EP3003543B1 - Exhaust gas aftertreatment device - Google Patents

Exhaust gas aftertreatment device Download PDF

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Publication number
EP3003543B1
EP3003543B1 EP14807361.2A EP14807361A EP3003543B1 EP 3003543 B1 EP3003543 B1 EP 3003543B1 EP 14807361 A EP14807361 A EP 14807361A EP 3003543 B1 EP3003543 B1 EP 3003543B1
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EP
European Patent Office
Prior art keywords
feeding channel
exhaust gas
casing
aftertreatment device
wall
Prior art date
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Application number
EP14807361.2A
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German (de)
French (fr)
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EP3003543A4 (en
EP3003543A1 (en
Inventor
Jukka KURIKKA
Tuomas Tyni
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Proventia Emission Control Oy
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Proventia Emission Control Oy
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Publication of EP3003543A1 publication Critical patent/EP3003543A1/en
Publication of EP3003543A4 publication Critical patent/EP3003543A4/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2892Exhaust flow directors or the like, e.g. upstream of catalytic device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9431Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/21Mixing gases with liquids by introducing liquids into gaseous media
    • B01F23/213Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids
    • B01F23/2132Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids using nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/10Mixing by creating a vortex flow, e.g. by tangential introduction of flow components
    • B01F25/103Mixing by creating a vortex flow, e.g. by tangential introduction of flow components with additional mixing means other than vortex mixers, e.g. the vortex chamber being positioned in another mixing chamber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/31Injector mixers in conduits or tubes through which the main component flows
    • B01F25/313Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit
    • B01F25/3131Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit with additional mixing means other than injector mixers, e.g. screens, baffles or rotating elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/31Injector mixers in conduits or tubes through which the main component flows
    • B01F25/314Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit
    • B01F25/3141Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit with additional mixing means other than injector mixers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/32Injector mixers wherein the additional components are added in a by-pass of the main flow
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • F01N3/208Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F2025/93Arrangements, nature or configuration of flow guiding elements
    • B01F2025/931Flow guiding elements surrounding feed openings, e.g. jet nozzles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/20Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a flow director or deflector
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the invention relates to an exhaust gas aftertreatment device, which comprises a casing, which casing has an inlet opening for the inflow of the exhaust gas, an outlet opening for the outflow of the exhaust gas, a feed hole for dispensing reactive substance to the casing, a mixing tube extending from the outlet opening for mixing the exhaust gas and reactive substance and a feeding channel for guiding the exhaust gas to the mixing tube, which feeding channel has an open first end directed to the outlet opening, the cross-sectional area of which first end is smaller than the cross-sectional area of the outlet opening.
  • a technique where nitrogen oxides are transformed into harmless compounds with the aid of a reactive substance to be mixed into the exhaust gas and a catalyser, is used for reducing NOx emissions of the exhaust gasses from diesel engines.
  • SCR Selective catalytic reduction
  • urea into ammonia occurs in several stages and different intermediate products can be generated in the process, which intermediate products can precipitate in the urea injection site or in the spots of the exhaust gas passage following the injection site.
  • Precipitates can accumulate in the exhaust gas passage to such an amount that they weaken the flow of the exhaust gas and increase the counter pressure in the engine too high. The precipitates also decrease the distribution of the reactive substance in the exhaust gas passage, which decreases the efficiency of the SCR system.
  • the injected urea should mix as well as possible with the exhaust gas without colliding with the walls of the exhaust gas passage. Additionally, the temperature of the exhaust gas should be sufficiently high and the distance between the injection site and the catalyser should be sufficiently long. In practice, the dimensions of the vehicles and the placement of the engine set their own limits for the structure of the exhaust gas passage, which makes it more difficult to optimally arrange the urea feeding.
  • the publication EP 1770253 discloses a cleaning device for the exhaust gas, in which cleaning device the exhaust gas flow is divided into a centre flow and an edge flow circulating the centre flow.
  • the reactive substance such as urea/water solution, is fed to the centre flow, whereby it stays in the mixing tube separated from the wall of the mixing tube as long as possible.
  • Document EP 2465602 discloses an exhaust gas aftertreatment device according to the preamble of claim 1.
  • the invention relates to an exhaust gas aftertreatment device, which is especially suitable for cleaning the exhaust gas from diesel engines.
  • the aftertreatment device has a casing, which has an inlet opening for the inflow of the exhaust gas, an outlet opening for the outflow of the exhaust gas and a feed hole for dispending reactive substance to the casing.
  • the reactive substance can be for example fuel, ammonium or preferably urea/water solution.
  • the feed hole can be a nozzle or an injector, through which the reactive substance is sprayed with a desired spraying pattern into the casing, or the feed hole can be a through mounting hole, to which the actual spraying nozzle or injector for the reactive substance is mounted.
  • a mixing tube directed outwards from the casing for mixing the exhaust gas and the reactive substance.
  • a feeding channel for guiding the exhaust gas to the mixing tube.
  • the feeding channel has an open first end directed to the outlet opening, the cross-sectional area of which first end is smaller than the cross-sectional area of the outlet opening.
  • the first end of the feeding channel can extend as far as to the outlet opening or it can extend to a distance from the outlet opening.
  • the exhaust gas can flow to the outlet opening through the feeding channel through the open first end of the feeding channel as well as through the annular slot around the first end of the feeding channel.
  • the exhaust gas flowing through the feeding channel forms a centre flow to the mixing tube and the exhaust gas flowing through the slot surrounding the feeding channel forms an edge flow surrounding the centre flow.
  • Said feeding channel has a wall, which wall has holes for the inflow of the exhaust gas. It has been observed that by guiding the exhaust gas into the feeding channel through the small holes in the wall, a relatively steady flow is formed inside the feeding channel.
  • sufficiently small round holes e.g. having a diameter of 3 mm
  • the wall of the feeding channel can be made to function as a flow equalizer, with which a nearly laminar exhaust gas flow rotating around the central axis of the feeding channel is formed inside the feeding channel.
  • the casing has an outer jacket, a first end wall and a second end wall, wherein the feed hole for feeding the reactive substance is located in the first end wall and the outlet opening is located in the second end wall.
  • the feeding channel is located in the outer jacket so that the feed hole is directed into the feeding channel.
