EP2776164A4 - Process for producing methanation catalyst and process for methanation of synthesis gas - Google Patents

Process for producing methanation catalyst and process for methanation of synthesis gas

Info

Publication number
EP2776164A4
EP2776164A4 EP12847684.3A EP12847684A EP2776164A4 EP 2776164 A4 EP2776164 A4 EP 2776164A4 EP 12847684 A EP12847684 A EP 12847684A EP 2776164 A4 EP2776164 A4 EP 2776164A4
Authority
EP
European Patent Office
Prior art keywords
methanation
synthesis gas
producing
catalyst
methanation catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12847684.3A
Other languages
German (de)
French (fr)
Other versions
EP2776164A1 (en
Inventor
Claudia Querner
Andrian Milanov
Stephan Schunk
Andreas Strasser
Guido Wasserschaff
Thomas Roussière
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP12847684.3A priority Critical patent/EP2776164A4/en
Publication of EP2776164A1 publication Critical patent/EP2776164A1/en
Publication of EP2776164A4 publication Critical patent/EP2776164A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B01J27/236—Hydroxy carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0081—Preparation by melting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP12847684.3A 2011-11-08 2012-11-07 Process for producing methanation catalyst and process for methanation of synthesis gas Withdrawn EP2776164A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12847684.3A EP2776164A4 (en) 2011-11-08 2012-11-07 Process for producing methanation catalyst and process for methanation of synthesis gas

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188238 2011-11-08
EP12847684.3A EP2776164A4 (en) 2011-11-08 2012-11-07 Process for producing methanation catalyst and process for methanation of synthesis gas
PCT/IB2012/056208 WO2013068931A1 (en) 2011-11-08 2012-11-07 Process for producing methanation catalyst and process for methanation of synthesis gas

Publications (2)

Publication Number Publication Date
EP2776164A1 EP2776164A1 (en) 2014-09-17
EP2776164A4 true EP2776164A4 (en) 2015-08-19

Family

ID=48288611

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12847684.3A Withdrawn EP2776164A4 (en) 2011-11-08 2012-11-07 Process for producing methanation catalyst and process for methanation of synthesis gas

Country Status (8)

Country Link
EP (1) EP2776164A4 (en)
JP (1) JP6125518B2 (en)
KR (1) KR20140097308A (en)
CN (1) CN104039452B (en)
CA (1) CA2854914A1 (en)
RU (1) RU2014123057A (en)
WO (1) WO2013068931A1 (en)
ZA (1) ZA201404092B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140099475A (en) * 2011-11-08 2014-08-12 바스프 에스이 Process for producing reforming catalyst and reforming of methane
CN104028270A (en) * 2014-06-10 2014-09-10 中国华能集团清洁能源技术研究院有限公司 Methanation catalyst and preparation method thereof
CN105817219B (en) * 2015-01-04 2018-10-16 神华集团有限责任公司 A kind of methanation catalyst and its preparation method and application
WO2018219992A1 (en) 2017-06-02 2018-12-06 Basf Se Method for carbon dioxide hydrogenation in the presence of a nickel- and magnesium-spinel-containing catalyst
WO2021152614A1 (en) * 2020-01-31 2021-08-05 Institute Of Chemical Technology Catalyst for co2 methanation reaction having high activity and long term stability and process thereof
CN114250357B (en) * 2020-09-22 2023-07-25 中冶长天国际工程有限责任公司 High-hydrogen low-carbon sintering material layer structure, sintering system and method
CN113368851A (en) * 2021-06-09 2021-09-10 中国科学院青岛生物能源与过程研究所 Method for preparing oxide-supported metal and application
KR102619167B1 (en) * 2022-02-25 2023-12-27 포항공과대학교 산학협력단 MANUFACTURING METHOD of METHANE REFORMING REACTION CATALYST WITH IMPROVED THERMAL STABILITY AND CATALYSTS THEREOF

