EP2491407A1 - Alignment and anti-drift mechanism - Google Patents
Alignment and anti-drift mechanismInfo
- Publication number
- EP2491407A1 EP2491407A1 EP09850676A EP09850676A EP2491407A1 EP 2491407 A1 EP2491407 A1 EP 2491407A1 EP 09850676 A EP09850676 A EP 09850676A EP 09850676 A EP09850676 A EP 09850676A EP 2491407 A1 EP2491407 A1 EP 2491407A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- displacement sensor
- actuator
- move
- target object
- change
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01Q—SCANNING-PROBE TECHNIQUES OR APPARATUS; APPLICATIONS OF SCANNING-PROBE TECHNIQUES, e.g. SCANNING PROBE MICROSCOPY [SPM]
- G01Q10/00—Scanning or positioning arrangements, i.e. arrangements for actively controlling the movement or position of the probe
- G01Q10/04—Fine scanning or positioning
- G01Q10/06—Circuits or algorithms therefor
- G01Q10/065—Feedback mechanisms, i.e. wherein the signal for driving the probe is modified by a signal coming from the probe itself
Definitions
- This invention relates to an alignment and anti-drift mechanism.
- beam deflection, astigmatic detection, and capacitance measurement are commonly used for micrometer scale and nanometer scale measurements of the position and orientation of a target object.
- These precision displacement measurement systems are sensitive to environmental changes, such as changes in temperature or humidity or changes to internal components of the system.
- beam deflection and astigmatic detection use optical measurement schemes involving a light source (e.g., a laser), lenses, and a photosensor.
- a change in ambient temperature or humidity may cause a change in the wavelength emitted by the light source.
- Thermal gradients caused by heat sources (such as the light source) within the displacement system and/or stress relaxation in components of the system can affect the separation between different components inside the displacement system, resulting in drift of the detection signals.
- a change in ambient temperature or humidity affects signals in the electronic circuits, such as circuitry in a displacement sensor of the system. Furthermore, the heat capacity of the instrument can cause a time delay of temperature-related drift. In general, the more components there are in a displacement measurement system, the more susceptible the system becomes to both internal and external environmental changes.
- Thermal expansion is a main factor influencing signal drift. Even if a displacement sensor is fixed by firm mechanical attachment, the detected displacement signal representative of the spacing between the sensor and a target object may still drift with time due to a slow change in the spacing.
- aluminum is widely used in manufacturing the frame of many instruments because it is relatively inexpensive and easy to machine. Aluminum has a thermal expansion coefficient of 22.2 x 10 ⁇ 6 m-K "1 . This means that if two components are fixed on an aluminum frame separated by a distance of 10 mm, a one degree increase in temperature will cause a 222 nm increase in spacing between the two components as a result of thermal expansion of the frame. Under the same conditions but using steel instead of aluminum for the frame, the increase in spacing would be 130 nm.
- each component in a precision displacement measurement system may have a different thermal expansion rate, and thus it is not always straightforward to predict the magnitude and the direction of drift in a displacement measurement.
- thermal drift of hundreds of nanometers seriously degrades the measurement precision and accuracy.
- an astigmatic detection system measures translational displacement of a sample along one axis and angular displacement of the sample around two axes.
- the ADS includes an optical path mechanism in which a laser beam is focused on the surface of an object by a lens assembly. Light reflected from the object surface passes back through the lens assembly and forms a light spot on a photo sensor. The shape and position of the light spot on the photo sensor are used to determine translational and angular displacements of the object.
- the ADS is capable of detecting displacements of the object when the object surface is near the focal point of the detection light beam and/or within the linear region of the focus error signal of the ADS.
- the typical linear range of the focus error signal is about 6-8 ⁇ .
- a fine linear translation stage may be used. However, even with a fine adjustment stage, signal drift problems still arise and can cause the object surface to drift out of the detection region of the ADS displacement sensor.
- a system in a general aspect, includes a displacement sensor, an actuator connected to the displacement sensor, and a feedback unit.
- the displacement sensor is configured to measure at least one of a relative position and a relative orientation between the displacement sensor and the target object.
