EP3092672A1 - Flow-guiding plate for a fuel cell - Google Patents
Flow-guiding plate for a fuel cellInfo
- Publication number
- EP3092672A1 EP3092672A1 EP15702522.2A EP15702522A EP3092672A1 EP 3092672 A1 EP3092672 A1 EP 3092672A1 EP 15702522 A EP15702522 A EP 15702522A EP 3092672 A1 EP3092672 A1 EP 3092672A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- flow
- flow channels
- face
- plate
- channels
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 50
- 239000012528 membrane Substances 0.000 claims description 32
- 238000009792 diffusion process Methods 0.000 claims description 14
- 230000000712 assembly Effects 0.000 claims description 4
- 238000000429 assembly Methods 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 229910000851 Alloy steel Inorganic materials 0.000 claims description 2
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 2
- 229910001362 Ta alloys Inorganic materials 0.000 claims description 2
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 2
- 230000000295 complement effect Effects 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 24
- 239000002184 metal Substances 0.000 description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 16
- 239000007800 oxidant agent Substances 0.000 description 15
- 230000001590 oxidative effect Effects 0.000 description 10
- 239000012530 fluid Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000004891 communication Methods 0.000 description 7
- 239000002826 coolant Substances 0.000 description 7
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000012809 cooling fluid Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 102100025532 Male-enhanced antigen 1 Human genes 0.000 description 1
- 102100034256 Mucin-1 Human genes 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000002047 photoemission electron microscopy Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0206—Metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
- H01M8/0254—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form corrugated or undulated
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
- H01M8/0265—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant the reactant or coolant channels having varying cross sections
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the invention relates to fuel cells, and in particular fuel cells comprising an alternation of proton exchange membranes and bipolar plates.
- Fuel cells are envisaged as a power supply system for large scale motor vehicles in the future, as well as for a large number of applications.
- a fuel cell is an electrochemical device that converts chemical energy directly into electrical energy.
- a fuel such as dihydrogen or methanol is used as the fuel of the fuel cell.
- dihydrogen In the case of dihydrogen, it is oxidized and ionized on one electrode of the cell and an oxidizer is reduced on another electrode in the cell.
- the chemical reaction produces water at the cathode, with oxygen being reduced and reacting with the protons.
- the great advantage of the fuel cell is that it avoids releases of atmospheric pollutants at the place of generation.
- Proton exchange membrane fuel cells operate at low temperatures and have particularly advantageous compactness properties.
- Each cell comprises an electrolyte membrane allowing only the passage of protons and not the passage of electrons.
- the membrane comprises an anode on a first face and a cathode on a second face to form a membrane / electrode assembly called AME.
- dihydrogen is ionized to produce protons crossing the membrane.
- the electrons produced by this reaction migrate to a flow plate and then pass through an electrical circuit external to the cell to form an electric current.
- oxygen is reduced and reacts with the protons to form water.
- the fuel cell may comprise several so-called bipolar plates, for example made of metal, stacked on top of one another.
- the membrane is disposed between two bipolar plates.
- Bipolar plates may include channels and outlets for guiding reagents and products to / from the membrane, guiding coolant, and separating different compartments.
- Bipolar plates are also electrically conductive to form collectors of electrons generated at the anode.
- Bipolar plates also have a mechanical function of transmission of clamping forces of the stack, necessary to the quality of the electrical contact. Gaseous diffusion layers are interposed between the electrodes and the bipolar plates and are in contact with the bipolar plates.
- the bipolar plates continuously feed the reactive surfaces of the electrodes into reagents, as and when they are consumed.
- the distribution of the reagents to the electrodes should be as homogeneous as possible over their entire surface.
- the bipolar plates comprise networks of flow channels ensuring the distribution of reagents.
- a network of flow channels is dedicated to the anode fluid, and a network of flow channels is dedicated to the cathodic fluid.
