EP2464329A2 - Compounds for hair care comprising rambutan oil - Google Patents

Abstract

The invention relates to cosmetic agents containing rambutan oil and surfactants in a cosmetic carrier and additional active ingredients, selected in particular from cationic polymers and casein.

Description

 "Hair Care Compositions Containing Rambutan Oil"

The invention relates to compositions for hair care containing rambutan oil. Particular compositions for hair care contain in addition to rambutan oil other active ingredients such as cationic polymers and / or proteins.

 The cosmetic treatment of keratinic fibers, especially of human hair, is an important part of human body care. For example, human hair is today treated in a variety of ways with hair cosmetic preparations.

 However, the known active ingredients can not cover all needs sufficiently. There is therefore still a need for active ingredients or combinations of active substances for cosmetic products with good care properties and good biodegradability. Furthermore, the compatibility of the cosmetic compositions is an extremely important criterion.

 Detergents for skin and hair not only have to have a good cleansing power, but should continue to be well tolerated by the skin and mucous membranes and not lead to excessive defatting or skin dryness even with frequent use. In addition, modern compositions are expected to have a significantly improved condition of the skin relative to the moisture balance of the dry skin. The wetting of skin and hair with impurities should be significantly delayed.

 The feeling of skin and hair after cosmetic treatments is an essential criterion, whether the appropriate composition is perceived by the consumer as pleasant. The sensor technology and in particular the feel of a composition are thus essential effects that the consumer can experience. We are therefore looking for precisely those compositions which not only care for the skin and hair but also, through their sensory and haptic properties in particular, noticeably and tangibly change the surface of the skin and hair.

 Natural oils, such as soybean oil or almond oil, are difficult to incorporate in surface-active agents. If, on the other hand, their ethoxylates, for example ethoxylated soybean oil, are used, sufficient conditioning, insufficient combability of the wet and dry fibers, too low gloss is achieved. Furthermore, for example, almond oil or paraffin oil can not be incorporated into the formulations in a stable manner.

 The object of the present invention is to significantly improve the conditioning properties and the gloss of keratinic fibers in the application of surfactant agents and also to give them additionally sensory, especially tactile effects.

 It has surprisingly been found that rambutan oil is outstandingly suitable for this purpose.

 A first subject of the present invention is therefore a composition for the treatment of keratinic fibers, in particular human hair, containing

a) at least 0.01 to 10.0 wt.% Rambutanöl and b) at least one anionic, amphoteric, cationic or nonionic

Surfactant and

 c) an aqueous carrier.

 Furthermore, the compositions according to the invention comprising the active substance complex according to the invention are distinguished by a significantly improved state of the keratinic fibers with respect to the moisture balance of the keratinic fibers. Finally, it has surprisingly been found that the compositions according to the invention lead to a significantly delayed re-soiling of the keratinic fibers.

 Ingredients a) and b) are described in detail below. As far as the following from

Active ingredient complex (A) is spoken, this statement refers to the ingredients contained in the inventive compositions a) and b).

 Hair treatment compositions according to the present invention are, for example, hair shampoos,

Hair conditioners, conditioning shampoos, hair conditioners, hair conditioners, hair wraps,

Hair tonics, hair dye shampoos or their combinations.

 By combing is understood according to the invention both the combability of the wet fiber, as well as the combability of the dry fiber.

 As a handle defines the tactility of a fiber collective, the expert sensory the

Parameter abundance and suppleness of the collective feels and evaluates.

 Shaping is understood to mean the ability to give a shape change to a group of previously treated keratin-containing fibers, in particular human hair. Hair cosmetics also speak of hair styling.

 Suitable cosmetic vehicles according to the invention are in particular O / W, W / O and W / O / W.

Emulsions in the form of creams or gels or surfactant-containing foaming solutions, such as shampoos, foam aerosols or other preparations, in particular for the

Application on the hair are suitable. The cosmetic carriers may in particular be aqueous or aqueous-alcoholic.

 An aqueous cosmetic carrier contains at least 50% by weight of water.

For the purposes of the present invention, aqueous-alcoholic cosmetic carriers include aqueous solutions containing from 3 to 70% by weight of a C ₁ -C ₆ -alcohol, in particular methanol,

Ethanol or propanol, isopropanol, butanol, isobutanol, tert-butanol, n-pentanol, iso-pentanols, n-hexanol, isohexanols, glycol, glycerol, 1, 2-pentanediol, 1, 5-pentanediol, 1, 2-hexanediol or

1, 6-hexanediol to understand. The agents according to the invention may additionally contain further organic

Solvents, such as, for example, methoxybutanol, benzyl alcohol, ethyl diglycol or 1, 2

Propylene glycol, included. Preference is given to all water-soluble organic solvents.

As ingredient a) the compositions according to the invention contain at least 0.01 to 10% by weight, preferably 0.01 to 7.5% by weight and in particular 0.01 to 5.0% by weight of rambutan oil.

Rambutan oil is a natural oil. Rambutan is also known as Nepelium Lappaceum and with

Lychee related. Like lychee, rambutan is found mainly in Southeast Asia. The

Rambutan oil is in the compositions of the invention in an amount based on the

Total composition of 0.01 to 10 wt.%. preferably from 0.01 to 7.5% by weight, in particular from 0.1 to 5.0% by weight. Surfactants are used as ingredient b), with both anionic and zwitterionic, ampholytic, nonionic and cationic surfactants being suitable in principle. The selection depends on the type of product. In the case of a shampoo, in particular at least one surfactant is selected from the group of anionic, zwitterionic or nonionic surface-active substances. It is preferred here that at least one anionic and at least one zwitterionic surface-active substance is chosen. These surface-active substances are particularly preferably selected from the group of particularly mild surface-active substances. The ratio between anionic and zwitterionic surface-active substances is between 10: 1 and 1: 5. The ratio is particularly preferably 5: 1 to 1: 2.

 Suitable anionic surfactants (tanion) in preparations according to the invention are all anionic surfactants suitable for use on the human body. Typical examples of anionic surfactants are:

 linear and branched fatty acids with 8 to 30 carbon atoms (soaps),

Ethercarbonsäuren the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear alkyl group having 8 to 30 carbon atoms and x = 0 or 1 to 16 and their salts,

 Acylsarcosides having 8 to 24 carbon atoms in the acyl group,

 Acyltaurides having 8 to 24 carbon atoms in the acyl group,

 Acyl isethionates having 8 to 24 carbon atoms in the acyl group,

 Sulfobernsteinsäuremono- and dialkyl esters having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethylester having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups.

 linear alkanesulfonates having 8 to 24 C atoms,

 linear alpha-olefin sulfonates having 8 to 24 C atoms,

 Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms,

- Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ H, in which R is a preferably linear alkyl group having 8 to 30 carbon atoms and x = 0 or 1 to 12, hydroxysulfonates substantially corresponding to at least one of the following two formulas or mixtures thereof and salts thereof,

CH ₃ - (CH ₂ ) _y -CHOH- (CH ₂ ) _p - (CH-SO ₃ M) - (CH ₂ ) _z -CH ₂ -O- (C _n H _2n O) _x -H, and / or

CH ₃ - (CH ₂ ) _y - (CH-SO ₃ M) - (CH ₂ ) _p -CHOH- (CH ₂ ) _z - CH ₂ -O- (C _n H _2n O) _x -H where in both formulas y and z = 0 or integers from 1 to 18, p = 0, 1 or 2 and the sum (y + z + p) a number from 12 to 18, x = 0 or a number from 1 to 30 and n one integer from 2 to 4 and M = H or alkali metal, in particular sodium, potassium, lithium, alkaline earth metal, in particular magnesium, calcium, zinc and / or an ammonium ion, which may optionally be substituted, in particular mono-, di-, tri or tetraammonium ions having C1 to C4 alkyl, alkenyl or aryl radicals,

sulfated hydroxyalkylpolyethylene and / or hydroxyalkylene glycol ethers of the formula R ¹ - (CHOSO ₃ M) -CHR ³ - (OCHR ⁴ -CH ₂ ) n-OR ² with R ¹ , a linear alkyl radical having 1 to 24 C atoms, R ² for a linear or branched, saturated alkyl radical having 1 to 24 C atoms, R ^{3 is} hydrogen or a linear alkyl radical having 1 to 24 C atoms, R ^{4 is} hydrogen or a methyl radical and M is hydrogen, ammonium, alkylammonium, alkanolammonium, in which the alkyl and alkanol radicals each have 1 to 4 C atoms, or a metal atom selected from lithium, sodium, potassium, calcium or magnesium and n is a number in the range of 0 to 12 and furthermore the total number of C atoms contained in R ¹ and R ^{3 is} 2 to 44,

 Sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds, esters of tartaric acid and citric acid with alcohols which are adducts of about 2 to 15 molecules of ethylene oxide and / or propylene oxide onto fatty alcohols having 8 to 22 carbon atoms,

 Alkyl and / or alkenyl ether phosphates of the formula

R ¹ (OCH ₂ CH ₂ ) _n -O- (PO-OX) -OR ² ,

in the R ^{1 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{2 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ² or X, n is from 1 to 10 and X is hydrogen, an alkali metal radical or alkaline earth metal or NR ³ R ⁴ R ⁵ R ⁶ , where R ³ to R ⁶ independently of one another represent hydrogen or a C ¹ to C ₄ hydrocarbon radical,

sulfated fatty acid alkylene glycol esters of the formula RCO (AlkO) _n SO ₃ M

in the RCO-- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, Alk for CH ₂ CH ₂ , CHCH ₃ CH ₂ and / or CH ₂ CHCH ₃ , n for numbers of 0 , 5 to 5 and M is a metal such as alkali metal, in particular sodium, potassium, lithium, alkaline earth metal, in particular magnesium, calcium, zinc, or ammonium ion, such as ⁺ NR ³ R ⁴ R ⁵ R ⁶ , with R ³ to R ⁶ independently of one another represent hydrogen or a C1 to C4 hydrocarbon radical,

 Monoglyceride sulfates and monoglyceride ether sulfates of the formula

R ⁸ OC- (OCH ₂ CH ₂ ) _x -OCH ₂ - [CHO (CH ₂ CH ₂ O) _y H] -CH ₂ O (CH ₂ CH ₂ O) _z -SO ₃ X,

in which R ⁸ CO is a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10, and X is an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Preferably monoglyceride sulfates are used, in which R ⁸ CO is a linear acyl radical having 8 to 18 carbon atoms,

Amide ether carboxylic acids, R ¹ -CO-NR ² -CH ₂ CH ₂ -O- (CH ₂ CH ₂ O) _n CH ₂ COOM, with R ¹ as the straight-chain or branched alkyl or alkenyl radical having a number of carbon atoms in the chain of 2 to 30, n is an integer from 1 to 20, and R ² is hydrogen, methyl, ethyl, propyl, isopropyl, n-butyl, t-butyl or iso-butyl, and M is Hydrogen or a metal such as alkali metal, in particular sodium, potassium, lithium, alkaline earth metal, in particular magnesium, calcium, zinc, or an ammonium ion, such as ⁺ NR ³ R ⁴ R ⁵ R ⁶ , where R ³ to R ⁶ are each independently hydrogen or a C1 to C4 hydrocarbon radical. Such products are available, for example, by the company Chem Y under the product Akypo ^®.