- the feedback unit receives a signal from the displacement sensor related to the measured relative position or relative orientation and controls the actuator to move the displacement sensor on the basis of variations in the received signal arising due to a change in environmental conditions.
- Embodiments may include one or more of the following.
- the change in environmental conditions includes at least one of a change in temperature or a change in humidity.
- the change in environmental conditions includes a local change in temperature.
- the variations in the received signal further arise from a relaxation of mechanical stress in the system.
- the feedback unit controls the actuator on the basis of low frequency variations in the received signal.
- the frequency of the low frequency variations is less than about 1 Hz, or between about 1 ⁇ and 100 mHz.
- the displacement sensor includes a photo detector and an objective lens positioned between the target object and the photo detector.
- the feedback unit includes an integrator, an amplifier, and a noise minimization unit.
- the relative position includes a vertical or a lateral separation between the displacement sensor and the target object.
- the actuator is connected to the objective lens and the feedback unit controls the actuator to move the objective lens.
- the actuator includes a stack of piezoelectric ceramics or a voice coil motor.
- the actuator includes a damping material. The damping material is selected to reduce at least one of a resonance amplitude and a quality factor of the actuator, or to change a resonance frequency of the actuator.
- a method in another aspect, includes measuring at least one of a relative position and a relative orientation between a displacement sensor and a target object; receiving, at a feedback unit, a signal related to the measured relative position or relative orientation; and, on the basis of variations in the received signal arising due to a change in environmental conditions, controlling an actuator to move the displacement sensor.
- Embodiments may include one or more of the following.
- the method further includes setting a set point of the feedback unit. Controlling the actuator to move the displacement sensor comprises maintaining the received signal within a preselected range of the set point.
- the method further includes setting at least one of a driving speed and a driving bandwidth of the feedback unit. At least one of the driving speed and the driving bandwidth is varied on the basis of a deviation between the received signal and the set point of the feedback unit.
- An alignment and anti-drift mechanism as described herein has a number of advantages. Slowly varying signal drift in a precision displacement measurement system is markedly reduced, and alignment of the relative position and orientation between a target object and a displacement sensor in such a measurement system is maintained for as long as a day. This stability enables high resolution measurement of microscale and nanoscale features, such as structures in micro/nano electromechanical systems (MEMS/NEMS) devices, and of mechanical dynamics of microfabricated elements. Furthermore, vibrational noise in the system is reduced, thus allowing high resolution displacement measurements to be performed with a non-rigid actuator such as that used in CD and DVD optical heads.
- MEMS/NEMS micro/nano electromechanical systems
- Fig. 1 is a plot of the time variation of a signal output from a displacement sensor.
- Fig. 2 is a plot of temperature variation with time for an air conditioned system.
- Fig. 3 is a schematic diagram of an alignment and anti-drift system.
- Fig. 4 A is a plot of typical ambient temperature variations.
- Fig. 4B is a plot showing the effect of compensation from an alignment and anti-drift system in the environment characterized by Fig. 4A.
- Fig. 5 is a block diagram of the feedback control driver of an alignment and anti-drift system.
- Fig. 6 is a schematic diagram of an astigmatic detection system (ADS) employing an alignment and anti-drift system.
- ADS astigmatic detection system
- Fig. 7A is a block diagram of an ADS employing an alignment and anti-drift mechanism.
- Fig. 7B is a block diagram of an alignment and anti-drift system with a damped actuator.
- Fig. 8 is a frequency domain plot of a noise spectrum of an actuator.
- Fig. 9 is a plot of signal drift in various astigmatic detection systems.
- Fig. 10 is a schematic diagram of a laser hologram unit employing an alignment and anti-drift system.
- an output signal 100 in a displacement measurement system drifts quickly when the system is first turned on (region 102) and then stabilizes (region 104) within a few seconds to a few minutes, depending on the system.
- output signal 100 continues to drift slowly during the operation of the displacement measurement system.
- a large part of the signal drift is due to fluctuations in ambient temperature; if the displacement measurement system is operated with no environmental control and without any compensation for drift, the output signal drifts in a manner roughly proportional to the temperature change of the system.