- the networks of anode and cathode flow channels are never in communication inside the cell, in order to avoid the direct combustion of the fuel and the oxidant. Reaction products and non-reactive species are flow-stripped to the outlet of the distribution channel networks.
- the bipolar plates have flow channels through which cooling fluid flows, allowing the evacuation of the heat generated.
- the serpentine channels one or more channels traverse the entire active surface in several round trips.
- the parallel channels a bundle of parallel and through channels runs through the active surface from one side to the other.
- the interdigital channels a bundle of parallel and clogged channels runs through the active surface from one side to the other. Each channel is clogged either on the inlet side or the fluid outlet side. The fluid entering a channel is then forced to pass locally through the gas diffusion layer to join an adjacent channel and then reach the fluid outlet of this adjacent channel.
- the flow channels may be rectilinear or slightly wavy.
- the most commonly used materials for bipolar plates are the carbon-polymer composite and the stamped metal.
- the stamped metal proves to be a solution favoring the lightening and the compactness of the piles.
- the bipolar plates then use thin metal sheets, for example stainless steel.
- the flow channels are obtained by stamping. Most frequently, a first flow plate is used in the form of a first stamped sheet defining the anode flow channel and a second flow plate in the form of a second pressed sheet defining the cathodic flow channel. These two plates of the flow plates are joined back to back by welding to form a bipolar plate. A cooling fluid flow channel is provided in the space between the sheets.
- the carbon-polymer composite technology allows for greater flexibility in designing flow channels by molding thicker plates.
- FR2973583 proposes to remove the coolant channel in a bipolar plate out of two.
- the bipolar plate devoid of coolant channel includes a single stamped sheet, which lighten the fuel cell.
- the cathodic flow channels are formed on a first face of the sheet, while the anodic flow channels are formed on the other face of the sheet.
- the passage section in the anode channels must be lower than that in the cathode channels in order to obtain a pressure drop of the same order of magnitude. Indeed, the hydrogen is less viscous than the oxidant circulating at the cathode and its flow is lower.
- the molar flow rate of dihydrogen consumed in a cell is equal to I /, I being the electric current produced and F the Faraday constant.
- the molar flow of air consumed is equal to 1 .2 * I / F.
- the fuel and oxidant rates introduced into the cells are always greater than the flow rates consumed, according to a factor of increase.
- the mark-up factor is generally between 1 and 2.5.
- the increase factor is generally between 1.2 and 3, to ensure a sufficient amount of oxygen output.
- the ratio between the molar flow rates of air and of hydrogen is at least 2, and most commonly between 3 and 5.
- the viscosity of the wet dihydrogen is of the order of 8 * 10-6 to 1 3 * 1 0 6
- the viscosity of moist air is of the order of 1 2 * 1 0 "6 to 21 * 1 0 " 6 Pa.s.
- the invention aims to solve one or more of these disadvantages.
- the invention aims in particular to allow the use of the same sheets for a bipolar plate with a single flow plate and for a bipolar plate with double flow plates, without anodic and cathodic flow disparities for these two types of bipolar plates. , and promoting a homogenization of the charge losses between the anode channels and the cathode channels.
- the invention thus relates to a fuel cell flow guide plate as defined in the appended claims.
- the invention further relates to a fuel cell as defined in the appended claims.
- FIG 1 is an exploded perspective view of an example of a fuel cell
- FIG. 2 is a perspective view of flow channels on a first face of a first embodiment of a metal sheet for a fuel cell flow plate;
- FIG. 3 is a view from above of the first face of the metal sheet of FIG. 2;
- FIG. 4 is a cross-sectional view of the metal sheet of FIG. 2 at access ports to flow channels;
- FIG 5 is a cross-sectional view of the metal sheet of Figure 2 in its middle part
- FIG. 6 is a cross-sectional view of the metal sheet of FIG. 2 at a second end of the flow channels;
- FIGS. 7 and 8 are perspective views of the second face of the sheet of FIG. 2, at the access orifices to the flow channels;
- FIG 9 is a cross-sectional view of a fuel cell including different bipolar plates formed from metal sheets of Figure 2;
- FIGS. 10 to 13 illustrate different longitudinal sectional views of the fuel cell of FIG. 9;
- FIGS. 14 and 15 are perspective views of the first face of second and third embodiments of metal sheets
- FIG. 16 is a cross-sectional view of a variant of the first embodiment of a metal sheet at access orifices to the flow channels.