 Acylglutamates of the formula XOOC-CH 2 CH 2 CH (C (NH) OR) -COOX in which RCO is a linear or branched acyl radical having 6 to 22 carbon atoms and 0 and / or 1, 2 or 3 double bonds and X is hydrogen, an alkali metal and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium,

Condensation products of a water-soluble salt of a water-soluble protein hydrolyzate with a C8-C30 fatty acid. Such products are available under the trademark Lamepon® ^®, Maypon ^®, Gluadin® ^®, Hostapon® ^® KCG or Amisoft ^® long been commercially.

 Alkyl and / or alkenyl oligoglycoside carboxylates, sulfates, phosphates and / or isethionates, acyl lactylates and

 Hydroxymischethersulfate.

If the mild anionic surfactants contain polyglycol ether chains, it is particularly preferred that they have a narrow homolog distribution. Further, in the case of mild anionic surfactants having polyglycol ether units, it is preferable that the number of glycol ether groups is 1 to 20, preferably 2 to 15, more preferably 2 to 12. Particularly mild anionic surfactants having polyglycol ether groups with no restricted homolog distribution can be obtained, for example on the one hand the number of polyglycol ether groups is 4 to 12 and Zn or Mg ions are selected as the counterion. One example is the commercial product Texapon.RTM ^® ASV.

 Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyl dimethylammonium glycinate, N-acylaminopropyl N, N-dimethylammonium glycinates, for example cocoacylaminopropyl dimethylammonium glycinate, and 2-alkyl 3-carboxymethyl-3-hydroxyethyl-imidazolines having in each case 8 to 18 C atoms in the alkyl or acyl group, and also the cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.

Ampholytic surfactants (Tampho) are understood as meaning those surface-active compounds which are capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkylimino-dipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C atoms in the alkyl group. Typical examples of amphoteric or zwitterionic surfactants are alkylbetaines, alkylamidobetaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ -C ₁₈ -acylsarcosine.

Nonionic surfactants (Tnio) are for example Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 6 to 30 carbon atoms, the fatty alcohol polyglycol ethers or the Fettalkoholpolypropylenglykolether or mixed fatty alcohol polyethers,

Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty acids having 6 to 30 carbon atoms, the fatty acid polyglycol ethers or the Fettsäurepolypropylenglykolether or mixed fatty acid polyethers,

Addition products of 2 to 50 mol of ethylene oxide and / or 0 to 5 mol of propylene oxide onto linear and branched alkylphenols having 8 to 15 C atoms in the alkyl group, the alkylphenol polyglycol ethers or the alkylpolypropylene glycol ethers, or mixed alkylpolyolpolyethers,

with a methyl or C ₂ - C ₆ - alkyl radical end-capped addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and with alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as those available under the trade names Dehydol ^® LS, LT Dehydol ^® types (Cognis),

C ₁₂ -C ₃ o-fatty acid mono- and diesters of addition products of 1 to 30 mol ethylene oxide onto glycerol,

Addition products of 5 to 60 mol ethylene oxide onto castor oil and hydrogenated castor oil, polyol fatty acid esters, such as the commercially available product ^® Hydagen HSP (Cognis) or Sovermol ^® - types (Cognis),

alkoxylated triglycerides,

alkoxylated fatty acid alkyl esters of the formula (Tnio-1)

R ¹ CO- (OCH ₂ CHR ² ) _W OR ³ (Tnio-1)

in the R ¹ CO is a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{2 is} hydrogen or methyl, R ^{3 is a} linear or branched alkyl radical having 1 to 4 carbon atoms and w is a number from 1 to 20 stands, amine oxides,

Hydroxy mixed ethers, R ¹ O [CH ₂ CH (CH ₃ ) O] _x (CH ₂ CHR ² O) _y [CH ₂ CH (OH) R ³ ] _z with R ^{1 being} a linear or branched, saturated or unsaturated alkyl and / or alkenyl radical having 2 to 30 C atoms, R ^{2 is} hydrogen, a methyl, ethyl, propyl or iso-propyl radical, R ^{3 is} a linear or branched alkyl radical having 2 to 30 C atoms, x standing for 0 or a number from 1 to 20, Y for a number from 1 to 30 and z standing for the number 1, 2, 3, 4 or 5.

 Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as the polysorbates,

 Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters, addition products of ethylene oxide onto fatty acid alkanolamides and fatty amines,

Sugar surfactants of the alkyl and alkenyl oligoglycoside type,

Sugar surfactants of the fatty acid N-alkyl polyhydroxyalkylamide type,

Fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, Mixed ethers or mixed formals and polysorbates.

 Further, as the cationic surfactant, at least one quaternary imidazoline compound, i. a compound having a positively charged imidazoline ring. The formula I shown below shows the structure of these compounds.

 Formula I

The radicals R and R1 are each independently a saturated or unsaturated, linear or branched hydrocarbon radical having a chain length of 8 to 30 carbon atoms. The preferred compounds of the formula I contain for R and R1 in each case the same hydrocarbon radical. The chain length of the radicals R and R1 is preferably 12 carbon atoms. Particular preference is given to compounds having a chain length of at least 16 carbon atoms and very particularly preferably having at least 20 carbon atoms. A most preferred compound of formula I has a chain length of 21 carbon atoms. A product of this chain length is, for example, under the name quaternium-91 or trade names Crodazosoft ^® DBQ which, in addition quaternium-91 further includes Cetrimonium Methosulfate and Cetearyl Alcohol, and Crodazosoft ^® SCQ which, in addition quaternium-91 further including the PPG-3 benzyl ether myristate , known. Suitable counterions are all physiologically compatible counterions, for example methosulfates, halides such as chloride, fluoride, bromide, or even phosphates. Examples according to the invention are available, for example, under the INCII names Quaternium-27, Quaternium-72, Quaternium-83 and Quaternium-91. On bevorzugtesten the commercial products Crodazosoft ^® DBQ and Crodazosoft ^® SCQ be, or quaternium-91, is used.

 The imidazolines of the formula I are present in the compositions according to the invention in amounts of from 0.01 to 20% by weight, preferably in amounts of from 0.05 to 10% by weight and very particularly preferably in amounts of from 0.1 to 7.5% by weight. % contain. The very best results are obtained with amounts of from 0.1 to 5% by weight, based in each case on the total composition of the particular agent.

Furthermore, the following cationic surfactants according to the formula (Tkat-2) can be used. RCO-XN ⁺ R ¹ R ² R ³ A ^" (Tkat-2)

 R here stands for a substituted or unsubstituted, branched or straight-chain alkyl or alkenyl radical having 11 to 35 carbon atoms in the chain,

X is - O - or - NR ⁵ -,

R ¹ represents an alkylene group having 2 to 6 C atoms, which may be unsubstituted or substituted, in which case substitution with an -OH or -NH group is preferred in the case of a substitution, R ² , R ³ each independently represents an alkyl or hydroxyalkyl group of 1 up to

6 C - atoms in the chain, where the chain can be rectilinear or branched.

 R5 is hydrogen or a C1 to C6 straight or branched alkyl or

Alkenyl radical, which may also be substituted by a hydroxy group.

 Within this structural class, the compounds are preferably one of the following

Structures used:

CH ₃ (CH _{2) 2} OCONH (CH _{2) 3} - N ⁺ (CHs) ₂ -CH ₂ CH ₃ A ^"(Tkat-3)

CH ₃ (CH ₂ ) ₂₀ CONH (CH ₂ ) ₃ - N ⁺ (CH ₃ ) ₂ -CH ₂ (CHOH) CH ₂ OH A ^" (Tkat-4)

CH ₃ (CH 2) ₂₀ COOCH ₂ CHOHCH ₂ - N ⁺ (CH ₃ ) ₃ A ^" (Tkat-5)

CH ₃ (CH ₂ ) ₂₀ CONH (CH ₂ ) ₃ - N ⁺ (CH ₃ ) ₂ -CH ₂ CH ₂ OH A ^" (Tkat-6)

Examples of such commercial products are Schercoquat BAS, Lexquat AMG-BEO, Akypoquat

131 or Incroquat Behenyl HE.

 Furthermore, esterquats according to the formula (Tkat1-2) can be used.

