EP2480087A2 - Control of elasmopalpus - Google Patents

Control of elasmopalpus

Info

Publication number
EP2480087A2
EP2480087A2 EP10754925A EP10754925A EP2480087A2 EP 2480087 A2 EP2480087 A2 EP 2480087A2 EP 10754925 A EP10754925 A EP 10754925A EP 10754925 A EP10754925 A EP 10754925A EP 2480087 A2 EP2480087 A2 EP 2480087A2
Authority
EP
European Patent Office
Prior art keywords
spp
plant
propagation material
composition
abamectin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP10754925A
Other languages
German (de)
French (fr)
Inventor
José SOTO VEIGA
Leandro Martinho
Henrique De Jesus Ferreira
Paulo Hiromitu ARAMAKI
Joao Carlos DA SILVA NUNES
Alexandre Jose Da Silva
Dieter Hofer
Andre Luiz FREITAS DE OLIVEIRA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syngenta Participations AG
Original Assignee
Syngenta Participations AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Participations AG filed Critical Syngenta Participations AG
Priority to EP10754925A priority Critical patent/EP2480087A2/en
Publication of EP2480087A2 publication Critical patent/EP2480087A2/en
Withdrawn legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Definitions

  • the present invention relates to the use of abamectin for control of damage caused by Elasmopalpus, such as Elasmopalpus lignosellus.
  • Tillage and destruction of weeds are recommended prior to planting because this helps to destroy larvae that may be present in the soil and might damage seedlings, the stage most susceptible to destruction.
  • crop culture that uses conservation tillage i.e., retention of crop residue at the soil surface
  • CROPSTAR® imidacloprid and thiodicarb
  • STANDAK® propronil
  • the present invention provides a method of protecting a plant propagation material and a plant, part of a plant and/or plant organ that grow at a later point in time against damage by Elasmopalpus applying to the plant propagation material a composition comprising abamectin.
  • the present invention provides a method of controlling or preventing by Elasmopalpus damage in a plant propagation material, and a plant, part of a plant and/or plant organ that grow at a later point in time, which comprises applying applying to the plant propagation material a composition comprising abamectin.
  • the invention provide a method of improving the growing characterictics of a plant, which comprises applying to the plant propagation material a composition comprising abamectin.
  • Controlling, preventing or protecting and its inflections, within the context of the present invention, mean reducing any undesired effect, such as
  • the composition is preferably applied or treated on the plant propagation material before it is sown or planted. Suitable treament and application techniquires for abamectin containing compositions to plant propagation material, such as a seed, are known.
  • the composition defined in the first aspect particularly controls Elasmopalpus in its larval stage.
  • the larve damage young plants, which can cause gaps in the stand and/or distort the stem/stalk.
  • the improvement in the growing (or growth) characteristics of a plant can manifest in a number of different ways, but ultimately it results in a better product of the plant. It can, for example, manifest in improving the yield and/or vigour of the plant or quality of the harvested product from the plant, which improvement may not be connected to the control of pests.
  • the phrase "improving the yield" of a plant relates to an increase in the yield of a product of the plant by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the subject method. It is preferred that the yield be increased by at least about 0.5%, more preferred that the increase be at least about 1 %, even more preferred is about 2%, and yet more preferred is about 4%, or more.
  • Yield can be expressed in terms of an amount by weight or volume of a product of the plant on some basis. The basis can be expressed in terms of time, growing area, weight of plants produced, amount of a raw material used, or the like.
  • the phrase "improving the vigour" of a plant relates to an increase or improvement of the vigour rating, or the stand (the number of plants per unit of area), or the plant height, or the plant canopy, or the visual appearance (such as greener leaf colour), or the root rating, or emergence, or protein content, or increased tillering, or bigger leaf blade, or less dead basal leaves, or stronger tillers, or less fertilizer needed, or less seeds needed, or more productive tillers, or earlier flowering, or early grain maturity, or less plant verse (lodging), or increased shoot growth, or earlier germination, or any combination of these factors, or any other advantages familiar to a person skilled in the art, by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the subject method.
  • the present method is capable of "improving the yield and/or vigour" of a plant
  • the present method results in an increase in either the yield, as described above, or the vigor of the plant, as described above, or both the yield and the vigor of the plant.
  • composition of the invention can be formulated for a particular use.
  • the composition is formulated for protecting propagation materials.
  • the present invention relates to a method which comprises (i) treating a plant propagation material, such as a seed, with a composition as defined in the first aspect, and (ii) planting or sowing the treated propagation material, wherein the composition protects against pest damage (for example by Elasmopalpus, such as
  • Elasmopalpus lignosellus a nematode from the class Insecta, such as Meloidogyne spp. Heterodera spp. Pratylenchus spp.) of the treated plant propagation material, or part of plant, plant organ and/or plant grown from the treated propagation material.
  • the present invention relates to a method which comprises (i) treating a plant propagation material, such as a seed, with a composition as defined in the first aspect, and (ii) planting or sowing the treated propagation material, and (iii) achieving protection against pest damage (for example by Elasmopalpus, such as Elasmopalpus lignosellus, a nematode from the class Insecta, such as Meloidogyne spp. Heterodera spp. Pratylenchus spp.) of the treated plant propagation material, or part of plant, plant organ and/or plant grown from the treated propagation material.
  • a plant propagation material such as a seed
  • a composition as defined in the first aspect for example by Elasmopalpus, such as Elasmopalpus lignosellus, a nematode from the class Insecta, such as Meloidogyne spp. Heterodera spp. Pra
  • plant propagation material is understood to denote all the generative parts of the plant, such as seeds, which can be used for the multiplication of the latter and vegetative plant materials such as cuttings and tubers (for example, potatoes). Accordingly, as used herein, part of a plant includes propagation material. There may be mentioned, e.g., the seeds (in the strict sense), roots, fruits, tubers, bulbs, rhizomes, parts of plants. Germinated plants and young plants, which are to be transplanted after germination or after emergence from the soil, may also be mentioned. These young plants may be protected before transplantation by a total or partial treatment by immersion.
  • Parts of plant and plant organs that grow at later point in time are any sections of a plant that develop from a plant propagation material, such as a seed. Parts of plant, plant organs, and plants can also benefit from the pest damage protection achieved by the application of a composition on to the plant propagation material.
  • certain parts of a plant and certain plant organs that grow at later point in time can also be considered as plant propagation material, which can themselves be applied (or treated) with the composition; and consequently, the plant, further parts of the plant and further plant organs that develop from the treated parts of plant and treated plant organs can also benefit from the pest damage protection achieved by the application of the composition on to the certain parts of plant and certain plant organs.
  • Methods for applying or treating pesticidal active ingredients and mixtures thereof on to plant propagation material, especially seeds are known in the art, and include dressing, coating, pelleting and soaking application methods of the propagation material. Such methods are also applicable to the present invention.
  • the composition defined in the first aspect is applied or treated on to the plant propagation material by a method such that the germination is not induced; generally seed soaking induces germination because the moisture content of the resulting seed is too high.
  • suitable methods for applying (or treating) a plant propagation material, such as a seed is seed dressing, seed coating or seed pelleting and alike. It is preferred that the plant propagation material is a seed.
  • the present method can be applied to a seed in any physiological state, it is preferred that the seed be in a sufficiently durable state that it incurs no damage during the treatment process.
  • the seed would be a seed that had been harvested from the field; removed from the plant; and separated from any cob, stalk, outer husk, and surrounding pulp or other non-seed plant material.
  • the seed would preferably also be biologically stable to the extent that the treatment would cause no biological damage to the seed. It is believed that the treatment can be applied to the seed at any time between harvest of the seed and sowing of the seed or during the sowing process (seed directed
  • the seed may also be primed either before or after the treatment.
  • Treatment could vary from a thin film
  • the formulation containing the composition for example, a mixture of active ingredient(s), on a plant propagation material, such as a seed, where the original size and/or shape are recognizable to an intermediary state (such as a coating) and then to a thicker film (such as pelleting with many layers of different materials (such as carriers, for example, clays; different formulations, such as of other active ingredients; polymers; and colourants) where the original shape and/or size of the seed is no longer recognisable.
  • an intermediary state such as a coating
  • a thicker film such as pelleting with many layers of different materials (such as carriers, for example, clays; different formulations, such as of other active ingredients; polymers; and colourants) where the original shape and/or size of the seed is no longer recognisable.
  • An aspect of the present invention includes application of the composition onto the plant propagation material in a targeted fashion, including positioning the ingredients in the composition onto the entire plant propagation material or on only parts thereof, including on only a single side or a portion of a single side.
  • One of ordinary skill in the art would understand these application methods from the description provided in EP 954 213 B1 and WO 06/1 12700.