  • the reactive substance such as urea/water solution, to be dispensed through the feed hole into the casing, is thus directed into the feeding channel, where it starts to mix with the exhaust gas present in the mixing tube.
  • the reactive substance is passed with the exhaust gas flowing through the feeding channel through the outlet opening to the mixing tube, where the final mixing of the reactive substance with the exhaust gas occurs.
  • the feeding channel has a second end, the cross-sectional area of which second end is unequal to the cross-sectional area of the first end.
  • the cross-sectional area of the feeding channel does not remain constant along the entire length of the feeding channel.
  • the wall of the feeding channel has at least along a part of its length a conical shape.
  • the cross-sectional area of the first end of the feeding channel can be smaller than the cross-sectional area of the second end. In case of a conical feeding channel this means that the feeding channel contracts towards the outlet opening.
  • the cross-sectional area of the first end of the feeding channel can be bigger than the cross-sectional area of the second end. In case of a conical feeding channel this alternative means that the feeding channel extends towards the outlet opening.
  • the second end of the feeding channel is substantially connected to the first end wall of the casing.
  • the first end wall thus closes the second end of the feeding channel, whereby the exhaust gas can flow into the feeding channel only through the holes in the wall of the feeding channel.
  • the cross-sectional area of the first end of the feeding channel is substantially smaller than the cross-sectional area of the mixing tube.
  • the first end of the feeding channel extends through the outlet opening into the mixing tube.
  • the point of discontinuity of the edge flow formed immediately to the place of the outlet opening to the starting point of the mixing tube cannot thus influence on the centre flow coming through the feeding channel.
  • the cross-sectional area of the flowing route of the edge flow coming from the casing to the mixing tube is reduced when the exhaust gas flow is transferred from the inside of the casing to the mixing tube. As a result, the flow velocity of the edge flow increases remarkably.
  • the edge flow flowing in the mixing tube has thus a high flow velocity and a gentle angle of elevation of the spiral of the flow.
  • the feed hole is located to the first end wall substantially on the imaginary central axis of the feeding channel.
  • the spraying pattern of the reactive substance to be dispensed to the feeding channel through the feed hole is thus directed in the direction of the central axis of the feeding channel, what is appropriate in the case of the symmetrical spraying pattern. If the spraying pattern of the reactive substance is asymmetrical, the feed hole does not necessarily need to be located on the central axis of the feeding channel.
  • the aftertreatment device has a swirl structure for guiding the exhaust gas led into the casing to rotate around the feeding channel in one direction of rotation.
  • the rotating nature of the exhaust gas flow remains when the exhaust gas flows from the inside of the casing from the slot between the edge of the outlet opening and the wall of the feeding channel to the mixing tube, i.e. the edge flow flowing in the mixing tube has a spirally advancing flowing pattern rotating along the walls of the mixing tube.
  • the exhaust gas rotates around the feeding channel in one direction of rotation and a part of the exhaust gas travels through the holes in the wall of the feeding channel into the feeding channel.
  • the rotating movement of the exhaust gas flow is remarkably reduced when travelling through the wall of the feeding channel, so the exhaust gas flowing inside the feeding channel can in practice have a nearly laminar flow.
  • the exhaust gas flowing through the wall has, despite of the reduction, also a remaining tangential flowing component.
  • the centre flow led to the middle of the mixing tube through the feeding channel and the edge flow flowing around the centre flow are thus most likely both spiral flows, but they have a substantially different flow velocity and a different angle of elevation of the spiral of the flow.
  • the swirl structure can comprise at least one flow guide for guiding the exhaust gas flowing from the inlet opening to the casing to rotate around the feeding channel. It is appropriate to locate the flow guide in connection with the inlet opening of the casing either inside the casing or immediately outside the outer jacket of the casing.
  • the flow guide has preferably a shape of a curved plate.
  • the feeding channel is located in an eccentric manner to the casing and the edge of the inlet opening has a collar for guiding the exhaust gas flow to the widest point of the slot between the outer jacket of the casing and the wall of the feeding channel in the direction of the tangent of the wall.
  • the aftertreatment device further comprises a substrate casing, inside of which an aftertreatment substrate of the exhaust gas is located.
  • the aftertreatment substrate is a particulate filter or an oxidation catalyst, through which the exhaust gas is guided to flow.
  • the substrate casing has an inlet pipe for the inflow of the exhaust gas and an outlet connection, which is connected to the inlet opening of the casing. Between the outlet connection and the inlet opening there is no separate connecting pipe in addition to a possible collar, but the substrate casing is in practice directly connected to the side of the casing. The flowing route of the exhaust gas from the substrate into the casing is thus made as short as possible, whereby the temperature of the exhaust gas entering to the casing remains high, what in its part prevents the formation of precipitations.
  • the advantage of the aftertreatment device according to the invention is that a reactive substance, such as urea/water solution, can be made to mix evenly with the exhaust gas. Thus, harmful agents in the exhaust gas can be effectively removed with the invention.
  • the advantage of the invention is that the reactive substance to be fed with the aid of it to the exhaust gas flow can be kept separated from the walls of the exhaust gas passage for a long time, what reduces the formation of harmful precipitations.
  • FIGs 1a and 1b show by way of an example an exhaust gas aftertreatment device according to the invention seen from two different directions.
  • the aftertreatment device has a casing 10, which has two round-shaped end walls, a first end wall 13 and a second end wall 15 as well as an outer jacket 11 having a cylindrical shape.
  • the first end wall has a feed hole 16, to which a nozzle spraying a reactive substance to the exhaust gas is fixed (the nozzle is not shown in the figure).
  • the second end wall has a mixing tube 18 directed outwards from the end wall.
  • the mixing tube has been illustrated as a short tube. In practice, the length of the mixing tube has not been restricted to any specific length, but its length can be chosen as desired.
  • the side of the outer jacket has a hole slightly smaller than the diameter of the outer jacket, a fixing collar 19 surrounding the edges of which hole. The free edge of the fixing collar defines the inlet opening 12 opening into the casing.
  • the aftertreatment device further comprises an aftertreatment substrate of the exhaust gas, which substrate can be for example a particulate filter (diesel particulate filter) or an oxidation catalyst (diesel oxidation catalyst).
