EP2719295A1 - Article à fumer ventilé incluant un matériau sorbant - Google Patents

Article à fumer ventilé incluant un matériau sorbant Download PDF

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Publication number
EP2719295A1
EP2719295A1 EP12188478.7A EP12188478A EP2719295A1 EP 2719295 A1 EP2719295 A1 EP 2719295A1 EP 12188478 A EP12188478 A EP 12188478A EP 2719295 A1 EP2719295 A1 EP 2719295A1
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EP
European Patent Office
Prior art keywords
filter
sorbent material
smoking article
ventilation
ventilation zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12188478.7A
Other languages
German (de)
English (en)
Inventor
Celine Gambs
Ping Li
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Philip Morris Products SA
Original Assignee
Philip Morris Products SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philip Morris Products SA filed Critical Philip Morris Products SA
Priority to EP12188478.7A priority Critical patent/EP2719295A1/fr
Publication of EP2719295A1 publication Critical patent/EP2719295A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04—Tobacco smoke filters characterised by their shape or structure
    • A24D3/043—Tobacco smoke filters characterised by their shape or structure with ventilation means, e.g. air dilution
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04—Tobacco smoke filters characterised by their shape or structure
    • A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives

Definitions

  • the present invention relates to a ventilated smoking article incorporating a filter wrapper with a sorbent.
  • Filter cigarettes typically comprise a rod of tobacco cut filler surrounded by a paper wrapper and a cylindrical filter aligned in end-to-end relationship with the wrapped tobacco rod, with the filter attached to the tobacco rod by tipping paper.
  • the filter may consist of a plug of cellulose acetate tow wrapped in porous plug wrap.
  • Ventilation zone in a smoking article, typically in the form of perforations provided in the tipping paper or the plug wrap, or both.
  • the ventilation zone allows air to enter the filter during smoking and the air dilutes the mainstream smoke coming through the filter from the burning tobacco rod, thereby reducing the levels of smoke constituents delivered to the consumer.
  • the ventilation zone typically includes perforations provided at one or more positions along the filter of the smoking article and some of the perforations can be inadvertently blocked during smoking, for example, by the lips or fingers of the consumer. Air is thereby prevented from entering the filter and the amount of ventilation of the mainstream smoke decreases.
  • a sorbent material such as activated carbon within the filter of a smoking article as an additional means to reduce the level of certain smoke constituents.
  • sorbent materials may adversely affect the taste of the mainstream smoke in a way that is unfavourable to some consumers. Therefore it would be desirable to provide a novel filter arrangement for a smoking article that substantially maintains the delivery level of certain smoke constituents whilst having a low amount of sorbent material.
  • a smoking article comprising a tobacco rod, and a filter connected to the tobacco rod and comprising one or more filter segments circumscribed by a filter wrapper including a sorbent material.
  • the filter comprises a ventilation zone provided upstream of at least 80% by weight of the sorbent material.
  • the sorbent material and the ventilation zone are provided in order to reduce mainstream gas phase smoke constituents.
  • the ventilation zone is designed so as to provide from about 10% to about 60% ventilation of mainstream smoke and the contribution of the sorbent material to the reduction of mainstream gas phase smoke constituents is at least 20% by weight, based on the total weight of mainstream gas phase smoke constituents reduced by the sorbent material and ventilation.
  • the ventilation zone refers to the arrangement of perforations or holes that are provided on the filter to allow ventilation of the filter and ventilation of the mainstream smoke during smoking, through the ingress of air through the holes into the filter.
  • the ventilation zone is arranged to provide from about 10% to about 60% ventilation of mainstream smoke.
  • 10% to 60%, by volume, of the total air content that passes through the filter during smoking arrives through the ventilation zone.
  • 'ventilation' refers to the percentage by volume of air that is included in the smoke delivered to the consumer from the mouth end of the filter when the ventilation zone is fully open. By 'fully open' it means that no part of the ventilation zone is covered by, for example, the fingers of a consumer. More preferably, the ventilation zone provides between 15% and 55% ventilation of the mainstream smoke, more preferably between 20% and 50%. The level of ventilation achieved by the ventilation zone can be determined using ISO test method 9512:2002.