  • composition described herein can also be used to enhance the growth of a plant through treating, or applying, a composition according to the present on to a "pill” or a suitable substrate and placing, or sowing, the treated pill, or substrate, next to a plant propagation material .
  • Such techniques are known in the art, particularly in EP 1 124 414, WO 07/067042, and WO 07/067044.
  • Application of the composition described herein onto plant propagation material also includes protecting the plant propagation material treated with the composition of the present invention by placing one or more pesticide-containing particles next to a pesticide-treated seed, wherein the amount of pesticide is such that the pesticide-treated seed and the pesticide-containing particles together contain an Effective Dose of the pesticide and the pesticide dose contained in the pesticide-treated seed is less than or equal to the Maximal Non-Phytotoxic Dose of the pesticide.
  • Such techniques are known in the art, particularly in WO 05/120226.
  • composition onto the seed also includes controlled release coatings on the seeds, wherein the ingredients of the composition are incorporated into materials that release the ingredients over time. Examples of controlled release seed treatment
  • the seed treatment occurs to an unsown seed, and the term "unsown seed” is meant to include seed at any period between the harvest of the seed and the sowing of the seed in the ground for the purpose of germination and growth of the plant. Treatment to an unsown seed is not meant to include those practices in which the active ingredient is applied to the soil but would include any application practice that would target the seed during the planting process.
  • the treatment occurs before sowing of the seed so that the sown seed has been pre-treated with the composition.
  • seed coating or seed pelleting are preferred in the treatment of the composition according to the invention.
  • the ingredients in the composition are adhered on to the seed and therefore available for pest control.
  • the treated seeds can be stored, handled, sowed and tilled in the same manner as any other active ingredient treated seed.
  • crops suitable for use in the present invention are: cereals, such as wheat, barley, rye, oats, rice, maize (fodder maize and sugar maize / sweet and field corn) or sorghum; beet, such as sugar or fodder beet; fruit, for example pomaceous fruit, stone fruit, tree nut or soft fruit, such as apples, pears, plums, peaches, bananas, almonds, walnuts, pistachios, cherries or berries, for example strawberries, raspberries or blackberries;
  • cereals such as wheat, barley, rye, oats, rice, maize (fodder maize and sugar maize / sweet and field corn) or sorghum
  • beet such as sugar or fodder beet
  • fruit for example pomaceous fruit, stone fruit, tree nut or soft fruit, such as apples, pears, plums, peaches, bananas, almonds, walnuts, pistachios, cherries or berries
  • leguminous crops such as beans, lentils, peas or soya
  • oil crops such as oilseed rape, mustard, poppies, olives, sunflowers, coconut, castor, cocoa or ground nuts
  • cucurbits such as pumpkins, marrow, cucumbers or melons
  • fibre plants such as cotton, flax, hemp or jute
  • citrus fruit such as oranges, lemons, grapefruit or tangerines
  • vegetables such as spinach, lettuce, asparagus, cabbages, iceberg, carrots, onions, tomatoes, paprika, potatoes or bell peppers
  • Lauraceae such as avocado, Cinnamonium or camphor
  • composition is suitable for sugar cane, soybean, corn, sugar beet, cotton, coffee, citrus, cereals , stone fruits (especially apple, pears, plums, peaches), tree nuts (especially almonds and pistachios), and vegetable crops.
  • suitable crops are corn, soybean, cereals including dry land rice and cotton.
  • Suitable target crops also include transgenic crop plants of the foregoing types.
  • the transgenic crop plants used according to the invention are plants, or propagation material thereof, which are transformed by means of recombinant DNA technology in such a way that they are - for instance - capable of synthesizing selectively acting toxins as are known, for example, from toxin-producing invertebrates, especially of the phylum Arthropoda, as can be obtained from Bacillus thuringiensis strains; or as are known from plants, such as lectins; or in the alternative capable of expressing a herbicidal or fungicidal resistance.
  • Examples of such toxins, or transgenic plants which are capable of synthesizing such toxins, have been disclosed, for example, in EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529 and EP-A-451 878 and are incorporated by reference in the present application.
  • the rates of application (use) of the composition vary, for example, according to type of use, type of crop, but is such that the abamectin is an effective amount to provide the desired enhanced action (such as pest control of at least Elasmopalpus, such as Elasmopalpus lignosellus) and can be determined by trials and routine experimentation known to one of ordinary skill in the art.
  • abamectin is used at a rate 0.1 to 1 mg Active Ingredient/seed, preferably 0.2 to 0.8 mg Al/seed, especially 0.4 to 0.7 mg Al/seed.
  • a single pesticidal active ingredient may have activity in more than one area of pest control, for example, a pesticide may have fungicide, insecticide and nematicide activity.
  • aldicarb is known for insecticide, acaricide and nematicide activity
  • metam is known for insecticide, herbicide, fungicide and nematicide activity
  • thiabendazole and captan can provide nematicide and fungicide activity.
  • the abamectin containing composition of the present invention may be used alone or in combination with one or more other agents having pest control characteristics.
  • agents include pesticides (e.g. fungicide, insecticide, nematicide, bactericide, etc), biological agents (such as Bacillus firmus strain 1-1582), and Harpin.
  • the abamectin containing composition of the present invention may also be used with agents that improve the growth of the crops, such as plant growth regulatory, plant growth activators, isoflavanones, and adjuvants (a substance which in itself doesn't show pesticidal activity but enhances the activity of the pesticide - usually crop oil concentrates and surfactants).
  • agents that improve the growth of the crops such as plant growth regulatory, plant growth activators, isoflavanones, and adjuvants (a substance which in itself doesn't show pesticidal activity but enhances the activity of the pesticide - usually crop oil concentrates and surfactants).
  • the other agent is a pesticide.
  • the one or more other pesticides can be also applied or treated to the plant propagation material simultaneously, prior to, or in succession to, the abamectin-containing composition.
  • the abamectin- containing composition further comprises the one or more other agents having pest control characteristics.
  • pestcides include azoxystrobin, trifloxystrobin, fluoxastrobin, cyproconazole, difenoconazole, prothioconazole, tebuconazole, triticonazole, fludioxonil, thiabendazole, ipconazole, cyprodinil, myclobutanil, metalaxyl, metalaxyl-M (also known as mefenoxam), ortho-cyclopropyl-carboxanilide of formula (a), compound of formula ( ⁇ ), thiamethoxam, clothianidin, imidacloprid, abamectin, fipronil, pymetrozine, lambda-cyhalothrin, tefluthrin, beta-c fluthrin, thiodicarb, compound of formula ( ⁇ ), wherein compound (a) is
  • preferred pesticides are azoxystrobin, fludioxonil, thiabendazole, metalaxyl, metalaxyl-M (also known as mefenoxam), ortho-cyclopropyl-carboxanilide of formula (a), thiamethoxam, clothianidin, imidacloprid, thiodicarb, fipronil, pymetrozine, thiodicarb and lambda-cyhalothrin.
  • azoxystrobin fludioxonil, thiabendazole, metalaxyl, metalaxyl-M (also known as mefenoxam), ortho-cyclopropyl-carboxanilide of formula (a), thiamethoxam, clothianidin, imidacloprid, thiodicarb, fipronil, pymetrozine, thiodicarb and lambda-cyhalothrin.
  • abamectin and one or more other agents having pest control characteristics may be used either in pure form, i.e., as a solid active ingredient, for example, in a specific particle size, they are preferably used in the form of formulation comprising at least one of the auxiliary customary in formulation technology, such as extenders, e.g., solvents or solid carriers, or surface-active compounds (surfactants) in the present invention.
  • auxiliary customary in formulation technology such as extenders, e.g., solvents or solid carriers, or surface-active compounds (surfactants) in the present invention.
  • the abamectin containing composition and one or more other agents having pest control characteristics are applied as a composition.
  • the composition contains abamectin, one more oother agents having pest control characteristics, and one or more customary formulation auxiliarie, which composition may be in the form of a tank-mix or pre-mix composition.
  • the composition is in the form of a pre-mix composition (or formulated product).
  • the weight ratio of abamectin to any other agents is selected as to give the desired, for example, synergistic action.
  • the weight ratio of abamectin to any agent is from 100:1 to 1 :100, preferably 50:1 to 1 :50, more preferably 1 :1 to 1 :50, especially 1 :5 to 1 :40, advantageously 1 :7 to 1 :40, such as 1 :10 to 1 :30.
  • the composition defined in the first aspect, as well as controlling Elasmopalpus may control other pests selected from the class Insecta, Arachnida and Nematoda.
  • pests examples include: from the order Lepidoptera, for example, Acleris spp., Adoxophyes spp., Aegeria spp., Agrotis spp., Alabama argillaceae, Amylois spp., Anticarsia gemmatalis, Archips spp., Argyrotaenia spp., Autographa spp., Busseola fusca, Cadra cautella, Carposina nipponensis, Chilo spp., Choristoneura spp., Clysia ambiguella, Cnaphalocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp., Crocidolomia spp., Cryptophlebia leucotreta, Crysodeixis includens, Cydia spp., Diatraea spp., Diparopsis castane
  • Eucosma spp. Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Grapholita spp., Hedya nubiferana, Heliothis spp., Hellula undalis, Hyphantria cunea, Keiferia lycopersicella, Leucoptera scitella, Lithocollethis spp., Lobesia botrana, Lymantria spp., Lyonetia spp., Malacosoma spp., Mamestra brassicae, Manduca sexta, Operophtera spp., Ostrinia nubilalis, Pammene spp., Pandemis spp., Panolis flammea, Pectinophora gossypiella, Phthorimaea operculella, Pieris rapae, Pieris spp., Plutella x
  • Scirpophaga spp. Sesamia spp., Sparganothis spp., Spodoptera spp., Synanthedon spp., Thaumetopoea spp., Tortrix spp., Trichoplusia ni and Yponomeuta spp.; from the order Coleoptera, for example, Agriotes spp., Anthonomus spp., Atomaria linearis, Ceutorhynchus spp., Chaetocnema tibialis, Cosmopolites spp., Curculio spp., Dermestes spp., Diabrotica spp., Epilachna spp., Eremnus spp., Gonocephalum spp., Heteronychus spp., Leptinotarsa decemlineata, Lissorhoptrus spp., Melolontha spp.