- Figure 1 is a schematic exploded perspective view of a stack of cells 1 of a fuel cell 4.
- the fuel cell 4 comprises a plurality of cells 1 superimposed.
- the cells 1 are of the proton exchange membrane or polymer electrolyte membrane type.
- the fuel cell 4 comprises a fuel source 40.
- the fuel source 40 supplies an inlet of each cell 1 with dihydrogen.
- the fuel cell 4 also comprises a source of oxidant 42.
- the source of oxidant 42 supplies an inlet of each cell 1 with air, the oxygen of the air being used as an oxidizer.
- Each cell 1 also includes exhaust channels.
- Each cell 1 also has a cooling circuit.
- Each cell 1 comprises a membrane / electrode assembly 1 1 0 or
- a membrane / electrode assembly 1 1 0 comprises an electrolyte 1 13, a cathode 1 1 2 (not shown in Figure 1) and an anode 1 1 1 placed on either side of the electrolyte and fixed on this electrolyte 1 1 3.
- the fuel cell 4 here comprises alternating bipolar plates 51 and 52.
- the bipolar plates 51 include a flow plate formed of a single metal sheet or foil 53.
- a bipolar plate 51 the relief of a first face of its metal sheet defines the anodic flow channels, and the relief of a second face of its metal sheet defines the cathodic flow channels.
- Bipolar plates 52 include two flow plates 53. Each of these flow plates 53 includes a metal sheet or sheet. The sheets are superimposed and fixed together by means of welds 54.
- the relief of a face of a first flow plate 53 defines the anodic flow channels and the relief of a face a flow plate 53 defines the cathodic flow channels.
- a coolant flow channel is provided between the metal plates of the flow plates 53 of a bipolar plate 52.
- the metal sheets forming the flow plates 53 of a bipolar plate 52 are identical.
- the metal sheets forming the flow plates 53 of the bipolar plates 51 and 52 are identical.
- the metal sheets are for example formed of stainless steel, of alloy steel, of titanium alloy, aluminum alloy, nickel alloy or tantalum alloy.
- dihydrogen flows in an anode flow conduit between a bipolar plate and a 1 1 1 anode;
- a cell of the fuel cell usually generates a DC voltage between its anode and its cathode of the order of 1 V.
- the catalyst material used at the anode 11 1 advantageously includes platinum, for its excellent performance. catalyst.
- FIG 2 is a perspective view of anodic side flow channels of a first embodiment of a conductive sheet of a flow guide plate 53 according to the invention.
- Figure 3 is a top view of the plate 53.
- Such a flow guide plate 53 can be used to form different types of bipolar plates, as detailed below.
- the plate 53 has a first face 55 illustrated in FIG. 2 and a second face 56.
- the relief of the flow guide plate 53 defines an alternation of flow channels on the opposite faces 55 and 56.
- two channels successive flow of the same face of the plate 53 are separated by walls 559 delimiting a flow channel of the other face.
- the flow channels of the faces 55 and 56 extend in the same longitudinal direction. In this example, the flow channels are substantially straight.
- the flow channels are split into first and second groups.
- Access ports 551 open into flow channels 553 of the first group.
- the access ports 551 are disposed at a first end of the flow channels 553.
- a first flat portion 535 forms a flow guide surface extending between the various access ports 551.
- An inclined wall 557 forms a junction between an access orifice
- a second flat portion 536 forms a flow guiding surface extending between the various access ports 552.
