EP3061610B1 - A printing head - Google Patents

A printing head Download PDF

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Publication number
EP3061610B1
EP3061610B1 EP15202656.3A EP15202656A EP3061610B1 EP 3061610 B1 EP3061610 B1 EP 3061610B1 EP 15202656 A EP15202656 A EP 15202656A EP 3061610 B1 EP3061610 B1 EP 3061610B1
Authority
EP
European Patent Office
Prior art keywords
primary
drops
printing head
drop
separator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP15202656.3A
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German (de)
French (fr)
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EP3061610A1 (en
Inventor
Piotr Jeuté
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JEUTE, PIOTR
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Individual
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Filing date
Publication date
Priority claimed from PL411383A external-priority patent/PL226751B1/en
Application filed by Individual filed Critical Individual
Priority to EP15202656.3A priority Critical patent/EP3061610B1/en
Priority to GB1707885.8A priority patent/GB2546710B/en
Priority to JP2017540678A priority patent/JP6657531B2/en
Priority to PCT/EP2016/054090 priority patent/WO2016135294A2/en
Priority to GB1707883.3A priority patent/GB2546709B/en
Priority to AU2016223384A priority patent/AU2016223384B2/en
Priority to JP2017540629A priority patent/JP6657530B2/en
Priority to US15/552,274 priority patent/US10369786B2/en
Priority to CA2974760A priority patent/CA2974760C/en
Priority to AU2016223382A priority patent/AU2016223382B2/en
Priority to US15/552,275 priority patent/US10538103B2/en
Priority to CN201680011499.3A priority patent/CN107405928B/en
Priority to CN201680011740.2A priority patent/CN107257738B/en
Priority to CA2974812A priority patent/CA2974812C/en
Priority to PCT/EP2016/054093 priority patent/WO2016135296A2/en
Publication of EP3061610A1 publication Critical patent/EP3061610A1/en
Publication of EP3061610B1 publication Critical patent/EP3061610B1/en
Application granted granted Critical
Priority to US16/443,724 priority patent/US20200156370A1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/21Ink jet for multi-colour printing
    • B41J2/2107Ink jet for multi-colour printing characterised by the ink properties
    • B41J2/211Mixing of inks, solvent or air prior to paper contact

