EP2912285A1 - Systèmes et procédés ajustables destinés à améliorer l'efficacité d'un cycle kalina - Google Patents

Systèmes et procédés ajustables destinés à améliorer l'efficacité d'un cycle kalina

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Publication number
EP2912285A1
EP2912285A1 EP12883661.6A EP12883661A EP2912285A1 EP 2912285 A1 EP2912285 A1 EP 2912285A1 EP 12883661 A EP12883661 A EP 12883661A EP 2912285 A1 EP2912285 A1 EP 2912285A1
Authority
EP
European Patent Office
Prior art keywords
kalina cycle
working fluid
control system
stream
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12883661.6A
Other languages
German (de)
English (en)
Other versions
EP2912285A4 (fr
Inventor
Henry A. MLCAK
Mark D. Mirolli
Yakov Lerner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/597,132 external-priority patent/US9031705B2/en
Application filed by Individual filed Critical Individual
Publication of EP2912285A1 publication Critical patent/EP2912285A1/fr
Publication of EP2912285A4 publication Critical patent/EP2912285A4/fr
Withdrawn legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00—General layout or general methods of operation of complete plants
    • F01K13/02—Controlling, e.g. stopping or starting
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/06—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using mixtures of different fluids
    • F01K25/065—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using mixtures of different fluids with an absorption fluid remaining at least partly in the liquid state, e.g. water for ammonia

Definitions

  • the present invention relates to systems, methods, and apparatus adapted to increase the efficiency of a thermodynamic cycle.
  • the present invention relates to monitoring and adjusting various parameters of a Kalina Cycle to increase the overall efficiency of the cycle.
  • thermodynamic system can include Kalina Cycles.
  • a Kalina Cycle is a "closed-loop" thermodynamic cycle used in converting thermal energy to mechanical power by way of a turbine.
  • the Kalina Cycle's efficiency is at least partially dependent on temperatures of the heat source and the cooling source.
  • Turbines typically cannot directly use the "heat source” and "cooling source;” therefore, a medium, referred to as a "working fluid,” is used to go between the heat source and the cooling source.
  • a medium referred to as a "working fluid”
  • the heat from relatively hot liquids in a geothermal vent e.g., "brine”
  • the fluid is heated from a low energy and low temperature fluid state into a relatively high- temperature vapor.
  • the high-temperature vapor working fluid can then be passed through one or more turbines, causing the one or more turbines to spin and generate electricity.
  • the vapor expands and exits the turbine at a lower pressure and temperature.
  • the fluid After exiting the turbine, the fluid is condensed to a liquid in a condenser using a "cooling source.”
  • a higher cycle efficiency (and thus more power output) can be realized when the pressure differential between the turbine inlet and turbine exhaust is optimized. These pressures are dependent on the "heat source” and “cooling source” temperatures.
  • thermodynamic cycles utilize a working fluid that is a single (or pure) component fluid.
  • a working fluid that is a single (or pure) component fluid.
  • Pure working fluids like water, are typically limited in heat exchange between the heat and cooling sources. This is because pure fluids boil and condense at a constant temperature. This constant temperature can be in direct conflict with the variable temperature nature of most "heat” and “cooling” sources.
  • the constant versus variable temperature difference between the working fluid and heat/cooling sources is a thermodynamic structural difference that can result in efficiency losses in Rankine Cycle power plants.
  • Kalina Cycle plants differ from Rankine Cycle plants in at least one very distinctive way.
  • the working fluid in Kalina Cycle plants is typically an ammonia-water mixture.
  • Ammonia-water mixtures have many basic features unlike that of either pure water or pure ammonia. A mixture of the two fluids can perform like a totally new fluid.
  • the essence of the Kalina Cycle takes advantage of the ability of an ammonia-water mixture to boil and condense at a variable temperature - similar to the heat and cooling sources, and thus, better exchange energy with these sources. This can result in higher cycle efficiency.
  • the temperatures of the heating and cooling sources are determined. Based on this determination, the optimal concentration of the ammonia-water working fluid is calculated to allow the working fluid to best exchange energy with the heating and cooling sources, and thus, maximize the efficiency of the system.
  • various other parameters of the Kalina Cycle can influence the overall efficiency of the cycle.
  • Some such parameters include the pressure of the working fluid, and the flow rate of the working fluid in relation to the flow rate of the heating and or cooling source.
  • each of these parameters is optimized based on an initial determination of the heating and cooling source temperatures and other system parameters. Once these various parameters are initially set, some are rarely adjusted.
  • the heating and cooling sources may undergo change both slowly over time and in some cases rapidly. These changes in one or more of the heating and cooling sources can influence the efficiency of the Kalina Cycle. Furthermore, the reduction in efficiency due to these temperature swings is especially pronounced in applications where the difference between the heat source temperature and the cooling source temperature is low, e.g. low temperature geothermal applications.
  • a Kalina Cycle control system can include one or more sensors that monitor the heating source and the cooling source. The control system can then automatically adjust one or more of the operating parameters of the Kalina Cycle in response to detected changes in one or more of the heating or cooling source.
  • a Kalina Cycle control system can monitor one or more operating parameters of the Kalina Cycle, and can automatically adjust one or more of the operating parameters to increase the efficiency of the Kalina Cycle.
  • a control system for maximizing the efficiency of a Kalina Cycle of one or more implementations can include a control system processor.
  • the control system can also include one or more sensors adapted to measure one or more parameters of the Kalina Cycle, and transmit measured data to the control system processor.
  • the control system can further include one or more Kalina Cycle components adapted to be controlled by the control system processor to modify one or more additional parameters of the Kalina Cycle.
  • a method of increasing the efficiency of a Kalina Cycle of one or more implementations can involve collecting data at one or more sensors indicative of one or more parameters of the Kalina Cycle upon which the efficiency of the Kalina Cycle depends.
  • the method can also involve transmitting the data to a control system processor using one or more transmission mechanisms.
  • the method can involve calculating one or more actual parameters based upon the data using a control system processor.
  • the method can involve determining one or more optimal parameters that will increase the efficiency of the Kalina Cycle.
  • the method can further involve automatically adjusting the one or more actual parameters to the one or more optimal parameters.
  • an apparatus for implementing a thermodynamic cycle of one or more implementations can include an expander adapted to expand a multi-component vapor working stream transforming its energy into a useable form and producing a spent stream.
  • the apparatus can also include a separator adapted to separate the spent stream into a rich stream and a lean stream.
  • the apparatus can include a tank adapted to receive at least a portion of the lean stream from the separator and hold an amount of the lean stream therein.
  • the apparatus can further include a valve adapted to influence the volume flow rate of the lean stream exiting the tank.
  • the apparatus can include a mixer adapted to mix the lean stream exiting the tank with the rich stream producing a combined stream.
  • the apparatus can also include a condenser adapted to condense the combined stream producing a multi-component working stream.
  • the apparatus can further include a second heat exchanger adapted to heat the multi-component working stream producing the vapor working stream.
  • the apparatus can include a sensor adapted to measure a concentration ratio of multi-component working stream.
  • the apparatus can additionally include a control system adapted to automatically manipulate the valve to change the concentration ratio of the multi-component working stream in response to a change in a parameter of the thermodynamic cycle.
  • a control system for increasing the efficiency of a Kalina Cycle includes a control system processor and one or more sensors adapted to measure one or more parameters of the Kalina Cycle and transmit measured data to the control system processor.
  • the one or more parameters include a concentration of a basic working fluid within the Kalina Cycle.
  • the system also includes a first set of one or more Kalina Cycle components adapted to be controlled by the control system processor to modify the concentration of the basic working fluid without modifying an equilibrium concentration of the working fluid in the Kalina Cycle.
