EP2510283A2 - Burner unit for steel making facilities - Google Patents
Burner unit for steel making facilitiesInfo
- Publication number
- EP2510283A2 EP2510283A2 EP10787770A EP10787770A EP2510283A2 EP 2510283 A2 EP2510283 A2 EP 2510283A2 EP 10787770 A EP10787770 A EP 10787770A EP 10787770 A EP10787770 A EP 10787770A EP 2510283 A2 EP2510283 A2 EP 2510283A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- feed channels
- burner unit
- burner
- fuel
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009628 steelmaking Methods 0.000 title claims abstract description 10
- 239000000446 fuel Substances 0.000 claims abstract description 104
- 238000002485 combustion reaction Methods 0.000 claims abstract description 69
- 230000001172 regenerating effect Effects 0.000 claims abstract description 7
- 239000007789 gas Substances 0.000 claims description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000000571 coke Substances 0.000 claims description 4
- 239000003345 natural gas Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 description 19
- 239000003546 flue gas Substances 0.000 description 11
- 239000011449 brick Substances 0.000 description 5
- 206010037660 Pyrexia Diseases 0.000 description 4
- 239000011819 refractory material Substances 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/20—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone
- F23D14/22—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/03005—Burners with an internal combustion chamber, e.g. for obtaining an increased heat release, a high speed jet flame or being used for starting the combustion
Definitions
- the present invention relates to a burner unit for steel making facilities. More particularly, the present invention relates to an external burner unit of a regenerative or recuperative heat generator.
- the regenerative heat generator may e.g. be a hot blast stove of a blast furnace.
- Such stoves generally comprise a combustion chamber and a heat-retention shaft.
- the combustion chamber and the heat- retention shaft are separated from one another by a wall constructed from refractory bricks.
- a burner unit is generally located in a bottom section of the combustion chamber.
- Combustion air and combustible fuel generally combustible gases, are supplied to the burner unit and a mixture of the combustion air and fuel is burned in the combustion chamber of the stove.
- the flue gases emanating from the combustion rise upwards in the combustion chamber, are diverted via a dome and then pass through the heat-retention shaft filled with checker bricks. Heat from the flue gases is absorbed by the checker bricks.
- the flue gasses which have now cooled down escape the stove via an exhaust gas chamber and at least one discharge port.
- the supply of combustion air and fuel is discontinued and air is blown through the stove in the opposite direction.
- the air is heated as it passes through the heat- retention shaft containing the hot checker bricks, diverted via a dome into the combustion chamber, where it leaves the stove via a hot blast outlet in the shell of the stove to be fed to the blast furnace.
- the burner unit comprises a ceramic burner arranged within the stove, i.e. in the bottom section of its combustion chamber. It is also possible to provide external burner units, which are installed outside the shell of the stove. One or more such external burner units may be used instead of an internal ceramic burner. Alternatively, such external burner units may be used as additional heaters if used in conjunction with an internal ceramic burner.
- the object of the present invention is to provide an improved burner unit for steel making facilities, in particular in connection with regenerative or recuperative heat generators. This object is achieved by a burner unit as claimed in claim 1 .
- the present invention proposes a burner unit for steel making facilities, in particular for use in connection with a regenerative or recuperative heat generator, wherein the burner unit comprises a mixing zone, a plurality of fuel feed channels for feeding combustible fuel to the mixing zone; and a plurality of air feed channels for feeding combustion air to the mixing zone.
- the burner unit comprises a primary burner with an annular feed arrangement comprising circumferentially alternating fuel feed channels and air feed channels; a central channel through the annular feed arrangement and a secondary burner arranged in the central channel of the burner unit, the central channel being coaxial with the annular feed arrangement.
- the primary burner may be considered as main burner, dimensioned to generally work like a conventional burner.
- the secondary burner may be considered as auxiliary burner for carrying out additional tasks, such as e.g. heating up the burner unit before the primary burner is switched on or aiding the combustion of the primary burner.
- the secondary burner can be used as post combustion burner for using up any excess combustible fuel or combustion air from the primary burner, thereby altering the composition of the flue gasses exiting the burner unit.
- the secondary burner can be used as post combustion burner for using up any excess combustible fuel or combustion air from the primary burner, thereby altering the composition of the flue gasses exiting the burner unit.
- only one type of combustible fuel and one type of combustion air can be used at any one time, regulation of the flue gases composition may be difficult.
- a mixing of different types of combustible fuel or combustion air may be carried out before feeding it to the burner unit.
- the present invention allows, through the use of the secondary burner, to mix different types of combustible fuel or combustion air within the burner unit; i.e. two different types of combustible fuel or combustion air may be fed to the mixing zone, thereby altering the burning conditions and the flue gas temperature and/or composition.