R2

I ₊

 R1 - -N- A- R4 Q

 R3

 (Tkat1-2)

 Here, the radicals R1, R2 and R3 are each independently and may be the same or different. The radicals R1, R2 and R3 mean:

 a branched or unbranched alkyl radical having 1 to 4 carbon atoms, which may contain at least one hydroxyl group, or

 a saturated or unsaturated, branched or unbranched or a cyclic saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, which may contain at least one hydroxyl group, or

 an aryl or alkaryl radical, for example phenyl or benzyl,

 the rest (- A - R4), with the proviso that at most 2 of the radicals R1, R2 or R3 can stand for this radical:

 The remainder - (A - R4) is contained at least 1 to 3 times.

Herein A stands for:

 1) - (CH 2) n - with n = 1 to 20, preferably n = 1 to 10 and particularly preferably n = 1 - 5, or

 2) - (CH 2 -CHR 5 -O) n - where n = 1 to 200, preferably 1 to 100, particularly preferably 1 to 50, and particularly preferably 1 to 20 with R 5 in the meaning of hydrogen, methyl or ethyl,

and R4 stands for:

1) R 6 -O-CO-, wherein R 6 is a saturated or unsaturated, branched or unbranched or cyclic saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, which may contain at least one hydroxy group, and which optionally further with 1 to 100 ethylene oxide units and or 1 to 100 propylene oxide units may be ethoxylated, or 2) R7-C0-, wherein R7 is a saturated or unsaturated, branched or unbranched or cyclic saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, which may contain at least one hydroxy group, and which optionally further with 1 to 100 ethylene oxide units and / or 1 to 100 propylene oxide units can be ethoxylated,

and Q is a physiologically acceptable organic or inorganic anion.

Such products are marketed under the trademarks Rewoquat ^®, Stepantex® ^{®, ®} and Dehyquart® Armocare® ^®. The products Armocare ^® VGH-70, a N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75, Dehyquart ^® C-4046, Dehyquart ^® L80, Dehyquart ^® F-30, Dehyquart ^® AU 35, Rewoquat ^® WE18, Rewoquat WE38 ^® DPG and Stepantex ^® VS 90 are examples of such esterquats.

Further compounds of the formula (Tkat1-2) which are particularly preferred according to the invention belong to the formula (Tkat1-2.1), the cationic betaine esters. )

 R8 corresponds in its meaning R7.

 As a further ingredient Monoalkyltrimethylammoniumsalze with a chain length of the

Alkyl radicals of 16 to 24 carbon atoms may be included.

 These compounds have the structure shown in the formula (Tkat1-1)

R1

I ₊

 R4-N-R2

 R3

 (TkatM)

 Wherein R1, R2 and R3 are each a methyl group and R4 is a saturated, branched or unbranched alkyl radical having a chain length of 16 to 24 carbon atoms. Examples of compounds of the formula (Tkat1-1) are cetyltrimethylammonium chloride, cetyltrimethylammonium bromide, cetyltrimethylammonium methosulfate,

Stearyltrimethylammonium chloride, behenyltrimethylammonium chloride,

Behenyltrimethylammonium bromide and behenyltrimethylammonium methosulfate.

In a particularly preferred embodiment of the invention, the compositions according to the invention furthermore comprise at least one amine and / or cationized amine, in particular an amidoamine and / or a cationized amidoamine having the following structural formulas:

R ¹ --NH - (CH ₂ ) _n --NR ² R ³ (Tkat7) and / or

R ¹ --NH - (CH ₂ ) _n --NR ² R ³ R ⁴ (Tkatδ)

wherein R 1 is an acyl or alkyl radical having 6 to 30 C atoms, which may be branched or unbranched, saturated or unsaturated, and wherein the acyl radical and / or the alkyl radical may contain at least one OH group, and R 2, R 3 and R 4 are each, independently of one another, hydrogen or an alkyl radical having 1 to 4 C

Atoms which may be the same or different, saturated or unsaturated, and

X ^" an anion and

n is an integer between 1 and 10.

 Preference is given to a composition in which the amine and / or the quaternized amine according to general formulas (Tkat7) and / or (Tkatδ) is an amidoamine and / or a quaternized amidoamine, in which R1 is a branched or unbranched, saturated or unsaturated acyl radical with 6 to 30 carbon atoms, which may contain at least one OH group means. Preference is given in this case to a fatty acid radical of oils and waxes, in particular of natural oils and waxes. Examples of these include lanolin, bees or candellila waxes.

Also preferred are those amidoamines and / or quaternized amidoamines in which R 2, R 3 and / or R 4 in formulas (Tkat7) and / or (Tkatδ) represent a radical according to the general formula CH ₂ CH ₂ OR 5, where R 5 is the meaning of alkyl radicals having 1 to 4 carbon atoms, hydroxyethyl or hydrogen. The preferred size of n in the general formulas (Tkat7) and / or (Tkatδ) is an integer between 2 and 5.

Also preferred are amidoamines and / or quaternized amidoamines of the general formulas (Tkat7) and / or (Tkatδ) in which the anion X ^"is a halide ion or a compound of the general formula RSO ₃ ^" , where R is the meaning of saturated or unsaturated alkyl radicals having 1 to 4 carbon atoms.

The alkyl radical having 1 to 4 carbon atoms of R 2, R 3 and R 4 and / or the alkyl radical having 1 to 4 carbon atoms of RSO ₃ ^" in the general formula (Tkat7) and / or (Tkatδ) may contain at least one hydroxyl group.

 The alkylamidoamines can both be present as such and converted by protonation in a correspondingly acidic solution into a quaternary compound in the composition. According to the invention, the cationic alkylamidoamines are preferred.

Suitable amidoamines to be used according to the invention, which may optionally be quaternized, are, for example, amidoamines: Witcamine 100 (Witco, INCI name: Cocamidopropyl Dimethylamine), Incromine BB (Croda, INCI name: behenamidopropyl dimethylamine), Mackin 401 (McIntyre, INCI name: isostearylamidopropyl dimethylamine) and other Mackine types, Adogen S1 δV (Witco, INCI name: Stearylamidopropyl Dimethylamine), and as permanent cationic aminoamines: Rewoquat RTM 50 (Witco Surfactants GmbH, INCI name: Ricinoleamidopropyltrimonium Methosulfate), Empigen CSC (Albright & Wilson, INCI name: Cocamidopropyltrimonium chloride), Swanol Lanoquat DES-50 (Nikko, INCI name: Quatemium-33), Rewoquat UTM 50 (Witco Surfactants GmbH, Undecyleneamidopropyltrimonium Methosulfate).

The anion of all cationic compounds is selected from the physiologically acceptable anions. Examples of these are the halide ions, fluoride, chloride, bromide, sulfate of the general formula RSO ₃ ^" , in which R has the meaning of saturated or unsaturated alkyl radicals having 1 to 4 carbon atoms, or anionic radicals of organic acids such as maleate, fumarate, oxalate, tartrate, Citrate, lactate or acetate, called. The aforementioned cationic surfactants can be used individually or in any combination with each other, wherein amounts between 0.01 to 20 wt.%, Preferably in amounts of 0.01 to 10 wt.% And most preferably in amounts of 0.1 to 7.5% by weight. The very best results are obtained with amounts of from 0.1 to 5% by weight, based in each case on the total composition of the particular agent.

The surfactants (T) are used in amounts of 0.05-45% by weight, preferably 0.1-30% by weight and very particularly preferably 0.5-25% by weight, based on the total agent used according to the invention ,

 Highly preferred compositions comprising the combination of active substances (A) according to the invention are characterized in that they furthermore comprise at least one native oil or at least one ester oil or at least one silicone oil or at least one polymer.

Ester oils are to be understood as meaning the esters of C ₆ - C ₃₀ fatty acids with C ₂ - C ₃₀ fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, Gadoleic acid, behenic acid and erucic acid and their technical mixtures. Examples of the fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. According to the invention, particularly preferred are isopropyl myristate (IPM Rilanit ^®), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), stearic acid-2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, Kokosfettalkohol- caprate / caprylate (Cetiol ^® LC), n-butyl stearate, oleyl erucate (Cetiol ^® J 600), isopropyl palmitate (IPP Rilanit ^®), oleyl Oleate (Cetiol ^®), lauric acid hexyl ester (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B), myristyl myristate (Cetiol ^® MM), Cetearyl Isononanoate (Cetiol ^® SN), decyl oleate (Cetiol ^® V).

Of course, the ester oils may also be alkoxylated with ethylene oxide, propylene oxide, or mixtures of ethylene oxide and propylene oxide. The alkoxylation can be found both on the fatty alcohol part and on the fatty acid part and on both parts of the ester oils. However, preference is given according to the invention if the fatty alcohol was first alkoxylated and then esterified with fatty acid. In the formula (D4-II), these compounds are generally shown.

 R 1 is a saturated or unsaturated, branched or unbranched, cyclic saturated cyclic unsaturated acyl radical having 6 to 30 carbon atoms,

AO is ethylene oxide, propylene oxide or butylene oxide, X is a number between 1 and 200, preferably 1 and 100, more preferably between 1 and 50, most preferably between 1 and 20, most preferably between 1 and 10 and most preferably between 1 and 5,

 R 2 represents a saturated or unsaturated, branched or unbranched cyclic saturated cyclic unsaturated alkyl, alkenyl, alkynyl, phenyl or benzyl radical having from 6 to 30 carbon atoms. Examples of fatty acid moieties used as radical R1 in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid , Gadoleic acid, behenic acid and erucic acid and their technical mixtures. Examples of the fatty alcohol moieties as radical R2 in the ester oils are benzyl alcohol, isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol , Elearstearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. A particularly preferred ester oil according to the invention is obtainable, for example, under the INCI name PPG-3 benzyl ether myristate. Furthermore, ester oils are to be understood as meaning:

 Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2- ethylhexanoate), propylene glycol diisostearate,

Propylene glycol di-pelargonate, butanediol diisostearate, neopentyl glycol, as well as symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, for example glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC),

 Trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol,

 Fatty acid partial glycerides, ie monoglycerides, diglycerides and their technical mixtures. Typical examples are mono- and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, Gadoleic acid, behenic acid and erucic acid and their technical mixtures. Preferably, oleic acid monoglycerides are used.