  • the system includes a second set of one or more Kalina Cycle components adapted to be controlled by the control system processor to modify the concentration of the basic working fluid in connection with modifying an equilibrium concentration of the working fluid in the Kalina Cycle.
  • Another implementation of a method of increasing the efficiency of a Kalina Cycle involves collecting data at one or more sensors indicative of one or more parameters of the Kalina Cycle upon which the efficiency of the Kalina Cycle depends.
  • the one or more parameters comprise a concentration of a basic working fluid within the Kalina Cycle.
  • the method involves transmitting the data to a control system processor using one or more transmission mechanisms and calculating one or more actual parameters based upon the data using a control system processor.
  • the method also includes determining a concentration of the working fluid that will increase the efficiency of the Kalina Cycle.
  • the method involves automatically adjusting an equilibrium concentration of basic working fluid in the Kalina Cycle.
  • the method involves adjusting the concentration of the basic working fluid mixture in the Kalina Cycle.
  • an apparatus for implementing a thermodynamic cycle includes a Kalina Cycle system, a first external tank holding rich working fluid or lean working fluid, and a control system.
  • the Kalina Cycle system includes an expander adapted to expand a multi-component vapor working stream transforming its energy into a useable form and producing a spent stream.
  • the Kalina Cycle system also includes a separator adapted to separate the spent stream into a rich stream and a lean stream.
  • the Kalina Cycle system includes a first tank adapted to receive at least a portion of the lean stream from the separator and hold an amount of the lean stream therein.
  • the Kalina Cycle system includes a mixer adapted to mix the lean stream exiting the first tank with the rich stream producing a combined stream.
  • the Kalina Cycle system also includes a condenser adapted to condense the combined stream producing a multi- component working stream.
  • the Kalina Cycle system additionally includes a second heat exchanger adapted to heat the multi-component working stream producing the multi- component vapor working stream.
  • the first external tank is coupled to the Kalina cycle system and adapted to add rich working fluid or lean working fluid to the Kalina Cycle system.
  • the control system is adapted to automatically add rich working fluid or lean working fluid from the first external tank to the Kalina Cycle system to change an equilibrium concentration of basic working fluid in the Kalina Cycle system.
  • FIG. 1 illustrates a schematic diagram of a Kalina Cycle energy conversion system, including a control system in accordance with an implementation of the present invention
  • Figure 2 illustrates an exemplary graph of a relationship between cooling source temperature and the ammonia concentration for the Kalina Cycle of Figure 1 in accordance with an implementation of the present invention
  • Figure 3 illustrates a schematic diagram of the Kalina Cycle of Figure 1 in which the control system has adjusted the concentration of the basic working fluid mixture in response to an increase in the temperature of the cooling source;
  • Figure 4 illustrates a schematic diagram of the Kalina Cycle of Figure 1 in which the control system has adjusted the concentration of the basic working fluid mixture in response to a decrease in the temperature of the cooling source;
  • FIG. 5 illustrates a schematic diagram of another Kalina Cycle energy conversion system, including a control system in accordance with an implementation of the present invention
  • Figure 6 illustrates an exemplary graph of a potential relationship between ammonia concentration and efficiency of a Kalina Cycle at different turbine inlet pressures
  • FIG. 7 illustrates a schematic diagram of yet another Kalina Cycle energy conversion system, including a control system in accordance with an implementation of the present invention
  • Figure 8A illustrates a schematic diagram of the Kalina Cycle of Figure 7 in which the control system has increased an equilibrium concentration and increased the concentration of the basic working fluid mixture;
  • Figure 8B illustrates a schematic diagram of the Kalina Cycle of Figure 7 in which the control system has decreased an equilibrium concentration and decreased the concentration of the basic working fluid mixture
  • FIG. 9 illustrates a schematic diagram of still one other Kalina Cycle energy conversion system, including a control system in accordance with an implementation of the present invention.
  • a Kalina Cycle control system can include one or more sensors that monitor the heating source and the cooling source. The control system can then automatically adjust one or more of the operating parameters of the Kalina Cycle in response to detected changes in one or more of the heating or cooling source.
  • a Kalina Cycle control system can monitor one or more operating parameters of the Kalina Cycle, and can automatically adjust one or more of the operating parameters to increase the efficiency of the Kalina Cycle.
  • the various implementations of the present invention may be implemented with a closed-loop thermodynamic system which utilizes a multi-component working fluid, such as a Kalina Cycle system. While it is understood that the invention may be incorporated into a variety of different types of thermodynamic cycle systems, reference will be made herein specifically to a Kalina Cycle system. The particular Kalina Cycles illustrated and described herein are only examples of a few of the various Kalina Cycles with which the present invention may be implemented. Other exemplary Kalina Cycle technologies with which the present invention may be implemented are illustrated in U.S. Patent Nos. 7,516,619; 5,822,990; 5,953,918; 5,572,871; 5,440,882 and 4,982,568, the contents of each of which are hereby incorporated by reference in their entirety.
  • one or more implementations of the present invention can include a control system, and related methods, for monitoring the concentration of the basic working fluid in a Kalina Cycle, the temperature of the heat source for the Kalina Cycle, and/or the temperature of the cooling source of the Kalina Cycle. Whenever the heat source temperature and/or cooling source temperature changes, the control system can adjust the concentration of the basic working fluid of the Kalina Cycle accordingly to increase the efficiency of the Kalina Cycle, and thus, increase the power output of the Kalina Cycle.
  • Kalina Cycles where one or more of the temperatures of the heat source or cooling source are dynamic.
  • Kalina Cycles can include cycles that utilize waste energy from a process plant, such as, for example, a steel mill or foundry as a heat source.
  • the process plant may have batch type operations which result is heat source temperatures that cycle hourly, or even more frequently.
  • Figure 1 illustrates a schematic of a Kalina Cycle 100 including a control system 130.
  • the control system 130 can adjust the concentration of the basic working fluid of the Kalina Cycle 100 based on a change in temperature of one or more of a heat source 122 and a cooling source 124.
  • the control system 130 can adjust the concentration of the basic working fluid to increase, or optimize, the efficiency of the Kalina Cycle 100.
  • the Kalina Cycle 100 can include a first heat exchanger or condenser 104, a feed pump 106, a second heat exchanger 108, a third heat exchanger or evaporator 110, and a turbine 112. Additionally, the Kalina Cycle 100 can include a separator 114, a drain tank 116, a drain pump 118, and a tank 120. As explained in greater detail below, the Kalina Cycle 100 can work with an external heating source 122 and an external cooling source 124.
  • the working fluid (an ammonia-water mixture) has a certain set of parameters at point 11 , referred to herein after as the basic mixture or basic working fluid mixture.
  • the working fluid is then pumped to a higher pressure by pump 106 to create a pressurized working fluid at point 12.
  • the pressurized working fluid then passes through the second heat exchanger 108, where it is preheated by the stream exiting the turbine 112 to create a preheated working fluid at point 14.
  • the preheated working fluid then passes through heat exchanger 110, where it is heated by the external heat source 122 to create an at least partially evaporated working stream at point 16.
  • the at least partially evaporated working stream then passes through the turbine 112, and drives the turbine 112 to generate mechanical energy that is converted into electrical energy by a generator 126.
  • the working stream expands, and exits the turbine 112 as a low- pressure working stream or an at least partially spent stream at point 18.
  • the low-pressure working stream then passes through the secondary side of the second heat exchanger 108 to preheat the pressurized working fluid, as mentioned above.
  • the low-pressure working stream is cooled to create a partially condensed working stream or cooled spent stream at point 20.
  • the partially condensed working stream then enters separator 114.
  • the separator 114 divides the partially condensed working stream into a lean (low in ammonia content relative to the basic mixture) stream at point 22, and a rich (high in ammonia content relative to the basic mixture) vapor stream at point 24. That is, the lean stream contains less ammonia by weight than the basic working fluid. By contrast, the rich stream contains more ammonia by weight that the basic working fluid.