- the burner unit according to the present invention is therefore much more flexible, where operation modes are concerned, than conventional burner units.
- the burner unit may also be used to directly supply fumes of a particular composition to the steel making facility to which it is connected.
- air feed channels may also be referred to as oxygen feed channels. Indeed, instead of combustion air, oxygen O2 may be fed through the air feed channels to the mixing zone.
- the burner unit further comprises auxiliary feed channels for feeding combustible fuel or combustion air to the mixing zone, the auxiliary feed channels having a cross-section smaller than a cross-section of the fuel feed channels or air feed channels.
- the auxiliary feed channels comprise auxiliary fuel feed channels for feeding combustible fuel to the mixing zone, the auxiliary fuel feed channels having a cross-section smaller than a cross-section of the fuel feed channels of the primary burner.
- the auxiliary feed channels may also further comprise auxiliary air feed channels for feeding combustion air to the mixing zone, the auxiliary air feed channels having a cross-section smaller than a cross-section of the air feed channels of the primary burner.
- Both the auxiliary fuel feed channels and the auxiliary air feed channels are thus preferably low flow rate channels whereas the fuel feed channels and the air feed channels are preferably high flow rate channels.
- the auxiliary feed channels allow feeding additional combustible fuel and/or combustion air to the mixing zone, thereby altering the combustion conditions of the primary burner.
- the additional combustible fuel or combustion air may be of the same type than that fed through the main fuel and air feed channels, thereby adjusting the burning combustion conditions of the primary burner.
- the additional combustible fuel or combustion air is of a different type than that fed through the main fuel and air feed channels, thereby also altering the composition of the flue gasses.
- the additional combustible fuel or combustion air may also provide the primary burner with a non-stoichiometric mixture, whereby the primary burner only achieves a partial combustion of the mixture. The secondary burner may then be used to complete the combustion of the mixture.
- the auxiliary feed channels thus contribute to the flexibility of the burner unit.
- the combustible fuel fed through the fuel feed channels may be blast furnace gas and/or the combustion air fed through the air feed channels may be air or low calorific gas.
- the combustible fuel fed through the auxiliary fuel feed channels may be high calorific gas, such as natural gas or coke oven gas and/or the combustion air fed through the auxiliary air feed channels may be oxygen.
- the secondary burner preferably comprises air and fuel feed lines, thereby allowing the secondary burner to be used independently from the primary burner. It should be noted however that it is not excluded to provide the secondary burner with only one of the air and fuel feed lines. Indeed, the secondary burner may be used as post combustion burner, receiving air or fuel from the flue gasses from the primary burner.
- the secondary burner may be of any appropriate type, depending on the fuel to be used. Such fuel may be chosen from the non-exhaustive list comprising oil, coke oven gas, blast furnace gas or natural gas.
- the auxiliary fuel feed channels and/or the auxiliary air feed channels pass through a circumferential wall of the burner unit.
- Annular feed chambers may be arranged around an exterior wall of the burner unit, the annular feed chambers being arranged for feeding combustible fuel or combustion air to the auxiliary fuel feed channels and the auxiliary air feed channels.
- the auxiliary fuel feed channels and/or the auxiliary air feed channels pass through a rear wall of the burner unit, the auxiliary fuel feed channels and/or the auxiliary air feed channels being arranged parallel to the axis of the burner unit.
- the auxiliary fuel feed channels and/or the auxiliary air feed channels may be arranged between the annular feed arrangement of the primary burner and the secondary burner.
- the auxiliary fuel feed channels and/or the auxiliary air feed channels may be arranged within the annular feed arrangement of the primary burner.
- the annular feed arrangement is preferably formed by an annular channel comprising a plurality of inner channels therein, the inner channels dividing the annular channel into the circumferentially alternating fuel feed channels and air feed channels, wherein the annular channel is connected for conveying one of the combustible fuel or the combustion air and the inner channels are used for conveying the other one of the combustible fuel or the combustion air.
- the air feed channels and fuel feed channels are preferably parallel to the central axis if the burner unit. Other configurations should however not be excluded.
- the air and fuel feed channels may e.g. be twisted around the central axis, which may provide a swirling of the combustible fuel and the combustion air when entering the mixing zone. Although generally not desired, in some instances such a swirl may be advantageous. It should be noted that other means for achieving a swirl may also be used.
- the burner unit may also be used in connection with other steel making facilities, such as e.g. pulverised coal injection (PCI) installations or direct recuperative heat exchangers.
