EP2760984B1 - Procédé et composition pour le nettoyage de surfaces dures - Google Patents

Procédé et composition pour le nettoyage de surfaces dures Download PDF

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Publication number
EP2760984B1
EP2760984B1 EP12756756.8A EP12756756A EP2760984B1 EP 2760984 B1 EP2760984 B1 EP 2760984B1 EP 12756756 A EP12756756 A EP 12756756A EP 2760984 B1 EP2760984 B1 EP 2760984B1
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EP
European Patent Office
Prior art keywords
composition
quaternary silane
anionic surfactant
hard surface
mixture
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Not-in-force
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EP12756756.8A
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German (de)
English (en)
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EP2760984A1 (fr
Inventor
Wuye OUYANG
Qingsheng Tao
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Unilever PLC
Unilever NV
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Unilever PLC
Unilever NV
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/162—Organic compounds containing Si

Definitions

  • the present invention relates to a method and a composition for cleaning hard surfaces, to obtain a protective layer for robust water sheeting effect and/or a long lasting effect for cleaning. Moreover, the invention relates to a process for making the hard surface cleaning composition.
  • Forming a water sheeting layer during cleaning and after cleaning may deliver such benefits.
  • the hard surface will dry easily due to the water spreading area being larger upon sheeting. Also drying will be more uniform such that unappealing water mark will not be formed onto the hard surfaces, giving the consumer an appealing appearance, even when the hardness of water is high. The end cleaning result will be better.
  • the soil particulates will be distributed uniformly on the hard surface instead of aggregated within the water marks, due to the uniform water film. Therefore, another benefit is that the hard surface has visually cleaner appearance. Thus the period between cleaning can be prolonged, and so save effort and time for consumers.
  • Hard surface for the purposes of the present invention means any surface comprising a hard material such as glass, glazed ceramics, metal, stone, plastics, lacquer, wood, or combination thereof. Typically, the hard surface is in a household including window, kitchen, bathroom, toilet, furniture, floor, or the like.
  • Hydrophilic for the purposes of the present invention is used to describe a molecule or portion of a molecule that is attracted to, and tends to be dissolved by water, or a surface that has a contact angle of water less than 90 ° at 25 °C.
  • Olemer for the purposes of the present invention means a molecule that consists of several monomer units, for example, from 2 to 100, more preferably, from 2 to 60 monomer units.
  • Hydrolyzation for the purposes of the present invention refers to a reaction with water.
  • “Hydrolyzable” herein means the compound may react with water.
  • “Hydrolyzed” means the compound is the reaction product of another compound with water.
  • the present invention provides a method for cleaning a hard surface comprising:
  • the present invention provides a hard surface cleaning composition comprising:
  • the present invention provides a process for the preparation of a hard surface cleaning composition comprising the steps of:
  • the hydrolyzed quaternary silane in this invention is a silane with four ligands wherein three ligands are hydroxy ligands and other ligand is hydrophilic group.
  • the hydrophilic group may be selected from -OH, -SH, -NH 2 .
  • the hydrophilic group comprises group having a molar ratio of C:Q less than 3:1, preferably from 1:2 to 2:1, wherein Q is selected from O, S, N, or combination thereof. Too high ratio of C:Q will destroy the hydrophilicity of the group.
  • two or more silanol of the hydrolyzed quaternary silane condensate together to form oligomers. However, this condensation should not lead to excessive polymerization, otherwise, the silane may not be well dispersed and may even precipitate.
  • the hydrolyzed quaternary silane may be hydrolyzed from quaternary silane precursor having a formula; (R 1 ) 3 Si - R 2 .
  • R 1 represents the hydrolysable ligands which could be hydrolyzed to be hydroxyl group.
  • R 1 may be selected from alkoxy, halogen, or the like.
  • the requirement for R 2 is to be hydrophilic itself if it is not hydrolysable, or could become hydrophilic group after hydrolysis if it is hydrolysable.