- the signal may drift in a positive direction, as shown, or in a negative direction, depending on the thermal expansion characteristics of the materials in the displacement measurement system and on the presence or absence of a relaxation of mechanical stresses in the system.
- the drift rate of the output signal due to relaxation of mechanical stresses in components of the displacement measurement system or to changes in electronic characteristics of a displacement sensor is of a similar order of magnitude.
- displacement signals related to the mechanical movement of an object have a frequency on the order of 100 mHz or higher, much faster than the drift rate. It is therefore possible to compensate for the slowly-varying drift of the displacement signal while still measuring the fast- varying displacement signal and other related signals derived therefrom.
- an alignment and anti-drift system 300 for use in a displacement measurement system aligns the relative position and/or orientation between a displacement sensor 302 and a top surface 304 of an object 306.
- Anti-drift system 300 also compensates for the drift of an output signal from displacement sensor 302.
- Anti-drift system 300 includes a low-speed feedback control driver 308, an actuator 310, and displacement sensor 302.
- Displacement sensor 302 may be any displacement sensor compatible with a precision displacement measurement system, such as a focus sensor or an astigmatic detection sensor.
- the relative position or relative orientation between displacement sensor 302 and the top surface of object 306 is measured by displacement sensor 302, which generates an output signal that is sent to feedback control driver 308.
- feedback control driver 308 drives actuator 310 to adjust or maintain the relative position or relative orientation between displacement sensor 302 and the top surface of object 306. For instance, to minimize or eliminate signal drift, actuator 310 is controlled such that a constant time-averaged displacement signal from displacement sensor 302 is maintained.
- anti-drift system 300 maintains the output signal of displacement sensor 302 in a region of displacement sensor 302 that has linear or quasi-linear response characteristics in order to minimize measurement uncertainty and to maximize the sensitivity of the displacement sensor.
- the focus error signal versus the translational displacement of the object surface exhibits a linear detection region in which the measured displacement signal has a high sensitivity to the displacement of the object. Referring to Figs.
- an exemplary displacement measurement system is located in a room with a temperature variation shown in curve 400. Without compensation for drift associated with the temperature variation, the output signal of displacement sensor 302 has significant variability, as shown in curve 402.
- anti-drift mechanism 300 is included with the displacement measurement system, the distance between the displacement sensor 302 and the object 306 being measured is maintained, assuming there is no mechanical vibration of the object. As a result, the output signal of displacement sensor 302 is much more stable, as shown in curve 404.
- the output signal from displacement sensor 302 can be separated into two components: a high-frequency component and a low- frequency component.
- the high-frequency (i.e., fast- varying) component contains information about the mechanical movement of object 306 and is used for measurement purposes.
- the low-frequency (i.e., slowly-varying) component is related to signal drift and is used as the input signal of feedback control driver 308.
- low-speed feedback control driver 308 includes an integrator 502, an amplifier 504, and a noise reduction unit 506.
- Noise reduction unit 506 includes a low pass filter, a passive voltage divider, or another noise reduction component for the optimization of the signal-to-noise ratio of the electronics of the feedback control driver.
- a low pass filter and a passive voltage divider are both used simultaneously to minimize noise in the feedback control driver 308.
- the low pass filter is formed of low noise components such as metal film resistors and foil capacitors and is located between feedback control driver 308 and actuator 310.
- the passive voltage divider is formed of low noise metal film resistors.
- Feedback control driver 308 may be an analog-controller based circuit, a digital signal processing (DSP)-based system, or any other digital board or platform containing a software based controller or other controller that is combined with a suitable actuator driver.
- DSP digital signal processing
- the relative position and orientation between displacement sensor 302 and the top surface of object 306 are adjusted by selecting a set point of feedback control driver 308.
- the driving speed and/or driving bandwidth of the feedback control driver 308 are set to achieve desired measurement conditions and are generally fixed throughout an entire displacement measurement. A low driving speed or driving bandwidth reduces noise in the measured displacement signal. However, the response of feedback control driver 308 is slower under these conditions, which slows tracking or and initial alignment of displacement sensor 302 to a desired position or orientation relative to object 306.