  • the aftertreatment substrate is located in the substrate casing 30, which has a cylindrical wall.
  • the first end of the substrate casing has a conically extending inlet pipe 34 for the inflow of the exhaust gas and the second end has an adjustment element 36, with which the substrate casing is connected from its one end to the fixing collar 19 of the casing 10.
  • the distance between the aftertreatment substrate and the casing is thus made as short as possible, whereby the exhaust gas has no time to cool down on the way, but enters the casing having a temperature as high as possible.
  • FIG. 2a A cross-sectional view of an exhaust gas aftertreatment device in the longitudinal direction of the casing 10 of Figures 1a and 1b is illustrated in Figure 2a , and the cross-sectional view of the same device is illustrated in Figure 2b in the transversal direction of the casing.
  • the aftertreatment device of Figures 2a and 2b is illustrated in Figure 2c as seen diagonally from above, so the casing and the substrate casing are transparent.
  • a substrate casing 30, inside of which the aftertreatment substrate 32 is located, is shown in the figures on the side of the casing.
  • the first end of the substrate casing has an inlet pipe 34, which is connected to the exhaust gas system of a vehicle, such as to the exhaust pipe near the exhaust manifold of the engine or to the exhaust pipe of the turbocharger.
  • the exhaust gas to be treated is thus guided through the inlet pipe into the substrate casing.
  • the inlet pipe extends in a funnel-shaped manner in the flow direction of the exhaust gas.
  • the aftertreatment substrate inside the substrate casing is limited in its edges to the walls of the substrate casing, so that the exhaust gas led inside of it is made to flow through the aftertreatment substrate.
  • the outer jacket 11 of the casing 10 of the aftertreatment device has a fixing collar 19, the free end of which defines the inlet opening 12 opening into the casing.
  • the fixing collar is fixed to the outlet connection 36 of the substrate casing, which outlet connection has an outlet hole equally large with the inlet opening. The exhaust gas flown through the aftertreatment substrate exits thus from the substrate casing through the outlet connection 36 and the fixing collar directly to the casing 10.
  • the casing 10 comprises a first end wall 13, a second end wall 15, as well as an outer jacket 11 ( Fig. 2a ) having a cylindrical shape.
  • the first end wall has a feed hole 16 for fixing a nozzle feeding the reactive substance (the nozzle is not illustrated in the figure).
  • the second end wall 15 has a round outlet opening 14, from which a mixing tube 18 having a round cross-section extends from the second end wall.
  • the inner diameter of the mixing tube is substantially smaller than the inner diameter of the casing and substantially equally large with the diameter of the outlet opening 14.
  • a feeding channel 20 which has a wall 22 having a conical shape.
  • the first end of the feeding channel 20 extends through the outlet opening 14 into the mixing tube 18.
  • the first end of the feeding channel extends preferably 20-30 mm into the mixing tube.
  • the diameter of the first end of the feeding channel is substantially smaller than the diameter of the outlet opening, so that an annular slot remains between the edge of the outlet opening and the wall of the feeding channel, through which slot the exhaust gas can flow from the casing to the mixing tube.
  • the feeding channel and the mixing tube have the same imaginary central axis, so the annular slot surrounding the first end of the feeding channel has a constant width.
  • the feed hole 16 in the first end wall is located on the same central axis of the mixing tube and the feeding channel.
  • the first end of the feeding channel is open and the second end of the feeding channel extends so as to be connected to the first end wall 13.
  • the wall 22 of the feeding channel 20 has holes 24 in the entire area of the wall.
  • the holes are relatively small in their size, and they are substantially evenly distributed to the entire surface area of the wall.
  • the holes are preferably round holes having a diameter of couple of millimetres.
  • the holes form a flowing route of the exhaust gas from the inside of the casing into the feeding channel.
  • the exhaust gas can exit from the feeding channel to the mixing tube through the open first end of the feeding channel.
  • the exhaust gas flows also through the wall of the feeding channel through some of the holes into the feeding channel and through some other holes back outside the feeding channel. Such back flow occurring through the holes is, however, so slight that it is not significant in view of the operation of the device.
  • the feeding channel 20 is located in the casing 10 in an eccentric manner, i.e. the imaginary central axis of the feeding channel does not pass through the midpoints of the end walls 13, 15 of the casing.
  • the eccentric placement results in the fact that the width of the annular space between the outer jacket 11 of the casing and the wall 22 of the feeding channel, which width has been measured in the direction of the radius of the feeding channel, varies according to the measuring point.
  • a curved flow guide 17 formed of a metal plate, which flow guide surrounds the feeding channel from a distance from the feeding channel. As seen from the direction of the inlet opening the flow guide covers the feeding channel nearly entirely out of sight.
  • the inlet opening 12 and the flow guide 17 defined by the fixing collar 19 guide the exhaust gas to the widest point of the annular space between the wall 22 of the feeding channel and the outer jacket 11 of the casing in the direction of the tangent of the wall of the feeding channel.
  • the exhaust gas is thus guided to the spiral flow rotating inside the casing in one direction around the feeding channel.
  • the eccentric placement of the feeding channel results further in the fact that the flow route of the exhaust gas between the outer jacket of the casing and the wall 22 of the feeding channel rotating around the mixing tube tapers, i.e. the cross-sectional area of the flow route of the exhaust gas reduces in the flow direction of the exhaust gas. This leads to the increase of the pressure of the exhaust gas while the flow is advancing, what makes a part of the exhaust gas to flow through the holes 24 of the walls 22 of the feeding channel 20 into the feeding channel.
  • the wall of the feeding channel is in its entire length conical and the narrower end of the feeding channel leads to the outlet opening.
  • the feeding channel has a conical portion and a cylindrical portion, i.e. the feeding channel is only along a part of its length conical.
  • the wider end of the feeding channel can lead to the outlet opening and the narrower end can extend to the first end wall, i.e. the feeding channel can extend in the flow direction of the exhaust gas.
  • the wall of the feeding channel has holes only in a part of the surface area of the wall of the feeding channel or that the total surface area, the shape and/or the size of the holes vary in different parts of the wall of the feeding channel.