 The ester oils are present in the compositions according to the invention in an amount of from 0.01 to 20% by weight, preferably from 0.01 to 10.0% by weight, particularly preferably from 0.01 to 7.5% by weight, most preferably from 0, 1 to 5.0 wt.% Used. Of course, it is also possible according to the invention to use several ester oils at the same time.

Furthermore, natural oils can additionally be used with the active ingredient combination (A) according to the invention. The natural oils may also be waxy or solid at room temperature. Preferably, these oils, oil body, a melting point less than 50 ⁰ C, more preferably less than 45 ⁰ C, most preferably less than 40 ⁰ C, most preferably smaller than 35 ^° C and most preferably the cosmetic oils are at a temperature less than 30

⁰ C free-flowing. Under the natural oils according to the invention are also understood synthetic oils such as hydrocarbons. In the following, these oils are defined and described in more detail. For example, the oils according to the invention include:

 vegetable oils. Examples of such oils are sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, orange oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil. Also suitable, however, are other triglyceride oils such as the liquid portions of beef tallow as well as synthetic triglyceride oils.

liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether Di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl-n Undecyl ether and di-tert-butyl ether, di-iso-pentyl ether, di-3-ethyldecyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether. The compounds are available as commercial products 1, 3-di- (2-ethyl-hexyl) - cyclohexane (Cetiol ^® S), and di-n-octyl ether (Cetiol ^® OE) may be preferred.

 Natural oils include, for example, amaranth seed oil, apricot kernel oil, argan oil,

Avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, thistle oil, peanut oil,

Pomegranate seed oil, grapefruit seed oil, hemp oil, hazelnut oil, elderflower seed oil,

Currant seed oil, jojoba oil, cocoa butter, linseed oil, macadamia nut oil, corn oil, almond oil,

Marula oil, evening primrose oil, olive oil, palm oil, rapeseed oil, rice oil, sea buckthorn oil,

Buckthorn seed oil, sesame oil, shea butter, soybean oil, sunflower oil, grapeseed oil, walnut oil or

Wild rose oil according to the invention into consideration.

 The natural oils are present in the compositions according to the invention in an amount of from 0.01 to 20% by weight, preferably from 0.01 to 10.0% by weight, particularly preferably from 0.01 to 7.5% by weight, most preferably from 0 , 1 to 5.0 wt.% Used. Of course, it is also possible according to the invention to use several of the natural oils at the same time.

 As a further highly preferred ingredient for increasing the action of the active ingredient complex (A), the compositions according to the invention preferably contain at least one silicone polymer selected from the group of dimethiconols and / or the group of amino-functional silicones and / or the group of dimethicones and / or the group of cyclomethicones , These ingredients are described below.

 The dimethicones according to the invention can be both linear and branched as well as cyclic or cyclic and branched. Linear dimethicones can be represented by the following structural formula (Sil):

(SiR ¹ ₃ ) - O - (SiR ² ₂ - O -) _x - (SiR ¹ ₃ ) (Sil)

Branched dimethicones can be represented by the structural formula (SM .1): )

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. The numbers x, y and z are integers and each run independently from 0 to 50,000. The molecular weights of Dimethicone lie between 1,000 D and 10000000 D. The viscosities are between 100 and 10,000,000 cPs measured at 25 ⁰ C by means of a glass capillary viscometer according to Dow Corning Corporate Test Method CTM 0004 dated 20 July 1970. Preferred viscosities are 1000-5000000 cPs, most preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps. Most preferred are viscosities around the range of about 60,000 cps. As an example, please refer to the product "Dow Corning 200 with 6000OcSt".

 Particularly preferred cosmetic or dermatological preparations according to the invention are characterized in that they contain at least one silicone of the formula (Sil .2)

(CH ₃₎ 3 Si- [O-Si (CH3) 2] χ-O-Si (CH ₃₎ 3 (Sil .2)

in which x is a number from 0 to 100, preferably from 0 to 50, more preferably from 0 to 20 and in particular 0 to 10.

 The dimethicones (Sil) are present in the compositions according to the invention in amounts of from 0.01 to 10% by weight, preferably from 0.01 to 8% by weight, more preferably from 0.1 to 7.5% by weight and in particular from 0.1 to 5 wt.% Based on the total composition.

Particularly preferred agents according to the invention contain one or more amino-functional silicones. Such silicones may e.g. by the formula (Si-2)

M (R _a Q _b Si0 ₍₄ - _a - _b) , ₂ ) _x (R _c Si0 ₍₄ - _{c) / 2} ) _y M (Si-2)

Be described, taking in the above formula

R is a hydrocarbon or a hydrocarbon radical having from 1 to about 6

 Carbon atoms,

Q is a polar radical of the general formula -R ¹ HZ,

 wherein

R ^{1 is} a divalent linking group bonded to hydrogen and the radical Z composed of carbon and hydrogen atoms, carbon, hydrogen and oxygen atoms or carbon, hydrogen and nitrogen atoms, and

Z is an organic, amino-functional group containing at least one amino-functional group; a assumes values in the range of about 0 to about 2,

b takes values in the range of about 1 to about 3,

a + b is less than or equal to 3, and

c is a number in the range of about 1 to about 3, and

x is a number ranging from 1 to about 2,000, preferably from about 3 to about 50, and most preferably from about 3 to about 25, and

y is a number in the range of from about 20 to about 10,000, preferably from about 125 to about 10,000, and most preferably from about 150 to about 1,000, and M is a suitable silicone end group as known in the art, preferably trimethylsiloxy ,

Z is according to formula (Si-2) an organic, amino-functional radical containing at least one functional amino group. A possible formula for said Z is NH (CH ₂ ) _z NH ₂ , where z is an integer greater than or equal to 1. Another possible formula for said Z is -NH (CH ₂ ) _Z (CH ₂ ) _zz NH, wherein both z and zz independently of one another are an integer greater than or equal to 1, this structure comprising diamino ring structures, such as piperazinyl. Said Z is most preferably an -NHCH ₂ CH ₂ NH ₂ radical. Another possible formula for said Z is - N (CH ₂ ) _Z (CH ₂ ) _ZZ NX ₂ or -NX ₂ , wherein each X of X _{2 is} independently selected from the group consisting of hydrogen and alkyl groups of 1 to 12 carbon atoms, and zz is 0.

Q according to formula (Si-2) is most preferably a polar amino-functional radical of formula - CH ₂ CH ₂ CH ₂ NH ₂ CH ₂ CH ₂ NH ₂ .

 In the formula (Si-2), α assumes values in the range of 0 to 2, b takes values in the range of 2 to 3, a + b is less than or equal to 3, and c is a number in the range of 1 to 3. Suitable for the purposes of the invention are cationic silicone oils such as, for example, the commercially available products Dow Corning (DC) 929 emulsion, DC 2-2078, DC 5-7113, SM-2059 (General Electric) and SLM-55067 (Wacker).

 Particularly preferred agents according to the invention are characterized in that they contain at least one amino-functional silicone of the formula (Si 3-a)

(CH ₃₎ 3 Si- [O-Si (CH3) _2] n [O-Si (CH3)] _m OSi (CH ₃₎ 3 (Si-3a)

 I

CH ₂ CH (CH ₃ ) CH ₂ NH (CH ₂ ) ₂ NH ₂

in which m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values of 0 to 1999 and in particular of 49 to 149 and m preferably values of 1 to 2000 , in particular from 1 to 10 assumes.

These silicones are referred to as trimethylsilylamodimethicones according to the INCI declaration and are available, for example, under the name Q2-7224 (manufacturer: Dow Corning, a stabilized trimethylsilylamodimethicone).

Particular preference is also given to compositions according to the invention which contain at least one amino-functional silicone of the formula (Si-3b) R- [Si (CH _{3) 2} -O] _n1 [Si (R ') - O] _m - [Si (CH _{3) 2} -O] _n2 SiMe ₂ R (Si-3b),

 I

(CH ₂ ) ₃ NH (CH ₂ ) ₂ NH ₂

contain, in which

R is -OH, (optionally ethoxylated and / or propoxylated) (C ₁ to C ₂₀ ) -

Alkoxy group or a -CH ₃ group,

R 'is -OH, a (C ₁ to C ₂₀ ) alkoxy group or a -CH ₃ group and

m, n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2000, preferably between 50 and 150, the sum (n1 + n2) preferably having values from 0 to 1999 and in particular from 49 to 149 and m preferably assumes values of from 1 to 2000, in particular from 1 to 10.

 These silicones are according to the INCI declaration as Amodimethicone, or as functionalized Amodimethicone, such as bis (C13-15 alkoxy) PG Amodimethicone (for example, as a commercial product: DC 8500 from Dow Corning available), trideceth-9 PG-amodimethicones (for example as a commercial product Silcare Silicone SEA available from Clariant). Suitable diquaternary silicones are selected from compounds of the general formula (Si3c)

[R ¹ R ² R ³ N ⁺ -A-SiR ⁷ R ⁸ - (O-SiR ⁹ R ¹⁰ ) _n -O-SiR ¹¹ R ¹² -A-N ⁺ R ⁴ R ⁵ R ⁶ ] 2X ^" (Si 3c) where R 1 to R 6 independently of one another are C 1 to C 22 -alkyl radicals which may contain hydroxyl groups and where preferably at least one of the radicals has at least 8 C atoms and the remaining radicals have 1 to 4 C atoms,

the radicals R 7 to R 12, independently of one another, are identical or different and are C 1 to C 10 -alkyl or phenyl, A is a divalent organic compound group,

n is a number from 0 to 200, preferably from 10 to 120, more preferably from 10 to 40, and X ^'is an anion.