  • R 2 comprises hydroxy, alkoxy, alkylhydroxy, alkylamine, alkyloic acid, or its ether, ester or amide. Additionally or alternatively, R 2 comprises halogen.
  • the quaternary silane precursor employed in this invention preferably comprises tetraethyl orthosilicate (TEOS), tetramethyl orthosilicate (TMOS), tetrapropyl orthosilicate (TPOS), tetrabutyl orthosilicate (TBOS), aminomethyltriethoxysilane, aminomethyltrimethoxysilane, sulfanylmethyltriethoxysilane, N-(3-triethoxysilylpropyl)gluconamide (GLU-S), tetrabromosilane, tetrachlorosilane.
  • TEOS tetraethyl orthosilicate
  • TMOS tetramethyl orthosilicate
  • TPOS tetrapropyl orthosilicate
  • TBOS tetrabutyl orthosilicate
  • aminomethyltriethoxysilane aminomethyltrimethoxysilane
  • sulfanylmethyltriethoxysilane N-
  • the quaternary silane precursor comprises TEOS, TMOS, TPOS, TBOS, N-(3-triethoxysilylpropyl)gluconamide, tetrachlorosilane, or a mixture thereof. Even more preferably, the quaternary silane precursor is selected from TEOS, TBOS, N-(3-triethoxysilylpropyl)gluconamide or a mixture thereof.
  • the quaternary silane precursors suitable for use in this invention include TEOS from Shanghai Chemical Reagent Co. Ltd (China); TBOS from Sigma-Aldrich (Germany); and/or GLU-S) from Gelest Inc. (USA).
  • the amount of the hydrolyzed quaternary silane and/or its oligomer, employed in the hard surface cleaning formulation will be from 0.001 to 10% by weight of the composition, more preferably from 0.01 to 4%, and most preferably from 0.05 to 2%.
  • the surfactant suitable for this invention at least comprises anionic surfactant.
  • the anionic surfactant preferably comprises alkyl benzene sulphonate, secondary alkane sulphonate, primary alkyl sulphate, alkyl ether sulphate, alpha olefin sulphonate, alkyl carboxylates, or a mixture thereof.
  • anionic surfactants are salts of
  • the preferred anionic surfactants are the alkali metal (such as sodium and potassium) and/or alkaline earth metal (such as calcium and magnesium) salt of alkyl ether sulphate having 10 to 20 carbon atoms and 1 to 5 ethoxy groups, and/or alkyl benzene sulphonate wherein the alkyl contains 10 to 14 carbon atoms. More preferably, the anionic surfactants comprise sodium lauryl ether sulphate, linear alkyl benzene sulphonate sodium, mixtures thereof, or the like.
  • the hard surface cleaning composition comprises anionic surfactant in an amount of 0.01 to 50 % by weight, preferably 0.01 to 10% by weight. More preferably, the hard surface cleaning composition comprises anionic surfactant in an amount of 0.01 to 3.9% by weight, and most preferably, from 0.05 to 2% by weight.
  • surfactant may be present. But preferably at least 50% by total weight of surfactant is anionic surfactant, more preferably, at least 75% by weight, most preferably from 80 to 100%.
  • the weight ratio of hydrolyzed quaternary silane, and/or its oligomer to anionic surfactant is preferably in the range of 20:1 to 1:20. More preferably, the weight ratio of silane: surfactant is in the range of the 10:1 to 1:5. In the most preferred embodiment, the weight ratio of silane: surfactant is in the range of 4:1 to 1:2.
  • the hard surface cleaning composition preferably comprises water in the range of 0.01 to 99.9 % by weight of the composition, more preferably 5% to 99% by weight. Even more preferably, the hard surface cleaning composition comprises water in an amount of 25 to 95% by weight.
  • composition may also comprise colourants, whiteners, optical brightness, soil suspending agents, detersive enzymes, bleaching agent, gel-control agents, freeze-thaw stabilisers, bactericides, abrasives, preservatives, and/or perfumes.
