EP2303451A4 - Mullite-containing carrier for ethylene oxide catalysts - Google Patents

Mullite-containing carrier for ethylene oxide catalysts Download PDF

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Publication number
EP2303451A4
EP2303451A4 EP09798545.1A EP09798545A EP2303451A4 EP 2303451 A4 EP2303451 A4 EP 2303451A4 EP 09798545 A EP09798545 A EP 09798545A EP 2303451 A4 EP2303451 A4 EP 2303451A4
Authority
EP
European Patent Office
Prior art keywords
mullite
ethylene oxide
oxide catalysts
containing carrier
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09798545.1A
Other languages
German (de)
French (fr)
Other versions
EP2303451A2 (en
EP2303451B1 (en
Inventor
Serguei Pak
Andrzej Rokicki
Shuji Kawabata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scientific Design Co Inc
Original Assignee
Scientific Design Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scientific Design Co Inc filed Critical Scientific Design Co Inc
Publication of EP2303451A2 publication Critical patent/EP2303451A2/en
Publication of EP2303451A4 publication Critical patent/EP2303451A4/en
Application granted granted Critical
Publication of EP2303451B1 publication Critical patent/EP2303451B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B01J27/055—Sulfates with alkali metals, copper, gold or silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP09798545.1A 2008-07-18 2009-06-26 Mullite-containing carrier for ethylene oxide catalysts Not-in-force EP2303451B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8201608P 2008-07-18 2008-07-18
US12/360,457 US8349765B2 (en) 2008-07-18 2009-01-27 Mullite-containing carrier for ethylene oxide catalysts
PCT/US2009/048816 WO2010008920A2 (en) 2008-07-18 2009-06-26 Mullite-containing carrier for ethylene oxide catalysts

Publications (3)

Publication Number Publication Date
EP2303451A2 EP2303451A2 (en) 2011-04-06
EP2303451A4 true EP2303451A4 (en) 2017-02-22
EP2303451B1 EP2303451B1 (en) 2019-04-03

Family

ID=41530882

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09798545.1A Not-in-force EP2303451B1 (en) 2008-07-18 2009-06-26 Mullite-containing carrier for ethylene oxide catalysts

Country Status (11)

