EP2731695A2 - Injection flocculation and compression dewatering unit for solids control and management of drilling fluids and methods relating thereto - Google Patents

Injection flocculation and compression dewatering unit for solids control and management of drilling fluids and methods relating thereto

Info

Publication number
EP2731695A2
EP2731695A2 EP12733274.0A EP12733274A EP2731695A2 EP 2731695 A2 EP2731695 A2 EP 2731695A2 EP 12733274 A EP12733274 A EP 12733274A EP 2731695 A2 EP2731695 A2 EP 2731695A2
Authority
EP
European Patent Office
Prior art keywords
flocculation
dewatering
fluid
inches
dewatering system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12733274.0A
Other languages
German (de)
French (fr)
Inventor
Charles R. Landis
Roger H. WOODS
Douglas H. PULLMAN
Ryan P. COLLINS
Edward Anderson
David W. DONALD
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roger H Woods Ltd
Halliburton Energy Services Inc
Original Assignee
Roger H Woods Ltd
Halliburton Energy Services Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roger H Woods Ltd, Halliburton Energy Services Inc filed Critical Roger H Woods Ltd
Publication of EP2731695A2 publication Critical patent/EP2731695A2/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B21/00Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
    • E21B21/06Arrangements for treating drilling fluids outside the borehole
    • E21B21/063Arrangements for treating drilling fluids outside the borehole by separating components
    • E21B21/065Separating solids from drilling fluids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/26Separation of sediment aided by centrifugal force or centripetal force
    • B01D21/262Separation of sediment aided by centrifugal force or centripetal force by using a centrifuge

Definitions

  • the present invention relates to flocculation and dewatering systems for separating solid-liquid mixtures. More particularly, the present invention relates to flocculation and dewatering systems for recycling and reconditioning subterranean treatment fluids and methods of use thereof.
  • drilling fluids also commonly referred to as drilling muds
  • drilling muds are used in most modern drilling operations.
  • a drilling fluid provides a number of important functions, which includes preventing formation fluids from entering the wellbore, carrying out drill cuttings, suspending drill cuttings while drilling is paused, and keeping the drill bit cool and clean.
  • drilling fluids provide stability to a wellbore during a drilling operation.
  • Some fluids are referred to as "drill-in fluids.” Drill-in fluids are specialty drilling fluids designed for drilling through the reservoir section of a wellbore.
  • Drill-in fluids are often brines comprising only solids of appropriate particle size ranges such as salt crystals or calcium carbonate and polymers. Generally, only additives essential for filtration control and cuttings carrying are present in a drill-in fluid.
  • drilling fluids as used herein includes drill-in fluids.
  • drilling fluids there are many different types of drilling fluids including water- based, oil-based, polymer-based, clay-based, and synthetic-based fluids. While the composition may vary, a drilling fluid is generally composed of a fluid (liquid or gas) and may further comprise various additives including, but not limited to, polymers, salts, clays, and viscosifiers. The exact composition of a drilling fluid may be engineered to meet the specific needs of a drilling operation based on factors such as rock formation, type of petroleum being recovered, environmental concerns, and the like. A drilling fluid is usually homogeneous and mixed prior to circulation in a subterranean environment. However, once a drilling fluid is introduced to a wellbore, its composition can change drastically.
  • drill cuttings such as rocks, sand, shale, grit, and other contaminants can become suspended and mixed in the drilling fluid during a drilling operation. These solids inevitably make their way up as part of returned fluids as the drilling fluid is returned to the surface.
  • drilling fluids provide numerous advantages, there are several drawbacks. For example, drilling fluids can be very costly and, while the exact cost depends on the operation, can take up a significant portion of the total cost of drilling a well. Moreover, the long term effects that drilling fluids have on the environment may be uncertain. These important considerations have spurred efforts to recondition returned drilling fluids so that the drilling fluids may be recycled and reintroduced in a wellbore.
  • the drilling fluids are recirculated after removing the drilling cutting and other solid contaminants from the fluid.
  • This recycling and reconditioning process generally involves recovering the returned drilling fluid at the surface, removing drilling cuttings and undesirable drill solids, and recirculating the reconditioned drilling fluid into the well.
  • the removal or separation of solids from the drilling fluids is typically done using a size exclusion screen. Smaller solids may further be removed, at least partially, by additional processing equipments such as a hydrocyclone or centrifuges.
  • a hydrocyclone or a centrifuge separate suspensions by density and generate two types of fluids, an overflow and an underflow.
  • the composition of the overflow is the same or very similar to a new drilling fluid and may be reintroduced into the wellbore without further treatment.
  • the underflow is a concentrated fluid comprising much of the unwanted solids present in the returned fluid.
  • the present invention relates to flocculation and dewatering systems for separating solid-liquid mixtures. More particularly, the present invention relates to flocculation and dewatering systems for recycling and reconditioning well treatment fluids and methods of use thereof.
  • a flocculation and dewatering system comprises: a solid-liquid sorter; a flocculation chamber comprising : a flocculation trough comprising : at least one baffle; an injection port for introducing a flocculant; and an outlet for removing a flocculated fluid; a dewatering rack wherein the outlet introduces the flocculated fluid into the dewatering rack comprising : at least one filtration collection bag; a filter press; and a pump for pumping fluids in a conduit network running at least partially through the flocculation and dewatering system.
  • a flocculation chamber comprises: a flocculation trough comprising : at least one baffle; an injection port for introducing a flocculant; and an outlet for removing a flocculated fluid.
  • a dewatering rack comprises: at least one filtration collection bag situated in at least one collection basket; and a filter press.
  • Figure 1A- 1B are schematic diagrams of a flocculation and dewatering system.
  • Figure 1A is an embodiment of a flocculation and dewatering system in reconditioning mode.
  • Figure IB is an embodiment of a flocculation and dewatering system in mixing mode.
  • Figure 2 is a close-up schematic diagram of an embodiment of a flocculation chamber and a dewatering rack.
  • Figure 3A-3C are schematic diagrams of the different positions of a multi-position lever system of a filter press.
