EP2855041A1 - Method and device for producing shaped sheet metal parts at a low temperature - Google Patents
Method and device for producing shaped sheet metal parts at a low temperatureInfo
- Publication number
- EP2855041A1 EP2855041A1 EP13726170.7A EP13726170A EP2855041A1 EP 2855041 A1 EP2855041 A1 EP 2855041A1 EP 13726170 A EP13726170 A EP 13726170A EP 2855041 A1 EP2855041 A1 EP 2855041A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- semi
- forming tool
- board
- finished product
- sheet metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J1/00—Preparing metal stock or similar ancillary operations prior, during or post forging, e.g. heating or cooling
- B21J1/06—Heating or cooling methods or arrangements specially adapted for performing forging or pressing operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D37/00—Tools as parts of machines covered by this subclass
- B21D37/16—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J1/00—Preparing metal stock or similar ancillary operations prior, during or post forging, e.g. heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21K—MAKING FORGED OR PRESSED METAL PRODUCTS, e.g. HORSE-SHOES, RIVETS, BOLTS OR WHEELS
- B21K7/00—Making railway appurtenances; Making vehicle parts
- B21K7/12—Making railway appurtenances; Making vehicle parts parts for locomotives or vehicles, e.g. frames, underframes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49616—Structural member making
- Y10T29/49622—Vehicular structural member making
Definitions
- the invention relates to a method for producing a formed sheet metal part from a board or a semi-finished product made of a material consisting of steel mi at least 60 wt. - Fe and a Austenitites content of at least 5%, wherein the board or the semi-finished product before forming at least partially is cooled to a temperature of less than -20 ° C and is formed at a temperature below -20 ° C in a forming tool.
- the invention relates to a device for carrying out the method and an advantageous use of the produced
- Sheet metal parts In order to meet the increasing requirements for weight savings, for example in the automotive industry, methods for the production of formed sheet metal parts have been developed, especially under the term
- the hot-forming process can be subjected to a press-hardening process
- the board or the semi-finished product usually has to be heated to a temperature above the AC : - transformation temperature point, so that in
- Substantially austenitic microstructure is present in the sheet metal part, in order subsequently to be converted at very high temperature and rapidly cooled. This ensures that the austenitic structure during rapid cooling in Converts martensite, so that very high tensile strengths and yield strengths can be provided.
- manganese-boron steels for example a manganese-boron steel of the type
- MBW1500 can be provided by this method tensile strengths in the range of more than 1100 MPa.
- the known methods for hot forming have been further developed, so that the sheet metal parts can also be provided in regions with enormous yield strengths and tensile strengths and thus a load-friendly design of the
- Sheet metal parts can be achieved.
- Corrosion protection is required. Conventionally, hot-dip aluminized or However, semi-finished products provided with an Al-Si coating are used, but have no cathodic corrosion protection. Although zinc-containing surface coatings have cathodic protection against corrosion, there is the risk of the zinc melting on the surface
- Patent application is proposed to cool the components at least partially by liquid oxygen, liquid nitrogen or dry ice or in another way and to reform at temperatures of -50 ° C to -200 ° C. It is proposed to immerse the components for this purpose in the appropriate cooling media to cool them extremely strong. On the one hand, the immersion of the sheet metal parts in liquid nitrogen or oxygen or even dry ice for large-scale use is not readily suitable. In addition, there are dangers for the operating personnel
- Object of the present invention is therefore, a
- the above-indicated object is achieved according to the first teaching of the present invention in that a reduction of the material temperature of the board or the semi-finished product to below -20 ° C takes place in a tempered cooling device.
- the board or the semi-finished product is tempered
- Cooling device at forming temperature below -20 ° C, preferably at a temperature in the range of -40 ° C to -180 ° C tempered.
- the low temperatures in combination with a transformation effect. the used one
- the tempered cooling device also makes it possible in a simple way the risk by using liquid, frozen cooling media such as liquid
- the blanks or semi-finished products be positioned and brought to cryogenic using appropriately cold cooling media.
- the cooling medium for example with liquid oxygen, nitrogen or carbon dioxide.
- Forming can be held and insofar also at least at the beginning of the forming process, the desired temperature
- the tempered cooling device it is possible to use a temperature-controlled forming tool, so that the board or semi-finished product removed from the cooling device can be kept at low temperature in the forming tool for as long as possible.
- Forming tool has for this purpose means for cooling the board or. for tempering the areas in contact with the blank or semifinished product so that an optimal cooling process is achieved.
