EP2865774A1 - Alliage de fonderie d'aluminium - Google Patents
Alliage de fonderie d'aluminium Download PDFInfo
- Publication number
- EP2865774A1 EP2865774A1 EP20130382424 EP13382424A EP2865774A1 EP 2865774 A1 EP2865774 A1 EP 2865774A1 EP 20130382424 EP20130382424 EP 20130382424 EP 13382424 A EP13382424 A EP 13382424A EP 2865774 A1 EP2865774 A1 EP 2865774A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- alloy
- aluminium casting
- casting alloy
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 55
- 239000000956 alloy Substances 0.000 title claims abstract description 55
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 26
- 239000004411 aluminium Substances 0.000 title claims abstract description 22
- 238000005266 casting Methods 0.000 title claims abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 239000011777 magnesium Substances 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 239000010703 silicon Substances 0.000 claims abstract description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 239000011701 zinc Substances 0.000 claims abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 5
- 239000010936 titanium Substances 0.000 claims abstract description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 239000011572 manganese Substances 0.000 claims description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 235000019589 hardness Nutrition 0.000 description 11
- 238000005299 abrasion Methods 0.000 description 6
- 229910000765 intermetallic Inorganic materials 0.000 description 5
- 229910005347 FeSi Inorganic materials 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000004512 die casting Methods 0.000 description 3
- 238000005476 soldering Methods 0.000 description 3
- 238000007669 thermal treatment Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910016943 AlZn Inorganic materials 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical group [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
Definitions
- the field of the invention is related to aluminium casting alloys.
- the present invention relates to a hypoeutectic secondary aluminum-silicon alloy, useful to produce, by high pressure die casting, components which have to fulfill premium abrasion resistance requirements in as-cast condition at room temperature.
- Aluminum casting alloys have not been traditionally well suited for abrasion applications in which, among others, high hardness properties must be present.
- hypereutectic alloys are not so well suited. They do not fulfill the required hardness (above 115-120HB), Nickel is superfluous and Phosphorous is so volatile that requires skilled technicians to melt the alloy, which must be hold at temperatures above 750°C. Only high hardness and high strength are the objective properties, which opens the door to components produced by high pressure die casting (HPDC) with hypoeutectic aluminum.
- HPDC high pressure die casting
- HPDC process has been widely employed to new applications in the last twenty years, due to its low cost for big series, a high component reproducibility and reliability and it is hence mostly preferred when compared with GC.
- Alloys of primary quality with a Fe/Mn ratio of 1 ⁇ 2 has been disclosed in the prior art, and decrease die soldering and reduce as much as possible the negative effect of Al 5 FeSi intermetallics on the elongation values.
- elongation and mechanical properties elongation (A) equal to or more than 1%, yield strength (Rp0.2) equal to or more than 200 MPa, ultimate tensile strength (Rm) equal to or more than 300 MPa and Brinell Hardness (HB) equal to or more than 120 HB.
- elongation and mechanical properties are required for components designed to support simultaneously high abrasion and high static bending/torsion loads, maintaining a minimal ductility and other processing properties as alloy fluidity, low die soldering, easy welding or high machinability, among others.
- a preferred embodiment of the present invention is an aluminium casting alloy, wherein said alloy comprises:
- Silicon content has been set into a wide range between 7-11% by weight to guarantee high fluidity, especially for thin wall castings.
- Copper content has been set at values above 4% as it is required to get hardness above 125 HB and high strength.
- Magnesium content is also a key element to maximize the hardness and mechanical properties, whose content must be coupled with the copper content, showing best performance when both set above 0.5% by weight and 4% by weight, respectively.
- Iron content plays a key role into the mechanical properties and hence it has been limited to 0.6-1% by weight to guarantee both low mold soldering and small volume fraction of Al 5 FeSi intermetallics, which are minimized by the manganese content, implying an elongation above 1%.
- the manganese content helps to transform the Al 5 FeSi intermetallics into Al 12 (Mn,Fe)Si 2 and to reduce as much as possible the negative effect of those intermetallics. Values of manganese above 0.3% by weight were not found to be useful in terms of Al 5 FeSi intermetallics transformation.
- a further embodiment of the invention is the aluminium casting alloy of the invention, wherein said alloy comprises 8-9% by weight of silicon.
- a further embodiment of the invention is the aluminium casting alloy of the invention, wherein said alloy comprises 0.8-1 % by weight of iron.
- a further embodiment of the invention is the aluminium casting alloy of the invention, wherein said alloy comprises 0.7-1.4% by weight of copper.
- a further embodiment of the invention is the aluminium casting alloy of the invention, wherein said alloy comprises 4-4.5% by weight of copper.
- a further embodiment of the invention is the aluminium casting alloy of the invention, wherein said alloy comprises 0.05-0.3% by weight of manganese.