- PCI pulverised coal injection
- Fig .1 is a cut through a burner unit according to a first embodiment of the present invention
- Fig.2 is a partial section view across the burner unit along line A-A of Fig .1 ;
- Fig.3 is a cut through a burner unit according to a second embodiment of the present invention.
- Fig.4 is a partial section view across the burner unit along line B-B of Fig.3.
- Fig.1 shows a cut through a burner unit 10 according to a first embodiment of the present invention.
- the burner unit 10 comprises a front section 12 with a combustion chamber 14 and a rear section 16 with feed lines for feeding combustible fuel and combustion air to a mixing zone 18 of the combustion chamber 14.
- the front section 12 comprises an opening 20 for feeding flue gases from the burner unit 10 to a steel making facility such as e.g. a hot blast stove (not shown).
- the burner unit 10 is connected to the hot blast stove via a connection flange 22.
- refractory material 24 is applied against the inner surface 26 of the circumferential wall 28 to protect the latter from the heat generated in the combustion chamber 14.
- the rear section 16 which comprises the feed lines, is more easily described by referring to both Fig.1 and Fig.2, the latter being a partial section view along line A-A of Fig .1 .
- the rear section 16 comprises an annular feed arrangement 30 alternately comprising fuel feed channels 32 and air feed channels 34.
- the fuel and air feed channels 32, 34 are arranged circumferentially, in alternating manner, preferably in regular sectors.
- the fuel feed channels 32 and air feed channels 34 respectively lead combustible fuel and combustion air from a fuel inlet 36 and an air inlet 38 to the mixing zone 18 of the combustion chamber 14. In the mixing zone 18 the combustible fuel and combustion air meet and the mixture thereof is ignited to form a first combustion, represented by flames 40.
- the annular feed arrangement 30 with its fuel and air feed channels 32, 34 forms a primary burner 42 of the burner unit 10.
- the annular feed arrangement 30 surrounds a central channel 44, which is configured so as to receive a secondary burner 46 therein.
- the annular feed arrangement 30 and central channel 44 are coaxial with a central axis 47 of the burner unit 10.
- the central channel 44 is lined with refractory material 48.
- the secondary burner 46 feeds combustible fuel and combustion air to the mixing zone 18, where a mixture thereof ignites to form a second combustion, represented by flame 50.
- the secondary burner 46 is inserted into the burner unit 10 though a socket 52 in a rear wall 54 of the burner unit 10.
- the construction of the annular feed arrangement 30 of the primary burner 42 can be more closely described by referring to Fig.2.
- the annular feed arrangement 30 is formed by two coaxial pipes - an outer pipe 56 and an inner pipe 58 - between which an annular channel 60 is formed.
- a plurality of inner channels 61 are formed by inserting pipe-like elements 62 connected to the inner pipe 58.
- the pipe-like elements 62 form a gas tight separation wall between the inner channels 61 and the annular channel 60, thereby forming the fuel feed channels 32 and air feed channels 34.
- Auxiliary fuel feed channels 64 and auxiliary air feed channels 66 may be provided for feeding further combustible fuel and further combustion air to the mixing zone 18.
- Fig.1 shows both the auxiliary fuel feed channels 64 and the auxiliary air feed channels 66, it should be noted that it is also possible to provide the burner unit 10 with only one of these auxiliary feed channels 64, 66.
- the auxiliary fuel feed channels 64 are arranged so as to feed further combustible fuel from an annular fuel feed chamber 68 connected to a fuel inlet 70 through the circumferential wall 28 of the burner unit 10 into the mixing zone 18.
- the auxiliary air feed channels 66 are arranged so as to feed further combustion air from an annular air feed chamber 72 connected to an air inlet 74 through the circumferential wall 28 of the burner unit 10 into the mixing zone 18.
- the auxiliary fuel and air feed channels 64, 66 are low flow rate channels arranged so as to deliver high calorific gas, such as natural gas or coke oven gas or oxygen to the mixing zone 18, thereby altering the combustion conditions of the primary burner 42.
- the further fuel and/or air fed to the mixing zone 18 may be in quantities such that the mixture in the mixing zone 18 is non- stoichiometric, thereby only achieving a partial combustion with the primary burner 42. Further combustion of the flue gases from the first combustion may then be achieved with the aid of the secondary burner 46.
- Figs 3 and 4 show a burner unit 10 according to a second embodiment of the invention, wherein Fig.4 is a partial section view along line B-B of Fig.3.
- This burner unit is very similar to the one shown in Figs 1 and 2 and will therefore not be described herein in detail. Same reference numerals refer to identical features in both embodiments.
- the burner unit of Fig. 2 and 3 differs from the first embodiment in the location of the auxiliary feed channels.