  • the term 'mainstream gas phase smoke constituents' is intended to refer to gas phase carbonyl compounds, including aldehyde and ketone compounds.
  • the gas phase constituents may include one or more of formaldehyde, acetaldehyde, acetone and acrolein, butyraldehyde, crotonaldehyde, formaldehyde, methylethylketone and propionaldehyde.
  • the level of mainstream gas phase smoke constituents delivered during smoking of a smoking article according to the invention with the ventilation zone providing 10% to 60% ventilation of mainstream smoke may be determined by smoking the smoking article under ISO conditions (35ml puffs lasting 2 seconds each, every 60 seconds).
  • the level of mainstream gas phase smoke constituents is normalised to nicotine delivery, so that the level is expressed per mg of nicotine.
  • a first smoking article having no ventilation is smoked according to ISO conditions and the amount, by weight, of mainstream gas phase smoke constituents, is calculated.
  • a second smoking article identical to the first smoking article and having a given ventilation, as defined above, but not containing any sorbent material is then smoked according to the ISO conditions and the amount, by weight, of mainstream gas phase smoke constituents, is calculated.
  • the difference between the results for the first and second smoking articles is measured allowing the contribution of the ventilation to the reduction of the mainstream gas phase smoke constituents to be calculated.
  • a third smoking article identical to the second smoking article but containing the sorbent material is then smoked according to the ISO conditions. The difference in the weight of mainstream gas phase smoke constituents between the second and the third smoking article is measured allowing the contribution of the sorbent material to be calculated.
  • the level of gas phase smoke constituents in the mainstream smoke is determined as an average for a sample of 20 smoking articles.
  • the level of smoke constituents is measured as the aggregate amount of the carbonyl compounds referred to above.
  • the present invention provides an effective way of maintaining a relatively constant delivery of gas phase smoke constituents in a ventilated smoking article, regardless of whether the reduction is due to ventilation or sorption by the sorbent material. Furthermore, at lower levels of ventilation the contribution of the sorbent remains important whereas, at higher levels of ventilation the contribution of the sorbent material is reduced so much that the sorbent material is no longer necessary.
  • the reduction of smoke constituents in the mainstream smoke is achieved both through the ventilation of the mainstream smoke and by the sorbent material.
  • the arrangement of the sorbent material and ventilation zone is such that there is a balance between the reduction of gas phase smoke constituents by ventilation and the reduction of the same gas phase smoke constituents by the sorbent material, wherein the balance will automatically shift depending on the degree to which the ventilation zone is blocked. If the level of ventilation decreases as a result of blocking of the ventilation zone, the sorption of smoke constituents by the sorbent material will increase to compensate for the lower ventilation. The total level of smoke constituents can therefore be maintained with as little variation as possible, irrespective of whether the ventilation zone is open, partially blocked, or fully blocked.
  • the balance between the level of ventilation of the mainstream smoke achieved by the ventilation zone and the sorption of mainstream smoke constituents by the sorbent material can be controlled by adjusting parameters of the filter, including but not limited to the positioning and distribution of the ventilation zone, the level of ventilation achieved by the ventilation zone, and the positioning, distribution and amount of sorbent material provided, as described in more detail below.
  • the amount and position of the ventilation zone and the amount and position of the sorbent material can be adjusted such that the delivery of gas phase smoke constituents is the same whether the ventilation zone is more open or more closed.
  • the ventilation zone may be provided upstream of most or all of the sorbent material.
  • the flow of the mainstream smoke within the filter changes depending on how much air is drawn through the filter from the ventilation zone.
  • the ventilated air is typically drawn through the filter on the outside of the filter material, constraining the flow of the mainstream smoke towards the centre of the filter.