  • the present invention relates to flocculation and dewatering systems for separating solid-liquid mixtures. More particularly, the present invention relates to flocculation and dewatering systems for recycling and reconditioning well treatment fluids and methods of use thereof.
  • returned fluid generally refers to a treatment fluid that has been introduced to a subterranean environment and that has been circulated back up to the surface.
  • Suitable examples of returned fluids for use in conjunction with the present invention include, but are not limited to, drilling fluids, completion fluids, and combinations thereof.
  • Fluids suitable for use in conjunction with the present invention may be water-based, oil-based, polymer-based, clay-based ⁇ e.g., bentontite), synthetic- based, and the like.
  • an example of a returned fluid may be a drilling fluid that has been used in a drilling operation and that includes various solid contaminants such as drill cuttings, rocks, sand, shale, grit, assorted debris, and other solid contaminants.
  • the flocculation and dewatering system 100 of the present invention provides elements, such as, solid-liquid sorter 102, flocculation chamber 104, dewatering rack 110, etc., that may be used individually or in tandem to recondition returned fluids thereby forming a reconditioned fluid which may be recycled by being reused.
  • the flocculation and dewatering system 100 of the present invention may also be used to mix various fluids and starting materials to provide treatment fluids which may be introduced into a subterranean environment.
  • the elements may be modular in natu re and may be rearranged and/or reconfigu red as desired .
  • the reconditioned fluids may be reused by being reintroduced into a su bterranean environment thereby minimizing generated chemical wastes.
  • the present invention provides superior separation of solid-liquid mixtu res compared to typical separation systems and techniques. Specifically, it is believed that the present invention would provide a higher ratio of overflow to underflow as compared to typical separation systems and methods.
  • overflow refers to a separated portion of a returned fluid that may be reused and recycled .
  • underflow refers to a separated portion of a retu rned fluid that requires reconditioning to recover reusable and recyclable portions of a treatment fluid .
  • the overflow may be reused without fu rther reconditioning .
  • the u nderflow generally comprises solid contaminants such as those accu mu lated while a retu rned fluid is circulating in a su bterranean environment.
  • solid contaminants may be drill cuttings, rocks, sand, shale, grit, assorted debris, and other solid contaminants which can become suspended and mixed in the drilling fluid du ring a drilling operation.
  • the overflow comprises reusable treatment fluids which may be introduced into the mixing unit 126.
  • the present invention is able to recondition the u nderflow so that a large portion is reusable in a subterranean operation and thus recyclable.
  • the solid contaminants which are separated are typically not reusable.
  • the present invention provides superior efficiency in the reconditioning of the underflow as compared to typical separation systems and techniques.
  • This superior efficiency is in part related to the superior mixing and flocculating characteristics of the flocculating chamber 104, in particu lar, the flocculating trough 106.
  • the geometry (e.g., the slope of the trough) of the floccu lating trough 106 unexpectedly enhances the mixing and flocculation of the u nderflow. This ability to recondition returned fluids for su bsequent reuse in su bterranean operations enables the operator to save considerable costs.
  • Another advantage of the present invention is that the elements of the flocculation and dewatering system 100 have been configured (e.g. , geometrically, volumetrically, etc. ) and optimized to ease the handling of large amounts of returned fluids. Yet another advantage is that some or all of the elements of the present invention have been designed to be portable.
  • the present invention also provides a single system which is able to function in two separate modes: reconditioning mode (Figure 1A) and mixing mode (Figure IB). This dual functionality provides added convenience and saves considerable cost. This may be particularly important if the particular flocculation and dewatering operation is located in a remote or hard to reach location.
  • FIG. 1A shows a schematic diagram representing one embodiment of the present invention.
  • the flocculation and dewatering system 100 of the present invention generally comprises a solid-liquid sorter 102, a flocculation chamber 104, a pump 108, and a dewatering rack 110.
  • the flocculation chamber generally comprise a flocculation trough 106.
  • the flocculation and dewatering system 100 may comprise a mixing unit 126 comprising a basin 128 for reintroducing overflow or reconditioned fluid.
  • Figures 1A- 1B also show various elements of the present invention, including dewatering rack 110, hopper 112, pit/sump 114, filter 116, filtration collection bag 118, outlet 120, collection basket 122, filter press 124, mixing unit 126, basin 128, conduit network 130, two-way valve 132, active tank 134, baffle 200, injection port 202, flocculant dispenser 208, and lever system 300.
  • dewatering rack 110 hopper 112
  • pit/sump 114 filter 116
  • filtration collection bag 118 outlet 120
  • collection basket 122 collection basket 122
  • filter press 124 mixing unit 126
  • basin 128 conduit network 130
  • two-way valve 132 active tank 134
  • baffle 200 injection port 202
  • flocculant dispenser 208 flocculant dispenser 208
  • the solid-liquid sorter 102 may sort a solid-liquid mixture such as a suspension by density using centrifugal force.
  • a solid-liquid sorter 102 will separate a returned fluid such as a drilling fluid which has been circulated in a subterranean environment into a relatively lower density fluid (overflow) comprising relatively fewer solid contaminants and a relatively higher density fluid (underflow) comprising relatively more solid contaminants.
  • Suitable examples of solid-liquid sorter 102 include, but are not limited to, centrifuges, shaker beds, helix tubular sorters, counterspinning screens, vibrating beds, filter boxes and/or hydrocyclones.
  • the returned fluid may be introduced in a solid-liquid sorter 102 in a number of ways including a conduit network 130 comprising a two-way valve 132 which controls the direction of fluid flow.
  • a conduit network 130 comprising a two-way valve 132 which controls the direction of fluid flow.
  • a plurality of one-way valves may be used instead of two-way valves 132.
  • the conduit network 130 at least partially runs through the flocculation and dewatering system 100 thereby providing a fluidic connection between the elements.
  • the condu it network 130 is connected to the basin 128 of a mixing unit 126.
  • a basin 128 may be connected to an active tank 134.
  • an active tank 134 may be used as a reservoir to store the overflow and/or reconditioned fluids.
  • an active tank 134 may i ntroduce fluids (e.g., overflow, recondition fluid, etc.) to a basin 128 which then acts as a reservoir for mixing fluids.