Definitions

  • the present invention relates to printing heads.
  • Ink jet printing is a type of printing that recreates a digital image by propelling drops of ink onto paper, plastic, or other substrates.
  • a high-pressure pump directs the liquid solution of ink and fast drying solvent from a reservoir through a gunbody and a microscopic nozzle, creating a continuous stream of ink drops via the Plateau-Rayleigh instability.
  • a piezoelectric crystal creates an acoustic wave as it vibrates within the gunbody and causes the stream of liquid to break into drops at regular intervals.
  • the ink drops are subjected to an electrostatic field created by a charging electrode as they form; the field varies according to the degree of drop deflection desired. This results in a controlled, variable electrostatic charge on each drop. Charged drops are separated by one or more uncharged "guard drops" to minimize electrostatic repulsion between neighboring drops.
  • the charged drops pass through an electrostatic field and are directed (deflected) by electrostatic deflection plates to print on the receptor material (substrate), or allowed to continue on undeflected to a collection gutter for re-use.
  • the more highly charged drops are deflected to a greater degree. Only a small fraction of the drops is used to print, the majority being recycled.
  • the ink system requires active solvent regulation to counter solvent evaporation during the time of flight (time between nozzle ejection and gutter recycling), and from the venting process whereby gas that is drawn into the gutter along with the unused drops is vented from the reservoir. Viscosity is monitored and a solvent (or solvent blend) is added to counteract solvent loss.
  • Drop-on-demand may be divided into low resolution DOD printers using electro valves in order to eject comparatively big drops of inks on printed substrates, or high resolution DOD printers, may eject very small drops of ink by means of using either a thermal DOD and piezoelectric DOD method of discharging the drop.
  • the print cartridges In the thermal inkjet process, the print cartridges contain a series of tiny chambers, each containing a heater. To eject a drop from each chamber, a pulse of current is passed through the heating element causing a rapid vaporization of the ink in the chamber to form a bubble, which causes a large pressure increase, propelling a drop of ink onto the paper. The ink's surface tension, as well as the condensation and thus contraction of the vapor bubble, pulls a further charge of ink into the chamber through a narrow channel attached to an ink reservoir.
  • the inks used are usually water-based and use either pigments or dyes as the colorant. The inks used must have a volatile component to form the vapor bubble, otherwise drop ejection cannot occur.
  • Piezoelectric DOD method uses a piezoelectric material in an ink-filled chamber behind each nozzle instead of a heating element. When a voltage is applied, the piezoelectric material changes shape, which generates a pressure pulse in the fluid forcing a drop of ink from the nozzle.
  • a DOD process uses software that directs the heads to apply between zero to eight drops of ink per dot, only where needed.
  • High resolution printers alongside the office applications, are also being used in some applications of industrial coding and marking.
  • Thermal Ink Jet more often is used in cartridge based printers mostly for smaller imprints, for example in pharmaceutical industry.
  • Piezoelectric printheads of companies like Spectra or Xaar have been successfully used for high resolution case coding industrial printers.
  • CIJ technology also proves to have inherent limitations. So far CIJ has not been successfully used for high resolution imprints due to the fact that it needs certain drop size in order to work well.
  • the other well-known disadvantage of CIJ technology is high usage of solvent. This causes not only high costs of supplies, but also may be hazardous for operators and the environment, since most efficient solvents are poisonous, such as the widely used MEK (Methyl Ethyl Ketone).
  • Double-shot inkjet printing of donor-acceptor-type organic charge-transfer complexes Wet/nonwet definition and its use for contact engineering
  • T. Hasegawa et al presents a double-shot inkjet printing (DS-IJP) technique, wherein two kinds of picoliter-scale ink drops including soluble component donor (e.g. tetrathiafulvalene, TTF) and acceptor (e.g. tetracyanoquinodimethane, TCNQ) molecules are individually deposited at an identical position on the substrate surfaces to form hardly soluble metal compound films of TTF-TCNQ.
  • the technique utilizes the wet/nonwet surface modification to confine the intermixed drops of individually printed donor and acceptor inks in a predefined area, which results in the picoliter-scale instantaneous complex formation.
  • a US patent US7429100 presents a method and a device for increasing the number of ink drops in an ink drop jet of a continuously operating inkjet printer, wherein ink drops of at least two separately produced ink drop jets are combined into one ink drop jet, so that the combined ink drop jet fully encloses the separate ink drops of the corresponding separate ink drop jets and therefore has a number of ink drops equal to the sum of the numbers of ink drops in the individual stream.
  • the drops from the individual streams do not collide with each other and are not combined with each other, but remain separate drops in the combined drop jet.
  • a US patent application US20050174407 presents a method for depositing solid materials, wherein a pair of inkjet printing devices eject ink drops respectively in a direction such that they coincide during flight, forming mixed drops which continue onwards towards a substrate, wherein the mixed drops are formed outside the printing head.
  • a US patent US8092003 presents systems and methods for digitally printing images onto substrates using digital inks and catalysts which initiate and/or accelerate curing of the inks on the substrates.
  • the ink and catalyst are kept separate from each other while inside the heads of an inkjet printer and combine only after being discharged from the head, i.e. outside the head. This may cause problems in precise control of coalescence of the drops in flight outside the head and corresponding lack of precise control over drop placement on the printed object.
  • a Japanese patent application JP2010105163A discloses a nozzle plate that includes a plurality of nozzle holes that discharge liquids that combine in flight outside the nozzle plate.
  • a US patent US8092003 presents systems and methods for digitally printing images onto substrates using digital inks and catalysts which initiate and/or accelerate curing of the inks on the substrates.
  • the ink and catalyst are kept separate from each other while inside the heads of an inkjet printer and combine only after being discharged from the head, i.e. outside the head. This may cause problems in precise control of coalescence of the drops in flight outside the head and corresponding lack of precise control over drop placement on the printed object.
  • the drops of respective primary liquids are not guided after being discharged from respective nozzles. Therefore, their path of flight on their way towards the point of connection where they start to form a mixed, combined drop, is not controlled.
  • Such control may become necessary when mixing chemically reacting substrates in order to avoid accidental and undesired contact between substrates in the area of nozzle endings, where such too early contact might lead to residue build up of the combined substance and blocking the nozzle with time while the combined substance solidifies.
  • a US patent application US2011/0181674 discloses an inkjet print head including a pressure chamber storing a first ink drawn in from a reservoir and transferring the first ink to a nozzle by a driving force of an actuator; and a damper disposed between the pressure chamber and the nozzle and allowing the first ink to be mixed with a second ink drawn through an ink flow path for the second ink.
  • the disadvantage of that solution is that the mixed ink is in contact with the nozzle.
  • the present invention combines those two advantages and brings them to the level available so far only to CIJ printers and unavailable in the area of DOD technology in general (mainly when it comes to drying time) and high resolution DOD technology in particular, where both drying (curing) time and drop energy have been have been very much improved compared to the present state of technology.
  • the present invention addresses also the main disadvantages of CIJ technology leading to min.
  • the invention relates to an inkjet printing head according to the appended set of claims.
  • FIG. 1 A first embodiment of the inkjet printing head 100 according to the invention is shown in an overview in Fig. 1 and in a detailed cross-sectional views in various variants on Figs. 2A-2E .
  • Figs. 2A and 2B show the same cross-sectional view, but for clarity of the drawing different elements have been referenced on different figures.
  • the inkjet printing head 100 may comprise one or more nozzle assemblies 110, each configured to produce a combined drop 122 formed of two primary drops 121A, 121B ejected from a pair of nozzles 111A, 111B separated by a separator 131.
  • the embodiment can be second section located between the first section and the nozzle outlets and having a width increasing upstream; and further comprising a source of a gas stream to flow downstream inside primary enclosure.
  • the nozzles can be inclined with respect to the longitudinal axis of the head at an angle from 0 to 90 degrees, preferably from 5 to 75 degrees, more preferably from 15 to 45 degrees.
  • the primary drops can be ejected from the nozzles with respect to the longitudinal axis of the head at an ejection angle from 0 to 90 degrees, preferably from 5 to 75 degrees, more preferably from 15 to 45 degrees, in particular 90 degrees.
  • the primary drops may be ejected at the ejection angle equal to the angle of inclination of nozzles with respect to the longitudinal axis of the head.
  • the primary drops may be ejected at the ejection angle different to the angle of inclination of nozzles with respect to the longitudinal axis of the head.
  • the primary drops may be ejected perpendicularly to the longitudinal axis of the head.
  • Both nozzles can be inclined with respect to the longitudinal axis of the head at the same angle.
  • the nozzles can be inclined with respect to the longitudinal axis of the head at different angles.
  • the primary enclosure may further comprise a third section extending upstream in parallel to the external walls of the nozzles.
  • the diameter of the first section of the primary enclosure can be equal to the diameter of the combined drop.
  • the cross-section area of the first section of the primary enclosure may be not smaller than 80% of the cross-section area of the combined drop.
  • the length of the first section of the primary enclosure may be not smaller than the diameter of the combined drop.
  • the printing head may further comprise a secondary enclosure surrounding the primary enclosure and connected to the source of a gas stream and comprising a first section extending downstream from the outlet of the first section of the primary enclosure and having a diameter decreasing downstream to a diameter larger than the diameter of the combined drop.
  • the printing head may further comprise deflecting electrodes at the outlet of the secondary enclosure.
  • the printing head may further comprise charging electrodes at the outlet of the primary enclosure.
  • the printing head may comprise a plurality of nozzle assembles arranged in parallel.
  • the nozzle outlets can be heated.
  • the printing head may further comprise a cover enclosing the nozzle outlets and the connection point.
  • the cover may comprise heating elements for heating the volume within the cover.
  • the printing head may be configured to operate as a Drop-on-demand (DOD) printing head.
  • DOD Drop-on-demand
  • FIG. 1 A first embodiment of the inkjet printing head 100 according to the invention is shown in an overview in Fig. 1 and in a detailed cross-sectional views in various variants on Figs. 2A-2E .
  • Figs. 2A and 2B show the same cross-sectional view, but for clarity of the drawing different elements have been referenced on different figures.
  • the inkjet printing head 100 may comprise one or more nozzle assemblies 110, each configured to produce a combined drop 122 formed of two primary drops 121A, 121B ejected from a pair of nozzles 111A, 111B separated by a separator 131.
  • the embodiment can be enhanced by using more than two nozzles.
  • Fig. 1 shows a head with 8 nozzle assemblies 110 arranged in parallel to print 8-dot rows 191 on a substrate 190. It is worth noting that the printing head in alternative embodiments may comprise only a single nozzle assembly 110 or more or less than 8 nozzle assemblies, even as much as 256 nozzle assemblies or more for higher-resolution print.
  • Each nozzle 111A, 111B of the pair of nozzles in the nozzle assembly 110 has a channel 112A, 112B for conducting liquid from a reservoir 116A, 116B.
  • the liquid is formed into primary drops 121A, 121B as a result of operation of propelling devices shown in Figs. 8 , 9 , 10 .
  • the nozzle outlets 113A, 113B are adjacent to a separator 131 having a downstream-narrowing cross-section (preferably in a shape of a longitudinal wedge or a cone) that separates the nozzle outlets 113A, 113B and thus prevents the undesirable contact between primary drops 121A and 121B prior to their full discharge from their respective nozzle outlets 113A and 113B.
  • the primary drops 121A, 121B ejected from the nozzle outlets 113A, 113B move along the separator 131 towards its tip 132, where they combine to form a combined drop 122, which separates from the separator tip 132 and travels towards the surface to be printed.
  • the liquids supplied from the two reservoirs 116A, 116B are preferably an ink and a catalyst for initiating curing of the ink. This allows initiation of curing of the ink in the combined drop before it reaches the surface to be printed, so that the ink may adhere more easily to the printed surface and/or cure more quickly at the printed surface.
  • the ink may comprise acrylic acid ester (from 50 to 80 parts by weight), acrylic acid (from 5 to 15 parts by weight), pigment (from 3 to 40 parts by weight), surfactant (from 0 to 5 parts by weight), glycerin (from 0 to 5 parts by weight), viscosity modifier (from 0 to 5 parts by weight).
  • the catalyst may comprise azaridine based curing agent (from 30 to 50 parts by weight), pigment (from 3 to 40 parts by weight), surfactant (from 0 to 5 parts by weight), glycerin (from 0 to 5 parts by weight), viscosity modifier (from 0 to 5 parts by weight), solvent (from 0 to 30 parts by weight).
  • the liquids may have a viscosity from 1 to 30 mPas and surface tension from 20 - 50 mN/m.
  • Other inks and catalysts known from the prior art can be used as well.
  • the solvent amounts to a maximum of 10%, preferably a maximum of 5% by weight of the combined drop. This allows to significantly decrease the content of the solvent in the printing process, which makes the technology according to the invention more environmentally-friendly than the current CIJ technologies, where the content of solvents usually exceeds 50% of the total mass of the drop during printing process. For this reason, the present invention is considered to be a green technology.
  • the ink drop is combined with the catalyst drop within the head 100, i.e. when the drops are in contact with the components of the head 100, in particular at the separator tip 132.
  • the head construction is such that the nozzle outlets 113A, 113B are separated from each other by the separator 131 and therefore the ink and the catalyst will not mix directly at the nozzle outlets 113A, 113B, which prevents the nozzle outlets 113A, 113B from clogging.
