidant and inert) may be recycled or not. The pressure inside the chamber is controlled by means of fluid extraction in the sealing devices but can also be done by the extraction slots when the fluid is not recycled. This allows avoiding an overpressure in the chamber as well as a flow of the oxidant in the other parts of the furnace. The extraction flow is adjusted by control of the pressure inside the chamber versus that in the other parts of the furnace. A typical flow control may be done in agreement with the PID principle represented in
figure 9 . The oxide thickness is measured across the strip width by a dedicated system installed after the oxidation section which means outside of the chamber and eventually on each side of the strip. - The invention has been illustrated and described for an oxidation chamber with transversal openings located at the top of the chamber, the oxidant and the inert gas moving down because their temperatures are inferior to that of the strip. The description also covers the configuration with the transversal openings located at the bottom of the oxidation chamber. In this case, the extraction zones must be disposed at the top of the chamber and the inert gas and the main oxidant must be heated at a temperature superior to that of the strip in order to move up. The lateral openings are similarly disposed downstream of the oxidant flow.
- While the invention has been illustrated and described in detail in the drawings and foregoing description, such illustration and description are to be considered illustrative or exemplary and not restrictive. It will be understood that changes and modifications may be made by those of ordinary skill within the scope of the following claims. In particular, the present invention covers further embodiments with any combination of features from different embodiments described above and below.
- The terms used in the claims should be construed to have the broadest reasonable interpretation consistent with the foregoing description. For example, the use of the article "a" or "the" in introducing an element should not be interpreted as being exclusive of a plurality of elements. Likewise, the recitation of "or" should be interpreted as being inclusive, such that the recitation of "A or B" is not exclusive of "A and B," unless it is clear from the context or the foregoing description that only one of A and B is intended.
-
- (1) Annealing furnace
- (2) Reaction section, also called reaction chamber, and, in particular, oxidation section or chamber
- (3) Lateral opening for injecting the inert gas, also called inert gas opening
- (4) Transversal opening for injecting the reactant, and in particular the oxidant, also called reactant opening
- (5) Strip or sheet
- (6) Reinforcement in the transversal opening
- (7) Extraction opening
- (8) Sealing roll
- (9) Zinc bath
- (10) Heating means
- (11) Valve
Claims (15)
- A continuous annealing furnace (1) for annealing steel strips (5) comprising a reaction chamber (2) wherein the steel strips (5) are transported vertically, said chamber (2) comprising openings (4) supplied with a reactant, also called reactant openings, located at the top or at the bottom of the reaction chamber (2),
wherein the reaction chamber (2) further comprises other openings (3) supplied with an inert gas, also called inert gas openings, said inert gas openings (3) being located on the lateral sides of the reaction chamber (2). - A furnace according to claim 1, wherein the inert gas openings (3) are located in such a way as to be downstream of the reactant flow from the reactant openings (4).
- A furnace according to any of the previous claims, comprising one or several inert gas openings (3) on each lateral side of the reaction chamber (2).
- A furnace according to any of the previous claims, comprising means for controlling the flow and the temperature of the inert gas.
- A furnace according to any of the previous claims, comprising means for separately controlling the flow of the inert gas on each lateral side of the reaction chamber (2).
- A furnace according to any of the previous claims, wherein the reaction chamber (2) comprises extraction openings (7) for avoiding an overpressure inside the reaction chamber (2), said extraction openings (7) being located in such a way as to be downstream of the reactant flow and of the inert gas flow respectively leaving the reactant openings (4) and the inert gas openings (3).
- A furnace according to any of the previous claims, wherein the distance between the lateral sides of the reaction chamber (2) and the edges of the steel strip (5) is comprised between 75 and 220mm, preferably between 100 and 200mm and more preferably is of 100mm.
- A furnace according to any of the previous claims, wherein the reaction chamber (2) comprises a reactant opening (4) facing each side of the steel strip (5).
- A furnace according to any of the previous claims, wherein the reaction chamber (2) is an oxidation chamber and the reactant is an oxidant.