- the driving speed and driving bandwidth of feedback control driver 308 are adjustable according to an algorithm. For instance, the driving speed or driving bandwidth is controlled to vary with the deviation between the detected displacement signal and the set point. When the deviation is large, such as at start-up of a measurement, a high driving speed or driving bandwidth is used to allow for rapid initial alignment; when the deviation is small, a lower driving speed or bandwidth is used.
- Actuator 310 is driven by feedback control driver 308 at a speed slower than the displacement speed due to mechanical movement of object 306 but faster than the drift rate of the signal from displacement sensor 302. Actuator 310 is typically driven at a speed less than about 100 mHz, or between 1 ⁇ - 100 mHz. In situations in which the object to be measured vibrates or undergoes displacement at a speed greater than 100 mHz or 100 nm/second, which is faster than the speed of compensation, the anti-drift mechanism only negligibly affects the measurement results of the displacement sensor.
- actuator 310 is a rigid structure such as a stack of piezoelectric ceramics. Because a rigid actuator can respond quickly to feedback control, the driving bandwidth of feedback control unit 308 can be relatively fast to compensate for the signal drift.
- actuator 310 is a non-rigid structure such as a voice coil motor used in a typical DVD optical head. The stiffness and mass of the voice coil motor are such that a mechanical resonator is formed into which environmental vibrations are readily coupled, affecting or contaminating the displacement signals.
- the driving bandwidth of feedback control driver 308 is preferably relatively low, although still faster than the thermal drift rate.
- the vibrations of actuator 310 are further damped by adding a damping material or by other damping methods such as eddy current damping or magnetic fluids, as discussed in greater detail below.
- an alignment and anti-drift mechanism is incorporated into an astigmatic detection system (ADS) 3 used for the measurement of the height, angle, and variations thereof of the surface of an object 4.
- a light source 31 such as a laser diode, emits a light beam 604, which is reflected by a beam splitter 32 through a collimator 33 and to an objective lens 34.
- Objective lens 34 focuses the light beam into a focused detection light spot on the surface of object 4.
- Light reflected from object 4 passes through objective lens 34, collimator 33, and beam splitter 32, and is focused on a position sensitive detector (PSD) assembly 35.
- PSD position sensitive detector
- PSD assembly 35 is composed of four quadrants 35a, 35b, 35c, and 35d housing photo sensors that output measurement signals SA, S B , SC, and S D , respectively. Translational and angular displacements of object 4 are determined based on the shape and position of the light spot focused on PSD assembly 35.
- the algorithms for processing measurement signals SA, S B , SC, and S D to obtain the displacement of object 4 are described in U.S. Patent No. 7,247,827, the contents of which are incorporated herein by reference.
- objective lens 34 is fixed on an actuator 602, such as a voice coil motor, which moves along the direction of the impinging detection light beam 604 (i.e., the Z direction), thus changing the vertical position of the focal point of objective lens 34.
- actuator 602 such as a voice coil motor
- ADS 3 and object 4 are fixed by a firm mechanical attachment, such as a metal frame 5.
- a feedback control driver 608, which receives processed displacement signals from PSD assembly 35 in ADS 3, controls the Z-axis motion of actuator 602, and thus controls the focus of objective lens 34, in order to maintain the processed displacement signals from PSD assembly 35 at fixed operational points (i.e., free of drift).
- the alignment and anti-drift mechanism maintains the focus error signal within a region of PSD assembly 35 having a maximum sensitivity to linear displacement and/or a region having a locally constant gradient. That is, the height of the surface of object 4 is kept near the focus position of the detection light beam.
- actuator 602 also provides motion along the X-axis and the Y-axis for multi-axis linear alignment of the detection light beam on different positions of the surface of object 4.
- actuator 602 of ADS 3 is not sufficiently rigid, external vibrations will induce unwanted movements between ADS 3 and the surface of object 4.
- the working speed of actuator 602 can be adjusted by choosing an appropriate damping material and applying the damping material to the actuator in an appropriate quantity. Applying a high- viscosity damping material reduces the sensitivity of the system to external vibrations, but also lowers the working bandwidth or working speed of the actuator.
- damping material is chosen to maintain a working bandwidth or working speed higher than the change rate of the ambient conditions in order to retain the ability to compensate for signal drift.