  • the basin 128 may be used to mix various components, including the starting materials of a treatment fluid and the reconditioned fluid .
  • the flocculation and dewatering system 100 may switch between a mixing mode wherein the primary function is to prepare a treatment fluid to a reconditioning mode wherein the primary function is to recondition a returned fluid for subsequent use in a su bterranean application.
  • a switch between the modes can be quickly and efficiently performed in the field, without having to relocate or reconfigure the floccu lation and dewatering system 100.
  • FIG. 1A is a schematic diagram of the floccu lation and dewatering system 100 in a typical reconditioning mode.
  • multiple two-way valves 132 are positioned so that retu rned fluid may be drawn from a pit or sump 114 through a conduit network 130 by a pump 108.
  • the returned fluid may pass through an optional filter 116 in order to remove solids that are above the maximum size tolerated by the floccu lation and dewatering system 100.
  • a filter 116 include a cylindrical sleeve and/or tube having openings in the periphery so that flu id may enter axially at one end and exit radially through the peripheral openings.
  • the returned fluid is introduced into solid-liquid sorter 102 for flocculation and later dewatered in a dewatering rack 110.
  • the condu it network 130 may also be used to transfer the removed water from the dewatering rack 110 to other elements of the flocculation and dewatering system 100.
  • FIG. IB is a schematic diagram of the floccu lation and dewatering system 100 in a typical mixing mode.
  • the elements of the flocculation and dewatering system 100 are modular and may be rearranged and/or reconfigured as desired .
  • the flocculation and dewatering system 100 is generally configured similar to U. S. Patent No. 5,779,355, which is herein incorporated by reference.
  • the floccu lation cham ber 104 and the dewatering rack 110 are not actively used.
  • a pump 108 may be used to transfer fluids through the conduit network 130.
  • a pump include piston pumps, screw type pu mps, diaphrag m pumps, positive displacement pu mps, and centrifugal pu mps.
  • the pu mp 108 is rated between about 5 horsepowers to about 25 horsepowers.
  • the pump 108 weighs less than about 1000 pounds.
  • the pu mp 108 is useful for transferring fluids from one element (e.g. , mixing unit 126, solid-liqu id sorter 102, etc.) of the floccu lation and dewatering system 100 to another element (e.g.
  • the pump 108 may be installed anywhere within the flocculation and dewatering system 100. In some embodiments, a plurality of pumps may be used .
  • the solid-liquid sorter 102 is generally configured to transfer the u nderflow to the flocculation chamber 104 by a pump 108 or by other suitable techniques such as by gravity and the like. Where desirable, the solid-liquid sorter 102 will be configured to conveniently transfer the overflow to a mixing unit 126 comprising a basin 128 through the conduit network 130.
  • the mixing unit 126 may have several functions including, but not limited to, mixing the overflow with u nused treatment fluids and reintroducing the mixture into a su bterranean environment.
  • the mixing u nit 126 may also comprise a hopper 112 for introducing dry reagent products which is later mixed in with the treatment flu id .
  • the subterranea n environment may be a wellbore for oil drilling, geological coring, mineral exploring and the like.
  • Figu re 2 is a close-u p schematic showing the solid-liquid sorter 102, flocculation chamber 104 and the dewatering rack 110.
  • the solid-liquid sorter 102 is a hydrocyclone.
  • the flocculation chamber 104 generally comprises a flocculation trough 106 which comprises at least one baffle 200 and an injection port 202 for introducing a flocculant and an outlet 120 for removing a flocculated fluid.
  • the outlet 120 is used to transfer a flocculated fluid from the flocculation chamber 104 to the dewatering rack 110.
  • a hydrocyclone will comprise a conical base wherein the top size of the conical base is about 2 inches to about 4 inches in diameter. In some embodiments, the top size of the conical base is about 1 inch to about 2 inches in diameter. The top size of the conical base determines the size or range of sizes of particles which may be separated. Generally, a larger top size will separate relatively larger solids while a smaller top size will separate relatively smaller solids. It is believed that a top size of about 2 inches to 4 inches in diameter will separate approximately 15-30 micron solids. In some embodiments, a plurality of hydrocyclones may be used to separate a multiple range of solid sizes. The plurality of hydrocyclones may be used sequentially or in replacement.
  • the injection port [0033] Referring to Figure 2, in some embodiments, the injection port
  • flocculant dispenser 208 shown in Figure 1A which can introduce wet or dry flocculants into the flocculation chamber 104.
  • the mixing of the flocculant with the underflow forms a flocculated fluid.
  • flocculants include, but are not limited to, alum, polyacrylamide, partially- hydrolyzed polyacrylamide (PHPA), chitosan, guar, and gelatin.
  • the flocculation trough 106 may be partitioned to divide the flocculation chamber 104 into an upper flocculation chamber 204 and a lower flocculation chamber 206.
  • the partition is created by having a flocculation trough 106 having a slope of about 1 degree to about 46 degrees as measured from the bottom of the flocculation chamber 104.
  • the sloped flocculation trough 106 comprises the upper flocculation chamber 204 while the bottom portion of the flocculation chamber 104 comprises the lower flocculation chamber 206.
  • the lower flocculation chamber 206 may comprise an outlet 120 for transferring the flocculated fluid out of the flocculation chamber 104.
  • the partitioning of the flocculation chamber 104 into an upper flocculation chamber 204 and a lower flocculation chamber 206 may enhance mixing of the flocculant with the underflow thereby enhancing the flocculation of the underflow for several reasons. Without being limited by theory, it is believed that the baffle 200 and the slope of the flocculation trough 106 will facilitate the mixing of the returned fluid and the flocculant.
  • the partition lengthens the duration of mixing as the fluids must travel a farther distance before exiting the flocculation chamber 104.
  • the dimensions of the flocculation trough 106 is about 24 inches to about 48 inches in length, about 6.5 inches to about 18 inches in width, and about 10 inches to 24 inches in height.
  • the dewatering rack 110 generally comprise at least one filtration collection bag 118; and a filter press 124.
  • the filtration collection bag 118 may be a weeping bag.