  • the separator 131 guides the drops 121A, 121B along its surface, therefore the drops 121A, 121B are guided in a controlled and predictable manner until they meet each other. It enables much better control over the coalescence process of two primary drops as well as the control over the direction that the combined drop will follow after its discharge from the separator tip 132. It is therefore easy to control drop placement of the combined drop 122 on the surface to be printed.
  • the separator 131 functions as a guide for the primary drops 121A, 121B within the printing head 100 from the nozzle outlet 113A, 113B to a connection point, i.e. the separator tip 132.
  • the separator tip 132 restricts the freedom of combination of primary drops 121A, 121B into a combined drop 122, i.e. the combined drop may form only under the separator tip 132, which impacts its further path of travel - downwards, towards the opening in the cover 181.
  • the drops 121A, 121B of at least two components, which before the combination have properties of stable liquids are guided to a connection point wherein they are still kept in contact with the components of the head, i.e. with the separator 131 down to its tip 132. Therefore, during combination and coalescence of the primary drops 121A,121B, they are in contact with the head components.
  • the nozzles 112A, 112B have drop generating and propelling devices 161A, 161B for ejecting the drops, which are only schematically marked in Figs. 2A and 2B , and their schematically depicted types are shown in Figs. 10 - 12 .
  • the drop generating and propelling devices may be for instance of thermal ( Fig. 10 ), piezoelectric ( Fig. 11 ) or valve ( Fig. 12 ) type. In case of the valve the liquid would need to be delivered at adequate pressure.
  • the separator 131 as shown in Figs. 2A and 2B is symmetrical, i.e. the inclination angles ⁇ A, ⁇ B of its side walls 114A, 114B are the same with respect to the axis of the head 100 or of the nozzle arrangement 110.
  • the separator may be asymmetric, i.e. the angles ⁇ A, ⁇ B may be different, depending on the parameters of liquids supplied from the nozzle outlets 113A, 113B.
  • the inclination angles ⁇ A, ⁇ B are possible from 0 to up to 90 degrees, preferably from 5 to 75 degrees, and more preferably from 15 to 45 degrees.
  • the inclination angles ⁇ A, ⁇ B of the nozzle channels 112A, 112B are not smaller (as shown in Fig. 2B ) than the inclination angles ⁇ A, ⁇ B of the corresponding separator walls 114A, 114B, so that the ejected primary drops 121A, 121B are forced into contact with the separator walls 114A, 114B.
  • the separator 131 can be replaceable, which allows to assembly the head 110 with a separator 131 having parameters corresponding to the type of liquid used for printing.
  • the separator 131 preferably has a length LA, LB of its side wall 114A, 114B, respectively, measured from the nozzle outlet 113A, 113B to the separator tip 132, not shorter than the diameter dA, dB of the primary drop 121A, 121B exiting the nozzle outlet 113A, 113B at that side wall 114A, 114B. This prevents the primary drops 121A, 121B from merging before they exit the nozzle outlets 113A, 113B.
  • the surface of the separator 131 has preferably a low friction coefficient to provide low adhesion of the drops 121A, 121B, 122, such as not to limit their movement and not introduce spin rotation of the primary drops 121A, 121B.
  • the side walls of the separator 131 are inclined such as to have a high wetting angle between the side walls and the primary drops, such as to decrease adhesion.
  • the separator and/or the nozzle outlets 113A, 113B may be heated to a temperature higher than the temperature of the environment.
  • the liquids in the reservoirs 116A, 116B may be also preheated. Increased temperature of working fluids (i.e. ink and catalyst) may also lead to improved coalescence process of primary drops and preferably increase adhesion and decrease the curing time of the combined drop 122 when applied on the substrate.
  • the separator 131 may be common for a plurality of nozzle assemblies 110.
  • each nozzle assembly 110 may have its own separator 131 and/or cover 181 or a sub-group of nozzle assemblies 110 may have its own common separator 131 and/or cover 181.
  • the printing head may further comprise a cover 181 which protects the head components, in particular the separator tip 132 and the nozzle outlets 113A, 113B, from the environment, for example prevents them from touching by the user or the printed substrate.
  • the cover 181 may comprise heating elements 182 for heating the volume within the cover 181, i.e. the volume surrounding of the nozzle outlets 113A, 113B and the separator 131 to a predetermined temperature, for example from 40°C to 60°C (other temperatures are possible as well, depending on the parameters of the drops), such as to provide stable conditions for combining of the drops.
  • a temperature sensor 183 may be positioned within the cover 181 to sense the temperature.
  • the printing head 110 may comprise gas-supplying nozzles 119A, 119B for blowing gas (such as air or nitrogen), preferably heated, towards the separator tip 132, in order to decrease the curing time, increase the dynamics of movement of the drops and to blow away any residuals that could be formed at the nozzles outlets 113A, 113B separator tip 132.
  • gas such as air or nitrogen
  • the second variant of the first embodiment differs from the first variant of Fig. 2A in that a tube 141 of a narrowing cross-section is formed at the outlet opening of the cover 181.
  • the downstream outlet of the tube 141 has preferably a cross-section of a diameter substantially equal to the desired diameter of the combined drop 122, or alternatively it is not smaller than at least 80% of the cross-section of the combined drop 122. Therefore, at the downstream outlet of the tube 141 there is formed a kind of pneumatic combined drop nozzle, through which the drop is pushed thanks to its kinetic energy. This improves precision of its movement directly forward, which facilitates precise drop placement, which in turn improves the print quality.
  • the tube 141 is located at some distance from the connection point, which in this variant is at the tip of the separator 131.
  • the third variant of the first embodiment differs from the second variant of Fig. 2C in that the tube 141 is located at the connection point, such that it's both the tube 141 and the tip of the separator 131 that jointly function as means for restricting the freedom of combination of the primary drops into a combined drop at the connection point. Therefore, the tube 141 functions both as the restricting means and a combined drop nozzle.
  • the fourth variant of the first embodiment differs from the second variant of Fig. 2C in that the separator 131E has a truncated tip 132E, such that the primary drops are only guided from the nozzle outlets towards the connection point, but are no longer in contact with the separator 131E at the connection point.
  • the coalescence process occurs unrestricted at the connection point, but is at least partially controlled in that the primary drops have been guided by the separator side walls, so that their direction is more precisely set as compared to droplets which would have been discharged directly from the nozzle outlets and not guided on their way towards the connection point.
  • the tube 141 is used to catch the combined drop 122 and to form it to a desired diameter and align it with a desired axis of flow.
  • the tube 141 is herein distanced downstream from the connection point.
  • FIG. 3 A first variant of the second embodiment of the inkjet printing head 200 according to the invention is shown in an overview in Fig. 3 .
  • Figs. 4A and 4B show the same longitudinal cross-sectional view, but for clarity of the drawing different elements have been referenced on different figures.
  • Fig. 5 shows a longitudinal cross-sectional view along a section parallel to that in Figs. 4A and 4B .
  • Fig. 6 shows various transverse cross-sectional views.
  • the inkjet printing head 200 may comprise one or more nozzle assemblies 210, each configured to produce a combined drop 222 formed of two primary drops 221A, 221B ejected from a pair of nozzles 211A, 211B.
  • Fig. 3 shows a head with a plurality of nozzle assemblies 210 arranged in parallel to print multi-dot rows 291 on a substrate 290. It is worth noting that the printing head may comprise only a single nozzle assembly 210 or even as much as 256 nozzle assemblies or more.
  • Each nozzle 211A, 211B of the pair of nozzles in the nozzle assembly 210 has a channel 212A, 212B for conducting liquid from a reservoir 216A, 216B.
  • the liquid forms a primary drop 221A, 221B.
  • the liquid is formed into primary drops 221A, 221B as a result of operation of propelling devices shown on Figs. 10, 11, 12 .
  • the nozzle outlets 213A, 213B are adjacent to a conical-shaped separator 231 that separates the nozzle outlets 213A, 213B.
  • the primary drops ejected from the nozzle outlets 213A, 213B move along the separator 231 towards its tip 232, where they combine to form a combined drop 222, which separates from the separator tip 232 and travels towards the surface to be printed.
  • the primary drops 221A, 221B are guided along the surface of the separator 231 by streams 271A, 271B of gas (such as air or nitrogen, provided from a pressurized gas input 219, having a pressure of preferably 5 bar) inside a primary enclosure 241.
  • gas such as air or nitrogen
  • the shape of the primary enclosure 241 in its upper part helps to direct the stream of gas alongside the nozzles 211A, 211B and guides drops from the outlets 213A, 213B of the nozzles 211A, 211B towards the connection point at the separator tip 232, at which they join to form the combined drop 222.
  • connection point can be considered as any point on the path of the primary drops, starting from the point at which the coalescence starts, via points at which the coalescence develops, towards a point at which the coalescence ends, i.e. the combined drop is formed to its final shape. It is important that the separator guides the drops towards that connection point. Preferably, at the connection point, the freedom of combination of the primary drops into a combined drop is restricted, so as to aid development of the combined drop.
  • the nozzles 212A, 212B have drop generating and propelling devices 261A, 261B for ejecting the drops, which are only schematically marked in Figs. 4A and 4B , and their schematically depicted types are shown in Figs. 10-12 .
  • the drop generating and propelling devices may be for instance of thermal ( Fig. 10 ), piezoelectric ( Fig. 11 ) or valve ( Fig. 12 ) type. In case of the valve the liquid would need to be delivered at adequate pressure.
  • the primary enclosure 241 has sections of different shapes.
  • the first section 243 which is located furthest downstream (i.e. towards the direction of flow of the combined drop 222) has preferably a constant, round cross-section of a diameter D1 substantially equal to the desired diameter dC of the combined drop 222.
  • the cross-section of the first section 243 is preferably not smaller than at least 80% of the cross-section of the combined drop 222. Therefore, at the outlet of the primary enclosure 241 at the downstream end of the first section 243, there is formed a kind of combined drop nozzle, through which the drop is pushed thanks to its kinetic energy enhanced by moving gas. This improves precision of its movement directly forward, which facilitates precise drop placement, which in turn improves the print quality.
  • the second section 244 (of primary enclosure 241) is located between the first section 243 and the nozzle outlets 213A, 213B and has a diameter which increases upstream (i.e. opposite the direction of drops flow), such that its upstream diameter encompasses the nozzle outlets 213A, 213B and leaves some space for gas 271A, 271B to flow between the enclosure walls and nozzle outlets 213A, 213B.
  • the cross section of the primary enclosure 241 changes upstream from round to elliptical one, since the width of the cross section increases more with length upstream, than its depth (cf. cross section E-E on Fig. 6 ).
  • the internal walls of the second section 244 converge downstream, therefore the flowing gas stream 271A, 271B forms an outer gas sleeve that urges the drops 221A, 221B, 222 towards the centre of the enclosure 241.
  • the primary enclosure 241 may further comprise a third section 245 located upstream the second section, which has internal walls in parallel to the external walls of the nozzles 211A, 211B.
  • a third section 245 located upstream the second section, which has internal walls in parallel to the external walls of the nozzles 211A, 211B.
  • the nozzle 211A is surrounded by the primary enclosure 241 and separated from the nozzle 211B by the blocking element 233, such that the stream of gas 271A flows only at the outer periphery of the nozzles 211A, 211B but not between the nozzles 211A, 211B wherein it is blocked by the blocking element 233, which then forms the separator 231.
  • the stream of gas 271A, 271B that is guided by this section is in parallel to the direction of ejecting of the primary drops 221A, 221B from the nozzle outlets 213A, 213B.
  • Parallel direction of the flowing gas stabilized prior to its contact with primary drops improves the control over the path of drops flow starting from the nozzle outlets 213A, 213B, since from the very moment of discharge, their flow is supported in terms of energy and direction by the flowing gas.
  • the shape of the primary enclosure 241 is preferably designed in such a way to enhance the appropriate velocity of gas flowing thorough respective sections, i.e. 245, 244, 243.
  • the velocity of the flowing gas is preferably higher than drop velocity precisely at the nozzle outlets area, which is close to the end of section 245, preferably at least not lower than the drop velocity in the area of the section 244 and higher again in the nozzle 243, where the flow will be forced to be of higher velocity again due to the smaller cross section surface of the outflow channel, i.e. the nozzle 243.
  • Such design would leave some room for gas pressure momentary compensating adjustments while for the short instant the gas flow through the nozzle 243 would slow down by passing combined drop 222. This momentary pressure increase in the section 244 would preferably add more kinetic energy for the drop 222 on leaving the nozzle 243.
  • the gas stream 271A, 271B is preferably configured to flow with a linear velocity not smaller than the velocity of the primary ink drops 221A, 221B ejected from the nozzle outlets 213A, 213B.
  • the temperature of the gas may be increased to allow better coalescence and mixing of the primary drops 221A, 221B by decreasing the surface tension and viscosity of the ink and the curing agent (polymerization initiator).
  • the geometry of the first section 243 relative to the second section 244 - especially the decrease of cross section surface of section 243 vs. section 244 - is designed such that the gas increases its velocity, preferably from 5 to 20 times, thus increasing the kinetic energy of the coalesced combined drop 222 and stabilizing the flow of the combined drop 222.
  • the liquids supplied from the two reservoirs 216A, 216B are preferably an ink and a catalyst for initiating curing of the ink, as described with reference to the first embodiment.
  • the ink drop is combined with the catalyst drop within the head 200, i.e. before combined drop 222 exits the primary enclosure 241.
  • the head construction is such that the nozzle outlets 213A, 213B are separated from each other by the separator 231, which does not allow the primary drops 221A, 221B to combine at the nozzle outlets 213A, 213B. Therefore, the ink and the catalyst will not mix directly at the nozzle outlets 213A, 213B, which prevents the nozzle outlets 213A, 213B from clogging.