- noise spectra for the detected focus error signal of ADS 3 are shown for an actuator without damping material (curve 802) and an actuator with damping material (curve 804).
- the actuator is a voice coil motor.
- the damping material is a cream-like oil having a kinematic viscosity at 20 °C (68 °F) of between 0.1 - 100 mm 2 /s, such as the commercially available products DC-976 Dow Corning high vacuum grease or Krytox® GPL 223 Anti-Corrosion Perfluorinated Polyether Grease manufactured by DuPont.
- the damping material reduces the resonance amplitude and the quality factor of actuator 602, thus changing the resonance frequency of the actuator.
- the measured focus error signal is compared for a DVD optical head based ADS operated with various control mechanisms.
- a voice coil motor actuator is free, with no feedback control and no damping material.
- the focus error signal drifts at about 4 nm/second; higher- frequency fluctuations induced by external vibrations are also evident in the signal.
- the voice coil motor is fixed on the ADS with glue but no feedback control is used. In this case, the high-frequency vibrational fluctuations are greatly reduced due to the rigidity of the structure. Nevertheless, the focus error signal still drifts at a rate of about 0.25 nm/second.
- the ADS is modified with an alignment and anti-drift mechanism such as that shown in Fig. 7B. That is, damping material is added to the actuator and a low-speed feedback control driver is employed to control the actuator.
- the focus error signal of the ADS is very close to zero and does not drift during the measurement. Indeed, good alignment of the detection light beam on the object surface with little drift can be maintained for more than one day, indicating the effectiveness of the alignment and anti- drift mechanism. Furthermore, the focus error signal in this case shows very little vibrational noise, suggesting that high resolution displacement measurements are possible even with a non-rigid actuator.
- ADS 3 including an alignment and anti-drift mechanism is employed as the focus sensor of a laser hologram unit 6.
- This setup is used, for instance, in CD and DVD optical drives.
- a laser diode 62 emits a light beam which passes through a collimator 65 and an objective lens 64 and projects onto the surface of an object 4 at or near the focus of objective lens 64, forming a detection light spot on the surface of object 4.
- a light beam reflected from the surface of object 4 passes through objective lens 64, collimator 63, and a holographic optical element 61, and is focused on a photo detector 63.
- the Z-direction displacement of the surface of object 4 can be determined from the focus error signal by calculating detected signals from photo detector 63.
- Objective lens 64 is attached to an actuator 70, typically a voice coil motor, which can be moved at least along the direction of the impinging detection light beam (i.e., the Z direction).
- the actuator is controlled by a low- speed feedback driver (not shown) to move objective lens 64 in the Z direction to change the focus condition so that the output of the photo detector 63 is maintained at a desired value.
- actuator 70 also provides additional one- or two-dimensional motion along the X axis and/or Y axis for multi-axis linear alignment of the focused detection light beam on different positions on the surface of object 4.
- the alignment and anti-drift mechanism described herein can be used to detect mechanical motion (i.e., translational or angular displacement) of microfabricated elements, such as microfabricated cantilevers or other micro electromechanical system (MEMS) devices.
- MEMS micro electromechanical system
- This mechanism is thus applicable to techniques such as atomic force microscopy (AFM) and to chemical and biological sensing based on the detection of static deformation or dynamic motion of suspended elements in MEMS and nanoelectromechanical systems (NEMS).
- AFM atomic force microscopy
- NEMS nanoelectromechanical systems
- the object 4 referred to above is an AFM cantilever or a suspended element in MEMS or NEMS applications, respectively.
- the object 4 may also be a generic sample. For instance, as shown in Fig.
- the alignment and anti-drift mechanism is used with a surface profilometer to detect the height and/or tilt angle of the surface of sample 4.
- the alignment and anti-drift mechanism aligns the focused detection beam on the sample surface and compensates for slowly-varying signal drifts that occur during fast scanning of the sample.
- the displacement sensor detects the vertical height between the sensor and the surface of the object, i.e., the separation between the sensor and the object.