- Particularly advantageous in this embodiment of the method according to the invention is that the board or the semi-finished product only has to be introduced into a forming tool and can be formed in this without further removal or transport. As a result, a maximum process control is achieved because the forming temperatures can be easily controlled by the forming tool.
- the forming tool tempers the board to be reshaped or the semi-finished product to be reshaped only in the
- Providing a protective gas atmosphere to the cooled areas of the board or the forming tool is achieved that no humidity can condense or freeze out at these points and is reflected at the areas of the board, the semi-finished product or the forming tool.
- This measure can, for example, with mechanical
- the cooling of the forming tool the
- Semi-finished product flows.
- particularly small wall thicknesses of the board or of the semifinished product can be used. These are preferably 0, 5 mm to 1.80 mm, more preferably 0.7 mm to 1.20 mm.
- the tempered forming tool is a corresponding deformation of the board or semi-finished with these small thicknesses particularly advantageous because they can be brought very quickly to low temperature in the forming and thus with a relatively low cycle time load-adapted, formed sheet metal parts can be produced which the higher-load areas have significant increases in strength.
- a board or a semi-finished formed which or. which has a surface coating, wherein as a surface coating optionally a zinc-containing surface coating is used. In the case of low-temperature forming, the surface coating is not damaged, so that cathodic corrosion protection can be readily used by using a zinc-containing surface coating without adversely affecting the forming process
- Forming tool which has a receptacle for inserting a circuit board or a semi-finished product and
- Means are provided for at least partially cooling the board or semi-finished product to a temperature below -20 ° C in the recording.
- the device according to the invention makes it possible, the board or the semi-finished in
- Tempering and forming step from the forming tool no longer needs to be done.
- the forming tool preferably has means for de-icing the cooled areas of the forming tool, the blank and / or the semifinished product, in order to ensure a permanent, process-reliable operation.
- the funds can do this
- the Device has the forming tool at least in the areas in contact with the board or the semi-finished in contact areas flow channels through which a cooling medium flows for local cooling of the board or the semi-finished product.
- the cooling medium used is preferably an anhydrous cooling medium, for example dry ice or liquid nitrogen.
- the flow channels can also run only in Umfortntechnikmaschine, so that no cooling media, such as oxygen, nitrogen or carbon dioxide leak in the area of the forming tool.
- the above object is achieved by the use of a
- Sheet metal part which was produced by the process according to the invention, as a structural part of a motor vehicle, wherein the structural part areas with different
- the Sheet metal part is particularly advantageous to use the Sheet metal part as a pillar, carrier, large-area component, floor panel, tunnel, front wall or wheel arch of a
- Sheet metal parts the opportunity to save costs, because no more expensive tailored blanks, which consist of several sheets, must be used.
- Sheet metal parts also have no strength debilitating
- the sheet metal part as A-, B-, C- column of a
- the sheet metal part is used as a longitudinal member in the front region of a motor vehicle and the longitudinal member has a front region which has a lower strength than the rear region.
- the front portion of the longitudinal member in the front area with lower strength is to deform in the event of an impact and thus absorb the impact energy.
- the rear area of the sheet metal part is used as a longitudinal member in the front region of a motor vehicle and the longitudinal member has a front region which has a lower strength than the rear region.
- FIG. 2 shows an alternative embodiment to that shown in FIG. 1 illustrated method
- Fig. 4 shows another embodiment of a
- Fig. 1 a schematic diagram of the method for producing a formed sheet metal part is first shown, in which a circuit board 1 is to be formed in a forming tool 2.
- the forming tool 2 is as simple
- the forming tool 2 stands for any forming tools, as they are for
- the board 1 consists of a steel with at least 60 wt. -% Fe and a retained austenite content of at least 5%.
- Typical representatives of these steel grades are, for example, high-manganese steels but also TRIP steels. In these steels, especially in the
- TRIP steels Residual austenitic steels (TRIP steels) are observed to be austenitic at very low temperatures during forming
- Solidification process which in addition to the classic workhardening effect still a so-called TRIP effect, can lead to very high yield strengths and tensile strengths.
- TRIP steel RA-K 40/70 steel
- the yield strength can be increased from 410 MPa to over 800 MPa.
- Embodiment of the method the circuit board. 1
- a cooling device 3 first in a cooling device 3 to a temperature of below -20 ° C, preferably at a temperature of. - 40 ° C to -190 ° C cooled. This can be done in the
- Cooling media such as liquid
- Cooling device for example, have closed circuits of the correspondingly cool cooling media, which heat, for example, via direct metal contact to the
- Transfer board or semi-finished product Reaches the board, which has a wall thickness of preferably 0, 5 mm to 1, 8 mm, more preferably 0.70 mm to 1.20 mm, the
- Forming temperature is removed from the cooling device 3 and fed to the forming tool 2 shortly before the forming process.