  • a feeding system of the reactive substance such as urea/water solution
  • the aftertreatment device is connected to the aftertreatment device according to the invention, with the aid of a nozzle belonging to which feeding system, reactive substance is sprayed to the exhaust gas flowing in the feeding channel 20.
  • the nozzle can be any nozzle suitable for injecting a liquid agent.
  • Especially the nozzle and the entire feeding system for the urea/water solution can be a part of a more extensive system affecting the operation and control of the engine.
  • the mixture of the exhaust gas and the reactive substance flowing through the feeding channel 20 to the mixing tube 18, forms the centre flow of the exhaust gas, and the exhaust gas flowing through the slot between the wall of the feeding channel and the edges of the outlet opening 14 forms the edge flow surrounding the centre flow.
  • the urea/water solution is preferably fed with the nozzle to the exhaust gas flow in small drops.
  • the urea included in the solution is under the influence of the heat of the exhaust gas turned into ammonia, which reacts with the nitrogen oxides (NOx) present in the exhaust gas, whereby nitrogen gas and water are generated.
  • This reaction occurs in the SCR catalyser located in the exhaust gas passage, which catalyser is placed in the exhaust gas passage in the flow direction of the exhaust gas below the mixing tube 18 (the SCR catalyser is not shown in the figure).
  • the vaporization of urea, its turning into ammonia and the mixing of the ammonia with the exhaust gas take place in the mixing tube and in the part of the exhaust gas passage between the mixing tube and the SCR catalyser.
  • the flow guide according to the invention suits especially well to be used in the cleaning processes according to the so-called SCR technique.
  • the invention is, however, not limited only to the SCR technique or to the usage of the urea/water solution, but the reactive substance to be injected to the exhaust gas can also be some other agent, which is desired to be mixed evenly with the exhaust gas flow and/or to remain separated from the walls of the exhaust gas passage as long as possible.
  • the reactive substance may thus be for example a urea solution, ammonia, some hydrocarbon-based reactive substance or fuel.

Description

  • The invention relates to an exhaust gas aftertreatment device, which comprises a casing, which casing has an inlet opening for the inflow of the exhaust gas, an outlet opening for the outflow of the exhaust gas, a feed hole for dispensing reactive substance to the casing, a mixing tube extending from the outlet opening for mixing the exhaust gas and reactive substance and a feeding channel for guiding the exhaust gas to the mixing tube, which feeding channel has an open first end directed to the outlet opening, the cross-sectional area of which first end is smaller than the cross-sectional area of the outlet opening.
  • A technique, where nitrogen oxides are transformed into harmless compounds with the aid of a reactive substance to be mixed into the exhaust gas and a catalyser, is used for reducing NOx emissions of the exhaust gasses from diesel engines. SCR (Selective catalytic reduction) technique uses for example a urea/water mixture as a reactive substance, which mixture is fed in small drops to the exhaust gas. Under the influence of the heat of the exhaust gas the water in the urea/water mixture is vaporized and the urea is disintegrated into ammonia, which reacts in the SCR catalyser with the nitrogen oxides. Pure nitrogen and water is generated as a final result of the reaction.
  • The disintegration of urea into ammonia occurs in several stages and different intermediate products can be generated in the process, which intermediate products can precipitate in the urea injection site or in the spots of the exhaust gas passage following the injection site. Too low surface temperatures of the exhaust gas passage, insufficient vaporizing time of urea before ending up in the catalyser, and bends in the exhaust gas passage, where the urea drops collide with the walls, increase the formation of precipitates. Precipitates can accumulate in the exhaust gas passage to such an amount that they weaken the flow of the exhaust gas and increase the counter pressure in the engine too high. The precipitates also decrease the distribution of the reactive substance in the exhaust gas passage, which decreases the efficiency of the SCR system.
  • In order to ensure the vaporization of the urea the injected urea should mix as well as possible with the exhaust gas without colliding with the walls of the exhaust gas passage. Additionally, the temperature of the exhaust gas should be sufficiently high and the distance between the injection site and the catalyser should be sufficiently long. In practice, the dimensions of the vehicles and the placement of the engine set their own limits for the structure of the exhaust gas passage, which makes it more difficult to optimally arrange the urea feeding.
  • The publication EP 1770253 discloses a cleaning device for the exhaust gas, in which cleaning device the exhaust gas flow is divided into a centre flow and an edge flow circulating the centre flow. The reactive substance, such as urea/water solution, is fed to the centre flow, whereby it stays in the mixing tube separated from the wall of the mixing tube as long as possible. With this known solution, good cleaning results of the exhaust gas are achieved, while the amount of precipitations remains small. Along with the gradual tightening of the limit values for exhaust gas emissions there is still a great need for the continuous improvement of the aftertreatment devices.
  • Document EP 2465602 discloses an exhaust gas aftertreatment device according to the preamble of claim 1.
  • It is an object of the invention to provide an exhaust gas aftertreatment device, by which the disadvantages relating to the prior art can be reduced and better cleaning results can be achieved.
  • The objects of the invention are obtained with an aftertreatment device, which is characterized by what is presented in the independent claim. Some advantageous embodiments of the invention are presented in the dependent claims.
  • The invention relates to an exhaust gas aftertreatment device, which is especially suitable for cleaning the exhaust gas from diesel engines. The aftertreatment device has a casing, which has an inlet opening for the inflow of the exhaust gas, an outlet opening for the outflow of the exhaust gas and a feed hole for dispending reactive substance to the casing. The reactive substance can be for example fuel, ammonium or preferably urea/water solution. The feed hole can be a nozzle or an injector, through which the reactive substance is sprayed with a desired spraying pattern into the casing, or the feed hole can be a through mounting hole, to which the actual spraying nozzle or injector for the reactive substance is mounted. As an extension of the outlet opening there is a mixing tube directed outwards from the casing for mixing the exhaust gas and the reactive substance. Inside the casing there is a feeding channel for guiding the exhaust gas to the mixing tube. The feeding channel has an open first end directed to the outlet opening, the cross-sectional area of which first end is smaller than the cross-sectional area of the outlet opening. The first end of the feeding channel can extend as far as to the outlet opening or it can extend to a distance from the outlet opening. The exhaust gas can flow to the outlet opening through the feeding channel through the open first end of the feeding channel as well as through the annular slot around the first end of the feeding channel. The exhaust gas flowing through the feeding channel forms a centre flow to the mixing tube and the exhaust gas flowing through the slot surrounding the feeding channel forms an edge flow surrounding the centre flow. Said feeding channel has a wall, which wall has holes for the inflow of the exhaust gas. It has been observed that by guiding the exhaust gas into the feeding channel through the small holes in the wall, a relatively steady flow is formed inside the feeding channel. By using sufficiently small round holes, e.g. having a diameter of 3 mm, in the wall of the feeding channel and by locating them in the wall of the feeding channel appropriately, the wall of the feeding channel can be made to function as a flow equalizer, with which a nearly laminar exhaust gas flow rotating around the central axis of the feeding channel is formed inside the feeding channel.
