EP2616415A4 - Method of producing valuable aromatics and olefins from hydrocarbonaceous oils derived from coal or wood - Google Patents

Method of producing valuable aromatics and olefins from hydrocarbonaceous oils derived from coal or wood

Info

Publication number
EP2616415A4
EP2616415A4 EP11825444.0A EP11825444A EP2616415A4 EP 2616415 A4 EP2616415 A4 EP 2616415A4 EP 11825444 A EP11825444 A EP 11825444A EP 2616415 A4 EP2616415 A4 EP 2616415A4
Authority
EP
European Patent Office
Prior art keywords
olefins
coal
wood
oils derived
producing valuable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11825444.0A
Other languages
German (de)
French (fr)
Other versions
EP2616415A2 (en
EP2616415B1 (en
Inventor
Hong Chan Kim
Yong Seung Kim
Sung Won Kim
Sang Hun Oh
Hyuck Jae Lee
Dae Hyun Choo
Cheol Joong Kim
Gyung Rok Kim
Myoung Han Noh
Jae Suk Koh
Hyun Chul Choi
Eun Kyoung Kim
Yoon Kyung Lee
Jong Hyung Lee
Sun Choi
Seung Hoon Oh
Jae Hyun Koh
Sang Il Lee
Seung Woo Lee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SK Innovation Co Ltd
Original Assignee
SK Innovation Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SK Innovation Co Ltd filed Critical SK Innovation Co Ltd
Publication of EP2616415A2 publication Critical patent/EP2616415A2/en
Publication of EP2616415A4 publication Critical patent/EP2616415A4/en
Application granted granted Critical
Publication of EP2616415B1 publication Critical patent/EP2616415B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/13—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation with simultaneous isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/50—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • C07C2529/22—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP11825444.0A 2010-09-16 2011-09-15 Method of producing valuable aromatics and olefins from hydrocarbonaceous oils derived from coal or wood Active EP2616415B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020100091052A KR101735108B1 (en) 2010-09-16 2010-09-16 The method for producing valuable aromatics and olefins from hydrocarbonaceous oils derived from coal or wood
PCT/KR2011/006813 WO2012036484A2 (en) 2010-09-16 2011-09-15 Method of producing valuable aromatics and olefins from hydrocarbonaceous oils derived from coal or wood

Publications (3)

Publication Number Publication Date
EP2616415A2 EP2616415A2 (en) 2013-07-24
EP2616415A4 true EP2616415A4 (en) 2015-03-04
EP2616415B1 EP2616415B1 (en) 2016-08-31

Family

ID=45832112

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11825444.0A Active EP2616415B1 (en) 2010-09-16 2011-09-15 Method of producing valuable aromatics and olefins from hydrocarbonaceous oils derived from coal or wood

Country Status (9)

Country Link
US (1) US8962901B2 (en)
EP (1) EP2616415B1 (en)
JP (1) JP5890836B2 (en)
KR (1) KR101735108B1 (en)
CN (1) CN103108849B (en)
BR (1) BR112013006211B1 (en)
ES (1) ES2597702T3 (en)
SG (1) SG188984A1 (en)
WO (1) WO2012036484A2 (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101973703B1 (en) * 2011-07-29 2019-04-29 사우디 아라비안 오일 컴퍼니 Hydrotreating of Aromatic-Extracted Hydrocarbon Streams
CN108530256B (en) * 2012-04-19 2021-07-23 沙特阿拉伯石油公司 Combined dealkylation-transalkylation process for maximizing xylene production from heavy reformate
US9102884B2 (en) * 2012-08-31 2015-08-11 Exxonmobil Chemical Patents Inc. Hydroprocessed product
US9162955B2 (en) 2013-11-19 2015-10-20 Uop Llc Process for pyrolysis of a coal feed
US9079816B2 (en) * 2013-11-19 2015-07-14 Uop Llc Process for producing alkylated aromatic compounds
US9067853B2 (en) 2013-11-19 2015-06-30 Uop Llc Process for selectively dealkylating aromatic compounds
US9073811B2 (en) 2013-11-19 2015-07-07 Uop Llc Process for providing aromatics from coal tar
US20150141726A1 (en) * 2013-11-19 2015-05-21 Uop Llc Process for producing olefins from a coal feed
US9061955B2 (en) * 2013-11-19 2015-06-23 Uop Llc Method of converting a coal to chemicals
US9073805B2 (en) 2013-11-19 2015-07-07 Uop Llc Hydrocracking process for a hydrocarbon stream
CN105085154B (en) * 2014-05-14 2017-09-15 中国石油化工股份有限公司 Increase production the method for aroamtic hydrocarbon raw material by heavy aromatics inferior
JP6882169B2 (en) 2014-07-01 2021-06-02 アネロテック・インコーポレイテッドＡｎｅｌｌｏｔｅｃｈ，Ｉｎｃ． Process for converting biomass to BTX with low sulfur, low nitrogen, and low olefin content by catalytic rapid pyrolysis process
CN104447159B (en) * 2014-11-11 2016-09-14 中国海洋石油总公司 A kind of C10+the combined technical method of heavy aromatics lighting
WO2016099787A1 (en) 2014-12-17 2016-06-23 Exxonmobil Chemical Patents Inc. Methods and systems for treating a hydrocarbon feed
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
CN106433774A (en) * 2016-11-30 2017-02-22 黑龙江省能源环境研究院 Method for upgrading and converting wood tar into diesel oil
US10035742B1 (en) * 2017-05-26 2018-07-31 Saudi Arabian Oil Company Process for maximizing xylenes production from heavy aromatics for use therein
US11279888B2 (en) 2020-02-13 2022-03-22 Saudi Arabian Oil Company Process and system for hydrogenation of aromatic complex bottoms
WO2024030742A1 (en) * 2022-08-03 2024-02-08 Eastman Chemical Company Waste plastic pyrolysis vapors and residue as feedstock to fluidized catalytic cracker