The divalent linking group is preferably a C1 to C12 alkylene or alkoxyalkylene group which may be substituted with one or more hydroxyl groups. Particularly preferred is the group - (CH ₂ ) ₃ -O-CH ₂ -CH (OH) -CH ₂ -.

The anion X ^' can be a halide ion, an acetate, an organic carboxylate or a compound of the general formula RSO ₃ ^" , in which R has the meaning of C 1 -C 4 -alkyl radicals.

 A preferred diquaternary silicone has the general formula (Si3d)

[RN ⁺ Me ₂ -A- (SiMe ₂ O) _n -SiMe ₂ -A-N ⁺ Me ₂ R] 2 CH ₃ COO ^" (Si 3d),

where A is the group - (CH ₂ ) ₃ - O - CH ₂ - CH (OH) - CH ₂ -,

R is an alkyl radical having at least 8 C atoms and n is a number from 10 to 120.

Suitable silicone polymers having two terminal quaternary ammonium groups are known under the INCI name Quaternium-80. These are dimethylsiloxanes with two terminal trialkylammonium groups. Such diquaternary polydimethylsiloxanes are marketed by Evonik under the trade names Abil ^® Quat 3270, 3272 and 3474th Cosmetic or dermatological preparations preferred according to the invention are characterized in that, based on their weight, they contain 0.01 to 10% by weight, preferably 0.01 to 8% by weight, particularly preferably 0.1 to 7.5% by weight and in particular from 0.2 to 5% by weight of amino-functional silicone (s) and / or diquaternary silicone.

 As a silicone, the compositions of the invention may contain at least one polyammonium-polysiloxane compound. The polyammonium-polysiloxane compounds can be obtained, for example, under the trade name Baysilone® from GE Bayer Silicones. The products with the names Baysilone TP 391 1, SME 253 and SFE 839 are preferred. Very particular preference is given to the use of Baysilone TP 3911 as the active component of the compositions according to the invention. The polyammonium-polysiloxane compounds are present in the compositions according to the invention in an amount of from 0.01 to 10% by weight, preferably from 0.01 to 7.5, particularly preferably from 0.01 to 5.0% by weight, very particularly preferably from 0 , 05 to 2.5 wt.% Each used in relation to the total composition.

 The cyclic dimethicones designated as cyclomethicones according to INCI are also preferably used according to the invention. Here, cosmetic or dermatological preparations according to the invention are preferred which contain at least one silicone of the formula (Si-4)

 in which x is a number from 3 to 200, preferably from 3 to 10, more preferably from 3 to 7 and in particular 3, 4, 5 or 6 stands.

 Agents which are likewise preferred according to the invention are characterized in that they contain at least one silicone of the formula (Si-5)

R ₃ Si [O-SiR ₂ ] _x - (CH ₂ ) _n - [O-SiR ₂ ] _y -O-SiR ₃ (Si-5),

included, in which R stands for identical or different radicals from the group -H, -phenyl, -benzyl, -CH ₂ -CH (CH ₃₎ Ph, the CI_ ₂₀ -alkyl, preferably -CH _3, -CH ₂ CH _3, -CH ₂ CH ₂ CH ₃ , - CH (CH ₃ ) ₂ , -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C ( CH ₃ ) ₃ , x and y are a number from 0 to 200, preferably from 0 to 10, more preferably from 0 to 7 and in particular 0, 1, 2, 3, 4, 5 or 6, and n is a number from 0 to 10, preferably from 1 to 8 and in particular from 2, 3, 4, 5, 6.

 As further silicones in addition to the dimethicones, dimethiconols, amodimethicones and / or cyclomethicones according to the invention, water-soluble silicones may be present in the compositions according to the invention.

Corresponding hydrophilic silicones are selected, for example, from the compounds of the formulas (Si-6) and / or (Si-7). Particularly preferred water-soluble silicone-based surfactants are selected from the group of dimethicone copolyols which are preferably alkoxylated, in particular polyethoxylated or polypropoxylated. Dimethicone copolyols according to the invention are preferably polyoxyalkylene-modified

Dimethylpolysiloxanes of the general formulas (Si-6) or (Si-7) understood:

R ¹ - Si- ^■ [OSi (CH _{3) 2] x} - (OC ₂ H _{4) a} - (OC ₃ H _{6) b} -OR "

 3 (Si-7)

in which the radical R represents a hydrogen atom, an alkyl group having 1 to 12 C atoms, an alkoxy group having 1 to 12 C atoms or a hydroxyl group, the radicals R 'and R "denote alkyl groups having 1 to 12 C atoms, x is an integer from 1 to 100, preferably from 20 to 30, y is an integer from 1 to 20, preferably from 2 to 10, and a and b are integers from 0 to 50, preferably from 10 to 30 ,

 Particularly preferred dimethicone copolyols according to the invention are, for example, the products sold commercially under the trade names SILWET (Union Carbide Corporation) and DOW CORNING. Particularly preferred dimethicone copolyols according to the invention are Dow Corning 190 and Dow Corning 193.

 The dimethicone copolyols are present in the compositions according to the invention in amounts of from 0.01 to 10% by weight, preferably from 0.01 to 8% by weight, more preferably from 0.1 to 7.5% by weight and in particular from 0.1 to 5% by weight. % of dimethicone copolyol based on the composition.

Finally, among the silicone compounds Dimethiconole (Si8) understood. The dimethiconols according to the invention can be both linear and branched as well as cyclic or cyclic and branched. Linear dimethiconols can be represented by the following structural formula (Si8-I):

(SiOHR ¹ ₂ ) - O - (SiR ² ₂ - O -) _x - (SiOHR ¹ ₂ ) (Si 8 - I)

 Branched dimethiconols can be represented by the structural formula (Si8 - II):

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. The numbers x, y, and z are integers and are each running independently from 0 to 50,000. The molecular weights of Dimethiconole lie between

D 1000 and 10000000 D. The viscosities are between 100 and 10,000,000 cPs measured at 25 ⁰ C by means of a glass capillary viscometer according to Dow Corning Corporate Test Method CTM 0004 dated 20 July 1970. Preferred viscosities are 1000 to 5,000,000 cps, most preferred viscosities lie between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.

 Examples of such products include the following commercial products: Dow Coming 1-1254 Fluid, Dow Corning 2-9023 Fluid, Dow Coming 2-9026 Fluid, Abil OSW 5 (Degussa Care Specials), Dow Coming 1401 Fluid, Dow Corning 1403 Fluid Dow Corning 1501 Fluid, Dow Corning 1784 HVF Emulsion, Dow Corning 9546 Silicone Elastomer Blend, SM555, SM2725, SM2765, SM2785 (all four aforementioned GE Silicones), Wacker-Belsil CM 1000, Wacker-Belsil CM 3092, Wacker-Belsil CM 5040, Wacker-Belsil DM 3096, Wacker-Belsil DM 3112 VP, Wacker-Belsil DM 8005 VP, Wacker-Belsil DM 60081 VP (all Wacker-Chemie GmbH mentioned above).

 The dimethiconols (Si8) are present in the compositions according to the invention in amounts of from 0.01 to 10% by weight, preferably from 0.01 to 8% by weight, more preferably from 0.1 to 7.5% by weight and in particular from 0.1 to 5% by weight of dimethiconol based on the composition.

Furthermore, in a most preferred embodiment, polymers for increasing the activity of the active ingredient complex (A) are included. The interaction of the rambutan oil with the cationic polymers leads to a particularly intensive improvement in the care properties. In particular, the combability of the wet and dry hair as well as the gloss are greatly improved by this combination.

 The cationic polymers may be homopolymers or copolymers wherein the quaternary nitrogen groups are contained either in the polymer chain or preferably as a substituent on one or more of the monomers. The ammonium group-containing monomers may be copolymerized with non-cationic monomers. Suitable cationic monomers are unsaturated, free-radically polymerizable compounds which carry at least one cationic group, in particular ammonium-substituted vinyl monomers, for example trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium,

Dialkyl diallyl ammonium and quaternary vinyl ammonium monomers with cyclic, cationic nitrogen-containing groups such as pyridinium, imidazolium or quaternary pyrrolidones, e.g. Alkylvinylimidazolium, Alkylvinylpyridinium, or Alyklvinylpyrrolidon salts. The alkyl groups of these monomers are preferably lower alkyl groups such as C1 to C7 alkyl groups, more preferably C1 to C3 alkyl groups.

The ammonium group-containing monomers may be copolymerized with non-cationic monomers. Suitable comonomers are, for example, acrylamide, methacrylamide; Alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, vinyl esters, for example vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, wherein the alkyl groups of these monomers preferably C1 to C7 alkyl groups, particularly preferably C1 to C3 Alkyl groups are. Suitable polymers with quaternary amine groups are, for example, those in CTFA Cosmetic

Ingredient Dictionary described under the names Polyquaternium polymers such

Methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16) or quaternized vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (Polyquaternium-1 1).

Among the cationic polymers that can be included in the inventive composition, for example vinylpyrrolidone / dimethylaminoethyl copolymer available under the trade names Gafquat ^® 755 N and Gafquat ^® 734, United States is marketed by Gaf Co. and of which the Gafquat ^® 734 is particularly preferred suitable. Further cationic polymers are, for example, those of the company BASF, Germany under the

Tradename Luviquat ^® HM 550 displaced copolymer of polyvinylpyrrolidone and

Imidazoliminemethochloride that by Calgon / USA under the trade name Merquat ^®

Plus 3300 distributed terpolymers of dimethyldiallylammonium chloride, sodium acrylate and

Acrylamide and sold by the company ISP under the trade name Gafquat ^® HS 100

Vinyl pyrrolidone / methacrylamidopropyl trimethyl ammonium chloride copolymer.

Homopolymers of the general formula (P1), - {CH ₂ - [CR ¹ COO- (CH ₂ ) _m N ⁺ R ² R ³ R ⁴ ]} _n X ^" ,

in which R ^{1 is} -H or -CH ₃ , R ² , R ³ and R ^{4 are} independently selected from C 1-4 -alkyl.