- An inclined wall 558 forms a junction between the access ports 552 and the middle portion of their flow channel 553. .
- each flow channel 553 in its middle portion, between its access ports 551 and 552, is greater than the cross section at the access ports 551 and 552.
- the inclined walls 557 and 558 are thus extend in depth to a flat bottom of the flow channel 553.
- the middle portion of the flow channels 553 is thus devoid of flow restriction.
- the face 55 has flow channels 554 of the second group.
- the face 55 comprises an alternation of flow channels 553 and 554 in a transverse direction.
- the flow channels 554 have a wall 556 at their first end and a wall 555 at their second end.
- Each wall 555 extends from the bottom of a flow channel 554 to the top of the flat portion 536.
- Each wall 556 extends from the bottom of a flow channel 554 to the top of the
- the cross section of the flow channels 554 at the walls 555 and 556 is smaller than the cross section of the access ports 551 and 552 to the flow channels of the first group.
- Each of these walls 555 and 556 thus forms a flow restriction of a flow channel 554.
- Each flow channel 554 thus has at least one flow restriction.
- the passage section of a flow restriction is defined as the cross section of the flow channel at this flow restriction.
- the walls 555 and 556 extend here to the top of their flow channel 554 and to the bottom of the flow channels 563 of the face 56 detailed thereafter.
- FIGS. 7 and 8 illustrate in perspective the first ends of two types of access orifices 561 to the channels 56. flow 563.
- Each flow channel 563 is delimited with respect to the flow channels 553 and 554 of the face 55 through walls 559.
- the flow channels 553 and 554 comprise respective bottoms 565 and 566 intended to form, for example, cathodic conduction contacts at the face 56.
- each flow channel 563 in its middle portion is greater than the cross section at these access ports. Inclined walls thus extend in depth from an access port to a flat bottom of their flow channel 563.
- the middle portion of the flow channels 563 is thus devoid of flow restriction.
- two successive flow channels 563 are in communication at each of their ends, because of the passages formed to arrange the walls 555 and 556 at the access ports. Consequently, any dispersions of pressure drops between two successive channels 563 can be homogenized by such a communication.
- Fig. 4 is a cross-sectional view of the plate 53 in the flat portion 535.
- Fig. 5 is a cross-sectional view of the plate 53 in the middle portion of the flow channels.
- Figure 6 is a cross-sectional view of the plate 53 at the access ports 552.
- the flat portion 535 extends between the access ports of the first end of the flow channels 563.
- the flat portion 535 thus forms a tundish between the flow channel access ports 563 at that first end. .
- the flat portion 536 extends between the access ports of the second end of the flow channels 563.
- the flat portion 536 thus forms a splitter between the flow channel access ports 563 at this second end. .
- the walls 559 provide a separation between the flow channels of the two faces.
- the bottom of a channel 563 is thus disposed at the top a channel 553 or 554, and vice versa.
- the bottoms of the various flow channels are intended to form conductive surfaces for collecting the electric current to pass through the guide plates 53.
- the access ports to the flow channels 563 have the same section at both ends of these flow channels.
- the access orifices 562 of the second end of the flow channels 563 are illustrated in FIG. 6. These access orifices 562 here have a height corresponding to half the height of the channels 563. The assembly of two plates guide 53 in a stack of fuel cell cells 4 is thus facilitated.
- the plate 53 is here formed of a metal sheet pressed to give it a relief.
- the shape of the face 55 is therefore the complementary or the negative of the shape of the face 56.
- the plate 53 may for example be made by stamping a metal sheet.
- the flow channels 553 and 554 have the same cross section over at least 75% of their median portion.
- the bottom of the flow channels 554 provides a very large area for collecting cathodic current as appropriate.