  • Thysanoptera for example, Frankliniella spp., Hercinothrips spp., Taeniothrips spp., Thrips palmi, Thrips tabaci and Scirtothrips aurantii; from the order Heteroptera, for example, Dichelops melacanthus, Distantiella theobroma, Dysdercus spp., Euchistus spp., Eurygaster spp., Leptocorisa spp., Nezara spp., Piesma spp., Rhodnius spp., Sahlbergella singularis, Scotinophara spp. and Triatoma spp.;
  • Homoptera for example, Aleurothrixus floccosus, Aleyrodes brassicae, Aonidiella spp., Aphididae, Aphis spp., Aspidiotus spp., Bemisia tabaci, Ceroplaster spp., Chrysomphalus aonidium, Chrysomphalus dictyospermi, Coccus hesperidum, Empoasca spp., Eriosoma larigerum, Erythroneura spp., Gascardia spp., Laodelphax spp., Lecanium corni, Lepidosaphes spp., Macrosiphus spp., Myzus spp., Nephotettix spp., Nilaparvata spp., Paratoria spp., Pemphigus spp., Planococcus spp., Pseu
  • Saissetia spp. Scaphoideus spp., Schizaphis spp., Sitobion spp., Trialeurodes vaporariorum, Trioza erytreae and Unaspis citri; from the order Hymenoptera, for example, Acromyrmex, Athalia rosae, Atta spp., Cephus spp., Diprion spp., Diprionidae, Gilpinia polytoma, Hoplocampa spp., Lasius spp.,
  • Nematoda for example, the species of Meloidogyne spp. (for example, Meloidogyne incoginita and Meloidogyne javanica), Heterodera spp. (for example,
  • composition defined in the first aspect is suitable for control of one or more pests from class Nematoda.
  • a composition comprising a mixture of abamectin and one or more of thiamethoxam, imidacloprid, clothianidin, fipronil and thiodicarb is suitable.
  • the weight ratio is preferably from 1 :1 to 1 .5:1 respectively; whereas in instance the mixture is abamectin and imidacloprid, the weight ratio is preferably from 1 :1 to 1 :1 .5 respectively; whereas in instance the mixture is abamectin and fipronil, the weight ratio is preferably from 1 .5:1 to 1 :1.5; and whereas in instance the mixture is abamectin and thiodicarb, the weight ratio is preferably from 1 :4 to 1 :5 respectively.
  • the spectrum of control is broadened to include pathogens.
  • phytopathogenic fungi especially occurring in plants, including seedborne fungi belong to the following classes: Ascomycetes (e.g. Penicillium, Gaeumannomyces graminis);
  • Basidiomycetes e.g. the genus Hemileia, Rhizoctonia, Puccinia
  • Fungi imperfecti e. g. Botrytis, Helminthosporium, Rhynchosporium, Fusarium, Septoria, Cercospora, Alternaria, Pyricularia and Pseudocercosporella herpotrichoides
  • Oomycetes e. g. Phytophthora, Peronospora, Bremia, Pythium, Plasmopara
  • Zygomycetes e.g., Rhizopus spp.
  • a combination is especially effective against Alternaria spp., Aspergillus spp., Ascochyta spp., Botrytis cinerea, Cercospora spp., Claviceps purpurea, Cochliobolus spp. (such as
  • Cochliobolus sativus Colletotrichum spp., Diplodia maydis, Epicoccum spp., Erysiphe graminis, Fusarium spp. (such as Fusarium culmorum, Fusarium subglutinans, Fusarium oxysporium, Fusarium solani, Fusarium graminearum, Fusarium proliferatum, and Fusarium moniliforme), Gaeumannomyces graminis, Giberella fujikuroi, Giberella zeae,
  • Sclerotinia spp. Sphacelotheca reilliana, Tilletia spp., Rhizopus spp., Typhula spp., Ustilago spp., Urocystis occulta, Sphacelotheca spp. (e.g. Spacelotheca reilliani), Thielaviopsis basicola, Typhula incarnata, Thanatephorus cucumeris, and Verticillium spp.
  • foliar formulation types for pre-mix compositions are:
  • WP wettable powders
  • WG water dispersable granules (powders)
  • EW emulsions, oil in water
  • aqueous suspo-emulsion aqueous suspo-emulsion.
  • formulation types suitable for tank-mix compositions are solutions, dilute emulsions, suspensions, or a mixture thereof, and dusts.
  • the methods of application such as foliar, drench, spraying, atomizing, dusting, scattering, coating or pouring, are chosen in accordance with the intended objectives and the prevailing circumstances.
  • the tank-mix compositions are generally prepared by diluting with a solvent (for example, water) the one or more pre-mix compositions containing different pesticides, and optionally further auxiliaries, including adjuvants.
  • Suitable carriers and adjuvants can be solid or liquid and are the substances ordinarily employed in formulation technology, e.g. natural or regenerated mineral substances, solvents, dispersants, wetting agents, tackifiers, thickeners, binders or fertilizers.
  • the formulations are prepared in known manner, e.g., by homogeneously mixing and/or grinding the active ingredients with extenders, e.g., solvents, solid carriers and, where appropriate, surface-active compounds (surfactants).
  • extenders e.g., solvents, solid carriers and, where appropriate, surface-active compounds (surfactants).
  • Suitable solvents are: aromatic hydrocarbons, preferably the fractions containing 8 to 12 carbon atoms, e.g. xylene mixtures or substituted naphthalenes, phthalates, such as dibutyl phthalate or dioctyl phthalate, aliphatic hydrocarbons, such as cyclohexane or paraffins, alcohols and glycols and their ethers and esters, such as ethanol, ethylene glycol, ethylene glycol monomethyl or monoethyl ether, ketones, such as cyclohexanone, strongly polar solvents, such as N-methyl-2-pyrrolidone, dimethyl sulfoxide or dimethylformamide, as well as vegetable oils or epoxidised vegetable oils, such as epoxidised coconut oil or soybean oil; or water.
  • aromatic hydrocarbons preferably the fractions containing 8 to 12 carbon atoms, e.g. xylene mixtures or substituted naphthalenes
  • the solid carriers used are normally natural mineral fillers, such as calcite, talcum, kaolin, montmorillonite or attapulgite.
  • calcite talcum
  • kaolin kaolin
  • montmorillonite attapulgite
  • highly dispersed silicic acid or highly dispersed absorbent polymers e.g., calcite, talcum, kaolin, montmorillonite or attapulgite.
  • Suitable granulated adsorptive carriers are porous types, for example pumice, broken brick, sepiolite or bentonite, and suitable nonsorbent carriers are, for example, calcite or sand.
  • pregranulated materials of inorganic or organic nature can be used, e.g., especially dolomite or pulverized plant residues.
  • suitable surface-active compounds are non-ionic, cationic and/or anionic surfactants having good emulsifying, dispersing and wetting properties.
  • surfactants will also be understood as comprising mixtures of surfactants.
  • Particularly advantageous application-promoting adjuvants are also natural or synthetic phospholipids of the cephalin and lecithin series, e.g., phosphatidylethanolamine, phos- phatidylserine, phosphatidylglycerol and lysolecithin.
  • phospholipids of the cephalin and lecithin series e.g., phosphatidylethanolamine, phos- phatidylserine, phosphatidylglycerol and lysolecithin.
  • a tank-mix formulation for foliar or soil application comprises 0.1 to 20%, especially 0.1 to 15 %, active ingredient compounds, and 99.9 to 80 %, especially 99.9 to 85 %, of a solid or liquid auxiliaries (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 20 %, especially 0.1 to 15 %, based on the tank-mix formulation.
  • auxiliaries including, for example, a solvent such as water
  • a pre-mix formulation for foliar application comprises 0.1 to 99.9 %, especially 1 to 95 %, active ingredient compounds, and 99.9 to 0.1 %, especially 99 to 5 %, of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 50 %, especially 0.5 to 40 %, based on the pre-mix formulation.
  • a solid or liquid adjuvant including, for example, a solvent such as water
  • a tank-mix formulation for seed treatment application comprises 0.25 to 80%, especially 1 to 75 %, of the desired ingredients, and 99.75 to 20 %, especially 99 to 25 %, of a solid or liquid auxiliaries (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 40 %, especially 0.5 to 30 %, based on the tank-mix formulation.
  • auxiliaries including, for example, a solvent such as water
  • a pre-mix formulation for seed treatment application comprises 0.5 to 99.9 %, especially 1 to 95 %, of the desired ingredients, and 99.5 to 0.1 %, especially 99 to 5 %, of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 50 %, especially 0.5 to 40 %, based on the pre-mix formulation.
  • Preferred seed treatment pre-mix formulations are aqueous suspension concentrates.
  • the formulation can be applied to the seeds using conventional treating techniques and machines, such as fluidized bed techniques, the roller mill method, rotostatic seed treaters, and drum coaters. Other methods, such as spouted beds may also be useful.
  • the seeds may be presized before coating. After coating, the seeds are typically dried and then transferred to a sizing machine for sizing. Such procedures are known in the art.
  • the pre-mix compositions of the invention contain 0.5 to 99.9 especially 1 to 95, advantageously 1 to 50 , %, by mass of the desired ingredients, and 99.5 to 0.1 , especially 99 to 5, %, by mass of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries (or adjuvant) can be a surfactant in an amount of 0 to 50, especially 0.5 to 40, %, by mass based on the mass of the pre-mix formulation.
  • a solid or liquid adjuvant including, for example, a solvent such as water
  • Preferred abamectin-containing compositions are aqueous suspension concentrates, emulsifiable concentrates and emulsion in water, particularly preferred are suspension concentrates.
  • the pre-mix compositions of the invention contain 0.5 to 99.9 especially 1 to 95, advantageously 1 to 50 , %, by mass of active ingredient compounds, and 99.5 to 0.1 , especially 99 to 5, %, by mass of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries (or adjuvant) can be a surfactant in an amount of 0 to 50, especially 0.5 to 40, %, by mass based on the mass of the pre-mix formulation.
  • a solid or liquid adjuvant including, for example, a solvent such as water
  • Silicone oil (in the form of a 75 % emulsion in water) 0.2 %
  • the finely ground combination is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water.
  • a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water.
  • living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion.
  • the active ingredient composition of the present invention is distinguished by the fact that they are especially well tolerated by plants and are environmentally friendly.
  • the abamectin containing composition is for use in the agrochemical industry.
  • a description of the abamectin and other agents e.g., fungicides, insecticides, nematicides, plant growth regulators
  • Example 1 Elasmopalpus control by Abamectin seed treatment in corn
  • Table 2 Control of Elasmopalpus attack in corn (average of 13 trials with high infestation).
  • Table 3 Yield effect of Elasmopalpus control in corn treated with Avicta and difference to the standard CROPSTAR® treatment in %.
  • Table 4 lists the treatment list and rates applied for the design. Four repetitions where done per treatment.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Peptides Or Proteins (AREA)
  • Feed For Specific Animals (AREA)