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3436358A (en) * 1962-12-29 1969-04-01 Haldor Frederik Axel Topsoe Reforming with a nickel and nickel oxide catalyst on a magnesium-aluminate-spinel containing support
US3866353A (en) * 1973-03-24 1975-02-18 Metallgesellschaft Ag Process for producing methane-rich gases from hydrocarbons
EP0031472A2 (en) * 1979-12-29 1981-07-08 Ruhrchemie Aktiengesellschaft Process for the manufacture of methanisation catalysts
US6416731B1 (en) * 1998-12-22 2002-07-09 Haldor Topsoe A/S Process for catalytical steam reforming of a hydrocarbon feedstock
KR100892033B1 (en) * 2007-10-08 2009-04-07 한국에너지기술연구원 High surface area spinel structured nano crystalline sized ymgo (1-y) al2o3-supported nano-sized nickel reforming catalysts and their use for producing synthesis gas from combined steam and carbon dioxide reforming of natural gas
EP2226308A1 (en) * 2007-12-28 2010-09-08 Toda Kogyo Corporation Molded porous article, method for production thereof, catalyst carrier, and catalyst
EP2308594A2 (en) * 2008-08-01 2011-04-13 Hyundai Heavy Industries Co., Ltd. Catalyst for preparing synthesis gas from natural gas and carbon dioxide, and preparation method thereof

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2231317A1 (en) * 1972-06-27 1974-01-10 Basf Ag CATALYST AND ITS USE IN THE MANUFACTURE OF METHANE
CA1078878A (en) * 1975-07-16 1980-06-03 Nl Industries Process of catalytic methanation
US4217295A (en) * 1975-07-16 1980-08-12 Nl Industries, Inc. Process of catalytic methanation
DE2729921C3 (en) * 1977-07-02 1985-01-03 Metallgesellschaft Ag, 6000 Frankfurt Process for generating a gas that is exchangeable with natural gas
GB2222963B (en) * 1988-09-23 1992-01-02 British Gas Plc Catalysts
US5399537A (en) * 1992-12-21 1995-03-21 Amoco Corporation Method for preparing synthesis gas using nickel catalysts
JP3676300B2 (en) * 1999-10-01 2005-07-27 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド Production of synthesis gas using hydrotalcite-derived nickel catalyst
FR2809030B1 (en) * 2000-05-22 2002-08-16 Univ Pasteur CATALYST FOR GASIFICATION OF BIOMASS IN A FLUIDIZED BED, PROCESS FOR OBTAINING AND USES OF SUCH A CATALYST
KR100398058B1 (en) * 2001-05-18 2003-09-19 주식회사 경동도시가스 Modified θ-alumina-supported nickel reforming catalysts and its use for producing synthesis gas from natural gas
JP4488178B2 (en) * 2004-02-26 2010-06-23 戸田工業株式会社 Methanation catalyst and method for producing the same, and method for methanation of carbon monoxide using the methanation catalyst

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3436358A (en) * 1962-12-29 1969-04-01 Haldor Frederik Axel Topsoe Reforming with a nickel and nickel oxide catalyst on a magnesium-aluminate-spinel containing support
US3866353A (en) * 1973-03-24 1975-02-18 Metallgesellschaft Ag Process for producing methane-rich gases from hydrocarbons
EP0031472A2 (en) * 1979-12-29 1981-07-08 Ruhrchemie Aktiengesellschaft Process for the manufacture of methanisation catalysts
US6416731B1 (en) * 1998-12-22 2002-07-09 Haldor Topsoe A/S Process for catalytical steam reforming of a hydrocarbon feedstock
KR100892033B1 (en) * 2007-10-08 2009-04-07 한국에너지기술연구원 High surface area spinel structured nano crystalline sized ymgo (1-y) al2o3-supported nano-sized nickel reforming catalysts and their use for producing synthesis gas from combined steam and carbon dioxide reforming of natural gas
EP2226308A1 (en) * 2007-12-28 2010-09-08 Toda Kogyo Corporation Molded porous article, method for production thereof, catalyst carrier, and catalyst
EP2308594A2 (en) * 2008-08-01 2011-04-13 Hyundai Heavy Industries Co., Ltd. Catalyst for preparing synthesis gas from natural gas and carbon dioxide, and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CAVANI F ET AL: "Hydrotalcite-type anionic clays: preparation, properties and applications", CATALYSIS TODAY, ELSEVIER, NL, vol. 11, 1 January 1991 (1991-01-01), pages 173 - 301, XP002497610, ISSN: 0920-5861, DOI: 10.1016/0920-5861(91)80068-K *
See also references of WO2013068931A1 *

Also Published As

Publication number Publication date
CN104039452B (en) 2017-03-08
KR20140097308A (en) 2014-08-06
WO2013068931A1 (en) 2013-05-16
CA2854914A1 (en) 2013-05-16
EP2776164A1 (en) 2014-09-17
ZA201404092B (en) 2016-06-29
RU2014123057A (en) 2015-12-20
CN104039452A (en) 2014-09-10
JP2015502247A (en) 2015-01-22
JP6125518B2 (en) 2017-05-10

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