- the alignment and anti-drift mechanism enables adjustment of the height to a desired position and maintenance of the height without drift. This mechanism can also be used to adjust and maintain the lateral position of the object. In some embodiments, the lateral position of the object is maintained and adjusted by using image processing to calculate the slow drift of the object as described in co-pending
- multiple feedback control drivers are used, each driver controlling an actuator.
- some DVD optical heads are equipped with voice coil motors that allow the adjustment of two-dimensional linear displacements (i.e., along the beam axis and perpendicular to the beam axis) and one-dimensional tilt of the objective lens.
- An alignment and anti-drift mechanism applied to these DVD heads would enable alignment and maintenance of the positioning in one dimension and the tilt in two dimensions of an optical disk to be read by the DVD head.
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Radiology & Medical Imaging (AREA)
- Length Measuring Devices By Optical Means (AREA)
- Optical Recording Or Reproduction (AREA)
Abstract
Description
Claims
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2009/061822 WO2011049577A1 (en) | 2009-10-23 | 2009-10-23 | Alignment and anti-drift mechanism |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2491407A1 true EP2491407A1 (en) | 2012-08-29 |
| EP2491407A4 EP2491407A4 (en) | 2014-03-26 |
Family
ID=43900588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09850676.9A Withdrawn EP2491407A4 (en) | 2009-10-23 | 2009-10-23 | ALIGNMENT AND ANTIDERIVE MECHANISM |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP2491407A4 (en) |
| CN (1) | CN102844665B (en) |
| WO (1) | WO2011049577A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6706519B2 (en) * | 2015-03-31 | 2020-06-10 | 株式会社日立ハイテクサイエンス | Scanning probe microscope, measuring range adjusting method of scanning probe microscope, and measuring range adjusting program |
| CN107228621A (en) * | 2017-06-08 | 2017-10-03 | 重庆腾毅兴精密电子有限公司 | A kind of voice coil motor swing detecting device and its method |
| CN107238361B (en) * | 2017-06-08 | 2019-09-06 | 蔡银花 | A kind of voice coil motor displacement accuracy and reliability checking method |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5661548A (en) * | 1994-11-30 | 1997-08-26 | Nikon Corporation | Projection exposure method and apparatus including a changing system for changing the reference image-formation position used to generate a focus signal |
| US6078044A (en) * | 1996-05-13 | 2000-06-20 | Seiko Instruments Inc. | Probe scanning apparatus |
| US5852232A (en) * | 1997-01-02 | 1998-12-22 | Kla-Tencor Corporation | Acoustic sensor as proximity detector |
| US6323483B1 (en) * | 1999-09-20 | 2001-11-27 | Veeco Instruments Inc. | High bandwidth recoiless microactuator |
| US6590208B2 (en) * | 2001-01-19 | 2003-07-08 | Veeco Instruments Inc. | Balanced momentum probe holder |
| JP2003215018A (en) * | 2002-01-23 | 2003-07-30 | Jeol Ltd | Surface information measuring method and surface information measuring device |
| KR100501893B1 (en) * | 2002-11-14 | 2005-07-25 | 한국전자통신연구원 | Non-contact scanning apparatus using frequency response separation scheme and scanning method thereof |
| US6845655B2 (en) * | 2003-03-17 | 2005-01-25 | Wisconsin Alumni Research Foundation | Heterodyne feedback system for scanning force microscopy and the like |
| US7247827B1 (en) * | 2006-05-31 | 2007-07-24 | Academia Sinica | System for measurement of the height, angle and their variations of the surface of an object |
| US8904560B2 (en) * | 2007-05-07 | 2014-12-02 | Bruker Nano, Inc. | Closed loop controller and method for fast scanning probe microscopy |
-
2009
- 2009-10-23 WO PCT/US2009/061822 patent/WO2011049577A1/en not_active Ceased
- 2009-10-23 CN CN200980162097.3A patent/CN102844665B/en not_active Expired - Fee Related
- 2009-10-23 EP EP09850676.9A patent/EP2491407A4/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP2491407A4 (en) | 2014-03-26 |
| WO2011049577A1 (en) | 2011-04-28 |
| CN102844665B (en) | 2015-04-29 |
| CN102844665A (en) | 2012-12-26 |
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