EP2683479A4 - Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite y and associated hydrocarbon conversion processes - Google Patents

Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite y and associated hydrocarbon conversion processes

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Publication number
EP2683479A4
EP2683479A4 EP12755532.4A EP12755532A EP2683479A4 EP 2683479 A4 EP2683479 A4 EP 2683479A4 EP 12755532 A EP12755532 A EP 12755532A EP 2683479 A4 EP2683479 A4 EP 2683479A4
Authority
EP
European Patent Office
Prior art keywords
zeolite
hydrocarbon conversion
conversion processes
catalysts containing
hydrocracking catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12755532.4A
Other languages
German (de)
French (fr)
Other versions
EP2683479A1 (en
Inventor
Christopher G Oliveri
Wenyih Frank Lai
Ajit B Dandekar
Scott J Weigel
Robert Ellis Kay
Jianxin Jason Wu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/041,597 external-priority patent/US8852326B2/en
Priority claimed from US13/412,945 external-priority patent/US8778171B2/en
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of EP2683479A1 publication Critical patent/EP2683479A1/en
Publication of EP2683479A4 publication Critical patent/EP2683479A4/en
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7026—MFS-type, e.g. ZSM-57
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
EP12755532.4A 2011-03-07 2012-03-07 Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite y and associated hydrocarbon conversion processes Withdrawn EP2683479A4 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/041,597 US8852326B2 (en) 2011-03-07 2011-03-07 Aggregates of small particles of synthetic faujasite zeolite
US201161512042P 2011-07-27 2011-07-27
US201161512067P 2011-07-27 2011-07-27
US13/412,945 US8778171B2 (en) 2011-07-27 2012-03-06 Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite Y associated hydrocarbon conversion processes
PCT/US2012/027960 WO2012122208A1 (en) 2011-03-07 2012-03-07 Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite y and associated hydrocarbon conversion processes

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CN103934019B (en) * 2014-04-21 2015-11-11 四川省中明环境治理有限公司 A kind of preparations and applicatio method of producing ultra-clean low-coagulation diesel oil catalyst
CN105435835B (en) * 2014-08-29 2019-01-08 中国石油化工股份有限公司 A kind of hydrocracking catalyst and its preparation and application
CN105435837B (en) * 2014-08-29 2019-01-08 中国石油化工股份有限公司 A kind of hydrocracking catalyst and its preparation and application
US11311866B2 (en) * 2020-08-27 2022-04-26 Saudi Arabian Oil Company Cracking catalyst comprising platinum encapsulated in microporous silica

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US5993773A (en) * 1997-11-27 1999-11-30 Tosoh Corporation Low-silica faujasite type zeolite and method for producing the same
US20030100439A1 (en) * 2000-03-24 2003-05-29 Canos Avelino Corma Catalytic cracking materials based on ITQ-7 zeolites and their use in hydrocarbons cracking processes
US20090036294A1 (en) * 2004-01-29 2009-02-05 Younes Bouizi Catalyst in the form of grains comprising an acidic porous core surrounded by a uniform outer layer
US20100092383A1 (en) * 2004-04-23 2010-04-15 Massachusetts Institute Of Technology Mesostructured Zeolitic Materials and Methods of Making and Using the Same
WO2010077352A1 (en) * 2008-12-16 2010-07-08 Exxonmobil Research And Engineering Company Integrated hydrocracking and dewaxing of hydrocarbons

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US4897178A (en) * 1983-05-02 1990-01-30 Uop Hydrocracking catalyst and hydrocracking process
US6261441B1 (en) * 1998-09-24 2001-07-17 Mobil Oil Corporation Integrated hydroprocessing scheme with segregated recycle
US6500329B2 (en) * 1998-12-30 2002-12-31 Exxonmobil Research And Engineering Company Selective ring opening process for producing diesel fuel with increased cetane number
US6843977B2 (en) * 2000-05-25 2005-01-18 Board Of Trustees Of Michigan State University Ultrastable porous aluminosilicate structures and compositions derived therefrom
US6902664B2 (en) * 2002-11-08 2005-06-07 Chevron U.S.A. Inc. Extremely low acidity USY and homogeneous, amorphous silica-alumina hydrocracking catalyst and process
US7641788B2 (en) * 2003-06-26 2010-01-05 Haldor Topsoe A/S Hydrocarbon conversion process and catalyst

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US5993773A (en) * 1997-11-27 1999-11-30 Tosoh Corporation Low-silica faujasite type zeolite and method for producing the same
US20030100439A1 (en) * 2000-03-24 2003-05-29 Canos Avelino Corma Catalytic cracking materials based on ITQ-7 zeolites and their use in hydrocarbons cracking processes
US20090036294A1 (en) * 2004-01-29 2009-02-05 Younes Bouizi Catalyst in the form of grains comprising an acidic porous core surrounded by a uniform outer layer
US20100092383A1 (en) * 2004-04-23 2010-04-15 Massachusetts Institute Of Technology Mesostructured Zeolitic Materials and Methods of Making and Using the Same
WO2010077352A1 (en) * 2008-12-16 2010-07-08 Exxonmobil Research And Engineering Company Integrated hydrocracking and dewaxing of hydrocarbons

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EP2683479A1 (en) 2014-01-15
SG192577A1 (en) 2013-09-30
CA2825324C (en) 2017-09-05
CA2825324A1 (en) 2012-09-13

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