Abstract

A method of protecting a plant propagation material and a plant, part of a plant and/or plant organ that grows at a later point in time against damage by Elasmopalpus applying to the plant propagation material a composition comprising abamectin.

Description

Control of Elasmopalpus
The present invention relates to the use of abamectin for control of damage caused by Elasmopalpus, such as Elasmopalpus lignosellus.
The lesser cornstalk borer, Elasmopalpus lignosellus, was described by Zeller in 1848, but it was not considered of economic importance until 1881 (Riley 1882). It is a pest of several economically important crops. The management of this pest is regularly achieved by insecticides applied in a granular formulation in the seed furrow or in a band over the seed bed. Liquid formulations can also be applied, but it is important that they be directed to the root zone. Modified planting practices have long been used to minimize crop loss. Populations tend to increase over the course of a season, so some damage can be avoided by early planting. Tillage and destruction of weeds are recommended prior to planting because this helps to destroy larvae that may be present in the soil and might damage seedlings, the stage most susceptible to destruction. However, crop culture that uses conservation tillage (i.e., retention of crop residue at the soil surface) experiences less injury from lesser cornstalk borer feeding because the larvae feed freely on crop residue and other organic matter, sparing the young crop plants. CROPSTAR® (imidacloprid and thiodicarb) and STANDAK® (fipronil) are generally applied in corn and soy respectively for control of Elasmopalpus lignosellus.
It is now been found that treatment of plant propagation material, such as a seed, by a composition comprising abamectin reduces the damage caused by Elasmopalpus.
Accordingly, in a first aspect the present invention provides a method of protecting a plant propagation material and a plant, part of a plant and/or plant organ that grow at a later point in time against damage by Elasmopalpus applying to the plant propagation material a composition comprising abamectin.
In a second aspect the present invention provides a method of controlling or preventing by Elasmopalpus damage in a plant propagation material, and a plant, part of a plant and/or plant organ that grow at a later point in time, which comprises applying applying to the plant propagation material a composition comprising abamectin.
The control of the damage caused by the pest leads to improvement in the growing characteristics of a plant; therefore, in a further aspect, the invention provide a method of improving the growing characterictics of a plant, which comprises applying to the plant propagation material a composition comprising abamectin.
Controlling, preventing or protecting and its inflections, within the context of the present invention, mean reducing any undesired effect, such as
- pest infestation or attack of, and
- pest damage on,
a plant, part of the plant or plant propagation material to such a level that an improvement is demonstrated.
The composition is preferably applied or treated on the plant propagation material before it is sown or planted. Suitable treament and application techniquires for abamectin containing compositions to plant propagation material, such as a seed, are known. The composition defined in the first aspect particularly controls Elasmopalpus in its larval stage.
The larve damage young plants, which can cause gaps in the stand and/or distort the stem/stalk.
The improvement in the growing (or growth) characteristics of a plant can manifest in a number of different ways, but ultimately it results in a better product of the plant. It can, for example, manifest in improving the yield and/or vigour of the plant or quality of the harvested product from the plant, which improvement may not be connected to the control of pests.
As used herein the phrase "improving the yield" of a plant relates to an increase in the yield of a product of the plant by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the subject method. It is preferred that the yield be increased by at least about 0.5%, more preferred that the increase be at least about 1 %, even more preferred is about 2%, and yet more preferred is about 4%, or more. Yield can be expressed in terms of an amount by weight or volume of a product of the plant on some basis. The basis can be expressed in terms of time, growing area, weight of plants produced, amount of a raw material used, or the like.
As used herein the phrase "improving the vigour" of a plant relates to an increase or improvement of the vigour rating, or the stand (the number of plants per unit of area), or the plant height, or the plant canopy, or the visual appearance (such as greener leaf colour), or the root rating, or emergence, or protein content, or increased tillering, or bigger leaf blade, or less dead basal leaves, or stronger tillers, or less fertilizer needed, or less seeds needed, or more productive tillers, or earlier flowering, or early grain maturity, or less plant verse (lodging), or increased shoot growth, or earlier germination, or any combination of these factors, or any other advantages familiar to a person skilled in the art, by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the subject method.
When it is said that the present method is capable of "improving the yield and/or vigour" of a plant, the present method results in an increase in either the yield, as described above, or the vigor of the plant, as described above, or both the yield and the vigor of the plant.
The composition of the invention can be formulated for a particular use. Preferably, the composition is formulated for protecting propagation materials.
Further, in an embodiment the present invention relates to a method which comprises (i) treating a plant propagation material, such as a seed, with a composition as defined in the first aspect, and (ii) planting or sowing the treated propagation material, wherein the composition protects against pest damage (for example by Elasmopalpus, such as
Elasmopalpus lignosellus, a nematode from the class Insecta, such as Meloidogyne spp. Heterodera spp. Pratylenchus spp.) of the treated plant propagation material, or part of plant, plant organ and/or plant grown from the treated propagation material. Also, in an embodiment the present invention relates to a method which comprises (i) treating a plant propagation material, such as a seed, with a composition as defined in the first aspect, and (ii) planting or sowing the treated propagation material, and (iii) achieving protection against pest damage (for example by Elasmopalpus, such as Elasmopalpus lignosellus, a nematode from the class Insecta, such as Meloidogyne spp. Heterodera spp. Pratylenchus spp.) of the treated plant propagation material, or part of plant, plant organ and/or plant grown from the treated propagation material.
The term "plant propagation material" is understood to denote all the generative parts of the plant, such as seeds, which can be used for the multiplication of the latter and vegetative plant materials such as cuttings and tubers (for example, potatoes). Accordingly, as used herein, part of a plant includes propagation material. There may be mentioned, e.g., the seeds (in the strict sense), roots, fruits, tubers, bulbs, rhizomes, parts of plants. Germinated plants and young plants, which are to be transplanted after germination or after emergence from the soil, may also be mentioned. These young plants may be protected before transplantation by a total or partial treatment by immersion.
Parts of plant and plant organs that grow at later point in time are any sections of a plant that develop from a plant propagation material, such as a seed. Parts of plant, plant organs, and plants can also benefit from the pest damage protection achieved by the application of a composition on to the plant propagation material. In an embodiment, certain parts of a plant and certain plant organs that grow at later point in time can also be considered as plant propagation material, which can themselves be applied (or treated) with the composition; and consequently, the plant, further parts of the plant and further plant organs that develop from the treated parts of plant and treated plant organs can also benefit from the pest damage protection achieved by the application of the composition on to the certain parts of plant and certain plant organs.
Methods for applying or treating pesticidal active ingredients and mixtures thereof on to plant propagation material, especially seeds, are known in the art, and include dressing, coating, pelleting and soaking application methods of the propagation material. Such methods are also applicable to the present invention. In a preferred embodiment, the composition defined in the first aspect is applied or treated on to the plant propagation material by a method such that the germination is not induced; generally seed soaking induces germination because the moisture content of the resulting seed is too high. Accordingly, examples of suitable methods for applying (or treating) a plant propagation material, such as a seed, is seed dressing, seed coating or seed pelleting and alike. It is preferred that the plant propagation material is a seed.