  • any general way for cleaning a hard surface is acceptable.
  • the way for treating a hard surface by the composition is spraying the composition onto the hard surface, or wiping the hard surface by wipe impregnated with the composition, or dripping the composition onto the hard surface, or combination thereof.
  • the way for treating a hard surface is spraying the composition onto a hard surface, and/or wiping a hard surface by wipe impregnated with the composition.
  • the spraying is employed for treating a hard surface, there is no limitation how the composition is sprayed.
  • a spraying bottle for hard surface cleaning product is favourable.
  • wipe including woven or nonwoven cloth, natural or synthetic sponges or spongy sheets, "squeegee” materials, paper towel, or the like is suitable.
  • the wipe may be impregnated dry, or more preferably in wet form.
  • the method for cleaning hard surface may optionally further comprises the steps of allowing soil and/or stains to deposit.
  • the soil or stains will be easily removed when the hard surface is subsequently cleaned according to the method of this invention.
  • the hydrolyzed quaternary silane and/or its oligomer and anionic surfactant are also preferably applied to the hard surface during the subsequent cleaning.
  • treating of a hard surface with the composition may be followed by a rinsing step, preferably with water.
  • a preferred method for cleaning a hard surface comprises the steps in sequence of:
  • the soils and stains of present invention may comprise all kinds of soils and stains generally encountered in the household, either of organic or inorganic origin, whether visible or invisible to the naked eye, including soiling solid debris and/or with bacteria or other pathogens.
  • the method and compositions according to the invention may be used to treat surface susceptible to fatty or greasy soil and stains.
  • the hard surface of present invention generally refers to any surface in household including the window, kitchen, bathroom, toilet, furniture, floor, or the like or any surface in car, ship, and airplane including windows, mirrors, sinks, basins, toilet bowls, baths/shower trays, wall tiles, floor tiles, cooker tops, oven interiors, cookware, washing machine drums, cooker hoods, extractor fans.
  • These surfaces may be made of glass, glazed ceramics, metal, stone, plastics, lacquer, wood, or combination thereof.
  • the method and composition according to the invention is used to treat the hard surface of window, kitchen, bathroom, and toilet.
  • the method and composition in this invention is used to treat glass.
  • the process for the preparation of a hard surface cleaning composition comprises the steps of:
  • the hydrolyzation of quaternary silane precursor could be carried out when the mixture is either acidic or alkali.
  • the mixture is preferably acidic. More preferably, the pH value of the mixture is in the range of 2 to 7. The lower the pH of the mixture is, the faster the hydrolyzation of quaternary silane precursor will be conducted when the mixture is acid.
  • the acid used to tune the pH of the mixture for example, hydrochloric acid, sulphuric acid, or citric acid. It is noted that another requirement for the hydrolyzation of quaternary silane precursor is that the quaternary silane precursor has an amount of less than 10% by weight of the mixture, preferably, less than 4% by weight of the mixture.
  • a hydrolyzed quaternary silane having three hydroxy ligands and one hydrophilic ligand, and/or its oligomer is provided.
  • the hydrophilic ligand is selected from -OH, -SH, -NH 2 , group having a molar ratio of C: Q less than 3:1, wherein Q is selected from O, S, N, or combination thereof.
  • any other necessary or optional components may be combined with the mixture.
  • test surfaces in the examples included standard mirror (glass), plastic coated panel, or steel. These surfaces were cleaned prior to the use by commercial hard surface deaner.
  • the artificial soil used in the examples has the formulation: 0.51 wt. % of tripalmitin, 0.26 wt. % of glyceryl trioleate, 0.1 wt. % of paraffin, 0.05 wt. % of palmitic acid, 3.6 wt. % of kaolin, 0.02 wt. % of carbon black and 95.48 wt. % of ethanol.