  • the air drawn through the ventilation zone therefore provides an outer, concentric layer which effectively separates and shields the mainstream smoke from the sorbent material that is included in the filter wrapper.
  • the mainstream smoke has a reduced contact with the sorbent material.
  • it is advantageous for the sorbent material to contribute to the reduction of mainstream smoke constituents and so it is desirable that ventilation of mainstream smoke is not the sole factor responsible for reducing mainstream smoke constituents.
  • the ventilation is 'upstream' of at least 80% by weight of the sorbent material, meaning that the ventilation is provided further from the mouth end of the smoking article than at least 80% by weight of the sorbent material.
  • the mainstream smoke is drawn through the smoking article from an upstream end, closest to the burning end of the tobacco rod, to a downstream end, at the mouth end of the filter. The mainstream smoke will therefore pass the ventilation zone first, before reaching at least 80% by weight of the sorbent material in the filter wrapper.
  • the ventilation zone is in the form of one or more rows of perforations extending circumferentially around the filter.
  • a plurality of rows of perforations may be provided at spaced apart locations along the filter, for example at least 5mm from one another, or at least 10mm from one another.
  • This arrangement means that air is admitted into the filter at different positions during smoking and may help to maintain a consistent layer of air between the mainstream smoke and the sorbent material along the full length of the sorbent material.
  • the most upstream ventilation zone may be upstream of all or most of the sorbent material.
  • the flow of air and smoke through the filter will be a combination of two flow patterns. That is, mainstream smoke will comprise a combination of smoke arriving through the tobacco rod and air arriving through the ventilation zone.
  • the ventilation level can advantageously be adjusted to control the thickness of the concentric air layer flowing through the outer concentric region of the filter and separating the mainstream smoke from the sorbent material.
  • the most upstream portion of the ventilation zone is provided between 20 mm and 30 mm from the mouth end of the smoking article.
  • the most upstream portion of the ventilation zone is provided at least 2 mm from the rod end of the filter, where the filter abuts the tobacco rod. This positioning of the ventilation zone away from the mouth end of the filter and towards the tobacco rod advantageously increases the available area in which the sorbent material may be placed downstream of the ventilation zone.
  • the ventilation zone is preferably provided upstream of all, or substantially all of the sorbent material. Whilst the ventilation zone is preferably provided upstream of all of the sorbent material, the skilled person will appreciate that the desired effect of the present invention can be achieved where the majority of the sorbent material is downstream of the ventilation zone, even if a small proportion is provided at the position of the ventilation zone, or upstream of the ventilation zone.
  • the ventilation zone is provided upstream of at least 80% of the sorbent material.
  • the sorbent material contributes at least 20% by weight to the reduction of mainstream gas constituents based on the total weight of mainstream gas phase smoke constituents reduced by the combination of sorbent material and ventilation. Preferably the contribution is at least 30%.
  • the sorbent material may contribute up to about 100% of the reduction. Preferably, the sorbent material contributes up to about 95%, more preferably up to about 80% of the reduction.
  • the sorbent material may comprise any suitable sorbent or combination of sorbents.
  • Suitable sorbents include but are not limited to activated carbon, zeolites, sepiolites, alumina, molecular sieves and combinations thereof.
  • the sorbent material is activated carbon.
  • the filter wrapper of smoking articles according to the invention comprises a layer of sorbent material applied over an area of a surface of the filter wrapper.
  • the amount of sorbent material in the layer is at least about 20 mg.
  • the amount of sorbent material is preferably up to about 120 mg, more preferably up to about 100 mg, even more preferably up to about 60 mg.
  • the amount of sorbent material is between about 20 mg and about 120 mg, more preferably between about 40 mg and about 60 mg.
  • the sorbent material is preferably provided in the form of a particulate or granular sorbent, which is preferably applied to a layer of adhesive or binder on the surface of the filter wrapper.
  • the sorbent material may be provided as a separate layer located at the surface of the filter wrapper.