Alkyl, alkenyl or hydroxyalkyl groups, m = 1, 2, 3 or 4, n is a natural number and

X ^"is a physiologically acceptable organic or inorganic anion

Polymers are those inventively preferred for which at least one of the following

Conditions are: R ¹ is a methyl group, R ² , R ³ and R ⁴ are methyl groups, m is 2.

As a physiologically acceptable counterion X ^" come, for example, halide ions,

Sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate,

Tartrate and acetate ions into consideration. Preference is given to halide ions, in particular chloride.

 A particularly suitable homopolymer is, if desired, crosslinked,

Poly (methacryloyloxyethyltrimethylammonium chloride) with the INCI name Polyquaternium

37. Such products (for example, under the names Rheocare ^® Cosmetic CTH

Rheologies) and Synthalen® ^® CR (3V Sigma) are commercially available.

 The homopolymer is preferably used in the form of a non-aqueous polymer dispersion.

Such polymer dispersions are available under the names Salcare ^® SC 95 and Salcare ^® SC 96 in the trade.

 A preferred copolymer according to the invention is the crosslinked acrylamide

Methacryloyloxyethyltrimethylammonium chloride copolymer. Such copolymers are commercially available under the name Salcare ^® SC 92nd

 Suitable cationic polymers derived from natural polymers are cationic ones

Derivatives of polysaccharides, for example, cationic derivatives of cellulose, starch or

Guar. Also suitable are chitosan and chitosan derivatives. Cationic polysaccharides have the general formula (P-3) GOB-N + R _a R _b R _c X ^"

 G is an anhydroglucose residue, for example starch or cellulose anhydroglucose;

 B is a divalent linking group, for example alkylene, oxyalkylene, polyoxyalkylene or

hydroxyalkylene; R _a , R _b and R _c are independently alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or

Alkoxyaryl each having up to 18 carbon atoms, wherein the total number of carbon atoms in R _a , R _b and R _{c is} preferably not more than 20;

X ^" is a common counteranion and is preferably chloride.

A cationic cellulose is sold under the name Polymer JR 400 from Amerchol ^® and has the INCI designation Polyquaternium-10 degrees. Another cationic cellulose bears the INCI name Polyquaternium-24 and is sold under the trade name Polymer LM-200 by Amerchol. Other commercial products are the compounds Celquat ^® H 100, Celquat ^® L and 200. The commercial products mentioned are preferred cationic celluloses.

Suitable cationic guar derivatives are marketed under the trade name Jaguar ^® and have the INCI name guar hydroxypropyltrimonium chloride. Further particularly suitable cationic guar derivatives are also used by the company. Hercules under the name N-Hance ^® commercially. Other cationic guar derivatives are marketed by the company. Cognis under the name Cosmedia® ^®. A preferred cationic guar derivative is the commercial product AquaCat® ^® from. Hercules. This raw material is an already pre-dissolved cationic guar derivative.

A suitable chitosan is sold, for example, by Kyowa Oil & Fat, Japan under the trade name Flonac ^®. A preferred chitosan is chitosoniumpyrrolidone is, for example, sold under the name Kytamer ^® PC by Amerchol, USA. Further chitosan derivatives are Hydagen® ^® CMF, Hydagen® ^® HCMF and Chitolam ^® NB / 101 freely available under the trade names in the trade.

 Further preferred cationic polymers are, for example

cationic alkyl polyglycosides,

cationized honey, for example the commercial product Honeyquat ^® 50,

polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride

Acrylamide copolymer) commercially available products are examples of such cationic polymers,

Vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,

quaternized polyvinyl alcohol,

and the polymers known under the names Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and Polyquaternium 27 with quaternary nitrogen atoms in the polymer main chain,

Vinylpyrrolidone-vinylcaprolactam-acrylate terpolymers, such as those offered with acrylic acid esters and acrylamides as the third monomer building commercially, for example, under the name Aquaflex ^® SF 40. Also usable according to the invention are the copolymers of vinylpyrrolidone, as they are known as

Commercial products Copolymer 845 (manufacturer: ISP), Gaffix ^® VC 713 (manufacturer: ISP), Gafquat ^® ASCP 1011, Gafquat ^® HS 110 Luviquat.RTM ^® 8155 and Luviquat.RTM ^® MS are available 370th Furthermore, cationized protein hydrolysates are to be counted among the cationic polymers, wherein the underlying protein hydrolyzate from the animal, for example from collagen, milk or keratin, from the plant, for example from wheat, corn, rice, potatoes, soy or almonds, marine life forms, for example from fish collagen or algae, or biotechnologically derived protein hydrolysates. As typical examples of the cationic protein hydrolysates and derivatives according to the invention, those mentioned under the INCI names in the "International Cosmetic Ingredient Dictionary and Handbook", (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1101 17 ^th Street, NW, Suite 300 Washington, DC 20036-4702) and commercially available products.

The cationic polymers are contained in the compositions according to the invention preferably in amounts of 0.01 to 10 wt .-%, based on the total agent. Levels of 0.05 to 5 wt .-% are particularly preferred.

Furthermore, amphoteric polymers can be used as polymers. The term amphoteric polymers includes both those polymers which contain in the molecule both free amino groups and free -COOH or SO ₃ H groups and are capable of forming internal salts, as well as zwitterionic polymers which in the molecule have quaternary ammonium groups and -COO or -SO ₃ ^~ groups, and those polymers comprising -COOH or SO ₃ H groups and quaternary ammonium groups.

 Amphoteric and / or cationic polymers preferred according to the invention are those polymers in which a cationic group is derived from at least one of the following monomers:

(i) monomers having quaternary ammonium groups of the general formula (monol),

R ¹ -CH = CR ² -CO-Z- (C _n H _2n ) -N ⁽⁺⁾ R ² R ³ R ⁴ A ⁽⁾ (monol)

in which R ¹ and R ² independently of one another are hydrogen or a methyl group and R ³ , R ⁴ and R ⁵ independently of one another are alkyl groups having 1 to 4 carbon atoms, Z is an NH group or an oxygen atom, n is an integer of 2 to 5 and A ^{() is} the anion of an organic or inorganic acid,

(ii) monomers having quaternary ammonium groups of the general formula (mono 2),

wherein R ⁶ and R ^{7 are} independently a (C ₁ to C ₄ ) alkyl group, in particular a methyl group and

A ^"is the anion of an organic or inorganic acid,

(iii) monomeric carboxylic acids of the general formula (mono 3),

R ⁸ -CH = CR ⁹ -COOH (mono 3)

in which R ⁸ and R ^{9 are} independently hydrogen or methyl groups. Particularly preferred are those polymers in which monomers of type (i) are used in which R ³ , R ⁴ and R ^{5 are} methyl groups, Z is an NH group and A ^{() is} a halide,

Methoxy sulfate or ethoxy sulfate ion; Acrylamidopropyltrimethylammonium chloride is a particularly preferred monomer (i). As the monomer (ii) for the polymers mentioned, acrylic acid is preferably used.

 Particularly preferred amphoteric polymers are copolymers of at least one monomer

(Monol) or (Mono2) with the monomer (Mono3), in particular copolymers of the

Monomers (Mono2) and (Mono3). Very particularly preferably used according to the invention amphoteric polymers are copolymers of diallyl dimethyl ammonium chloride and acrylic acid.

These copolymers are sold under the INCI name Polyquaternium-22, among others, with the trade name Merquat ^® 280 (Nalco).

 In addition, the amphoteric polymers of the invention may be used in addition to a monomer

(Monol) or (mono 2) and one monomer (mono 3) additionally one monomer (mono 4)

(iv) monomeric carboxylic acid amides of the general formula (mono 4),

wherein R ¹⁰ and R ^{11 are} independently hydrogen or methyl groups and R ^{12 is} a hydrogen atom or a (C 1 to C ₈ ) alkyl group.

Amphoteric polymers based on a comonomer (Mono4) which are very particularly preferably used according to the invention are terpolymers of diallyldimethylammonium chloride, acrylamide and acrylic acid. These copolymers are marketed ^® under the INCI name Polyquaternium-39, among others, with the trade name Merquat Plus 3330 (Nalco).

 The amphoteric polymers can generally be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention.

 The amphoteric polymers are contained in the agents according to the invention preferably in amounts of 0.01 to 10 wt .-%, based on the total agent. Amounts of 0.01 to 5 wt .-% are particularly preferred.

 The anionic polymers are anionic polymers which have carboxylate and / or sulfonate groups. Examples of anionic monomers from which such polymers may consist are acrylic acid, methacrylic acid, crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. The acidic groups may be wholly or partly present as sodium, potassium, ammonium, mono- or triethanolammonium salt. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

Anionic polymers which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer can be found to be particularly effective, it being possible for the sulfonic acid group to be wholly or partly present as sodium, potassium, ammonium, mono- or triethanolammonium salt ,

Particularly preferred is the homopolymer of 2-acrylamido-2-acid methylpropansulfon, available for example under the name Rheothik ^® 11-80 is commercially. Within this embodiment, it may be preferable to use copolymers of at least one anionic monomer and at least one nonionic monomer. With regard to the anionic monomers, reference is made to the substances listed above. Preferred nonionic monomers are acrylamide, methacrylamide, acrylic esters, methacrylic esters, vinylpyrrolidone, vinyl ethers and vinyl esters.

Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with sulfonic acid-containing monomers. Such a polymer is contained in the commercial product Sepigel ^® 305 from SEPPIC.

Also sold under the name Simulgel ^® 600 as a compound with isohexadecane and polysorbate 80 Natriumacryloyldimethyltaurat copolymers have proven to be particularly effective according to the invention.