- An auxiliary air feed channel 76 is arranged between the fuel feed channels 32 and air feed channels 34 of the annular feed arrangement 30 and the refractory material 48 of the central channel 44. At one end, the auxiliary air feed channel 76 is connected to an air inlet 78 arranged in the rear wall 54 of the burner unit 10; at the opposite end, the auxiliary air feed channel 76 comprises a port 80 opening into the mixing zone 18 of the burner unit 10.
- Fig.2 shows an auxiliary air feed channel 76 only, it should be noted that it is also possible to provide the burner unit 10 with an auxiliary fuel feed channel in a similar manner.
- combustible fuel and combustion air are generally fed through the fuel feed channels 32 and air feed channels 34, so as to form a combustible mixture in the mixing zone 18.
- the flue gases from the combustion of this combustible mixture by the primary burner 42 is then fed through the opening 20 into the hot blast stove.
- the auxiliary fuel and air feed channels 64, 66 allow the introduction of additional combustible fuel and combustion air into the mixing zone 18, thereby creating a combustible mixture potentially comprising two distinctive types of combustible fuel and two distinctive types of combustion air.
- the flue gas composition can therefore be altered without having to resort to a potentially dangerous mixture upstream of the burner unit 10.
- the secondary burner not only allows burning any excess component in the flue gases from the primary burner, it also allows heating up the burner unit and any downstream equipment before the primary burner is switched on.
- the expressions "high flow rate” and “low flow rate” of the fuel and air feed channels and auxiliary fuel and air feed channels are relative to each other.
- the flow rate or section size of the feed channels will strongly depend on the combustion media used.
- the high flow rate, fuel and air feed channels 32, 34 may have a section in the region of 1500 cm 2 ; and the low flow rate, auxiliary fuel and air feed channels 64, 66 may have a section in the region of 200 cm 2 .
- Table 1 A non-exhaustive list of examples for operation modes of the burner unit according to the present invention is shown in Table 1 .
- connection flange 61 inner channels
- annular feed arrangement 68 annular fuel feed chamber
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion Of Fluid Fuel (AREA)
- Gas Burners (AREA)
- Pre-Mixing And Non-Premixing Gas Burner (AREA)
- Air Supply (AREA)
Abstract
Description
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10787770.6A EP2510283B1 (en) | 2009-12-08 | 2010-12-08 | Burner unit for steel making facilities |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09178385A EP2333412A1 (en) | 2009-12-08 | 2009-12-08 | Burner unit for steel making facilities |
| PCT/EP2010/069177 WO2011070070A2 (en) | 2009-12-08 | 2010-12-08 | Burner unit for steel making facilities |
| EP10787770.6A EP2510283B1 (en) | 2009-12-08 | 2010-12-08 | Burner unit for steel making facilities |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2510283A2 true EP2510283A2 (en) | 2012-10-17 |
| EP2510283B1 EP2510283B1 (en) | 2013-07-03 |
Family
ID=41563196
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09178385A Withdrawn EP2333412A1 (en) | 2009-12-08 | 2009-12-08 | Burner unit for steel making facilities |
| EP10787770.6A Active EP2510283B1 (en) | 2009-12-08 | 2010-12-08 | Burner unit for steel making facilities |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09178385A Withdrawn EP2333412A1 (en) | 2009-12-08 | 2009-12-08 | Burner unit for steel making facilities |
Country Status (11)
| Country | Link |
|---|---|
| EP (2) | EP2333412A1 (en) |
| JP (1) | JP5636435B2 (en) |
| KR (1) | KR101732396B1 (en) |
| CN (1) | CN102713436B (en) |
| AU (1) | AU2010329886B2 (en) |
| BR (1) | BR112012013643B1 (en) |
| CA (1) | CA2782763A1 (en) |
| DE (1) | DE09178385T1 (en) |
| IN (1) | IN2012DN04997A (en) |
| RU (1) | RU2533269C2 (en) |