  • the chemicals involved in the examples include:
  • composition containing quaternary silane precursor TEOS, TBOS, GLU-S or mixtures thereof
  • surfactant SLES, CTAB, or AEO7
  • water water
  • the quaternary silane precursor, surfactant, and deionized water were mixed under stirring of 400 rpm by stirrer (IKA, RT 15 power, Germany) at ambient condition.
  • stirrer IKA, RT 15 power, Germany
  • HCl was added to the mixture to adjust the pH of the mixture to 3.
  • the quaternary silane precursor will be hydrolyzed under such condition.
  • the hydrolysis speed will depend on the acidity of the mixture. Higher the acidity is, faster the hydrolyzation is.
  • composition After stirring for another three hours, the composition was ready for treating a hard surface.
  • the composition containing only quaternary silane precursor and water was prepared, all the steps were same except that no surfactant was mixed.
  • the composition of surfactant and water were prepared, only the weighing and mixing steps were needed.
  • the composition was packaged into conventional container for household care product including spray applicator and bottle for further use.
  • compositions are used for cleaning a hard surface.
  • One ordinary way to cleaning a hard surface is spray and wipe or drip and wipe. Firstly, 0.1 to 0.2 g of the composition is sprayed by a spray applicator or placed by a pipette onto a hard surface (mirror/glass, steel, plastic coated panel). Subsequently, the hard surface is wiped by wipe from J-Cloth (UK) for one minute. Then, the hard surface is air dried for 10 minutes.
  • This method is designed to test the robustness of the protective layer.
  • a mirror plate was cleaned by a composition according to the hard surface cleaning method. Then, the hydrophilicity test was conducted on the mirror plate. After air drying for 1 hour, the mirror plate was flushed by tap water for 10 seconds. The hydrophilicity test was conducted again after air drying for 1 hour. The difference of results for these two hydrophilicity test demonstrate the robustness of protective layer. The smaller the difference is, the better the robustness is.
  • the cleaning test is used to measure how the composition will influence the subsequent cleaning steps.
  • a mirror plate (with area of 42 cm by 15 cm) was cleaned by ordinary household product in market.
  • the artificial soil (6.8 g) is sprayed onto the mirror plate and aged overnight for 12 to 20 hours.
  • 4 g of composition is placed on the onto the mirror plate by spraying or dripping, followed by a cleaning process by mop for 1 minutes.
  • the residue is measured by optical image.
  • a mirror plate (48 cm by 33 cm) was cleaned according to the hard surface cleaning method, left half by the composition according to the invention, right half is cleaned by a comparative cleaning comprising a commercial polymeric agent (PolyQuart Ampho 149, from Cognis, Germany) claimed to assistant hard surface cleaning.
  • the mirror plate was placed almost vertically on a balcony with a tilt angle of about 85 ° to the horizontal surface. After a certain period of time, optical image was recorded to compare the hydrophilicity and cleanness.
  • This example demonstrates the effect of surfactants on water sheeting effect of cleaning compositions.
  • Formulations A, B, C, and D in Table 1 were prepared (according to section of Preparation of the composition ). It is noted that composition D was not stable. There was white precipitate in the composition D after storage over one night. Then, these formulations were used to clean the mirror plates and the hydrophilicity test was conducted onto the mirror plates (according to section of Test ). The result of hydrophilicity test is shown in the right hand column of Table 1.
  • the content of hydrolyzed TEOS is calculated by dividing the weight concentration of TEOS by molecular weight of TEOS and multiplying the molecular weight of tetrahydroxysilane. ** The mirror was treated by formulation D before there was precipitation visible by naked eye.
  • This example demonstrates the increase of durability of hydrophilicity by combination of hydrolyzed quaternary silane with anionic surfactant.
  • Formulation E and F in Table 2 were prepared (according to section of Preparation of the composition ). These formulations were used to conduct hydrophilicity test and robustness test of hydrophilicity (according to the method in section of Test ). The result is shown in Table 2.