  • the lean stream passes into drain tank 116, and is then pumped by drain pump 118 to a higher pressure to create a pressurized lean stream at point 26.
  • the pressurized lean stream is then sprayed or mixed with the rich vapor stream as they both enter the condenser 104 to create a combined stream at point 28. Spraying the lean liquid stream into the rich vapor stream can aid in condensing the rich vapor stream.
  • the combined stream 28 is cooled within the condenser 104 by the external cooling source 124 to create the basic mixture at point 10.
  • the basic mixture then enters the tank 120. The process is then repeated in a closed loop arrangement.
  • control system 130 can monitor the parameters of the working fluid at the various points in the Kalina Cycle 100. Additionally, the control system 130 can also monitor one or more of the heat source 122 temperature and the cooling source 124 temperature. Based on the measured parameters of the working fluid and the temperatures of the heating and cooling sources, the control system can optimize or otherwise modify the concentration of the working fluid to increase the efficiency of the Kalina Cycle 100. In other words, the control system 130 can increase or decrease the amount of ammonia in the basic working fluid mixture to influence the efficiency of the Kalina Cycle 100.
  • control system 130 can include a first sensor 128 that measures a parameter of the cooling source 124.
  • a transmission mechanism A can transmit data recorded or measured by the sensor 128 to a control system processor or computer of the control system 130.
  • the transmission mechanism A can send data to the system processor of the control system 130 via a universal serial bus (USB) connection, serial connection, parallel connection, wireless connection, Bluetooth connection, and/or any other communication connection.
  • USB universal serial bus
  • the sensor 128 can be a temperature sensor adapted to measure the temperature of the cooling source 124 and transmit the cooling source 124 temperature to the control system processor or computer of the control system 130. In another embodiment, sensor 128 can be adapted to measure other characteristics or parameters of the cooling source, such as fluid flow properties like flow rate for example.
  • the control system processor of the control system 130 is located on site with the Kalina Cycle 100. According to alternative implementations of the present invention, the control system processor of the control system 130 is located remotely from the site of the Kalina Cycle 100.
  • control system 130 can include a sensor 132 that measures the density (or ammonia-water concentration) of the basic working fluid.
  • a transmission mechanism B can transmit data recorded or measured by the sensor 132 to a control system processor or computer of the control system 130.
  • the transmission mechanism B can send data to the system processor of the control system 130 via a universal serial bus (USB) connection, serial connection, parallel connection, wireless connection, Bluetooth connection, and/or any other communication connection.
  • USB universal serial bus
  • the control system 130 can also include a drain tank level transmitter 134 that measures the level of the lean stream within the drain tank 116.
  • a transmission mechanism can transmit data recorded or measured by the sensor 132 to a control system processor or computer of the control system 130.
  • the transmission mechanism can send data to the system processor of the control system 130 via a universal serial bus (USB) connection, serial connection, parallel connection, wireless connection, Bluetooth connection, and/or any other communication connection.
  • USB universal serial bus
  • the control system 130 can include a drain tank level control valve 136, which allows the control system 130 to control the amount or level of the lean liquid stream within the drain tank 116.
  • control system 130 can calculate, or can download, the relationship between the optimal basic mixture concentration (percent of ammonia in the basic mixture) and the cooling source temperature.
  • a graph of this relationship for the Kalina Cycle 100 using an external heat source 122 having a temperature of 310° F is illustrated in Figure 2.
  • the math function for the curve depicted in Figure 2 is:
  • the control system can measure the temperature of the cooling source 124 using the sensor 128. Based on the measured temperature, which according to one or more implementations of the present invention is an average temperature over a given period of time (e.g., 15 to 30 minutes), the processor of the control system 130 can calculate the optimal ammonia to water concentration of the basic mixture that will produce the maximum efficiency for the Kalina Cycle 100. The control system then measures the actual concentration of the basic mixture using sensor 132. Thereafter, the control system 130 can compare the optimal ammonia to water concentration with the actual ammonia to water concentration.
  • the measured temperature which according to one or more implementations of the present invention is an average temperature over a given period of time (e.g., 15 to 30 minutes)
  • the processor of the control system 130 can calculate the optimal ammonia to water concentration of the basic mixture that will produce the maximum efficiency for the Kalina Cycle 100.
  • the control system measures the actual concentration of the basic mixture using sensor 132. Thereafter, the control system 130 can compare the optimal ammonia to water concentration with the actual ammonia to
  • the control system 130 can increase the ammonia concentration in the basic mixture.
  • the control system 130 can determine the actual level of the lean stream in the drain tank 116 using the drain tank level transmitter 134.
  • the control system 130 can then automatically set the target level of the drain tank to a "higher" set -point, and automatically adjust the drain tank level control valve 136 to maintain the new set-point level. In this case, the control system 130 will restrict the flow of the pressurized lean stream through the drain tank level control valve 136 until the level of the lean stream in the drain tank 116 reaches the new set-point level.
  • the control system 130 can reduce the water concentration in the working fluid cycling through the system 100 and thereby increase the ammonia concentration of the basic mixture.
  • the control system 130 can reduce the water concentration in the working fluid cycling through the system 100 and thereby increase the ammonia concentration of the basic mixture.
  • more of the lean stream is stored within the drain tank 116, more of the basic mixture stored within the tank 120 is removed and allowed to circulate through the Kalina Cycle 100 to maintain a consistent amount of working fluid.
  • Figure 1 illustrates the Kalina Cycle 100 in which the control system has adjusted or optimized the concentration of the basic mixture to 86.9% ammonia and 13.1% water in light of a cooling source temperature of 70° F.
  • Figure 3 illustrates the Kalina Cycle 100 in which the control system has adjusted the level of lean stream in the drain tank 116 in response to an increase in temperature of the cooling source 124 to 100° F.
  • the control system has adjusted the concentration of the basic mixture to 90.0% ammonia and 10.0% water.
  • the Kalina Cycle 100 in Figure 3 includes a greater amount of lean stream stored in the drain tank 116 compared to the Kalina Cycle 100 of Figure 1.
  • the Kalina Cycle 100 of Figure 3 also has a smaller amount of basic mixture stored in tank 120, than the Kalina Cycle 100 of Figure 1.
  • the equilibrium concentration (the ammonia-water mixture that would result if all the ammonia and water fluids within the various parts of the Kalina Cycle 100 were mixed together in a single vessel) can remain constant.
  • the equilibrium composition is the average composition of fluid in the Kalina Cycle 100, if all of the fluids in the Kalina Cycle 100 were mixed together. This is because the Kalina Cycle 100 is a closed system.
  • the Kalina Cycle 100 of the present invention may include an increased amount of working fluid when compared to a conventional Kalina Cycle.
  • both the drain tank 116 and the tank 120 can include substantially increased storing capacity to allow the Kalina Cycle 100 to store the additional working fluid.
  • the concentration of the lean stream and rich stream in the other parts of the Kalina Cycle 100 can automatically adjust based upon the concentration of the basic mixture.
  • the concentration of both the lean stream and the rich vapor stream can automatically adjust based on the concentration of the basic mixture as shown in Figures 1 and 3.
  • the lean stream in the drain tank 116 of Figure 1 can have a concentration of 56.6% ammonia and 43.4% water. This concentration can automatically adjust as the control system 130 changes the concentration of the basic working fluid.
  • the lean stream in the drain tank 116 of Figure 3 can automatically adjust to a concentration of 65.1% ammonia and 34.9% water.