  • the sorbent material may be applied as a separate layer to the outer surface of a filter segment and the filter wrapper may be wrapped over the layer of sorbent material to bring the surface of the filter wrapper into contact with the sorbent material.
  • a sorbent material may be incorporated towards the outside of the filter material itself.
  • a particulate sorbent material may be provided in a concentric, outer layer of the filter tow, for example a concentric, outer layer that is less than 1 mm thick.
  • the sorbent material may be provided uniformly in a concentric outer layer of the filter tow, or there may be a concentric gradient of sorbent material within the filter, wherein the proportion of sorbent material in the filter tow increases towards the outside of the filter.
  • a sorbent material may be incorporated into the sheet material forming the filter wrapper, for example, the sorbent material may be incorporated into a paper material during production of the paper material.
  • the sorbent material preferably covers at least 50% of the outer or inner surface of the filter wrapper, more preferably at least 60%.
  • the sorbent material may be provided within a single area, or may be provided in a plurality of areas over the surface of the filter wrapper, for example, in the form of a pattern applied to the surface of the filter wrapper.
  • the sorbent material is preferably provided on the inner surface of the filter wrapper, wherein the 'inner' surface refers to the radially inner surface of the wrapper, which is closest to the filter segment.
  • the sorbent material may be provided on either or both of the inner and outer surfaces since the mainstream smoke will be in contact with both surfaces during smoking.
  • the filter wrapper to which the sorbent material is applied is a plug wrap circumscribing the filter along at least a part of its length.
  • the sorbent material may be applied to an inner layer of plug wrap, the inner surface of which is in contact with the underlying filter material.
  • the filter is wrapped with a second layer of plug wrap, for example a layer of plug wrap that combines the different segments of a multi-component filter.
  • sorbent material may be applied to this second layer of plug wrap, which overlies one or more inner layers of an air permeable plug wrap.
  • the sorbent material may be applied to an area of the inner surface of the second layer of plug wrap.
  • the sorbent material may be applied to the outer surface of the second layer of plug wrap, in particular where the second layer of plug wrap is formed of a substantially air permeable sheet material so that the mainstream smoke will readily permeate through the second layer of plug wrap to come into contact with the sorbent material.
  • the filter wrapper to which the sorbent material is applied is a tipping wrapper, such as a tipping paper, circumscribing the filter and connecting the filter to the tobacco rod.
  • the sorbent material is provided on the tipping wrapper, the sorbent material should be applied to the inner surface of the tipping wrapper so that it is not exposed at the outside of the filter.
  • the filter of smoking articles according to the present invention may include a single filter segment.
  • the filter may comprise two or more filter segments in axial alignment with each other.
  • the filter segment or segments may take a variety of forms and suitable filter segments would be known to the skilled person.
  • the filter segments may be of the same construction and materials as each other, or may have a different construction, or contain different filtration material or additives.
  • the filter segment or segments are each formed of a plug of fibrous filtration material, such as cellulose acetate tow or paper, and wrapped with a plug wrap.
  • One or more of the filter segments may include a particulate material.
  • the particulate material is preferably incorporated in an upstream filter segment, for example, in a rod end filter segment.
  • the particulate material may be dispersed through a plug of fibrous filtration material, such as cellulose acetate or paper.
  • a filter plasticiser may be applied to the fibrous filtration material in a conventional manner, by spraying it onto the separated fibres, preferably before applying the particulate material to the filtration material.
  • the filter may include a filter segment with a hollow cavity at least partially filled with a particulate material. In such cases, the hollow cavity is preferably provided between two plugs of a filtration material.
  • the particulate material incorporated into the filter may include at least one sorbent material, such as those indicated above for inclusion in the filter wrapper. Where a sorbent material is incorporated within the filter, the amount of sorbent material within the filter should be less than the amount of sorbent material included in the filter wrapper so that the performance characteristics of the filter can be maintained.