  • the filtration collection bag 118 may be placed in a collection basket 122 or on the ground .
  • the collection basket 122 may be configured to allow fluids to pass through.
  • the collection basket 122 may comprise meshes 210, pores, or be generally permeable.
  • the filtration collection bag 118 may be made from woven felt, non-woven felt, or a combination of both.
  • the filtration collection bag 118 may hold about 10 gallons to about 100 gallons of flocculated fluid.
  • a filter press 124 shown in Figure 3A-3C may be used to remove water from the flocculated fluid to form a dewatered flocculated fluid.
  • the removed water may then be introduced into the mixing unit 126 or into the flocculant dispenser 208.
  • FIGS 3A-3C show the filter press 124 with a lever system 300.
  • the filter press 124 is generally configured to engage the filtration collection bag 118 and dewater the flocculated fluid.
  • the filter press 124 may be activated manually as by a lever system 300.
  • the lever system 300 may be a multi-position lever system.
  • Figure 3A shows the filter press 124 in an uncompressed state.
  • Figure 3B shows the filter press 124 in a semi-compressed state.
  • Figure 3C shows the filter press 124 in a fully compressed state.
  • the filter press 124 may dewater the flocculated fluid hydraulically, pneumatically, or both.
  • the methods of the present invention generally comprise providing a returned fluid comprising a fluid; and a solid contaminant; introducing the returned fluid into a solid-liquid sorter thereby separating the returned fluid into an overflow and an underflow; flocculating the underflow in a flocculating chamber 104 thereby forming a flocculated fluid; and dewatering the flocculated fluid using a dewatering rack 110.
  • the fluid may be a liquid or gas-based fluid.
  • the returned fluid may comprise a drilling fluid wherein the drilling fluid has been circulated in a subterranean environment. Flowing the returned fluid through a hydrocyclone may separate the returned fluid into an overflow and an underflow.
  • the overflow may comprise reusable drilling fluid.
  • the underflow may comprise solid contaminants.
  • the overflow may be introduced into a mixing unit 126 comprising a basin 128.
  • the underflow may be flocculated in a flocculation chamber 104 and dewatered in a dewatering rack 110.
  • the underflow may be dewatered by pressing the filtration collection bag 118 such as by pressing a filter press 124.
  • compositions and methods are described in terms of “comprising,” “containing,” or “including” various components or steps, the compositions and methods can also “consist essentially of” or “consist of” the various components and steps. All numbers and ranges disclosed above may vary by some amount. Whenever a numerical range with a lower limit and an upper limit is disclosed, any number and any included range falling within the range is specifically disclosed. In particular, every range of values (of the form, “from about a to about b,” or, equivalently, “from approximately a to b,” or, equivalently, “from approximately a-b”) disclosed herein is to be understood to set forth every number and range encompassed within the broader range of values.

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Filtration Of Liquid (AREA)
  • Treatment Of Sludge (AREA)

Abstract

A flocculation and dewatering system may include a solid-liquid sorter; a flocculation chamber including a flocculation trough that comprises at least one baffle; an injection port for introducing a flocculant; and an outlet for removing a flocculated fluid; a dewatering rack in which the outlet introduces the flocculated fluid into the dewatering rack that comprises at least one filtration collection bag; a filter press; and a pump for pumping fluids in a conduit network running at least partially through the flocculation and dewatering system.

Description

NOVEL INJECTION FLOCCULATION AND COMPRESSION DEWATERING UNIT FOR SOLIDS CONTROL AND MANAGEMENT OF DRILLING FLUIDS AND METHODS RELATING THERETO CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] The present invention is related to co-pending U.S. application
Ser. No. [Attorney Docket No. HES 2011-IP-046463U2] entitled "NOVEL
INJECTION FLOCCULATION AND COMPRESSION DEWATERING UNIT FOR SOLIDS CONTROL AND MANAGEMENT OF DRILLING FLUIDS AND METHODS RELATING THERETO," filed concurrently herewith, the entire disclosure of which is hereby incorporated by reference.
BACKGROUND
[0002] The present invention relates to flocculation and dewatering systems for separating solid-liquid mixtures. More particularly, the present invention relates to flocculation and dewatering systems for recycling and reconditioning subterranean treatment fluids and methods of use thereof.
[0003] Subterranean operations such as drilling, mineral exploring and geological coring often require fluids that are introduced into the subterranean environment for the completion of desired tasks. For example, drilling fluids, also commonly referred to as drilling muds, are used in most modern drilling operations. In a drilling operation, a drilling fluid provides a number of important functions, which includes preventing formation fluids from entering the wellbore, carrying out drill cuttings, suspending drill cuttings while drilling is paused, and keeping the drill bit cool and clean. Overall, drilling fluids provide stability to a wellbore during a drilling operation. Some fluids are referred to as "drill-in fluids." Drill-in fluids are specialty drilling fluids designed for drilling through the reservoir section of a wellbore. The reasons for using a specially designed mud are: ( 1) to drill the reservoir zone successfully, often a long, horizontal drainhole; (2) to minimize damage and maximize production of exposed zones; and (3) to facilitate the well completion needed, which can include complicated procedures. Drill-in fluids are often brines comprising only solids of appropriate particle size ranges such as salt crystals or calcium carbonate and polymers. Generally, only additives essential for filtration control and cuttings carrying are present in a drill-in fluid. The term drilling fluids as used herein includes drill-in fluids.
[0004] There are many different types of drilling fluids including water- based, oil-based, polymer-based, clay-based, and synthetic-based fluids. While the composition may vary, a drilling fluid is generally composed of a fluid (liquid or gas) and may further comprise various additives including, but not limited to, polymers, salts, clays, and viscosifiers. The exact composition of a drilling fluid may be engineered to meet the specific needs of a drilling operation based on factors such as rock formation, type of petroleum being recovered, environmental concerns, and the like. A drilling fluid is usually homogeneous and mixed prior to circulation in a subterranean environment. However, once a drilling fluid is introduced to a wellbore, its composition can change drastically. For example, drill cuttings such as rocks, sand, shale, grit, and other contaminants can become suspended and mixed in the drilling fluid during a drilling operation. These solids inevitably make their way up as part of returned fluids as the drilling fluid is returned to the surface.