Likewise preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene may be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-retaining polymers. A 1, 9-decadiene crosslinked maleic acid-methyl vinyl ether copolymer is available under the name ^® Stabileze QM. The anionic polymers are preferably contained in the agents according to the invention in amounts of from 0.05 to 10% by weight, based on the total agent. Amounts of 0.1 to 5 wt .-% are particularly preferred.

An inventively particularly preferred polyurethane is available under the trade name Luviset.RTM ^® PUR (BASF).

 In a further embodiment, the agents according to the invention may contain nonionogenic polymers.

 Suitable nonionic polymers are, for example:

Vinylpyrrolidone / vinyl ester copolymers, as sold, for example, under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.

Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and hydroxypropylcellulose Methylhy-, as sold for example under the trademark Culminal® ^® and Benecel ^® (AQUALON) and Natrosol ^® grades (Hercules).

Starch and its derivatives, in particular starch, such as Structure XL ^® (National Starch), a multifunctional, salt-tolerant starch;

 shellac

Polyvinylpyrrolidones, as sold for example under the name Luviskol ^® (BASF).

The nonionic polymers are preferably contained in the compositions according to the invention in amounts of from 0.05 to 10% by weight, based on the total agent. Amounts of 0.1 to 5 wt .-% are particularly preferred. It is also possible according to the invention that the preparations used contain a plurality, in particular two, different polymers of the same charge and / or in each case an ionic and an amphoteric and / or nonionic polymer.

 The polymers (P) are preferably present in the compositions used according to the invention in amounts of from 0.01 to 30% by weight, based on the total composition. Amounts of from 0.01 to 25, in particular from 0.01 to 15 wt .-%, are particularly preferred.

Of course, the compositions of the invention may further contain conventional ingredients in cosmetic compositions.

Emulsifiers which can be used according to the invention are, for example

 Addition products of 4 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear fatty alcohols having 8 to 22 carbon atoms, to fatty acids having 12 to 22 carbon atoms and on

Alkylphenols having 8 to 15 C atoms in the alkyl group,

C ₂ -C ₂₂ -fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto polyols having from 3 to 6 carbon atoms, in particular to glycerol,

 Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters,

Fatty acid alkanolamides and fatty acid glucamides,

C ₈ -C ₂₂ -alkylmono- and -oligoglycosides and their ethoxylated analogues, where C ¹ degrees of gyration of from 1.1 to 5, in particular 1.2 to 2.0, and glucose as sugar component are preferred,

Glucosides mixtures of alkyl (oligo) and fatty alcohols, for example, the commercially available product ^® Montanov 68,

 Addition products of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil,

Partial esters of polyols of 3-6 carbon atoms with saturated fatty acids of 8 to 22

C-atoms,

 Sterols, both from animal tissue (zoosterols, cholesterol, lanosterol) as from vegetable fats (phytosterols, ergosterol, stigmasterol, sitosterol) or from fungi and

Yeasts (mycosterines),

 Phospholipids (lecithins, phopshatidylcholines),

 Fatty acid esters of sugars and sugar alcohols, such as sorbitol,

 Polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate

(Dehymuls ^® PGPH commercial product).

 The agents according to the invention preferably contain the emulsifiers in amounts of 0.1-25% by weight, in particular 0.5-15% by weight, based on the total agent.

As fatty acids (Fatac) can be used linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms. Preference is given to fatty acids having 10 to 22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Further typical examples of such fatty acids are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myrotic acid, ristinic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid,

Petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.

 The amount used is 0.1 - 15 wt.%, Based on the total mean. The amount is preferably 0.5-10% by weight, with amounts of 1-5% by weight being particularly advantageous.

As fatty alcohols (fatal) it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ -, preferably C ₁₀ -C ₂₂ -and very particularly preferably C ₁₂ -C ₂₂ -carbon atoms. Decanols, octanols, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, caprylic alcohol, capric alcohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol are, for example, decanol, octanolol, dodecadienol, decadienol , as well as their Guerbet alcohols, this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® such as Stenol ^® 1618 or Lanette ^® such as Lanette ^® O or Lorol ^®, for example, Lorol ^® C8, Lorol C14 ^®, Lorol C18 ^{®, ®} Lorol C8-18, HD-Ocenol ^®, Crodacol ^® such as Crodacol ^® CS, Novol ^®, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb ^® 12, Isocarb ^® 16 or acquire Isocarb® ^® 24 for sale. Of course, wool wax alcohols, as are commercially available, for example under the names of Corona ^®, White Swan ^®, Coronet ^® or Fluilan ^® can be used according to the invention. The fatty alcohols are used in amounts of from 0.1 to 30% by weight, based on the total preparation, preferably in amounts of from 0.1 to 20% by weight.

 As natural or synthetic waxes (Fatwax), solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP can be used according to the invention. Such waxes are available, for example, from Kahl & Co., Trittau.

 The amount used is 0.1-50 wt.% Based on the total agent, preferably 0.1 to 20 wt.% And particularly preferably 0.1 to 15 wt.% Based on the total agent.

The total amount of oil and fat components in the compositions according to the invention is usually 0.5-75% by weight, based on the total agent. Amounts of 0.5-35 wt .-% are preferred according to the invention.

Another inventive synergistic active ingredient in the compositions according to the invention with the active ingredient complex according to the invention are protein hydrolysates and / or derivatives thereof (P). According to the invention, protein hydrolysates of both vegetable and animal or marine or synthetic origin can be used.

Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolysates, which may also be present in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois ^® (Interorgana)

Collapuron ^® (Cognis), Nutrilan® ^® (Cognis), Gelita-Sol ^® (German Gelatinefabriken Stoess & Co)

Lexein ^® (Inolex) and kerasol tm ^® (Croda) sold.

 Furthermore, according to the invention preferred vegetable protein hydrolysates such as

Soy, almonds, peas, moringa, potato and wheat protein hydrolysates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), diamine ^® (Diamalt) ^®

(Inolex), Hydrosoy ^® (Croda), hydro Lupine ^® (Croda), hydro Sesame ^® (Croda), Hydro tritium ^® (Croda)

Crotein ^® (Croda) and Puricare ^® LS 9658 available from the Fa. Laboratoires Serobiologiques.

Further preferred protein hydrolysates according to the invention are of maritime origin. These include, for example, collagen hydrolyzates of fish or algae as well as protein hydrolysates of

Mussels or pearl hydrolyzates. Examples of pearl extracts according to the invention are the

Commercial products Pearl Protein Extract BG ^® or Crodarom ^® Pearl.

 However, it is most preferred if casein is used as the protein hydrolyzate. The

Use of casein in the compositions together with rambutan oil leads to sensory and noticeable haptic effects on the skin and the hair. Thus, the hair treated with it feels much stronger and stronger due to its haptic properties. On the one hand, the surface is smooth and supple, and on the other hand, the coverage of the surface with the active ingredient combination is still noticeable.

 The protein hydrolysates (P) are in the compositions in concentrations of 0.001

% By weight up to 20% by weight, preferably from 0.05% by weight up to 15% by weight and very particularly preferably in amounts of from 0.05% by weight up to 5% by weight.

 The effect of the compositions according to the invention can furthermore be achieved by a

Pyrrolidinone-5-carboxylic acid and its derivatives (J) can be increased. Preferred are the

Sodium, potassium, calcium, magnesium or ammonium salts in which the ammonium ion in addition to hydrogen carries one to three C ₁ - to C ₄ alkyl groups. The sodium salt is most preferred. The amounts used in the compositions according to the invention are from 0.05 to 10% by weight, based on the total composition, particularly preferably from 0.1 to 5, and in particular

0.1 to 3 wt.%.

 Another preferred group of ingredients of the compositions according to the invention with the active ingredient complex according to the invention are vitamins, provitamins or vitamin precursors.

Vitamins, pro-vitamins and vitamin precursors are particularly preferred to the groups

A, B, C, E, F and H are assigned.

The group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The ß-carotene is the provitamin of retinol. As a vitamin

A component according to the invention, for example, vitamin A acid and its esters,

Vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate in Consideration. The agents according to the invention preferably contain the vitamin A component in

Amounts of 0.05-1 wt .-%, based on the total preparation.

 The vitamin B group or the vitamin B complex include u. a .:

Vitamin B ₁ (thiamine)

Vitamin B ₂ (riboflavin)

Vitamin B ₃ . Under this designation are often the compounds nicotinic acid and

Nicotinic acid amide (niacinamide). Preferred according to the invention is the nicotinic acid amide which is contained in the agents used according to the invention preferably in amounts of from 0.05 to 1% by weight, based on the total agent.

Vitamin B ₅ (pantothenic acid, panthenol and pantolactone). Panthenol and / or pantolactone are preferably used in the context of this group. Usable according to the invention

Derivatives of panthenol are in particular the esters and ethers of panthenol as well as cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, the

Panthenol monoethyl ether and its monoacetate and cationic panthenol derivatives.

Pantothenic acid is preferred as a derivative in the form of the more stable calcium salts and sodium salts

(Ca-pantothenate, Na-pantothenate) used in the present invention.

Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal).

The said compounds of the vitamin B type, in particular vitamin B ₃ , B ₅ and B ₆ , are preferably present in the agents according to the invention in amounts of 0.05-10% by weight, based on the total agent. Amounts of 0.1-5 wt .-% are particularly preferred.

 Vitamin C (ascorbic acid). Vitamin C is preferred in the agents according to the invention

Quantities of 0.1 to 3 wt .-%, based on the total agent used. The use in

Form of palmitic acid ester, glucosides or phosphates may be preferred. The

Use in combination with tocopherols may also be preferred.

 Vitamin E (tocopherols, especially α-tocopherol). Tocopherol and its derivatives, which include in particular the esters such as the acetate, the nicotinate, the phosphate and the succinate, are preferably present in the agents according to the invention in amounts of 0.05-1% by weight, based on the total agent.

 Vitamin F. The term "vitamin F" is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.