  • the particulate material incorporated into the filter may include at least one flavourant material.
  • the particulate material may include particles of a sorbent material or cellulosic material loaded with a liquid flavourant, such as menthol.
  • the particulate material may comprise particles of plant material.
  • the plant material may be in the form of plant leaf, as described in EP-A-1,958,523 .
  • the filter segment may include leaf from tobacco, green tea, mint, such as peppermint or spearmint, laurel, eucalyptus, basil, sage, verbena and tarragon.
  • the plant material may alternatively be in the form of a seed, root, bark or flower, such as those typically used as spices.
  • one or more of the filter segments may have a liquid flavourant such as menthol applied directly to the filtration material.
  • the overall length of smoking articles according to the invention is between 70 mm and about 128 mm, for example about 84 mm.
  • the external diameter of smoking articles according to the invention is between about 5 mm and about 8.5 mm, more preferably about 7.9 mm.
  • the overall length of the filters of smoking articles according to the invention is between about 18 mm and about 36 mm, more preferably about 27 mm.
  • the smoking articles of the present invention comprise a rod of tobacco material, which is attached to the filter by a tipping wrapper.
  • the rod of tobacco material may include cut tobacco taken from one or more types of tobacco leaf, expanded tobacco, reconstituted tobacco, or combinations thereof.
  • the filter cigarette 10 shown in Figure 1 comprises a wrapped rod 12 of tobacco cut filler, which is attached to an axially aligned filter 14.
  • the tobacco rod 12 is wrapped with a cigarette paper (not shown).
  • the filter 14 comprises a single segment 16, which is formed of a plug of cellulose acetate tow.
  • the filter segment 16 is wrapped with a plug wrap 18 which circumscribes the entire length of the filter 14.
  • the plug wrap 18 is formed of a sheet of an air permeable paper material and includes a layer of sorbent material 20 covering an area corresponding to approximately 50% of the inner surface of the plug wrap 18.
  • the layer of sorbent material 20 is formed of a substantially evenly distributed layer of around 50 mg of particulate activated carbon, which has been affixed to the inner surface of the plug wrap 18 by a suitable adhesive. In the assembled filter, the layer of sorbent material 20 extends circumferentially around the filter segment 16 and is in contact with the outer surface of the filter segment 16.
  • the wrapped tobacco rod 12 and the wrapped filter 14 are joined to each other by an outer tipping wrapper 22, which circumscribes the entire length of the filter 14 and an adjacent portion of the tobacco rod 12, and overlies the plug wrap 16.
  • the tipping wrapper 22 is formed of a tipping paper which has been provided with ventilation zone comprising a row of perforations 24 extending circumferentially around the filter 14.
  • the row of perforations 24 is positioned on the filter at the rod end of the filter segment 16, adjacent the interface between the filter 14 and the tobacco rod 12.
  • the entire area of the layer of sorbent material 20 is downstream of the row of perforations 24. With the perforations open, the ventilation zone provides about 60% ventilation of the mainstream smoke during smoking.
  • the positioning of the row of perforations 24 upstream of the entire layer of sorbent material 20 ensures that the mainstream smoke is directed away from the outside of the filter segment 16 into the centre of the filter before the mainstream smoke reaches the part of the filter segment at which the layer of sorbent material 20 starts.
  • the consumer may inadvertently block some of the perforations 24, for example, by placing their fingers around the filter in the region of the ventilation zone, so that less air is admitted into the filter 14 through the ventilation zone.
  • the volume of air admitted to the filter 14 will decrease and the ventilation of the mainstream smoke will also decrease so that the reduction in the levels of gas phase constituents as a result of ventilation will be less.
  • the contact of the mainstream smoke with the activated carbon in the layer of sorbent material 20 will increase the reduction of the gas phase constituents by the sorbent material so that the overall level of the gas phase constituents remains constant.
  • the layer of sorbent material is provided on the inner surface of the plug wrap, it will be appreciated that different arrangements of the layer of sorbent material on the plug wrap and/or the tipping wrapper could be provided with the same effect on the reduction of the gas phase constituents of the mainstream smoke, as described above.