[0005] While drilling fluids provide numerous advantages, there are several drawbacks. For example, drilling fluids can be very costly and, while the exact cost depends on the operation, can take up a significant portion of the total cost of drilling a well. Moreover, the long term effects that drilling fluids have on the environment may be uncertain. These important considerations have spurred efforts to recondition returned drilling fluids so that the drilling fluids may be recycled and reintroduced in a wellbore.
[0006] In conventional drilling operations, the drilling fluids are recirculated after removing the drilling cutting and other solid contaminants from the fluid. This recycling and reconditioning process generally involves recovering the returned drilling fluid at the surface, removing drilling cuttings and undesirable drill solids, and recirculating the reconditioned drilling fluid into the well. The removal or separation of solids from the drilling fluids is typically done using a size exclusion screen. Smaller solids may further be removed, at least partially, by additional processing equipments such as a hydrocyclone or centrifuges. A hydrocyclone or a centrifuge separate suspensions by density and generate two types of fluids, an overflow and an underflow. The composition of the overflow is the same or very similar to a new drilling fluid and may be reintroduced into the wellbore without further treatment. On the other hand, the underflow is a concentrated fluid comprising much of the unwanted solids present in the returned fluid.
[0007] There are, however, limitations on current separation techniques. For example, in a typical recycling and reconditioning process, only about 50-80% of the returned fluid may be separated into overflow. This means that a significant volume of underflow is left over. Because this underflow typically needs further treatment before it can be disposed or reused, there are considerable cost and time considerations.
SUMMARY OF THE INVENTION
[0008] The present invention relates to flocculation and dewatering systems for separating solid-liquid mixtures. More particularly, the present invention relates to flocculation and dewatering systems for recycling and reconditioning well treatment fluids and methods of use thereof.
[0009] In one embodiment, a flocculation and dewatering system comprises: a solid-liquid sorter; a flocculation chamber comprising : a flocculation trough comprising : at least one baffle; an injection port for introducing a flocculant; and an outlet for removing a flocculated fluid; a dewatering rack wherein the outlet introduces the flocculated fluid into the dewatering rack comprising : at least one filtration collection bag; a filter press; and a pump for pumping fluids in a conduit network running at least partially through the flocculation and dewatering system.
[0010] In one embodiment, a flocculation chamber comprises: a flocculation trough comprising : at least one baffle; an injection port for introducing a flocculant; and an outlet for removing a flocculated fluid.
[0011] In one embodiment, a dewatering rack comprises: at least one filtration collection bag situated in at least one collection basket; and a filter press.
[0012] The features and advantages of the present invention will be readily apparent to those skilled in the art upon a reading of the description of the preferred embodiments that follows.
BRIEF DESCRIPTION OF THE DRAWINGS
[0013] The following figures are included to illustrate certain aspects of the present invention, and should not be viewed as exclusive embodiments. The subject matter disclosed is capable of considerable modification, alteration, and equivalents in form and function, as will occur to those skilled in the art and having the benefit of this disclosure.
[0014] Figure 1A- 1B are schematic diagrams of a flocculation and dewatering system. Figure 1A is an embodiment of a flocculation and dewatering system in reconditioning mode. Figure IB is an embodiment of a flocculation and dewatering system in mixing mode.
[0015] Figure 2 is a close-up schematic diagram of an embodiment of a flocculation chamber and a dewatering rack.
[0016] Figure 3A-3C are schematic diagrams of the different positions of a multi-position lever system of a filter press.
DETAILED DESCRIPTION
[0017] The present invention relates to flocculation and dewatering systems for separating solid-liquid mixtures. More particularly, the present invention relates to flocculation and dewatering systems for recycling and reconditioning well treatment fluids and methods of use thereof.
[0018] The present invention provides systems and methods for recycling and reconditioning returned fluids. As used herein, "returned fluid" generally refers to a treatment fluid that has been introduced to a subterranean environment and that has been circulated back up to the surface. Suitable examples of returned fluids for use in conjunction with the present invention include, but are not limited to, drilling fluids, completion fluids, and combinations thereof. Fluids suitable for use in conjunction with the present invention may be water-based, oil-based, polymer-based, clay-based {e.g., bentontite), synthetic- based, and the like.
[0019] In particular, an example of a returned fluid may be a drilling fluid that has been used in a drilling operation and that includes various solid contaminants such as drill cuttings, rocks, sand, shale, grit, assorted debris, and other solid contaminants. As shown in Figure 1, the flocculation and dewatering system 100 of the present invention provides elements, such as, solid-liquid sorter 102, flocculation chamber 104, dewatering rack 110, etc., that may be used individually or in tandem to recondition returned fluids thereby forming a reconditioned fluid which may be recycled by being reused. The flocculation and dewatering system 100 of the present invention may also be used to mix various fluids and starting materials to provide treatment fluids which may be introduced into a subterranean environment. The elements may be modular in natu re and may be rearranged and/or reconfigu red as desired . The reconditioned fluids may be reused by being reintroduced into a su bterranean environment thereby minimizing generated chemical wastes.
[0020] It is believed that the present invention provides superior separation of solid-liquid mixtu res compared to typical separation systems and techniques. Specifically, it is believed that the present invention would provide a higher ratio of overflow to underflow as compared to typical separation systems and methods. As used herein, "overflow" refers to a separated portion of a returned fluid that may be reused and recycled . As used herein, "underflow" refers to a separated portion of a retu rned fluid that requires reconditioning to recover reusable and recyclable portions of a treatment fluid . Typically, the overflow may be reused without fu rther reconditioning . The u nderflow generally comprises solid contaminants such as those accu mu lated while a retu rned fluid is circulating in a su bterranean environment. In a drilling operation, solid contaminants may be drill cuttings, rocks, sand, shale, grit, assorted debris, and other solid contaminants which can become suspended and mixed in the drilling fluid du ring a drilling operation. In some embodiments, the overflow comprises reusable treatment fluids which may be introduced into the mixing unit 126. Moreover, the present invention is able to recondition the u nderflow so that a large portion is reusable in a subterranean operation and thus recyclable. The solid contaminants which are separated are typically not reusable. It is also believed that the present invention provides superior efficiency in the reconditioning of the underflow as compared to typical separation systems and techniques. This superior efficiency is in part related to the superior mixing and flocculating characteristics of the flocculating chamber 104, in particu lar, the flocculating trough 106. It is believed that the geometry (e.g., the slope of the trough) of the floccu lating trough 106 unexpectedly enhances the mixing and flocculation of the u nderflow. This ability to recondition returned fluids for su bsequent reuse in su bterranean operations enables the operator to save considerable costs.