  • In a preferred embodiment of the aftertreatment device the casing has an outer jacket, a first end wall and a second end wall, wherein the feed hole for feeding the reactive substance is located in the first end wall and the outlet opening is located in the second end wall. The feeding channel is located in the outer jacket so that the feed hole is directed into the feeding channel. The reactive substance, such as urea/water solution, to be dispensed through the feed hole into the casing, is thus directed into the feeding channel, where it starts to mix with the exhaust gas present in the mixing tube. The reactive substance is passed with the exhaust gas flowing through the feeding channel through the outlet opening to the mixing tube, where the final mixing of the reactive substance with the exhaust gas occurs.
  • In another preferred embodiment of the aftertreatment device the feeding channel has a second end, the cross-sectional area of which second end is unequal to the cross-sectional area of the first end. Thus, the cross-sectional area of the feeding channel does not remain constant along the entire length of the feeding channel. Preferably the wall of the feeding channel has at least along a part of its length a conical shape. The cross-sectional area of the first end of the feeding channel can be smaller than the cross-sectional area of the second end. In case of a conical feeding channel this means that the feeding channel contracts towards the outlet opening. Alternatively, the cross-sectional area of the first end of the feeding channel can be bigger than the cross-sectional area of the second end. In case of a conical feeding channel this alternative means that the feeding channel extends towards the outlet opening.
  • In a third preferred embodiment of the aftertreatment device the second end of the feeding channel is substantially connected to the first end wall of the casing. In practise, the first end wall thus closes the second end of the feeding channel, whereby the exhaust gas can flow into the feeding channel only through the holes in the wall of the feeding channel.
  • In still another preferred embodiment of the aftertreatment device according to the invention the cross-sectional area of the first end of the feeding channel is substantially smaller than the cross-sectional area of the mixing tube. The edge flow of the exhaust gas flowing between the edge of the outlet opening and the wall of the feeding channel has thus room to flow in the mixing tube around the centre flow coming through the feeding channel, whereby these flows remain in the mixing tube as "separate" flows as long as possible.
  • The first end of the feeding channel extends through the outlet opening into the mixing tube. The point of discontinuity of the edge flow formed immediately to the place of the outlet opening to the starting point of the mixing tube cannot thus influence on the centre flow coming through the feeding channel. The cross-sectional area of the flowing route of the edge flow coming from the casing to the mixing tube is reduced when the exhaust gas flow is transferred from the inside of the casing to the mixing tube. As a result, the flow velocity of the edge flow increases remarkably. The edge flow flowing in the mixing tube has thus a high flow velocity and a gentle angle of elevation of the spiral of the flow.
  • In yet another preferred embodiment of the aftertreatment device the feed hole is located to the first end wall substantially on the imaginary central axis of the feeding channel. The spraying pattern of the reactive substance to be dispensed to the feeding channel through the feed hole is thus directed in the direction of the central axis of the feeding channel, what is appropriate in the case of the symmetrical spraying pattern. If the spraying pattern of the reactive substance is asymmetrical, the feed hole does not necessarily need to be located on the central axis of the feeding channel.
  • The aftertreatment device according to the invention has a swirl structure for guiding the exhaust gas led into the casing to rotate around the feeding channel in one direction of rotation. The rotating nature of the exhaust gas flow remains when the exhaust gas flows from the inside of the casing from the slot between the edge of the outlet opening and the wall of the feeding channel to the mixing tube, i.e. the edge flow flowing in the mixing tube has a spirally advancing flowing pattern rotating along the walls of the mixing tube.
  • Due to the swirl structure the exhaust gas rotates around the feeding channel in one direction of rotation and a part of the exhaust gas travels through the holes in the wall of the feeding channel into the feeding channel. The rotating movement of the exhaust gas flow is remarkably reduced when travelling through the wall of the feeding channel, so the exhaust gas flowing inside the feeding channel can in practice have a nearly laminar flow. The exhaust gas flowing through the wall has, despite of the reduction, also a remaining tangential flowing component. The centre flow led to the middle of the mixing tube through the feeding channel and the edge flow flowing around the centre flow are thus most likely both spiral flows, but they have a substantially different flow velocity and a different angle of elevation of the spiral of the flow.
  • The swirl structure can comprise at least one flow guide for guiding the exhaust gas flowing from the inlet opening to the casing to rotate around the feeding channel. It is appropriate to locate the flow guide in connection with the inlet opening of the casing either inside the casing or immediately outside the outer jacket of the casing. The flow guide has preferably a shape of a curved plate.
  • In yet another preferred embodiment of the aftertreatment device the feeding channel is located in an eccentric manner to the casing and the edge of the inlet opening has a collar for guiding the exhaust gas flow to the widest point of the slot between the outer jacket of the casing and the wall of the feeding channel in the direction of the tangent of the wall. With this placement of the feeding channel it is achieved that the cross-sectional area of the flowing route of the exhaust gas is reduced inside the casing while the flow is advancing around the feeding channel. The reduction of the cross-sectional area of the flow increases the pressure of the exhaust gas, what forces a part of the exhaust gas to flow through the holes in the wall of the feeding channel into the feeding channel.