  • the rich stream at point 24 of Figure 1 can have a concentration of 99.6% ammonia and 0.4% water. This concentration can automatically adjust as the control system 130 changes the concentration of the basic working fluid. For instance, the rich stream at point 24 of Figure 3 can automatically adjust to a concentration of 99.7% ammonia and 0.3% water.
  • control system 130 can also, or alternatively, reduce the ammonia concentration due to a decrease in cooling source 124 temperature.
  • the control system 130 can measure the temperature of the cooling source 124 using the sensor 128. Based on the measured temperature, the processor of the control system 130 can calculate the optimal ammonia to water concentration of the basic mixture that produces the maximum efficiency for the Kalina Cycle 100. The control system 130 then can measure the actual concentration of the basic mixture using sensor 132. Thereafter, the control system 130 can compare the optimal ammonia to water concentration with the actual ammonia to water concentration.
  • the control system 130 can decrease the ammonia concentration in the basic mixture.
  • the control system 130 can determine the actual level of the lean stream in the drain tank 116 using the drain tank level transmitter 134.
  • the control system can then automatically set the target level of the drain tank to a "lower" set-point, and automatically adjust the drain tank level control valve 136 to maintain the new set-point level.
  • the control system 130 can increase the flow of the pressurized lean stream through the drain tank level control valve 136 until the level of the lean stream in the drain tank 116 reaches the new set-point level.
  • the control system 130 can increase the water concentration in the working fluid cycling through the system 100, and thereby, decrease the ammonia concentration of the basic mixture. According to one or more implementations of the present invention, as less of the lean stream is stored within the drain tank 116, more of the basic mixture is stored within the tank 120 to maintain a consistent amount of working fluid circulating through the Kalina Cycle 100.
  • Figure 4 illustrates the Kalina Cycle 100 in which the control system 130 has adjusted the level of lean stream in the drain tank 116 in response to a decrease in temperature of the cooling source 124 to 40° F.
  • the control system 130 has adjusted the concentration of the basic mixture to 84.9% ammonia and 15.1% water.
  • the Kalina Cycle 100 in Figure 4 includes a lesser amount of lean stream stored in the drain tank 116 compared to the Kalina Cycle 100 of Figure 1.
  • the Kalina Cycle 100 of Figure 4 also has a greater amount of basic mixture stored in tank 120, than the Kalina Cycle 100 of Figure 1.
  • the concentration of the lean stream and rich stream in the other parts of the Kalina Cycle 100 can automatically adjust based upon the concentration of the basic mixture.
  • the concentration of both the lean stream and the rich vapor stream can automatically adjust based on the concentration of the basic mixture as shown in Figures 1 and 4.
  • the lean stream in the drain tank 116 of Figure 1 can have a concentration of 56.6% ammonia and 43.4% water. This concentration can automatically adjust as the control system 130 changes the concentration of the basic working fluid.
  • the lean stream in the drain tank 116 of Figure 4 can automatically adjust to a concentration of 51.0% ammonia and 49.0% water.
  • the rich stream at point 24 of Figure 1 can have a concentration of 99.6% ammonia and 0.4% water. This concentration can automatically adjust as the control system 130 changes the concentration of the basic working fluid. For instance, the rich stream at point 24 of Figure 4 can automatically adjust to a concentration of 99.5% ammonia and 0. 5% water.
  • control system 130 measures the temperature of the cooling source 124 and adjusts the concentration of the basic mixture in response
  • the present invention is not so limited.
  • the control system 130 can measure the temperature of the condensed working fluid exiting the condenser 124, or other related parameters.
  • the control system 130 can include a tank level transmitter 139 for monitoring the amount of basic mixture stored in tank 120.
  • the control system 130 can adjust the concentration of the basic mixture in response to a change in the temperature of the heat source 122.
  • the control system 130 can include a sensor 138, such as a temperature sensor, that measures a parameter of the heating source 122, such as temperature, for example.
  • a transmission mechanism D can send data from the sensor 138 to the system processor of the control system 130 via a universal serial bus (USB) connection, serial connection, parallel connection, wireless connection, Bluetooth connection, and/or any other communication connection.
  • USB universal serial bus
  • sensor 138 can be adapted to measure flow rates and/or other characteristics or parameters of the heating source 122 which may influence the degree of heat transfer from the heat source 122 to the working stream.
  • the processor of the control system 130 can calculate the optimal ammonia to water concentration of the basic mixture that produces the maximum efficiency for the Kalina Cycle 100.
  • the control system 130 then can measure the actual concentration of the basic mixture using sensor 132. Thereafter, the control system 130 can compare the optimal ammonia to water concentration with the actual ammonia to water concentration.
  • the control system 130 can decrease the ammonia concentration in the basic mixture.
  • the control system 130 can determine the actual level of the lean stream in the drain tank 116 using the drain tank level transmitter 134.
  • the control system can then automatically set the target level of the drain tank to a "lower" set-point, and automatically adjust the drain tank level control valve 136 to maintain the new set-point level.
  • the control system 130 can increase the flow of the pressurized lean stream through the drain tank level control valve 136 until the level of the lean stream in the drain tank 116 reaches the new set-point level.
  • the control system 130 can increase the ammonia concentration in the basic mixture.
  • the control system 130 can determine the actual level of the lean stream in the drain tank 116 using the drain tank level transmitter 134.
  • the control system 130 can then automatically set the target level of the drain tank to a "higher" set- point, and automatically adjust the drain tank level control valve 136 to maintain the new set- point level. In this case, the control system 130 will restrict the flow of the pressurized lean stream through the drain tank level control valve 136 until the level of the lean stream in the drain tank 116 reaches the new set-point level.
  • control system 130 can be programmed to "anticipate" normal cyclic changes in the cooling or heat source temperatures (or predicted temperature changes) in order to change the concentration in advance of real (or actual) cooling or heat source temperature changes.
  • air temperature cycles during a given day can be very predicable, and thus a bias in the controls can be implemented for the anticipated "rising" temperature in the morning to early afternoon, and the “decreasing" temperature in the evening and night.
  • FIG. 5 illustrates a schematic diagram of a Kalina Cycle 200.
  • the Kalina Cycle 200 is similar to the Kalina Cycle 100 illustrated in Figures 1, 3, and 4; however, it includes a fourth heat exchanger 502 and a separator 504.
  • the working fluid (an ammonia- water mixture) has a certain set of parameters at point 10, referred to herein after as the basic mixture.
  • the working fluid is then pumped to a higher pressure by pump 106 to create a pressurized working fluid at point 12.
  • the pressurized working fluid then passes through the second heat exchanger 108, where it is preheated to create a preheated working fluid at point 14.
  • the preheated working fluid then passes through the fourth heat exchanger 502 where it is further heated and optionally partially evaporated to create a further heated working fluid at point 30.
  • the further heated working fluid is then passed through the third heat exchanger 110, where it is heated by the external heat source 122 to create an at least partially evaporated working stream at point 16.
  • the at least partially evaporated working stream then passes into and through a separator 504.
  • the separator 504 separates the at least partially evaporated working stream in to a rich vapor component at point 32, and a lean saturated liquid component at point 34.
  • the rich vapor component enters and drives the turbine 112 to generate mechanical energy that is converted into electrical energy by a generator 126. Within the turbine 112, the working stream expands to a form a low-pressure working stream or spent stream at point 18.
  • the lean saturated liquid component is cooled in the fourth heat exchanger 502 (by heating the preheated working fluid) and creates a partially cooled lean component at point 36.
  • the partially cooled lean component then is combined with the low-pressure working stream or spent stream to create a combined spent stream at point 38, which then passes through the second heat exchanger 108 where it is cooled by heating the pressurized working fluid to create a partially condensed working stream at point 20.
  • the partially condensed working stream then enters separator 114.
  • the separator 114 divides the partially condensed working stream into a lean (low in ammonia content relative to the basic mixture) liquid stream at point 22, and a rich (high in ammonia content relative to the basic mixture) vapor stream at point 24.