- the deformation then takes place directly, so that the temperature rise due to the removal from the
- Cooling device is limited.
- Forming tool 2 even be tempered, so that a significant increase in temperature of the board is prevented in the forming tool.
- the cooling device 3 provides a discontinuous operation of the cooling of the board 1 available.
- Cooling device 3 ' so that the board 1 and. the semifinished product 1 at the outlet of the cooling device 3 'was brought to deformation temperature.
- the board 1 resp. the semifinished product 1 is then inserted immediately after leaving the cooling device 3 'in the forming tool 2 and reshaped.
- the forming tool 2 is merely here Represented as a thermoforming tool.
- AHU / hydroforming tools and any other forming tools are conceivable, which cause a deformation and thus a solidification in the sheet metal part suitable.
- a cooling medium for example liquid nitrogen or liquid oxygen or else deep-frozen carbon dioxide flows through the
- Forming tool shown which has a closed circuit with respect to the cooling medium.
- forming tool 9 shown schematically has in the region of the punch or. the die coolant channels 10, through which a correspondingly low-temperature
- the board 1 which is arranged between the two halves of the forming tool 9 and having these surface contact, is in the range of
- the mechanical deicing means 12 consist of a holder for receiving a scraper 12a, which cleans the surface of the punch 9 ', for example, when the forming tool 9 is opened. It is also conceivable to use brushes instead of the scraper 12a.
- shown forming tool 9 can be an inserted board 1 in a relatively short time due to the large
- FIGS. 5, 6 and 7 show typical embodiments of advantageous uses of the formed sheet metal part 1.
- the use of the sheet metal part as a B-pillar 13 of a motor vehicle 14 is shown schematically.
- the B-pillar 13 should preferably have a high yield strength and tensile strength roof connection area 13b and one with lower strength but with a
- this B-pillar can be prepared in an economical manner by the upper
- Fig. 6. shows two longitudinal members of a front region of a vehicle body, which have two different functions in one component.
- the longitudinal members 17 serve
- the longitudinal members 17 are usually such
- a longitudinal member 17 can now be produced such that its front region 17a. has a lower strength than the rear portion 17b, wherein in the forming tool, the rear portion of the longitudinal member 17b is strongly cooled. This will achieve that the yield strength and tensile strengths of the two areas differ significantly.
- the high yield strength portion of the side member 17 as in the other uses previously as well
- Yield strength of more than 800 MPa provided so that this area is particularly strong.
- the area 17a is made soft in the same operation, since this area of the forming tool is not tempered.
- the use of possible tailored blanks, which additionally require work steps to provide a similar strength profile, can therefore be dispensed with.
- FIG. 7 shows an example of an end wall 18, which is preferably also produced by the method according to the invention.
- the end wall 18 is usually
- Forming tool not only be achieved that specific areas of the end wall 18 a significantly different
- Umformverha11en in the event of an impact show, but also local areas with corresponding. Yield strength, and
- Tensile strengths are provided, which are used to hold aggregates, such as brake booster,
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SI201330995T SI2855041T1 (en) | 2012-05-31 | 2013-05-28 | Method for producing shaped sheet metal parts at a low temperature |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012104734A DE102012104734A1 (en) | 2012-05-31 | 2012-05-31 | Method and device for producing formed sheet metal parts at cryogenic temperature |
PCT/EP2013/060934 WO2013178615A1 (en) | 2012-05-31 | 2013-05-28 | Method and device for producing shaped sheet metal parts at a low temperature |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2855041A1 true EP2855041A1 (en) | 2015-04-08 |