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  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
EP12188478.7A 2012-10-15 2012-10-15 Article à fumer ventilé incluant un matériau sorbant Withdrawn EP2719295A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12188478.7A EP2719295A1 (fr) 2012-10-15 2012-10-15 Article à fumer ventilé incluant un matériau sorbant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12188478.7A EP2719295A1 (fr) 2012-10-15 2012-10-15 Article à fumer ventilé incluant un matériau sorbant

Publications (1)

Publication Number Publication Date
EP2719295A1 true EP2719295A1 (fr) 2014-04-16

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EP12188478.7A Withdrawn EP2719295A1 (fr) 2012-10-15 2012-10-15 Article à fumer ventilé incluant un matériau sorbant

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2949225A1 (fr) 2014-05-27 2015-12-02 Reemtsma Cigarettenfabriken GmbH Article à fumer
CN105192886A (zh) * 2015-10-21 2015-12-30 云南中烟工业有限责任公司 一种可调节卷烟烟气浓度的卷烟滤嘴
CN106018005A (zh) * 2016-06-24 2016-10-12 深圳瀚星翔科技有限公司 一种用于检测电子烟雾化蒸汽中羰基化合物的采样管及其制备方法和应用
CN106163302A (zh) * 2014-04-03 2016-11-23 日本烟草产业株式会社 低焦油薄荷醇香烟

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2249936A (en) * 1990-11-19 1992-05-27 Cigarette Components Ltd Smoke filter containing particulate smoke modifying additive
GB2261152A (en) * 1991-10-14 1993-05-12 Cigarette Components Ltd Tobacco smoke filter
WO2008074977A1 (fr) * 2006-12-21 2008-06-26 British American Tobacco (Investments) Limited Filtre pour article à fumer
EP1958523A2 (fr) 2006-08-04 2008-08-20 Philip Morris Products S.A. Filtre à multiples composants permettant de réhausser de multiple arômes
WO2009098462A1 (fr) * 2008-02-07 2009-08-13 Filtrona International Limited Filtre pour fumée de tabac
EP2510814A1 (fr) * 2011-04-15 2012-10-17 Philip Morris Products S.A. Article à fumer ventilé incluant un matériau sorbant

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2249936A (en) * 1990-11-19 1992-05-27 Cigarette Components Ltd Smoke filter containing particulate smoke modifying additive
GB2261152A (en) * 1991-10-14 1993-05-12 Cigarette Components Ltd Tobacco smoke filter
EP1958523A2 (fr) 2006-08-04 2008-08-20 Philip Morris Products S.A. Filtre à multiples composants permettant de réhausser de multiple arômes
WO2008074977A1 (fr) * 2006-12-21 2008-06-26 British American Tobacco (Investments) Limited Filtre pour article à fumer
WO2009098462A1 (fr) * 2008-02-07 2009-08-13 Filtrona International Limited Filtre pour fumée de tabac
EP2510814A1 (fr) * 2011-04-15 2012-10-17 Philip Morris Products S.A. Article à fumer ventilé incluant un matériau sorbant

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106163302A (zh) * 2014-04-03 2016-11-23 日本烟草产业株式会社 低焦油薄荷醇香烟
CN106163302B (zh) * 2014-04-03 2019-08-09 日本烟草产业株式会社 低焦油薄荷醇香烟
EP2949225A1 (fr) 2014-05-27 2015-12-02 Reemtsma Cigarettenfabriken GmbH Article à fumer
WO2015180821A1 (fr) 2014-05-27 2015-12-03 Reemtsma Cigarettenfabriken Gmbh Article à fumer
RU2649272C1 (ru) * 2014-05-27 2018-03-30 Реемтсма Цигареттенфабрикен Гмбх Курительное изделие
TWI643563B (zh) * 2014-05-27 2018-12-11 里滋麻煙草廠股份有限公司 吸煙物品
CN105192886A (zh) * 2015-10-21 2015-12-30 云南中烟工业有限责任公司 一种可调节卷烟烟气浓度的卷烟滤嘴
CN106018005A (zh) * 2016-06-24 2016-10-12 深圳瀚星翔科技有限公司 一种用于检测电子烟雾化蒸汽中羰基化合物的采样管及其制备方法和应用

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