[0021 ] Another advantage of the present invention is that the elements of the flocculation and dewatering system 100 have been configured (e.g. , geometrically, volumetrically, etc. ) and optimized to ease the handling of large amounts of returned fluids. Yet another advantage is that some or all of the elements of the present invention have been designed to be portable. The present invention also provides a single system which is able to function in two separate modes: reconditioning mode (Figure 1A) and mixing mode (Figure IB). This dual functionality provides added convenience and saves considerable cost. This may be particularly important if the particular flocculation and dewatering operation is located in a remote or hard to reach location.
[0022] To facilitate a better understanding of the present invention, the following examples of preferred embodiments are given. In no way should the following examples be read to limit, or to define, the scope of the invention.
[0023] Figure 1A shows a schematic diagram representing one embodiment of the present invention. Referring to Figure 1A, the flocculation and dewatering system 100 of the present invention generally comprises a solid-liquid sorter 102, a flocculation chamber 104, a pump 108, and a dewatering rack 110. The flocculation chamber generally comprise a flocculation trough 106. Optionally, the flocculation and dewatering system 100 may comprise a mixing unit 126 comprising a basin 128 for reintroducing overflow or reconditioned fluid. Figures 1A- 1B also show various elements of the present invention, including dewatering rack 110, hopper 112, pit/sump 114, filter 116, filtration collection bag 118, outlet 120, collection basket 122, filter press 124, mixing unit 126, basin 128, conduit network 130, two-way valve 132, active tank 134, baffle 200, injection port 202, flocculant dispenser 208, and lever system 300. The elements of the present invention will be described below.
[0024] In some embodiments, the solid-liquid sorter 102 may sort a solid-liquid mixture such as a suspension by density using centrifugal force. For example, a solid-liquid sorter 102 will separate a returned fluid such as a drilling fluid which has been circulated in a subterranean environment into a relatively lower density fluid (overflow) comprising relatively fewer solid contaminants and a relatively higher density fluid (underflow) comprising relatively more solid contaminants. Suitable examples of solid-liquid sorter 102 include, but are not limited to, centrifuges, shaker beds, helix tubular sorters, counterspinning screens, vibrating beds, filter boxes and/or hydrocyclones.
[0025] In the embodiment shown in Figure 1A, the returned fluid may be introduced in a solid-liquid sorter 102 in a number of ways including a conduit network 130 comprising a two-way valve 132 which controls the direction of fluid flow. In some embodiments, a plurality of one-way valves (not shown) may be used instead of two-way valves 132. The conduit network 130 at least partially runs through the flocculation and dewatering system 100 thereby providing a fluidic connection between the elements. In some embodiments, there may be a plu rality of two-way valves 132 to form a two- way valve system . In some embodiments, the condu it network 130 is connected to the basin 128 of a mixing unit 126. In some embodiments, a basin 128 may be connected to an active tank 134. In some embodiments, an active tank 134 may be used as a reservoir to store the overflow and/or reconditioned fluids. In some embodiments, an active tank 134 may i ntroduce fluids (e.g., overflow, recondition fluid, etc.) to a basin 128 which then acts as a reservoir for mixing fluids.
[0026] Referring to Figures 1A- 1 B, the basin 128 may be used to mix various components, including the starting materials of a treatment fluid and the reconditioned fluid . In some embodiments, the flocculation and dewatering system 100 may switch between a mixing mode wherein the primary function is to prepare a treatment fluid to a reconditioning mode wherein the primary function is to recondition a returned fluid for subsequent use in a su bterranean application. A switch between the modes can be quickly and efficiently performed in the field, without having to relocate or reconfigure the floccu lation and dewatering system 100.
[0027] Figure 1A is a schematic diagram of the floccu lation and dewatering system 100 in a typical reconditioning mode. In the embodiment shown in Figure 1A, multiple two-way valves 132 are positioned so that retu rned fluid may be drawn from a pit or sump 114 through a conduit network 130 by a pump 108. The returned fluid may pass through an optional filter 116 in order to remove solids that are above the maximum size tolerated by the floccu lation and dewatering system 100. Su itable examples of a filter 116 include a cylindrical sleeve and/or tube having openings in the periphery so that flu id may enter axially at one end and exit radially through the peripheral openings. Eventually, the returned fluid is introduced into solid-liquid sorter 102 for flocculation and later dewatered in a dewatering rack 110. The condu it network 130 may also be used to transfer the removed water from the dewatering rack 110 to other elements of the flocculation and dewatering system 100.
[0028] Figure IB is a schematic diagram of the floccu lation and dewatering system 100 in a typical mixing mode. The elements of the flocculation and dewatering system 100 are modular and may be rearranged and/or reconfigured as desired . In the mixing mode, the flocculation and dewatering system 100 is generally configured similar to U. S. Patent No. 5,779,355, which is herein incorporated by reference. Generally, while in the mixing mode, the floccu lation cham ber 104 and the dewatering rack 110 are not actively used.
[0029] Generally, as shown in Figures 1A- 1B, a pump 108 may be used to transfer fluids through the conduit network 130. Suitable examples of a pump include piston pumps, screw type pu mps, diaphrag m pumps, positive displacement pu mps, and centrifugal pu mps. In some embodiments, the pu mp 108 is rated between about 5 horsepowers to about 25 horsepowers. In some embodiments, the pump 108 weighs less than about 1000 pounds. The pu mp 108 is useful for transferring fluids from one element (e.g. , mixing unit 126, solid-liqu id sorter 102, etc.) of the floccu lation and dewatering system 100 to another element (e.g. , solid-liqu id sorter 102, flocculation chamber 104, etc. ) of the flocculation and dewatering system 100. Depending on desirability, the pump 108 may be installed anywhere within the flocculation and dewatering system 100. In some embodiments, a plurality of pumps may be used .