  • the lean stream passes into drain tank 116, and is then pumped by drain pump 118 to a higher pressure to create a pressurized lean stream at point 26.
  • the pressurized lean stream is then sprayed or mixed with the rich vapor stream as they both enter the condenser 104 to create a combined stream at point 28. Spraying the lean liquid stream into the rich vapor stream can aid in condensing the rich vapor stream.
  • the combined stream 28 is cooled within the condenser 104 by the external cooling source 124.
  • the cooled combined stream becomes the basic mixture upon exiting the condenser 104, which then enters the tank 120.
  • the process is then repeated in a
  • the control system 130 can include a first separator tank level transmitter 506 that measures the level of the lean saturated liquid component within the separator 504.
  • a transmission mechanism F can send data from the separator tank level transmitter 506 to the system processor of the control system 130 via a universal serial bus (USB) connection, serial connection, parallel connection, wireless connection, Bluetooth connection, and/or any other communication connection.
  • the control system 130 can include a separator tank level control valve 508, which allows the control system 130 to control the amount of lean saturated liquid component within the tank of the separator 504 via a control mechanism G.
  • the control mechanism G can comprise a communication mechanism similar to those described above in relation to transmission mechanisms A, C, D, and E, and an actuator adapted to open and close the valve 508.
  • the control system 130 can adjust the level of lean saturated liquid component within the separator 504 to adjust the concentration of the basic mixture in response to a change in the temperature of the cooling source 124 and/or the heat source 122.
  • the control system 130 can adjust the level of the lean saturated liquid component within the tank of the separator 504 in a manner similar to that described above in relation to the adjusting the level of the lean stream within the drain tank 116.
  • the control system 130 can set a target level and then adjust the separator tank level control valve 508 accordingly so the level of fluid within the tank of the separator 504 either increases or decreases.
  • the control system 130 can adjust both the level of the lean saturated liquid component within the separator 504 and the level of the lean stream in the drain tank 116 to adjust the concentration of the basic mixture.
  • control system 130 can rapidly adjust the concentration of the basic mixture. Indeed, in one or more implementations of the present invention, the control system 130 can adjust the concentration of the basic mixture daily, hourly, or in response to a temperature change of one or more of the heat source 122 and cooling source 124. In one or more implementations of the present invention, the control system 130 can monitor and adjust the basic mixture in response to a temperature change of one or more of the heat source 122 and cooling source 124 in real time.
  • FIG. 6 depicts a graph illustrating a potential relationship between ammonia concentration of working fluid and efficiency of a Kalina Cycle based upon the pressure of the working fluid at the turbine inlet.
  • One or more implementations of a control system 130 of the present invention can calculate or download a similar relationship based upon the particular parameters of the Kalina Cycle which it controls. Using this information, the control system 130 can monitor the concentration of the basic mixture and automatically adjust the pressure at the turbine inlet accordingly to help ensure that the Kalina Cycle runs at an increased or maximum efficiency.
  • the control system 130 can monitor the concentration of the basic mixture using the sensor 132. Furthermore, according to one or more implementations of the present invention the sensor 132 can also measure the temperature and flow rate of the basic mixture. Based upon the measured concentration of the basic mixture, the processor of the control system 130 can calculate the turbine inlet pressure that will maximize the efficiency of the Kalina Cycle 100 using the graph illustrated in Figure 6 or similar data. The control system 130 can then measure the actual pressure at the turbine 112 using a turbine inlet pressure sensor 140.
  • a transmission mechanism E can send data from the sensor 140 to the system processor of the control system 130 via a universal serial bus (USB) connection, serial connection, parallel connection, wireless connection, Bluetooth connection, and/or any other communication connection.
  • USB universal serial bus
  • the control system 130 can measure the flow rate of the working fluid at the turbine 112 inlet and then calculate the pressure.
  • the control system 130 can adjust the actual turbine inlet pressure.
  • the control system 130 can adjust the output of pump 106, and thus, adjust the turbine inlet pressure.
  • the control system 130 can monitor and adjust the turbine inlet pressure to help ensure the Kalina Cycle is running at maximum efficiency.
  • concentration and turbine inlet pressure are just two exemplary parameters that the control system 130 of the present invention can monitor and automatically adjust to maximize the efficiency of a Kalina Cycle. Indeed, one or more implementations of the present invention can monitor any number of different cycle parameters upon which the efficiency of a given Kalina Cycle is based and automatically adjust the parameters to help the efficiency of the Kalina Cycle.
  • the Kalina Cycle has been described herein as a closed cycle; however, because turbine seals are imperfect, small amounts of rich vapor being expanded in the turbine can escape from the Kalina Cycle. Overtime this loss of working fluid can have negative affects on the operating efficiency of the Kalina Cycle by both reducing the amount of working fluid circulating through the Kalina Cycle and by adjusting the concentration of the working fluid.
  • One or more implementations of the present invention can monitor the amount of working fluid circulating in the Kalina Cycle by using the drain tank level transmitter 134 and the tank level transmitter 139. The control system 130 can then use the drain tank level control valve 136 to allow more working fluid to circulate in the Kalina Cycle, and thereby, account for any losses via the turbine seals. Additionally, the control system 130 can adjust the concentration of the basic mixture as described herein above to compensate for any change due to rich vapor leaking at the turbine seals.
  • Implementations of the present invention can also include methods of implementing and increasing the efficiency of a thermodynamic cycle.
  • the following describes at least one implementation of a method of increasing the efficiency of a Kalina cycle with reference to the components and diagrams of Figures 1 through 6.
  • the method can include an act of collecting data at one or more sensors indicative of one or more parameters of the Kalina Cycle upon which the efficiency of the Kalina Cycle depends.
  • the method can include measuring the temperature of one or more of a heat source 122 and a cooling source 124 using one or more temperature sensors 128, 138. Additionally, the method can include measuring the density of a basic working fluid mixture of the Kalina Cycle using a density sensor 132. Furthermore, the method can include measuring a turbine inlet pressure of a working fluid of the Kalina Cycle using a pressure sensor 140.
  • the method can also include an act of transmitting the data to a control system processor using one or more transmission mechanisms.
  • the method can include transmitting the temperature of one or more of a heat source 122 and a cooling source 124 to a processor of a control system 130 using a transmission mechanism A, D.
  • the method can include transmitting the concentration of a working fluid to a processor of a control system 130 using transmission mechanism B.
  • the method can include transmitting a turbine inlet pressure of a working fluid to a processor of a control system 130 using transmission mechanism E.
  • the method can additionally include an act of calculating one or more actual parameters based upon the data using a control system processor.
  • the method can include calculating the actual concentration of the working fluid, the actual amount of working fluid within the Kalina Cycle, or the actual pressure of the working fluid at a turbine inlet.
  • the method can include an act of determining one or more optimal parameters that will increase the efficiency of the Kalina Cycle. For instance, the method can involve calculating an optimum working fluid concentration based on the actual temperature of the heating and/or cooling source. Additionally, or alternatively, the method can include calculating an optimum working fluid concentration based on the actual pressure of the working fluid at the turbine inlet.
  • the method can also include an act of automatically adjusting the one or more actual parameters to the one or more optimal parameters.
  • the method can include adjusting the concentration of the basic working fluid mixture by manipulating a drain tank control valve 136 or a separator tank level control valve 508.
  • the method can include adjusting the turbine inlet pressure of a working fluid of the Kalina Cycle by adjusting the output of a pump 106.
  • Kalina Cycle can include methods and systems for adjusting concentration levels of the working fluid in response to temperature changes of the heat source and/or of the cooling source.
  • the control system can increase concentration of ammonia, with increased temperature of the cooling source, in order to maximize or increase the amount of energy generated by the Kalina Cycle.