Country Link
US (2) US8349765B2 (en)
EP (1) EP2303451B1 (en)
JP (1) JP2011528611A (en)
KR (1) KR20110033287A (en)
CN (2) CN105727916A (en)
BR (1) BRPI0916618A2 (en)
CA (1) CA2731213A1 (en)
MX (1) MX2011000720A (en)
RU (1) RU2495715C2 (en)
TW (1) TWI471170B (en)
WO (2) WO2010008920A2 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US8883678B2 (en) * 2010-06-04 2014-11-11 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
JP5656709B2 (en) * 2011-03-24 2015-01-21 株式会社日本触媒 A method for recovering an active component from a catalyst for producing ethylene oxide after use, and a method for producing a catalyst using the recovered component.
JP5656708B2 (en) * 2011-03-24 2015-01-21 株式会社日本触媒 A method for recovering an active component from a catalyst for producing ethylene oxide after use, and a method for producing a catalyst using the recovered component.
WO2012140616A1 (en) * 2011-04-14 2012-10-18 Basf Se Zinc-containing catalyst for the production of ethylene oxide
CN102989517B (en) * 2011-09-09 2015-07-29 中国石油天然气股份有限公司 Alumina support of bimodal pore size distribution and preparation method thereof
CN102989516B (en) * 2011-09-09 2015-05-27 中国石油天然气股份有限公司 Alumina-titanium oxide composite carrier and preparation method
SG11201401948UA (en) * 2011-10-31 2014-09-26 Dow Technology Investments Llc Methods for producing epoxidation catalysts and epoxidation methods utilizing these
CN104066504B (en) * 2011-11-21 2017-10-10 科学设计公司 Carrier for epoxyethane catalyst
TWI703108B (en) 2015-06-02 2020-09-01 美商科學設計有限公司 Method for producing porous bodies with enhanced properties
BR112019011162B1 (en) 2016-12-02 2022-08-16 Shell Internationale Research Maatschappij B.V. METHOD FOR THE CONDITIONING OF AN ETHYLENE EPOXIDATION CATALYST AND METHOD TO IMPROVE THE SELECTIVITY OF SUCH CATALYST IN AN ETHYLENE EPOXIDATION PROCESS
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
CN107715868B (en) * 2017-10-27 2019-07-23 万华化学集团股份有限公司 A kind of preparation method and its usage of oxidation catalyst of cyclopropene
EP3749449B1 (en) 2018-02-07 2022-02-02 Basf Se Method for preparing a silver impregnation solution
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57171435A (en) * 1981-04-14 1982-10-22 Noritake Co Ltd Alumina catalyst carrier for partial oxidation and prepatation thereof
US20080081920A1 (en) * 2006-09-29 2008-04-03 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1170663A (en) 1967-03-22 1969-11-12 Shell Int Research Process for preparing Silver Catalysts
US3702259A (en) 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4061659A (en) 1976-06-28 1977-12-06 Shell Oil Company Process for the production of ethylene oxide
US4087385A (en) 1977-03-23 1978-05-02 The Dow Chemical Company Process for making a silver catalyst for oxidizing ethylene to ethylene oxide
GB1594362A (en) 1977-05-23 1981-07-30 Ici Ltd Production of alkylene oxides and catalysts therefor
FR2412538A1 (en) 1977-12-22 1979-07-20 Ugine Kuhlmann SILVER BASED CATALYZERS FOR ETHYLENE OXIDE PRODUCTION
US5387751A (en) 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
US4350616A (en) 1980-07-03 1982-09-21 The Dow Chemical Company Method of making catalysts for the production of ethylene oxide
DE3528313A1 (en) 1985-08-07 1987-02-12 Basf Ag SILVER CATALYST, ITS PRODUCTION AND USE
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
DE68925767T2 (en) 1988-08-30 1996-08-14 Union Carbide Corp Catalysts for the production of ethylene oxide and processes for their production
EP0383636A1 (en) 1989-02-17 1990-08-22 Nippon Shokubai Co., Ltd. Carrier for catalyst and method for production thereof
US5187140A (en) 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5102848A (en) 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5112795A (en) 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
US5145824A (en) 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
CA2089510C (en) 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5407888A (en) 1992-05-12 1995-04-18 Basf Aktiengesellschaft Silver catalyst
US5266548A (en) 1992-08-31 1993-11-30 Norton Chemical Process Products Corp. Catalyst carrier
US5380697A (en) 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5418202A (en) 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
JP3537535B2 (en) 1994-07-14 2004-06-14 株式会社中埜酢店 Clinical test method based on immunoglobulin G-linked sugar chain structure
DE19506843A1 (en) * 1995-02-28 1996-08-29 Studiengesellschaft Kohle Mbh Microporous amorphous mixed metal oxides for shape-selective catalysis
US6035276A (en) 1997-10-17 2000-03-07 Veritas Medical Services, Inc. Medical practitioner credentialing system
JP3636912B2 (en) * 1997-12-25 2005-04-06 株式会社日本触媒 Method for producing catalyst for producing ethylene oxide
TW426545B (en) * 1997-12-25 2001-03-21 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
JP4210255B2 (en) * 1997-12-25 2009-01-14 株式会社日本触媒 Silver catalyst for producing ethylene oxide and method for producing ethylene oxide
JP2005052839A (en) * 1998-02-20 2005-03-03 Nippon Shokubai Co Ltd Production method of ethylene oxide
DE69919425T2 (en) 1998-02-20 2005-09-08 Nippon Shokubai Co. Ltd. Silver catalyst for the production of ethylene oxide, process for its preparation and process for the production of ethylene oxide
JP4001429B2 (en) * 1998-02-20 2007-10-31 株式会社日本触媒 Silver catalyst for producing ethylene oxide, method for producing the same, and method for producing ethylene oxide
AU754631B2 (en) 1998-11-17 2002-11-21 Nippon Shokubai Co., Ltd. Carrier for catalyst for use in production of ethylene oxide, catalyst for use in production of ethylene oxide, and method for production of ethylene oxide
US6372925B1 (en) 2000-06-09 2002-04-16 Shell Oil Company Process for operating the epoxidation of ethylene
DE10135490A1 (en) 2001-07-20 2003-01-30 Basf Ag Process for the hydrogenation of aromatic compounds with hydrogen containing residual gas
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
AU2003284195A1 (en) 2002-10-28 2004-05-25 Shell Internationale Research Maatschappij B.V. Olefin oxide catalysts
MY136774A (en) 2003-02-28 2008-11-28 Shell Int Research Method of improving the operation of a manufacturing process
CN1838991A (en) * 2003-08-22 2006-09-27 联合碳化化学及塑料技术公司 Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
CA2538989A1 (en) * 2003-08-22 2005-03-17 Union Carbide Chemicals & Plastics Technology Corporation Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
US7507844B2 (en) 2005-05-09 2009-03-24 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides
JP5313665B2 (en) 2006-05-02 2013-10-09 株式会社日本触媒 Olefin partial oxidation catalyst, method for producing the same, and method for producing alkylene oxide
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57171435A (en) * 1981-04-14 1982-10-22 Noritake Co Ltd Alumina catalyst carrier for partial oxidation and prepatation thereof
US20080081920A1 (en) * 2006-09-29 2008-04-03 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2010008920A2 *

Also Published As

Publication number Publication date
RU2495715C2 (en) 2013-10-20
US20100016617A1 (en) 2010-01-21
MX2011000720A (en) 2011-09-01
CN105727916A (en) 2016-07-06
KR20110033287A (en) 2011-03-30
US8349765B2 (en) 2013-01-08
WO2010008920A3 (en) 2010-04-15
WO2010008919A2 (en) 2010-01-21
US8916495B2 (en) 2014-12-23
WO2010008920A2 (en) 2010-01-21
BRPI0916618A2 (en) 2019-03-12
CA2731213A1 (en) 2010-01-21
CN102099109A (en) 2011-06-15
TW201016314A (en) 2010-05-01
US20130116456A1 (en) 2013-05-09
EP2303451A2 (en) 2011-04-06
TWI471170B (en) 2015-02-01
EP2303451B1 (en) 2019-04-03
RU2011106030A (en) 2012-08-27
JP2011528611A (en) 2011-11-24

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