  • Yet another preferred embodiment of the aftertreatment device further comprises a substrate casing, inside of which an aftertreatment substrate of the exhaust gas is located. Preferably the aftertreatment substrate is a particulate filter or an oxidation catalyst, through which the exhaust gas is guided to flow. The substrate casing has an inlet pipe for the inflow of the exhaust gas and an outlet connection, which is connected to the inlet opening of the casing. Between the outlet connection and the inlet opening there is no separate connecting pipe in addition to a possible collar, but the substrate casing is in practice directly connected to the side of the casing. The flowing route of the exhaust gas from the substrate into the casing is thus made as short as possible, whereby the temperature of the exhaust gas entering to the casing remains high, what in its part prevents the formation of precipitations.
  • The advantage of the aftertreatment device according to the invention is that a reactive substance, such as urea/water solution, can be made to mix evenly with the exhaust gas. Thus, harmful agents in the exhaust gas can be effectively removed with the invention.
  • Furthermore, the advantage of the invention is that the reactive substance to be fed with the aid of it to the exhaust gas flow can be kept separated from the walls of the exhaust gas passage for a long time, what reduces the formation of harmful precipitations.
  • In the following, the invention will be described in detail. In the description, reference is made to the enclosed drawings, in which
    • Figure 1a shows by way of an example an exhaust gas aftertreatment device according to the invention seen diagonally from above,
    • Figure 1b shows the aftertreatment device of Figure 1a seen from the side,
    • Figure 2a shows a cross-sectional view of the aftertreatment device of Figures 1a and 1b in the longitudinal direction of the casing,
    • Figure 2b shows a cross-sectional view of the aftertreatment device of Figures 1a, 1b and 2a in the transversal direction of the casing, and
    • Figure 2c shows an aftertreatment device according to the invention seen diagonally from above.
  • Figures 1a and 1b show by way of an example an exhaust gas aftertreatment device according to the invention seen from two different directions. The aftertreatment device has a casing 10, which has two round-shaped end walls, a first end wall 13 and a second end wall 15 as well as an outer jacket 11 having a cylindrical shape. The first end wall has a feed hole 16, to which a nozzle spraying a reactive substance to the exhaust gas is fixed (the nozzle is not shown in the figure). The second end wall has a mixing tube 18 directed outwards from the end wall. In Figures 1a and 1b the mixing tube has been illustrated as a short tube. In practice, the length of the mixing tube has not been restricted to any specific length, but its length can be chosen as desired. The side of the outer jacket has a hole slightly smaller than the diameter of the outer jacket, a fixing collar 19 surrounding the edges of which hole. The free edge of the fixing collar defines the inlet opening 12 opening into the casing.
  • The aftertreatment device further comprises an aftertreatment substrate of the exhaust gas, which substrate can be for example a particulate filter (diesel particulate filter) or an oxidation catalyst (diesel oxidation catalyst). The aftertreatment substrate is located in the substrate casing 30, which has a cylindrical wall. The first end of the substrate casing has a conically extending inlet pipe 34 for the inflow of the exhaust gas and the second end has an adjustment element 36, with which the substrate casing is connected from its one end to the fixing collar 19 of the casing 10. The distance between the aftertreatment substrate and the casing is thus made as short as possible, whereby the exhaust gas has no time to cool down on the way, but enters the casing having a temperature as high as possible.
  • A cross-sectional view of an exhaust gas aftertreatment device in the longitudinal direction of the casing 10 of Figures 1a and 1b is illustrated in Figure 2a, and the cross-sectional view of the same device is illustrated in Figure 2b in the transversal direction of the casing. The aftertreatment device of Figures 2a and 2b is illustrated in Figure 2c as seen diagonally from above, so the casing and the substrate casing are transparent. A substrate casing 30, inside of which the aftertreatment substrate 32 is located, is shown in the figures on the side of the casing. The first end of the substrate casing has an inlet pipe 34, which is connected to the exhaust gas system of a vehicle, such as to the exhaust pipe near the exhaust manifold of the engine or to the exhaust pipe of the turbocharger. The exhaust gas to be treated is thus guided through the inlet pipe into the substrate casing. The inlet pipe extends in a funnel-shaped manner in the flow direction of the exhaust gas. The aftertreatment substrate inside the substrate casing is limited in its edges to the walls of the substrate casing, so that the exhaust gas led inside of it is made to flow through the aftertreatment substrate.
  • The outer jacket 11 of the casing 10 of the aftertreatment device has a fixing collar 19, the free end of which defines the inlet opening 12 opening into the casing. The fixing collar is fixed to the outlet connection 36 of the substrate casing, which outlet connection has an outlet hole equally large with the inlet opening. The exhaust gas flown through the aftertreatment substrate exits thus from the substrate casing through the outlet connection 36 and the fixing collar directly to the casing 10.
  • The casing 10 comprises a first end wall 13, a second end wall 15, as well as an outer jacket 11 (Fig. 2a) having a cylindrical shape. The first end wall has a feed hole 16 for fixing a nozzle feeding the reactive substance (the nozzle is not illustrated in the figure). The second end wall 15 has a round outlet opening 14, from which a mixing tube 18 having a round cross-section extends from the second end wall. The inner diameter of the mixing tube is substantially smaller than the inner diameter of the casing and substantially equally large with the diameter of the outlet opening 14.
  • Inside the casing there is a feeding channel 20, which has a wall 22 having a conical shape. The first end of the feeding channel 20 extends through the outlet opening 14 into the mixing tube 18. The first end of the feeding channel extends preferably 20-30 mm into the mixing tube. The diameter of the first end of the feeding channel is substantially smaller than the diameter of the outlet opening, so that an annular slot remains between the edge of the outlet opening and the wall of the feeding channel, through which slot the exhaust gas can flow from the casing to the mixing tube. The feeding channel and the mixing tube have the same imaginary central axis, so the annular slot surrounding the first end of the feeding channel has a constant width. The feed hole 16 in the first end wall is located on the same central axis of the mixing tube and the feeding channel. The first end of the feeding channel is open and the second end of the feeding channel extends so as to be connected to the first end wall 13. The wall 22 of the feeding channel 20 has holes 24 in the entire area of the wall. The holes are relatively small in their size, and they are substantially evenly distributed to the entire surface area of the wall. The holes are preferably round holes having a diameter of couple of millimetres. The holes form a flowing route of the exhaust gas from the inside of the casing into the feeding channel. The exhaust gas can exit from the feeding channel to the mixing tube through the open first end of the feeding channel. Naturally, it is possible that the exhaust gas flows also through the wall of the feeding channel through some of the holes into the feeding channel and through some other holes back outside the feeding channel. Such back flow occurring through the holes is, however, so slight that it is not significant in view of the operation of the device.