EP2855041B1 EP2855041B1 (en) | 2018-01-31 |
Family
ID=48539135
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13726170.7A Not-in-force EP2855041B1 (en) | 2012-05-31 | 2013-05-28 | Method for producing shaped sheet metal parts at a low temperature |
Country Status (13)
Country | Link |
---|---|
US (1) | US10532395B2 (en) |
EP (1) | EP2855041B1 (en) |
JP (1) | JP6068627B2 (en) |
KR (1) | KR20150016319A (en) |
CN (1) | CN104379272B (en) |
BR (1) | BR112014030042A2 (en) |
DE (1) | DE102012104734A1 (en) |
ES (1) | ES2666312T3 (en) |
IN (1) | IN2014MN02371A (en) |
MX (1) | MX2014014544A (en) |
SI (1) | SI2855041T1 (en) |
WO (1) | WO2013178615A1 (en) |
ZA (1) | ZA201409111B (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
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EP3020491A1 (en) * | 2014-11-14 | 2016-05-18 | Linde Aktiengesellschaft | Method for forming aluminium sheet |
DE102015203644A1 (en) * | 2015-03-02 | 2016-09-08 | Bayerische Motoren Werke Aktiengesellschaft | Press-hardened sheet metal part with different sheet thicknesses and strengths |
DE102016102344B4 (en) * | 2016-02-10 | 2020-09-24 | Voestalpine Metal Forming Gmbh | Method and device for producing hardened steel components |
US10385415B2 (en) | 2016-04-28 | 2019-08-20 | GM Global Technology Operations LLC | Zinc-coated hot formed high strength steel part with through-thickness gradient microstructure |
US10619223B2 (en) | 2016-04-28 | 2020-04-14 | GM Global Technology Operations LLC | Zinc-coated hot formed steel component with tailored property |
CN106140924A (en) * | 2016-08-30 | 2016-11-23 | 山西北方机械制造有限责任公司 | A kind of method of extending of high-strength steel plate |
US20180221937A1 (en) * | 2017-02-06 | 2018-08-09 | Ross Casting And Innovation, Llc | Method and Apparatus For Producing A Forged Compressor Wheel |
CN108326159B (en) * | 2018-02-08 | 2020-03-17 | 苑世剑 | Freezing forming method for large-size aluminum alloy tailor-welded blank component |
WO2019222950A1 (en) | 2018-05-24 | 2019-11-28 | GM Global Technology Operations LLC | A method for improving both strength and ductility of a press-hardening steel |
CN112534078A (en) | 2018-06-19 | 2021-03-19 | 通用汽车环球科技运作有限责任公司 | Low density press hardened steel with enhanced mechanical properties |
JP2020146747A (en) * | 2019-03-15 | 2020-09-17 | 本田技研工業株式会社 | Manufacturing method for vehicle body frame and vehicle body frame |
US11530469B2 (en) | 2019-07-02 | 2022-12-20 | GM Global Technology Operations LLC | Press hardened steel with surface layered homogenous oxide after hot forming |
DE102020116126A1 (en) * | 2020-06-18 | 2021-12-23 | Bilstein Gmbh & Co. Kg | Process for press hardening of hot-formable blanks |
CN112588931B (en) * | 2020-11-26 | 2021-12-21 | 大连理工大学 | Ultralow-temperature medium pressure forming method for curved surface part with complex shape |
CN112916700B (en) * | 2021-02-05 | 2022-06-21 | 大连理工大学 | Local ultralow temperature forming method for large-size small-feature curved surface part |
CN117548551B (en) * | 2024-01-11 | 2024-03-26 | 湘潭大学 | Forming method of aluminum alloy |
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US3469972A (en) * | 1966-01-04 | 1969-09-30 | Sandvikens Jernverks Ab | Razor blades and similar thin elongated sharp-edged blades made of a chromium steel |
JPS5523884B2 (en) * | 1971-08-27 | 1980-06-25 | ||
US3972744A (en) * | 1974-02-11 | 1976-08-03 | Houdaille Industries, Inc. | Method of and means for making lightweight, low cost impact resistant bumpers |
JPS5540017A (en) * | 1978-09-08 | 1980-03-21 | Niigataken | Cooling and precision blanking method of stainless steel plate |
JPH06154894A (en) * | 1992-11-26 | 1994-06-03 | Kobe Steel Ltd | Method for forming al and al alloy plate |
JPH08108233A (en) * | 1994-10-07 | 1996-04-30 | Nissan Motor Co Ltd | Cool transporting device for sheet material |
JP3287148B2 (en) * | 1994-11-25 | 2002-05-27 | 日産自動車株式会社 | Press processing method and apparatus for aluminum or aluminum alloy plate and constant temperature apparatus used for the processing method |
JP3975382B2 (en) | 1998-12-21 | 2007-09-12 | 日産自動車株式会社 | Manufacturing method of press-molded parts |