  • the enclosure 241 guides the drops 221A, 221B, 222 towards its axis, therefore the drops 221A, 221B, 222 are guided in a controlled and predictable manner. It is therefore easy to control drop placement of the combined drop 222 on the surface to be printed.
  • the separator 231 and primary enclosure 241 function as a guide for the primary drops 221A, 221B within the printing head 200 from the nozzle outlet 213A, 213B to a connection point 232.
  • the separator 231 and the first section 243 of the primary enclosure restrict the freedom of combination of primary drops 221A, 221B into a combined drop 222, i.e. the combined drop 222 forms to a shape and dimensions defined by the inlet of the first section 243, and the separator 231 and the first section 243 impact the further path of travel of the combined drop 222 - downwards, towards the outlet of the first section 243.
  • the drops 221A, 221B of at least two components which before the combination have properties of stable liquids, are guided to a connection point 232 wherein they are still kept in contact with the components of the head, i.e. with the side walls of the first section 243 of the primary enclosure 241. Therefore, during combination and coalescence of the primary drops 221A, 221B, they are in contact with the head components.
  • the separator 231 may have the same properties as the separator 131 described for the first embodiment.
  • the inclination angles ⁇ A, ⁇ B of the nozzle channels 212A, 212B (which are in this embodiment also the ejection angles ⁇ B, ⁇ B at which the primary drops are ejected from the nozzle channels) as shown in Figs. 4A and 4B are the same as the inclination angles ⁇ A, ⁇ B of the side walls of the separator 231, so that the primary drops 221A, 221B are ejected from the nozzles in parallel to the separator walls. In alternate embodiments, they may be larger than the corresponding inclination angles ⁇ A, ⁇ B of the separator walls, so that the ejected primary drops 221A, 221B are forced into contact with the separator walls.
  • the inclination angles ⁇ A, ⁇ B of the nozzle channels 212A, 212B and the ejection angles ⁇ B, ⁇ B are smaller than the inclination angles ⁇ A, ⁇ B of the side walls of the separator 231, which may cause the ejected primary drops to separate from the side walls of the separator 231 and combine further downstream, i.e. below the tip of the separator.
  • the separator 231 functions as a guide for the primary drops 221A, 221B only partially and its main function is to separate the nozzle outlets 213A, 213B so as to prevent them from clogging.
  • the nozzles 212A, 212B shown in Fig. 4A are symmetrical, i.e. their angles of inclination ⁇ A, ⁇ B, and the ejection angles ⁇ B, ⁇ B are the same with respect to the axis of the head 200 or of the nozzle arrangement 210.
  • the nozzles 212A, 212B may be asymmetric, i.e. the angles ⁇ A, ⁇ B or ⁇ B, ⁇ B may be different, depending on the parameters of liquids supplied from the nozzle outlets 213A, 213B.
  • the inclination angles ⁇ A, ⁇ B and the ejection angles ⁇ B, ⁇ B can be from 0 to 90 degrees, preferably from 5 to 75 degrees, and more preferably from 15 to 45 degrees.
  • the primary enclosure 241 can be replaceable, which allows to assembly the head 210 with an enclosure 241 having parameters corresponding to the type of liquid used for printing.
  • enclosures 241 of different diameters D1 of the first section 243 can be used, depending on the actual features and size, as well as desired exit velocity of the combined drop 222.
  • the angles of inclination ⁇ A, ⁇ B of the nozzles 211A, 211B can be adjustable, to adjust the nozzle assembly 210 to parameters of the liquids stored in the reservoirs 216A, 216B.
  • the first section 243 of the primary enclosure 241 has preferably a length L1 not shorter than the diameter dC of the combined drop 222, and preferably the length L1 equal to a few diameters dC of the combined drop 222, to set its path of movement precisely for precise drop placement control.
  • the internal surface of the primary enclosure 241, especially at the first section 243 and at the second section 244 has preferably a low friction coefficient and low adhesion in order to prevent the drops 221A, 221B, 222 or residuals of their combination from adhering to the surface, helping to keep the device clean and allow the eventual residuals to be blown off by the stream of gas 271A, 271B.
  • the internal walls of the primary enclosure 241 are inclined such as to provide a low contact angle between the side walls and the primary drops, which could accidentally hit the internal walls, such as to decrease adhesion and facilitate drop bouncing.
  • the printing head may further comprise a secondary enclosure 251 which surrounds the primary enclosure 241 and has a shape corresponding to the primary enclosure 241 but a larger cross-sectional width, such that a second stream of gas 272, supplied from the pressurized gas inlet 219, can surround the outlet of the first section 243 of the primary enclosure 241, so that the combined drop 222 exiting the primary enclosure 241 is further guided downstream to facilitate control of its path.
  • the gas stream 272 may further increase its velocity in the area of second outlet section 253 due to its shape and thus further accelerate the drop 222 exiting the primary enclosure 241.
  • the surface of the cross section of the gas stream 272 decreases downwards which would cause the stream of gas 272 to reach the velocity not lower, but preferably higher than that of the combined drop 222 in the moment of leaving the section 243 of primary enclosure 241.
  • the cross-section of the second outlet section 253 of the secondary enclosure 251, which is between the outlet of the primary enclosure and the first outlet section 252 of the secondary enclosure is preferably decreasing downstream such as to direct the stream of gas 272 towards the central axis.
  • the first outlet section 252 of the secondary enclosure 251 has preferably a round cross-section and a diameter D2 that is preferably larger (preferably, at least 2 times larger) than the diameter D1 of the outlet of the section 243 of the primary enclosure, such that the combined drop 222 does not touch the internal side all of the secondary enclosure 251 to prevent clogging and is guided by the (now combined) streams of gas 271A, 271B, 272 between the combined drop 222 and the side walls of the secondary enclosure 251.
  • the secondary enclosure may have perforations (openings) 255 in the first outlet section 252, to aid in decompression of the gas stream in a direction other than the flow direction of the combined drop.
  • the diameter D2 is at least 2 times greater than the diameter dC of the combined drop.
  • the length L2 of the first outlet section 252 is from zero to a multiple of diameters dC of the combined drop 222, such as 10, 100 or even 1000 times the diameter dC, in order to guide the drop in a controllable manner and provide it with desired kinetic energy.
  • This may significantly increase the distance at which the combined drop 222 may be ejected from the printing head and still maintain the precise drop placement on the printed surface, which allows to print objects of variable surface.
  • this may allow to eject drops at an angle to the vector of gravity, while keeping satisfactory drop placement control.
  • relatively high length L2 may allow the combined drop to pre-cure before reaching the substrate 290.
  • the gas increases its velocity thus decreasing its pressure and consequently lowering its temperature. This may cause the increase of velocity and the decrease of the temperature of the combined drop 222, which remains within the gas stream. Lowering the temperature of the combined drop 222 may increase its viscosity and adhesion, which is desirable in the moment of reaching the substrate by the drop helping the drop to remain in the target point and preventing it from flowing sidewise.
  • the second embodiment may further comprise a cover 281, having configuration and functionality as described for the cover 181 of the first embodiment, including the heating elements and temperature sensor (not shown for clarity of drawing).
  • the second variant of the second embodiment differs from the first variant of Fig. 4A in that the side walls of separator 231C are slightly offset (not adjacent) from the internal side walls of the nozzle outlets, such that the primary drops 221A, 221B that are discharged are not immediately in contact with the side walls of the separator 231C. In that case, there is formed a thin layer of gas between the side walls of the separator 231C and the primary drops 221A, 221B.
  • the separator 231C restricts the freedom of gas flow and therefore the freedom of flow of the primary drops from the nozzle outlets towards the connection point, the separator 231C can be considered as indirectly guiding the primary drops.
  • the third embodiment of the head 300 is shown schematically in a longitudinal cross-section on Fig. 7 . It has most of its features in common with the second embodiment, with the following differences.
  • the output opening 3810 of the cover 381 has an appropriate width so that the deflected drop 322 does not come into contact with the cover 381.
  • the charging electrodes 362, 363 and the deflecting electrodes 364A, 364B can be designed in a manner known in the art from CIJ technology and therefore do not require further clarification on details.
  • FIG. 8 A fourth embodiment of the inkjet printing head 400 according to the invention is shown in Fig. 8 in a detailed cross-sectional view. Unless otherwise specified, the fourth embodiment shares common features with the first embodiment.
  • the inkjet printing head 400 may comprise one or more nozzle assemblies, each configured to produce a combined drop 422 formed of two primary drops 421A, 421B ejected from a pair of nozzles 411A, 411B separated by a separator 431.
  • the embodiment can be enhanced by using more than two nozzles.
  • Each nozzle 411A, 411B of the pair of nozzles in the nozzle assembly has a channel 412A, 412B for conducting liquid from a reservoir 416A, 416B.
  • the liquid is formed into primary drops 421A, 421B as a result of operation propelling devices shown on Figs. 10, 11, 12 .
  • the nozzle outlets 413A, 413B are separated by a separator 431 having a downstream-narrowing cross-section that separates the nozzle outlets 413A, 413B and thus prevents the undesirable contact between primary drops 421A and 421B prior to their full discharge from their respective nozzle outlets 413A and 413B.
  • the nozzles 412A, 412B have drop generating and propelling devices 461A, 461B for ejecting the drops, which are only schematically marked in Fig. 8 , and their schematically depicted types are shown in Figs. 10-12 .
  • the drop generating and propelling devices may be for instance of thermal ( Fig. 10 ), piezoelectric ( Fig. 11 ) or valve ( Fig. 12 ) type. In case of the valve the liquid would need to be delivered at adequate pressure.
  • the ejection angles ⁇ A, ⁇ B at which the primary drops 421A, 421B are ejected from the nozzle channels 412A, 412B are equal to 90 degrees, i.e. the primary drops 421A, 421B are ejected perpendicularly to the longitudinal axis of the head.
  • the nozzle inclination angles ⁇ A, ⁇ B are equal to 0 degrees, i.e. the nozzle channels are parallel to the longitudinal axis of the head, but in other embodiments they can be different.
  • the ejected primary drops 421A, 421B are guided along the separator 431, which has concave side walls 414A, 414B, towards its tip 432, where they combine to form a combined drop 422, which separates from the separator tip 432 and travels towards the surface to be printed.
  • the separator 431 which has concave side walls 414A, 414B, towards its tip 432, where they combine to form a combined drop 422, which separates from the separator tip 432 and travels towards the surface to be printed.
  • it is the geometry of the separator, and not of the nozzles, that determines collision parameters of the primary drops allowing for full coalescence.
  • the separator can be exchangeable, allowing for the modification of collision parameters. Furthermore, any residual drops being formed from the nozzles may be guided along the side walls of the separator and outside the printing head and also by means of the stream of gas flowing alongside the path of the primary drops and - from the connection point - alongside the path of the combined drop.
  • FIG. 9 A fifth embodiment of the inkjet printing head 500 according to the invention is shown in Fig. 9 in a detailed cross-sectional view. Unless otherwise specified, the fourth embodiment shares common features with the first embodiment.
  • the inkjet printing head 500 may comprise one or more nozzle assemblies, each configured to produce a combined drop 522 formed of two primary drops 521A, 521B ejected from a pair of nozzles 511A, 511B separated by a separator 531.
  • the embodiment can be enhanced by using more than two nozzles.
  • Each nozzle 511A, 511B of the pair of nozzles in the nozzle assembly has a channel 512A, 512B for conducting liquid from a reservoir 516A, 516B.
  • the liquid is formed into primary drops 521A, 521B as a result of operation propelling devices shown on Figs. 10, 11, 12 .
  • the nozzle outlets 513A, 513B are separated by a separator 531 having a downstream-narrowing cross-section that separates the nozzle outlets 513A, 513B and thus prevents the undesirable contact between primary drops 521A and 521B prior to their full discharge from their respective nozzle outlets 513A and 513B.
  • the nozzles 512A, 512B have drop generating and propelling devices 561A, 561B for ejecting the drops, which are only schematically marked in Fig. 9 and their schematically depicted types are shown in Figs. 10-12 .
  • the drop generating and propelling devices may be for instance of thermal ( Fig. 10 ), piezoelectric ( Fig. 11 ) or valve ( Fig. 12 ) type. In case of the valve the liquid would need to be delivered at some pressure.
  • the printing head may further comprise a cover 581 which protects the head components, in particular the separator tip 532 and the nozzle outlets 513A, 513B, from the environment, for example prevents them from touching by the user or the printed substrate.
  • the ejection angles ⁇ A, ⁇ B at which the primary drops 521A, 521B are ejected from the nozzle channels 512A, 512B are equal to 90 degrees, i.e. the primary drops 521A, 521B are ejected perpendicularly to the axis of the head.
  • the ejected primary drops 521A, 521B have their trajectory changed by bouncing from the side walls 514A, 514B of the separator, which are preferably flat, so that their trajectory is redirected towards a connection point where they combine to form a combined drop 522, which travels towards the surface to be printed.
  • the angle of incidence determines the angle of reflection thus the trajectory of the drop is determined by the angle of inclination of the walls of the separator.
  • the primary drops coalesce at the connection point which is downstream in relation to the tip of the separator.
  • one or both of the liquids stored in liquid reservoirs may be pre-charged with a predetermined electrostatic charge, such that one or both of the primary drops exiting the nozzle outlets are charged, which may facilitate drops combination to a combined drop.
  • the present invention is particularly applicable for high resolution DOD inkjet printers. However, the present invention can be also applied to low resolution DOD based on valves allowing to discharge drops of pressurized ink.
  • the present invention uniquely combines the features and advantages of two well known ink jet technologies by means of delivering the working drop ink in the way DOD printers work - including high resolution ones - but being able to deflect and control its flight path in the way CIJ printers work, with the drying or curing time of the imprint also closer to CIJ standards.
  • Such invention improves technical possibilities to apply high quality durable digital imprints on vast variety of substrates and products. This feature will prove to be especially advantageous in majority of industrial marking and coding applications.