  • Table 2 Formulation Composition Test result Hydrolyzed TEOS* (wt%) SLES (wt%) water Diameter before rinse (mm) Diameter after rinse (mm) E - 0.3 to 100% 15.6 ⁇ 0.2 9.0 ⁇ 0.5 F 0.18 0.3 to 100% 16.1 ⁇ 1.5 13.0 ⁇ 0.8 * Calculated as in Example 1.
  • This example demonstrates the water sheeting effects of formulations with different weight ratio of hydrolyzed quaternary silane with anionic surfactant.
  • Formulations in Table 3 were prepared (according to section of Preparation of the composition ). Hydrophilicity tests were conducted (according to the method in section of Test. The results are shown in Table 3.
  • the formulations impart better water sheeting effect to the mirror plates when the weight ratio of hydrolyzed TEOS to SLES is in the range of 9:1 to 1:13.
  • the best water sheeting effect in Table 3 is achieved when the weight ratio of hydrolyzed TEOS to SLES is 3:5.
  • This example demonstrates the water sheeting effects of formulations prepared from various quaternary silane precursors including GLU-S and TBOS, or their combination with TEOS, and SLES.
  • Formulations in Table 4 were prepared (according to section of Preparation of the composition ). Hydrophilicity tests were conducted (according to the method in section of Test. The results are shown in Table 4.
  • hydrolyzed GLU-S means the product of hydrolyzation of GLU-S.
  • the content of hydrolyzed GLU-S is calculated by dividing the weight concentration of GLU-S by molecular weight of GLU-S and multiplying the molecular weight of N-(3- trihydroxysilylpropyl)gluconamide.
  • hydrolyzed TEOS means the product of hydrolyzation of TBOS.
  • the content of hydrolyzed TBOS is calculated by dividing the weight concentration of TEOS by molecular weight of TBOS and multiplying the molecular weight of tetrahydroxysilane.
  • Formulation R and S indicates the combination of GLU-S, TEOS, and SLES also results in the excellent water sheeting effect. Similar effects can be achieved by combining TBOS and SLES (see formulation T). These results demonstrate both GLU-S and TBOS can combine with SLES to cooperatively induce water sheeting effect.
  • This example demonstrates the immediate cleaning performance of the formulation L (see Table 3) by comparing it with a polymer-based hard surface formulation.
  • Figure 3 show the cleaning effect for longer time. Clearly apparent is that the right half of the mirror plate is covered by a layer of white dust which results in decreased transparency. The left half is clearer with less soil deposited. These results demonstrate the long last cleaning effect of formulation L, resisting the deposition of soils even over two months.
  • Formulation L was used to treat steel and plastic coated panel (according to the cleaning method in the section of Test ). On each plate, only the right half was treated by formulation L.
  • Figure 4 shows the result on plastic coated panel. As can be seen, the diameter of water droplet on the right half is much bigger than that of the left one, indicating much better water sheeting effect of right half than left half.
  • Figure 5 is the result on the steel surface. It is also demonstrated that the water sheeting becomes better after treatment by formulation L. This example demonstrates formulation L is suitable to be employed to a range of hard surfaces including steel and plastic coated panel.

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Claims (20)

  1. Procédé pour un nettoyage d'une surface dure comprenant :
    le traitement de la surface avec une composition comprenant :
    (a) de 0,001 à 10 % en poids d'un silane quaternaire hydrolysé présentant trois ligands hydroxy et un ligand hydrophile, et/ou son oligomère ;
    (b) un tensioactif anionique ; et
    (c) de l'eau ;
    dans lequel le ligand hydrophile est choisi parmi -OH, -SH, -NH2, ou un groupe présentant un rapport molaire de C:Q inférieur à 3:1, où Q est choisi parmi O, S, N, ou une combinaison de ceux-ci.