  • The feeding channel 20 is located in the casing 10 in an eccentric manner, i.e. the imaginary central axis of the feeding channel does not pass through the midpoints of the end walls 13, 15 of the casing. The eccentric placement results in the fact that the width of the annular space between the outer jacket 11 of the casing and the wall 22 of the feeding channel, which width has been measured in the direction of the radius of the feeding channel, varies according to the measuring point. In the place of the inlet opening 12 there is a curved flow guide 17 formed of a metal plate, which flow guide surrounds the feeding channel from a distance from the feeding channel. As seen from the direction of the inlet opening the flow guide covers the feeding channel nearly entirely out of sight. The inlet opening 12 and the flow guide 17 defined by the fixing collar 19 guide the exhaust gas to the widest point of the annular space between the wall 22 of the feeding channel and the outer jacket 11 of the casing in the direction of the tangent of the wall of the feeding channel. The exhaust gas is thus guided to the spiral flow rotating inside the casing in one direction around the feeding channel.
  • The eccentric placement of the feeding channel results further in the fact that the flow route of the exhaust gas between the outer jacket of the casing and the wall 22 of the feeding channel rotating around the mixing tube tapers, i.e. the cross-sectional area of the flow route of the exhaust gas reduces in the flow direction of the exhaust gas. This leads to the increase of the pressure of the exhaust gas while the flow is advancing, what makes a part of the exhaust gas to flow through the holes 24 of the walls 22 of the feeding channel 20 into the feeding channel.
  • In the description presented above the wall of the feeding channel is in its entire length conical and the narrower end of the feeding channel leads to the outlet opening. However, it is possible, that the feeding channel has a conical portion and a cylindrical portion, i.e. the feeding channel is only along a part of its length conical. Further, it is conceivable, that the wider end of the feeding channel can lead to the outlet opening and the narrower end can extend to the first end wall, i.e. the feeding channel can extend in the flow direction of the exhaust gas. Furthermore, it is possible that the wall of the feeding channel has holes only in a part of the surface area of the wall of the feeding channel or that the total surface area, the shape and/or the size of the holes vary in different parts of the wall of the feeding channel.
  • In an operating situation, a feeding system of the reactive substance, such as urea/water solution, is connected to the aftertreatment device according to the invention, with the aid of a nozzle belonging to which feeding system, reactive substance is sprayed to the exhaust gas flowing in the feeding channel 20. The nozzle can be any nozzle suitable for injecting a liquid agent. Especially the nozzle and the entire feeding system for the urea/water solution can be a part of a more extensive system affecting the operation and control of the engine. The mixture of the exhaust gas and the reactive substance flowing through the feeding channel 20 to the mixing tube 18, forms the centre flow of the exhaust gas, and the exhaust gas flowing through the slot between the wall of the feeding channel and the edges of the outlet opening 14 forms the edge flow surrounding the centre flow. By feeding the reactive substance into the centre flow it is ensured that the reactive substance is evenly mixed with the exhaust gas and the passing of the reactive substance to the walls of the exhaust gas passage in a too early stage is prevented.
  • The urea/water solution is preferably fed with the nozzle to the exhaust gas flow in small drops. The urea included in the solution is under the influence of the heat of the exhaust gas turned into ammonia, which reacts with the nitrogen oxides (NOx) present in the exhaust gas, whereby nitrogen gas and water are generated. This reaction occurs in the SCR catalyser located in the exhaust gas passage, which catalyser is placed in the exhaust gas passage in the flow direction of the exhaust gas below the mixing tube 18 (the SCR catalyser is not shown in the figure). The vaporization of urea, its turning into ammonia and the mixing of the ammonia with the exhaust gas take place in the mixing tube and in the part of the exhaust gas passage between the mixing tube and the SCR catalyser.
  • The flow guide according to the invention suits especially well to be used in the cleaning processes according to the so-called SCR technique. The invention is, however, not limited only to the SCR technique or to the usage of the urea/water solution, but the reactive substance to be injected to the exhaust gas can also be some other agent, which is desired to be mixed evenly with the exhaust gas flow and/or to remain separated from the walls of the exhaust gas passage as long as possible. The reactive substance may thus be for example a urea solution, ammonia, some hydrocarbon-based reactive substance or fuel.
  • Some advantageous embodiments of the aftertreatment device according to the invention have been described above. The invention is not limited to the solutions described above, but it can be applied in different ways within the scope of the claims.

Claims (13)

  1. An exhaust gas aftertreatment device, which comprises a casing (10), which casing has an inlet opening (12) for the inflow of the exhaust gas, an outlet opening (14) for the outflow of the exhaust gas, a feed hole (16) for dispensing reactive substance to the casing, a mixing tube (18) extending from the outlet opening for mixing the exhaust gas and the reactive substance and a feeding channel (20) for guiding the exhaust gas to the mixing tube, which feeding channel has a wall (22), which wall has holes (24) for the inflow of the exhaust gas, and an open first end directed to the outlet opening, the cross-sectional area of which first end is smaller than the cross-sectional area of the outlet opening and which aftertreatment device has a swirl structure for guiding the exhaust gas led into the casing (10) to rotate around the feeding channel (20) in one direction of rotation, characterized in that said first end of the feeding channel (20) extends through the outlet opening (14) into the mixing tube (18).
  2. The aftertreatment device according to claim 1, characterized in that the casing (10) has an outer jacket (11), a first end wall (13) and a second end wall (15), whereby the feed hole (16) for feeding the reactive substance is located in the first end wall and the outlet opening (14) is located in the second end wall and the feeding channel (20) is located inside the outer jacket so that the feed hole (16) is directed into the feeding channel.
  3. The aftertreatment device according to claim 1 or 2, characterized in that the feeding channel (20) has a second end, the cross-sectional area of which second end is unequal to the cross-sectional area of the first end.