Landscapes

  • Ink Jet (AREA)

Description

    TECHNICAL FIELD
  • The present invention relates to printing heads.
  • BACKGROUND
  • Ink jet printing is a type of printing that recreates a digital image by propelling drops of ink onto paper, plastic, or other substrates. There are two main technologies in use: continuous (CIJ) and Drop-on-demand (DOD) inkjet.
  • In continuous inkjet technology, a high-pressure pump directs the liquid solution of ink and fast drying solvent from a reservoir through a gunbody and a microscopic nozzle, creating a continuous stream of ink drops via the Plateau-Rayleigh instability. A piezoelectric crystal creates an acoustic wave as it vibrates within the gunbody and causes the stream of liquid to break into drops at regular intervals. The ink drops are subjected to an electrostatic field created by a charging electrode as they form; the field varies according to the degree of drop deflection desired. This results in a controlled, variable electrostatic charge on each drop. Charged drops are separated by one or more uncharged "guard drops" to minimize electrostatic repulsion between neighboring drops. The charged drops pass through an electrostatic field and are directed (deflected) by electrostatic deflection plates to print on the receptor material (substrate), or allowed to continue on undeflected to a collection gutter for re-use. The more highly charged drops are deflected to a greater degree. Only a small fraction of the drops is used to print, the majority being recycled. The ink system requires active solvent regulation to counter solvent evaporation during the time of flight (time between nozzle ejection and gutter recycling), and from the venting process whereby gas that is drawn into the gutter along with the unused drops is vented from the reservoir. Viscosity is monitored and a solvent (or solvent blend) is added to counteract solvent loss.
  • Drop-on-demand (DOD) may be divided into low resolution DOD printers using electro valves in order to eject comparatively big drops of inks on printed substrates, or high resolution DOD printers, may eject very small drops of ink by means of using either a thermal DOD and piezoelectric DOD method of discharging the drop.
  • In the thermal inkjet process, the print cartridges contain a series of tiny chambers, each containing a heater. To eject a drop from each chamber, a pulse of current is passed through the heating element causing a rapid vaporization of the ink in the chamber to form a bubble, which causes a large pressure increase, propelling a drop of ink onto the paper. The ink's surface tension, as well as the condensation and thus contraction of the vapor bubble, pulls a further charge of ink into the chamber through a narrow channel attached to an ink reservoir. The inks used are usually water-based and use either pigments or dyes as the colorant. The inks used must have a volatile component to form the vapor bubble, otherwise drop ejection cannot occur.
  • Piezoelectric DOD method uses a piezoelectric material in an ink-filled chamber behind each nozzle instead of a heating element. When a voltage is applied, the piezoelectric material changes shape, which generates a pressure pulse in the fluid forcing a drop of ink from the nozzle. A DOD process uses software that directs the heads to apply between zero to eight drops of ink per dot, only where needed.
  • High resolution printers, alongside the office applications, are also being used in some applications of industrial coding and marking. Thermal Ink Jet more often is used in cartridge based printers mostly for smaller imprints, for example in pharmaceutical industry. Piezoelectric printheads of companies like Spectra or Xaar have been successfully used for high resolution case coding industrial printers.
  • All DOD printers share one feature in common: the discharged drops of ink have longer drying time compared to CIJ technology when applied on non porous substrate. The reason being usage of fast drying solvent, which is well accepted by CIJ technology designed with fast drying solvent in mind, but which usage needs to be limited in DOD technology in general and high resolution DOD in particular. That is because fast drying inks would cause the dry back on the nozzles. In most of known applications the drying time of high resolution DOD printers' imprints on non porous substrates would be at least twice and usually well over three times as long as that of CIJ. This is a disadvantage in certain industrial coding applications, for instance very fast production lines where drying time of few seconds may expose the still wet (not dried) imprint for damage when it gets in contact with other objects.
  • Another disadvantage of high resolution DOD technology is limited drop energy, which requires the substrate to be guided very evenly and closely to printing nozzles. This also proves to be disadvantageous for some industrial applications. For example when coded surface is not flat, it cannot be guided very close to nozzles.
  • CIJ technology also proves to have inherent limitations. So far CIJ has not been successfully used for high resolution imprints due to the fact that it needs certain drop size in order to work well. The other well-known disadvantage of CIJ technology is high usage of solvent. This causes not only high costs of supplies, but also may be hazardous for operators and the environment, since most efficient solvents are poisonous, such as the widely used MEK (Methyl Ethyl Ketone).
  • The following documents illustrate various improvements to the ink jet printing technology.
  • An article "Double-shot inkjet printing of donor-acceptor-type organic charge-transfer complexes: Wet/nonwet definition and its use for contact engineering" by T. Hasegawa et al (Thin Solid Films 518 (2010) pp. 3988-3991) presents a double-shot inkjet printing (DS-IJP) technique, wherein two kinds of picoliter-scale ink drops including soluble component donor (e.g. tetrathiafulvalene, TTF) and acceptor (e.g. tetracyanoquinodimethane, TCNQ) molecules are individually deposited at an identical position on the substrate surfaces to form hardly soluble metal compound films of TTF-TCNQ. The technique utilizes the wet/nonwet surface modification to confine the intermixed drops of individually printed donor and acceptor inks in a predefined area, which results in the picoliter-scale instantaneous complex formation.
  • A US patent US7429100 presents a method and a device for increasing the number of ink drops in an ink drop jet of a continuously operating inkjet printer, wherein ink drops of at least two separately produced ink drop jets are combined into one ink drop jet, so that the combined ink drop jet fully encloses the separate ink drops of the corresponding separate ink drop jets and therefore has a number of ink drops equal to the sum of the numbers of ink drops in the individual stream. The drops from the individual streams do not collide with each other and are not combined with each other, but remain separate drops in the combined drop jet.
  • A US patent application US20050174407 presents a method for depositing solid materials, wherein a pair of inkjet printing devices eject ink drops respectively in a direction such that they coincide during flight, forming mixed drops which continue onwards towards a substrate, wherein the mixed drops are formed outside the printing head.
  • A US patent US8092003 presents systems and methods for digitally printing images onto substrates using digital inks and catalysts which initiate and/or accelerate curing of the inks on the substrates. The ink and catalyst are kept separate from each other while inside the heads of an inkjet printer and combine only after being discharged from the head, i.e. outside the head. This may cause problems in precise control of coalescence of the drops in flight outside the head and corresponding lack of precise control over drop placement on the printed object.
  • A Japanese patent application JP2010105163A discloses a nozzle plate that includes a plurality of nozzle holes that discharge liquids that combine in flight outside the nozzle plate.
  • A US patent US8092003 presents systems and methods for digitally printing images onto substrates using digital inks and catalysts which initiate and/or accelerate curing of the inks on the substrates. The ink and catalyst are kept separate from each other while inside the heads of an inkjet printer and combine only after being discharged from the head, i.e. outside the head. This may cause problems in precise control of coalescence of the drops in flight outside the head and corresponding lack of precise control over drop placement on the printed object.
  • In all of the above-mentioned methods, the drops of respective primary liquids are not guided after being discharged from respective nozzles. Therefore, their path of flight on their way towards the point of connection where they start to form a mixed, combined drop, is not controlled. Such control may become necessary when mixing chemically reacting substrates in order to avoid accidental and undesired contact between substrates in the area of nozzle endings, where such too early contact might lead to residue build up of the combined substance and blocking the nozzle with time while the combined substance solidifies.
  • A US patent application US2011/0181674 discloses an inkjet print head including a pressure chamber storing a first ink drawn in from a reservoir and transferring the first ink to a nozzle by a driving force of an actuator; and a damper disposed between the pressure chamber and the nozzle and allowing the first ink to be mixed with a second ink drawn through an ink flow path for the second ink. The disadvantage of that solution is that the mixed ink is in contact with the nozzle. This can lead to problems when the physicochemical parameters of the mixed ink do not allow for jetting of the mixed ink, or the mixed ink is not chemically stable and reactions occurring within the mixed ink cause the change of physicochemical parameters that do not allow for jetting of the mixed ink, or the reaction causes solidification of the mixed ink. In case the chemical reaction is initiated while mixing the ink components, any residue of the mixed ink which gets in contact with the nozzle may cause the residue build up, leading to clogging the nozzle during printing process.
  • SUMMARY
  • The problem associated with inkjet printing - especially in its DOD version - is the relatively long time of curing of the ink after its deposition on the surface remains actual.
  • There is still a need to improve the DOD inkjet printing technology in order to shorten the time of curing of the ink after its deposition on the surface. In addition, it would be advantageous to obtain such result combined with higher drop energy and more precise drop placement in order to code different products of different substrates and shapes.
  • There is a need to improve the inkjet print technologies in attempt to decrease the drying (or curing) time of the imprint and to increase the energy of the printing drop being discharged from the printer. The present invention combines those two advantages and brings them to the level available so far only to CIJ printers and unavailable in the area of DOD technology in general (mainly when it comes to drying time) and high resolution DOD technology in particular, where both drying (curing) time and drop energy have been have been very much improved compared to the present state of technology. The present invention addresses also the main disadvantages of CIJ technology leading to min. 10 times reduction of solvent usage and allowing much smaller - compared to those of CIJ - drops to be discharged with higher velocity, while the resulting imprint could be consolidated on the wide variety of substrates still in a very short time and with very high adhesion.
  • US-A-2011/0181674 discloses the preamble of claim 1.
  • The invention relates to an inkjet printing head according to the appended set of claims.
  • BRIEF DESCRIPTION OF DRAWINGS
  • The invention is shown by means of exemplary embodiment on a drawing, in which:
    • Fig. 1 shows schematically the overview of the first embodiment of the invention;
    • Figs. 2A and 2B show schematically the first variant of the first embodiment;
    • Fig. 2C shows schematically the second variant of the first embodiment;
    • Fig. 2D shows schematically the third variant of the first embodiment
    • Fig. 2E shows schematically the fourth variant of the first embodiment
    • Figs. 3, 4A, 4B, 5 and 6 show schematically the first variant of the second embodiment of the invention;
    • Fig. 4C shows schematically the second variant of the second embodiment of the invention;
    • Fig. 7 shows schematically the third embodiment of the invention;
    • Fig. 8 shows schematically the fourth embodiment of the invention;
    • Fig. 9 shows schematically the fifth embodiment of the invention;
    • Figs. 10, 11, 12 show schematically different devices for propelling a drop out of the nozzle.
    DETAILED DESCRIPTION First embodiment
  • A first embodiment of the inkjet printing head 100 according to the invention is shown in an overview in Fig. 1 and in a detailed cross-sectional views in various variants on Figs. 2A-2E. Figs. 2A and 2B show the same cross-sectional view, but for clarity of the drawing different elements have been referenced on different figures.
  • The inkjet printing head 100 may comprise one or more nozzle assemblies 110, each configured to produce a combined drop 122 formed of two primary drops 121A, 121B ejected from a pair of nozzles 111A, 111B separated by a separator 131. The embodiment can be second section located between the first section and the nozzle outlets and having a width increasing upstream; and further comprising a source of a gas stream to flow downstream inside primary enclosure.
  • The nozzles can be inclined with respect to the longitudinal axis of the head at an angle from 0 to 90 degrees, preferably from 5 to 75 degrees, more preferably from 15 to 45 degrees.
  • The primary drops can be ejected from the nozzles with respect to the longitudinal axis of the head at an ejection angle from 0 to 90 degrees, preferably from 5 to 75 degrees, more preferably from 15 to 45 degrees, in particular 90 degrees. The primary drops may be ejected at the ejection angle equal to the angle of inclination of nozzles with respect to the longitudinal axis of the head.
  • The primary drops may be ejected at the ejection angle different to the angle of inclination of nozzles with respect to the longitudinal axis of the head.
  • In particular, the primary drops may be ejected perpendicularly to the longitudinal axis of the head.
  • Both nozzles can be inclined with respect to the longitudinal axis of the head at the same angle.
  • The nozzles can be inclined with respect to the longitudinal axis of the head at different angles.
  • The primary enclosure may further comprise a third section extending upstream in parallel to the external walls of the nozzles.
  • The diameter of the first section of the primary enclosure can be equal to the diameter of the combined drop.
  • The cross-section area of the first section of the primary enclosure may be not smaller than 80% of the cross-section area of the combined drop.
  • The length of the first section of the primary enclosure may be not smaller than the diameter of the combined drop.
  • The printing head may further comprise a secondary enclosure surrounding the primary enclosure and connected to the source of a gas stream and comprising a first section extending downstream from the outlet of the first section of the primary enclosure and having a diameter decreasing downstream to a diameter larger than the diameter of the combined drop.
  • The printing head may further comprise deflecting electrodes at the outlet of the secondary enclosure.
  • The printing head may further comprise charging electrodes at the outlet of the primary enclosure.
  • The printing head may comprise a plurality of nozzle assembles arranged in parallel. The nozzle outlets can be heated.
  • The printing head may further comprise a cover enclosing the nozzle outlets and the connection point.
  • The cover may comprise heating elements for heating the volume within the cover.
  • The printing head may be configured to operate as a Drop-on-demand (DOD) printing head.
  • BRIEF DESCRIPTION OF DRAWINGS
  • The invention is shown by means of exemplary embodiment on a drawing, in which:
    • Fig. 1 shows schematically the overview of the first embodiment of the invention;
    • Figs. 2A and 2B show schematically the first variant of the first embodiment;
    • Fig. 2C shows schematically the second variant of the first embodiment;
    • Fig. 2D shows schematically the third variant of the first embodiment
    • Fig. 2E shows schematically the fourth variant of the first embodiment
    • Figs. 3, 4A, 4B, 5 and 6 show schematically the first variant of the second embodiment of the invention;
    • Fig. 4C shows schematically the second variant of the second embodiment of the invention;
    • Fig. 7 shows schematically the third embodiment of the invention;
    • Fig. 8 shows schematically the fourth embodiment of the invention;
    • Fig. 9 shows schematically the fifth embodiment of the invention;
    • Figs. 10, 11, 12 show schematically different devices for propelling a drop out of the nozzle.
    DETAILED DESCRIPTION First embodiment
  • A first embodiment of the inkjet printing head 100 according to the invention is shown in an overview in Fig. 1 and in a detailed cross-sectional views in various variants on Figs. 2A-2E. Figs. 2A and 2B show the same cross-sectional view, but for clarity of the drawing different elements have been referenced on different figures.
  • The inkjet printing head 100 may comprise one or more nozzle assemblies 110, each configured to produce a combined drop 122 formed of two primary drops 121A, 121B ejected from a pair of nozzles 111A, 111B separated by a separator 131. The embodiment can be enhanced by using more than two nozzles. Fig. 1 shows a head with 8 nozzle assemblies 110 arranged in parallel to print 8-dot rows 191 on a substrate 190. It is worth noting that the printing head in alternative embodiments may comprise only a single nozzle assembly 110 or more or less than 8 nozzle assemblies, even as much as 256 nozzle assemblies or more for higher-resolution print.
  • Each nozzle 111A, 111B of the pair of nozzles in the nozzle assembly 110 has a channel 112A, 112B for conducting liquid from a reservoir 116A, 116B. At the nozzle outlet 113A, 113B the liquid is formed into primary drops 121A, 121B as a result of operation of propelling devices shown in Figs. 8, 9, 10. The nozzle outlets 113A, 113B are adjacent to a separator 131 having a downstream-narrowing cross-section (preferably in a shape of a longitudinal wedge or a cone) that separates the nozzle outlets 113A, 113B and thus prevents the undesirable contact between primary drops 121A and 121B prior to their full discharge from their respective nozzle outlets 113A and 113B. The primary drops 121A, 121B ejected from the nozzle outlets 113A, 113B move along the separator 131 towards its tip 132, where they combine to form a combined drop 122, which separates from the separator tip 132 and travels towards the surface to be printed.
  • The liquids supplied from the two reservoirs 116A, 116B are preferably an ink and a catalyst for initiating curing of the ink. This allows initiation of curing of the ink in the combined drop before it reaches the surface to be printed, so that the ink may adhere more easily to the printed surface and/or cure more quickly at the printed surface.