  • one or more implementations include a Kalina Cycle system that may require a relatively large amount of ammonia in order to increase the total ammonia concentration within the system.
  • the Kalina Cycle system can include one or more external storage tanks, which can accommodate storage of fluid. More specifically, the Kalina Cycle system can incorporate one or more lean stream (or lean fluid) storage tanks and/or one or more rich fluid storage tanks.
  • the external storage tanks can facilitate addition of fluid with high and/or low ammonia concentration into the Kalina Cycle.
  • the external storage tanks also can facilitate removal of fluid with high and/or low ammonia concentration from the Kalina Cycle. Accordingly, the external storage tanks can provide additional flexibility to the Kalina Cycle (especially in large systems), which may allow the Kalina Cycle to operate more efficiently in environments that have relatively large temperature fluctuations.
  • a Kalina Cycle 300 can include a first heat exchanger or condenser 104, a feed pump 106, a second heat exchanger 108, the third heat exchanger or evaporator 110, and a turbine 112.
  • the Kalina Cycle 300 also can include a separator 114, a drain tank 116, a drain pump 118, and a tank 120. As explained above in connection with the Kalina Cycle 100 ( Figure 1), the Kalina Cycle 300 also can work with the external heating source 122 and the external cooling source 124.
  • the Kalina Cycle 300 can include a rich fluid external storage tank 702 and a lean fluid external storage tank 704.
  • the Kalina Cycle 300 can have one or more connections from the rich fluid external storage tank 702 to the tank 120, as further described below.
  • the Kalina Cycle 300 also can provide one or more connections from the lean fluid external storage tank 704 to the drain tank drain tank 116.
  • the working fluid has a certain set of parameters at points 10, 11.
  • the working fluid is then pumped to a higher pressure by the feed pump 106, to create a pressurized working fluid at point 12.
  • the pressurized working fluid then passes through the second heat exchanger 108, where it is preheated to create the preheated working fluid at point 14.
  • the preheated working fluid is then passed through the evaporator 110, where it is heated by the external heat source 122 to create an at least partially evaporated working stream at point 16.
  • the at least partially evaporated working stream enters and drives the turbine 112 to generate mechanical energy that is converted into electrical energy by the generator 126.
  • the working stream expands to a form the low- pressure working stream or spent stream at point 18.
  • the low-pressure working stream then passes through the secondary side of the second heat exchanger 108 to preheat the pressurized working fluid, as mentioned above.
  • the low-pressure working stream is cooled to create a partially condensed working stream or cooled spent stream at point 20.
  • the partially condensed working stream then enters the separator 114.
  • the separator 114 divides the partially condensed working stream into the lean (low in ammonia content relative to the basic mixture) stream at point 22, and the rich (high in ammonia content relative to the basic mixture) vapor stream at point 24.
  • the lean stream can pass into the drain tank 116, and can be then pumped by the drain pump 118 to a higher pressure to create a pressurized lean stream at point 26. Additionally or alternatively, as further described below, the lean stream can pass into the lean fluid external storage tank 704.
  • the pumped and pressurized lean liquid stream (at point 26) is then sprayed or mixed with the rich vapor stream as they both enter the condenser 104 to create a combined stream at point 28. Spraying the lean liquid stream into the rich vapor stream can aid in condensing the rich vapor stream.
  • the combined stream is cooled within the condenser 104 by the external cooling source 124 to create the basic mixture at point 10. Subsequently, the basic mixture at point 10 can enter the tank 120 and/or the rich fluid external storage tank 702. The process is then repeated in a closed loop arrangement.
  • control system 130 can adjust the amount of lean stream stored in the drain tank 116. More specifically, to increase concentration of ammonia in the basic working fluid control system 130, using the drain tank level transmitter 134a, can automatically increase the level of lean stream stored in the drain tank 116. Conversely, to decrease concentration of ammonia in the working fluid, control system 130 can decrease the amount of lean stream stored in the drain tank 116.
  • the rich fluid external storage tank 702 and the lean fluid external storage tank 704 can be considered to be external to the Kalina Cycle 300. Accordingly, any fluid circulating through the Kalina Cycle 300 during normal operation of the Kalina Cycle 300 may not enter the rich fluid external storage tank 702 and the lean fluid external storage tank 704. In other words, the equilibrium concentration of the fluid within the Kalina Cycle 300 can be a fixed value, while the fluid circulates in a closed loop system, which does not include the rich fluid external storage tank 702 and the lean fluid external storage tank 704.
  • the control system 130 can adjust the concentration of the basic mixture as described above.
  • the equilibrium concentration the ammonia-water mixture that would result if all the ammonia and water fluids within the various parts of the Kalina Cycle 300 (except the rich fluid external storage tank 702 and lean fluid external storage tank 704) were mixed together in a single vessel) can remain constant.
  • adding fluid from the rich fluid external storage tank 702 and/or lean fluid external storage tank 704 can change the equilibrium concentration.
  • removing fluid into the rich fluid external storage tank 702 and/or lean fluid external storage tank 704 also can change the equilibrium concentration.
  • the control system 130 can use the tank level transmitter 139b to determine the amount of rich fluid in the rich fluid external storage tank 702. Accordingly, the control system can regulate the amount of rich fluid that enters and/or exits the rich fluid external storage tank 702 (i.e., the amount of fluid added to or removed from the Kalina Cycle 300). Similarly, the lean fluid storage tank level transmitter 134b can allow the control system 130 to determine the amount of lean fluid entering and/or exiting the lean fluid external storage tank 704 by monitoring the level of the lean fluid external storage tank 704. Thus, the control system 130 can control the amount of lean fluid entering and/or exiting the Kalina Cycle 300.
  • the control system 130 can increase the concentration of the basic working fluid by adding rich fluid from the rich fluid external storage tank 702 into the tank 120.
  • the control system 130 can increase the overall equilibrium concentration of the Kalina Cycle 300.
  • the rich fluid can have 60.9% ammonia.
  • the rich fluid also can have higher and lower concentrations than 60.9% of ammonia.
  • the control system 130 can increase the overall equilibrium concentration of the Kalina Cycle 300 by removing the lean fluid from the Kalina Cycle 300 and into the lean fluid external storage tank 704. Therefore, by increasing the overall equilibrium concentration of the Kalina Cycle 300, the control system 130 also can increase the maximum concentration of the basic working fluid.
  • control system 130 can reduce the overall equilibrium concentration of the Kalina Cycle 300 by adding lean fluid from the lean fluid external storage tank 704 into the Kalina Cycle 300 system. Additionally or alternatively, removing working fluid into the rich fluid external storage tank 702, which has a higher ammonia concentration than the lean fluid, also can reduce the overall equilibrium concentration of the Kalina Cycle 300.
  • the Kalina Cycle 300 can include a valve 706, which can regulate the direction of flow of the basic fluid from point 10 into the tank 120 and/or into the rich fluid external storage tank 702.
  • Control system 130 can control the valve 706, and can allow the working fluid from point 10 to flow into the tank 120, the rich fluid external storage tank 702, or a combination thereof.
  • the Kalina Cycle 300 can include a rich fluid storage tank level control valve 708 and feed pump 710.
  • the feed pump 710 can pump the rich fluid from the rich fluid external storage tank 702 into the tank 120.
  • the control system 130 can activate the feed pump 710 as well as open the rich fluid storage tank level control valve 708 to add rich fluid to the Kalina Cycle 300.