[0030] Referring to Figure 1A, the solid-liquid sorter 102 is generally configured to transfer the u nderflow to the flocculation chamber 104 by a pump 108 or by other suitable techniques such as by gravity and the like. Where desirable, the solid-liquid sorter 102 will be configured to conveniently transfer the overflow to a mixing unit 126 comprising a basin 128 through the conduit network 130. In some embod iments, the mixing unit 126 may have several functions including, but not limited to, mixing the overflow with u nused treatment fluids and reintroducing the mixture into a su bterranean environment. The mixing u nit 126 may also comprise a hopper 112 for introducing dry reagent products which is later mixed in with the treatment flu id . In some embodiments, the subterranea n environment may be a wellbore for oil drilling, geological coring, mineral exploring and the like.
[0031 ] Figu re 2 is a close-u p schematic showing the solid-liquid sorter 102, flocculation chamber 104 and the dewatering rack 110. In the embodiment shown in Figure 2, the solid-liquid sorter 102 is a hydrocyclone. Referring to Figure 2, the flocculation chamber 104 generally comprises a flocculation trough 106 which comprises at least one baffle 200 and an injection port 202 for introducing a flocculant and an outlet 120 for removing a flocculated fluid. The outlet 120 is used to transfer a flocculated fluid from the flocculation chamber 104 to the dewatering rack 110.
[0032] Referring to Figure 2, in some embodiments, a hydrocyclone will comprise a conical base wherein the top size of the conical base is about 2 inches to about 4 inches in diameter. In some embodiments, the top size of the conical base is about 1 inch to about 2 inches in diameter. The top size of the conical base determines the size or range of sizes of particles which may be separated. Generally, a larger top size will separate relatively larger solids while a smaller top size will separate relatively smaller solids. It is believed that a top size of about 2 inches to 4 inches in diameter will separate approximately 15-30 micron solids. In some embodiments, a plurality of hydrocyclones may be used to separate a multiple range of solid sizes. The plurality of hydrocyclones may be used sequentially or in replacement.
[0033] Referring to Figure 2, in some embodiments, the injection port
202 is connected to a flocculant dispenser 208 (shown in Figure 1A) which can introduce wet or dry flocculants into the flocculation chamber 104. The mixing of the flocculant with the underflow forms a flocculated fluid. Suitable examples of flocculants include, but are not limited to, alum, polyacrylamide, partially- hydrolyzed polyacrylamide (PHPA), chitosan, guar, and gelatin.
[0034] Referring to Figure 2, in some embodiments, the flocculation trough 106 may be partitioned to divide the flocculation chamber 104 into an upper flocculation chamber 204 and a lower flocculation chamber 206. In some cases, the partition is created by having a flocculation trough 106 having a slope of about 1 degree to about 46 degrees as measured from the bottom of the flocculation chamber 104. The sloped flocculation trough 106 comprises the upper flocculation chamber 204 while the bottom portion of the flocculation chamber 104 comprises the lower flocculation chamber 206. In some embodiments, the lower flocculation chamber 206 may comprise an outlet 120 for transferring the flocculated fluid out of the flocculation chamber 104. The partitioning of the flocculation chamber 104 into an upper flocculation chamber 204 and a lower flocculation chamber 206 may enhance mixing of the flocculant with the underflow thereby enhancing the flocculation of the underflow for several reasons. Without being limited by theory, it is believed that the baffle 200 and the slope of the flocculation trough 106 will facilitate the mixing of the returned fluid and the flocculant. The partition lengthens the duration of mixing as the fluids must travel a farther distance before exiting the flocculation chamber 104. It is also believed that mixing and flocculating is further enhanced by the impact created as the returned fluid is introduced into the flocculation chamber 104 and crashes into the flocculation trough 106. This was an unexpected result confirmed by visual inspection. Once the flocculant is introduced into the flocculation trough 106 and mixed with the underflow, a flocculated fluid will form. In some embodiments, the dimensions of the flocculation trough 106 is about 24 inches to about 48 inches in length, about 6.5 inches to about 18 inches in width, and about 10 inches to 24 inches in height.
[0035] Referring again to Figure 2, the dewatering rack 110 generally comprise at least one filtration collection bag 118; and a filter press 124. In some embodiments, the filtration collection bag 118 may be a weeping bag. In some embodiments, the filtration collection bag 118 may be placed in a collection basket 122 or on the ground . The collection basket 122 may be configured to allow fluids to pass through. For example, the collection basket 122 may comprise meshes 210, pores, or be generally permeable. In some embodiments, the filtration collection bag 118 may be made from woven felt, non-woven felt, or a combination of both. The filtration collection bag 118 may hold about 10 gallons to about 100 gallons of flocculated fluid. In some embodiments, there may be more than one filtration collection bag 118. Once the filtration collection bag 118 is filled with a flocculated fluid, a filter press 124 (shown in Figure 3A-3C) may be used to remove water from the flocculated fluid to form a dewatered flocculated fluid. Referring to Figure 1A, in some embodiments, the removed water may then be introduced into the mixing unit 126 or into the flocculant dispenser 208.
[0036] Figures 3A-3C show the filter press 124 with a lever system 300. Referring to Figures 3A-3C, the filter press 124 is generally configured to engage the filtration collection bag 118 and dewater the flocculated fluid. In some embodiments, the filter press 124 may be activated manually as by a lever system 300. As shown in Figures 3A-3C, the lever system 300 may be a multi-position lever system. Figure 3A shows the filter press 124 in an uncompressed state. Figure 3B shows the filter press 124 in a semi-compressed state. Figure 3C shows the filter press 124 in a fully compressed state. In some embodiments, the filter press 124 may dewater the flocculated fluid hydraulically, pneumatically, or both.