  • For example, the ink may comprise acrylic acid ester (from 50 to 80 parts by weight), acrylic acid (from 5 to 15 parts by weight), pigment (from 3 to 40 parts by weight), surfactant (from 0 to 5 parts by weight), glycerin (from 0 to 5 parts by weight), viscosity modifier (from 0 to 5 parts by weight). The catalyst may comprise azaridine based curing agent (from 30 to 50 parts by weight), pigment (from 3 to 40 parts by weight), surfactant (from 0 to 5 parts by weight), glycerin (from 0 to 5 parts by weight), viscosity modifier (from 0 to 5 parts by weight), solvent (from 0 to 30 parts by weight). The liquids may have a viscosity from 1 to 30 mPas and surface tension from 20 - 50 mN/m. Other inks and catalysts known from the prior art can be used as well. Preferably, the solvent amounts to a maximum of 10%, preferably a maximum of 5% by weight of the combined drop. This allows to significantly decrease the content of the solvent in the printing process, which makes the technology according to the invention more environmentally-friendly than the current CIJ technologies, where the content of solvents usually exceeds 50% of the total mass of the drop during printing process. For this reason, the present invention is considered to be a green technology.
  • In the first variant of the first embodiment, as shown in Figs. 2A and 2B, the ink drop is combined with the catalyst drop within the head 100, i.e. when the drops are in contact with the components of the head 100, in particular at the separator tip 132. However, the head construction is such that the nozzle outlets 113A, 113B are separated from each other by the separator 131 and therefore the ink and the catalyst will not mix directly at the nozzle outlets 113A, 113B, which prevents the nozzle outlets 113A, 113B from clogging. Once the drops are combined to a combined drop 122, there risk of clogging of the separator tip 132 is minimized, as the separator tip 132 has a small surface and the kinetic energy of the moving combined drop 122 is high enough to detach the combined drop 122 from the separator tip 132. The separator 131 guides the drops 121A, 121B along its surface, therefore the drops 121A, 121B are guided in a controlled and predictable manner until they meet each other. It enables much better control over the coalescence process of two primary drops as well as the control over the direction that the combined drop will follow after its discharge from the separator tip 132. It is therefore easy to control drop placement of the combined drop 122 on the surface to be printed. Even if, due to differences in size or density or kinetic energy of the primary drops 121A, 121B, the combined drop 122 would not exit the head perpendicularly (as shown in Figs. 2A and 2B) but at an inclined angle, that angle would be relatively constant and predictable for all drops, therefore it could be taken into account during the printing process. Even relatively large-size drops - like those used for instance in low resolution valve based ink jet printers - can be combined due to the use of the separator 131 in a more predictable manner than in the prior art solutions where drops combine in-flight outside the printhead.
  • Therefore, the separator 131 functions as a guide for the primary drops 121A, 121B within the printing head 100 from the nozzle outlet 113A, 113B to a connection point, i.e. the separator tip 132. The separator tip 132 restricts the freedom of combination of primary drops 121A, 121B into a combined drop 122, i.e. the combined drop may form only under the separator tip 132, which impacts its further path of travel - downwards, towards the opening in the cover 181. In other words, in the presented inkjet head, the drops 121A, 121B of at least two components, which before the combination have properties of stable liquids, are guided to a connection point wherein they are still kept in contact with the components of the head, i.e. with the separator 131 down to its tip 132. Therefore, during combination and coalescence of the primary drops 121A,121B, they are in contact with the head components.
  • The nozzles 112A, 112B have drop generating and propelling devices 161A, 161B for ejecting the drops, which are only schematically marked in Figs. 2A and 2B, and their schematically depicted types are shown in Figs. 10 - 12. The drop generating and propelling devices may be for instance of thermal (Fig. 10), piezoelectric (Fig. 11) or valve (Fig. 12) type. In case of the valve the liquid would need to be delivered at adequate pressure.
  • The separator 131 as shown in Figs. 2A and 2B is symmetrical, i.e. the inclination angles αA, αB of its side walls 114A, 114B are the same with respect to the axis of the head 100 or of the nozzle arrangement 110. In alternative embodiments, the separator may be asymmetric, i.e. the angles αA, αB may be different, depending on the parameters of liquids supplied from the nozzle outlets 113A, 113B.
  • The inclination angles αA, αB are possible from 0 to up to 90 degrees, preferably from 5 to 75 degrees, and more preferably from 15 to 45 degrees.
  • Preferably, the inclination angles βA, βB of the nozzle channels 112A, 112B (which are in this embodiment equal to the ejection angles γA, γB at which the primary drops are ejected from the nozzle channels) are not smaller (as shown in Fig. 2B) than the inclination angles αA, αB of the corresponding separator walls 114A, 114B, so that the ejected primary drops 121A, 121B are forced into contact with the separator walls 114A, 114B.
  • The separator 131 can be replaceable, which allows to assembly the head 110 with a separator 131 having parameters corresponding to the type of liquid used for printing.
  • The separator 131 preferably has a length LA, LB of its side wall 114A, 114B, respectively, measured from the nozzle outlet 113A, 113B to the separator tip 132, not shorter than the diameter dA, dB of the primary drop 121A, 121B exiting the nozzle outlet 113A, 113B at that side wall 114A, 114B. This prevents the primary drops 121A, 121B from merging before they exit the nozzle outlets 113A, 113B.
  • The surface of the separator 131 has preferably a low friction coefficient to provide low adhesion of the drops 121A, 121B, 122, such as not to limit their movement and not introduce spin rotation of the primary drops 121A, 121B. Moreover, the side walls of the separator 131 are inclined such as to have a high wetting angle between the side walls and the primary drops, such as to decrease adhesion. In order to decrease adhesion between the separator and the drops 121A, 121B, 122, the separator and/or the nozzle outlets 113A, 113B may be heated to a temperature higher than the temperature of the environment. The liquids in the reservoirs 116A, 116B may be also preheated. Increased temperature of working fluids (i.e. ink and catalyst) may also lead to improved coalescence process of primary drops and preferably increase adhesion and decrease the curing time of the combined drop 122 when applied on the substrate.
  • As shown in Fig. 1, the separator 131 may be common for a plurality of nozzle assemblies 110. In alternative embodiments, each nozzle assembly 110 may have its own separator 131 and/or cover 181 or a sub-group of nozzle assemblies 110 may have its own common separator 131 and/or cover 181.
  • The printing head may further comprise a cover 181 which protects the head components, in particular the separator tip 132 and the nozzle outlets 113A, 113B, from the environment, for example prevents them from touching by the user or the printed substrate.
  • Moreover, the cover 181 may comprise heating elements 182 for heating the volume within the cover 181, i.e. the volume surrounding of the nozzle outlets 113A, 113B and the separator 131 to a predetermined temperature, for example from 40°C to 60°C (other temperatures are possible as well, depending on the parameters of the drops), such as to provide stable conditions for combining of the drops. A temperature sensor 183 may be positioned within the cover 181 to sense the temperature.
  • Moreover, the printing head 110 may comprise gas-supplying nozzles 119A, 119B for blowing gas (such as air or nitrogen), preferably heated, towards the separator tip 132, in order to decrease the curing time, increase the dynamics of movement of the drops and to blow away any residuals that could be formed at the nozzles outlets 113A, 113B separator tip 132.
  • The second variant of the first embodiment, as shown in Fig. 2C, differs from the first variant of Fig. 2A in that a tube 141 of a narrowing cross-section is formed at the outlet opening of the cover 181. The downstream outlet of the tube 141 has preferably a cross-section of a diameter substantially equal to the desired diameter of the combined drop 122, or alternatively it is not smaller than at least 80% of the cross-section of the combined drop 122. Therefore, at the downstream outlet of the tube 141 there is formed a kind of pneumatic combined drop nozzle, through which the drop is pushed thanks to its kinetic energy. This improves precision of its movement directly forward, which facilitates precise drop placement, which in turn improves the print quality. The tube 141 is located at some distance from the connection point, which in this variant is at the tip of the separator 131.
  • The third variant of the first embodiment, as shown in Fig. 2D, differs from the second variant of Fig. 2C in that the tube 141 is located at the connection point, such that it's both the tube 141 and the tip of the separator 131 that jointly function as means for restricting the freedom of combination of the primary drops into a combined drop at the connection point. Therefore, the tube 141 functions both as the restricting means and a combined drop nozzle.
  • The fourth variant of the first embodiment, as shown in Fig. 2E, differs from the second variant of Fig. 2C in that the separator 131E has a truncated tip 132E, such that the primary drops are only guided from the nozzle outlets towards the connection point, but are no longer in contact with the separator 131E at the connection point. In that case, the coalescence process occurs unrestricted at the connection point, but is at least partially controlled in that the primary drops have been guided by the separator side walls, so that their direction is more precisely set as compared to droplets which would have been discharged directly from the nozzle outlets and not guided on their way towards the connection point. In order to correct any irregularities that may have appeared at the combined drop 122 due to its free coalescence, the tube 141 is used to catch the combined drop 122 and to form it to a desired diameter and align it with a desired axis of flow. The tube 141 is herein distanced downstream from the connection point.
  • Second embodiment
  • A first variant of the second embodiment of the inkjet printing head 200 according to the invention is shown in an overview in Fig. 3. Figs. 4A and 4B show the same longitudinal cross-sectional view, but for clarity of the drawing different elements have been referenced on different figures. Fig. 5 shows a longitudinal cross-sectional view along a section parallel to that in Figs. 4A and 4B. Fig. 6 shows various transverse cross-sectional views.
  • The inkjet printing head 200 may comprise one or more nozzle assemblies 210, each configured to produce a combined drop 222 formed of two primary drops 221A, 221B ejected from a pair of nozzles 211A, 211B. Fig. 3 shows a head with a plurality of nozzle assemblies 210 arranged in parallel to print multi-dot rows 291 on a substrate 290. It is worth noting that the printing head may comprise only a single nozzle assembly 210 or even as much as 256 nozzle assemblies or more.
  • Each nozzle 211A, 211B of the pair of nozzles in the nozzle assembly 210 has a channel 212A, 212B for conducting liquid from a reservoir 216A, 216B. At the nozzle outlet 213A, 213B the liquid forms a primary drop 221A, 221B. At the nozzle outlet 213A, 213B the liquid is formed into primary drops 221A, 221B as a result of operation of propelling devices shown on Figs. 10, 11, 12. The nozzle outlets 213A, 213B are adjacent to a conical-shaped separator 231 that separates the nozzle outlets 213A, 213B. The primary drops ejected from the nozzle outlets 213A, 213B move along the separator 231 towards its tip 232, where they combine to form a combined drop 222, which separates from the separator tip 232 and travels towards the surface to be printed.
  • The primary drops 221A, 221B are guided along the surface of the separator 231 by streams 271A, 271B of gas (such as air or nitrogen, provided from a pressurized gas input 219, having a pressure of preferably 5 bar) inside a primary enclosure 241. The shape of the primary enclosure 241 in its upper part helps to direct the stream of gas alongside the nozzles 211A, 211B and guides drops from the outlets 213A, 213B of the nozzles 211A, 211B towards the connection point at the separator tip 232, at which they join to form the combined drop 222. Therefore, for all embodiments, the connection point can be considered as any point on the path of the primary drops, starting from the point at which the coalescence starts, via points at which the coalescence develops, towards a point at which the coalescence ends, i.e. the combined drop is formed to its final shape. It is important that the separator guides the drops towards that connection point. Preferably, at the connection point, the freedom of combination of the primary drops into a combined drop is restricted, so as to aid development of the combined drop.
  • The nozzles 212A, 212B have drop generating and propelling devices 261A, 261B for ejecting the drops, which are only schematically marked in Figs. 4A and 4B, and their schematically depicted types are shown in Figs. 10-12. The drop generating and propelling devices may be for instance of thermal (Fig. 10), piezoelectric (Fig. 11) or valve (Fig. 12) type. In case of the valve the liquid would need to be delivered at adequate pressure.
  • The primary enclosure 241 has sections of different shapes. The first section 243, which is located furthest downstream (i.e. towards the direction of flow of the combined drop 222) has preferably a constant, round cross-section of a diameter D1 substantially equal to the desired diameter dC of the combined drop 222. Alternatively, the cross-section of the first section 243, is preferably not smaller than at least 80% of the cross-section of the combined drop 222. Therefore, at the outlet of the primary enclosure 241 at the downstream end of the first section 243, there is formed a kind of combined drop nozzle, through which the drop is pushed thanks to its kinetic energy enhanced by moving gas. This improves precision of its movement directly forward, which facilitates precise drop placement, which in turn improves the print quality. The second section 244 (of primary enclosure 241) is located between the first section 243 and the nozzle outlets 213A, 213B and has a diameter which increases upstream (i.e. opposite the direction of drops flow), such that its upstream diameter encompasses the nozzle outlets 213A, 213B and leaves some space for gas 271A, 271B to flow between the enclosure walls and nozzle outlets 213A, 213B. At the same time the cross section of the primary enclosure 241 changes upstream from round to elliptical one, since the width of the cross section increases more with length upstream, than its depth (cf. cross section E-E on Fig. 6). The internal walls of the second section 244 converge downstream, therefore the flowing gas stream 271A, 271B forms an outer gas sleeve that urges the drops 221A, 221B, 222 towards the centre of the enclosure 241.
  • The primary enclosure 241 may further comprise a third section 245 located upstream the second section, which has internal walls in parallel to the external walls of the nozzles 211A, 211B. As more clearly visible in the cross-section B-B (shown for the left part only) of Fig. 6, the nozzle 211A is surrounded by the primary enclosure 241 and separated from the nozzle 211B by the blocking element 233, such that the stream of gas 271A flows only at the outer periphery of the nozzles 211A, 211B but not between the nozzles 211A, 211B wherein it is blocked by the blocking element 233, which then forms the separator 231.
  • The stream of gas 271A, 271B that is guided by this section is in parallel to the direction of ejecting of the primary drops 221A, 221B from the nozzle outlets 213A, 213B. Parallel direction of the flowing gas stabilized prior to its contact with primary drops improves the control over the path of drops flow starting from the nozzle outlets 213A, 213B, since from the very moment of discharge, their flow is supported in terms of energy and direction by the flowing gas. It is worth noticing that the shape of the primary enclosure 241 is preferably designed in such a way to enhance the appropriate velocity of gas flowing thorough respective sections, i.e. 245, 244, 243. The velocity of the flowing gas is preferably higher than drop velocity precisely at the nozzle outlets area, which is close to the end of section 245, preferably at least not lower than the drop velocity in the area of the section 244 and higher again in the nozzle 243, where the flow will be forced to be of higher velocity again due to the smaller cross section surface of the outflow channel, i.e. the nozzle 243. Such design would leave some room for gas pressure momentary compensating adjustments while for the short instant the gas flow through the nozzle 243 would slow down by passing combined drop 222. This momentary pressure increase in the section 244 would preferably add more kinetic energy for the drop 222 on leaving the nozzle 243.
  • In any case in the second section 244 of the primary enclosure 241 the gas stream 271A, 271B is preferably configured to flow with a linear velocity not smaller than the velocity of the primary ink drops 221A, 221B ejected from the nozzle outlets 213A, 213B. The temperature of the gas may be increased to allow better coalescence and mixing of the primary drops 221A, 221B by decreasing the surface tension and viscosity of the ink and the curing agent (polymerization initiator). The geometry of the first section 243 relative to the second section 244 - especially the decrease of cross section surface of section 243 vs. section 244 - is designed such that the gas increases its velocity, preferably from 5 to 20 times, thus increasing the kinetic energy of the coalesced combined drop 222 and stabilizing the flow of the combined drop 222.
  • The liquids supplied from the two reservoirs 216A, 216B are preferably an ink and a catalyst for initiating curing of the ink, as described with reference to the first embodiment.
  • In the second embodiment, the ink drop is combined with the catalyst drop within the head 200, i.e. before combined drop 222 exits the primary enclosure 241. The head construction is such that the nozzle outlets 213A, 213B are separated from each other by the separator 231, which does not allow the primary drops 221A, 221B to combine at the nozzle outlets 213A, 213B. Therefore, the ink and the catalyst will not mix directly at the nozzle outlets 213A, 213B, which prevents the nozzle outlets 213A, 213B from clogging. Once the drops are combined to a combined drop 222, there is no risk of clogging of the primary enclosure 241 at the connection point or downstream the enclosure 241, as the combined drop 222 is already separated from the nozzle outlets 213A, 213B and the stream of gas 271A, 271B (which preferably flows continuously) can effectively remove any residuals that would stick to the separator 231 or enclosure walls 241 before solidifying. The enclosure 241 guides the drops 221A, 221B, 222 towards its axis, therefore the drops 221A, 221B, 222 are guided in a controlled and predictable manner. It is therefore easy to control drop placement of the combined drop 222 on the surface to be printed. Even if, due to differences in size or density of the primary drops 221A, 221B, the combined drop 222 would tend to deviate from the axis of the primary enclosure 241, it will be aligned with its axis at the end of the enclosure 241, and therefore exit the enclosure 241 along its axis. Therefore, even relatively large-size drops and primary drops having different sizes can be combined due to the use of the primary enclosure 241 in a more predictable manner than in the prior art solutions where drops combine in-flight outside the printhead.