  2. Procédé selon la revendication 1, dans lequel le silane quaternaire hydrolysé est hydrolysable à partir d'un précurseur de silane quaternaire présentant la formule ; (R1)3Si-R2 dans laquelle
    R1 est choisi parmi un groupe alcoxy, ou un halogène ; et
    R2 est choisi parmi un groupe hydroxy, hydroxyalkyle, aminoalkyle, alcoxy, ou son ester, ou un amide, ou un halogène.
  3. Procédé selon la revendication 2, dans lequel le précurseur de silane quaternaire comprend de l'orthosilicate de tétraéthyle (TEOS), de l'orthosilicate de tétraméthyle (TMOS), de l'orthosilicate de tétrapropyle (TPOS), de l'orthosilicate de tétrabutyle (TBOS), du N-(3-triéthoxysilylpropyl)gluconamide, du tétrachlorosilane, ou un mélange de ceux-ci.
  4. Procédé selon l'une quelconque des revendications 1 à 3, dans lequel le tensioactif anionique comprend un benzènesulfonate d'alkyle, un sulfonate d'alcane secondaire, un sulfate d'alkyle primaire, un sulfate d'alkyléther, un sulfonate d'oléfine-alpha, des carboxylates d'alkyle, ou un mélange de ceux-ci.
  5. Procédé selon la revendication 4, dans lequel le tensioactif anionique comprend du lauryléthersulfate de sodium, un benzènesulfonate de sodium d'alkyle linéaire, ou un mélange de ceux-ci.
  6. Procédé selon l'une quelconque des revendications précédentes, dans lequel la composition comprend le tensioactif anionique dans une quantité dans l'intervalle de 0,01 à 10 % en poids.
  7. Procédé selon la revendication 6, dans lequel la composition comprend le tensioactif anionique dans une quantité dans l'intervalle de 0,01 à 3,9 % en poids.
  8. Procédé selon l'une quelconque des revendications précédentes, dans lequel la composition comprend le silane quaternaire hydrolysé et/ou son oligomère dans l'intervalle de 0,01 à 4 % en poids.
  9. Procédé selon l'une quelconque des revendications précédentes, dans lequel la composition comprend le silane quaternaire hydrolysé et/ou son oligomère et un tensioactif anionique dans un rapport massique entre 1:20 et 20:1.
  10. Procédé selon l'une quelconque des revendications précédentes, dans lequel la composition comprend un constituant présentant un groupe acide carboxylique.
  11. Procédé selon la revendication 10, dans lequel le constituant comprend de l'acide acrylique, de l'acide citrique, du poly(acide acrylique), ou un mélange de ceux-ci.
  12. Procédé selon l'une quelconque des revendications précédentes, dans lequel la surface dure comprend du verre, du métal, du bois, des matières plastiques, de l'émail vitreux, de la pierre, de la céramique, ou des combinaisons de ceux-ci.
  13. Procédé selon l'une quelconque des revendications précédentes, dans lequel le procédé comprend de plus l'étape consistant à laisser de la salissure ou des taches se déposer sur la surface après le traitement de la surface avec la composition.
  14. Procédé selon la revendication 13, dans lequel la saleté ou la tache est une saleté ou une tache grasse.
  15. Composition de nettoyage de surface dure comprenant :
    (a) de 0,001 à 10 % en poids d'un silane quaternaire hydrolysé présentant trois ligands hydroxy et un ligand hydrophile, et/ou son oligomère ;
    (b) de 0,001 à 3,9 % en poids d'un tensioactif anionique ; et
    (c) de l'eau ;
    dans laquelle le ligand hydrophile est choisi parmi -OF, -SH, - NH2, ou un groupe présentant un rapport molaire de C:Q inférieur à 3:1, où Q est choisi parmi O, S, N, ou une combinaison de ceux-ci.