  4. The aftertreatment device according to claim 3, characterized in that the wall (22) of the feeding channel (20) has at least along a part of its length a conical shape.
  5. The aftertreatment device according to claim 3 or 4, characterized in that the cross-sectional area of the first end of the feeding channel (20) is smaller than the cross-sectional area of the second end.
  6. The aftertreatment device according to claim 3 or 4, characterized in that the cross-sectional area of the first end of the feeding channel (20) is larger than the cross-sectional area of the second end.
  7. The aftertreatment device according to any of the claims 3-6, characterized in that the second end of the feeding channel (20) is substantially connected to the first end wall (13) of the casing (10).
  8. The aftertreatment device according to any of the claims 1-7, characterized in that the cross-sectional area of the first end of the feeding channel (20) is substantially smaller than the cross-sectional area of the first end of the mixing tube (18).
  9. The aftertreatment device according to any of the claims 1-8, characterized in that the feed hole (16) is located to the first end wall (13) substantially on the imaginary central axis of the feeding channel (20).
  10. The aftertreatment device according to any of the claims 1-9, characterized in that said swirl structure comprises at least one flow guide (17) for guiding the exhaust gas flowing from the inlet opening (12) to the casing (10) to rotate around the feeding channel (20).
  11. The aftertreatment device according to any of the claims 1-10, characterized in that the feeding channel (20) is located in an eccentric manner to the casing (10) and the edge of the inlet opening (12) has a collar (19) for guiding the exhaust gas flow to the widest point of the slot between the outer jacket (11) of the casing and the wall of the feeding channel (20) in the direction of the tangent of the wall of the feeding channel.
  12. The aftertreatment device according to any of the claims 1-11, characterized in that it further comprises a substrate casing (30), inside of which an aftertreatment substrate (32) of the exhaust gas is located and which substrate casing has an inlet pipe (34) and an outlet connection (36), which outlet connection is connected to the inlet opening (12) of the casing.
  13. The aftertreatment device according to claim 12, characterised in that said aftertreatment substrate (32) is a particulate filter or an oxidation catalyst.
EP14807361.2A 2013-06-03 2014-06-02 Exhaust gas aftertreatment device Active EP3003543B1 (en)

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FI20135612A FI125946B (en) 2013-06-03 2013-06-03 Exhaust after-treatment device
PCT/FI2014/050443 WO2014195576A1 (en) 2013-06-03 2014-06-02 Exhaust gas aftertreatment device

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Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2985166B1 (en) * 2014-08-14 2017-08-02 CNH Industrial Italia S.p.A. Exhaust system for an off-road vehicle
US10179315B2 (en) * 2015-06-12 2019-01-15 Donaldson Company, Inc. Exhaust treatment device
GB2539711B (en) * 2015-06-26 2017-08-16 Proventia Emission Control Oy Method and apparatus for evenly mixing reactant to exhaust gas flow
DE102016004333A1 (en) 2016-04-13 2017-10-19 Roth Technik Austria Gesellschaft Mit Beschränkter Haftung Exhaust after-treatment device with catalyst and mixing device
GB2558222B (en) * 2016-12-22 2019-05-29 Perkins Engines Co Ltd Flow hood assembly
US10883411B2 (en) 2018-06-06 2021-01-05 Ford Global Technologies, Llc Systems and methods for an exhaust-gas aftertreatment device
EP3760846A1 (en) 2019-07-04 2021-01-06 Donaldson Company, Inc. System for mixing a liquid spray into a gaseous flow and exhaust aftertreatment device comprising same
CN113356981A (en) * 2021-07-19 2021-09-07 无锡威孚力达催化净化器有限责任公司 Sleeve pipe shunting urea mixing arrangement

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6722123B2 (en) 2001-10-17 2004-04-20 Fleetguard, Inc. Exhaust aftertreatment device, including chemical mixing and acoustic effects
WO2006009056A1 (en) 2004-07-16 2006-01-26 Nissan Diesel Motor Co., Ltd. Exhaust purification apparatus for engine
US8173088B2 (en) * 2010-02-24 2012-05-08 International Engine Intellectual Property Company, Llc Method, system and apparatus for liquid injection into a gas system
DE202007010324U1 (en) * 2007-07-25 2008-11-27 Heinrich Gillet Gmbh Apparatus for aftertreating the exhaust gases of diesel engines
US8297050B2 (en) * 2008-07-11 2012-10-30 GM Global Technology Operations LLC Nozzle diffuser mixer
JP2011064069A (en) * 2009-09-15 2011-03-31 Toyota Industries Corp Exhaust gas treatment system
EP2314837A1 (en) 2009-10-16 2011-04-27 Swenox AB Mixing apparatus for mixing an exhaust gas with a liquid
US8240137B2 (en) 2009-10-27 2012-08-14 Cummins Filtration Ip, Inc. Reductant injection and decomposition system
FR2957119B1 (en) 2010-03-02 2013-05-10 Peugeot Citroen Automobiles Sa CHAMBER FOR MIXING A REDUCING PRODUCT WITH EXHAUST GASES
US9670811B2 (en) * 2010-06-22 2017-06-06 Donaldson Company, Inc. Dosing and mixing arrangement for use in exhaust aftertreatment
SE535198C2 (en) 2010-09-30 2012-05-15 Scania Cv Ab Arrangement for introducing a liquid medium into exhaust gases from an internal combustion engine
FI20106317A0 (en) * 2010-12-14 2010-12-14 Proventia Emission Control Oy METHOD AND DEVICE FOR CLEANING THE EXHAUST GAS
DE102011120685A1 (en) 2011-12-09 2012-07-05 Daimler Ag Exhaust gas system for vehicle, has shielding element formed as cover and arranged on side of mixing pipe turned towards inlet for shielding feed unit against subjection with exhaust gas heat
DE102012010878A1 (en) 2012-06-01 2013-12-05 Daimler Ag Reductant addition and treatment system of a motor vehicle

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

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FI20135612A (en) 2014-12-04
WO2014195576A1 (en) 2014-12-11
US20160115848A1 (en) 2016-04-28
US9964016B2 (en) 2018-05-08
EP3003543A1 (en) 2016-04-13
FI125946B (en) 2016-04-29

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