CN2680680Y (en) * | 2003-11-07 | 2005-02-23 | 钢铁研究总院 | Pressure quenching apparatus for thin armour plate |
SE528130C2 (en) * | 2004-10-04 | 2006-09-12 | Gestamp Hardtech Ab | Ways to heat mold and harden a sheet metal |
ES2273589B1 (en) * | 2005-08-05 | 2008-04-16 | Mondragon Utillaje Y Sistemas, S.Coop. | TROQUEL WITH COOLING CIRCUIT. |
EP1767659A1 (en) * | 2005-09-21 | 2007-03-28 | ARCELOR France | Method of manufacturing multi phase microstructured steel piece |
JP4619262B2 (en) * | 2005-10-24 | 2011-01-26 | 新日本製鐵株式会社 | Press forming method of high strength steel sheet with residual austenite transformation induced plasticity |
JP4760338B2 (en) * | 2005-11-29 | 2011-08-31 | 日産自動車株式会社 | Material cooling method and apparatus in low temperature forming process |
JP4823718B2 (en) * | 2006-03-02 | 2011-11-24 | 新日本製鐵株式会社 | Hot forming mold, press forming apparatus, and hot press forming method |
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DE102008020794B4 (en) * | 2008-02-04 | 2018-03-29 | Volkswagen Ag | Method for laser hardening steel workpieces and associated laser hardening system |
US20090242086A1 (en) * | 2008-03-31 | 2009-10-01 | Honda Motor Co., Ltd. | Microstructural optimization of automotive structures |
CN101280352B (en) * | 2008-05-21 | 2010-06-09 | 钢铁研究总院 | Producing method of thermoforming martensitic steel parts |
EP2175041A1 (en) * | 2008-10-09 | 2010-04-14 | C.R.F. Società Consortile per Azioni | Method of hot forming metal plates |
JP4811692B2 (en) * | 2009-02-24 | 2011-11-09 | 山形県 | Martensitic cast steel and martensitic cast steel manufacturing method |
DE102009050623A1 (en) * | 2009-10-24 | 2010-05-20 | Daimler Ag | Steel sheet component i.e. B-column, manufacturing method for vehicle, involves differently tempering preset regions of steel sheet after heating and before deformation and/or hardening of steel sheet |
DE102011012240A1 (en) * | 2010-03-02 | 2011-11-03 | GM Global Technology Operations LLC | Method for pressing desired shape from metal sheet blank, involves cooling metal sheet blank with fluid stream in predetermined area of high stress concentration |
DE102010012579B3 (en) * | 2010-03-23 | 2011-07-07 | Benteler Automobiltechnik GmbH, 33102 | Method and device for producing hardened molded components |
DE102010020373A1 (en) * | 2010-05-12 | 2011-11-17 | Voestalpine Stahl Gmbh | Process for producing a component from an iron-manganese steel sheet |
-
2012
- 2012-05-31 DE DE102012104734A patent/DE102012104734A1/en not_active Withdrawn
-
2013
- 2013-05-28 BR BR112014030042A patent/BR112014030042A2/en not_active Application Discontinuation
- 2013-05-28 ES ES13726170.7T patent/ES2666312T3/en active Active
- 2013-05-28 WO PCT/EP2013/060934 patent/WO2013178615A1/en active Application Filing
- 2013-05-28 MX MX2014014544A patent/MX2014014544A/en unknown
- 2013-05-28 EP EP13726170.7A patent/EP2855041B1/en not_active Not-in-force
- 2013-05-28 CN CN201380028507.1A patent/CN104379272B/en not_active Expired - Fee Related
- 2013-05-28 JP JP2015514458A patent/JP6068627B2/en not_active Expired - Fee Related
- 2013-05-28 SI SI201330995T patent/SI2855041T1/en unknown
- 2013-05-28 KR KR1020147034450A patent/KR20150016319A/en active IP Right Grant
- 2013-05-28 IN IN2371MUN2014 patent/IN2014MN02371A/en unknown
-
2014
- 2014-11-26 US US14/554,206 patent/US10532395B2/en active Active
- 2014-12-11 ZA ZA2014/09111A patent/ZA201409111B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2013178615A1 * |
Also Published As
Publication number | Publication date |
---|---|
US10532395B2 (en) | 2020-01-14 |
ZA201409111B (en) | 2017-09-27 |
CN104379272B (en) | 2017-03-15 |
EP2855041B1 (en) | 2018-01-31 |
BR112014030042A2 (en) | 2019-09-03 |
JP2015519205A (en) | 2015-07-09 |
JP6068627B2 (en) | 2017-01-25 |
DE102012104734A1 (en) | 2013-12-05 |
MX2014014544A (en) | 2015-09-04 |
IN2014MN02371A (en) | 2015-08-14 |
ES2666312T3 (en) | 2018-05-03 |
US20150082636A1 (en) | 2015-03-26 |
SI2855041T1 (en) | 2018-06-29 |
WO2013178615A1 (en) | 2013-12-05 |
CN104379272A (en) | 2015-02-25 |
KR20150016319A (en) | 2015-02-11 |
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