Although it is believed that the present method can be applied to a seed in any physiological state, it is preferred that the seed be in a sufficiently durable state that it incurs no damage during the treatment process. Typically, the seed would be a seed that had been harvested from the field; removed from the plant; and separated from any cob, stalk, outer husk, and surrounding pulp or other non-seed plant material. The seed would preferably also be biologically stable to the extent that the treatment would cause no biological damage to the seed. It is believed that the treatment can be applied to the seed at any time between harvest of the seed and sowing of the seed or during the sowing process (seed directed
applications). The seed may also be primed either before or after the treatment.
Even distribution of ingredients in the composition and adherence thereof to the seeds is desired during propagation material treatment. Treatment could vary from a thin film
(dressing) of the formulation containing the composition, for example, a mixture of active ingredient(s), on a plant propagation material, such as a seed, where the original size and/or shape are recognizable to an intermediary state (such as a coating) and then to a thicker film (such as pelleting with many layers of different materials (such as carriers, for example, clays; different formulations, such as of other active ingredients; polymers; and colourants) where the original shape and/or size of the seed is no longer recognisable.
An aspect of the present invention includes application of the composition onto the plant propagation material in a targeted fashion, including positioning the ingredients in the composition onto the entire plant propagation material or on only parts thereof, including on only a single side or a portion of a single side. One of ordinary skill in the art would understand these application methods from the description provided in EP 954 213 B1 and WO 06/1 12700.
The composition described herein can also be used to enhance the growth of a plant through treating, or applying, a composition according to the present on to a "pill" or a suitable substrate and placing, or sowing, the treated pill, or substrate, next to a plant propagation material . Such techniques are known in the art, particularly in EP 1 124 414, WO 07/067042, and WO 07/067044. Application of the composition described herein onto plant propagation material also includes protecting the plant propagation material treated with the composition of the present invention by placing one or more pesticide-containing particles next to a pesticide-treated seed, wherein the amount of pesticide is such that the pesticide-treated seed and the pesticide-containing particles together contain an Effective Dose of the pesticide and the pesticide dose contained in the pesticide-treated seed is less than or equal to the Maximal Non-Phytotoxic Dose of the pesticide. Such techniques are known in the art, particularly in WO 05/120226.
Application of the composition onto the seed also includes controlled release coatings on the seeds, wherein the ingredients of the composition are incorporated into materials that release the ingredients over time. Examples of controlled release seed treatment
technologies are generally known in the art and include polymer films, waxes, or other seed coatings, wherein the ingredients may be incorporated into the controlled release material or applied between layers of materials, or both.
The seed treatment occurs to an unsown seed, and the term "unsown seed" is meant to include seed at any period between the harvest of the seed and the sowing of the seed in the ground for the purpose of germination and growth of the plant. Treatment to an unsown seed is not meant to include those practices in which the active ingredient is applied to the soil but would include any application practice that would target the seed during the planting process.
Preferably, the treatment occurs before sowing of the seed so that the sown seed has been pre-treated with the composition. In particular, seed coating or seed pelleting are preferred in the treatment of the composition according to the invention. As a result of the treatment, the ingredients in the composition are adhered on to the seed and therefore available for pest control. The treated seeds can be stored, handled, sowed and tilled in the same manner as any other active ingredient treated seed.
Examples of crops suitable for use in the present invention are: cereals, such as wheat, barley, rye, oats, rice, maize (fodder maize and sugar maize / sweet and field corn) or sorghum; beet, such as sugar or fodder beet; fruit, for example pomaceous fruit, stone fruit, tree nut or soft fruit, such as apples, pears, plums, peaches, bananas, almonds, walnuts, pistachios, cherries or berries, for example strawberries, raspberries or blackberries;
leguminous crops, such as beans, lentils, peas or soya; oil crops, such as oilseed rape, mustard, poppies, olives, sunflowers, coconut, castor, cocoa or ground nuts; cucurbits, such as pumpkins, marrow, cucumbers or melons; fibre plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruit or tangerines; vegetables, such as spinach, lettuce, asparagus, cabbages, iceberg, carrots, onions, tomatoes, paprika, potatoes or bell peppers; Lauraceae, such as avocado, Cinnamonium or camphor; and also tobacco, nuts, coffee, eggplants, sugarcane, tea, pepper, grapevines, hops, the plantain family, latex plants, lawn, turf, fodder grass, and ornamentals roses, chrysanthemums, carnation, gerberas, petunias, geranium/pelargoniums, pansies and impatiens; and shrubs, broad-leaved trees and evergreens, such as conifers. In particular, the composition is suitable for sugar cane, soybean, corn, sugar beet, cotton, coffee, citrus, cereals , stone fruits (especially apple, pears, plums, peaches), tree nuts (especially almonds and pistachios), and vegetable crops. Especially suitable crops are corn, soybean, cereals including dry land rice and cotton.
Suitable target crops also include transgenic crop plants of the foregoing types. The transgenic crop plants used according to the invention are plants, or propagation material thereof, which are transformed by means of recombinant DNA technology in such a way that they are - for instance - capable of synthesizing selectively acting toxins as are known, for example, from toxin-producing invertebrates, especially of the phylum Arthropoda, as can be obtained from Bacillus thuringiensis strains; or as are known from plants, such as lectins; or in the alternative capable of expressing a herbicidal or fungicidal resistance. Examples of such toxins, or transgenic plants which are capable of synthesizing such toxins, have been disclosed, for example, in EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529 and EP-A-451 878 and are incorporated by reference in the present application. The rates of application (use) of the composition vary, for example, according to type of use, type of crop, but is such that the abamectin is an effective amount to provide the desired enhanced action (such as pest control of at least Elasmopalpus, such as Elasmopalpus lignosellus) and can be determined by trials and routine experimentation known to one of ordinary skill in the art.
In an embodiment, abamectin is used at a rate 0.1 to 1 mg Active Ingredient/seed, preferably 0.2 to 0.8 mg Al/seed, especially 0.4 to 0.7 mg Al/seed. A single pesticidal active ingredient may have activity in more than one area of pest control, for example, a pesticide may have fungicide, insecticide and nematicide activity. Specifically, aldicarb is known for insecticide, acaricide and nematicide activity, while metam is known for insecticide, herbicide, fungicide and nematicide activity, and thiabendazole and captan can provide nematicide and fungicide activity.
The abamectin containing composition of the present invention may be used alone or in combination with one or more other agents having pest control characteristics. Examples of such agents include pesticides (e.g. fungicide, insecticide, nematicide, bactericide, etc), biological agents (such as Bacillus firmus strain 1-1582), and Harpin.
The abamectin containing composition of the present invention may also be used with agents that improve the growth of the crops, such as plant growth regulatory, plant growth activators, isoflavanones, and adjuvants (a substance which in itself doesn't show pesticidal activity but enhances the activity of the pesticide - usually crop oil concentrates and surfactants).
In an embodiment, the other agent is a pesticide.
In the event one or more other pesticides are used in combination with the abamectin containing composition defined in the first aspect, the one or more other pesticides can be also applied or treated to the plant propagation material simultaneously, prior to, or in succession to, the abamectin-containing composition. In an embodiment, the abamectin- containing composition further comprises the one or more other agents having pest control characteristics. Examples of pestcides include azoxystrobin, trifloxystrobin, fluoxastrobin, cyproconazole, difenoconazole, prothioconazole, tebuconazole, triticonazole, fludioxonil, thiabendazole, ipconazole, cyprodinil, myclobutanil, metalaxyl, metalaxyl-M (also known as mefenoxam), ortho-cyclopropyl-carboxanilide of formula (a), compound of formula (β), thiamethoxam, clothianidin, imidacloprid, abamectin, fipronil, pymetrozine, lambda-cyhalothrin, tefluthrin, beta-c fluthrin, thiodicarb, compound of formula (δ), wherein compound (a) is
(a).
a compound (β) is
(β). and compound (δ) is