  16. Composition de nettoyage selon la revendication 15, dans laquelle le silane quaternaire hydrolysé est hydrolysable à partir d'un précurseur de silane quaternaire comprenant de l'orthosilicate de tétraéthyle (TEOS), de l'orthosilicate de tétraméthyle (TMOS), de l'orthosilicate de tétrapropyle (TPOS), de l'orthosilicate de tétrabutyle (TBOS), du N-(3-triéthoxysilylpropyl)gluconamide, du tétrachlorosilane, ou un mélange de ceux-ci.
  17. Composition de nettoyage selon les revendications 15 ou 16, dans laquelle le tensioactif anionique comprend un benzènesulfonate d'alkyle, un sulfonate d'alcane secondaire, un sulfate d'alkyle primaire, un sulfate d'alkyléther, un sulfonate d'oléfine-alpha, et des carboxylates d'alkyle, ou un mélange de ceux-ci.
  18. Composition de nettoyage selon l'une quelconque des revendications 15 à 17, dans laquelle la composition comprend un silane quaternaire hydrolysé et/ou son oligomère et un tensioactif anionique dans un rapport massique entre 1:10 et 10:1.
  19. Procédé pour la préparation d'une composition de nettoyage de surface dure comprenant les étapes consistant :
    (a) à former un mélange réactionnel comprenant de l'eau et de 0,001 à 10 % en poids d'un précurseur de silane quaternaire ; et
    (b) à hydrolyser le précurseur de silane quaternaire dans le mélange pour fournir un silane quaternaire hydrolysé présentant trois ligands hydroxy et un ligand hydrophile, et/ou son oligomère ; et
    (c) à combiner le mélange avec de 0,001 à 3,9 % en poids d'un tensioactif anionique ; et
    (d) à récupérer la composition de nettoyage de surface dure ;
    dans lequel le ligand hydrophile est choisi parmi -OH, -SH, -NH2, ou un groupe présentant un rapport molaire de C:Q inférieur à 3:1, où Q est choisi parmi 0, S, N, ou une combinaison de ceux-ci.
  20. Procédé selon la revendication 19, dans lequel le précurseur de silane quaternaire présente la formule ; (R1)3Si-R2 dans laquelle
    R1 est choisi parmi un groupe alcoxy, ou un halogène ; et
    R2 est choisi parmi un groupe hydroxy, hydroxyalkyle, aminoalkyle, alcoxy, un halogène, ou son ester, ou un amide.
EP12756756.8A 2011-09-30 2012-09-13 Procédé et composition pour le nettoyage de surfaces dures Not-in-force EP2760984B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2011001655 2011-09-30
PCT/EP2012/067918 WO2013045277A1 (fr) 2011-09-30 2012-09-13 Procédé et composition pour le nettoyage de surfaces dures

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HU (1) HUE026232T2 (fr)
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CA2883494C (fr) 2012-08-31 2021-08-24 3M Innovative Properties Company Compositions multifonctionnelles comprenant un silane hydrophile

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US4549979A (en) * 1984-03-27 1985-10-29 Dow Corning Corporation Detergent composition with siliconate-silicate copolymer
JPH07331178A (ja) * 1994-06-14 1995-12-19 Toray Ind Inc コーティング用組成物およびその製造方法
US6926745B2 (en) 2002-05-17 2005-08-09 The Clorox Company Hydroscopic polymer gel films for easier cleaning
DE10258831A1 (de) 2002-12-17 2004-07-08 Henkel Kgaa Reinigungsmittel für harte Oberflächen
DE102007051093A1 (de) * 2007-10-24 2009-04-30 Henkel Ag & Co. Kgaa Wasch- oder Reinigungsmittelcompounds und deren Herstellung
UA99353C2 (ru) 2008-04-04 2012-08-10 Юнилевер Н.В. Применение цитрата в качестве средства для очистки твердой поверхности и способ удаления загрязнений или пятен с твердой поверхности

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HUE026232T2 (en) 2016-06-28
EP2760984A1 (fr) 2014-08-06
WO2013045277A1 (fr) 2013-04-04
ZA201401733B (en) 2016-01-27

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