[0037] The methods of the present invention generally comprise providing a returned fluid comprising a fluid; and a solid contaminant; introducing the returned fluid into a solid-liquid sorter thereby separating the returned fluid into an overflow and an underflow; flocculating the underflow in a flocculating chamber 104 thereby forming a flocculated fluid; and dewatering the flocculated fluid using a dewatering rack 110.
[0038] The fluid may be a liquid or gas-based fluid. In some embodiments, the returned fluid may comprise a drilling fluid wherein the drilling fluid has been circulated in a subterranean environment. Flowing the returned fluid through a hydrocyclone may separate the returned fluid into an overflow and an underflow. The overflow may comprise reusable drilling fluid. The underflow may comprise solid contaminants. In some cases, the overflow may be introduced into a mixing unit 126 comprising a basin 128. In some embodiments, the underflow may be flocculated in a flocculation chamber 104 and dewatered in a dewatering rack 110. In some embodiments, the underflow may be dewatered by pressing the filtration collection bag 118 such as by pressing a filter press 124.
[0039] Therefore, the present invention is well adapted to attain the ends and advantages mentioned as well as those that are inherent therein. The particular embodiments disclosed above are illustrative only, as the present invention may be modified and practiced in different but equivalent manners apparent to those skilled in the art having the benefit of the teachings herein. Furthermore, no limitations are intended to the details of construction or design herein shown, other than as described in the claims below. It is therefore evident that the particular illustrative embodiments disclosed above may be altered, combined, or modified and all such variations are considered within the scope and spirit of the present invention. While compositions and methods are described in terms of "comprising," "containing," or "including" various components or steps, the compositions and methods can also "consist essentially of" or "consist of" the various components and steps. All numbers and ranges disclosed above may vary by some amount. Whenever a numerical range with a lower limit and an upper limit is disclosed, any number and any included range falling within the range is specifically disclosed. In particular, every range of values (of the form, "from about a to about b," or, equivalently, "from approximately a to b," or, equivalently, "from approximately a-b") disclosed herein is to be understood to set forth every number and range encompassed within the broader range of values. Also, the terms in the claims have their plain, ordinary meaning unless otherwise explicitly and clearly defined by the patentee. Moreover, the indefinite articles "a" or "an," as used in the claims, are defined herein to mean one or more than one of the element that it introduces. If there is any conflict in the usages of a word or term in this specification and one or more patent or other documents that may be incorporated herein by reference, the definitions that are consistent with this specification should be adopted.

Claims

CLAIMS The invention claimed is:
1. A flocculation and dewatering system comprising :
a solid-liquid sorter;
a flocculation chamber comprising :
a flocculation trough comprising :
at least one baffle;
an injection port for introducing a flocculant; and an outlet for removing a flocculated fluid;
a dewatering rack wherein the outlet introduces the flocculated fluid into the dewatering rack comprising :
at least one filtration collection bag;
a filter press; and
a pump for pumping fluids in a conduit network running at least partially through the flocculation and dewatering system.
2. The flocculation and dewatering system of claim 1 wherein the solid-liquid sorter is a centrifuge, a shaker bed, a helix tubular sorter, a counterspinning screen, a vibrating bed, a filter box, or a hydrocyclone.
3. The flocculation and dewatering system of claim 1 wherein a flocculant comprises at least one flocculant selected from the group consisting of: alum, polyacrylamide, partially-hydrolyzed polyacrylamide (PHPA), chitosan, guar, and gelatin.
4. The flocculation and dewatering system of claim 1 wherein the filtration collection bag is placed in a collection basket.
5. The flocculation and dewatering system of claim 2 wherein the hydrocyclone comprises a conical base wherein the top size of the conical base is between about 2 to 4 inches in diameter.
6. The flocculation and dewatering system of claim 2 further comprising at least one additional hydrocyclone.
7. The flocculation and dewatering system of claim 6 wherein the additional hydrocyclone comprises a conical base wherein the top size of the conical base is between about 1 to 2 inches in diameter.
8. The flocculation and dewatering system of claim 1 wherein the pump comprises at least one pump selected from the group consisting of: a piston pump, a screw type pump, a diaphragm pump, a positive displacement pump, and a centrifugal pump.
9. The flocculation and dewatering system of claim 1 wherein the filter press compresses the filtration collection bag hydraulically, pneumatically, or a combination thereof.
10. The flocculation and dewatering system of claim 1 further comprising a mixing unit comprising a basin for reintroducing overflow or reconditioned fluid.
11. A flocculation chamber comprising :
a flocculation trough comprising :
at least one baffle;
an injection port for introducing a flocculant; and
an outlet for removing a flocculated fluid.
12. The flocculation chamber of claim 11 wherein the flocculant comprises at least one flocculant selected from the group consisting : alum, polyacrylamide, partially-hydrolyzed polyacrylamide (PHPA), chitosan, guar, and gelatin.
13. The flocculation chamber of claim 11 wherein the flocculation trough is about 24 inches to about 48 inches in length, about 6.5 inches to about 18 inches in width, and about 10 inches to 24 inches in height.
14. The flocculation chamber of claim 11 wherein the flocculation trough is sloped at an angle of about 1 degree to about 46 degrees as measured from the bottom of the flocculation chamber.
15. The flocculation chamber of claim 11 wherein the injection port is connected to a flocculant dispenser.
16. A dewatering rack comprising :
at least one filtration collection bag situated in at least one collection basket; and
a filter press.
17. The portable dewatering rack of claim 16 wherein the collection basket is meshed, permeable, or porous.
18. The dewatering rack of claim 16 wherein the filtration collection bag comprises one selected from the group consisting of: non-woven felt, woven felt, and a combination thereof.
19. The dewatering rack of claim 16 wherein the filter press is activated by a lever system.
20. The dewatering rack of claim 16 wherein the filter press compresses the filtration collection bag hydraulically, pneumatically, or a combination thereof.
EP12733274.0A 2011-07-11 2012-06-18 Injection flocculation and compression dewatering unit for solids control and management of drilling fluids and methods relating thereto Withdrawn EP2731695A2 (en)

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