- the flow channels 553, 554 and 563 have an identical cross section in their middle part. Consequently, these channels may have the minimum width corresponding to their formation technology, and this in order to optimize the homogeneity of distribution of the current through the bipolar plate to be formed. Furthermore, the use of the same cross sections for the two-sided flow channels facilitates the assembly of two flow guiding plates 53 to form a bipolar plate.
- the flat portions 535 and 536 are placed at the same height and the flow channels 553, 554 and 563 have the same depth with respect to these flat portions 535 and 536.
- the access ports 551 are intended to communicate with an opening 40 formed through the flat portion 535.
- the access orifices at the first end of the flow channels 563 are intended to communicate with an opening 43 formed through the flat portion 535.
- the openings 40 and 43 are intended to be isolated from each other by means of joints, in a manner known per se.
- the access ports 552 are intended to communicate with an opening 41 formed through the flat portion 536.
- the access orifices 562 at the second end of the channels 563 are intended to communicate with an opening 42 formed through the flat portion 536.
- the openings 41 and 42 are intended to be isolated from each other by means of joints, in a manner known per se.
- Fig. 9 is a cross-sectional view of an example of a fuel cell 4 using flow guide plates 53 as detailed above.
- the fuel cell 4 comprises membrane / electrode assemblies 1 1, 12 and 13. Each membrane / electrode assembly here comprises a gas diffusion layer 21 placed in contact with an anode 11 1.
- the anode 11 1 is fixed on a proton exchange membrane 1 13.
- a cathode 12 is fixed on the proton exchange membrane 1 13.
- a gaseous diffusion layer 22 is placed in contact with the cathode 1 12.
- the fuel cell 4 further comprises flow guide plates 531, 532 and 533 as detailed with reference to FIGS. 1 to 8.
- the flow guide plate 531 here in itself forms a bipolar plate 51 disposed between the membrane / electrode assembly 11 and the membrane / electrode assembly 12.
- the bottom wall of the flow channels 563 is here in contact with the gas diffusion layer 21 of the membrane / electrode assembly 12.
- the bottom wall of the flow channels 553 and 554 is here in contact with the gas diffusion 22 of the membrane / electrode assembly 1 1.
- the flow guide plates 532 and 533 here form a bipolar plate 52 disposed between the membrane / electrode assembly 12 and the membrane / electrode assembly 13.
- the bottom wall of the flow channels 563 of the plate 532 is here placed in contact with the bottom wall 566 of the flow channels 554 of the plate 533.
- the plate 532 can be fixed to the plate 533 by means of welds (not illustrated) promoting electrical conduction between the plates 532 and 533 .
- the bottom wall of the flow channels 554 of the plate 532 is here in contact with the gas diffusion layer 22 of the membrane / electrode assembly 12.
- the bottom wall of the flow channels 563 of the plate 533 is here in contact with the gas diffusion layer 21 of the membrane / electrode assembly 13.
- the geometry of an object is usually defined by the shape of an object or its morphological characteristics.
- the flow channels 563 of the plate 531 are intended to be traversed by oxidant, for example air.
- the flow channels 553 of the plate 531 are intended to be traversed by fuel, for example dihydrogen.
- the flow channels 554 are not intended to be traversed by a flow (or marginally by flow through the diffusion layers) due to the presence of flow restrictions, despite the same cross-sectional area. flow channels 553 and 554 over most of their middle part. For the same flow conditions, the pressure drop across the flow channels of the face 55 is greater than the pressure drop across the flow channels of the face 56.
- the flow channels 563 of the plate 532 are intended to be traversed by oxidant.
- the flow channels 553 of the plate 533 are intended to be traversed by fuel.
- the flow channels 554 of the plate 533 are not intended to be traversed by fuel, due to the presence of flow restrictions.
- the pressure losses for the fuel are therefore identical for the two types of bipolar plates 51 and 52.
- the pressure drops for the oxidant are also identical for the two types of bipolar plates.
- the flow of gas is between an inlet and an outlet of the same flow channel 563.
- the flow is here of the parallel type.