  • Therefore, the separator 231 and primary enclosure 241 function as a guide for the primary drops 221A, 221B within the printing head 200 from the nozzle outlet 213A, 213B to a connection point 232. The separator 231 and the first section 243 of the primary enclosure restrict the freedom of combination of primary drops 221A, 221B into a combined drop 222, i.e. the combined drop 222 forms to a shape and dimensions defined by the inlet of the first section 243, and the separator 231 and the first section 243 impact the further path of travel of the combined drop 222 - downwards, towards the outlet of the first section 243. In other words, in the presented inkjet head, the drops 221A, 221B of at least two components, which before the combination have properties of stable liquids, are guided to a connection point 232 wherein they are still kept in contact with the components of the head, i.e. with the side walls of the first section 243 of the primary enclosure 241. Therefore, during combination and coalescence of the primary drops 221A, 221B, they are in contact with the head components.
  • The separator 231 may have the same properties as the separator 131 described for the first embodiment.
  • The inclination angles βA, βB of the nozzle channels 212A, 212B (which are in this embodiment also the ejection angles γB, γB at which the primary drops are ejected from the nozzle channels) as shown in Figs. 4A and 4B are the same as the inclination angles αA, αB of the side walls of the separator 231, so that the primary drops 221A, 221B are ejected from the nozzles in parallel to the separator walls. In alternate embodiments, they may be larger than the corresponding inclination angles αA, αB of the separator walls, so that the ejected primary drops 221A, 221B are forced into contact with the separator walls.
  • However, an alternate embodiment is possible, wherein the inclination angles βA, βB of the nozzle channels 212A, 212B and the ejection angles γB, γB are smaller than the inclination angles αA, αB of the side walls of the separator 231, which may cause the ejected primary drops to separate from the side walls of the separator 231 and combine further downstream, i.e. below the tip of the separator. In such a case the separator 231 functions as a guide for the primary drops 221A, 221B only partially and its main function is to separate the nozzle outlets 213A, 213B so as to prevent them from clogging. In that case, it is mostly the stream of gas 271A, 271B formed by the inside walls of the preliminary enclosure 241 that acts this way (i.e. via moving gas) as means for guiding the primary drops 221A, 221B within the printing head 200 from the nozzle outlet 213A, 213B to a connection point. The freedom of combination of primary drops 221A, 221B into the combined drop 222 at the connection point is then also restricted by the force of the stream of gas 271A, 271B formed by the internal walls of the primary enclosure 241.
  • The nozzles 212A, 212B shown in Fig. 4A are symmetrical, i.e. their angles of inclination βA, βB, and the ejection angles γB, γB are the same with respect to the axis of the head 200 or of the nozzle arrangement 210. In alternative embodiments, the nozzles 212A, 212B may be asymmetric, i.e. the angles βA, βB or γB, γB may be different, depending on the parameters of liquids supplied from the nozzle outlets 213A, 213B.
  • The inclination angles βA, βB and the ejection angles γB, γB can be from 0 to 90 degrees, preferably from 5 to 75 degrees, and more preferably from 15 to 45 degrees.
  • The primary enclosure 241 can be replaceable, which allows to assembly the head 210 with an enclosure 241 having parameters corresponding to the type of liquid used for printing. For example, enclosures 241 of different diameters D1 of the first section 243 can be used, depending on the actual features and size, as well as desired exit velocity of the combined drop 222. The angles of inclination βA, βB of the nozzles 211A, 211B can be adjustable, to adjust the nozzle assembly 210 to parameters of the liquids stored in the reservoirs 216A, 216B.
  • The first section 243 of the primary enclosure 241 has preferably a length L1 not shorter than the diameter dC of the combined drop 222, and preferably the length L1 equal to a few diameters dC of the combined drop 222, to set its path of movement precisely for precise drop placement control.
  • The internal surface of the primary enclosure 241, especially at the first section 243 and at the second section 244 has preferably a low friction coefficient and low adhesion in order to prevent the drops 221A, 221B, 222 or residuals of their combination from adhering to the surface, helping to keep the device clean and allow the eventual residuals to be blown off by the stream of gas 271A, 271B. Moreover, the internal walls of the primary enclosure 241 are inclined such as to provide a low contact angle between the side walls and the primary drops, which could accidentally hit the internal walls, such as to decrease adhesion and facilitate drop bouncing. In order to prevent any residue build-up side walls of the separator as well as primary enclosure are smooth with sharp edge endings, preferably covered in material having high contact angle to the primary drop liquid. The stream of gas preferably prevents also any particles from the outside environment to contaminate the inside of the primary enclosure 243.
  • The printing head may further comprise a secondary enclosure 251 which surrounds the primary enclosure 241 and has a shape corresponding to the primary enclosure 241 but a larger cross-sectional width, such that a second stream of gas 272, supplied from the pressurized gas inlet 219, can surround the outlet of the first section 243 of the primary enclosure 241, so that the combined drop 222 exiting the primary enclosure 241 is further guided downstream to facilitate control of its path. The gas stream 272 may further increase its velocity in the area of second outlet section 253 due to its shape and thus further accelerate the drop 222 exiting the primary enclosure 241. The surface of the cross section of the gas stream 272 decreases downwards which would cause the stream of gas 272 to reach the velocity not lower, but preferably higher than that of the combined drop 222 in the moment of leaving the section 243 of primary enclosure 241. In order to further increase the drop velocity the cross-section of the second outlet section 253 of the secondary enclosure 251, which is between the outlet of the primary enclosure and the first outlet section 252 of the secondary enclosure, is preferably decreasing downstream such as to direct the stream of gas 272 towards the central axis. The first outlet section 252 of the secondary enclosure 251 has preferably a round cross-section and a diameter D2 that is preferably larger (preferably, at least 2 times larger) than the diameter D1 of the outlet of the section 243 of the primary enclosure, such that the combined drop 222 does not touch the internal side all of the secondary enclosure 251 to prevent clogging and is guided by the (now combined) streams of gas 271A, 271B, 272 between the combined drop 222 and the side walls of the secondary enclosure 251. Moreover, the secondary enclosure may have perforations (openings) 255 in the first outlet section 252, to aid in decompression of the gas stream in a direction other than the flow direction of the combined drop. Preferably, the diameter D2 is at least 2 times greater than the diameter dC of the combined drop. Preferably, the length L2 of the first outlet section 252 is from zero to a multiple of diameters dC of the combined drop 222, such as 10, 100 or even 1000 times the diameter dC, in order to guide the drop in a controllable manner and provide it with desired kinetic energy. This may significantly increase the distance at which the combined drop 222 may be ejected from the printing head and still maintain the precise drop placement on the printed surface, which allows to print objects of variable surface. Moreover, this may allow to eject drops at an angle to the vector of gravity, while keeping satisfactory drop placement control. Moreover, relatively high length L2 may allow the combined drop to pre-cure before reaching the substrate 290.
  • In the outlet sections 252, 253 of the secondary enclosure 251 the gas increases its velocity thus decreasing its pressure and consequently lowering its temperature. This may cause the increase of velocity and the decrease of the temperature of the combined drop 222, which remains within the gas stream. Lowering the temperature of the combined drop 222 may increase its viscosity and adhesion, which is desirable in the moment of reaching the substrate by the drop helping the drop to remain in the target point and preventing it from flowing sidewise.
  • The second embodiment may further comprise a cover 281, having configuration and functionality as described for the cover 181 of the first embodiment, including the heating elements and temperature sensor (not shown for clarity of drawing).
  • The second variant of the second embodiment, as shown in Fig. 4C, differs from the first variant of Fig. 4A in that the side walls of separator 231C are slightly offset (not adjacent) from the internal side walls of the nozzle outlets, such that the primary drops 221A, 221B that are discharged are not immediately in contact with the side walls of the separator 231C. In that case, there is formed a thin layer of gas between the side walls of the separator 231C and the primary drops 221A, 221B. However, since the separator 231C restricts the freedom of gas flow and therefore the freedom of flow of the primary drops from the nozzle outlets towards the connection point, the separator 231C can be considered as indirectly guiding the primary drops. Similarly as to the variant of the first embodiment shown in Fig. 2E, it is mostly the downstream-narrowing tubular end of the primary enclosure 241 that restricts the freedom of combination of the primary drops into a combined drop 222 at the connection point and/or shapes the combined drop and aligns its output flow axis.
  • Third embodiment
  • The third embodiment of the head 300 is shown schematically in a longitudinal cross-section on Fig. 7. It has most of its features in common with the second embodiment, with the following differences.
  • At the first section 343 of the primary enclosure 341 and at the first section 352 of the secondary enclosure 351, there are charging electrodes 362, 363 which apply electrostatic charge to the combined drop 322.
  • Moreover, downstream, behind at the first outlet section 352 of the secondary enclosure 351 there are deflecting electrodes 364A, 364B which deflect the direction of the flow of the charged drops 322 in a controllable direction. Thereby, the drop 322 placement can be effectively controlled. In order to allow change of the outlet path of the drops 322 from the inside of the head 300, the output opening 3810 of the cover 381 has an appropriate width so that the deflected drop 322 does not come into contact with the cover 381.
  • The charging electrodes 362, 363 and the deflecting electrodes 364A, 364B can be designed in a manner known in the art from CIJ technology and therefore do not require further clarification on details.
  • The other elements, having reference numbers starting with 3 (3xx) correspond to the elements of the second embodiment having reference numbers starting with 2 (2xx).
  • Fourth embodiment
  • A fourth embodiment of the inkjet printing head 400 according to the invention is shown in Fig. 8 in a detailed cross-sectional view. Unless otherwise specified, the fourth embodiment shares common features with the first embodiment.
  • The inkjet printing head 400 may comprise one or more nozzle assemblies, each configured to produce a combined drop 422 formed of two primary drops 421A, 421B ejected from a pair of nozzles 411A, 411B separated by a separator 431. The embodiment can be enhanced by using more than two nozzles. Each nozzle 411A, 411B of the pair of nozzles in the nozzle assembly has a channel 412A, 412B for conducting liquid from a reservoir 416A, 416B. At the nozzle outlet 413A, 413B the liquid is formed into primary drops 421A, 421B as a result of operation propelling devices shown on Figs. 10, 11, 12. The nozzle outlets 413A, 413B are separated by a separator 431 having a downstream-narrowing cross-section that separates the nozzle outlets 413A, 413B and thus prevents the undesirable contact between primary drops 421A and 421B prior to their full discharge from their respective nozzle outlets 413A and 413B.
  • The nozzles 412A, 412B have drop generating and propelling devices 461A, 461B for ejecting the drops, which are only schematically marked in Fig. 8, and their schematically depicted types are shown in Figs. 10-12. The drop generating and propelling devices may be for instance of thermal (Fig. 10), piezoelectric (Fig. 11) or valve (Fig. 12) type. In case of the valve the liquid would need to be delivered at adequate pressure.
  • The printing head may further comprise a cover 481 which protects the head components, in particular the separator tip 432 and the nozzle outlets 413A, 413B, from the environment, for example prevents them from touching by the user or the printed substrate.
  • In the fourth embodiment, the ejection angles γA, γB at which the primary drops 421A, 421B are ejected from the nozzle channels 412A, 412B are equal to 90 degrees, i.e. the primary drops 421A, 421B are ejected perpendicularly to the longitudinal axis of the head. In this embodiment, the nozzle inclination angles βA, βB are equal to 0 degrees, i.e. the nozzle channels are parallel to the longitudinal axis of the head, but in other embodiments they can be different. Next, the ejected primary drops 421A, 421B are guided along the separator 431, which has concave side walls 414A, 414B, towards its tip 432, where they combine to form a combined drop 422, which separates from the separator tip 432 and travels towards the surface to be printed. In this embodiment it is the geometry of the separator, and not of the nozzles, that determines collision parameters of the primary drops allowing for full coalescence.
  • The separator can be exchangeable, allowing for the modification of collision parameters. Furthermore, any residual drops being formed from the nozzles may be guided along the side walls of the separator and outside the printing head and also by means of the stream of gas flowing alongside the path of the primary drops and - from the connection point - alongside the path of the combined drop.
  • Fifth embodiment
  • A fifth embodiment of the inkjet printing head 500 according to the invention is shown in Fig. 9 in a detailed cross-sectional view. Unless otherwise specified, the fourth embodiment shares common features with the first embodiment.
  • The inkjet printing head 500 may comprise one or more nozzle assemblies, each configured to produce a combined drop 522 formed of two primary drops 521A, 521B ejected from a pair of nozzles 511A, 511B separated by a separator 531. The embodiment can be enhanced by using more than two nozzles. Each nozzle 511A, 511B of the pair of nozzles in the nozzle assembly has a channel 512A, 512B for conducting liquid from a reservoir 516A, 516B. At the nozzle outlet 513A, 513B the liquid is formed into primary drops 521A, 521B as a result of operation propelling devices shown on Figs. 10, 11, 12. The nozzle outlets 513A, 513B are separated by a separator 531 having a downstream-narrowing cross-section that separates the nozzle outlets 513A, 513B and thus prevents the undesirable contact between primary drops 521A and 521B prior to their full discharge from their respective nozzle outlets 513A and 513B.
  • The nozzles 512A, 512B have drop generating and propelling devices 561A, 561B for ejecting the drops, which are only schematically marked in Fig. 9 and their schematically depicted types are shown in Figs. 10-12. The drop generating and propelling devices may be for instance of thermal (Fig. 10), piezoelectric (Fig. 11) or valve (Fig. 12) type. In case of the valve the liquid would need to be delivered at some pressure.
  • The printing head may further comprise a cover 581 which protects the head components, in particular the separator tip 532 and the nozzle outlets 513A, 513B, from the environment, for example prevents them from touching by the user or the printed substrate.
  • In the fifth embodiment, the ejection angles γA, γB at which the primary drops 521A, 521B are ejected from the nozzle channels 512A, 512B are equal to 90 degrees, i.e. the primary drops 521A, 521B are ejected perpendicularly to the axis of the head. Next, the ejected primary drops 521A, 521B have their trajectory changed by bouncing from the side walls 514A, 514B of the separator, which are preferably flat, so that their trajectory is redirected towards a connection point where they combine to form a combined drop 522, which travels towards the surface to be printed. The angle of incidence determines the angle of reflection thus the trajectory of the drop is determined by the angle of inclination of the walls of the separator. In this embodiment, the primary drops coalesce at the connection point which is downstream in relation to the tip of the separator.
  • Further embodiments
  • A skilled person will realize that the features of the embodiments described above can be further mixed between the embodiments. For example there can be more than two nozzles directing more than two primary drops in order to form one combined drop by means of using the same principles of discharging, guiding, forming, also by means of controlled coalescence, and accelerating drops within the print head as described above.
  • Moreover, one or both of the liquids stored in liquid reservoirs may be pre-charged with a predetermined electrostatic charge, such that one or both of the primary drops exiting the nozzle outlets are charged, which may facilitate drops combination to a combined drop.
  • It shall be noted that the drawings are schematic and not in scale and are used only to illustrate the embodiments for better understanding of the principles of operation.
  • The present invention is particularly applicable for high resolution DOD inkjet printers. However, the present invention can be also applied to low resolution DOD based on valves allowing to discharge drops of pressurized ink.
  • Moreover, the present invention uniquely combines the features and advantages of two well known ink jet technologies by means of delivering the working drop ink in the way DOD printers work - including high resolution ones - but being able to deflect and control its flight path in the way CIJ printers work, with the drying or curing time of the imprint also closer to CIJ standards. Such invention improves technical possibilities to apply high quality durable digital imprints on vast variety of substrates and products. This feature will prove to be especially advantageous in majority of industrial marking and coding applications.