  • Kalina Cycle 300 also can include a valve 712 which can regulate the flow of the lean stream (at point 22) from the separator 114 into the drain tank 116 and/or into the lean fluid external storage tank 704. More specifically, the control system 130 can control the valve 712 to allow the lean stream from the separator 114 to flow into the drain tank 116 and/or into the lean fluid external storage tank 704. Additionally, the Kalina Cycle 300 can include a lean fluid storage tank level control valve 714 and a feed pump 716. Particularly, control system can activate the feed pump 716 and open the lean fluid storage tank level control valve 714 to add the lean fluid into the Kalina Cycle 300.
  • Figure 8A illustrates the Kalina Cycle 300, which has an adjusted overall equilibrium concentration of the fluid.
  • Figure 8A illustrates the Kalina Cycle 300 that has an increased overall equilibrium concentration (as compared with the equilibrium concentration illustrate in Figure 7).
  • rich fluid from the rich fluid external storage tank 702 can flow into the tank 120, as described above.
  • lean stream or lean fluid can flow out of the Kalina Cycle 300 and into the lean fluid external storage tank 704.
  • the system capacity may be insufficient to accommodate addition of rich fluid without removal of the lean stream therefrom (e.g., in order to achieve a desired equilibrium concentration).
  • Removing the lean stream from the Kalina Cycle 300 can provide additional space in the drain tank 116, which would be otherwise occupied with the lean stream stored therein. Such additional space can allow the control system 130 to further increase the concentration of the basic working fluid by increasing the level of lean stream in the drain tank 116 (which would not be possible without removal of the lean stream from the Kalina Cycle). More specifically, as described above and as illustrated in Figure 8 A, the control valve 136 can allow the control system 130 to increase the amount of lean stream in the drain tank 116.
  • control system 130 can remove the lean stream from the Kalina Cycle 300 into the lean fluid external storage tank 704 and add rich fluid from the rich fluid external storage tank 702.
  • the removal of the lean stream and addition of the rich fluid can occur concurrently or may be sequential (e.g., the lean stream may be removed from the Kalina Cycle 300 and, subsequently, the rich fluid may be added).
  • control system 130 can increase the overall equilibrium concentration either by removing the lean stream from the Kalina Cycle 300 into the lean fluid external storage tank 704 or by adding rich fluid from the rich fluid external storage tank 702.
  • control system 130 also can decrease the overall equilibrium concentration in the Kalina Cycle 300.
  • the control system 130 can add the lean fluid to the Kalina Cycle 300, by activating the feed pump 716 and opening the valve 712, thereby pumping the lean fluid into the drain tank 116 and reducing the overall equilibrium concentration.
  • the control system 130 can remove a desired amount of the basic working fluid from the Kalina Cycle 300, for example, by controlling valve 706 to allow the basic working fluid to flow into the rich fluid external storage tank 702.
  • control system 130 can reduce the overall equilibrium concentration of the fluid in the Kalina Cycle 300 by removing a desired amount of the working fluid from the Kalina Cycle 300.
  • control system 130 can (at least partially) open the valve 706 to allow at least some (or a desired amount of) basic working fluid to flow into the rich fluid external storage tank 702, thereby reducing the overall equilibrium concentration of the Kalina Cycle 300.
  • control system 130 can regulate the level of the rich fluid in the rich fluid external storage tank 702, thereby regulating the amount of rich (or working) fluid added to or removed from the Kalina Cycle 300.
  • the concentration of the working fluid can be more sensitive to changes in the level of the lean stream in the drain tank 116. More specifically, reducing the level of lean stream contained within the drain tank 116 can reduce the concentration of the basic working fluid by a greater amount than without removal of the working fluid from the Kalina Cycle 300. Furthermore, as noted above, to reduce the overall equilibrium concentration, the control system 130 can add the lean fluid into the Kalina Cycle 300, from the lean fluid external storage tank 704, and remove working fluid from the Kalina Cycle 300 into the rich fluid storage tanks 702.
  • the control system 130 can increase or decrease the overall equilibrium concentration of the Kalina Cycle 300 by adding fluids to and/or removing fluids from the Kalina Cycle 300, as described above.
  • incorporating the rich fluid external storage tank 702 and/or lean fluid external storage tank 704 can increase flexibility of the Kalina Cycle 300, by allowing the control system 130 to change the equilibrium concentration of the system.
  • incorporating the rich fluid external storage tank 702 and/or the lean fluid external storage tank 704 can allow an operator to service the Kalina Cycle 300. More specifically, the operator can remove fluids from the entire or a portion of the Kalina Cycle 300 into the rich fluid external storage tank 702 and/or into the lean fluid external storage tank 704.
  • FIG. 9 illustrates a Kalina Cycle 400 that incorporates multiple cooling sources.
  • the Kalina Cycle 400 incorporates cooling sources 124a, 124b, which can enter heat exchanges or condensers 104a, 104b.
  • the Kalina Cycle 400 also can include two other heat exchangers, such as heat exchangers 910, 920, as well as a separator 930.
  • the Kalina Cycle 400 also can work with one or more external heat sources 122 as well as a heat exchanger or evaporator 110, a turbine 112, and a generator 126.
  • the Kalina Cycle 400 can include a drain tank 116 (containing the lean fluid) and a tank 120 (containing the basic working fluid). Furthermore, similar to the Kalina Cycle 300, the Kalina Cycle 400 can include a rich fluid external storage tank 702 and/or a lean fluid external storage tank 704. Additionally, the Kalina Cycle 400 can include pumps 106, 118, 710, and 716, which can pump fluid within the Kalina Cycle 400 as well as into and out of the Kalina Cycle 400, as further described below.
  • the basic working fluid (at point 41) is pumped to a higher pressure by the feed pump 106 to create a pressurized working fluid at point 42.
  • the pressurized working fluid then passes through the heat exchanger 920, where it is preheated to create a preheated working fluid at point 43.
  • the preheated working fluid then passes through heat exchanger 110, where it is heated by the external heat source 122 to create an at least partially evaporated working stream at point 44.
  • the at least partially evaporated working stream then passes through the turbine 112, and drives the turbine 112 to generate mechanical energy that is converted into electrical energy by the generator 126.
  • the working stream expands, and exits the turbine 112 as a low- pressure working stream or an at least partially spent stream (i.e., a mixed stream of liquid and vapor) at point 45.
  • the low-pressure working stream then passes through the secondary side of the heat exchanger 910 to preheat the lean stream pumped from the drain tank 116 through the primary side of the heat exchanger 910, as further described below.
  • the low-pressure working stream is cooled to a mixed phase at point 46.
  • the low-pressure working stream is mixed with a cooled lean liquid stream exiting the secondary side of the heat exchanger 920 (described below), and the combined mixture enters the condenser 104b.
  • the combined mixture is then further cooled within the condenser 104b by the external cooling source 124b, and then exits the condenser 104b at point 48 as a cooled lean liquid stream.
  • the lean stream can enter the drain tank 116.
  • the drain pump 118 can pump the lean stream into the primary side of the heat exchanger 910 as well as into the condenser 104a (as described below).
  • the portion of the lean stream that enters the heat exchanger 910 is then heated and exits the heat exchanger 910, at point 49, as a lean mixed (liquid/vapor phase) fluid.
  • the lean mixed fluid enters the separator 930, which separates the lean mixed fluid into a preheated lean liquid stream at point 50 and rich vapor at point 51 , which has an increased concentration as compared with the lean mixed fluid at the point 49.
  • the preheated lean liquid stream enters the heat exchanger 920 on the secondary side, and preheats the pressurized working fluid, as described above.
  • the preheated lean stream passes through the heat exchanger 920, the preheated lean stream cools, forming the cooled lean liquid stream at point 52.
  • the cooled lean stream is mixed with the low-pressure working stream, which exits the heat exchanger 910 at the point 46.