- Method for controlling a surface reaction on a steel strip (5) running vertically through the reaction chamber (2) of the furnace (1) according to any of the previous claims, comprising a step of injecting laterally an inert gas in the reaction chamber (2) and a step of injecting a reactant upstream of the inert gas flow in said chamber (2).
- Method according to claim 10, wherein the reaction chamber (2) is an oxidation chamber and the reactant is an oxidant, the oxygen content of the oxidant being comprised between 0.01 and 8% and preferably between 0.1 and 4% in volume.
- Method according to claim 10 or 11, wherein the inert gas flow is comprised between 5 and 70Nm3/h and preferably between 10 and 60Nm3/h.
- Method according to any previous claims 10 to 12, wherein the inert gas temperature is between 200 and 50°C below the steel strip temperature when the reaction of the steel strip (5) is performed by injecting the reactant at the top of the reaction chamber (2) and wherein the inert gas temperature is between 200 and 50°C above the steel strip temperature when the reaction of the steel strip (5) is performed by injecting the reactant at the bottom of the reaction chamber (2).
- Method according to any of previous claims 10 to 13, wherein there is a step of extracting a gas comprising the inert gas and the reactant, the extracted flow being calculated based on the difference of pressure between the inside of the reaction chamber (2) and the other parts of the furnace (1).
- Steel strip (5) obtained by the method according to any previous claims 11 to 14 wherein the steel strip (5) has at the exit of the oxidation chamber (2) an oxide layer with an increase of the mass per surface area between the value at the center of the strip and the maximum value at the edge of the strip inferior to 15% and preferably inferior to 10%.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15183169.0A EP3135778B1 (en) | 2015-08-31 | 2015-08-31 | Method and device for reaction control |
ES15183169.0T ES2689732T3 (en) | 2015-08-31 | 2015-08-31 | Procedure and device for reaction control |
CA2979814A CA2979814C (en) | 2015-04-02 | 2016-03-23 | Method and device for reaction control |
RU2017134711A RU2705846C2 (en) | 2015-04-02 | 2016-03-23 | Reaction control method and device |
PCT/EP2016/056305 WO2016156125A1 (en) | 2015-04-02 | 2016-03-23 | Method and device for reaction control |
CN201680017728.2A CN107429309B (en) | 2015-04-02 | 2016-03-23 | Annealing furnace, method for controlling surface reactions on a steel strip and steel strip |
JP2017549770A JP6792561B2 (en) | 2015-04-02 | 2016-03-23 | Methods and equipment for reaction control |
US15/561,525 US10801086B2 (en) | 2015-04-02 | 2016-03-23 | Method and device for reaction control |
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EP15183169.0A EP3135778B1 (en) | 2015-08-31 | 2015-08-31 | Method and device for reaction control |
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EP3135778B1 true EP3135778B1 (en) | 2018-07-11 |
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AU509460B2 (en) * | 1976-12-23 | 1980-05-15 | Armco Steel Corporation | Treating steel strip prior to metal coating |
BE1014997A3 (en) * | 2001-03-28 | 2004-08-03 | Ct Rech Metallurgiques Asbl | Continuous annealing of steel strip prior to galvanising using direct flame preheating to form an oxide film followed by full annealing and reduction stages to mature this oxide film |
CA2647687C (en) | 2006-04-26 | 2012-10-02 | Thyssenkrupp Steel Ag | Hot dip coating process for a steel plate product made of high strengthheavy-duty steel |
JP5505461B2 (en) * | 2012-05-24 | 2014-05-28 | Jfeスチール株式会社 | Continuous annealing furnace for steel strip, continuous annealing method for steel strip, continuous hot dip galvanizing equipment and method for manufacturing hot dip galvanized steel strip |
JP5884748B2 (en) * | 2013-02-25 | 2016-03-15 | Jfeスチール株式会社 | Steel strip continuous annealing equipment and continuous hot dip galvanizing equipment |
CN103849825B (en) * | 2014-03-05 | 2016-03-02 | 首钢总公司 | The flexible preoxidation device and method of a kind of continuous hot galvanizing line |
-
2015
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