- the flow of gas takes place between an inlet and an outlet of the same flow channel 553.
- the flow is here of the parallel type.
- the bipolar plate formed of the plates 532 and 533 comprises a flow circuit 57 intended to be traversed by coolant. In order to lighten the bipolar plate formed of the plate 531, it is devoid of coolant flow circuit.
- Figures 10 to 13 are longitudinal sectional views for illustrating different flow of fluids through the bipolar plates 51 and 52.
- the dashed flows correspond to flows of coolant.
- Discontinuous flows correspond to fuel flows.
- Solid flows correspond to flows of oxidizer.
- axis of symmetry is typically perpendicular to a median plane of the plate.
- Fig. 14 is a perspective view of anodic side flow channels of a second embodiment of a conductive sheet of a flow guide plate 53 according to the invention.
- This second embodiment is distinguished from the first embodiment by the presence of additional flow restrictions in the flow channels 554. Additional walls 555 are thus arranged to close the middle portion of the flow channels 554.
- FIG. 15 is a perspective view of anodic side flow channels of a third embodiment of a conductive sheet of a flow guide plate 53 according to the invention.
- This third embodiment is distinguished from the second embodiment by the absence of flow restrictions at the ends of the flow channels 554. Flow restrictions are here provided in the middle portion of the flow channels 554. Additional walls 555 are thus arranged to close off the median portion of the flow channels 554.
- FIG. 16 is a sectional view of a variant of a flow plate
- the flow plate 53 differs from that of the variant of FIGS. 1 to 8 by the geometry of the walls 555 and 556.
- the walls 555 and 556 do not extend to the top of their flow channel 554 (or not extend to the bottom of the 563 flow channels interposed). Therefore, a flow can pass through a flow channel 554 by surmounting the walls 555 and 556, but with pressure drops much greater than the pressure losses through a flow channel 553.
- the walls 555 and 556 are extend at least up to three-quarters of the depth of the flow channels 563 of the face 56.
- the flow channels have a rectilinear shape in the longitudinal direction.
- other geometries of flow channels may be provided, for example flow channels having corrugations along their longitudinal direction.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1450065A FR3016243B1 (en) | 2014-01-07 | 2014-01-07 | FLOW GUIDE PLATE FOR FUEL CELL |
PCT/FR2015/050013 WO2015104492A1 (en) | 2014-01-07 | 2015-01-06 | Flow-guiding plate for a fuel cell |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3092672A1 true EP3092672A1 (en) | 2016-11-16 |
EP3092672B1 EP3092672B1 (en) | 2017-10-18 |
Family
ID=50231435
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15702522.2A Active EP3092672B1 (en) | 2014-01-07 | 2015-01-06 | Flow-guiding plate for a fuel cell |
Country Status (5)
Country | Link |
---|---|
US (2) | US10170774B2 (en) |
EP (1) | EP3092672B1 (en) |
JP (1) | JP6556733B2 (en) |
FR (1) | FR3016243B1 (en) |
WO (1) | WO2015104492A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3016243B1 (en) * | 2014-01-07 | 2016-02-05 | Commissariat Energie Atomique | FLOW GUIDE PLATE FOR FUEL CELL |
FR3016242B1 (en) * | 2014-01-07 | 2016-02-05 | Commissariat Energie Atomique | FLOW GUIDE PLATE FOR FUEL CELL |
FR3040549B1 (en) * | 2015-08-26 | 2017-09-15 | Commissariat Energie Atomique | STACK OF ELECTROCHEMICAL CELLS DISTRIBUTED IN DISTINCT GROUPS COMPRISING A HOMOGENEOUS COMPARTMENT |
JP7202226B2 (en) * | 2019-03-13 | 2023-01-11 | 株式会社豊田中央研究所 | fuel cell system |
CN110247075B (en) * | 2019-06-17 | 2023-08-11 | 珠海格力电器股份有限公司 | Double-plate device and fuel cell with same |