In an embodiment, preferred pesticides are azoxystrobin, fludioxonil, thiabendazole, metalaxyl, metalaxyl-M (also known as mefenoxam), ortho-cyclopropyl-carboxanilide of formula (a), thiamethoxam, clothianidin, imidacloprid, thiodicarb, fipronil, pymetrozine, thiodicarb and lambda-cyhalothrin.
Although abamectin and one or more other agents having pest control characteristics may be used either in pure form, i.e., as a solid active ingredient, for example, in a specific particle size, they are preferably used in the form of formulation comprising at least one of the auxiliary customary in formulation technology, such as extenders, e.g., solvents or solid carriers, or surface-active compounds (surfactants) in the present invention.
In an embodiment, the abamectin containing composition and one or more other agents having pest control characteristics are applied as a composition. In an embodiment, the composition contains abamectin, one more oother agents having pest control characteristics, and one or more customary formulation auxiliarie, which composition may be in the form of a tank-mix or pre-mix composition. Preferably the composition is in the form of a pre-mix composition (or formulated product).
The weight ratio of abamectin to any other agents is selected as to give the desired, for example, synergistic action. In an embodiment, the weight ratio of abamectin to any agent is from 100:1 to 1 :100, preferably 50:1 to 1 :50, more preferably 1 :1 to 1 :50, especially 1 :5 to 1 :40, advantageously 1 :7 to 1 :40, such as 1 :10 to 1 :30. The composition defined in the first aspect, as well as controlling Elasmopalpus, may control other pests selected from the class Insecta, Arachnida and Nematoda. Examples of such pests include: from the order Lepidoptera, for example, Acleris spp., Adoxophyes spp., Aegeria spp., Agrotis spp., Alabama argillaceae, Amylois spp., Anticarsia gemmatalis, Archips spp., Argyrotaenia spp., Autographa spp., Busseola fusca, Cadra cautella, Carposina nipponensis, Chilo spp., Choristoneura spp., Clysia ambiguella, Cnaphalocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp., Crocidolomia spp., Cryptophlebia leucotreta, Crysodeixis includens, Cydia spp., Diatraea spp., Diparopsis castanea, Earias spp, Ephestia spp.,
Eucosma spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Grapholita spp., Hedya nubiferana, Heliothis spp., Hellula undalis, Hyphantria cunea, Keiferia lycopersicella, Leucoptera scitella, Lithocollethis spp., Lobesia botrana, Lymantria spp., Lyonetia spp., Malacosoma spp., Mamestra brassicae, Manduca sexta, Operophtera spp., Ostrinia nubilalis, Pammene spp., Pandemis spp., Panolis flammea, Pectinophora gossypiella, Phthorimaea operculella, Pieris rapae, Pieris spp., Plutella xylostella, Prays spp.,
Scirpophaga spp., Sesamia spp., Sparganothis spp., Spodoptera spp., Synanthedon spp., Thaumetopoea spp., Tortrix spp., Trichoplusia ni and Yponomeuta spp.; from the order Coleoptera, for example, Agriotes spp., Anthonomus spp., Atomaria linearis, Ceutorhynchus spp., Chaetocnema tibialis, Cosmopolites spp., Curculio spp., Dermestes spp., Diabrotica spp., Epilachna spp., Eremnus spp., Gonocephalum spp., Heteronychus spp., Leptinotarsa decemlineata, Lissorhoptrus spp., Melolontha spp., Orycaephilus spp., Otiorhynchus spp., Phlyctinus spp., Phyllotreta spp., Popillia spp., Protostrophus spp., Psylliodes spp., Rhizopertha spp., Scarabeidae, Sitophilus spp., Sitotroga spp., Tenebrio spp., Tribolium spp. and Trogoderma spp.; from the order Orthoptera, for example, Blatta spp., Blattella spp., Gryllotalpa spp.,
Leucophaea maderae, Locusta spp., Periplaneta spp. and Schistocerca spp.; from the order Isoptera, for example, Reticulitermes spp.; from the order Psocoptera, for example, Liposcelis spp.; from the order Anoplura, for example, Haematopinus spp., Linognathus spp., Pediculus spp., Pemphigus spp. and Phylloxera spp.; from the order Mallophaga, for example, Damalinea spp. and Trichodectes spp.; from the order Thysanoptera, for example, Frankliniella spp., Hercinothrips spp., Taeniothrips spp., Thrips palmi, Thrips tabaci and Scirtothrips aurantii; from the order Heteroptera, for example, Dichelops melacanthus, Distantiella theobroma, Dysdercus spp., Euchistus spp., Eurygaster spp., Leptocorisa spp., Nezara spp., Piesma spp., Rhodnius spp., Sahlbergella singularis, Scotinophara spp. and Triatoma spp.;
from the order Homoptera, for example, Aleurothrixus floccosus, Aleyrodes brassicae, Aonidiella spp., Aphididae, Aphis spp., Aspidiotus spp., Bemisia tabaci, Ceroplaster spp., Chrysomphalus aonidium, Chrysomphalus dictyospermi, Coccus hesperidum, Empoasca spp., Eriosoma larigerum, Erythroneura spp., Gascardia spp., Laodelphax spp., Lecanium corni, Lepidosaphes spp., Macrosiphus spp., Myzus spp., Nephotettix spp., Nilaparvata spp., Paratoria spp., Pemphigus spp., Planococcus spp., Pseudaulacaspis spp., Pseudococcus spp., Psylla spp., Pulvinaria aethiopica, Quadraspidiotus spp., Rhopalosiphum spp.,
Saissetia spp., Scaphoideus spp., Schizaphis spp., Sitobion spp., Trialeurodes vaporariorum, Trioza erytreae and Unaspis citri; from the order Hymenoptera, for example, Acromyrmex, Athalia rosae, Atta spp., Cephus spp., Diprion spp., Diprionidae, Gilpinia polytoma, Hoplocampa spp., Lasius spp.,
Monomorium pharaonis, Neodiprion spp., Solenopsis spp. and Vespa spp.; from the order Diptera, for example, Antherigona soccata, Bibio hortulanus, , Ceratitis spp., Chrysomyia spp., Culex spp., Cuterebra spp., Dacus spp., Delia spp., Drosophila
melanogaster, , Liriomyza spp., , Melanagromyza spp., , Orseolia spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Rhagoletis pomonella, Sciara spp.,; from the order Acarina, for example, Acarus siro, Aceria sheldoni, Aculus schlechtendali, Amblyomma spp., Argas spp., , Brevipalpus spp., Bryobia praetiosa, Calipitrimerus spp., Chorioptes spp., Dermanyssus gallinae, Eotetranychus carpini, Eriophyes spp., Hyalomma spp., Olygonychus pratensis, Ornithodoros spp., Panonychus spp., Phyllocoptruta spp. (such as Phyllocoptruta oleivora), Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Tarsonemus spp. and Tetranychus spp.; and from the class Nematoda, for example, the species of Meloidogyne spp. (for example, Meloidogyne incoginita and Meloidogyne javanica), Heterodera spp. (for example,
Heterodera glycines, Heterodera schachtii, Heterodora avenae and Heterodora trifolii), Globodera spp. (for example, Globodera rostochiensis), Radopholus spp. (for example, Radopholus similes), Rotylenchulus spp., Pratylenchus spp. (for example, Pratylenchus neglectans and Pratylenchus penetrans), Aphelenchoides spp., Helicotylenchus spp., Hoplolaimus spp., Paratrichodorus spp., Longidorus spp., Nacobbus spp., Subanguina spp. Belonlaimus spp., Criconemella spp., Criconemoides spp. Ditylenchus spp., Dolichodorus spp., Hemicriconemoides spp., Hemicycliophora spp., Hirschmaniella spp., Hypsoperine spp., Macroposthonia spp., Melinius spp., Punctodera spp., Quinisulcius spp., Scutellonema spp., Xiphinema spp., and Tylenchorhynchus spp.
In particular the composition defined in the first aspect is suitable for control of one or more pests from class Nematoda.
In an embodiment, a composition comprising a mixture of abamectin and one or more of thiamethoxam, imidacloprid, clothianidin, fipronil and thiodicarb is suitable. In the instance the mixture is abamectin and thiamethoxam or clothianidin, the weight ratio is preferably from 1 :1 to 1 .5:1 respectively; whereas in instance the mixture is abamectin and imidacloprid, the weight ratio is preferably from 1 :1 to 1 :1 .5 respectively; whereas in instance the mixture is abamectin and fipronil, the weight ratio is preferably from 1 .5:1 to 1 :1.5; and whereas in instance the mixture is abamectin and thiodicarb, the weight ratio is preferably from 1 :4 to 1 :5 respectively.
In the event an agent controlling pathogens is also present in the composition defined in the first aspect, the spectrum of control is broadened to include pathogens. Examples of phytopathogenic fungi, especially occurring in plants, including seedborne fungi belong to the following classes: Ascomycetes (e.g. Penicillium, Gaeumannomyces graminis);
Basidiomycetes (e.g. the genus Hemileia, Rhizoctonia, Puccinia), Fungi imperfecti (e. g. Botrytis, Helminthosporium, Rhynchosporium, Fusarium, Septoria, Cercospora, Alternaria, Pyricularia and Pseudocercosporella herpotrichoides); Oomycetes (e. g. Phytophthora, Peronospora, Bremia, Pythium, Plasmopara); Zygomycetes (e.g., Rhizopus spp.). A combination is especially effective against Alternaria spp., Aspergillus spp., Ascochyta spp., Botrytis cinerea, Cercospora spp., Claviceps purpurea, Cochliobolus spp. (such as
Cochliobolus sativus), Colletotrichum spp., Diplodia maydis, Epicoccum spp., Erysiphe graminis, Fusarium spp. (such as Fusarium culmorum, Fusarium subglutinans, Fusarium oxysporium, Fusarium solani, Fusarium graminearum, Fusarium proliferatum, and Fusarium moniliforme), Gaeumannomyces graminis, Giberella fujikuroi, Giberella zeae,
Helminthosporium graminearum, Microdochium nivale, Monographella nivalis, Penicillium spp., Puccinia spp., Pyrenophora spp. (such as Pyrenophora graminea), Peronosclerospora spp., Peronspora spp., Phakopsora pachyrhizi, Phythium spp., Phoma spp., Phomopsis spp., Rhizoctonia solani, Rhizoctonia cerealis, Septoria spp., Pseudocercosporella spp.,
Sclerotinia spp., Sphacelotheca reilliana, Tilletia spp., Rhizopus spp., Typhula spp., Ustilago spp., Urocystis occulta, Sphacelotheca spp. (e.g. Spacelotheca reilliani), Thielaviopsis basicola, Typhula incarnata, Thanatephorus cucumeris, and Verticillium spp.