Claims (15)

  1. An inkjet printing head comprising a nozzle assembly having at least two nozzles (111A, 111B; 211A, 211B; 311A, 311B; 411A, 411B; 511A, 511B), each nozzle being connected through a channel (112A, 112B; 212A, 212B; 312A, 312B; 412A, 412B; 512A, 512B) with a separate liquid reservoir for forming a primary drop (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) of liquid at the nozzle outlet, characterized in that it further comprises:
    - a separator (131, 231, 331, 431, 531) having a downstream-narrowing cross-section positioned between the nozzle outlets (113A, 113B; 213A, 213B; 313A, 313B; 413A, 413B; 513A, 513B) for restricting freedom of movement of the primary drops (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) within the printing head from the nozzle outlet in a direction towards a connection point (132; 232; 332; 432; 532) to be combined into a combined drop (122; 222; 322; 422; 522) at the connection point (132; 232; 332; 432; 532);
    - wherein the freedom of movement of the primary drops (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) is restricted along the length of each side wall of the separator (131, 231, 331, 431, 531) that is not smaller than the diameter of the primary drop (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) exiting the nozzle outlet (113A, 113B; 213A, 213B; 313A, 313B; 413A, 413B; 513A, 513B) at that side wall;
    - wherein the nozzle outlets are configured to discharge primary drops (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) at an angle inclined towards the longitudinal axis of the head; and
    - a cover (181, 281, 381, 481, 581) enclosing the nozzle outlets (113A, 113B; 213A, 213B; 313A, 313B; 413A, 413B; 513A, 513B) and the connection point (132; 232; 332; 432; 532).
  2. The printing head according to claim 1, wherein the separator (131, 231, 331, 431, 531) is further configured to change the path of movement of the primary drops (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) within the printing head from the nozzle outlet in a direction towards a connection point (132; 232; 332; 432; 532).
  3. The printing head according to any of claims 1-2, wherein the separator (131, 431) is configured to guide the primary drops (121A, 121B, 421A, 421B) along its side walls (114A; 114B; 414A, 414B).
  4. The printing head according to any of claims 1-2, wherein the separator (531) is configured to bounce the primary drops (521A, 521B) towards the connection point (532).
  5. The printing head according to any of previous claims, further comprising means for restricting the freedom of combination of the primary drops (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) into the combined drop (122; 222; 322; 422; 522) at the connection point.
  6. The printing head according to claim 4, wherein the separator (131, 231, 331, 431, 531) is configured to guide the primary drops (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) within the printing head from the nozzle outlet (113A, 113B; 213A, 213B; 313A, 313B; 413A, 413B; 513A, 513B) to the connection point and to restrict the freedom of combination of the primary drops into the combined drop (122; 222; 322; 422; 522) at the connection point (132; 232; 332; 432; 532).
  7. The printing head according to claim 5, wherein the means for restricting the freedom of combination of the primary drops (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) into the combined drop (122; 222; 322; 422; 522) at the connection point have a form of a tube (141, 241, 341) of a downstream-narrowing cross-section.
  8. The printing head according to claim 6, wherein the separator (131E) has a truncated tip (132E).
  9. The printing head according to claim 6, wherein the tube (141, 241, 341) is located at the connection point (132; 232; 332; 432; 532).
  10. The printing head according to claim 6, wherein the tube (141, 241, 341) is distanced downstream from the connection point (132; 232; 332).
  11. The printing head according to claim 4, wherein the separator (131 431) has its side walls adjacent to the nozzle outlets (113A, 113B; 413A, 413B) and configured to guide the primary drops (121A, 121B; 421A, 421B) along its side walls to combine into a combined drop (122; 422) at the separator tip (132; 432) which forms the means for restricting the freedom of combination of the primary drops (121A, 121B; 421A, 421B).
  12. The printing head according to any of previous claims, wherein the length of each side wall of the separator (131, 231, 331, 431, 531) is larger than the diameter of a primary drop (121A, 121B, 221A, 221B, 321A, 321B; 421A, 421B; 521A, 521B) exiting the nozzle outlet (113A, 113B; 213A, 213B; 313A, 313B; 413A, 413B; 513A, 513B) adjacent to that side wall.
  13. The printing head according to claim 2, wherein the means for restricting the freedom of combination of primary drops have a form of a primary enclosure (241; 341) surrounding the nozzle outlets (213A, 213B; 313A, 313B), extending downstream and having a first section (243; 343) with a diameter not smaller than the diameter of the combined drop (222, 322) and a second section (244; 344) located between the first section (243; 343) and the nozzle outlets (213A, 213B; 313A, 313B) and having a width increasing upstream; and further comprising a source (219; 319) of a gas stream to flow downstream inside primary enclosure.
  14. The printing head according to any of claims 10-12, further comprising a secondary enclosure (251; 351) surrounding the primary enclosure (241; 341) and connected to the source (219; 319) of a gas stream and comprising a first section (252; 352) extending downstream from the outlet of the first section (243; 343) of the primary enclosure (241; 341) and having a diameter decreasing downstream to a diameter (D2) larger than the diameter (dC) of the combined drop (222; 322).
  15. The printing head according to any of previous claims, configured to operate as a Drop-on-demand (DOD) printing head.
EP15202656.3A 2015-02-26 2015-12-24 A printing head Active EP3061610B1 (en)

Priority Applications (16)

Application Number Priority Date Filing Date Title
EP15202656.3A EP3061610B1 (en) 2015-02-26 2015-12-24 A printing head
CA2974760A CA2974760C (en) 2015-02-26 2016-02-26 A drop on demand printing head and printing method
US15/552,275 US10538103B2 (en) 2015-02-26 2016-02-26 Drop on demand printing head and printing method
PCT/EP2016/054090 WO2016135294A2 (en) 2015-02-26 2016-02-26 A drop on demand printing head and printing method
GB1707883.3A GB2546709B (en) 2015-02-26 2016-02-26 A drop on demand printing head
AU2016223384A AU2016223384B2 (en) 2015-02-26 2016-02-26 A drop on demand printing head and printing method
JP2017540629A JP6657530B2 (en) 2015-02-26 2016-02-26 Drop-on-demand print head and printing method
US15/552,274 US10369786B2 (en) 2015-02-26 2016-02-26 Printing of ink droplets combined in a reaction chamber
GB1707885.8A GB2546710B (en) 2015-02-26 2016-02-26 A drop on demand printing head
AU2016223382A AU2016223382B2 (en) 2015-02-26 2016-02-26 A drop on demand printing head and printing method
JP2017540678A JP6657531B2 (en) 2015-02-26 2016-02-26 Drop-on-demand print head and printing method
CN201680011499.3A CN107405928B (en) 2015-02-26 2016-02-26 Drop-on-demand ink print head and drop-on-demand printing method
CN201680011740.2A CN107257738B (en) 2015-02-26 2016-02-26 Drop on demand ink print head and drop on demand ink printing process
CA2974812A CA2974812C (en) 2015-02-26 2016-02-26 A drop on demand printing head and printing method
PCT/EP2016/054093 WO2016135296A2 (en) 2015-02-26 2016-02-26 A drop on demand printing head and printing method
US16/443,724 US20200156370A1 (en) 2015-02-26 2019-06-17 Printing of ink droplets combined in a reaction chamber

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
PL411383A PL226751B1 (en) 2015-02-26 2015-02-26 Printing head
GB1503290.7A GB2538220A (en) 2015-02-26 2015-02-27 A printing head
EP15177763 2015-07-21
EP15202656.3A EP3061610B1 (en) 2015-02-26 2015-12-24 A printing head

Publications (2)

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EP3061610A1 EP3061610A1 (en) 2016-08-31
EP3061610B1 true EP3061610B1 (en) 2019-06-05

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08323982A (en) * 1995-03-29 1996-12-10 Sony Corp Liquid-jet recording device
US20020148904A1 (en) * 2001-04-17 2002-10-17 Wen-Cheng Yu Multi-functional /nozzle for photoresist developer dispenser
JP2010105163A (en) * 2008-09-30 2010-05-13 Seiko Epson Corp Nozzle plate, liquid jet head, liquid discharge method, and printer
KR20110086946A (en) * 2010-01-25 2011-08-02 삼성전기주식회사 Inkjet print head
US8770722B2 (en) * 2012-03-28 2014-07-08 Eastman Kodak Company Functional liquid deposition using continuous liquid

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