| WO (1) | WO2011070070A2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408919A (en) * | 2011-10-11 | 2012-04-11 | 北京航天动力研究所 | Combustion nozzle combination device of multi-channel coal water slurry gasification furnace |
| CN103044036B (en) * | 2013-01-07 | 2014-09-24 | 中钢集团洛阳耐火材料研究院有限公司 | Sintering method of self-combination silicon-carbide refractories |
| JP6073270B2 (en) * | 2014-09-18 | 2017-02-01 | ボルカノ株式会社 | Combustion device, boiler, and combustion method |
| JP6054349B2 (en) * | 2014-09-03 | 2016-12-27 | ボルカノ株式会社 | Combustion device, boiler, and combustion method |
| US10520221B2 (en) | 2015-04-06 | 2019-12-31 | Carrier Corporation | Refractory for heating system |
| CN110291352B (en) * | 2017-02-13 | 2023-11-17 | 布卢姆工程公司 | Dual-mode electric storage burner system and method of heating a furnace using a dual-mode electric storage burner system |
| WO2018195789A1 (en) * | 2017-04-26 | 2018-11-01 | Linde Aktiengesellschaft | Method and burner for heating a furnace for metal processing |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2942655A (en) * | 1955-04-27 | 1960-06-28 | Fisher Scientific Co | Gas burner |
| GB957110A (en) * | 1961-11-22 | 1964-05-06 | British Oxygen Co Ltd | Process and jet for the treatment of metal |
| DE2215347C2 (en) * | 1972-03-29 | 1982-06-16 | Krupp-Koppers Gmbh, 4300 Essen | Ceramic burner for blast furnace wind heaters |
| SU964348A1 (en) * | 1981-01-05 | 1982-10-07 | Всесоюзный Научно-Исследовательский И Проектный Институт Вторичной Цветной Металлургии | Burner |
| US4403947A (en) * | 1981-08-12 | 1983-09-13 | Eclipse, Inc. | Gas mixing burner |
| SU1467322A1 (en) * | 1987-03-23 | 1989-03-23 | Предприятие П/Я Р-6603 | Burner device |
| US5454712A (en) * | 1993-09-15 | 1995-10-03 | The Boc Group, Inc. | Air-oxy-fuel burner method and apparatus |
| US5714113A (en) * | 1994-08-29 | 1998-02-03 | American Combustion, Inc. | Apparatus for electric steelmaking |
| KR100659678B1 (en) * | 1999-08-17 | 2006-12-21 | 닛폰화네스코교 가부시기가이샤 | Combustion method and burner |
| JP4068041B2 (en) * | 2002-10-22 | 2008-03-26 | 日本碍子株式会社 | Low NOx burner |
| JP2005226850A (en) * | 2004-02-10 | 2005-08-25 | Ebara Corp | Combustion device |
| FR2892498B1 (en) * | 2005-10-21 | 2007-12-28 | Lafarge Sa | BURNER FOR OVEN AT CLINKER |
| US7810333B2 (en) * | 2006-10-02 | 2010-10-12 | General Electric Company | Method and apparatus for operating a turbine engine |
-
2009
- 2009-12-08 EP EP09178385A patent/EP2333412A1/en not_active Withdrawn
- 2009-12-08 DE DE9178385T patent/DE09178385T1/en active Pending
-
2010
- 2010-12-08 CA CA2782763A patent/CA2782763A1/en not_active Abandoned
- 2010-12-08 RU RU2012128355/06A patent/RU2533269C2/en active
- 2010-12-08 CN CN201080055601.2A patent/CN102713436B/en active Active
- 2010-12-08 KR KR1020127017672A patent/KR101732396B1/en active Active
- 2010-12-08 EP EP10787770.6A patent/EP2510283B1/en active Active
- 2010-12-08 AU AU2010329886A patent/AU2010329886B2/en not_active Expired - Fee Related
- 2010-12-08 IN IN4997DEN2012 patent/IN2012DN04997A/en unknown
- 2010-12-08 BR BR112012013643-7A patent/BR112012013643B1/en active IP Right Grant
- 2010-12-08 JP JP2012542538A patent/JP5636435B2/en active Active
- 2010-12-08 WO PCT/EP2010/069177 patent/WO2011070070A2/en not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2011070070A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101732396B1 (en) | 2017-05-24 |
| AU2010329886B2 (en) | 2014-09-18 |
| AU2010329886A1 (en) | 2012-06-21 |
| EP2510283B1 (en) | 2013-07-03 |
| CA2782763A1 (en) | 2011-06-16 |
| EP2333412A1 (en) | 2011-06-15 |
| RU2533269C2 (en) | 2014-11-20 |
| JP2013513084A (en) | 2013-04-18 |
| BR112012013643A2 (en) | 2020-08-25 |
| RU2012128355A (en) | 2014-01-20 |
| DE09178385T1 (en) | 2011-12-01 |
| IN2012DN04997A (en) | 2015-10-02 |
| KR20120101531A (en) | 2012-09-13 |
| WO2011070070A2 (en) | 2011-06-16 |
| JP5636435B2 (en) | 2014-12-03 |
| BR112012013643B1 (en) | 2021-08-17 |
| CN102713436A (en) | 2012-10-03 |
| WO2011070070A3 (en) | 2011-08-11 |
| CN102713436B (en) | 2014-11-12 |
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