Examples of foliar formulation types for pre-mix compositions are:
GR: Granules
WP: wettable powders
WG: water dispersable granules (powders)
SG: water soluble granules
SL: soluble concentrates
EC: emulsifiable concentrate
EW: emulsions, oil in water
ME: micro-emulsion
SC: aqueous suspension concentrate
CS: aqueous capsule suspension
OD: oil-based suspension concentrate, and
SE: aqueous suspo-emulsion. Examples of formulation types suitable for tank-mix compositions are solutions, dilute emulsions, suspensions, or a mixture thereof, and dusts. As with the nature of the formulations, the methods of application, such as foliar, drench, spraying, atomizing, dusting, scattering, coating or pouring, are chosen in accordance with the intended objectives and the prevailing circumstances. The tank-mix compositions are generally prepared by diluting with a solvent (for example, water) the one or more pre-mix compositions containing different pesticides, and optionally further auxiliaries, including adjuvants.
Suitable carriers and adjuvants can be solid or liquid and are the substances ordinarily employed in formulation technology, e.g. natural or regenerated mineral substances, solvents, dispersants, wetting agents, tackifiers, thickeners, binders or fertilizers.
The formulations are prepared in known manner, e.g., by homogeneously mixing and/or grinding the active ingredients with extenders, e.g., solvents, solid carriers and, where appropriate, surface-active compounds (surfactants).
Suitable solvents are: aromatic hydrocarbons, preferably the fractions containing 8 to 12 carbon atoms, e.g. xylene mixtures or substituted naphthalenes, phthalates, such as dibutyl phthalate or dioctyl phthalate, aliphatic hydrocarbons, such as cyclohexane or paraffins, alcohols and glycols and their ethers and esters, such as ethanol, ethylene glycol, ethylene glycol monomethyl or monoethyl ether, ketones, such as cyclohexanone, strongly polar solvents, such as N-methyl-2-pyrrolidone, dimethyl sulfoxide or dimethylformamide, as well as vegetable oils or epoxidised vegetable oils, such as epoxidised coconut oil or soybean oil; or water.
The solid carriers used, e.g., for dusts and dispersible powders, are normally natural mineral fillers, such as calcite, talcum, kaolin, montmorillonite or attapulgite. In order to improve the physical properties it is also possible to add highly dispersed silicic acid or highly dispersed absorbent polymers. Suitable granulated adsorptive carriers are porous types, for example pumice, broken brick, sepiolite or bentonite, and suitable nonsorbent carriers are, for example, calcite or sand. In addition, a great number of pregranulated materials of inorganic or organic nature can be used, e.g., especially dolomite or pulverized plant residues. Depending upon the nature of the active ingredient compounds to be formulated, suitable surface-active compounds are non-ionic, cationic and/or anionic surfactants having good emulsifying, dispersing and wetting properties. The term "surfactants" will also be understood as comprising mixtures of surfactants.
Particularly advantageous application-promoting adjuvants are also natural or synthetic phospholipids of the cephalin and lecithin series, e.g., phosphatidylethanolamine, phos- phatidylserine, phosphatidylglycerol and lysolecithin.
Generally, a tank-mix formulation for foliar or soil application comprises 0.1 to 20%, especially 0.1 to 15 %, active ingredient compounds, and 99.9 to 80 %, especially 99.9 to 85 %, of a solid or liquid auxiliaries (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 20 %, especially 0.1 to 15 %, based on the tank-mix formulation.
Typically, a pre-mix formulation for foliar application comprises 0.1 to 99.9 %, especially 1 to 95 %, active ingredient compounds, and 99.9 to 0.1 %, especially 99 to 5 %, of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 50 %, especially 0.5 to 40 %, based on the pre-mix formulation.
Normally, a tank-mix formulation for seed treatment application comprises 0.25 to 80%, especially 1 to 75 %, of the desired ingredients, and 99.75 to 20 %, especially 99 to 25 %, of a solid or liquid auxiliaries (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 40 %, especially 0.5 to 30 %, based on the tank-mix formulation.
Typically, a pre-mix formulation for seed treatment application comprises 0.5 to 99.9 %, especially 1 to 95 %, of the desired ingredients, and 99.5 to 0.1 %, especially 99 to 5 %, of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 50 %, especially 0.5 to 40 %, based on the pre-mix formulation. Preferred seed treatment pre-mix formulations are aqueous suspension concentrates. The formulation can be applied to the seeds using conventional treating techniques and machines, such as fluidized bed techniques, the roller mill method, rotostatic seed treaters, and drum coaters. Other methods, such as spouted beds may also be useful. The seeds may be presized before coating. After coating, the seeds are typically dried and then transferred to a sizing machine for sizing. Such procedures are known in the art.
In general, the pre-mix compositions of the invention contain 0.5 to 99.9 especially 1 to 95, advantageously 1 to 50 , %, by mass of the desired ingredients, and 99.5 to 0.1 , especially 99 to 5, %, by mass of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries (or adjuvant) can be a surfactant in an amount of 0 to 50, especially 0.5 to 40, %, by mass based on the mass of the pre-mix formulation.
Whereas commercial products will preferably be formulated as concentrates (e.g., pre-mix composition (formulation)), the end user will normally employ dilute formulations (e.g., tank mix composition).
Preferred abamectin-containing compositions are aqueous suspension concentrates, emulsifiable concentrates and emulsion in water, particularly preferred are suspension concentrates.
In general, the pre-mix compositions of the invention contain 0.5 to 99.9 especially 1 to 95, advantageously 1 to 50 , %, by mass of active ingredient compounds, and 99.5 to 0.1 , especially 99 to 5, %, by mass of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries (or adjuvant) can be a surfactant in an amount of 0 to 50, especially 0.5 to 40, %, by mass based on the mass of the pre-mix formulation.
The Examples which follow serve to illustrate the invention and are not intended to limit the invention.
Flowable concentrate for seed treatment
active ingredients 40 %
propylene glycol 5 % copolymer butanol PO/EO 2 %
Tristyrenephenole with 10-20 moles EO 2 %
1 ,2-benzisothiazolin-3-one (in the form of a 20% solution in water) 0.5 %
monoazo-pigment calcium salt 5 %
Silicone oil (in the form of a 75 % emulsion in water) 0.2 %
Water 45.3 %
The finely ground combination is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water. Using such dilutions, living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion.
The active ingredient composition of the present invention is distinguished by the fact that they are especially well tolerated by plants and are environmentally friendly.
In each aspect and embodiment of the invention, "consisting essentially" and inflections thereof are a preferred embodiment of "comprising" and its inflections, and "consisting of" and inflections thereof are a preferred embodiment of "consisting essentially of" and its inflections.
Use of a term in a singular form also encompasses that term in plural form and vice a versa.
The abamectin containing composition is for use in the agrochemical industry. A description of the abamectin and other agents (e.g., fungicides, insecticides, nematicides, plant growth regulators) can be found in the e-Pesticide Manual, version 3.1 , 13th Edition, Ed. CDC Tomlin, British Crop Protection Council, 2004-05.
Example 1 : Elasmopalpus control by Abamectin seed treatment in corn
Large plot trials where placed at 13 locations. All seeds, including the check, were treated with a basic fungicide treatment (Fludioxonil, Mefenoxam and Thiabendazole at rates of 0.2, 0.17 & 1 .25, grams AI/100 kg of seeds, respectively). Table 1 lists the treatment list and rates applied for the design. For each treatment four repeated samples were taken.
Table 1 : Treatment list No grams Al /100 kg
1 Check
2 Abamectin 67.7
3 Abamectin 83.3
4 CROPSTAR® (Imidacloprid & Thiodicarb) 75+225
The efficacy of the different seed treatment products were assessed 7 and 14 days after emergence based on stand. Furthermore yield differences at harvest were also assessed. The results are set forth in Tables 2 & 3.
Table 2: Control of Elasmopalpus attack in corn (average of 13 trials with high infestation).
Table 3: Yield effect of Elasmopalpus control in corn treated with Avicta and difference to the standard CROPSTAR® treatment in %.
Example 2: Elasmopalpus control by Abamectin seed treatment in soy
Large plot trials were placed at 2 locations under natural infestation pressure. All seeds, including the check, were treated with a basic fungicide treatment (Fludioxonil and
Mefenoxam at rates of 2.5 & 1.0, grams AI/100 kg of seeds, respectively). Table 4 lists the treatment list and rates applied for the design. Four repetitions where done per treatment.
Table 4: Treatment list
4 Thiamethoxam 35
5 STANDAK 250 SC (Fipronil) 50
The efficacy of the different seed treatment products were assessed based on stand after 28DAE: the results are tabulated in Tables 5 & 6. Table 5: Location 1 : Stand loss and control %
Table 6: Location 2: Stand loss and control %
Treatment Stand loss (average of four repeats) Control, %
1 21.4 0
2 9.8 54
3 13.5 37
4 18.8 12
5 16.3 24