- a further embodiment of the invention is the aluminium casting alloy of the invention, wherein said alloy comprises 0.6-0.7% by weight of magnesium.
- Example 1 Aluminium casting alloys (prepararation, composition and mechanical properties)
- Aluminium compositions have been prepared by melting a standard EN-AC 46500 alloy in a holding furnace at 690°C and later poured into the injection vessel, being injected into the mold cavity of a 950 tonnes closing force HPDC machine at 685°C. No vacuum conditions were applied.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Conductive Materials (AREA)
- Fuel Cell (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES13382424.3T ES2582530T3 (es) | 2013-10-23 | 2013-10-23 | Aleación de aluminio para fundición |
| EP13382424.3A EP2865774B1 (fr) | 2013-10-23 | 2013-10-23 | Alliage de fonderie d'aluminium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13382424.3A EP2865774B1 (fr) | 2013-10-23 | 2013-10-23 | Alliage de fonderie d'aluminium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2865774A1 true EP2865774A1 (fr) | 2015-04-29 |
| EP2865774B1 EP2865774B1 (fr) | 2016-04-13 |
Family
ID=49517464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13382424.3A Active EP2865774B1 (fr) | 2013-10-23 | 2013-10-23 | Alliage de fonderie d'aluminium |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP2865774B1 (fr) |
| ES (1) | ES2582530T3 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105671353A (zh) * | 2016-01-26 | 2016-06-15 | 山东正诺集团有限公司 | 一种无机粒子增强的铝基刹车盘材料的制备方法 |
| CN106591640A (zh) * | 2016-11-18 | 2017-04-26 | 广州致远合金制品有限公司 | 一种耐磨铝合金 |
| EP3342888A1 (fr) * | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Alliage de fonderie d'aluminium |
| CN108411166A (zh) * | 2018-02-28 | 2018-08-17 | 山东河山机械股份有限公司 | 一种压铸铝合金及其制备方法 |
| EP3569722A4 (fr) * | 2017-02-17 | 2020-05-20 | Gam Co., Ltd. | Alliage d'aluminium haute résistance et pièce coulée d'alliage d'aluminium haute résistance |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0111082A1 (fr) * | 1982-10-16 | 1984-06-20 | Cosworth Research And Development Limited | Alliage de coulée à base d'aluminium |
| EP0924311A1 (fr) * | 1997-12-20 | 1999-06-23 | Federal-Mogul Bradford Limited | Alliage d'aluminium |
| US20030178106A1 (en) * | 2002-03-19 | 2003-09-25 | Dasgupta Rathindra | Aluminum alloy |
| WO2006066314A1 (fr) * | 2004-12-23 | 2006-06-29 | Commonwealth Scientific And Industrial Research Organisation | Traitement thermique d'articles coules en alliage d'aluminium, moules sous haute pression |
-
2013
- 2013-10-23 EP EP13382424.3A patent/EP2865774B1/fr active Active
- 2013-10-23 ES ES13382424.3T patent/ES2582530T3/es active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0111082A1 (fr) * | 1982-10-16 | 1984-06-20 | Cosworth Research And Development Limited | Alliage de coulée à base d'aluminium |
| EP0924311A1 (fr) * | 1997-12-20 | 1999-06-23 | Federal-Mogul Bradford Limited | Alliage d'aluminium |
| US20030178106A1 (en) * | 2002-03-19 | 2003-09-25 | Dasgupta Rathindra | Aluminum alloy |
| WO2006066314A1 (fr) * | 2004-12-23 | 2006-06-29 | Commonwealth Scientific And Industrial Research Organisation | Traitement thermique d'articles coules en alliage d'aluminium, moules sous haute pression |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105671353A (zh) * | 2016-01-26 | 2016-06-15 | 山东正诺集团有限公司 | 一种无机粒子增强的铝基刹车盘材料的制备方法 |
| CN106591640A (zh) * | 2016-11-18 | 2017-04-26 | 广州致远合金制品有限公司 | 一种耐磨铝合金 |
| EP3342888A1 (fr) * | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Alliage de fonderie d'aluminium |
| EP3569722A4 (fr) * | 2017-02-17 | 2020-05-20 | Gam Co., Ltd. | Alliage d'aluminium haute résistance et pièce coulée d'alliage d'aluminium haute résistance |
| CN108411166A (zh) * | 2018-02-28 | 2018-08-17 | 山东河山机械股份有限公司 | 一种压铸铝合金及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2865774B1 (fr) | 2016-04-13 |
| ES2582530T3 (es) | 2016-09-13 |
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Inventor name: CRESPO CAMINO, IGNACIO Inventor name: ANZA ORTIZ DE APODACA, INIGO Inventor name: ABUIN ARICETA, ALBERTO Inventor name: SAENZ DE TEJADA PICORNELL, FRANCISCO Inventor name: VICARIO GOMEZ, IBAN |
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