  • the condenser 104a As described above, another portion of the lean stream that is pumped from the drain tank 116 flows toward the condenser 104a. More specifically, at point 53, the rich vapor (from point 51) combines together with the lean liquid stream from the drain tank 116, and the combined working fluid flows into the condenser 104a. The condenser 104a, subsequently, cools the combined working fluid, and the cooled working fluid exits the condenser 104a at point 54. Subsequently, the working fluid can flow into the tank 120 and/or into the rich fluid external storage tank 702. In particular, when the valve 706 is closed to the rich fluid external storage tank 702, the working fluid flows from the point 54 into the tank 120. The process is then repeated in a closed loop arrangement.
  • Concentration of the working fluid can be adjusted by adjusting the level of the lean stream contained within the drain tank 116. More specifically, to increase the amount of ammonia in the working fluid the level of the lean stream contained within the drain tank 116 can be increased. Conversely, to decrease the amount of ammonia in the working fluid, the level of lean stream contained within the 116 can be decreased.
  • the control system 130 as described above in connection with Kalina Cycles 100, 200, and 300, can automate the process of adjusting the concentration of the working fluid, to optimize the output of the Kalina Cycle 400 at different temperatures of the heat source 122 and/or cooling sources 124a, 124b.
  • the control system 130 can monitor the parameters of the working fluid at the various points in the Kalina Cycle 400. Additionally, the control system 130 also can monitor one or more of the heat source 122 temperature and the cooling source 124 temperature. Based on the measured parameters of the working fluid and the temperatures of the heating and cooling sources, the control system can optimize or otherwise modify the concentration of the working fluid to increase the efficiency of the Kalina Cycle 400. In other words, the control system 130 can increase or decrease the amount of ammonia in the basic working fluid mixture to influence the efficiency of the Kalina Cycle 400.
  • control system 130 can include sensors 128a, 128b that measures a parameter of the cooling sources 124a, 124b.
  • a transmission mechanism A can transmit data recorded or measured by the sensors 128a, 128b to a control system processor or computer of the control system 130.
  • the transmission mechanism A can send data to the system processor of the control system 130 via a universal serial bus (USB) connection, serial connection, parallel connection, wireless connection, Bluetooth connection, and/or any other communication connection.
  • USB universal serial bus
  • the sensors 128a, 128b can be temperature sensors adapted to measure the temperature of the cooling source 124 and transmit the temperature of the cooling sources 124a, 124b to the control system processor or computer of the control system 130.
  • sensors 128a, 128b can be adapted to measure other characteristics or parameters of the cooling sources 124a, 124b, such as fluid flow properties (e.g., a flow rate).
  • the control system processor of the control system 130 is located on site with the Kalina Cycle 400. According to alternative implementations of the present invention, the control system processor of the control system 130 is located remotely from the site of the Kalina Cycle 400.
  • the transmission mechanism B can transmit data recorded or measured by the sensor 132 to a control system processor or computer of the control system 130, as described above.
  • the control system 130 can also include a drain tank level transmitter 134a that measures the level of the lean stream within the drain tank 116 and a lean fluid storage tank level transmitter 134b, which measures the level of the lean fluid in the lean fluid external storage tank 704. Transmission mechanisms can transmit data recorded or measured by the sensor 132 to the control system 130.
  • the drain tank level control valve 136 can allow the control system 130 to control the amount or level of lean stream contained within the drain tank 116.
  • the tank level transmitter 139a and the rich fluid storage tank transmitter 139b can allow the control system 130 to monitor the level of working fluid and rich fluid, respectively. Accordingly, the control system 130 can regulate fluid levels within the drain tank 116, tank 120, rich fluid external storage tank 702, and lean fluid external storage tank 704.
  • the equilibrium concentration of the Kalina Cycle 400 can remain constant. Moreover, as described above, in some instances, temperature fluctuations may require addition or removal of fluid (lean fluid and rich fluid) in order for the Kalina Cycle 400 to operate at an optimum efficiency. As described above, addition of rich fluid to the Kalina Cycle 400 can increase the overall equilibrium concentration of the Kalina Cycle 400. Conversely, removal of the rich fluid from the Kalina Cycle 400 can decrease the overall equilibrium concentration of the Kalina Cycle 400. Similarly, adding lean fluid to the Kalina Cycle 400 reduces the overall equilibrium concentration of the Kalina Cycle 400, and removing the lean stream from the Kalina Cycle 400 increases the overall equilibrium concentration of the Kalina Cycle 400.
  • the control system 130 can add rich fluid to the Kalina Cycle 400 from the rich fluid external storage tank 702, in order to increase the equilibrium concentration of the Kalina Cycle 400. Furthermore, the control system 130 can remove working fluid from the Kalina Cycle 400 into the rich fluid external storage tank 702, thereby reducing the overall equilibrium concentration of the Kalina Cycle 400, by allowing the working fluid to flow through the control valve 706 into the rich fluid external storage tank 702. Thus, by monitoring the fluid level in the rich fluid external storage tank 702, the control system 130 can use the tank level transmitter 139b (in conjunction with the transmission mechanism C) to determine the amount of rich fluid added to or removed from the Kalina Cycle 400.
  • control system 130 can remove lean stream from the Kalina Cycle 400 by opening the control valve 712 and allowing the lean stream exiting the separator 930 to enter into the lean fluid external storage tank 704. Moreover, the control system 130 also can activate the pump 716 and open the lean fluid storage tank level control valve 714 to allow the lean fluid from the lean storage tank 704 to flow into the drain tank 1 16. In addition to adding and/or removing lean and/or rich fluids, as described above in connection with the Kalina Cycle 300, the control system 130 can adjust the level of the lean stream within the drain tank 116, thereby affecting the concentration of the working fluid.
  • the rich fluid external storage tank 702 and the lean fluid external storage tank 704 respectively connect at certain points to the Kalina Cycle
  • the rich fluid external storage tank 702 and the lean fluid external storage tank 704 can connect at any number of other points.
  • the rich fluid external storage tank 702 can connect directly to the tank 120.
  • the control system can add fluid to the tank 120 directly from the rich fluid external storage tank 702 (or remove the fluid directly into the rich fluid external storage tank 702), thereby affecting the equilibrium concentration.
  • the lean fluid external storage tank 704 can connect directly to the drain tank 116 and also can directly exchange fluid with the drain tank 116, thereby affecting the equilibrium concentration.

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Abstract

L'invention concerne un système de commande de cycle Kalina qui surveille un ou plusieurs paramètres de fonctionnement du cycle Kalina. Le système calcule un ou plusieurs paramètres de fonctionnement optimaux permettant au cycle Kalina de fonctionner avec une efficacité accrue. Le système règle automatiquement lesdits un ou plusieurs paramètres de fonctionnement réels selon les valeurs optimales des paramètres afin d'améliorer l'efficacité du cycle Kalina. Les procédés d'amélioration de l'efficacité d'un cycle Kalina comprennent un réglage automatique d'un ou plusieurs paramètres de fonctionnement afin d'obtenir une configuration optimale.
EP12883661.6A 2012-08-28 2012-09-17 Systèmes et procédés ajustables destinés à améliorer l'efficacité d'un cycle kalina Withdrawn EP2912285A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/597,132 US9031705B2 (en) 2009-07-15 2012-08-28 Adjustable systems and methods for increasing the efficiency of a kalina cycle
PCT/US2012/055789 WO2014035441A1 (fr) 2012-08-28 2012-09-17 Systèmes et procédés ajustables destinés à améliorer l'efficacité d'un cycle kalina

Publications (2)

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EP2912285A1 true EP2912285A1 (fr) 2015-09-02
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WO2014035441A1 (fr) 2014-03-06
HK1183594A2 (en) 2013-12-27
TWI522527B (zh) 2016-02-21
MY192852A (en) 2022-09-12
TW201410959A (zh) 2014-03-16
EP2912285A4 (fr) 2016-07-20

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