Claims

1 . A method of protecting a plant propagation material and a plant, part of a plant and/or plant organ that grows at a later point in time against damage by Elasmopalpus which comprises applying to the plant propagation material a composition comprising abamectin.
2. A method of controlling or preventing damage by Elasmopalpus to a plant propagation material, a plant, a part of a plant and/or a plant organ that grows at a later point in time, which comprises applying a composition comprising abamectin to the plant propagation material.
3. A method of improving the growing characterictics of a plant generated from a plant propagation material, which comprises applying a composition comprising abamectin to the plant propagation material.
4. A method according to any one of claims 1 to 3 wherein the composition comprising abamectin is applied to the plant propagation material before plant propagation material is sown or planted.
5. A method according to any one of claims 1 to 4 wherein the composition further comprises at least one other agent having pest control characteristics.
6. A method according to claim 5 wherein the at least one agent is at least one pesticide.
7. A method according to claim 6 wherein the at least one pesticide is selected from azoxystrobin, trifloxystrobin, fluoxastrobin, cyproconazole, difenoconazole, prothioconazole, tebuconazole, triticonazole, fludioxonil, thiabendazole, ipconazole, cyprodinil, myclobutanil, metalaxyl, metalaxyl-M (also known as mefenoxam), ortho-cyclopropyl-carboxanilide of formula (a), compound of formula (β), thiamethoxam, clothianidin, imidacloprid, abamectin, fipronil, pymetrozine, lambda-cyhalothrin, tefluthrin, beta-cyfluthrin, thiodicarb, compound of formula (δ), wherein compound (a) is
8. A method according to claim 7 wherein the at least one pesticide is selected from azoxystrobin, fludioxonil, thiabendazole, metalaxyl, metalaxyl-M (also known as mefenoxam), ortho-cyclopropyl-carboxanilide of formula (a), thiamethoxam, clothianidin, imidacloprid, fipronil, pymetrozine, thiodicarb and lambda-cyhalothrin.
EP10754925A 2009-09-21 2010-09-16 Control of elasmopalpus Withdrawn EP2480087A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP10754925A EP2480087A2 (en) 2009-09-21 2010-09-16 Control of elasmopalpus

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09170869 2009-09-21
PCT/EP2010/063648 WO2011033041A2 (en) 2009-09-21 2010-09-16 Control of elasmopalpus
EP10754925A EP2480087A2 (en) 2009-09-21 2010-09-16 Control of elasmopalpus

Publications (1)

Publication Number Publication Date
EP2480087A2 true EP2480087A2 (en) 2012-08-01

Family

ID=43477911

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10754925A Withdrawn EP2480087A2 (en) 2009-09-21 2010-09-16 Control of elasmopalpus

Country Status (8)

Country Link
EP (1) EP2480087A2 (en)
AR (1) AR078398A1 (en)
BR (1) BR112012006266A2 (en)
CA (1) CA2771173A1 (en)
CL (1) CL2012000677A1 (en)
MX (1) MX2012003089A (en)
UY (1) UY32897A (en)
WO (1) WO2011033041A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102342285B (en) * 2011-11-11 2014-06-11 联保作物科技有限公司 Sterilization disease-resistant composition and suspension seed coating agent thereof
WO2018055022A1 (en) * 2016-09-22 2018-03-29 Syngenta Participations Ag Pesticidal mixtures
CN109601546A (en) * 2018-12-29 2019-04-12 广东真格生物科技有限公司 A kind of composition pesticide and its application containing thiodicarb

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR8600161A (en) 1985-01-18 1986-09-23 Plant Genetic Systems Nv CHEMICAL GENE, HYBRID, INTERMEDIATE PLASMIDIO VECTORS, PROCESS TO CONTROL INSECTS IN AGRICULTURE OR HORTICULTURE, INSECTICIDE COMPOSITION, PROCESS TO TRANSFORM PLANT CELLS TO EXPRESS A PLANTINIDE TOXIN, PRODUCED BY CULTURES, UNITED BY BACILLA
EP0374753A3 (en) 1988-12-19 1991-05-29 American Cyanamid Company Insecticidal toxines, genes coding therefor, antibodies binding them, transgenic plant cells and plants expressing these toxines
EP0427529B1 (en) 1989-11-07 1995-04-19 Pioneer Hi-Bred International, Inc. Larvicidal lectins and plant insect resistance based thereon
UA48104C2 (en) 1991-10-04 2002-08-15 Новартіс Аг Dna fragment including sequence that codes an insecticide protein with optimization for corn, dna fragment providing directed preferable for the stem core expression of the structural gene of the plant related to it, dna fragment providing specific for the pollen expression of related to it structural gene in the plant, recombinant dna molecule, method for obtaining a coding sequence of the insecticide protein optimized for corn, method of corn plants protection at least against one pest insect
US5530195A (en) 1994-06-10 1996-06-25 Ciba-Geigy Corporation Bacillus thuringiensis gene encoding a toxin active against insects
NL1004759C2 (en) 1996-12-12 1998-06-15 Plantenkwekerij G N M Grootsch Method for growing a plant using a cultivation block, cultivation block and apparatus for treating such blocks.
NL1012918C2 (en) 1999-08-26 2001-02-27 Incotec Internat B V Method for protecting seed to be germinated and pesticide-containing pill.
US20060150489A1 (en) 1999-08-26 2006-07-13 Legro Robert J Protection of germinating seed and pills containing pesticides
GB0412974D0 (en) 2004-06-10 2004-07-14 Syngenta Participations Ag Method of applying active ingredients
NL1028815C2 (en) 2005-04-19 2006-10-20 Grow Beheer B V Planting plant material.
AR056077A1 (en) * 2005-09-19 2007-09-19 Syngenta Participations Ag IMPROVED METHODS FOR THE CONTROL OF EARTH PESTS AND / OR DISEASES EMERGED FROM THE EARTH
EP1795071A1 (en) 2005-12-07 2007-06-13 Incotec International B.V. Modified active-ingredient-containing pellets/capsules

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2011033041A2 *

Also Published As

Publication number Publication date
CA2771173A1 (en) 2011-03-24
WO2011033041A3 (en) 2011-11-10
BR112012006266A2 (en) 2015-09-08
AR078398A1 (en) 2011-11-02
CL2012000677A1 (en) 2012-10-12
WO2011033041A2 (en) 2011-03-24
UY32897A (en) 2010-12-31
MX2012003089A (en) 2012-04-19

Similar Documents

Publication Publication Date Title
US8124565B2 (en) Method of protecting a plant propagation material, a plant, and/or plant organs
EP2100509B1 (en) Method of controlling pathogenic and/or pest damage in plants using a thiabendazole/abamectin containing composition
US20110319262A1 (en) Pesticidal combinations containing sulfoxaflor
US20100029479A1 (en) Pesticidal combinations
US20110263429A1 (en) Pesticidal Combinations
EP2028939A2 (en) Pesticidal combinations comprising flutriafol
US8598130B2 (en) Insecticidal combinations
EP2077720B1 (en) Pesticidal compositions comprising an azole, a phenylamide and azoxystrobin
WO2011033041A2 (en) Control of elasmopalpus
WO2007141010A1 (en) A method of protecting a plant propagation material, a plant, parts of a plant and/or plant organs
EP2020853A1 (en) Pesticidal combinations

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20120315

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20121108