SE544864C2 (en) * | 2020-12-18 | 2022-12-13 | Powercell Sweden Ab | Fuel cell assembly |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3400976B2 (en) * | 2000-07-07 | 2003-04-28 | 新日本製鐵株式会社 | Separator for polymer electrolyte fuel cell and fuel cell |
US6544681B2 (en) * | 2000-12-26 | 2003-04-08 | Ballard Power Systems, Inc. | Corrugated flow field plate assembly for a fuel cell |
JP4304955B2 (en) * | 2002-10-23 | 2009-07-29 | 日産自動車株式会社 | Solid polymer electrolyte fuel cell |
JP2005032578A (en) * | 2003-07-04 | 2005-02-03 | Nissan Motor Co Ltd | Separator for fuel cell, fuel cell, and fuel cell vehicle |
US6997824B2 (en) * | 2003-08-06 | 2006-02-14 | Cranman Roy M | Golf ball mark repair tool |
US7462415B2 (en) * | 2003-09-24 | 2008-12-09 | General Motors Corporation | Flow field plate arrangement for a fuel cell |
JP2006114386A (en) * | 2004-10-15 | 2006-04-27 | Toyota Motor Corp | Fuel cell |
JP4823550B2 (en) * | 2005-04-07 | 2011-11-24 | 本田技研工業株式会社 | Fuel cell, fuel cell manufacturing method, and fuel cell separator |
JP5077620B2 (en) * | 2005-12-16 | 2012-11-21 | トヨタ自動車株式会社 | Fuel cell separator |
JP5181634B2 (en) * | 2006-12-04 | 2013-04-10 | トヨタ自動車株式会社 | Fuel cell |
JP5180484B2 (en) * | 2007-02-01 | 2013-04-10 | 本田技研工業株式会社 | Fuel cell stack |
WO2009067617A1 (en) * | 2007-11-20 | 2009-05-28 | Bdf Ip Holdings Ltd. | Fuel cell flow field plate assembly |
WO2010080080A1 (en) * | 2009-01-08 | 2010-07-15 | Utc Power Corporation | Multiple transition flow field and method |
JP5261440B2 (en) * | 2010-06-07 | 2013-08-14 | 本田技研工業株式会社 | Fuel cell stack |
FR2973583B1 (en) | 2011-03-30 | 2014-03-14 | Peugeot Citroen Automobiles Sa | FUEL CELL COMPRISING A STACK OF CELLS AND BIPOLAR CONDUCTIVE PLATES |
KR101367394B1 (en) * | 2011-05-26 | 2014-02-24 | 도요타 지도샤(주) | Separator for fuel cell and fuel cell |
FR3016243B1 (en) * | 2014-01-07 | 2016-02-05 | Commissariat Energie Atomique | FLOW GUIDE PLATE FOR FUEL CELL |
FR3016242B1 (en) * | 2014-01-07 | 2016-02-05 | Commissariat Energie Atomique | FLOW GUIDE PLATE FOR FUEL CELL |
-
2014
- 2014-01-07 FR FR1450065A patent/FR3016243B1/en not_active Expired - Fee Related
-
2015
- 2015-01-06 WO PCT/FR2015/050013 patent/WO2015104492A1/en active Application Filing
- 2015-01-06 EP EP15702522.2A patent/EP3092672B1/en active Active
- 2015-01-06 JP JP2016544620A patent/JP6556733B2/en active Active
- 2015-01-06 US US15/110,127 patent/US10170774B2/en active Active
-
2018
- 2018-11-30 US US16/206,529 patent/US10680255B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
FR3016243A1 (en) | 2015-07-10 |
US20190097246A1 (en) | 2019-03-28 |
JP6556733B2 (en) | 2019-08-07 |
US10170774B2 (en) | 2019-01-01 |
EP3092672B1 (en) | 2017-10-18 |
US10680255B2 (en) | 2020-06-09 |
US20160336604A1 (en) | 2016-11-17 |
FR3016243B1 (en) | 2016-02-05 |
JP2017502473A (en) | 2017-01-19 |
WO2015104492A1 (en) | 2015-07-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3092672B1 (en) | Flow-guiding plate for a fuel cell | |
EP3171441B1 (en) | Bipolar plates for limiting the bypass of flow channels by the reagents | |
EP3171440B1 (en) | Bipolar plates for limiting the bypass of flow channels by the reagents | |
EP3175502B1 (en) | Electrochemical reactor balancing the charge loss of the homogenising zones of the cathode and the anode | |
EP3170220B1 (en) | Bipolar plate for an electrochemical reactor with a compact homogenisation zone and a low pressure differential | |
EP3092671B1 (en) | Flow-guiding plate for a fuel cell | |
EP3171439B1 (en) | Bipolar plates for limiting the bypass of flow channels by the reagents | |
EP3195392B1 (en) | Fluid flow plate for electrochemical reactor and assembly comprising the same | |