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100160699A1 (en) * 2008-12-23 2010-06-24 Frey Stanley Joseph Method for efficient use of hydrogen in aromatics production from heavy aromatics
WO2012053848A2 (en) * 2010-10-22 2012-04-26 Sk Innovation Co., Ltd. The method for producing valuable aromatics and light paraffins from hydrocarbonaceous oils derived from oil, coal or wood
EP2644584A1 (en) * 2010-11-25 2013-10-02 SK Innovation Co., Ltd. Method for producing high-added-value aromatic products and olefinic products from an aromatic-compound-containing oil fraction

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US6900365B2 (en) 1999-11-15 2005-05-31 Chevron Phillips Chemical Company Lp Process for converting heavy hydrocarbon feeds to high octane gasoline, BTX and other valuable aromatics
CN100389100C (en) * 2002-11-29 2008-05-21 中国石油化工股份有限公司 Process for preparing olefin by cracking of kerosene distillate
ES2913654T3 (en) * 2004-03-08 2022-06-03 China Petroleum & Chem Corp FCC procedure with two reaction zones
CN100487080C (en) 2004-03-08 2009-05-13 中国石油化工股份有限公司 Chemical oil-refining method for preparing low carbon olefin and arene
KR101234448B1 (en) 2005-11-14 2013-02-18 에스케이이노베이션 주식회사 Process for The Preparation of Aromatic Hydrocarbons and Liquefied Petroleum Gas from Hydrocarbon Mixture
WO2009111026A2 (en) 2008-03-04 2009-09-11 University Of Massachusetts Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100160699A1 (en) * 2008-12-23 2010-06-24 Frey Stanley Joseph Method for efficient use of hydrogen in aromatics production from heavy aromatics
WO2012053848A2 (en) * 2010-10-22 2012-04-26 Sk Innovation Co., Ltd. The method for producing valuable aromatics and light paraffins from hydrocarbonaceous oils derived from oil, coal or wood
EP2644584A1 (en) * 2010-11-25 2013-10-02 SK Innovation Co., Ltd. Method for producing high-added-value aromatic products and olefinic products from an aromatic-compound-containing oil fraction

Also Published As

Publication number Publication date
CN103108849B (en) 2016-04-06
US8962901B2 (en) 2015-02-24
KR101735108B1 (en) 2017-05-15
EP2616415A2 (en) 2013-07-24
JP5890836B2 (en) 2016-03-22
JP2013537223A (en) 2013-09-30
KR20120029143A (en) 2012-03-26
BR112013006211A2 (en) 2020-08-25
ES2597702T3 (en) 2017-01-20
WO2012036484A3 (en) 2012-05-18
SG188984A1 (en) 2013-06-28
WO2012036484A2 (en) 2012-03-22
CN103108849A (en) 2013-05-15
BR112013006211B1 (en) 2021-05-04
US20130178673A1 (en) 2013-07-11
EP2616415B1 (en) 2016-08-31

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