 Vitamin H. Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] - imidazole-4-valeric acid, for which, however, the trivial name biotin has meanwhile prevailed. Biotin is preferably present in the compositions according to the invention in amounts of from 0.0001 to 1.0% by weight, in particular in amounts of from 0.001 to 0.01% by weight.

 The compositions according to the invention preferably contain vitamins, provitamins and

Vitamin precursors from groups A, B, E and H. Panthenol, pantolactone, pyridoxine and its

Derivatives as well as nicotinic acid amide and biotin are particularly preferred.

 A particularly preferred group of ingredients in the cosmetic according to the invention

Compositions are the betainees mentioned below: carnitine, carnitine tartrate, carnitine

Magnesium citrate, acetylcarnitine, betalaine, 1, 1-dimethyl-proline, choline, choline chloride, Choline bitartrate, choline dihydrogen citrate and the compound referred to in the literature as betaine

N, N, N-trimethylglycine.

 Carnitine, histidine, choline and betaine are preferably used. In a particularly preferred embodiment of the invention, the active ingredient used is L-carnitine tartrate.

A particularly important ingredient is taurine and / or a derivative of taurine. Taurine is exclusively 2-aminoethanesulfonic acid and a derivative is understood to mean the explicitly mentioned derivatives of taurine. Derivatives of taurine include N-monomethyltaurine, N, N-dimethyltaurine, tauryllysylate, taurine tartrate, taurine ornithithate, lysyl taurine and ornithyl taurine. Further taurine derivatives for the purposes of the present invention are taurocholic acid and hypotaurine.

 Particularly preferred are agents according to the invention, which - based on their weight - 0.0001 to 10.0 wt .-%, preferably 0.0005 to 5.0 wt .-%, particularly preferably 0.001 to 2.0 wt .-% and In particular, 0.001 to 1, 0 wt .-% taurine and / or a derivative of taurine included. In a further embodiment preferred according to the invention, the compositions according to the invention contain biochinones. In the agents according to the invention, suitable biochinones are understood as meaning one or more ubiquinone (s) and / or plastoquinone (s). The preferred ubiquinones according to the invention have the following formula:

10th

Coenzyme Q-10 is most preferred.

 Preferred compositions of the invention contain purine and / or purine derivatives in narrower ranges. Here, preferred cosmetic compositions according to the invention are characterized in that they contain, based on their weight, from 0.001 to 2.5% by weight, preferably from 0.0025 to 1% by weight, particularly preferably from 0.005 to 0.5% by weight and in particular from 0.01 to 0.1% by weight of purine (s) and / or purine derivative (s). Cosmetic agents preferred according to the invention are characterized in that they contain purine, adenine, guanine, uric acid, hypoxanthine, 6-purinethiol, 6-thioguanine, xanthine, caffeine, theobromine or theophylline. In hair cosmetic preparations, caffeine is most preferred.

 In a further preferred embodiment of the present invention, the cosmetic agent contains ectoine ((S) -2-methyl-1, 4,5,6-tetrahydro-4-pyrimidinecarboxylic acid.

Particularly preferred according to the invention are agents which, based on their weight, are from 0.00001 to 10.0% by weight, preferably from 0.0001 to 5.0% by weight and in particular from 0.001 to 3% by weight, of the active compounds from A group formed by carnitine, taurine, coenzyme Q-10, ectoine, a B-series vitamin, a purine and its derivatives or physiologically acceptable salts.

 In a further embodiment, the agents according to the invention should additionally contain at least one UV light protection filter. UVB filters can be oil-soluble or water-soluble.

Examples of oil-soluble substances are: 3-benzylidene camphor, eg 3- (4-methylbenzylidene) camphor;

 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and A-

(Dimethylamino) benzoesäureamylester;

 Esters of cinnamic acid, preferably 2-ethylhexyl 4-methoxycinnamate, A-

Propyl methoxycinnamate, isoamyl 4-methoxycinnamate, 2-ethylhexyl 2-cyano-3-phenylcinnamate (octocrylene);

 Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropylbenzyl salicylate, homomenthyl salicylate;

 Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy

4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone;

 Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzmalonate;

Triazine derivatives, e.g. 2,4,6-Trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1, 3,5-triazine and

Octyl.

 Propane-1,3-diones, e.g. 1- (4-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione;

Suitable water-soluble substances are:

 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium,

Alkylammonium, alkanolammonium and glucammonium salts;

 Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone

5-sulfonic acid and its salts;

 Sulfonic acid derivatives of the 3-benzylidene camphor, e.g. 4- (2-oxo-3-bornylidenemethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) -sulfonic acid and its salts.

 As a typical UV-A filter in particular derivatives of benzoylmethane come into question, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1, 3-dione or 1-phenyl-3 (4'-isopropylphenyl) -propane-1,3-dione. Of course, the UV-A and UV-B filters can also be used in mixtures. In addition to the soluble substances mentioned, insoluble pigments are also suitable for this purpose, in particular finely dispersed metal oxides or salts, for example titanium dioxide, zinc oxide, iron oxide, aluminum oxide, cerium oxide, zirconium oxide, silicates (talc), barium sulfate and zinc stearate. The particles should have an average diameter of less than 100 nm, preferably between 5 and 50 nm and in particular between 15 and 30 nm. They may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape.

Finally, the use of plant extracts (L) in the compositions according to the invention gives rise to further advantages. The extracts of green tea, oak bark, stinging nettle, witch hazel, hops, henna, chamomile, burdock root, horsetail, hawthorn, linden, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime , Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Valerian, Meadowfoam, Quenelle, Yarrow, Thyme, Melissa, Hominy, Coltsfoot, Marshmallow, Meristem, Ginseng, Coffee, cocoa, moringa, ginger root and ayurvedic plant extracts such as

Aegle Marmelos (Bilwa), Cyperus Rotundus (Nagar Motha), Emblica Officinalis (Amalki), Morida Citrifolia (Ashyuka), Tinospora Cordifolia (Guduchi), Santalum album, (Chandana), Crocus Sativus (Kumkuma), Cinnamonum Zeylanicum and Nelumbo Nucifera ( Grasses such as wheat, barley, rye, oats, spelled, maize, the various types of millet (European millet, crab millet, millet as an example), cane, ryegrass, meadow foxtail, oat grass, ostrich grass, meadow fescue, whistling grass, bamboo, cotton grass, Lamprey Grasses, Andropogonodeae (Imperata Cylindrica also called Flaming Grass or Cogon Grass), Buffalo Grass, Mud Grass, Canine Grasses, Love Grasses, Cymbopogon (Lemongrass), Oryzeae (Rice), Zizania (Wild Rice), Beach Grass, Perennial Grass, Honey Grasses, Shivering Grasses, Field Grasses, Seagrass and Echinacea , in particular Echinacea angustifolia DC, Echinacea paradoxa (Norton), Echinacea simulata, E. atrorubens, E. tennesiensis, Echinacea strigosa (Mc Gregor), Echinacea laevigata, Echinacea purpurea (L.) Moench and Echinacea pallida (Nutt), all types of wine and Perikarp preferred by Litchie chinensis.

The plant extracts can be used according to the invention both in pure and in diluted form. If they are used in diluted form, they usually contain about 2 to 80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.

 Furthermore, the cosmetic agents may contain other active ingredients, auxiliaries and additives, such as

 Structurants such as maleic acid and lactic acid,

 Swelling agents such as urea, allantoin, carbonates or hydantoin,

 Dimethylisosorbide and cyclodextrins,

 Dyes for staining the agent,

 Anti-dandruff agents such as Piroctone Olamine, Zinc Omadine and Climbazole,

 Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,

 Opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers

 Pearlescing agents such as ethylene glycol mono- and distearate and PEG-3-distearate,

 pigments

 Stabilizing agent for hydrogen peroxide and other oxidizing agents,

Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,

 antioxidants

 Perfume oils, fragrances and fragrances.

 With regard to further optional components and the amounts of these components used, reference is expressly made to the relevant manuals known to the person skilled in the art.

 Another subject of the invention is a hair treatment process in which a cosmetic composition according to claim 1 is applied to the hair and is rinsed by the hair after a contact time.

The exposure time is preferably a few seconds to 100 minutes, more preferably 1 to 50 minutes and most preferably 1 to 30 minutes. Examples:

All quantities are, unless otherwise stated, parts by weight. The following formulations were provided using known preparation methods

 Plfegeshampoo:

Claims

claims:

1. Cosmetic composition for treating keratinous fibers, in particular containing human hair

 a. at least 0.01 to 10.0% by weight of rambutan oil and

 b. at least one anionic, amphoteric, cationic or nonionic surfactant and

 c. a cosmetic carrier.

 2. Cosmetic composition according to claim 1, characterized in that further at least one cationic polymer or a protein hydrolyzate is contained.

3. Cosmetic composition according to one of claims 1 or 2, characterized in that the protein hydrolyzate is casein.

 4. Cosmetic compositions according to any one of claims 1 to 3, characterized in that the cosmetic composition contains as surfactant at least one cationic surfactant in an amount of 0.01 to 20.0 wt.%.

 5. Cosmetic compositions according to any one of claims 1 to 4, characterized in that in addition at least one further ingredient selected from one of the groups of the native oils, ester oils or silicone oils is included.

 6. Cosmetic composition according to one of claims 1 to 5, characterized in that the silicone is selected from dimethicones, amodimethicones and dimethiconols.

 7. Cosmetic compositions according to claim 6, characterized in that the silicone has a viscosity of 40,000 to 80,000 mPa-s and is selected from dimethicones or dimethiconols.

 8. A process for the treatment of keratinic fibers, characterized in that a cosmetic composition according to any one of claims 1 to 7 is applied to the keratinic fibers and is rinsed again after a contact time of a few seconds up to 45 minutes.

 9. Use of an agent according to any one of claims 1 to 7 for the treatment of keratinous fibers.