EP3136492B1 (en) | Stack of electrochemical cells distributed into separate groups comprising a homogenisation compartment | |
EP3514875B1 (en) | Cellular assembly for adapting the power of electrochemical reactors | |
EP3662529A1 (en) | Bipolar plate for improving the efficiency of a proton-exchange membrane fuel cell | |
WO2019186051A1 (en) | Bipolar plate with undulating channels | |
EP3686976A1 (en) | Bipolar plate for homogenizing coolant liquid temperatures | |
EP3686977A1 (en) | Bipolar plate for homogenizing coolant liquid temperature | |
FR3091416A1 (en) | BIPOLAR PLATE WITH A HOMOGENEIZATION ZONE LIMITING SHORT-CIRCUIT FLOW RATES | |
WO2024121503A1 (en) | Spacer for a water electrolysis cell | |
EP4007019A1 (en) | Bipolar plate for electrochemical reactor | |
FR2897721A3 (en) | Fuel cell e.g. energy converter, for vehicle, has electrochemical cells each comprising assembly formed by electrolyte, anode and cathode and interposed between bipolar plates having channels which are not situated face to face | |
FR3033667A1 (en) | IMPROVED STACK FOR FUEL CELL FOR ESTABLISHING HOMOGENEOUS FLOW | |
FR3017245A1 (en) | ASSEMBLY STACK MEMBRANE / ELECTRODES ALLEGE | |
FR2997230A1 (en) | Fuel cell e.g. proton exchange membrane fuel cell, for use as car's energy source, has cathode comprising first section placed between second and third sections and including catalyst load decreased from second section to third section |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20160701 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R079 Ref document number: 602015005452 Country of ref document: DE Free format text: PREVIOUS MAIN CLASS: H01M0008020000 Ipc: H01M0008025800 |
|
DAX | Request for extension of the european patent (deleted) | ||
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: H01M 8/0254 20160101ALI20170410BHEP Ipc: H01M 8/1004 20160101ALI20170410BHEP Ipc: H01M 8/0265 20160101ALI20170410BHEP Ipc: H01M 8/0258 20160101AFI20170410BHEP Ipc: H01M 8/241 20160101ALI20170410BHEP Ipc: H01M 8/0206 20160101ALI20170410BHEP |
|
INTG | Intention to grant announced |
Effective date: 20170509 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 938677 Country of ref document: AT Kind code of ref document: T Effective date: 20171115 Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602015005452 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 4 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20171018 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 938677 Country of ref document: AT Kind code of ref document: T Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180118 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180119 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180218 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180118 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602015005452 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
26N | No opposition filed |
Effective date: 20180719 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180106 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20180131 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180131 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180131 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180131 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20150106 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 Ref country code: MK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20171018 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171018 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230123 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240119 Year of fee payment: 10 Ref country code: GB Payment date: 20240124 Year of fee payment: 10 |